Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises preparing a crosslinking elastomer concentrate that is added to a heated asphalt cut in a stirred tank and then aged to improve SHRP high temperature grading. The crosslinking elastomer concentrate is prepared by adding thermoplastic elastomer and crosslinking agents to a suitable carrier oil, preferably an aromatic oil such as Hydrolene H series. This concentrate is maintained at a temperature that promotes association between the crosslinking agents and the elastomer for a time sufficient for association to substantially complete. In one embodiment, the associating time is in excess of 2 hours up to 24 hours. The asphalt is heated to a temperature sufficient to allow the stirring of the asphalt in the tank. The crosslinking thermoplastic elastomer concentrate is added to the asphalt while continuing to stir the asphalt.

Abstract: The present invention is an asphalt-based, cold paving formulation that provides increased flexibility with respect to the choice of aggregate types, asphalt emulsion types, type and amount of the surfactants used to produce the asphalt emulsion, asphalt emulsion pH's and application temperature's than conventional cold paving formulations while providing good mix times and curing behavior. The present invention includes an asphalt-based formulation formed by mixing aggregate; water; an asphalt emulsion; at least one first compound in aqueous solution selected from the group consisting of alkali metal salts, alkali metal hydroxides, ammonium salts and ammonium hydroxide; and at least one second compound in aqueous solution selected from the group consisting of Group IIA salts, Group IIIA salts, Group IIIB salts, copper salts, zinc salts, cadmium salts, manganese salts, iron salts, cobalt salts and nickel salts.

Abstract: An asphalt modifier containing 1-50 wt. % of asphalt. A modified asphalt is produced by mixing the asphalt modifier and asphalt. The asphalt modifier of this invention has excellent uniformity of dispersion into asphalt so that the asphalt modifier can be effectively uniformly dispersed into asphalt for a short time, thereby enabling a modified asphalt in which modifying ingredients are uniformly dispersed in the asphalt to be produced for a short time.

Abstract: A filler composition comprising a filler material and a hydrocarbonaceous material having a volatility of less than or equal to 5% at 200° and a time of 2 hours. The hydrocarboneous material may comprise a bituminous material comprising bitumen, oxibitumen, or mixtures thereof; petroleum/oil cracker residue bottoms, for example ethylene cracker residues (ECR); carbon black feedstock fuels comprising less than or equal to 5%, by weight, sulfur and having a molar hydrogen to carbon ratio between 0.90:1 and 1.10:1; linear or cyclic condensation products comprising an aromatic alcohol, for example, phenol, catechol, resorcinol, naphthol, and an aldehyde, for example formaldehyde, preferably where the aromatic alcohol is present in a molar excess; or mixtures thereof.

Abstract: Polymer modified bituminous compositions which are stable against phase separation are provided at greater levels of incorporation of elastomeric polymer having a conjugated diene structure, such as styrene-butadiene rubbers, and/or cross-linking agent, specifically sulfur, by incremental addition of elastomeric polymer and/or cross-linking agent into the bitumen at elevated temperatures of about 150° to about 220° C.

Abstract: The present invention relates to novel polymer modified asphalt polyphosphoric and superphosphoric acid treated binder compositions having enhanced high service temperature performance properties and the method of making them and to road paving asphalts containing them.

Abstract: A process for the preparation of an asphalt and polymer composition in which a minor amount of polymer component is subjected to a crosslinking. An asphalt base material is heated in a mixing chamber at a temperature sufficient to melt the asphalt and allow stirring of the asphalt within the chamber. A thermoplastic elastomer is added to the chamber in an amount not greater than 12 wt. %. While the asphalt elastomer formulation is stirred, a crosslinking agent is added in an amount effective to crosslink the thermoplastic elastomer. The crosslinking agent formulation comprises at least two components. One component is a thiopolymer incorporating organic sulfur prepared by the reaction of 6-tertiary butyl cresol and sulfur dichloride which reacts to produce a reaction product comprising 4,4-thiobis(6-tertiary butyl-m-cresol) and the thiopolymer, followed by subsequent separation of the 4,4-thiobis(6-tertiary-butyl-m-cresol) from the thiopolymer product.

Abstract: A storage-stable modified asphalt composition, which comprises: 50-97.7 parts by weight of a base asphalt, 2.0-20.0 parts by weight of a polymer having double bonds, 0.1-20.0 parts by weight of a compatilizer, 0.1-10.0 parts by weight of a cross-linking reagent, and 0.1-10.0 parts by weight of a organic polar compound, and the softening point difference of its product determined by the stability test is lower than 2.5° C. The process for preparing said modified asphalt composition is mixing 50-97.7 parts by weight of a base asphalt, 2.0-20.0 parts by weight of a polymer having double bonds, 0.1-20.0 parts by weight of a compatilizer, 0.1-10.0 parts by weight of a cross-linking reagent, and 0.1-10.0 parts by weight of a organic polar compound under certain conditions. The modified asphalt provided by the present invention has good storage-stability. The preparation process provided by the present invention is simple, and there is no need for special apparatus.

Abstract: An acid-reacted polymer-modified asphalt composition comprising (1) at least about 80 weight percent, based upon the composition, of an asphalt; (ii) about 0.2 to about 15 weight percent, based upon the composition, of a polymer containing available epoxy groups; and (iii) an amount of an acid effective for promoting chemical bonding between the asphalt and the polymer, wherein the composition exhibits substantially improved Dynamic Shear Rheometer stiffness values without an appreciable loss in the G″ viscous component of complex modulus, and low temperature creep stiffness and “m” values.

Abstract: An asphalt emulsion and method and apparatus of making the same.

Abstract: Uses of syndiotactic/atactic block polypropylene are provided in which the molecular weight thereof is preferably at least 120 kD. The syndiotactic/atactic block polypropylene may be used as a polypropylene modifier, a component in an adhesive composition, a shock absorber component, a waterproof membrane component, a packaging film or component thereof, a shapable composition component, and an acoustic absorbent material component, a composition for moulding into a footwear component, a bitumen modifier, a compatibiliser, an emulgator or an emulsifier, as a viscosity improver, and as a spilled oil absorber.

Abstract: A bitumen emulsion comprising bituminous binder, emulsifier, and water. The bituminous binder comprises bitumen and an oxidised wax, and optionally one or more polymers. The incorporation of the oxidised wax into the bituminous binder provides modified bitumen with both a high softening point and a low enough viscosity to allow it to be emulsified. The emulsion may be used as a tack coat in applying a waterproofing layer to a roof base. The emulsion may be made using a static mixing emulsion process.

Abstract: Bituminous compositions of the bitumen-polymer type, in homogenous phase, contain at least one bitumen base and are prepared from at least one polymer of the thermoplastic polyolefin type. These compositions have a thermoplastic polyolefin content of at least 1% by weight of which the crystallinity rate is greater than or equal to 30%, a melting temperature greater than or equal to 110° C. and a penetrability at 25° C. less than or equal to 300 tenths of a millimeter.

Abstract: An emulsion consists essentially of clear binders and possibly colored pigments, and contains at least one clear synthetic binder with a softening point or ball-ring temperature (TBA), measured according to the NFT 66-008 standard, that ranges between 30 and 100° C.

Abstract: The invention concerns the continuous production of asphalts modified by the addition of polymers and reacted with sulfur. The binders produced by said methods can contain very high amounts of polymers, also combined with secondary materials such as: rubber, various plastics, and waste lubricants. This type of binder, which cannot be obtained by discontinuous batch technology, is produced by the continuous mixing of several asphalt components through a static mixer. Said binders provide very high-performance asphalts and agents for regenerating old asphalts contained in waste road materials, in the process of hot recycling of coated materials. They are also used for producing novel emulsions of highly modified binders, with multiple applications and in particular for cold recycling. This novel method, by regenerating old asphalt contained in waste coated materials, represents a means for waste conversion and for limiting the use of asphalt and road-surfacing aggregates.

Abstract: The pavement patch composition of the present invention comprises a lightweight aggregate and highly modified polymer asphalt binder. The composition is formed by heating the binder to a flowable state, mixing the flowable binder with a lightweight aggregate, and then allowing it to cool into a solid form. The pavement patch composition is used to repair voids in pavement, such as pot holes, cracks and depressions. It is applied by heating solid pavement patch composition to a flowable state and applying it to the void, or on a surface in need of repair, and then allowed to cool. The resulting patch is self-adhering, strong and flexible. The formulation of the pavement patch composition may be adjusted for specific use in a cold climate, a moderate climate, a warmer climate, or for use in various traffic applications.

Abstract: Flame retardant compositions of this invention are produced by incorporating an amino condensation compound or composition in a more flammable organic compound. The amino condensation compounds and compositions are produced by heating urea or heating urea with other nitrogen containing compounds that will condensate with or react with isocyanic acid and/or cyanic acid or heating urea first then reacting the condensation compounds with other nitrogen containing compounds. The amino condensation compounds may be mixed with or reacted with carbonization auxiliaries, aldehydes and mixed with fillers to produce an amino condensation composition which is incorporated in more flammable organic compositions such as polyurethanes, polyester resins, epoxy resins, vinyl resins and other resins. The amino condensation salts of phosphorus, boron or sulfur containing compounds and the amino condensation-aldehyde resins may also be used as the flame retardant compound in this invention.

Abstract: The present invention relates to the coagglomeration of random vinyl substituted aromatic/C4-C6 conjugated diolefin polymers With sulfur. Said coagglomerate is storage stable and easily blended with asphalt under a variety of mixing conditions. Further, polymer/asphalt blends prepared with the sulfur coagglomerated polymers show improved storage stability against phase separation.

Abstract: The present invention is a recipe and method for combining Gilsonite and other asphaltites with curative elastomers that are powder granular form and which are added to asphalt. Second recipe and method is disclosed to create a dry liquid concentrate comprised of cured elastomers in combination with tall oil or other fatty acids and may also include Gilsonite to be added to asphalt.

Abstract: The disclosure relates to polymeric blends comprising at least one polymer, at least one resin, at least one filler or corrosion reducing material, among other components. The blend can be fabricated into a virtually unlimited array of shapes such as extruded tapes, cast as sheets or films, sealants such as gaskets and caulks, extruded or shaped profiles, stamped, among other configurations.

Abstract: A multipurpose cement dispersing, shrinkage compensating and anticorrosive polymer and an admixture comprising said polymer, which improve the workability and the early strength development of fresh concrete, are described.

Abstract: Elastomeric polyurethane interpenetrating network compositions are disclosed which are preferably developed by in situ reaction of polyols with different isocyanates and polyisocyanates in a bituminous material, such as, asphalt, coal tar, polymer modified asphalt, oxidized, and unoxidized asphalt. The composition is preferably formed at a temperature between 200° F. and 350° F. The reaction kinetics can be accelerated by including catalysts and curing agents. Bituminous polyurethane interpenetrating network elastomers are suitable for a wide variety of applications including but not limited to roofing, new construction, and wall and foundation waterproofing applications.

Abstract: An acoustically effective, bituminous mass which can be applied hot by means of a flat extrusion mold contains an addition of a thermosetting resin or thermosetting reagent combination, plus bitumen, polymers and/or wax as well as fillers such as aluminum powder or zinc powder, powdered graphite or mica powder. This addition is added to the mass at temperatures under 125° C., so that the polymerization reaction does not occur until a subsequent heating.

Abstract: A composition comprises a bitumen and a poly(arylene ether) having an intrinsic viscosity less than 0.40 deciliters per gram. The composition exhibits high softening and flow temperatures, and high hardness.

Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion or aqueous emulsion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.

Abstract: Fully oxidized cutback asphalts suitable for application in roofing, waterproofing, and sealing applications in all weather conditions, including as mastics and other sealants. Compositions according to the invention comprise unprecedented proportions of solids and asphalts yet remain workable to temperatures as low as 20° F. or below. In addition to fully-oxidized roofing-grade asphalts, preferred compositions according to the invention also comprise hydrophobic agents selected from the group comprising fatty acids and amine compounds and may be applied in rain or other wet conditions, and include polybutene or fatty acid peptizers to control the glass transition temperature of the completed mastic and thereby permit application of the composition at extremely low temperatures. Preferred embodiments optionally also comprise fillers such as cellulose fibers, diatomaceous earth, limestone, and asbestos for various advantageous purposes.

Abstract: A modified coal tar useful in roofing applications, containing coal tar, a nitrile butadiene rubber, and in some instances an effective amount of a plasticizer is prepared by heating the coal tar to a molten temperature, adding the rubber in powder form and agitating the material in a suitable high shear mixing apparatus until adequate phase inversion occurs between the polymer and the coal tar phase. After preparation, the material is cooled in containers until use, at which time it is heated to a flowable temperature and applied using a roofing mop or squeegee. Effective plasticizers include the alkyl esters of di-functional carboxylic acids, such as di-octyl adipate and di-octyl phthalate.

Abstract: The invention provides a coating composition for building use, which contains a base polyamide resin coating and charcoal powder. The base polyamide resin coating contains a copolymeric nyron and a solvent therefor.

Abstract: New or improved tires and retreads for tires which incorporate Trinidad Lake Asphalt (TLA), also known as Trinidad Natural Asphalt or Epure, as a raw material therein. TLA is advantageously used in addition to or as a substitute for other known component(s) or raw material(s) in tire/retread formulations. As with other components, the amount of TLA used can vary depending on the performance characteristics desired. TLA can be added at any stage of the tire manufacturing/retread process for the purpose of reducing or replacing known raw materials or as a separate raw material to provide new and improved formulations for tires/retreads.

Abstract: The elastomeric polyurethane interpenetrating network compositions of the invention are developed by in situ reaction of polyols with different isocyanates and polyisocyanates in bituminous material. Suitable bituminous materials include asphalt, coal tar, polymer modified asphalt, oxidized, and unoxidized asphalt. The composition is preferably formed at a temperature between 200° F. and 350° F. The reaction kinetics can be accelerated by including catalysts and curing agents. The reaction kinetics were followed by measuring the torque increase as a function of reaction time. The gelation time is measured at the maximum torque. For testing, the bituminous polyurethane interpenetrating network elastomeric compositions were hot-sprayed-applied (200° F.-350° F.) on different substrates such as concrete, metal, wood, built-up roofing systems, polyurethane foams, and other construction materials with a specially designed spray applicator system.

Abstract: A method of converting stripped roofing material into a useful product comprising feeding roofing material removed during repair or reroofing of a building roof into a shredder introducing particles of material from said shredder together with particles of thermoplastic material and a particulate filler material into a high intensity mixer to form a batch of material to be mixed, intensely mixing said batch of material to produce a heated mass of hot particles of roofing material and filler material coated with molten thermoplastic, then molding said heated mass under pressure into a desired end product. The invention also includes products produced utilizing said stripped roofing material.

Abstract: A solid type pressure-sensitive adhesive composition containing a rubbery polymer as the main polymer; and pressure-sensitive adhesive sheets which use the pressure-sensitive adhesive composition, are excellent in adhesive strength and holding power, retain the intact holding power even when allowed to stand at high temperatures or made to have a reduced adhesive layer thickness, and are free from the problem of adhesive protrusion or adhesive remaining. The pressure-sensitive adhesive sheets comprise a substrate and formed thereon a layer comprising a solid type pressure-sensitive adhesive composition obtained by a method comprising adding a tackifier to a rubbery polymer and treating the resultant mixture with an isocyanate crosslinking agent to crosslink the polymer.

Abstract: In one embodiment, the present invention relates to an asphalt composition containing asphalt, a terpenoid liquid, a rubber at least partially soluble in the asphalt composition and a flexible aggregate.

Abstract: The present invention relates to bituminous compositions used for roofing and waterproofing membranes or material comprising asymmetrical coupled polyvinyl aromatic-polydiene block copolymers having improved physical properties over broader ranges of service temperatures than those obtained from bituminous compositions prepared with symmetrical block copolymers of similar type. The asymmetry of the copolymer which is characterised by polyvinyl aromatic endblocks of at least two different molecular weights, one high and one low, ensures improved physical performance to roofing and waterproofing membranes made from such compositions.

Abstract: A vibration-isolating laminar rubber structure including highly rigid hard plates and rubber layers which are alternately laminated on each other, wherein the rubber layers are formed of a rubber composition comprising 1-50 parts by weight of at least one kind of material selected from among asphalt materials (e.g., natural asphalt), tar materials and pitch materials, per 100 parts by weight of a rubber material (natural rubber and/or diene-based synthetic rubber). The rubber composition preferably further comprises 10-150 parts by weight of carbon black and/or 1-50 parts by weight of a plasticizer having a freezing point of not higher than −30° C, per 100 parts by weight of the rubber material.

Abstract: The invention provides a method comprising contacting, between 100° C. and 230° C. and under agitation, an elastomer, a functionalising agent and optionally, a peroxide compound. The functionalising agent is a thiolcarboxylic acid polyester or a reaction product of a thiolcarboxylic acid or ester with ethylene sulphide. The functionalised elastomer can also be pre-formed, then incorporated into the bitumen. The resulting compositions are usable directly or after dilution, for forming bituminous binders to produce surfacing, coating and waterproofing materials.

Abstract: A composition comprising a binder and a residue wherein the residue comprises a blend of polypropylene, styrene butadiene rubber and calcium carbonate. The residue is a novel material derived as a coproduct from the medium-pressure depolymerization of nylon 6 carpet. The compositions are useful as road asphalt, asphalt roof membranes, molding compounds, and plastic lumber such as palisades and spacers.

Abstract: The present invention provides a method for preparing an asphalt and thermoplastic elastomer composition. The process comprises heating an asphalt cut in a stirred tank to a temperature sufficient to allow the stirring of the asphalt in the tank. A thermoplastic elastomer or rubber is added to the asphalt while continuing to stir the asphalt. The mixture is stirred at a speed and for a period of time sufficient to increase the distribution of the elastomer into the asphalt. The stirring speed is reduced and the temperature is increased to add an oil dispersion of crosslinking agents to the tank. Stirring is continued for a period of time sufficient to improve the distribution of the crosslinking agent dispersion in the asphalt.

Abstract: Normally incompatible styrenic polymers are stably incorporated into bitumen by using an elastomeric triblock copolymer comprising polystyrene segments which is solubilized or compatibilized in the bituminous phase. The elastomeric triblock copolymer incorporated into the continuous bituminous phase provides polystyrene domains which are dispersed throughout the bitumen or a receiving unit which stabilize the particulate polystyrene against separation from the bitumen.

Abstract: Bituminous compositions modified with self-adhesive cold-application polymers generally used for manufacturing of watertight panels, said compositions comprising a mixture containing a rubbery styrene-diene polymeric mixture, one or more tackifying resins, and bitumen.

Abstract: Disclosed is a process for producing a highly reactive modified phenolic resin, which comprises mixing a heavy oil or pitch with 0.3 to 10 mol of a phenol, 0.2 to 9 mol in terms of formaldehyde, of a formaldehyde compound and 0.01 to 3.0 mol of an acid catalyst, each amount being based on 1 mol of the heavy oil or pitch calculated from an average molecular weight; and heating the resulting mixture with stirring, thereby to polycondensate the heavy oil or pitch, phenol and formaldehyde compound. According to this invention, there can be provided a process for producing simply and stably a highly reactive modified phenolic resin having low melt viscosity, excellent heat resistance and high reactivity with an epoxy resin, in one step.

Abstract: Bituminous compositions of the bitumen-polymer type, in homogenous phase, contain at least one bitumen base and are prepared from at least one polymer of the thermoplastic polyolefin type. These compositions have a thermoplastic polyolefin content of at least 1% by weight of which the crystallinity rate is greater than or equal to 30%, a melting temperature greater than or equal to 110.degree. C. and a penetrability at 25.degree. C. less than or equal to 300 tenths of a millimeter.

Abstract: A block copolymer composition for modifying asphalt, which comprises a mixture of: (A) a block copolymer comprising: at least two polymer blocks each mainly comprising a monoalkenyl aromatic compound; and at least one polymer block mainly comprising a conjugated diene compound; and (B) a block copolymer comprising: at least one polymer block mainly comprising a monoalkenyl aromatic compound; and at least one copolymer block mainly comprising a conjugated diene compound, and having a molecular weight equivalent to 1/3 to 2/3 of the molecular weight of block copolymer (A), wherein (a) the total bonding alkenyl aromatic compound content in the mixture of block copolymers (A) and (B) is from 10 to 50% by weight, wherein (b) the vinyl bond content in the conjugated diene polymer blocks is not greater than 70% by weight, and wherein the block copolymer composition has: (c) a content of (A) component is from 98 to 20% by weight and a content of (B) component is from 2 to 80% by weight; (d) a melt index value of from

Abstract: A method is provided for improving high temperature performance grade properties of unblown asphalt by i) heating an asphalt cement to 200.degree. F. to 500.degree. F. (93.degree. C. to 260.degree. C.), ii) adding 0.1 wt. % to 10 wt. % ethylene-vinyl acetate copolymer based on weight of said asphalt cement to the heated asphalt cement, iii) adding 0.05 wt. % to 1.0 wt. % phosphorus-containing acid, e.g., polyphosphoric acid, based on weight of said asphalt cement and iv) mixing the resulting blend, thereby providing an unblown asphalt composition of greater useful temperature index (UTI). The invention further relates to asphalt compositions thus made and paving compositions containing these asphalt compositions.

Abstract: It has been determined that a specific type of emulsion SBR can be used to modify asphalt cement to greatly enhance the resistance to shoving, rutting and low temperature cracking of asphalt concretes made therewith. It has further been determined that this emulsion SBR is compatible with virtually all types of asphalt and that modified asphalt cements made therewith have extremely high levels of force ductility, tenacity and toughness.

Abstract: An oil-free compound which comprises from 20 to 90% by weight of a block copolymer of a vinyl aromatic hydrocarbon and a conjugated diene optionally hydrogenated, from 10 to 70% by weight of a low viscosity amorphous polyolefin, and from 0.1 to 20% by weight of carbon black. A stable oil-free bituminous composition which comprises from 80 to 98% by weight of a bituminous component, from 2 to 20% by weight of the above compound. A membrane suitable for single ply roofing prepared from the above compound.

Abstract: A sulfur in oil in asphalt and polymer blend is disclosed. An asphalt and polymer blend is first prepared and then a slurry of solid sulfur in liquid oil added. Addition of a slurry of solid sulfur in oil or oil containing sulfur compounds, permits rapid and effective uniform dispersion of the sulfur component in the asphalt/polymer blend. Uneven mixing, which can occur when sulfur is separately added as a solid to the asphalt blend, is avoided. Polymer use is optimized because polymer matrix development (digestion/swelling) can be completed before cross-linking occurs. The method is safer because formation of explosive clouds of sulfur dust is avoided.

Abstract: In a method of melting asphalt in a vessel, the molten asphalt normally emitting fumes, 0.2 weight percent to 6 weight percent of a polymer is added to the asphalt to reduce the visual opacity of the fumes by at least 25% over the same asphalt without the polymer. In another embodiment, the total emissions of benzene soluble suspended particulates is reduced by at least 15% over the same asphalt without the polymer. Preferably, the added polymer has a melt flow index of from 15 grams/10 minutes to 95 grams/10 minutes, and the added polymer reduces the visual opacity of the fumes by forming a skim on the upper surface of the molten asphalt.

Abstract: An acid-reacted polymer-modified asphalt composition including (i) 80 weight percent asphalt, (ii) 0.2 to 15 weight percent polymer containing available epoxy groups, and (iii) an acid effective for promoting chemical bonding between the asphalt and the polymer, wherein the composition exhibits substantially improved Dynamic Shear Rheometer stiffness values, without an appreciable loss in the G" viscous component of the complex modulus, low temperature creep stiffness and "m" values of the composition.

Abstract: An additive for, a method of adding thereof to uncured mixes for and resulting cured cement-type concreations such as cured embodiments of concrete, marcadam, and roof-top shingles each exhibiting improved heat and freeze-thaw durability resulting from reduced efflorescence and stability against sun ultraviolet light exposure.