Heavy Metal Or Aluminum Containing Patents (Class 548/101)
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Patent number: 5132318Abstract: Azolylmethyloxiranes of the general formula I ##STR1## where A and B are cycloalkyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl, norbornyl, cycloalkenyl or phenyl, each of these radicals being unsubstituted or substituted, with the proviso that A and B are not simultaneously phenyl, D is O, X is CH or N, and their plant-tolerated acid addition salts or metal complexes, and fungicides containing these compounds.Type: GrantFiled: February 20, 1990Date of Patent: July 21, 1992Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Stefan Karbach, Thomas Kuekenhoehner, Hubert Sauter, Gisela Lorenz, Eberhard Ammermann
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Patent number: 5128357Abstract: 1-Alkoxy-1-azolylmethyloxiranes of the general ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.5 -C.sub.8 -cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenylyl or phenyl, each of which is unsubstituted or mono- to trisubstituted by halogen, nitro, phenoxy, amino, alkyl, alkoxy or haloalkyl of 1 to 4 carbon atoms in each case, R.sup.3 is C.sub.1 -C.sub.4 -alkyl, X is CH or N, the acid addition salts and metal complexes thereof which are tolerated by plants, processes for their manufacture, and their use for combating fungi.Type: GrantFiled: August 20, 1991Date of Patent: July 7, 1992Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Reiner Kober, Norbert Goetz, Eberhard Ammermann, Gisela Lorenz
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Patent number: 5122531Abstract: Vinylazoles of the general formula I ##STR1## where R.sup.1 and R.sup.2 are alkyl, cycloalkyl, tetrahydropyranyl, pyridyl, naphthyl, biphenyl or phenyl, these radicals being substituted or unsubstituted, X is CH or N, and plant-tolerated acid addition salts and metal complexes thereof, and crop protection agents containing these compounds.Type: GrantFiled: September 21, 1990Date of Patent: June 16, 1992Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Wolfgang Rohr, Bernhard Zipperer, Stefan Karbach, Lothar Rueb, Eberhard Ammermann, Gisela Lorenz, Wilhelm Rademacher, Johann Jung
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Patent number: 5122532Abstract: A microbicidal halogenoallyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents halogenoallyl, propargyl, substituted cycloalkyl or optionally substituted heteroaryl, or represents a radical of the formula ##STR2## where R.sup.3 represents hydrogen, halogen, or phenyl which is optionally substituted by halogen, phenoxy which is optionally substituted by halogen or phenoxymethyl which is optionally substituted by halogen,R.sup.4 represents hydrogen or halogen, andR.sup.5 represents iso-propyl, or phenyl which is optionally substituted by halogen or phenoxy which is optionally substituted by halogen or phenoxy which is optionally substituted by halogen,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkyl,X.sup.1 represents halogen,X.sup.2 represents halogen,X.sup.3 represents hydrogen or halogen andY represents nitrogen or a CH group,and addition products thereof with acids and metal salts.Type: GrantFiled: January 25, 1991Date of Patent: June 16, 1992Assignee: Bayer AktiengesellschaftInventors: Manfred Jautelat, Klaus Stroech, Gerd Hanssler, Stefan Dutzmann, Karl-Heinz Kuck, Wilhelm Brandes
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Patent number: 5102899Abstract: Azolylmethyloxiranes of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are substituted or unsubstituted alkyl, benzyl, naphthyl, biphenyl, dioxanyl, phenyl, tetrahydropyranyl, tetrahydrofuranyl, norbornyl, C.sub.3 -C.sub.12 -cycloalkyl or C.sub.3 -C.sub.12 -cycloalkenyl, and X is CH or N, and plant-tolerated acid addition salts and metal complexes thereof, and fungicides containing these compounds.Type: GrantFiled: March 14, 1990Date of Patent: April 7, 1992Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Walter Himmele, Stefan Karbach, Hubert Sauter, Eberhard Ammermann, Gisela Lorenz
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Patent number: 5096912Abstract: A microbicidal hydroxyethyl-cyclopropyl-azolyl derivative of the formula ##STR1## in which R.sup.1 represents halogen, phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents alkyl, phenyl or benzyl,R.sup.2 represents alkenyl, optionally substituted furyl, optionally substituted thienyl or the radical of the formula ##STR2## wherein R.sup.4 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, 1,1,2-trifluoro-2-chloro-ethoxy, cyano, formyl, alkoximinoalkyl, carbalkoxy, dialkoxyalkyl, phenoxyalkyl which is optionally substituted in the phenyl moiety by halogen, or benzyloxy which is optionally substituted in the phenyl moiety by halogen andR.sup.5 represents hydrogen or halogen, orR.sup.4 and R.sup.5 are linked in the ortho-position and together represent --O--CH.sub.2 --O--, orR.sup.2 represents the radical of the formula ##STR3## in which R.sup.6 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy or 1,1,2-trifluoro-2-chloro-ethoxy, orR.sup.Type: GrantFiled: June 8, 1990Date of Patent: March 17, 1992Assignee: Bayer AktiengesellschaftInventors: Jurgen Scherkenbeck, Monika Frie, Klaus Stroech, Thomas Himmler, Georg-W. Ludwig, Wilhelm Brandes, Stefan Dutzmann
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Patent number: 5087635Abstract: This invention relates to substituted and unsubstituted alpha-aryl-alpha-phenylethyl-1H-1,2,4-triazole-1-propanenitriles, their enantiomorphs, acid addition salts and metal salt complexes. These compounds, enantiomorphs, salts and complexes are highly active broad-spectrum systemic fungicides effective in controlling phytopathogenic fungi such as corn helminthosporium, barley helminthosporium, cucumber downy mildew, cucumber powdery mildew, cucumber anthracnose, botrytis, tomato early blight, tomato late blight, grape downy mildew, bean powdery mildew, peanut cercospora, rice blast, rice sheath blight, wheat leaf rust, wheat septoria nodorum, wheat powdery mildew and wheat stem rust. The invention also concerns a method of preparing alpha-aryl-alpha-triazolylmethylacetonitrile compounds by reacting an aryl-acetonitrile compound with a halomethyltriazole.Type: GrantFiled: July 7, 1989Date of Patent: February 11, 1992Assignee: Rohm and Haas CompanyInventor: Steven H. Shaber
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Patent number: 5084471Abstract: 1-Halovinylazoles of the general formula I ##STR1## where A and R are each alkyl, cycloalkyl, cycloalkenyl, pyridyl, tetrahydropyranyl, naphthyl, biphenyl or phenyl, each of these radicals being substituted or unsubstituted, D is chlorine or bromine, and X is CH or N, acid addition salts and metal complexes thereof which are tolerated by plants, and fungicides and growth regulators containing these compounds.Type: GrantFiled: March 28, 1990Date of Patent: January 28, 1992Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Reiner Kober, Norbert Goetz, Thomas Saupe, Eberhard Ammermann, Gisela Lorenz, Wilhelm Rademacher, Johann Jung
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Patent number: 5081140Abstract: New halogenovinyl-azole derivatives of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl or optionally substituted aryl, or represents optionally substituted heteroaryl,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkylX.sup.1 represents halogen,X.sup.2 represents halogen,X.sup.3 represents hydrogen or halogenY represents nitrogen or a CH group,and acid addition salts and metal salt complexes thereofare very effective for combating microbes in plant protection and in the preservation of materials.Type: GrantFiled: July 24, 1989Date of Patent: January 14, 1992Assignee: Bayer AktiengesellschaftInventors: Manfred Jautelat, Dieter Berg, Stefan Dutzmann, Wilhelm Brandes, Gerd Hanssler, Astrid Mauler, Wilfried Paulus, Monika Frie
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Patent number: 5068338Abstract: Nitrosamine-free 3-isothiazolone biocidal compositions suitable for applications where substantial human or animal contact is anticipated, their method of use and process of preparation are disclosed.Type: GrantFiled: March 27, 1990Date of Patent: November 26, 1991Assignee: Rohm and Haas CompanyInventors: Horst O. Bayer, Barry C. Lange, Ramesh B. Petigara
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Patent number: 5059237Abstract: A butenoic acid derivative of the formula: ##STR1## which is useful as a herbicide.Type: GrantFiled: August 13, 1986Date of Patent: October 22, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Hideo Kohsaka, Masayuki Takase
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Patent number: 5057531Abstract: Azolylmethyloxiranes of the general formula I ##STR1## where R.sub.1 and R.sub.2 are substituted or unsubstituted alkyl, naphthyl, biphenyl, dioxanyl or phenyl,m and n are each an integer from 1 to 5 or 0, with the proviso that m+n is 1 or more, D is oxygen or a single bond,X is CH or N, and their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.Type: GrantFiled: February 24, 1989Date of Patent: October 15, 1991Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Stefan Karbach, Norbert Goetz, Gisela Lorenz, Eberhard Ammermann
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Patent number: 5049573Abstract: Fungicidal trazoles of the formula ##STR1## in which Ar stands for optionally substituted aryl,A stands for the groups ##STR2## and X stands for the groups ##STR3## wherein R.sup.1 stands for hydrogen or alkyl,R.sup.2 stands for hydrogen or alkyl,R.sup.3 stands for hydrogen, alkyl, alkenyl, alkanoyl, for optionally substituted cycloalkyl or for in each case optionally substituted aralkyl or aroyl,R.sup.4 stands for hydrogen, alkyl, for optionally substutited cycloalkyl or for in each case optionally substituted aralkyl or aryl andR.sup.5 and R.sup.6 independently of one another stand for alkyl or for optionally substituted aralkyl or together stand for an optionally substituted doubly-linked alkylene radical,and addition products thereof with acids and metal salts.Type: GrantFiled: May 22, 1990Date of Patent: September 17, 1991Assignee: Bayer AktiengesellschaftInventors: Gerd Kleefeld, Stefan Dutzmann
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Patent number: 5041459Abstract: Microbicidal hydroxy-keto-azoles of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl or optionally substituted aryl,R.sup.2 represents optionally substituted aryl or a five- or six-membered heterocyclic radical having up to 3 hetero-atoms, which is optionally substituted and optionally fused to benzene, andX represents a nitrogen atom or a CH group,and addition products thereof with acids and metal salts.Type: GrantFiled: June 8, 1990Date of Patent: August 20, 1991Assignee: Bayer AktiengesellschaftInventors: Manfred Jautelat, Wilhelm Brandes, Stefan Dutzmann, Gerd Hanssler
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Patent number: 5039814Abstract: A process utilizes the tetrazole functional group to direct lithiation at the ortho position of a phenyltetrazole and generate a nucleophilic aryllithium species which then undergoes reaction with an electrophile to generate a 2-substituted 1-(tetrazol-5-yl)benzene. The process is useful in the production of intermediates in the synthesis of angiotensin II antagonists. This novel process is a more cost effective and versatile route for the large-scale preparation of these key intermediates.Type: GrantFiled: May 2, 1990Date of Patent: August 13, 1991Assignee: Merck & Co., Inc.Inventors: Richard F. Shuman, Anthony O. King, Robert K. Anderson
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Patent number: 5034052Abstract: Fungicidal and plant growth-regulating azolylmethylcyclopropyl derivatives of the formula ##STR1## in which R repesents halogen, alkyl or optionally substituted phenyl, or represents the groupings --Y--R.sup.2,whereinY represents oxygen, sulphur, SO or SO.sub.2 andR.sup.2 represents optionally substituted phenyl,R.sup.1 represents hydrogen, alkyl or acyl,X represents nitrogen or a CH group,Z represents halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 or 4 carbon atoms, halogenoalkyl with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio with 1 or 2 carbon atoms and 1 to 5 halogen atoms or phenyl which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen, or represents phenoxy which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen andm represents the number 0, 1, 2 or 3,and addition products thereof with acids and metal salts.Type: GrantFiled: February 13, 1990Date of Patent: July 23, 1991Assignee: Bayer AktiengesellschaftInventors: Klaus Stroech, Wilhelm Brandes, Stefan Dutzmann
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Patent number: 5030730Abstract: Curable mixtures comprisinga) at least one epoxy resin containing on average more than one 1,2-epoxy group per molecule,b) at least one cyclic carboxylic anhydride,c) an adduct of a zinc salt of a C.sub.6 -C.sub.18 carboxylic acid with a tertiary amine, andd) optionally a filler and/or further conventional modifiers have a long pot life without impairment of the brief curing time at elevated temperatures.Type: GrantFiled: February 21, 1990Date of Patent: July 9, 1991Assignee: Ciba-Geigy CorporationInventor: Kurt Munk
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Patent number: 5025030Abstract: Novel hydroxyalkinyl-azolyl derivatives of the formula ##STR1## in which Ar represents optionally substituted aryl,R represents alkyl, optionally substituted aryl or optionally substituted aralkyl,X.sup.1 represents halogen,X.sup.2 represents hydrogen or halogen,X.sup.3 represents hydrogen or halogen,X.sup.4 represents hydrogen or halogen andn represents 0 or 1,and acid addition salts and metal salt complexes thereof, are outstandingly effective as fungicides.Type: GrantFiled: July 7, 1989Date of Patent: June 18, 1991Assignee: Bayer AktiengesellschaftInventors: Reinhard Lantzsch, Ernst Kysela, Karl H. Buchel, Stefan Dutzmann, Wilhelm Brandes, Gerd Hanssler
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Patent number: 5017595Abstract: Azolylmethylallyl alcohols of the formula I ##STR1## where R.sub.1 and R.sub.2 are alkyl, naphthyl, biphenyl, cycloalkyl, cycloalkenyl or phenyl, these radicals being unsubstituted or substituted, X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.Type: GrantFiled: March 6, 1989Date of Patent: May 21, 1991Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Hubert Sauter, Reiner Kober, Eberhard Ammermann, Gisela Lorenz
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Patent number: 5017594Abstract: 1-Halo-1-azolylpropenes and -methyloxiranes of the formula I ##STR1## where R.sup.1 and R.sup.2 are alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, A is oxygen or a single bond, R.sup.3 is F, Cl or Br, X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.Type: GrantFiled: July 7, 1989Date of Patent: May 21, 1991Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Reiner Kober, Norbert Goetz, Eberhard Ammermann, Gisela Lorenz
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Patent number: 5006152Abstract: Azolylmethylcyclopropanes of the formula ##STR1## where R is alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, and these radicals are substituted or unsubstituted, A is H, F, Cl or Br, and X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides and growth-regulating agents containing these compounds.Type: GrantFiled: September 19, 1989Date of Patent: April 9, 1991Assignee: BASF AktiengesellschaftInventors: Rainer Seele, Reiner Kober, Stefan Karbach, Hubert Sauter, Eberhard Ammermann, Gisela Lorenz, Wilhelm Rademacher, Johann Jung
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Patent number: 5004494Abstract: This invention relates to triazole and imidazole compounds useful as fungicides, to a process for preparing them, to fungicidal compositions containing them, and to a method of combating fungal infections in plants using them.The triazole and imidazole compounds have the general formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, are hydrogen, alkyl, optionally substituted cycloalkyl, cycloalkylmethyl, alkenyl, heterocyclyl, aryl or aralkyl optionally substituted with halogen, nitro, alkyl, haloalkyl, alkoxy, phenyl, phenoxy, benzyl, benzyloxy, halophenyl or haloalkoxy; R.sup.3 is hydrogen, alkyl, alkenyl, alkynyl, aralkyl or acyl; R.sup.4 and R.sup.5, which may be the same or different, are hydrogen, alkyl, alkenyl or optionally substituted aryl; R.sup.6 and R.sup.7, which may be the same or different, are hydrogen, alkyl, alkenyl or optionally substituted aryl; X is oxygen or sulphur or is SO or SO.sub.Type: GrantFiled: January 18, 1989Date of Patent: April 2, 1991Assignee: Imperial Chemical Industries PLCInventors: Balasubramanyan Sugavanam, Paul A. Worthington, John M. Clough
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Patent number: 4999043Abstract: Triazole compounds useful as plant growth regulators of the formula ##STR1## and stereoisomers thereof, wherein R.sup.1 is selected from alkyl and haloalkyl groups, R.sup.2 is hydrogen, and R.sup.3 is a tertiary butyl group optionally substituted by halogen; and acid addition salts, and metal complexes thereof.Type: GrantFiled: February 6, 1989Date of Patent: March 12, 1991Assignee: Imperial Chemical Industries PLCInventors: Raymond Elliott, John Dalziel, Raymond L. Sunley
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Patent number: 4994480Abstract: Fungicidal substituted triazolylmethylcarbinols of the formula ##STR1## in which n stands for the numbers 0 or 1,Ar stands for optionally substituted phenyl or for optionally substituted naphthyl,R.sup.1 stands for hydrogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted aralkyl, cycloalkyl or optionally substituted heteroarylalkyl,R.sup.2 stands for alkyl, cycloalkyl, cycloalkylalkyl or alkenyl,R.sup.3 stands for methyl andR.sup.4 stands for methyl orR.sup.3 and R.sup.4 together stand for ethane-1,2-diyl, and addition products thereof with acids and metal salts. Intermediates of the formulas ##STR2## in which R.sup.6 stands for alkyl having more than one carbon atom, cycloalkyl, cycloalkylalkyl or alkenyl, are also new.Type: GrantFiled: April 12, 1989Date of Patent: February 19, 1991Assignee: Bayer AktiengesellschaftInventors: Karl H. Buchel, Graham Holmwood, Gerd Hannsler, Wilhelm Brandes, Stefan Dutzmann
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Patent number: 4990623Abstract: A new class of sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazole compounds and method for using them and other sulfonated hydroxyaryl benzotriazoles on nylon fibers to improve stain resistance and dye lightfastness has been discovered. A process is provided for improving stain resistance of nylon fibers by treatment with sulfonated aromatic-formaldehyde condensate and fluorinated dry soil resist agents.Type: GrantFiled: July 24, 1989Date of Patent: February 5, 1991Inventors: Morris B. Berenbaum, John H. Bonfield, Charles J. Cole, Paul W. Harris, Thomas P. J. Izod, Harry E. Ulmer, Frederick R. Hopf, James T. Yardley, Karen M. Bland
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Patent number: 4988382Abstract: Plant growth-regulating and fungicidal compounds of the formula ##STR1## in which Ar represents optionally substituted aryl or optionally substituted heteroaryl,R.sup.1 represents hydrogen, alkyl, alkenyl, alkinyl, trialkylsilyl, optionally substituted phenylalkyl or an acyl radical,R.sup.2 represents halogen, cyano, thiocyano, alkylcarbonyloxy, alkylcarbonylthio or the groupings --X--R.sup.3 and --NR.sup.4 R.sup.5,R.sup.3 represents alkyl, cycloalkyl, alkenyl, alkinyl, hydroxyalkyl, alkylthioalkyl, carboxyalkyl, alkoxycarbonylalkyl, optionally substituted aryl, optionally substituted aralkyl or the radical of the formula ##STR2## R.sup.4 and R.sup.5 independently of one another represent hydrogen or alkyl, orR.sup.4 and R.sup.5, together with the nitrogen atom to which they are bonded, represent an optionally substituted cycloaliphatic ring which can contain further heteroatoms,X represents oxygen, sulphur, an SO group or an SO.sub.2 group, orR.sup.Type: GrantFiled: December 28, 1989Date of Patent: January 29, 1991Assignee: Bayer AktiengesellschaftInventors: Klaus Bockmann, Erik Regel, Karl H. Buchel, Klaus Lurssen, Jorg Konze, Wilhelm Brandes
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Patent number: 4988721Abstract: Compounds of the general formula ##STR1## where 5 R is alkyl or substituted or unsubstituted aryl,X is C.dbd.O or CHOH and derivatives thereof,Y is hydrogen, alkyl, alkoxy, halogen, aryl or aryloxy, andn is 1 to 5,and fungicides containing these compounds.Type: GrantFiled: February 9, 1990Date of Patent: January 29, 1991Assignee: BASF AktiengesellschaftInventors: Ulf Baus, Wolfgang Reuther, Gisela Lorenz, Eberhard Ammermann
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Patent number: 4988383Abstract: Fungicidal and plant growth-regulating cyclopropyl-hydroxyethyl-azolyl-derivatives of the formula ##STR1## in which R.sup.1 represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, alkylthio having 1 to 4 carbon atoms, halogenoalkyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio having 1 or 2 carbon atoms and 1 to 5 halogen atoms, alkoximinomethyl having 1 to 4 carbon atoms in the alkoxy group, phenyl optionally substituted by alkyl having 1 to 2 carbon atoms and/or halogen or phenoxy optionally substituted by alkyl having 1 or 2 carbon atoms and/or halogen,m represents the numbers 0, 1, 2 or 3,R.sup.2 represents optionally substituted benzyl or the radical --COOR.sup.3, in whichR.sup.3 represents alkyl, optionally substituted phenyl or optionally substituted benzyl,andY represents oxygen or sulphur,and their acid addition salts and metal salt complexes.Type: GrantFiled: February 6, 1990Date of Patent: January 29, 1991Assignee: Bayer AktiengesellschaftInventors: Gerhard Jager, Udo Kraatz, Stefan Dutzmann, Wilhelm Brandes, Gerd Hanssler
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Patent number: 4988715Abstract: Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, or other radicalsR.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts.Type: GrantFiled: August 3, 1989Date of Patent: January 29, 1991Assignee: Bayer AktiengesellschaftInventors: Hans-Ludwig Elbe, Eckart Kranz, Wilhelm Brandes, Stefan Dutzmann, Gerd Hanssler
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Patent number: 4987143Abstract: Compounds of the general formula ##STR1## where X is CH.sub.2 or O, Y is hydrogen, alkyl, alkoxy, halogen, aryl or aryloxy and n is from 1 to 5, and their salts and complexes, and fungicides containing these compounds.Type: GrantFiled: February 14, 1990Date of Patent: January 22, 1991Assignee: BASF AktiengesellschaftInventors: Ulf Baus, Wolfgang Reuther, Gisela Lorenz, Eberhard Ammermann
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Patent number: 4983208Abstract: Fungicidal and plant growth-regulating hydroxyalkylazolyl derivatives of the formula ##STR1## in which R represents hydrogen, alkyl or acyl,R.sup.1 represents halogen, optionally substituted phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents optionally substituted alkyl, optionally substituted phenyl or optionally substituted phenylalkyl,R.sup.2 represents optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted naphthyl or the radical of the formula ##STR2## m represents the numbers, 0, 1, 2 or 3, or R.sup.2 represents the radical or the formula ##STR3## X represents nitrogen or a CH group and Y represents the groupings --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--, ##STR4## and their addition products with acids and metal salts. Intermediates of the formulas ##STR5## are also new.Type: GrantFiled: September 14, 1989Date of Patent: January 8, 1991Assignee: Bayer AktiengesellschaftInventors: Klaus Stroech, Monika Frie, Thomas Himmler, Wilhelm Brandes, Stefan Dutzmann, Gerd Hanssler
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Patent number: 4981846Abstract: A novel crystalline L-carnosine zinc complex is produced by reacting L-carnosine, a zinc salt and an alkali metal compound in an anhydrous or hydrous polar organic solvent.The crystalline L-carnosine zinc complex substantially corresponds to the formula C.sub.9 H.sub.12 N.sub.4 O.sub.3 Zn and has physical properties clearly different from the known amorphous L-carnosine zinc complex.As compared with the amorphous complex, the crystalline complex is very low in impurity, stable to heat and moisture, and easy to filtrate, and has higher anti-ulcer activity.Type: GrantFiled: July 20, 1988Date of Patent: January 1, 1991Assignee: Hamari Chemicals, Ltd.Inventors: Takefumi Matsukura, Tamiko Takahashi, Yasuhiro Nishimura, Masahiro Takaya, Hajime Fujimura
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Patent number: 4968712Abstract: Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen or halogen,R.sup.2 represents hydrogen or halogen,R.sup.3 represents hydrogen, halogen or trifluoromethoxy,R.sup.4 represents halogen, trifluoromethoxy, trifluoromethylthio, trifluoromethylsulphinyl, trifluoromethylsulphonyl, difluoromethoxy, difluorochloromethoxy, trifluorochloroethoxy, tetrafluoroethoxy, trifluoroethoxy, difluoromethylthio, trifluorochloroethylthio, tetrafuoroethylthio, difluoromethylsulphinyl, difluorochloromethylsulphinyl, trifluorochloroethylsulphinyl, tetrafluoroethylsulphinyl, difluoromethylsulphonyl, difluorochloromethylsulphonyl, trifluorochloroethylsulphonyl, tetrafluoroethylsulphonyl, difluorobromomethylthio, difluorobromomethylsulphinyl, difluorobromomethylsulphonyl or difluorochloromethylthio orR.sup.3 and R.sup.4 together represent alkylenedioxy substituted by halogen,R.sup.Type: GrantFiled: July 29, 1988Date of Patent: November 6, 1990Assignee: Bayer AktiengesellschaftInventors: Hans-Ludwig Elbe, Albrecht Marhold, Karl H. Buchel, Stefan Dutzmann, Paul Reinecke, Wilhelm Brandes, Gerhard Hanssler
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Patent number: 4963470Abstract: Titanocenes with silylated .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine, --CF.sub.3, --C.sub.2 F.sub.5, --CF.sub.2 CL or --CF.sub.2 CH.sub.3 in at least one of the two ortho-positions relative to the metal-carbon bonds, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates. They are distinguished by a high sensitivity, stability to air and the action of heat, and a high activity in the region of UV light to visible light. They are furthermore readily soluble in the photopolymerizable compositions.Type: GrantFiled: January 19, 1990Date of Patent: October 16, 1990Assignee: Ciba-Geigy CorporationInventors: Bernd Klingert, Franciszek Sitek, Manfred Rembold
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Patent number: 4962118Abstract: Fungicidal trazoles of the formula ##STR1## in which Ar stands for optionally substituted aryl,A stands for the groups ##STR2## and X stands for the groups ##STR3## wherein R.sup.1 stands for hydrogen or alkyl,R.sup.2 stands for hydrogen or alkyl,R.sup.3 stands for hydrogen, alkyl, alkenyl, alkanoyl, for optionally substituted cycloalkyl or for in each case optionally substituted aralkyl or aroyl,R.sup.4 stands for hydrogen, alkyl, for optionally substituted cycloalkyl or for in each case optionally substituted aralkyl or aryl andR.sup.5 and R.sup.6 independently of one another stand for alkyl or for optionally substituted aralkyl or together stand for an optionally substituted doubly-linked alkylene radical,and addition products thereof with acids and metal salts.Type: GrantFiled: February 15, 1989Date of Patent: October 9, 1990Assignee: Bayer AktiengesellschaftInventors: Gerd Kleefeld, Stefan Dutzmann
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Patent number: 4960781Abstract: Fungicidal bisazolyl-hydroxyalkyl derivatives of the formula ##STR1## in which Ar stands for optionally substituted aryl,X stands for a grouping --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --SCH.sub.2 -- or --SH.dbd.CH--,Y stands for a nitrogen atom or the grouping CR.sup.3,R.sup.1, R.sup.2 and R.sup.3 stand for hydrogen, halogen or methyl, andn stands for the numbers 0, 1 or 2,and acid addition salts and metal salt complexes thereof. Intermediates of the formulas ##STR2## are also new.Type: GrantFiled: February 16, 1990Date of Patent: October 2, 1990Assignee: Bayer AktiengesellschaftInventors: Graham Holmwood, Wolfgang Kramer, Erik Regel, Hans L. Elbe, Karl H. Buchel, Stefan Dutzmann, Wilhelm Brandes, Paul Reinecke
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Patent number: 4960456Abstract: Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents a substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cyclo-alkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.Type: GrantFiled: May 19, 1989Date of Patent: October 2, 1990Assignee: Bayer AktiengesellschaftInventors: Graham Holmwood, Erik Regel, Gerhard Jager, Karl H. Buchel, Klaus Lurssen, Paul-Ernst Frohberger, Wilhelm Brandes, Volker Paul
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Patent number: 4959135Abstract: Methods and apparatus for the extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising linear, pentadentate polyalkylamines and transition metal ions. The carrier compounds have the general formula: ##STR1## where, each of R.sub.1 and R.sub.2 is independently an organic group including a sulfur, an oxygen or a nitrogen coordinated to M;each of m, n, o, and p is 1, 2, 3, or 4;X is selected from the group consisting of 2,6-pyridyl, 2,6-piperidyl, 2,5-pyrrolyl, 2,4-imidazolyl, substituted heterocyclic amines, --)--, --S--, ##STR2## and ##STR3## where R.sub.3 is hydrogen, lower alkyl or aralkyl; and M is a transition metal ion.Type: GrantFiled: February 3, 1989Date of Patent: September 25, 1990Assignee: Aquanautics CorporationInventors: Bruce D. Zenner, Joseph P. Ciccone, Emory S. De Castro, Larrie A. Deardurff, John B. Kerr
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Patent number: 4956466Abstract: Thiazole derivatives of the general formula where: ##STR1## X is an anion of pharmaceutically acceptable acids; a is an integer from 1 to 5;b is an integer from 1 to 7;c is 0 or an integer from 1 to 4; andd is 2a-c for monovalent acid anions, is a-c for divalent acid anions, and is 0 or 2 when c=0.The process for the preparation of the above derivatives is based on reacting N-methyl-N'-2-((2-(dimethylaminomethyl)-4-thiazolyl) methylthio)ethyl)-2-nitro-1,1-ethylenediamine of formula II with an X anion containing zinc compound or an organozinc.Type: GrantFiled: May 23, 1989Date of Patent: September 11, 1990Assignee: Laboratorios Vinas, S. A.Inventor: Antonio B. Vinas
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Patent number: 4954162Abstract: Fungicidal and plant-growth regulating azolymethyl-cyclopropyl carbinol derivatives of the formula ##STR1## in which R represents perfluroalkyl having 1 to 4 carbon atoms, trichloromethyl, difluorochloromethyl or fluorodichloromethyl,R.sup.1 represents hydrogen, alkl or acyl,Z represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, alkylthio having 1 to 4 carbon atoms, halogenoakyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkythio having 1 to 2 carbon atoms and 1 to 5 halogen atoms, phenyl which is optionally substituted by alkyl having 1 to 2 carbon atoms and/or halogen, or phenoxy which is optionally substituted by alkyl having 1 or 2 carbon atoms and/or halogen,m represents the numbers 0, 1, 2 or 3 andn represents the numbers 0, 1 or 2 andX represents nitrogen or a CH group, and addition products thereof with acids and metal salts.Type: GrantFiled: June 9, 1988Date of Patent: September 4, 1990Assignee: Bayer AktiengesellschaftInventors: Klaus Stroech, Dietmar Beilefeldt, Wilhelm Brandes, Stefan Dutzmann
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Patent number: 4952289Abstract: Methods and apparatus for electrochemical extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising macrocyclic amines having the general formulas: ##STR1## where: A, B, C, D, E, and F are each nitrogen, oxygen, sulfur, or phosphorous;m, n, o, p, q, and r are each typically 2, 3, 4, 5, or 6;the R substituents are each generally H or short chain (linear or branched) alkyl, although R.sub.2 may represent ketyl (.dbd.o); andM is a suitable transition metal ion.Type: GrantFiled: May 9, 1988Date of Patent: August 28, 1990Assignee: Aquanautics CorporationInventors: Joseph P. Ciccone, Emory S. DeCastro, John B. Kerr
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Patent number: 4946493Abstract: Fungicidal or plant growth regulating triazoles or imidazoles of the formula ##STR1## wherein R.sup.1 is --CH.dbd.CH--X, --C.tbd.C--X or --CH.sub.2 --CH.sub.2 --X where X is H, alkyl, hydroxyalkyl, alkoxyalkyl, cycloalkyl or optionally substituted aryl, aralkyl, aryloxyalkyl, or heterocycle; and R.sup.2 is alkyl, cycloalkyl (e.g. cyclopropyl, cyclopentyl, or cyclohexyl) or optionally substituted aryl; Z is Cl, CN or OR.sup.3 where R.sup.3 is H, acetyl, alkenyl or aralkyl; Y is .dbd.N-- or .dbd.CH--; and acid addition salts and metal complexes thereof.Type: GrantFiled: January 27, 1987Date of Patent: August 7, 1990Assignee: Imperial Chemical Industries PLCInventor: Balasubramanyan Sugavanam
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Patent number: 4945101Abstract: Hydroxyalkinyl-azolyl derivatives of the formula ##STR1## in which A is a nitrogen atom or the CH group,R is optionally substituted alkyl, cycloalkyl or phenyl,R.sup.1 is hydrogen, alkyl, alkenyl, alkinyl, or optionally substituted benzyl,R.sup.2 is hydrogen or methyl, andX is hydrogen, bromine or iodine,or addition products thereof with acids or metal salts exhibit fungicidal activity. Some intermediates therefor are also new.Type: GrantFiled: October 4, 1985Date of Patent: July 31, 1990Assignee: Bayer AktiengesellschaftInventors: Gerhard Jager, Klaus Bockmann, Karl H. Buchel, Wilhelm Brandes, Paul-Ernst Frohberger, Hans Scheinpflug
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Patent number: 4940798Abstract: A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.Type: GrantFiled: September 24, 1987Date of Patent: July 10, 1990Assignee: Bayer AktiengesellschaftInventors: Hans-Ludwig Elbe, Wolf Reiser, Erik Regel, Karl H. Buchel, Paul Reinecke, Wilhelm Brandes, Klaus Lurssen, Paul-Ernst Frohberger
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Patent number: 4939162Abstract: Novel 1-(2-aryl-1,3-dioxan-2-ylmethyl)-1H-imidazoles and 1H-1,2,4-triazoles wherein the 1,3-dioxane ring is optionally substituted with 1 to 3 substituents.Type: GrantFiled: February 24, 1989Date of Patent: July 3, 1990Assignee: Janssen Pharmaceutica N.V.Inventors: Jan Heeres, Leo Backx, Adolf Hubele
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Patent number: 4938791Abstract: Fungicidal and plant growth regulating hydroxyethylazolyl derivatives of the formula ##STR1## in which R represents hydrogen, alkyl or acyl,R.sup.1 represents halogen, optionaly substituted phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents optionally substituted phenyl,R.sup.Type: GrantFiled: June 24, 1988Date of Patent: July 3, 1990Assignee: Bayer AktiengesellschaftInventors: Klaus Stroech, Klaus Bockmann, Stefan Dutzmann, Wilhelm Brandes, Klaus Lurssen, Paul Reinecke
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Patent number: 4936907Abstract: Plant growth-regulating azolyl spiro compounds of the formula ##STR1## in which R stands for halogen, alkyl, alkoxy, alkylthio, optionally substituted phenyl, optionally substituted phenoxy, amino, alkylamino and/or dialkylamino,n stands for the numbers 0, 1, 2 or 3 andX stands for nitrogen or a CH group,and addition products thereof with acids and metal salts.Type: GrantFiled: October 26, 1988Date of Patent: June 26, 1990Assignee: Bayer AktiengesellschaftInventors: Manfred Jautelat, Hans-Ludwig Elbe, Klaus Lurssen
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Patent number: 4935459Abstract: Flameproofed compositions of matter include an organic synthetic resin and, as a flame retardant therefor, an effective flameproofing amount of specified nitrogenous/halometallic compounds, certain of which are per se novel.Type: GrantFiled: August 24, 1989Date of Patent: June 19, 1990Assignee: AtochemInventors: Daniel Sallet, Pierre Deloy, Valerie Mailhos-Lefievre, Pierre Poisson
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Patent number: 4935436Abstract: Substituted triazole compounds, their preparation, compositions containing said compounds and the use of said compositions to control fungal infections in plants are disclosed.Type: GrantFiled: January 23, 1989Date of Patent: June 19, 1990Assignee: The Dow Chemical CompanyInventors: Lowell D. Markley, Richard B. Rogers, Neil V. Kirby, John W. Liebeschuetz, Peter F. S. Street
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Patent number: 4931082Abstract: This invention relates to heterocyclic compounds useful as plant growth regulating agents, to processes for preparing them, to compositions containing them and to methods of regulating plant growth using them.Type: GrantFiled: November 25, 1986Date of Patent: June 5, 1990Assignee: Imperial Chemical Industries PLCInventor: Raymond Elliott