Abstract: A method for producing a rigid, closed-cell polyurethane foam having a free-rise density of from about 1.3 lbs/ft.3 to about 4 lbs/ft.3 and exhibiting a shrinkage of less than 10%, comprises mixing together an isocyanate, at least one alkyl alkanoate blowing agent and at least one polyol having a hydroxyl number of from about 150 to about 800 and being selected from the group consisting of polyalkoxylated amines, polyalkoxylated ethers, and polyester polyols, to form a reaction mixture that is curable to produce such foam.

Abstract: The invention relates to a process for producing flexible polyurethane foams by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups in the presence of c) blowing agents, wherein the component b) comprises at least one polyether carbonate polyol bi) which can be prepared by addition of carbon dioxide and alkylene oxides onto H-functional starter substances using DMC catalysts and has a functionality of at least 2, a hydroxyl number in the range from 10 to 500 mg KOH/g and a content of incorporated carbon dioxide in the form of carbonate units of at least 2% by weight.

Abstract: A viscoelastic polyurethane foam is the reaction product of at least one natural oil derived polyol and at least one aromatic compound having an average of more than one isocyanate group. A viscoelastic polyurethane foam has an air flow of at least about 0.5 l/s, wherein the foam is formed in the substantial absence of copolymer polyol and has not (yet) been mechanically reticulated and is preferably prepared using at least one natural oil derived polyol, more preferably in an amount of at least about 20 weight percent of the polyols used. A process of preparing a viscoelastic foam, comprises steps of (A) forming a reaction mixture including at least one polyol, at least one polyisocyanate, water, at least one catalyst wherein a the polyol comprises at least one natural oil derived polyol; and (B) subjecting the reaction mixture to conditions sufficient to result in the reaction mixture to expand and cure to form a viscoelastic polyurethane foam.

Abstract: A composition for making a polyurethane foam includes a non-fugitive tertiary amine urethane catalyst and an ester alcohol or substituted carbamate thereof. Foams prepared from the reaction of a polyol and an organic isocyanate in the presence of these ingredients show excellent resistance to deterioration of physical properties upon humid ageing.

Abstract: A polyurethane foam sponge that picks up at least 80% of water in a wipe dry performance test is made by variably felting (compressing under heat and pressure) a foam sheet to a compression ratio of about 1.05 to 2.9. The resulting foam sponge has from 5% to 25% of its top and bottom surface portions modified by the variable felting, while its core portion remains substantially unmodified.

Abstract: A polyurethane molding is composed of at least two different polyurethane materials, namely of a polyurethane gel and a polyurethane foam. The foam and the gel are arranged in layers one above another so that both materials act together as spring or damping element with respect to a load in the transverse direction. These moldings may preferably be used as seat cushions.

Abstract: The invention provides a polyurethane foam manufactured from a polyisocyanate and a polycarbonate polyol. Moreover, the invention provides a method of manufacturing the polyurethane foam manufactured from a polyisocyanate and a polycarbonate polyol, comprising mixing the polyisocyanate and polycarbonate polyol together and foaming same.

Abstract: The invention provides a polyurethane foam manufactured from a polyisocyanate and a polycarbonate polyol. Moreover, the invention provides a method of manufacturing the polyurethane foam manufactured from a polyisocyanate and a polycarbonate polyol, comprising mixing the polyisocyanate and polycarbonate polyol together and foaming same.

Abstract: A storage stable polyol composition composed of at least 25% by weight of a polyol derived from a natural oil and a blowing agent composition which includes greater than 50% by weight of n-pentane.

Abstract: A new class of polyols derived from renewable resources, including polyglycerol and vegetable oils, the use of such polyols in polyurethane foams and cast resins, and methods for making the polyols and polyurethanes are provided.

Abstract: The polishing pad is suitable for planarizing at least one of semiconductor, optical and magnetic substrates. The polishing pad includes a cast polyurethane polymeric material formed with an isocyanate-terminated reaction product formed from a prepolymer reaction of a prepolymer polyol and a polyfunctional isocyanate. The isocyanate-terminated section product has 4.5 to 8.7 weight percent unreacted NCO; and the isocyanate-terminated reaction product is cured with a curative agent selected from the group comprising curative polyamines, curative polyols, curative alcoholamines and mixtures thereof. The polishing pad contains at least 0.1 volume percent filler or porosity.

Abstract: The invention relates to a process for producing rigid polyurethane and polyisocyanurate foams by reacting polyisocyanates a) with compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) in the presence of blowing agents c), wherein prepolymers which comprise isocyanate groups and have an NCO content in the range from 25 to 31% by weight, based on the weight of the prepolymer, and are prepared by reacting ai) mixtures of monomeric and polymeric diphenylmethane diisocyanate with at least one compound having more than one hydrogen atom which is reactive toward isocyanate groups aii) are used as polyisocyanates a) and the compounds having at least two hydrogen atoms which are reactive toward isocyanate groups b) comprise at least one polyester alcohol bi) which comprises at least one starting component which is hydrophobic.

Abstract: A process for preparing hydrophobic polyols that includes reacting A) a mixture having an OH content of from 180 to 300 mg KOH/g, a viscosity at 23° C. of from 5000 to 20 000 mPas and an OH functionality of from 2.8 to 4.5 including from 5 to 20 wt. % of 3-pentadecadienylphenol, from 5 to 10 wt. % of 3-pentadecadienyl-recorcinol and from 1 to 5 wt. % of 2-methyl 3-pentadecadienylrecorcinol; with B) alkylene oxides (AO) with addition of the AO monomers onto the AO-reactive groups of component A); the ratio of the amounts of A) to B) being from 1:9 to 9:1; where the hydrophobic polyols have an OH number of from 140 to 220 mg KOH/g and a viscosity at 23° C. of from 1000 to 4000 mPas. The hydrophobic polyols can be used in polyurethane systems, in coatings, adhesive bonds, sealants or moulding compounds, which can be used to coat substrates.

Abstract: The invention relates to isocyanate adducts which can be prepared by reacting at least one polyisocyanate with compounds having at least two hydrogen atoms which are reactive toward isocyanate groups and have a crystalline content of less than 10 J/g determined by differential scanning calorimetry in accordance with DIN 51 004 at 20 K/min from room temperature to 250° C. using a nitrogen flow of 3 l/h as carrier gas and an aromatics content reported as carbon atoms in aromatic rings of less than 31% by weight, based on the total weight of the isocyanate adducts.

Abstract: This invention relates to a process for the production of rigid and semi-rigid foams at low isocyanate levels, and to the foams produced by this process. The process comprises reacting a polyisocyanate component with an isocyanate-reactive component, in the presence of at least one blowing agent, at least one surfactant and at least one catalyst. Suitable isocyanate-reactive components are characterized as having a solids content of at least 40% by weight, and an overall hydroxyl number of the remaining liquid, non-solids portion of at least 160. In addition, the isocyanate-reactive component comprises at least 50% by weight of a polymer polyol having a solids content of at least 30% by weight and in which the base polyol has a hydroxyl number of at least 75.

Abstract: The present invention relates to polyol compositions which can be used to produce dimensionally stable, low density water-blown rigid foams which have acceptable compressive strengths and acceptable k-factors. In one embodiment of the present invention, the polyol compositions are composed of at least one aromatic amine-initiated polyether polyol and at least one polyether polyol having a functionality greater than or equal to 2.5 in which at least 50% by weight of the polyol composition is aromatic amine-initiated polyether polyol and in which no more than 50% by weight of the polyol composition is polyether polyol having a functionality greater than or equal to 2.5.

Abstract: The invention relates to novel microporous coatings based on polyurethane polyurea, and to a process for the production of microporous coatings, in which a composition comprising an aqueous, anionically hydrophilised polyurethane dispersion (I) and a cationic coagulant (II) containing a cationically hydrophilised polyurethane polyurea dispersion is foamed and dried.

Abstract: Odorless polyester polyols are described herein which are useful for forming substantially odorless polyurethane foams for cosmetic formulations. The polyester polyols are manufactured using a process that includes a stripping step to remove odorous volatile compounds.

Abstract: A method of forming a polyethercarbonate polyol enhances incorporation of CO2 into the polyethercarbonate polyol. The method provides a catalyst including a multimetal cyanide compound. The multimetal cyanide compound has an ordered structure defined by a cationic catalytic center and an anionic backbone with the anionic backbone spatially arranged about the cationic catalytic center. The anionic backbone is modified with a supplemental anionic spacer to affect the spatial arrangement and catalytic activity of the cationic catalytic center. The supplemental anionic spacer is incorporated into the multimetal cyanide compound to establish the general formula, M1a[M2b(CN)cMd3Xe]f, wherein M1, M2, and M3 are various metal ions and X is the supplemental anionic spacer. An H-functional initiator, an alkylene oxide, and CO2 are reacted in the presence of the modified multimetal cyanide compound to form the polyethercarbonate polyol.

Abstract: The present invention relates to a process for producing a synthetic resin foam which comprises reacting at least one polyol with at least one polyisocyanate compound in the presence of an organic blowing agent, wherein the organic blowing agent is a blowing agent for synthetic resin foams which is characterized by being a mixture comprising 1,1,1,3,3-pentafluorobutane (HFC-365mfc) and at least one halogen-containing compound and optionally containing at least one member selected from the group consisting of glycol compounds and amide compounds. Also provided are: a premix comprising the blowing agent and a polyol mixture; and a process for producing a synthetic resin foam from these.

Abstract: Super-soft foam materials, optionally for use as medical dressings, are provided. The pads are made of a foam prepared from NCO-terminated prepolymers in combination with an aqueous phase including fatty alcohols and alkyl polysaccharides. The foam may optionally contain at least one medicinal agent.

Abstract: We describe a process for the preparation of polyurethane polyol from CARDANOL 3-(8pentadecenyl)phenol, derived from cashew nut shell liquid (CNSL), a renewable resource material. The polyol is made by oxidation with peroxy acid generated in situ to give epoxidised CARDANOL 3-(8-pentadecenyl)phenol and the epoxy derivative is converted to the polyol in the presence of the organic acid. The cardanol-based polyol may be reacted with isocyanate to form polyurethane. Alternatively blowing agents are included with the cardanol-based polyol before it is reacted with the isocyanate. These polyols are especially suitable for making rigid foams of very low density and high compressive strength.

Abstract: The present invention relates to a method for the continuous mixing of at least one polyol component and at least one isocyanate component and optionally additives to form a polyurethane reaction mixture in a stirrer mixer with an axially conveying stirrer.

Abstract: Process for the preparation of foamed thermoplastic polyurethanes characterized in that the foaming of the thermoplastic polyurethane is carried out in the presence of thermally expandable microspheres.

Abstract: A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing a blowing agent comprising a C4 or C5 hydrocarbon, or mixtures thereof, with an average molecular weight of ?72 g/mole and a boiling point in the range of 27.8 to 50° C., and a silicone surfactant comprising a polyether-polysiloxane copolymer represented by the following formula: (CH3)3—Si—O—(Si(CH3)2—O)x—(Si(CH3)(R)O)y—Si(CH3)3 where R=(CH2)3—O—(—CH2—CH2—O)a—(CH2—CH(CH3)—O)b—R?, and where R? is H, (CH2)zCH3, or C(O)CH3; x+y+2 is 60–130; x/y is 5–14; z is 0–4; the total surfactant molecular weight, based on the formula, is 7000–30,000 g/mole, the wt % siloxane in the surfactant is 32–70 wt %, the blend average molecular weight (BAMW) of the polyether portion is 450–1000 g/mole, and the mole % of ethylene oxide in the polyether portion is 70–100 mole %.

Abstract: The invention relates to flame resistant rigid foams and formulations useful for the production thereof. The polyol formulation must include at least one substance which is inert with respect to isocyanates, does not deplete the ozone layer and has a boiling point below 55° C. and a reaction product of at least one compound with an aromatic ring, at least one aldehyde or ketone and at least one primary or secondary amine. This polyol formulation is reacted with an isocyanate, optionally with other commonly used additives, to produce rigid flame resistant foams.

Abstract: A solvent-free process for making a polyol fatty acid polyester composition useful for preparation of polyurethanes is described. These compositions are preferably made by reaction of a natural oil (from plant or animal) with a multi-functional hydroxyl compound derived from a natural source, such as sorbitol, in presence of an alkali metal salt or base such as potassium hydroxide as a catalyst which also acts to saponify the reaction mixture. The hydroxyl content of the prepared composition depends on the amount of the multi-functional hydroxyl compound used in the preparation. In another embodiment, the hydroxyl groups of these compositions are reacted with an isocyanate, such as the polymeric diphenylmethane diisocyanate (also known as 4,4?-diphenyl methane diisocyanate, or MDI) to form polyurethanes in a conventional manner.

Abstract: The present invention generally includes material comprising the reaction product of an A-side comprising an isocyanate and a B-side comprising a crosslinker, a catalyst, and a modified vegetable oil. The present invention also generally includes a material comprising the reaction product of an A-side comprising an isocyanate and a B-side comprising an oxylation compound, a modified vegetable oil, and a catalyst.

Abstract: An apparatus is disclosed for flatproofing a tire and wheel assembly with a flexible, lightweight foam-fill by supplying at least two polyurethane reactive materials to a static mixer. The static mixer mixes the reactants, and a nucleating gas is supplied to the mixed reactants in the static mixer to form a liquid reactant mixture with entrained gas. The reactant mixture is injected into the tire and wheel assembly where the mixture reacts and foams replacing the air in the tire with a flexible, lightweight semi-open cell foam-fill. The foam-filled tire and wheel assembly is then allowed to cure.

Abstract: Disclosed is a composition for preparing a rigid polyurethane foam having a good demolding property by defining polyol component and catalyst component. The polyol component comprises 40˜60 wt. % of polyol obtained by polymerization with an organic oxide using sorbitol as an initiator, 5˜10 wt. % of polyol obtained by polymerization with an organic oxide using ethylene diamine as an initiator, 20˜30 wt. % of polyol obtained by polymerization with an organic oxide using toluene diamine or toluene diamine and triethanol amine as a single or a complex initiator, and, optionally, 5˜20 wt. % of multivalent polyol of an ester structure, and the catalyst component is chosen in a group comprising a foaming catalyst, a gelling catalyst, a trimerization catalyst, a mixed form of the foaming catalyst and the gelling catalyst, and compound thereof.

Abstract: A static dissipative flexible polyurethane foam is formed under free rise expansion conditions from a polyether graft polyol and an isocyanate, wherein one or more anti-static additives are incorporated into the reaction mix in an amount from 0.10 to 20 parts by weight. Water is added in an amount of from 0.2 to 1.0 parts per weight. Upon curing, the foam has a density in the range of 6 to 20 pounds per cubic foot, a surface resistivity below 1×1011 ohms/square, and a pore size in the range of 100 to 250 pores per inch. The foam may be fabricated (cut or shaped) to form a shaped article, such as a roller, a clean room wipe, a cosmetic applicator or a packaging element.

Abstract: The present invention relates to a preparation method for low-density polyurethane foam excelling in the flame retardance and the dimensional stability, wherein rigid polyurethane foam having the average value for the ratio of lengthwise direction diameter/cross direction diameter of cells being 1.0 to 1.4 and the density of 20 to 40 kg/m3 is prepared by combining, as blowing agent, carbon dioxide generated in the reaction between water and polyisocyanate and carbon dioxide under supercritical state, subcritical state or liquid state, and by adding said water and said carbon dioxide under liquid state into said polyol component prior to mixing the polyisocyanate component and the polyol component, and to rigid polyurethane foam obtained by said method.

Abstract: Single component compositions for making a moisture-cured polyurethane foam are disclosed. Foam produced from the compositions of the present invention produce very low foaming pressure due to their 60-95 percent open-cell content. After these compositions are applied and cure, they form a permanent seal around the perimeter of installed fenestration products.

Abstract: A process for producing a polyurethane foam which comprises mixing a polyol solution comprising 100 parts by weight of a polyester-polyol, 0.1 to 1.8 parts by weight of water and 0.1 to 5 parts by weight of urea, and a catalyst with a polyisocyanate compound and foaming the mixture. According to the process, there can be produced a polyurethane foam which satisfies both productivity and moldability even when having a low density, and is suitable for use in shoe soles.

Abstract: A thermoformable polyurethane foam having excellent compression set resistance, and a thermoformable polyurethane foam having excellent compression set resistance and shape retention under load. In another embodiment, at least one additional layer of a polyurethane foam is integrally bonded to the thermoformable foam. A moisture management system for polyurethane foams is also described. The foams have particular utility as shoe sole inserts.

Abstract: Raw materials for anti-cracking polyurethane foams comprises: a mixed polyol 100 weight parts; an isocyanate 140˜180 weight parts; a catalyst 1.0˜3.0 weight parts; water 1˜2.5 weight parts; a foam blowing agent 30.0˜35.0 weight parts; and an additive 1.0˜3.0 weight parts, and a preparation method thereof.

Abstract: Polyurethane elastomers having a defined node density are produced from specific polyetherester polyols. These elastomers are particularly useful for the production of microcellular and solid polyurethane elastomer components.

Abstract: The present invention relates to polyester urethanes comprising polypentadecalactone segments. These polyester urethanes do show good properties which may be adjusted in a controlled manner. In preferred embodiments the polyester urethanes display additionally polycaprolactone segments. Such polymer may show shape memory effects.

Abstract: A process is disclosed for producing resilient polyurethane foams by foaming an organic polyisocyanate, an iso-cyanate-reactive compound and a fusible polymer. The improvement in the hardness of the foams is achieved without adversely affecting the other properties of the foams, such as tensile strength and elongation.

Abstract: In the process of the present invention, an organic polyisocyanate is reacted with a sorbitol-based polyether polyol having a number average molecular weight of from about 400 to about 1500, in the presence of a pentafluoropropane blowing agent, and a catalyst.

Abstract: An ester polyurethane foam is prepared by reacting a mixture of one or more polyester polyols with one or more isocyanates and one or more silicone surfactants in the presence of a blowing agent, such as water, and other additives, such as catalysts. The cured foam is chemically treated in a caustic solution and is then felted (compressed under heat and pressure) to form a hydrophilic ester polyurethane foam having a water absorption rate of at least 30 pounds of water per square foot per minute (1.44 kPa/min). The foam also has greater water holding capacity and wet strength than cellulose.

Abstract: The present invention is directed to a process for preparing water-blown rigid polyurethane foams having at least an 80% closed-cell content which involves reacting a) at least one polyol mixture which is composed of (i) at least one polymer polyol; (ii) at least one polyol having a hydroxyl value within the range of from about 200 to about 800; and (iii) optionally, at least one polyol having a hydroxyl value within the range of from about 25 to about 115; with b) at least one polymeric isocyanate and/or a prepolymer thereof; in the presence of c) optionally, at least one catalyst; d) water; and e) optionally, at least one additive or auxiliary agent. The present invention is also directed to the closed-cell water blown rigid polyurethane foams produced by the process of the present invention. The invention is further directed to a polyurethane-foam forming mixture which is used to produce the water-blown rigid polyurethane foams of the present invention.

Abstract: A process for preparing a polyurethane foam is provided which comprises reacting a polyisocyanate and an active hydrogen-containing component, including water and an organic polyol, in the presence of a catalytically effective amount of a delayed action amine catalyst system, and optionally an organotin catalyst. The delayed action catalyst is composed of the reaction product of (a) one or more carboxylic acids having hydroxy and/or halo functionality; (b) one or more tertiary amine ureas; and, optionally, (c) a reactant selected from the group consisting of specific reactive tertiary amine(s), specific tertiary amine carbamate(s) and mixture thereof.

Abstract: A rigid polyurethane foam is described which is preferably, while not exclusively, used for manufacturing composite building elements used in buildings or for manufacturing industrial constructions. The foam has a structure consisting of closed cells substantially free therein of optionally halogenated hydrocarbon foaming agents, having an adhesion strength to a supporting substrate, measured according to standards EN 1607, equal to or higher than 0.7 kg/cm2. The polyurethane foam may be obtained starting from at least one polyol and at least one isocyanate compound by using a water-based foaming agent entirely compatible with the strictest environmental requirements, and has good mechanical characteristics, characteristics of dimensional stability, characteristics of adhesion to a supporting substrate and, possibly, characteristics of fire resistance.

Abstract: The polyisocyanate polyaddition products comprise hydrophobic compounds plus at least one further compound selected from the group consisting of: (i) organic, cyclic compounds having a molecular weight of from 200 to 3000 g/mol, (ii) salts of metals of transition groups I, II and/or VIII, (iii) organic and/or inorganic acid anhydrides, (iv) cyclic sulfonic esters and/or sulfones, (v) lactones, lactams and/or cyclic esters and/or (vi) &agr;,&bgr;-unsaturated carboxylic acids, &agr;,&bgr;-unsaturated carboxylic acid derivatives, &agr;,&bgr;-unsaturated ketones and/or &agr;,&bgr;-unsaturated aldehydes.

Abstract: The subject invention provides a method of forming high resilience slabstock polyurethane foam having random cell structures to produce latex-like feel and characteristics. The method includes the first step of providing an isocyanate-reactive component and an isocyanate component to react with the isocyanate-reactive component. A first nucleation gas is provided under low pressure and is added into at least one of the isocyanate-reactive component and the isocyanate component to produce a first cell structure in the polyurethane foam. A second nucleation gas is provided under low pressure, being different than the first nucleation gas, and is added into at least one of the isocyanate-reactive component and the isocyanate component to produce a second cell structure in the polyurethane foam that is different than the first cell structure.

Abstract: A process for preparing a polyurethane foam, comprising reacting a polyol having a number-average molecular weight of not less than 1000 and less than 2500 with a polyisocyante compound in the presence of a catalyst and a blowing agent in a mold, to give a molded article having a density of 0.4 to 0.8 g/cm3, and heating the resulting molded article to a temperature of 60° to 100° C. The polyurethane foam is used as a cushioning material such as shoe soles of sports shoes.

Abstract: The present invention provides rigid foams made from aromatic polyester polyols and polyisocyanates. The foams are isocyanate-based foams and are preferably prepared without cell nucleating agents, and are formed from a mixture containing an aromatic polyester polyol, a polyisocyanate, and a blowing agent that includes water. The foams have a high closed cell content with cells having diameters of about 160 microns or less, high thermal resistance, and flame retardancy.

Abstract: An ester polyurethane foam is prepared by reacting a mixture of one or more polyester polyols with one or more isocyanates and one or more silicone surfactants in the presence of a blowing agent, such as water, and other additives, such as catalysts. The cured foam is chemically treated in a caustic solution and is then felted (compressed under heat and pressure) to form a hydrophilic ester polyurethane foam having a water absorption rate of at least 30 pounds of water per square foot per minute (1.44 kPa/min). The foam also has greater water holding capacity and wet strength than cellulose.

Abstract: Semiflexible and flexible polyurethane foams having significantly reduced fogging and improved physical properties such as tensile strength, useful in the transportation industry, are obtained from a polyurethane foam-forming reaction-mixture containing as a polyester polyol for the foam a polyester polyol substantially free of any ether components which comprising: (a) at least one polyfunctional carboxylic acid and/or carboxylic anhydride compound; (b) at least one linear polyhydric alcohol; and (c) at least one branched polyhydric alcohol wherein the reactants of the polyester polyol are selected such that they cannot combine to provide a cyclic ester comprising a 12 to 14 membered ring. Optionally, the polyester polyol can further contain (d) a branched polyol having a functionality of at least three.