Heavy Metal Or Aluminum Containing Patents (Class 548/101)
  • Patent number: 5132318
    Abstract: Azolylmethyloxiranes of the general formula I ##STR1## where A and B are cycloalkyl, tetrahydropyranyl, tetrahydrofuranyl, dioxanyl, norbornyl, cycloalkenyl or phenyl, each of these radicals being unsubstituted or substituted, with the proviso that A and B are not simultaneously phenyl, D is O, X is CH or N, and their plant-tolerated acid addition salts or metal complexes, and fungicides containing these compounds.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: July 21, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Stefan Karbach, Thomas Kuekenhoehner, Hubert Sauter, Gisela Lorenz, Eberhard Ammermann
  • Patent number: 5128357
    Abstract: 1-Alkoxy-1-azolylmethyloxiranes of the general ##STR1## where R.sup.1 and R.sup.2 are identical or different and each is C.sub.1 -C.sub.8 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.5 -C.sub.8 -cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenylyl or phenyl, each of which is unsubstituted or mono- to trisubstituted by halogen, nitro, phenoxy, amino, alkyl, alkoxy or haloalkyl of 1 to 4 carbon atoms in each case, R.sup.3 is C.sub.1 -C.sub.4 -alkyl, X is CH or N, the acid addition salts and metal complexes thereof which are tolerated by plants, processes for their manufacture, and their use for combating fungi.
    Type: Grant
    Filed: August 20, 1991
    Date of Patent: July 7, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Reiner Kober, Norbert Goetz, Eberhard Ammermann, Gisela Lorenz
  • Patent number: 5122531
    Abstract: Vinylazoles of the general formula I ##STR1## where R.sup.1 and R.sup.2 are alkyl, cycloalkyl, tetrahydropyranyl, pyridyl, naphthyl, biphenyl or phenyl, these radicals being substituted or unsubstituted, X is CH or N, and plant-tolerated acid addition salts and metal complexes thereof, and crop protection agents containing these compounds.
    Type: Grant
    Filed: September 21, 1990
    Date of Patent: June 16, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Wolfgang Rohr, Bernhard Zipperer, Stefan Karbach, Lothar Rueb, Eberhard Ammermann, Gisela Lorenz, Wilhelm Rademacher, Johann Jung
  • Patent number: 5122532
    Abstract: A microbicidal halogenoallyl-azolyl derivatives of the formula ##STR1## in which R.sup.1 represents halogenoallyl, propargyl, substituted cycloalkyl or optionally substituted heteroaryl, or represents a radical of the formula ##STR2## where R.sup.3 represents hydrogen, halogen, or phenyl which is optionally substituted by halogen, phenoxy which is optionally substituted by halogen or phenoxymethyl which is optionally substituted by halogen,R.sup.4 represents hydrogen or halogen, andR.sup.5 represents iso-propyl, or phenyl which is optionally substituted by halogen or phenoxy which is optionally substituted by halogen or phenoxy which is optionally substituted by halogen,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkyl,X.sup.1 represents halogen,X.sup.2 represents halogen,X.sup.3 represents hydrogen or halogen andY represents nitrogen or a CH group,and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: January 25, 1991
    Date of Patent: June 16, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Jautelat, Klaus Stroech, Gerd Hanssler, Stefan Dutzmann, Karl-Heinz Kuck, Wilhelm Brandes
  • Patent number: 5102899
    Abstract: Azolylmethyloxiranes of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are substituted or unsubstituted alkyl, benzyl, naphthyl, biphenyl, dioxanyl, phenyl, tetrahydropyranyl, tetrahydrofuranyl, norbornyl, C.sub.3 -C.sub.12 -cycloalkyl or C.sub.3 -C.sub.12 -cycloalkenyl, and X is CH or N, and plant-tolerated acid addition salts and metal complexes thereof, and fungicides containing these compounds.
    Type: Grant
    Filed: March 14, 1990
    Date of Patent: April 7, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Walter Himmele, Stefan Karbach, Hubert Sauter, Eberhard Ammermann, Gisela Lorenz
  • Patent number: 5096912
    Abstract: A microbicidal hydroxyethyl-cyclopropyl-azolyl derivative of the formula ##STR1## in which R.sup.1 represents halogen, phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents alkyl, phenyl or benzyl,R.sup.2 represents alkenyl, optionally substituted furyl, optionally substituted thienyl or the radical of the formula ##STR2## wherein R.sup.4 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy, 1,1,2-trifluoro-2-chloro-ethoxy, cyano, formyl, alkoximinoalkyl, carbalkoxy, dialkoxyalkyl, phenoxyalkyl which is optionally substituted in the phenyl moiety by halogen, or benzyloxy which is optionally substituted in the phenyl moiety by halogen andR.sup.5 represents hydrogen or halogen, orR.sup.4 and R.sup.5 are linked in the ortho-position and together represent --O--CH.sub.2 --O--, orR.sup.2 represents the radical of the formula ##STR3## in which R.sup.6 represents difluoromethoxy, 1,1,2,2-tetrafluoroethoxy or 1,1,2-trifluoro-2-chloro-ethoxy, orR.sup.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: March 17, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Scherkenbeck, Monika Frie, Klaus Stroech, Thomas Himmler, Georg-W. Ludwig, Wilhelm Brandes, Stefan Dutzmann
  • Patent number: 5087635
    Abstract: This invention relates to substituted and unsubstituted alpha-aryl-alpha-phenylethyl-1H-1,2,4-triazole-1-propanenitriles, their enantiomorphs, acid addition salts and metal salt complexes. These compounds, enantiomorphs, salts and complexes are highly active broad-spectrum systemic fungicides effective in controlling phytopathogenic fungi such as corn helminthosporium, barley helminthosporium, cucumber downy mildew, cucumber powdery mildew, cucumber anthracnose, botrytis, tomato early blight, tomato late blight, grape downy mildew, bean powdery mildew, peanut cercospora, rice blast, rice sheath blight, wheat leaf rust, wheat septoria nodorum, wheat powdery mildew and wheat stem rust. The invention also concerns a method of preparing alpha-aryl-alpha-triazolylmethylacetonitrile compounds by reacting an aryl-acetonitrile compound with a halomethyltriazole.
    Type: Grant
    Filed: July 7, 1989
    Date of Patent: February 11, 1992
    Assignee: Rohm and Haas Company
    Inventor: Steven H. Shaber
  • Patent number: 5084471
    Abstract: 1-Halovinylazoles of the general formula I ##STR1## where A and R are each alkyl, cycloalkyl, cycloalkenyl, pyridyl, tetrahydropyranyl, naphthyl, biphenyl or phenyl, each of these radicals being substituted or unsubstituted, D is chlorine or bromine, and X is CH or N, acid addition salts and metal complexes thereof which are tolerated by plants, and fungicides and growth regulators containing these compounds.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: January 28, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Reiner Kober, Norbert Goetz, Thomas Saupe, Eberhard Ammermann, Gisela Lorenz, Wilhelm Rademacher, Johann Jung
  • Patent number: 5081140
    Abstract: New halogenovinyl-azole derivatives of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl or optionally substituted aryl, or represents optionally substituted heteroaryl,R.sup.2 represents hydrogen, alkyl, alkenyl, acyl or aralkylX.sup.1 represents halogen,X.sup.2 represents halogen,X.sup.3 represents hydrogen or halogenY represents nitrogen or a CH group,and acid addition salts and metal salt complexes thereofare very effective for combating microbes in plant protection and in the preservation of materials.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: January 14, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Jautelat, Dieter Berg, Stefan Dutzmann, Wilhelm Brandes, Gerd Hanssler, Astrid Mauler, Wilfried Paulus, Monika Frie
  • Patent number: 5068338
    Abstract: Nitrosamine-free 3-isothiazolone biocidal compositions suitable for applications where substantial human or animal contact is anticipated, their method of use and process of preparation are disclosed.
    Type: Grant
    Filed: March 27, 1990
    Date of Patent: November 26, 1991
    Assignee: Rohm and Haas Company
    Inventors: Horst O. Bayer, Barry C. Lange, Ramesh B. Petigara
  • Patent number: 5059237
    Abstract: A butenoic acid derivative of the formula: ##STR1## which is useful as a herbicide.
    Type: Grant
    Filed: August 13, 1986
    Date of Patent: October 22, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hideo Kohsaka, Masayuki Takase
  • Patent number: 5057531
    Abstract: Azolylmethyloxiranes of the general formula I ##STR1## where R.sub.1 and R.sub.2 are substituted or unsubstituted alkyl, naphthyl, biphenyl, dioxanyl or phenyl,m and n are each an integer from 1 to 5 or 0, with the proviso that m+n is 1 or more, D is oxygen or a single bond,X is CH or N, and their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: October 15, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Stefan Karbach, Norbert Goetz, Gisela Lorenz, Eberhard Ammermann
  • Patent number: 5049573
    Abstract: Fungicidal trazoles of the formula ##STR1## in which Ar stands for optionally substituted aryl,A stands for the groups ##STR2## and X stands for the groups ##STR3## wherein R.sup.1 stands for hydrogen or alkyl,R.sup.2 stands for hydrogen or alkyl,R.sup.3 stands for hydrogen, alkyl, alkenyl, alkanoyl, for optionally substituted cycloalkyl or for in each case optionally substituted aralkyl or aroyl,R.sup.4 stands for hydrogen, alkyl, for optionally substutited cycloalkyl or for in each case optionally substituted aralkyl or aryl andR.sup.5 and R.sup.6 independently of one another stand for alkyl or for optionally substituted aralkyl or together stand for an optionally substituted doubly-linked alkylene radical,and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: May 22, 1990
    Date of Patent: September 17, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerd Kleefeld, Stefan Dutzmann
  • Patent number: 5041459
    Abstract: Microbicidal hydroxy-keto-azoles of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, optionally substituted alkenyl, optionally substituted cycloalkyl or optionally substituted aryl,R.sup.2 represents optionally substituted aryl or a five- or six-membered heterocyclic radical having up to 3 hetero-atoms, which is optionally substituted and optionally fused to benzene, andX represents a nitrogen atom or a CH group,and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: June 8, 1990
    Date of Patent: August 20, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Jautelat, Wilhelm Brandes, Stefan Dutzmann, Gerd Hanssler
  • Patent number: 5039814
    Abstract: A process utilizes the tetrazole functional group to direct lithiation at the ortho position of a phenyltetrazole and generate a nucleophilic aryllithium species which then undergoes reaction with an electrophile to generate a 2-substituted 1-(tetrazol-5-yl)benzene. The process is useful in the production of intermediates in the synthesis of angiotensin II antagonists. This novel process is a more cost effective and versatile route for the large-scale preparation of these key intermediates.
    Type: Grant
    Filed: May 2, 1990
    Date of Patent: August 13, 1991
    Assignee: Merck & Co., Inc.
    Inventors: Richard F. Shuman, Anthony O. King, Robert K. Anderson
  • Patent number: 5034052
    Abstract: Fungicidal and plant growth-regulating azolylmethylcyclopropyl derivatives of the formula ##STR1## in which R repesents halogen, alkyl or optionally substituted phenyl, or represents the groupings --Y--R.sup.2,whereinY represents oxygen, sulphur, SO or SO.sub.2 andR.sup.2 represents optionally substituted phenyl,R.sup.1 represents hydrogen, alkyl or acyl,X represents nitrogen or a CH group,Z represents halogen, alkyl with 1 to 4 carbon atoms, alkoxy with 1 to 4 carbon atoms, alkylthio with 1 or 4 carbon atoms, halogenoalkyl with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy with 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio with 1 or 2 carbon atoms and 1 to 5 halogen atoms or phenyl which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen, or represents phenoxy which is optionally substituted by alkyl with 1 or 2 carbon atoms and/or halogen andm represents the number 0, 1, 2 or 3,and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: February 13, 1990
    Date of Patent: July 23, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Stroech, Wilhelm Brandes, Stefan Dutzmann
  • Patent number: 5030730
    Abstract: Curable mixtures comprisinga) at least one epoxy resin containing on average more than one 1,2-epoxy group per molecule,b) at least one cyclic carboxylic anhydride,c) an adduct of a zinc salt of a C.sub.6 -C.sub.18 carboxylic acid with a tertiary amine, andd) optionally a filler and/or further conventional modifiers have a long pot life without impairment of the brief curing time at elevated temperatures.
    Type: Grant
    Filed: February 21, 1990
    Date of Patent: July 9, 1991
    Assignee: Ciba-Geigy Corporation
    Inventor: Kurt Munk
  • Patent number: 5025030
    Abstract: Novel hydroxyalkinyl-azolyl derivatives of the formula ##STR1## in which Ar represents optionally substituted aryl,R represents alkyl, optionally substituted aryl or optionally substituted aralkyl,X.sup.1 represents halogen,X.sup.2 represents hydrogen or halogen,X.sup.3 represents hydrogen or halogen,X.sup.4 represents hydrogen or halogen andn represents 0 or 1,and acid addition salts and metal salt complexes thereof, are outstandingly effective as fungicides.
    Type: Grant
    Filed: July 7, 1989
    Date of Patent: June 18, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Reinhard Lantzsch, Ernst Kysela, Karl H. Buchel, Stefan Dutzmann, Wilhelm Brandes, Gerd Hanssler
  • Patent number: 5017595
    Abstract: Azolylmethylallyl alcohols of the formula I ##STR1## where R.sub.1 and R.sub.2 are alkyl, naphthyl, biphenyl, cycloalkyl, cycloalkenyl or phenyl, these radicals being unsubstituted or substituted, X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.
    Type: Grant
    Filed: March 6, 1989
    Date of Patent: May 21, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Hubert Sauter, Reiner Kober, Eberhard Ammermann, Gisela Lorenz
  • Patent number: 5017594
    Abstract: 1-Halo-1-azolylpropenes and -methyloxiranes of the formula I ##STR1## where R.sup.1 and R.sup.2 are alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, A is oxygen or a single bond, R.sup.3 is F, Cl or Br, X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides containing these compounds.
    Type: Grant
    Filed: July 7, 1989
    Date of Patent: May 21, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Reiner Kober, Norbert Goetz, Eberhard Ammermann, Gisela Lorenz
  • Patent number: 5006152
    Abstract: Azolylmethylcyclopropanes of the formula ##STR1## where R is alkyl, cycloalkyl, cycloalkenyl, tetrahydropyranyl, norbornyl, pyridyl, naphthyl, biphenyl or phenyl, and these radicals are substituted or unsubstituted, A is H, F, Cl or Br, and X is CH or N, their plant-tolerated acid addition salts and metal complexes, and fungicides and growth-regulating agents containing these compounds.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: April 9, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Seele, Reiner Kober, Stefan Karbach, Hubert Sauter, Eberhard Ammermann, Gisela Lorenz, Wilhelm Rademacher, Johann Jung
  • Patent number: 5004494
    Abstract: This invention relates to triazole and imidazole compounds useful as fungicides, to a process for preparing them, to fungicidal compositions containing them, and to a method of combating fungal infections in plants using them.The triazole and imidazole compounds have the general formula (I): ##STR1## wherein R.sup.1 and R.sup.2, which may be the same or different, are hydrogen, alkyl, optionally substituted cycloalkyl, cycloalkylmethyl, alkenyl, heterocyclyl, aryl or aralkyl optionally substituted with halogen, nitro, alkyl, haloalkyl, alkoxy, phenyl, phenoxy, benzyl, benzyloxy, halophenyl or haloalkoxy; R.sup.3 is hydrogen, alkyl, alkenyl, alkynyl, aralkyl or acyl; R.sup.4 and R.sup.5, which may be the same or different, are hydrogen, alkyl, alkenyl or optionally substituted aryl; R.sup.6 and R.sup.7, which may be the same or different, are hydrogen, alkyl, alkenyl or optionally substituted aryl; X is oxygen or sulphur or is SO or SO.sub.
    Type: Grant
    Filed: January 18, 1989
    Date of Patent: April 2, 1991
    Assignee: Imperial Chemical Industries PLC
    Inventors: Balasubramanyan Sugavanam, Paul A. Worthington, John M. Clough
  • Patent number: 4999043
    Abstract: Triazole compounds useful as plant growth regulators of the formula ##STR1## and stereoisomers thereof, wherein R.sup.1 is selected from alkyl and haloalkyl groups, R.sup.2 is hydrogen, and R.sup.3 is a tertiary butyl group optionally substituted by halogen; and acid addition salts, and metal complexes thereof.
    Type: Grant
    Filed: February 6, 1989
    Date of Patent: March 12, 1991
    Assignee: Imperial Chemical Industries PLC
    Inventors: Raymond Elliott, John Dalziel, Raymond L. Sunley
  • Patent number: 4994480
    Abstract: Fungicidal substituted triazolylmethylcarbinols of the formula ##STR1## in which n stands for the numbers 0 or 1,Ar stands for optionally substituted phenyl or for optionally substituted naphthyl,R.sup.1 stands for hydrogen, optionally substituted alkyl, optionally substituted alkenyl, optionally substituted alkinyl, optionally substituted aralkyl, cycloalkyl or optionally substituted heteroarylalkyl,R.sup.2 stands for alkyl, cycloalkyl, cycloalkylalkyl or alkenyl,R.sup.3 stands for methyl andR.sup.4 stands for methyl orR.sup.3 and R.sup.4 together stand for ethane-1,2-diyl, and addition products thereof with acids and metal salts. Intermediates of the formulas ##STR2## in which R.sup.6 stands for alkyl having more than one carbon atom, cycloalkyl, cycloalkylalkyl or alkenyl, are also new.
    Type: Grant
    Filed: April 12, 1989
    Date of Patent: February 19, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Karl H. Buchel, Graham Holmwood, Gerd Hannsler, Wilhelm Brandes, Stefan Dutzmann
  • Patent number: 4990623
    Abstract: A new class of sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazole compounds and method for using them and other sulfonated hydroxyaryl benzotriazoles on nylon fibers to improve stain resistance and dye lightfastness has been discovered. A process is provided for improving stain resistance of nylon fibers by treatment with sulfonated aromatic-formaldehyde condensate and fluorinated dry soil resist agents.
    Type: Grant
    Filed: July 24, 1989
    Date of Patent: February 5, 1991
    Inventors: Morris B. Berenbaum, John H. Bonfield, Charles J. Cole, Paul W. Harris, Thomas P. J. Izod, Harry E. Ulmer, Frederick R. Hopf, James T. Yardley, Karen M. Bland
  • Patent number: 4988382
    Abstract: Plant growth-regulating and fungicidal compounds of the formula ##STR1## in which Ar represents optionally substituted aryl or optionally substituted heteroaryl,R.sup.1 represents hydrogen, alkyl, alkenyl, alkinyl, trialkylsilyl, optionally substituted phenylalkyl or an acyl radical,R.sup.2 represents halogen, cyano, thiocyano, alkylcarbonyloxy, alkylcarbonylthio or the groupings --X--R.sup.3 and --NR.sup.4 R.sup.5,R.sup.3 represents alkyl, cycloalkyl, alkenyl, alkinyl, hydroxyalkyl, alkylthioalkyl, carboxyalkyl, alkoxycarbonylalkyl, optionally substituted aryl, optionally substituted aralkyl or the radical of the formula ##STR2## R.sup.4 and R.sup.5 independently of one another represent hydrogen or alkyl, orR.sup.4 and R.sup.5, together with the nitrogen atom to which they are bonded, represent an optionally substituted cycloaliphatic ring which can contain further heteroatoms,X represents oxygen, sulphur, an SO group or an SO.sub.2 group, orR.sup.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: January 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Bockmann, Erik Regel, Karl H. Buchel, Klaus Lurssen, Jorg Konze, Wilhelm Brandes
  • Patent number: 4988721
    Abstract: Compounds of the general formula ##STR1## where 5 R is alkyl or substituted or unsubstituted aryl,X is C.dbd.O or CHOH and derivatives thereof,Y is hydrogen, alkyl, alkoxy, halogen, aryl or aryloxy, andn is 1 to 5,and fungicides containing these compounds.
    Type: Grant
    Filed: February 9, 1990
    Date of Patent: January 29, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Baus, Wolfgang Reuther, Gisela Lorenz, Eberhard Ammermann
  • Patent number: 4988383
    Abstract: Fungicidal and plant growth-regulating cyclopropyl-hydroxyethyl-azolyl-derivatives of the formula ##STR1## in which R.sup.1 represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, alkylthio having 1 to 4 carbon atoms, halogenoalkyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkylthio having 1 or 2 carbon atoms and 1 to 5 halogen atoms, alkoximinomethyl having 1 to 4 carbon atoms in the alkoxy group, phenyl optionally substituted by alkyl having 1 to 2 carbon atoms and/or halogen or phenoxy optionally substituted by alkyl having 1 or 2 carbon atoms and/or halogen,m represents the numbers 0, 1, 2 or 3,R.sup.2 represents optionally substituted benzyl or the radical --COOR.sup.3, in whichR.sup.3 represents alkyl, optionally substituted phenyl or optionally substituted benzyl,andY represents oxygen or sulphur,and their acid addition salts and metal salt complexes.
    Type: Grant
    Filed: February 6, 1990
    Date of Patent: January 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Jager, Udo Kraatz, Stefan Dutzmann, Wilhelm Brandes, Gerd Hanssler
  • Patent number: 4988715
    Abstract: Fungicidal dioxolanes of the formula ##STR1## in which R.sup.1 represents optionally substituted alkyl, or other radicalsR.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 independently of one another represent hydrogen, alkyl or cycloalkyl, orR.sup.3 and R.sup.4 together represent divalent alkanediyl and/orR.sup.5 and R.sup.6 together represent divalent alkanediyl andA represents nitrogen or a CH group,and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: August 3, 1989
    Date of Patent: January 29, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Ludwig Elbe, Eckart Kranz, Wilhelm Brandes, Stefan Dutzmann, Gerd Hanssler
  • Patent number: 4987143
    Abstract: Compounds of the general formula ##STR1## where X is CH.sub.2 or O, Y is hydrogen, alkyl, alkoxy, halogen, aryl or aryloxy and n is from 1 to 5, and their salts and complexes, and fungicides containing these compounds.
    Type: Grant
    Filed: February 14, 1990
    Date of Patent: January 22, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Ulf Baus, Wolfgang Reuther, Gisela Lorenz, Eberhard Ammermann
  • Patent number: 4983208
    Abstract: Fungicidal and plant growth-regulating hydroxyalkylazolyl derivatives of the formula ##STR1## in which R represents hydrogen, alkyl or acyl,R.sup.1 represents halogen, optionally substituted phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents optionally substituted alkyl, optionally substituted phenyl or optionally substituted phenylalkyl,R.sup.2 represents optionally substituted alkyl, optionally substituted cycloalkyl, optionally substituted naphthyl or the radical of the formula ##STR2## m represents the numbers, 0, 1, 2 or 3, or R.sup.2 represents the radical or the formula ##STR3## X represents nitrogen or a CH group and Y represents the groupings --CH.sub.2 --CH.sub.2 --, --CH.dbd.CH--, --C.tbd.C--, ##STR4## and their addition products with acids and metal salts. Intermediates of the formulas ##STR5## are also new.
    Type: Grant
    Filed: September 14, 1989
    Date of Patent: January 8, 1991
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Stroech, Monika Frie, Thomas Himmler, Wilhelm Brandes, Stefan Dutzmann, Gerd Hanssler
  • Patent number: 4981846
    Abstract: A novel crystalline L-carnosine zinc complex is produced by reacting L-carnosine, a zinc salt and an alkali metal compound in an anhydrous or hydrous polar organic solvent.The crystalline L-carnosine zinc complex substantially corresponds to the formula C.sub.9 H.sub.12 N.sub.4 O.sub.3 Zn and has physical properties clearly different from the known amorphous L-carnosine zinc complex.As compared with the amorphous complex, the crystalline complex is very low in impurity, stable to heat and moisture, and easy to filtrate, and has higher anti-ulcer activity.
    Type: Grant
    Filed: July 20, 1988
    Date of Patent: January 1, 1991
    Assignee: Hamari Chemicals, Ltd.
    Inventors: Takefumi Matsukura, Tamiko Takahashi, Yasuhiro Nishimura, Masahiro Takaya, Hajime Fujimura
  • Patent number: 4968712
    Abstract: Fungicidal 1,4-disubstituted 1-azolyl-3,3-dimethylbutane derivatives of the formula ##STR1## in which R.sup.1 represents hydrogen or halogen,R.sup.2 represents hydrogen or halogen,R.sup.3 represents hydrogen, halogen or trifluoromethoxy,R.sup.4 represents halogen, trifluoromethoxy, trifluoromethylthio, trifluoromethylsulphinyl, trifluoromethylsulphonyl, difluoromethoxy, difluorochloromethoxy, trifluorochloroethoxy, tetrafluoroethoxy, trifluoroethoxy, difluoromethylthio, trifluorochloroethylthio, tetrafuoroethylthio, difluoromethylsulphinyl, difluorochloromethylsulphinyl, trifluorochloroethylsulphinyl, tetrafluoroethylsulphinyl, difluoromethylsulphonyl, difluorochloromethylsulphonyl, trifluorochloroethylsulphonyl, tetrafluoroethylsulphonyl, difluorobromomethylthio, difluorobromomethylsulphinyl, difluorobromomethylsulphonyl or difluorochloromethylthio orR.sup.3 and R.sup.4 together represent alkylenedioxy substituted by halogen,R.sup.
    Type: Grant
    Filed: July 29, 1988
    Date of Patent: November 6, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Ludwig Elbe, Albrecht Marhold, Karl H. Buchel, Stefan Dutzmann, Paul Reinecke, Wilhelm Brandes, Gerhard Hanssler
  • Patent number: 4963470
    Abstract: Titanocenes with silylated .pi.-cyclopentadienyl ligands in which one or two carbo- or heterocyclic aromatic rings are bonded to the titanium, the aromatic rings being substituted by fluorine, --CF.sub.3, --C.sub.2 F.sub.5, --CF.sub.2 CL or --CF.sub.2 CH.sub.3 in at least one of the two ortho-positions relative to the metal-carbon bonds, are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated substrates. They are distinguished by a high sensitivity, stability to air and the action of heat, and a high activity in the region of UV light to visible light. They are furthermore readily soluble in the photopolymerizable compositions.
    Type: Grant
    Filed: January 19, 1990
    Date of Patent: October 16, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Bernd Klingert, Franciszek Sitek, Manfred Rembold
  • Patent number: 4962118
    Abstract: Fungicidal trazoles of the formula ##STR1## in which Ar stands for optionally substituted aryl,A stands for the groups ##STR2## and X stands for the groups ##STR3## wherein R.sup.1 stands for hydrogen or alkyl,R.sup.2 stands for hydrogen or alkyl,R.sup.3 stands for hydrogen, alkyl, alkenyl, alkanoyl, for optionally substituted cycloalkyl or for in each case optionally substituted aralkyl or aroyl,R.sup.4 stands for hydrogen, alkyl, for optionally substituted cycloalkyl or for in each case optionally substituted aralkyl or aryl andR.sup.5 and R.sup.6 independently of one another stand for alkyl or for optionally substituted aralkyl or together stand for an optionally substituted doubly-linked alkylene radical,and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: February 15, 1989
    Date of Patent: October 9, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerd Kleefeld, Stefan Dutzmann
  • Patent number: 4960781
    Abstract: Fungicidal bisazolyl-hydroxyalkyl derivatives of the formula ##STR1## in which Ar stands for optionally substituted aryl,X stands for a grouping --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --SCH.sub.2 -- or --SH.dbd.CH--,Y stands for a nitrogen atom or the grouping CR.sup.3,R.sup.1, R.sup.2 and R.sup.3 stand for hydrogen, halogen or methyl, andn stands for the numbers 0, 1 or 2,and acid addition salts and metal salt complexes thereof. Intermediates of the formulas ##STR2## are also new.
    Type: Grant
    Filed: February 16, 1990
    Date of Patent: October 2, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Graham Holmwood, Wolfgang Kramer, Erik Regel, Hans L. Elbe, Karl H. Buchel, Stefan Dutzmann, Wilhelm Brandes, Paul Reinecke
  • Patent number: 4960456
    Abstract: Compounds which are substituted 1-hydroxyalkyl-azolyl derivatives of the general formula ##STR1## in which A represents a nitrogen atom or a CH group,B represents oxygen, sulphur or a CH.sub.2 group,R represents a substituted alkyl, and, in the case in which B represents sulphur, also represents an unsubstituted alkyl, optionally substituted cyclo-alkyl or optionally substituted phenyl group,Z represents a halogen atom or an alkyl, cycloalkyl, alkoxy, alkylthio, halogenoalkyl, halogenoalkoxy, halogenoalkylthio, optionally substituted phenyl, optionally substituted phenoxy, optionally substituted phenylalkyl or optionally substituted phenylalkoxy group, andm is 0, 1, 2 or 3,and the acid addition salts and metal salt complexes thereof, are new, are prepared as described and find use as fungicides and plant growth regulators.
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: October 2, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Graham Holmwood, Erik Regel, Gerhard Jager, Karl H. Buchel, Klaus Lurssen, Paul-Ernst Frohberger, Wilhelm Brandes, Volker Paul
  • Patent number: 4959135
    Abstract: Methods and apparatus for the extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising linear, pentadentate polyalkylamines and transition metal ions. The carrier compounds have the general formula: ##STR1## where, each of R.sub.1 and R.sub.2 is independently an organic group including a sulfur, an oxygen or a nitrogen coordinated to M;each of m, n, o, and p is 1, 2, 3, or 4;X is selected from the group consisting of 2,6-pyridyl, 2,6-piperidyl, 2,5-pyrrolyl, 2,4-imidazolyl, substituted heterocyclic amines, --)--, --S--, ##STR2## and ##STR3## where R.sub.3 is hydrogen, lower alkyl or aralkyl; and M is a transition metal ion.
    Type: Grant
    Filed: February 3, 1989
    Date of Patent: September 25, 1990
    Assignee: Aquanautics Corporation
    Inventors: Bruce D. Zenner, Joseph P. Ciccone, Emory S. De Castro, Larrie A. Deardurff, John B. Kerr
  • Patent number: 4956466
    Abstract: Thiazole derivatives of the general formula where: ##STR1## X is an anion of pharmaceutically acceptable acids; a is an integer from 1 to 5;b is an integer from 1 to 7;c is 0 or an integer from 1 to 4; andd is 2a-c for monovalent acid anions, is a-c for divalent acid anions, and is 0 or 2 when c=0.The process for the preparation of the above derivatives is based on reacting N-methyl-N'-2-((2-(dimethylaminomethyl)-4-thiazolyl) methylthio)ethyl)-2-nitro-1,1-ethylenediamine of formula II with an X anion containing zinc compound or an organozinc.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: September 11, 1990
    Assignee: Laboratorios Vinas, S. A.
    Inventor: Antonio B. Vinas
  • Patent number: 4954162
    Abstract: Fungicidal and plant-growth regulating azolymethyl-cyclopropyl carbinol derivatives of the formula ##STR1## in which R represents perfluroalkyl having 1 to 4 carbon atoms, trichloromethyl, difluorochloromethyl or fluorodichloromethyl,R.sup.1 represents hydrogen, alkl or acyl,Z represents halogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, alkylthio having 1 to 4 carbon atoms, halogenoakyl having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkoxy having 1 or 2 carbon atoms and 1 to 5 halogen atoms, halogenoalkythio having 1 to 2 carbon atoms and 1 to 5 halogen atoms, phenyl which is optionally substituted by alkyl having 1 to 2 carbon atoms and/or halogen, or phenoxy which is optionally substituted by alkyl having 1 or 2 carbon atoms and/or halogen,m represents the numbers 0, 1, 2 or 3 andn represents the numbers 0, 1 or 2 andX represents nitrogen or a CH group, and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: September 4, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Stroech, Dietmar Beilefeldt, Wilhelm Brandes, Stefan Dutzmann
  • Patent number: 4952289
    Abstract: Methods and apparatus for electrochemical extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising macrocyclic amines having the general formulas: ##STR1## where: A, B, C, D, E, and F are each nitrogen, oxygen, sulfur, or phosphorous;m, n, o, p, q, and r are each typically 2, 3, 4, 5, or 6;the R substituents are each generally H or short chain (linear or branched) alkyl, although R.sub.2 may represent ketyl (.dbd.o); andM is a suitable transition metal ion.
    Type: Grant
    Filed: May 9, 1988
    Date of Patent: August 28, 1990
    Assignee: Aquanautics Corporation
    Inventors: Joseph P. Ciccone, Emory S. DeCastro, John B. Kerr
  • Patent number: 4946493
    Abstract: Fungicidal or plant growth regulating triazoles or imidazoles of the formula ##STR1## wherein R.sup.1 is --CH.dbd.CH--X, --C.tbd.C--X or --CH.sub.2 --CH.sub.2 --X where X is H, alkyl, hydroxyalkyl, alkoxyalkyl, cycloalkyl or optionally substituted aryl, aralkyl, aryloxyalkyl, or heterocycle; and R.sup.2 is alkyl, cycloalkyl (e.g. cyclopropyl, cyclopentyl, or cyclohexyl) or optionally substituted aryl; Z is Cl, CN or OR.sup.3 where R.sup.3 is H, acetyl, alkenyl or aralkyl; Y is .dbd.N-- or .dbd.CH--; and acid addition salts and metal complexes thereof.
    Type: Grant
    Filed: January 27, 1987
    Date of Patent: August 7, 1990
    Assignee: Imperial Chemical Industries PLC
    Inventor: Balasubramanyan Sugavanam
  • Patent number: 4945101
    Abstract: Hydroxyalkinyl-azolyl derivatives of the formula ##STR1## in which A is a nitrogen atom or the CH group,R is optionally substituted alkyl, cycloalkyl or phenyl,R.sup.1 is hydrogen, alkyl, alkenyl, alkinyl, or optionally substituted benzyl,R.sup.2 is hydrogen or methyl, andX is hydrogen, bromine or iodine,or addition products thereof with acids or metal salts exhibit fungicidal activity. Some intermediates therefor are also new.
    Type: Grant
    Filed: October 4, 1985
    Date of Patent: July 31, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gerhard Jager, Klaus Bockmann, Karl H. Buchel, Wilhelm Brandes, Paul-Ernst Frohberger, Hans Scheinpflug
  • Patent number: 4940798
    Abstract: A substituted azolylvinyl ketone or carbinol of the formula ##STR1## in which R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms, substituted cyclohexyl or the grouping ##STR2## wherein R.sup.3 represents optionally substituted phenyl, alkenyl, alkinyl, cyano or the grouping --Z--R.sup.4,whereinR.sup.4 represents alkyl, halogenoalkyl, optionally substituted phenyl or optionally substituted phenylalkyl andZ represents O, S, SO or SO.sub.2,n represents a number from 0 to 2,R.sup.2 represents alkyl, alkenyl, alkinyl, in each case optionally substituted phenyl or phenylalkyl, or in each case optionally substituted cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, bicycloalkyl or bicycloalkenyl, but R.sup.2 does not represent optionally substituted phenyl at the same time as R.sup.1 represents optionally substituted cycloalkyl with 3 to 5 carbon atoms or substituted cyclohexyl or R.sup.
    Type: Grant
    Filed: September 24, 1987
    Date of Patent: July 10, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hans-Ludwig Elbe, Wolf Reiser, Erik Regel, Karl H. Buchel, Paul Reinecke, Wilhelm Brandes, Klaus Lurssen, Paul-Ernst Frohberger
  • Patent number: 4939162
    Abstract: Novel 1-(2-aryl-1,3-dioxan-2-ylmethyl)-1H-imidazoles and 1H-1,2,4-triazoles wherein the 1,3-dioxane ring is optionally substituted with 1 to 3 substituents.
    Type: Grant
    Filed: February 24, 1989
    Date of Patent: July 3, 1990
    Assignee: Janssen Pharmaceutica N.V.
    Inventors: Jan Heeres, Leo Backx, Adolf Hubele
  • Patent number: 4938791
    Abstract: Fungicidal and plant growth regulating hydroxyethylazolyl derivatives of the formula ##STR1## in which R represents hydrogen, alkyl or acyl,R.sup.1 represents halogen, optionaly substituted phenyl or the grouping --Z--R.sup.3, whereinZ represents oxygen, sulphur, SO or SO.sub.2 andR.sup.3 represents optionally substituted phenyl,R.sup.
    Type: Grant
    Filed: June 24, 1988
    Date of Patent: July 3, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Klaus Stroech, Klaus Bockmann, Stefan Dutzmann, Wilhelm Brandes, Klaus Lurssen, Paul Reinecke
  • Patent number: 4936907
    Abstract: Plant growth-regulating azolyl spiro compounds of the formula ##STR1## in which R stands for halogen, alkyl, alkoxy, alkylthio, optionally substituted phenyl, optionally substituted phenoxy, amino, alkylamino and/or dialkylamino,n stands for the numbers 0, 1, 2 or 3 andX stands for nitrogen or a CH group,and addition products thereof with acids and metal salts.
    Type: Grant
    Filed: October 26, 1988
    Date of Patent: June 26, 1990
    Assignee: Bayer Aktiengesellschaft
    Inventors: Manfred Jautelat, Hans-Ludwig Elbe, Klaus Lurssen
  • Patent number: 4935459
    Abstract: Flameproofed compositions of matter include an organic synthetic resin and, as a flame retardant therefor, an effective flameproofing amount of specified nitrogenous/halometallic compounds, certain of which are per se novel.
    Type: Grant
    Filed: August 24, 1989
    Date of Patent: June 19, 1990
    Assignee: Atochem
    Inventors: Daniel Sallet, Pierre Deloy, Valerie Mailhos-Lefievre, Pierre Poisson
  • Patent number: 4935436
    Abstract: Substituted triazole compounds, their preparation, compositions containing said compounds and the use of said compositions to control fungal infections in plants are disclosed.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: June 19, 1990
    Assignee: The Dow Chemical Company
    Inventors: Lowell D. Markley, Richard B. Rogers, Neil V. Kirby, John W. Liebeschuetz, Peter F. S. Street
  • Patent number: 4931082
    Abstract: This invention relates to heterocyclic compounds useful as plant growth regulating agents, to processes for preparing them, to compositions containing them and to methods of regulating plant growth using them.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: June 5, 1990
    Assignee: Imperial Chemical Industries PLC
    Inventor: Raymond Elliott