Three Substituent Nitrogens Bonded Directly To The Three Carbons Of The Triazine Ring Patents (Class 544/196)
  • Patent number: 5536835
    Abstract: Novel carbamyl-methylated aminotriazines and curable compositions comprising these aminotriazines are disclosed. The carbamyl-methylated aminotriazines are substituted with derivatives of monoalkyl ethers and/or monoaryl ethers of alkylene glycols. The curable compositions are particularly useful as film formers in coatings.
    Type: Grant
    Filed: November 26, 1993
    Date of Patent: July 16, 1996
    Assignee: PPG Industries, Inc.
    Inventors: Daniel E. Rardon, Gregory J. McCollum
  • Patent number: 5534624
    Abstract: 1,3,5-Triazine-2,4,6-tris-alkylaminocarboxylic acid amino esters of the general formula (I): 1,3,5-triazine-2,4,6-tris[NH--(CH.sub.2).sub.n --CO--O--R.sup.1 ], in which R.sup.1 denotes the radical of an alkanolamine, can be employed as biocidal or biostatic compounds in aqueous systems, in particular in cooling lubricants.
    Type: Grant
    Filed: May 19, 1994
    Date of Patent: July 9, 1996
    Assignee: CG-Chemie GmbH
    Inventors: Jorg Lesmann, Hermann G. Schafer
  • Patent number: 5534625
    Abstract: A compound of the formula: ##STR1## wherein each R.sup.1, which may be the same or different, is hydrogen, alkyl, or an electron withdrawing group; andR.sup.2 is hydrogen, alkyl, or an electron withdrawing group.
    Type: Grant
    Filed: October 20, 1994
    Date of Patent: July 9, 1996
    Inventors: Michael Jarman, Helen M. Coley
  • Patent number: 5493023
    Abstract: Melamine cyanurate is prepared by heating melamine powder and cyanuric acid powder at 250.degree. to 500.degree. C. substantially in the absence of any liquid medium. The melamine cyanurate can be obtained in a granular form when the heating is conducted subsequent to granulation of a mixture of both the powders.
    Type: Grant
    Filed: December 2, 1993
    Date of Patent: February 20, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Kazuo Wakimura, Tetsuo Yoshiyama, Hiroshi Kato, Yuri Kawano
  • Patent number: 5493022
    Abstract: Salts of organic optical brighteners or light stabilizers with compounds which contain at least one ammonium, cycloammonium or immonium group and at least one aliphatic group, cycloaliphatic group, or aromatic group bonded to at least one (up to four) carbonyl group, or heteroaromatic group. resp. basic brighteners or light stabilizers with compounds which contain a radical containing at least one carboxylic acid or sulphonic acid radical and one aliphatic, cycloaliphatic, monomeric aromatic or heteroaromatic group, or contain a C.sub.2-14 -dicarboxylic acid or amino-C.sub.2-1 -alkylcarboxylic acid radical, are eminently suitable for the brightening and light stabilizing of synthetic plastic compositions.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: February 20, 1996
    Assignee: Sandoz Ltd.
    Inventors: Bansi L. Kaul, Angelos-Elie Vougioukas
  • Patent number: 5470921
    Abstract: A synthetic polyamide of formula I and its salts ##STR1## in which each R.sub.1 independently is selected from hydrogen, carboxyl, amino or a group of formula .alpha.-A.sub.1 -R.sub.10 (.alpha.)where A, is a bridging group and R.sub.10 is a sterically hindered amine group;each R.sub.2 independently is hydrogen or a group of formula .alpha.A is a bridging group of the formula ##STR2## is 0 or 1; R.sub.3 is hydrogen, C.sub.1-12 alkyl or is a significance of R.sub.10 ;R.sub.5 is hydrogen or C.sub.1-12 alkylR.sub.4 is a significance of R.sub.10 or a group of formula .alpha.; andp is an integer from 5 to 200;with the proviso that the compound of formula I contains 1-400 sterically hindered amine groups.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: November 28, 1995
    Assignee: Sandoz Ltd.
    Inventors: Bansi L. Kaul, Angelos-Elie Vougioukas, Jurgen Goldmann
  • Patent number: 5414084
    Abstract: Herbicidal sulfonylureas of the formula I, ##STR1## in which X is --O--, --O--NR.sup.2 -- or --SO.sub.2 --NR.sup.2 --, Y is --N-- or CH,R.sup.1 is (substituted) alkyl, (substituted) alkenyl or (substituted) alkynyl, or else, where X=O, (substituted) phenyl,R.sup.2 is H, alkyl, alkenyl, alkynyl or cycloalkyl,R.sup.3, R.sup.4 are H, (substituted) alkyl or (substituted) alkoxy, halogen, alkylthio, alkylamino or dialkylamino andR.sup.5, R.sup.
    Type: Grant
    Filed: March 5, 1992
    Date of Patent: May 9, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Lothar Willms, Stephen Lachhein, Gunter Schlegel, Heinz Kehne
  • Patent number: 5410051
    Abstract: Disclosed are novel nitrogen containing heterocyclic compounds and novel vinyl terminated polyurethane/polyamide polymers together with the use of both of these compounds in a novel adhesive and coating composition. The nitrogen containing heterocyclic compounds of the invention contain two vinyl-terminated substituents and at least one carbamylmethyl substituent and have a nucleus selected from melamine, oligomers of melamine, benzoguanamine, and oligomers of benzoguanamine, glycoluril and oligomers of glycoluril, cyclohexylguanamine, oligomers of cyclohexylguanamine, acetoguanamine, and oligomers of acetoguanamine. The vinyl terminated polyurethane compounds of the invention have a molecular weight of from about 3000 to about 80000, and contain at least two vinyl end groups.
    Type: Grant
    Filed: June 17, 1993
    Date of Patent: April 25, 1995
    Assignee: Cytec Technology Corp.
    Inventors: Peter S. Forgione, William A. Henderson, Balwant Singh, Yuhshi Luh
  • Patent number: 5364937
    Abstract: Compounds of the formula I or salts thereof, ##STR1## in which X is oxygen, --O--NR.sup.2 -- or --SO.sub.2 --NR.sup.2 --, and Y is N or CH,R.sup.1 is (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl or (C.sub.2 -C.sub.6)alkynyl, which are in each case optionally substituted, or, in the case where X=oxygen, also (subst.) phenyl,R.sup.2 is H, (C.sub.1 -C.sub.6)alkyl, (C.sub.2 -C.sub.6)alkenyl or -alkynyl or (C.sub.3 -C.sub.6) cycloalkyl,R.sup.3 and R.sup.4 are H, (subst.) (C.sub.1 -C.sub.4)alkyl or (subst.) (C.sub.1 -C.sub.4)alkoxy or halogen, (C.sub.1 -C.sub.4)alkylthio, (C.sub.1 -C.sub.4)alkylamino or di[(C.sub.1 -C.sub.4)alkyl]-amino,R.sup.5 is H or (C.sub.1 -C.sub.4)alkyl and R.sup.6 is hydrogen,may be prepared by reacting compounds of the formula II,R.sup.1 --X--R.sup.7 (II)with compounds of the formulae III, IV and VR.sup.8 --OCN (III)SO.sub.2 Cl.sub.2 (IV) ##STR2## where R.sup.7 and R.sup.8 are H, a quarternary ammonium ion or one equivalent of a metal cation.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: November 15, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Gunter Schlegel
  • Patent number: 5361616
    Abstract: A coating composition having photopolymerizability and heat curability, which comprises, as main components,(A) a vinyl copolymer having polymerizable double bonds and crosslinkable hydroxyl groups,(B) a condensation polymerizable compound of the following formula (i) or a condensation polymer thereof, and(C) a photopolymerization initiator: ##STR1## wherein each of the plurality of R which may be the same or different, is --H, --CH.sub.2 OH, --CH.sub.2 OCH.sub.3, --CH.sub.2 OC.sub.4 H.sub.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: November 8, 1994
    Assignee: Dai Nippon Toryo Co., Ltd.
    Inventors: Toshiya Takahashi, Norio Uriya, Yoshihisa Nagashima
  • Patent number: 5360804
    Abstract: Multicomponent agent or kit for preparing the sulpho-conjugated form of pyridino, pyrimidino or triazino N-oxide compounds and method of use.The present invention relates to a multicomponent agent or kit for preparing the sulpho-conjugated form of pyridino, pyrimidino or triazino N-oxide compounds,comprising at least one compound of the pyridino, pyrimidino or triazino N-oxide type, on the one hand,and a sulphating agent, on the other hand.
    Type: Grant
    Filed: December 12, 1991
    Date of Patent: November 1, 1994
    Assignee: L'Oreal
    Inventors: Quintino Gaetani, Andre Rougier, Albert Duranton, Michel Hocquaux
  • Patent number: 5332737
    Abstract: This invention concerns novel compounds of the formula I: ##STR1## in which P is a group of formula II or a group of formula III; R.sup.1 is alkyl, cycloalkyl, cycloalkylalkyl, phenyl or phenylalkyl; R.sup.2 is hydrogen, alkyl, amino or alkylamino; R.sup.3 and R.sup.4 are independently hydrogen, alkyl, phenyl or benzyl; R.sup.6 is alkyl amino or alkylamino; C and D are independently ethylene or trimethylene; Z is a direct bond between C and D, or an oxy, thio, carbonyl, methylene, ethylenedioxymethylene, ethylidene, or isopropylidene link, or Z is a group of the formula .dbd.N.R.sup.5 in which R.sup.5 is alkyl, phenyl or benzyl; R8 is hydrogen, cycloalkylalkyl, alkyl, alkenyl, alkynyl or phenylalkyl; or R8 is a alkylene or alkenylene linked to the nitrogen atom of the group Q.A.
    Type: Grant
    Filed: December 3, 1990
    Date of Patent: July 26, 1994
    Assignee: Imperial Chemical Industries PLC
    Inventors: Stuart D. Mills, Rodney B. Hargreaves, Bernard J. McLoughlin
  • Patent number: 5290902
    Abstract: The present invention is directed to a polyisocyanate mixture whichi) has an NCO content of 5 to 47% by weight,ii) is prepared from an isocyanate component substantially containing one or more cyclic organic diisocyanates having (cyclo)aliphatically-bound isocyanate groups andiii) contains isocyanurate and allophanate groups in a molar ratio of monolsocyanurates to monoallophanates of 10:1 to 1:10, wherein the allophanate groups are formed from urethane groups which are based on the reaction product of an organic diisocyanate having (cyclo)aliphatically bound isocyanate groups and a monoalcohol containing at least 1 carbon atom and having a molecular weight of up to 2500.The present invention is also directed to a process for the production of these polyisocyan mixtures and to their use, optionally in blocked form, as an isocyanate component in two-component coating compositions.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: March 1, 1994
    Assignee: Miles Inc.
    Inventors: Patricia B. Jacobs, Douglas A. Wicks
  • Patent number: 5290893
    Abstract: An aminotriazine prepolymer is provided which gives resin with toughness and favorable trans-Darency without use of filler agent by mixing 2-hydroxyethyl methacrylate (781 g: 6 mole), melamine (126 g: 1 mole), 95% by weight of p-formaldehyde (189 g: 6 mole as formaldehyde), p-toluene sulfonate (3.0 g), hydroquinone monomethyl ether (0.2 g) in a two liter separation flask with a stirring device, a thermometer, an air-inlet tube, and a cooling tube for removing the distillate. The mixture is heated while air is blown in. After the melamine and paraformaldehyde are dissolved in 2-hydroxyethyl methacrylate, at the temperature of 80.degree. C. to 100.degree. C., the reaction is continued in the temperature range of 105.degree. C. to 115.degree. C. until the quantity of extracted water is 108 g (6 mole). The triazine ring structure-containing methacrylate prepolymer thus obtained has a viscosity of 2,000 cP at 20.degree. C., a bromine number of 92.1 (Br g/100 g), and a Gardner color degree of not greater than 5.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: March 1, 1994
    Assignee: Aica Kogyo Co., Ltd.
    Inventors: Yutaka Hori, Takashi Kamiya, Takayuki Mano, Ryuzo Asami
  • Patent number: 5276130
    Abstract: According to the present invention, a .beta.-dicarbonyl functionality, an .alpha.,.beta.-unsaturation functionality, or a vinylogous amide functionality is incorporated into an aminoplast resin or an aminoplast resin precursor.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: January 4, 1994
    Assignee: BASF Corporation
    Inventors: Christopher J. Bradford, Adriana E. Ticu, Richard E. De Schepper
  • Patent number: 5258514
    Abstract: Novel s-triazine compounds containing at least one N,N-bis(alkoxy or hydroxyalkoxy-carbonyl-amino C.sub.2 -C.sub.10 alkyl) amino substituent function in self-condensation and as cross-linkers for compounds containing active hydrogen groups. The compositions cure to coatings with excellent properties, especially corrosion resistance, humidity resistance, abrasion resistance and flexibility. The coatings have excellent exterior durability.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: November 2, 1993
    Assignee: American Cyanamid Company
    Inventor: Girish G. Parekh
  • Patent number: 5254745
    Abstract: Polyoxyalkylene polyols initiated with melamine and coinitiated with toluene diamine and oxyalkylated with one or more alkylene oxides have relatively low viscosity and are suitable for preparing polyurethane foams.
    Type: Grant
    Filed: November 12, 1991
    Date of Patent: October 19, 1993
    Assignee: BASF Corporation
    Inventor: Joachim Jahme
  • Patent number: 5240499
    Abstract: Polymeric, water-soluble triazine compounds which contain both basic and acidic groups in the molecule have out-standing surfactant properties and are suitable for the preparation of dispersions of solids, preferably of dispersions of inorganic and/or organic pigments, in an aqueous or water-dilutable medium. Since these triazine compounds are colorless or only slightly colored, they do not influence the shade of the medium used.
    Type: Grant
    Filed: December 13, 1991
    Date of Patent: August 31, 1993
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Rainer Az, Wolfgang Schwab, Dieter Schnaitmann, Erwin Dietz
  • Patent number: 5236698
    Abstract: The invention relates to a compound of formula: ##STR1## where R.sub.1 is of the formula: ##STR2## where R.sub.3 represents a linear or branched C.sub.1 -C.sub.20 alkyl; R.sub.2 is identical to R.sub.1 or is a halogen or a linear or branched C.sub.1 -C.sub.20 alkoxy or mono- or dialkylamino or is of the formulae (III) or (IV): ##STR3## where R.sub.5 is a linear or branched C.sub.1 -C.sub.20 alkyl and n=0 or 1;R.sub.4 denotes H, OH or C.sub.1 -C.sub.5 alkoxy; ##STR4## Application of these compounds to the protection of the skin and hair against ultraviolet radiation.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: August 17, 1993
    Assignee: L'Oreal
    Inventors: Herve Richard, Madeleine Leduc, Alex Junino
  • Patent number: 5235018
    Abstract: The present invention is directed to a polyisocyanate mixture having an NCO content of 10 to 47% by weight and a viscosity of less than 10,000 mPa.s and containing isocyanurate and allophanate groups in a molar ratio of monoisocyanurates to monoallophanates of 10:1 to 1:5, wherein the allophanate groups are formed from urethane groups which are based on the reaction product of an organic diisocyanate having (cyclo)aliphatic bound isocyanate groups and a monoalcohol containing at least 10 carbon atoms and having a molecular weight of 158 to 2500.The present invention is also directed to a process for the production of a polyisocyanate mixture having an NCO content of 10 to 47% by weight, having a viscosity of less than 10,000 mPa.s and containing isocyanurate and allophanate groups in a molar ratio of monoisocyanurates to monoallophanates of 10:1 to 1:5 bya) catalytically trimerizing a portion of the isocyanate groups of an organic diisocyanate having (cyclo)aliphatically bound isocyanate groupsb) adding 0.
    Type: Grant
    Filed: May 6, 1992
    Date of Patent: August 10, 1993
    Assignee: Miles Inc.
    Inventors: Terry A. Potter, William E. Slack, Patricia B. Jacobs
  • Patent number: 5225549
    Abstract: Lubricants for electromagnetic recording media are characterized in that they are amides, imides or amide-imides consisting of perfluoroalkylpolyether derivatives. The derivatives are reacted with perfluoropolyether radicals and cyclic amino compounds, nitrogen-containing heterocyclic amino compounds and phosphonitrile amide compounds. The general formula is represented by (1)(Rf) l--Z . . . (1)with the molecular weight of the Rf group being comprised between 400 and 10,000.
    Type: Grant
    Filed: January 15, 1992
    Date of Patent: July 6, 1993
    Inventor: Takateru Dekura
  • Patent number: 5211740
    Abstract: Herbicidal aminoguanidinoazines of the formula ##STR1## in which R.sup.1 stands for an optionally substituted radical from the series comprising alkyl, aralkyl, aryl and hetaryl,R.sup.2 stands for hydrogen, halogen, hydroxyl, alkyl, halogenoalkyl, alkoxyalkyl, alkoxy, halogenoalkoxy, alkylthio, halogenoalkylthio, amino, alkylamino or dialkylamino,X stands for nitrogen or a --CH group,Y stands for nitrogen or a --CR.sup.3 group whereR.sup.3 stands for hydrogen, halogen, cyano, alkyl, formyl, alkyl-carbonyl or alkoxy-carbonyl, andZ stands for nitrogen or a --CR.sup.4 group whereR.sup.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: May 18, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christa Fest, Rolf Kirsten, Joachim Kluth, Klaus-Helmut Muller, Hans-Jochem Riebel, Hans-Joachim Santel, Robert R. Schmidt, Harry Strang
  • Patent number: 5202438
    Abstract: For the synthesis of melamine cyanurate, by the reaction of cyanuric acid and melamine in an aqueous medium, the reaction is conducted in the presence of a strong mineral acid at a pH not above 1.
    Type: Grant
    Filed: April 6, 1992
    Date of Patent: April 13, 1993
    Assignee: Elf Atochem S.A.
    Inventor: Jean-Michel Paul
  • Patent number: 5182388
    Abstract: Salts of triazinic compounds with oxygenated acids of phosphorus, of the eral formula (I): ##STR1## wherein: at least one of radicals for R to R.sub.5 is: ##STR2## being:m=an integer comprised between 2 and 8;p=an integer comprised between 2 and 6;The new salts having the general formula (I) are applied, in particular, as anti-flame additives for polymers.
    Type: Grant
    Filed: April 11, 1991
    Date of Patent: January 26, 1993
    Assignee: Ministero Dell' Universita' E Della Ricerca Scientifica E Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Gilberto Nucida, Enrico Masarati
  • Patent number: 5138055
    Abstract: Novel s-triazine compounds containing at least one N,N-bis(alkoxy or hydroxyalkoxy-carbonyl-amino C.sub.2 -C.sub.10 alkyl) amino substituent function in self-condensation and as cross-linkers for compounds containing active hydrogen groups. The compositions cure to coatings with excellent properties, especially corrosion resistance, humidity resistance, abrasion resistance and flexibility. The coatings have excellent exterior durability.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: August 11, 1992
    Assignee: American Cyanamid Company
    Inventor: Girish G. Parekh
  • Patent number: 5100913
    Abstract: The present invention relates, by way of novel industrial products, to the sulfonylphenyl-.beta.-D-thioxyloside compounds of the formula ##STR1## in which: X is a sulfur atom or an oxygen atom;R is a C.sub.1 -C.sub.4 alkyl group, a substituted amino group NR.sub.1 R.sub.2 (where R.sub.1 and R.sub.2, which are identical or different, are each a C.sub.1 -C.sub.4 alkyl group, it being possible for R.sub.1 and R.sub.2, taken together, to form a piperidinyl or morpholinyl group with the nitrogen atom to which they are bonded) or a phenyl group which is unsubstituted or substituted in the para position by a cyano group or by a halogen atom; andY is the hydrogen atom or an aliphatic acyl group.These compounds are useful in therapeutics, especially as venous antithrombotics.
    Type: Grant
    Filed: March 25, 1991
    Date of Patent: March 31, 1992
    Assignee: Fournier Industrie et Sante
    Inventors: Soth Samreth, Patrice Renaut, Jerzy Bajgrowicz, Jean Millet
  • Patent number: 5093462
    Abstract: Hydroxy functional epoxidized amino resins comprising glycidamide groups. The polyglycidamides are produced from alkoxymethyl amino resins by reaction with acrylamide, followed by reaction with a polyol to introduce hydroxy functionality and then the unsaturated groups of the hydroxyfunctional acrylamidomethyl amino resins are epoxidized with an epoxidation agent such as hydrogen peroxide. The polyglycidamides are formulated with epoxy reactants to provide curable epoxy systems.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: March 3, 1992
    Assignee: Monsanto Company
    Inventor: William F. Pfohl
  • Patent number: 5089617
    Abstract: Novel beta-hydroxyalkylcarbamylmethyl aminotriazines function in self-condensation and as cross-linkers for amino resins and also compounds containing active hydrogen groups. The compositions cure to coatings with excellent properties, and they can be used as binders for fillers such as insulating glass and foundry sand.
    Type: Grant
    Filed: November 13, 1987
    Date of Patent: February 18, 1992
    Assignee: American Cyanamid Company
    Inventors: Peter S. Forgione, Balwant Singh
  • Patent number: 5084541
    Abstract: Novel triisocyanato triazines and carbamoyl triazine derivatives thereof are disclosed. These compounds will self-cure and also function as crosslinkers for compounds containing active hydrogen groups. When the active hydrogen-containing compounds are hydroxylated polymers, environmentally-resistant coatings are provided.
    Type: Grant
    Filed: May 14, 1990
    Date of Patent: January 28, 1992
    Assignee: American Cyanamid Company
    Inventors: William J. Jacobs, III, Roland Dileone
  • Patent number: 5079361
    Abstract: Cross-linking reagents which are highly specific for sulphydryl groups and react with thiols at an excellent rate. The essential feature of the reagents is at least one vinyl group conjugated with an armoatic nitrogen heterocycle. Particular examples include vinyl pyridines, vinyl pyrimidines and vinyl triazines.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: January 7, 1992
    Assignee: Celltech Limited
    Inventors: Rikki P. Alexander, Michael A. W. Eaton, Thomas A. Millican, Richard C. D. Titmas
  • Patent number: 5059683
    Abstract: Compounds of the formula ##STR1## and acid addition salts thereof whereinA.sub.1 is C.sub.1-8 alkylene; C.sub.2-8 alkylene substituted by 1 or 2 substituents selected from hydroxy, halo and cyano; C.sub.2-8 alkenylene; cyclohexylene; cyclohexylene substituted by 1 to 3 C.sub.1-4 alkyl groups; phenylene or phenylene substituted by 1 or 2 substituents selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy,B.sub.1 is ##STR2## wherein the quaternized nitrogen atom is bound to a carbon atom of A.sub.1,R is hydrogen, C.sub.1-4 alkyl, C.sub.5-6 cycloalkyl, phenyl, benzyl or phenylethyl,T is hydrogen, cyano, --COOR.sub.1, --CON(R.sub.2).sub.2, --SO.sub.2 N(R.sub.2).sub.2, ##STR3## wherein R.sub.1 is C.sub.1-6 alkyl or phenyl(C.sub.1-3 alkyl),each R.sub.3 is independently hydrogen, C.sub.1-4 alkyl, --CON(R.sub.2).sub.2 or --N(R.sub.5).sub.2, andX.sub.1 is --S--, --O-- or --N(R.sub.5)--,Y is hydrogen or a chromophoric group, andZ is ##STR4## wherein R.sub.11 is ##STR5## wherein W is --NR.sub.6 R.sub.7 or --.sup..sym.
    Type: Grant
    Filed: May 5, 1989
    Date of Patent: October 22, 1991
    Assignee: Sandoz Ltd.
    Inventors: Helmut A. Moser, Roland Wald
  • Patent number: 5057610
    Abstract: Substituted amino carbamate derivatives corresponding to the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: October 15, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Stephen D. Pastor, Edward T. Hessell, Ramanathan Ravichandran
  • Patent number: 5034525
    Abstract: The lubricants according to the present invention are comprised of fluorine-containing alkyl carbonyl, polyperfluorooxyalkylenefluoropropionyl, polyperfluorooxyalkylene copolymerized oxyfluoroalkyl carbonyl chains and the like, and of which compounds are reacted with hetero cyclic groups obtained by amidization with polar groups between the radicals and compounds with typical organic end-groups.The novel compounds referred to above are lubricants characterized in that they can be represented by the general formula (1) and that the molecular weight of Rf ranges from 200 to 15,000. ##STR1## wherein Rf represents any one of the following groups: ##STR2## where l is an integer having a value between 3 and 150, and m an integer ranging from 1 to 50, and where X may be H--, F--, CF.sub.3 --, C.sub.2 F.sub.5 --, C.sub.3 F.sub.7 --, CF.sub.3 O--, C.sub.2 F.sub.5 O--, or C.sub.3 F.sub.7 O--, and Y may be F--, CF.sub.3 --, or C.sub.2 F.sub.5 -- respectively.
    Type: Grant
    Filed: September 19, 1988
    Date of Patent: July 23, 1991
    Inventor: Takateru Dekura
  • Patent number: 5023308
    Abstract: A polymeric compound, named poly(amino-s-triazine), which has a layer structure with a structural unit represented by (C.sub.3 N.sub.3).sub.2 N.sub.x H.sub.y, where 2.ltoreq.x.ltoreq.4 and 0.ltoreq.y.ltoreq.8, is obtained by reaction of cyanuric trichloride with ammonia or melamine. This compound is stable in the air up to about 400.degree. C. and exhibits fluorescence by excitation at wavelength of 365 nm. When the above reaction is carried out at a temperature ranging from room tempertaure to about 400.degree. C. the product is an oligomeric compound (C.sub.3 N.sub.3).sub.a (NH).sub.b (NH.sub.2).sub.c Cl.sub.d, where 2.ltoreq.a.ltoreq.10, 1.ltoreq.b.ltoreq.10, 0.ltoreq.c.ltoreq.11 and 1.ltoreq.d.ltoreq.12, and poly(amino-s-triazine) is obtained by heating the oligomeric compound at 400.degree.-600.degree. C. in an inactive gas. The oligomeric compound too exhibits fluorescence and is higher in fluorescence intensity.
    Type: Grant
    Filed: July 12, 1989
    Date of Patent: June 11, 1991
    Assignee: Central Glass Company, Limited
    Inventors: Masayuki Kawaguchi, Yasushi Kita, Kayoko Yamamoto, Koji Nozaki
  • Patent number: 5017699
    Abstract: Polyalkoxymethylmelamines are prepared by reacting melamine with formaldehyde and then alkylating the resultant polymethylolmelamine with a lower monohydric alcohol, having 1 to 4 carbon atoms, especially methanol, in the presence of a solid "superacid" catalyst.
    Type: Grant
    Filed: July 19, 1990
    Date of Patent: May 21, 1991
    Inventor: Tzeng J. Suen
  • Patent number: 5006653
    Abstract: Novel alkylcarbamylmethyl aminotriazines self-cure and also function as crosslinkers for compounds containing active hydrogen groups. When the active hydrogen-containing compounds are hydroxylated polymers, coatings are provided with exceptional resistance to detergent and salt-spray exposure and improved abrasion resistance. The novel aminotriazines also can be combined with fillers as binders which when cured provide shaped articles of manufacture, such as insulation and foundry core molds.
    Type: Grant
    Filed: November 12, 1987
    Date of Patent: April 9, 1991
    Assignee: American Cyanamid Company
    Inventors: Peter S. Forgione, Balwant Singh
  • Patent number: 5003066
    Abstract: The polyglycidamides are epoxy derivatives of cyclic ureas such as glycouril and aminotriazines such as melamine and guanamines. They are prepared from cyclic ureas and aminotriazines by methylolating with formaldehyde, etherifying with an alcohol, transetheramidizing with acrylamide and epoxidizing with hydrogen peroxide. They are used with polyamines and other epoxy reactive oligomers to provide crosslinkable coating systems which posses solvent, chemical and water resistance and UV stability.
    Type: Grant
    Filed: March 29, 1989
    Date of Patent: March 26, 1991
    Assignee: Monsanto Company
    Inventor: William F. Pfohl
  • Patent number: 4981965
    Abstract: A base precursor in the form of a salt of an organic base with a carboxylic acid is disclosed. The organic base is a diacidic to tetraacidic base which is composed of two to four guanidine moieties and at least one linking group for the guanidine moities. The organic base is such a hydrophilic compound that the number of carbon atoms contained in the organic base is not more than six times the number of the guanidine moieties. The linking group is a residue of a hydrocarbon or a heterocyclic ring. The guanidine moiety corresponds to an atomic group formed by removing one or two hydrogen atoms from a compound having the following formula (I): ##STR1## where each of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 independently is hydrogen, an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, an aralkyl group, an aryl group or a heterocyclic group, each of which may have one or more substituent groups, and any two of R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.
    Type: Grant
    Filed: September 9, 1988
    Date of Patent: January 1, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshiharu Yabuki, Jiro Tsukahara, Taku Nakamura
  • Patent number: 4968796
    Abstract: Disclosed is a process for the preparation of a sulphonylisothiourea of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, X, Y, and Z are as defined herein, which comprises reacting a sulphonic acid amide of the formulaR.sup.1 --SO.sub.2 --NH.sub.2, (II)or a metal salt thereof, with an N-heteroaryl-iminodithiocarbonic acid S,S-diester of the formula ##STR2## at a temperature between about 20.degree. C. and 200.degree. C. Intermediates and a process for their preparation are also disclosed.
    Type: Grant
    Filed: August 17, 1989
    Date of Patent: November 6, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventor: Hans-Jochem Riebel
  • Patent number: 4931536
    Abstract: Hydroxy functional acrylamido amino resins comprising hydroxy-hydrocarbyl groups. The resins are produced by reaction of alkoxymethyl amino resins with acrylamide to introduce acrylamidomethyl groups and then with a polyol to introduce hydroxy functionality. The hydroxy functional acrylamido amino resins may be epoxidized to form polyglycidamides which can then be formulated with epoxy reactants to provide curable epoxy systems.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: June 5, 1990
    Assignee: Monsanto Company
    Inventor: William F. Pfohl
  • Patent number: 4931537
    Abstract: Curable epoxy systems comprising polyglycidamides and epoxy reactants. The polyglycidamides are hydroxy functional polyglycidamides derived from amino resins. The epoxy systems can be used as laminating, encapsulating and coating resins. When the epoxy reactant is an anhydride, cure under ambient conditions is obtained.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: June 5, 1990
    Assignee: Monsanto Company
    Inventor: William F. Pfohl
  • Patent number: 4910238
    Abstract: Stabilizers for synthetic polymer compositions are provided which are poly(2,2,6,6-tetramethyl piperidyl amino)-1,3,5-triazines having the formula: ##STR1## in which: R is selected from the group consisting of hydrogen; alkyl, alkenyl, cycloalkyl, hydroxyalkyl and alkoxy having from one to about twelve carbon atoms; acyl having from the one to about twelve carbon atoms; and oxyl;X and Y are each selected from the group consisting of ##STR2## wherein: R.sub.1 is selected from the group consisting of alkyl, hydroxylalkyl and alkylenealkoxy having from one to about twelve carbon atoms; cycloalkyl having from three to about twelve carbon atoms; and aryl having from six to about eighteen carbon atoms;R.sub.2 and R.sub.3 are selected from the group consisting of hydrogen; alkyl having from one to about twelve carbon atoms; cycloalkyl having from three to about twelve carbon atoms; and aryl having from six to about eighteen carbon atoms; and R.sub.2 and R.sub.
    Type: Grant
    Filed: July 10, 1986
    Date of Patent: March 20, 1990
    Assignee: Adeka Argus Chemical Co. Ltd.
    Inventors: Yutaka Nakahara, Etsuo Tobita
  • Patent number: 4886882
    Abstract: Hydroxyoxaalkylmelamines of the general formula I ##STR1## where the radicals R may be identical or different and are each hydrogen or a radical of the general formula IIH--(--O--CHR'--CHR'--)--.sub.n (II)where the radicals R' may be indentical or different and are each hydrogen or C.sub.1 -C.sub.4 -alkyl and n is 2 or 3, and mixtures of these, are useful intemediates for the preparation of urethanes and for modifying aminoplast resins.
    Type: Grant
    Filed: August 18, 1986
    Date of Patent: December 12, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Klaus Ebel, Wolfgang Reuther
  • Patent number: 4874858
    Abstract: At least three, and as many as eighteen, most preferably at least nine, crosslinking sites are provided through the alkoxy groups in multiple chains on a triazine ring (hence "multisilane"), on a single molecule of the multisilane. The multisilane, useful as a coupling agent, is formed by reacting a triazine-containing compound with a suitable aminoalkyl-alkoxysilane, or, alkyl-aminoalkyl-alkoxysilane in either an anhydrous, or an aqueous liquid medium. A size containing the multisilane, enhances the reinforced properties of organic synthetic resinous materials in which the fibers are used, and most particularly those of rigid poly(vinyl chloride) (PVC) with which it provides cohesive bonding of glass fiber surfaces.
    Type: Grant
    Filed: March 28, 1988
    Date of Patent: October 17, 1989
    Assignee: The B. F. Goodrich Company
    Inventor: Angelo J. Magistro
  • Patent number: 4861881
    Abstract: The polyglycidamides are epoxy derivatives of cyclic ureas such as glycouril and aminotriazines such as melamine and guanamines. They are prepared from cyclic ureas and aminotriazines by methylolating with formaldehyde, etherifying with an alcohol, transetheramidizing with acrylamide and epoxidizing with hydrogen peroxide. They are used with polyamines and other epoxy reactive oligomers to provide crosslinkable coating systems which possess solvent, chemical and water resistance and UV stability.
    Type: Grant
    Filed: May 2, 1984
    Date of Patent: August 29, 1989
    Assignee: Monsanto Company
    Inventor: William F. Pfohl
  • Patent number: 4826930
    Abstract: Novel melamine-poly(oxyethylene or oxypropylene) diamine condensates are prepared which have the formula: ##STR1## Wherein: R represents H or--NH--CHR'--(CH.sub.2).sub.x --[--O--CH.sub.2 --CHR"--].sub.n --O--(CH.sub.2).sub.x --CHR'--NH.sub.2R' represents H or --CH.sub.3,R" represents H or -CH.sub.3 or CH.sub.2 CH.sub.3,x represents an integer having a value of 1 or 2, andn is a number having an average value of about 1 to about 2.The melamine-poly(oxyethylene or oxypropylene) diamine condensates have utility as curing agents for epoxy resins.
    Type: Grant
    Filed: April 22, 1988
    Date of Patent: May 2, 1989
    Assignee: Texaco Chemical Company
    Inventors: Robert L. Zimmerman, Harold G. Waddill, George P. Speranza
  • Patent number: 4824845
    Abstract: Novel substituted acylamino-s-triazine compounds of the formula ##STR1## wherein R is C.sub.1 -C.sub.4 -alkyl, R.sub.1 is hydrogen, or C.sub.2 --C.sub.12 -acyl which is unsubstituted or substituted by halogen or C.sub.1 --C.sub.4 -alkoxy, and R.sub.2 is C.sub.2 --C.sub.12 -acyl which is unsubstituted or substituted by halogen or C.sub.1 --C.sub.4 -alkoxy, including the salts thereof. The novel compounds have valuable insecticidal and laryicidal properties, and can be used as active substances for controlling phytoparasitic and zooparasitic insects, expecially the larvae thereof, amongst these in particular ectoparasites.
    Type: Grant
    Filed: August 17, 1988
    Date of Patent: April 25, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Claude Gehret, Odd Kristiansen
  • Patent number: 4802910
    Abstract: Novel herbicides of the formula ##STR1## in which R.sup.1 represents an organic radical,R.sup.2 represents hydrogen or an organic radical,R.sup.3 represents an organic radical or an amino radical,R.sup.4 represents hydrogen, an organic radical, an ether radical or an amino radical,X represents N or CH,Y and Z each represent N, CH or a substituted C radical, andM is H, a metal ion or an acyl radical, or a strong acid adduct thereof. Some intermediates are also new.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: February 7, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Kirsten, Joachim Kluth, Klaus-Helmut Muller, Theodor Pfister, Hans-Jochem Riebel, Hans-Joachim Santel, Robert R. Schmidt
  • Patent number: 4788287
    Abstract: A high performance water and oil repellant composed of a compound comprising at least two terminal segments and an intermediate segment connecting the terminal segments and having a molecular weight of from 800 to 20,000, each terminal segment containing at least one polyfluoroalkyl group connected by a --CONH-- linking group, said intermediate segment being a urethane oligomer containing at least two --CONH-- linking groups in one molecule, and said terminal segments and intermediate segment being connected by a --CONH-- linking group.
    Type: Grant
    Filed: September 3, 1986
    Date of Patent: November 29, 1988
    Assignee: Asahi Glass Company Ltd.
    Inventors: Masashi Matsuo, Masayuki Tamura, Katsuji Ito
  • Patent number: 4762833
    Abstract: 2,4,6-Tris-tertiary-butylamino-1,3,5-triazine of the formula I ##STR1## for the prophylaxis and treatment of epilepsy and anxiety states, and the use for the preparation of a medicament for the prophylaxis and treatment of epilepsy and anxiety states, are described.
    Type: Grant
    Filed: April 3, 1987
    Date of Patent: August 9, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Alfred Kreutzberger, Alfons Soder, Hermann J. Gerhards