The Single Bonded Oxygen Is Bonded Directly To An Additional Carbon, Which Carbon May Be Single Bonded To Any Element But May Be Multiple Bonded Only To Carbon (i.e., Carboxylic Acid Esters) Patents (Class 44/388)
  • Publication number: 20120055078
    Abstract: A low-carbon high-hydrogen fuel: which comprises a combination of additives, base oil, diesel fuel.
    Type: Application
    Filed: September 8, 2010
    Publication date: March 8, 2012
    Inventor: Xiqi Ma
  • Publication number: 20120055079
    Abstract: A method of making biofuels and valuable food and neutraceutical products includes dewatering intact algal cells to make an algal biomass, extracting neutral lipids along with carotenoids and chlorophylls from the algal biomass, and separating the carotenoids and chlorophylls. The remaining neutral lipids are esterified with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising omega-3 fatty acids esters and remaining carotenoids. The method further includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.
    Type: Application
    Filed: October 14, 2011
    Publication date: March 8, 2012
    Inventor: Aniket KALE
  • Publication number: 20120055080
    Abstract: Compositions containing phenolic antioxidant solutions are provided. The invention further provides methods of making and using such compositions as well as compositions that contain both biodiesel and at least one antioxidant concentrate solutions and blended fuel compositions containing biodiesel blended with other fuels.
    Type: Application
    Filed: November 10, 2011
    Publication date: March 8, 2012
    Applicant: Eastman Chemical Company
    Inventors: Thomas Edward Carter, Joy Lynn Laningham, Phillip Montgomery Hudnall, Sharon Metcalf Cline
  • Publication number: 20120047795
    Abstract: A process useful for treating biologically derived oils in the production of biofuels is described. A biologically derived oil feed is deoxygenated by contacting the feed with a metal titanate catalyst. The process does not require the addition of hydrogen.
    Type: Application
    Filed: August 31, 2010
    Publication date: March 1, 2012
    Inventors: Zhen Zhou, Shabbir Husain, Lin Li
  • Patent number: 8123822
    Abstract: The present invention relates to a process and apparatus for the production of carboxylic acid esters and/or biodiesel fuel from feedstocks containing fatty acids, glycerated fatty acids, and glycerin by reactive distillation. Specifically, in one embodiment, the present invention relates to the production of biodiesel fuels having low glycerin, water, and sulfur content on an industrial scale.
    Type: Grant
    Filed: March 13, 2008
    Date of Patent: February 28, 2012
    Assignee: Endicott Biofuels II, LLC
    Inventor: William Douglas Morgan
  • Publication number: 20120036767
    Abstract: The presently described invention relates to systems for continuously culturing, harvesting, and oil extraction of algal cultures for the production of algae oils.
    Type: Application
    Filed: August 4, 2009
    Publication date: February 16, 2012
    Inventor: Mario C. Larach
  • Publication number: 20120023812
    Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an FT synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.
    Type: Application
    Filed: October 10, 2011
    Publication date: February 2, 2012
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventor: Hideaki SUGANO
  • Publication number: 20120028339
    Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids from the algal biomass, and esterifying the neutral lipids with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method further includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.
    Type: Application
    Filed: October 7, 2011
    Publication date: February 2, 2012
    Applicant: Heliae Development, LLC
    Inventor: Aniket Kale
  • Patent number: 8105399
    Abstract: The present invention relates to a process and apparatus for the production of diesel fuel from feedstocks containing fatty acids, glycerated fatty acids, and glycerin by catalytic and/or non-catalytic pyrolysis followed by esterification. Specifically, the present invention relates to the production of Renewable Diesel having low glycerin, water, and sulfur content.
    Type: Grant
    Filed: July 14, 2008
    Date of Patent: January 31, 2012
    Assignee: Endicott Biofuels II, LLC
    Inventor: William Douglas Morgan
  • Publication number: 20120017493
    Abstract: Methods for producing low oxygen biomass-derived pyrolysis oil are provided. Starting biomass-derived pyrolysis oil is deoxygenated by exposing the biomass-derived oil to a first catalyst in the presence of hydrogen-containing gas at first hydroprocessing conditions to produce a partially deoxygenated biomass-derived pyrolysis oil. The first catalyst has a neutral catalyst support. The partially deoxygenated biomass-derived pyrolysis oil is exposed to a second catalyst in the presence of additional hydrogen-containing gas at second hydroprocessing conditions to produce a hydrocarbon product. The biomass-derived pyrolysis oil may be esterified prior to deoxygenation. A portion of the low oxygen biomass-derived pyrolysis oil is recycled.
    Type: Application
    Filed: July 26, 2010
    Publication date: January 26, 2012
    Applicant: UOP LLC
    Inventors: Thomas Traynor, Timothy A. Brandvold
  • Publication number: 20120017494
    Abstract: Processes for producing a low acid biomass-derived pyrolysis oil are provided that include pre-treating a biomass-derived pyrolysis oil to form a treated acid-containing biomass-derived pyrolysis oil. The processes also include esterifying the treated acid-containing biomass-derived pyrolysis oil in the presence of supercritical alcohol and a catalyst composition to form the low-acid biomass-derived pyrolysis oil, the catalyst composition comprising a material selected from the group consisting of an unsupported solid acid catalyst, an unsupported solid base catalyst, and a catalytic metal dispersed on a metal oxide support.
    Type: Application
    Filed: July 26, 2010
    Publication date: January 26, 2012
    Applicant: UOP LLC
    Inventors: Thomas Traynor, Timothy A. Brandvold
  • Publication number: 20120021118
    Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids from the algal biomass, and esterifying the neutral lipids with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method further includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.
    Type: Application
    Filed: September 30, 2011
    Publication date: January 26, 2012
    Inventor: Aniket Kale
  • Publication number: 20120021091
    Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids from the algal biomass, and esterifying the neutral lipids with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method further includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.
    Type: Application
    Filed: September 30, 2011
    Publication date: January 26, 2012
    Inventor: Aniket Kale
  • Publication number: 20120017495
    Abstract: Methods for deoxygenating treated biomass-derived pyrolysis oil are provided. The treated biomass-derived pyrolysis oil is exposed to a catalyst having a neutral catalyst support such as a non-alumina metal oxide support, a theta alumina support, or both. The non-alumina metal oxide support may be a titanium oxide (TiO2) support, a silicon oxide support, a zirconia oxide (ZrO2) support, a niobium oxide (Nb2O5) support, or a support having a mixture of non-alumina metal oxides. The catalyst may include a noble metal or a Group VIII non-noble metal and a Group VIB non-noble metal on the neutral catalyst support. The treated biomass-derived pyrolysis oil is introduced into a hydroprocessing reactor in the presence of the catalyst under hydroprocessing conditions to produce low oxygen biomass-derived pyrolysis oil.
    Type: Application
    Filed: July 26, 2010
    Publication date: January 26, 2012
    Applicant: UOP LLC
    Inventors: Thomas Traynor, Timothy A. Brandvold, Jennifer F. Abrahamian
  • Publication number: 20120011765
    Abstract: The invention relates to an aviation fuel containing between 1 and 100 wt.-% of a fraction of a compound obtained by means of chemical transformation from renewable, natural optionally-hydroxylated monounsaturated fatty acids having a chain length at least equal to 14 carbon atoms, selected from among nitriles and medium fatty acid esters containing between 7 and 12 carbon atoms per molecule and between 0 and 99 wt.-% of a kerosene originating from petrol that meets global aviation fuel specifications.
    Type: Application
    Filed: March 8, 2010
    Publication date: January 19, 2012
    Inventor: Jean-Luc Dubois
  • Publication number: 20120005951
    Abstract: A copolymer with high chemical homogeneity, consisting of (A) 50 to 30% by weight of ethylene, (B) 50 to 70% by weight of C4- to C24-hydrocarbyl ester of (meth)acrylic acid, (C) 0 to 5% by weight of (meth)acrylic acid and (D) 0 to 10% by weight of copolymerizable monomers, obtainable by polymerizing a mixture of 80 to 60% by weight of ethylene, 20 to 40% by weight of (meth)acrylic acid and 0 to 10% by weight of copolymerizable monomers in a backmixing, continuous polymerization apparatus, and subsequently polymer-analogously esterifying the resulting copolymer with C4- to C24-hydrocarbinols. The inventive copolymer is suitable for improving the cold flow properties of fuel oils, for lowering the lower mixing temperature of cold flow improver additives into fuel oils, and for improving the filterability of fuel oils comprising cold flow improver additives.
    Type: Application
    Filed: July 5, 2011
    Publication date: January 12, 2012
    Applicant: BASF SE
    Inventors: Frank-Olaf Mähling, Jan Strittmatter, Irene Trötsch-Schaller, Ivette Garcia Castro, Michael Schroers, Uwe Rebholz
  • Publication number: 20110314725
    Abstract: The present invention relates to methods of producing lipids. In particular, the present invention relates to methods of increasing the level of one or more non-polar lipids and/or the total non-polar lipid content in a transgenic organism or part thereof. In one particular embodiment, the present invention relates to the use of an acyltransferase, for example, a monoacylglycerol acyltransferase (MGAT) to increase the level of one or more non-polar lipids and/or the total non-polar lipid content in plants, plant seed and/or leaves, algae and fungi.
    Type: Application
    Filed: June 28, 2011
    Publication date: December 29, 2011
    Inventors: James Robertson Petrie, Thomas Vanhercke, Pushkar Shrestha, Oing Liu, Surinder Pal Singh
  • Publication number: 20110296744
    Abstract: A fuel blend consisting of a hydrocarbon-containing fuel component; and ethyl acetate is provided. The hydrocarbon-containing fuel component may be gasoline, diesel, bioethanol or biodiesel.
    Type: Application
    Filed: June 3, 2010
    Publication date: December 8, 2011
    Applicant: Lurgi PSI Inc.
    Inventor: Ray Jones
  • Publication number: 20110296745
    Abstract: The disclosure encompasses in-line reactive condensation processes via vapor phase esterification of bio-oil to decease reactive species concentration and water content in the oily phase of a two-phase oil, thereby increasing storage stability and heating value. Esterification of the bio-oil vapor occurs via the vapor phase contact and subsequent reaction of organic acids with ethanol during condensation results in the production of water and esters. The pyrolysis oil product can have an increased ester content and an increased stability when compared to a condensed pyrolysis oil product not treated with an atomized alcohol.
    Type: Application
    Filed: February 22, 2010
    Publication date: December 8, 2011
    Inventors: Roger Norris Hilten, Keshav Das, James R. Kastner, Brian P. Bibens
  • Publication number: 20110290997
    Abstract: A method for marking a petroleum hydrocarbon, biodiesel fuel or ethanol fuel by adding to the petroleum hydrocarbon, biodiesel fuel or ethanol fuel at least one compound having formula (I) wherein R1 and R2 independently represent at least one substituent selected from the group consisting of hydrogen, C1-C12 alkyl, C1-C12 alkoxy and nitro; and R3 and R4 independently represent hydrogen, methyl or ethyl.
    Type: Application
    Filed: May 23, 2011
    Publication date: December 1, 2011
    Inventors: George David Green, Raymond John Swedo
  • Publication number: 20110294173
    Abstract: The present invention provides a process for producing lipids for biofuel or lubricant and Streptomyces bacteria used in the process. The process comprises cultivating bacterial cells of the genus Streptomyces in a medium comprising organic waste(s) or residue(s) or mixtures thereof as carbon and/or nutrient source(s), recovering lipids from the cells of said bacteria or from the cultivation medium, and using the recovered lipids or a fraction thereof as biofuel and/or lubricant, or as a starting material for biofuel and/or lubricant production. In addition, in one aspect the invention provides products obtained by using the process according to this disclosure.
    Type: Application
    Filed: May 24, 2011
    Publication date: December 1, 2011
    Applicant: NESTE OIL OYJ
    Inventors: Maria Holmback, Miina Lehesto, Perttu Koskinen, Johan-Fredrik Selin
  • Publication number: 20110289831
    Abstract: A compound having formula (I) wherein G represents at least one substituent selected from the group consisting of C1-C12 alkyl and C1-C12 alkoxy.
    Type: Application
    Filed: May 23, 2011
    Publication date: December 1, 2011
    Inventors: George David Green, Raymond John Swedo
  • Publication number: 20110283605
    Abstract: Disclosed herein is the detoxified and transesterified Argemone oil, for used as bio-additive to petroleum diesel and process for preparation thereof.
    Type: Application
    Filed: May 18, 2011
    Publication date: November 24, 2011
    Inventor: Premananda DAS
  • Patent number: 8062389
    Abstract: Low vapor pressure compound-based fuels are provided. These fuels are useful in catalytic burner systems that can be used to disperse fragrances, insecticides, insect repellants (e.g., citronella), aromatherapy compounds, medicinal compounds, deodorizing compounds, disinfectant compositions, fungicides and herbicides.
    Type: Grant
    Filed: February 8, 2007
    Date of Patent: November 22, 2011
    Assignee: The Board of Regents of the University of Texas System
    Inventors: Thomas J. Pisklak, Kenneth J. Balkus, Jr.
  • Patent number: 8057558
    Abstract: The present invention is generally directed to novel biodiesel fuel compositions having enhanced low-temperature properties. The present invention is additionally directed to methods (i.e., processes) for making such enhanced biodiesel fuels by improving the low-temperature properties of ester-based biodiesel fuels via in situ enhancement and/or additive enhancement.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: November 15, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventors: Guangci Zhou, Curt Munson, Saleh Elomari, Stephen H. Roby
  • Publication number: 20110271585
    Abstract: A method is disclosed for obtaining an alkyl ester fuel, i.e., a biodiesel, and alcohol from a feedstock mixture of free fatty acids and/or glycerides mixed with a simple alcohol, such as methanol. The method uses an electrostatic probe to provide an electrical field within the reactor. This causes the glycerin molecules to precipitate out of the feedstock mixture. A drain is provided in the reactor, to drain the glycerin from the reactor. When the precipitated glycerin reaches a level to make contact with the electrostatic probe, an electrical circuit is closed, which causes the drain to open. When the level drops, the drain closes. Glycerin absorbs water and draining glycerin from the reactor naturally dehydrates the fuel.
    Type: Application
    Filed: February 1, 2010
    Publication date: November 10, 2011
    Inventor: David Miller
  • Publication number: 20110258916
    Abstract: The invention relates to a hydrocarbon composition which can be used as fuel and/or combustible, obtained by means of a process which comprises subjecting a gasoil component, a gasoline component and a component of biological origin to hydrotreatment.
    Type: Application
    Filed: October 16, 2009
    Publication date: October 27, 2011
    Applicant: ENI S.P.A.
    Inventors: Franco Baldiraghi, Silvia Guanziroli, Giovanni Faraci, Giacomo Rispoli
  • Publication number: 20110252696
    Abstract: Oleaginous yeast can be used to produce oil that can be extracted from oleaginous yeast biomass and converted into a wide variety of useful products, including fuels, hydrocarbon compositions, and/or oleochemicals.
    Type: Application
    Filed: April 14, 2011
    Publication date: October 20, 2011
    Applicant: Solazyme, Inc.
    Inventors: Scott Franklin, Stephen M. Decker, Janice Wee
  • Publication number: 20110252697
    Abstract: A process for producing biodiesel from fats, oils or split fatty acids containing steryl glycosides, wherein the fats, oils or split fatty acids are reacted with short-chain alkanols in the presence of a catalyst by transesterification or esterification to a fatty acid alkyl ester to obtain a first product stream, includes washing the first product stream with water in a washing device, so as to form a suspension layer on a phase boundary layer between a heavy phase rich in water and the first light phase rich in the fatty acid alkyl ester. The suspension layer is treated by introducing kinetic energy. A second product stream is withdrawn from the first light phase and intensively mixed with water to obtain a third product stream. A mechanical separation is performed on the third product stream to provide a fourth product stream and a fifth product stream. The fifth product stream is withdrawn as a heavy phase that is enriched in the steryl glycosides.
    Type: Application
    Filed: August 21, 2009
    Publication date: October 20, 2011
    Applicant: LURGI GMBH
    Inventors: Rudolf Boensch, Eckhard Seidel, Helmut Saft
  • Patent number: 8038742
    Abstract: The present invention provides a fuel for homogeneous charge compression ignition engines, which can achieve a stable homogeneous charge compression ignition at a higher output. The fuel satisfies the following requirements (1), (2), (3), and (4): (1) certain distillation characteristics between an initial boiling point (IBP): 0° C. or higher and 60° C. or lower; and an end point (EP): 250° C. or higher and 380° C. or lower; (2) research octane number: 62 or greater and 85 or less; (3) density at 15° C.: 0.700 g/cm3 or higher and lower than 0.800 g/cm3; and (4) Reid vapor pressure at 37.8° C.: 30 kPa or greater and lower than 65 kPa.
    Type: Grant
    Filed: March 12, 2009
    Date of Patent: October 18, 2011
    Assignee: Nippon Oil Corporation
    Inventor: Gen Shibata
  • Publication number: 20110239532
    Abstract: The invention relates to a hydrocarbon composition, which can be used as a fuel and/or fuel oil, containing a petroleum component (A) and a component of a biological origin (B), wherein the component of a biological origin is present in a quantity of up to 75% by volume with respect to the total composition.
    Type: Application
    Filed: March 5, 2008
    Publication date: October 6, 2011
    Applicants: ENI S.p.A., UOP LLC
    Inventors: Franco Baldiraghi, Silvia Guanziroli, Giovanni Faraci, Luigina Maria Flora Sabatino, Terry Louise Marker, John Anthony Petri
  • Patent number: 8029579
    Abstract: Provided herein are blends oils or fatty acids comprising more than 50% medium chain fatty acids, or the fatty acid alkyl esters thereof, and having low melting points. Such blends are useful as a fuel or as a starting material for the production of, for example, a biodiesel. Also provided genetically altered or modified plants, modified such that the amount of medium chain fatty acids generated by the plant are increased. Further provided is a method of predicting the melting point of a blend of fatty acid methyl esters and the use of such a method for identifying blends suitable for use as, for example, a biodiesel.
    Type: Grant
    Filed: June 27, 2007
    Date of Patent: October 4, 2011
    Assignee: COH Inc.
    Inventors: Mark Knuth, Peter R. Beetham, Keith A. Walker, Gregory Francis William Gocal
  • Publication number: 20110232168
    Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an Ft synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.
    Type: Application
    Filed: June 2, 2011
    Publication date: September 29, 2011
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventor: Hideaki SUGANO
  • Publication number: 20110232169
    Abstract: A fuel composition having an enhanced thermal stability in a diesel fuel application is provided comprising a base fuel containing: (a) 90 to 50% by volume based on the base fuel, of a petroleum refined diesel fuel having sulfur level of less than 500 ppm, and boiling point within the range of about 150 to about 400° C.; (b) 5 to 25% by volume based on the base fuel, a Fischer-Tropsch derived gas oil; and (c) 5 to 25% by volume based on the base fuel, a fatty acid alkyl ester having C18:2 to C18:1 ratio of 1.5 to 2.8 wherein the alkyl group has a carbon number from 1 to 4.
    Type: Application
    Filed: March 22, 2011
    Publication date: September 29, 2011
    Inventors: Ralph Anthony CHERRILLO, Mary Ann Dahlstrom, Edward Carl Nelson
  • Publication number: 20110225878
    Abstract: A process is disclosed for converting lipid-containing biomass to a liquid fuel and/or platform chemicals. The process comprises the steps of dissolving the lipid-containing biomass in an ionic liquid, whereby a lipid phase and a hydrophilic phase are formed. The lipid phase contains primarily triglycerides, which can be converted to biodiesel by transesterification to, e.g., methyl esters. The hydrophilic phase comprises dissolved biopolymers, such as cellulose, hemicellulose, and protein. The biopolymers are converted in situ to compounds that are insoluble in the ionic liquid. The ionic liquid is regenerated by removing insolubles, such as lignin, ash from the biomass, and water.
    Type: Application
    Filed: February 18, 2011
    Publication date: September 22, 2011
    Inventors: Jacob A. MOULIJN, Sjoerd DAAMEN, Paul O'CONNOR, Rob VAN DER MEIJ
  • Publication number: 20110225877
    Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an Ft synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.
    Type: Application
    Filed: June 2, 2011
    Publication date: September 22, 2011
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventor: Hideaki SUGANO
  • Publication number: 20110219675
    Abstract: The invention relates to a method of producing fatty acid ethyl esters comprising: a) reacting a substrate comprising triglycerides, diglycerides, monoglycerides, free fatty acids, or any combination thereof, with at least one immobilized lipolytenzyme, to provide a reaction mixture wherein the enzyme loading is below 30% w/w with respect to the substrate, and the molar ratio of ethanol to fatty acid (EtOH:FA) is at least 3.0 equivalents; b) separating the immobilized lipolytic enzyme from the resulting reaction mixture; and c) subjecting the immobilized lipolytic enzyme to at least one further reaction directly without modifications.
    Type: Application
    Filed: October 29, 2009
    Publication date: September 15, 2011
    Applicant: Novozymes A/S
    Inventors: Jesper Brask, Per Munk Nielsen, Yuan Xu
  • Publication number: 20110209389
    Abstract: This invention describes the use of doped nanomaterials for the conversion of non-edible oils into biodiesels with no undesirable products, higher yield and conversion at room temperature and standard atmospheric pressure.
    Type: Application
    Filed: March 1, 2010
    Publication date: September 1, 2011
    Inventors: Syed Tajammul Hussain, M. Bilal Khan
  • Publication number: 20110203167
    Abstract: A stabilized alkyl ester fuel is disclosed. The stabilized alkyl ester fuel comprises alkyl esters, an effective amount of an alkylalkanolamine, and an effective amount of an alkylhydroxylamine. The alkyl ester fuel is stabilized to oxidative degradation of the alkyl esters of unsaturated fatty acids found in alkyl ester fuels.
    Type: Application
    Filed: May 23, 2007
    Publication date: August 25, 2011
    Applicant: ARKEMA FRANCE
    Inventors: Michael D. Gernon, Nicholas M. Martyak, Conor M. Dowling
  • Patent number: 7998225
    Abstract: The invention provides methods of synthesizing and purifying methyl esters and specifically biodiesel fuels. The methods include acid-catalyzed transesterification of a triglyceride source followed by formation of an acidic emulsion that is subjected to an electric field to break the emulsion and recover the purified methyl esters. After recovery, the purified methyl esters may be used as a highly purified and stable biodiesel fuel without further treatment. The electric field may be efficiently applied to the acidic emulsion in an electrochemical reactor such as an electrocoagulation chamber.
    Type: Grant
    Filed: February 22, 2007
    Date of Patent: August 16, 2011
    Inventor: Scott W. Powell
  • Publication number: 20110192077
    Abstract: The present invention is directed to methods (processes) and systems for processing triglyceride-containing, biologically-derived oils to provide for base oils and transportation fuels, wherein partial oligomerization of fatty acids contained therein provide for an oligomerized mixture from which the base oils and transportation fuels can be extracted. Such methods and systems can involve an initial hydrotreating step or a direct isomerization of the oligomerized mixture.
    Type: Application
    Filed: April 20, 2011
    Publication date: August 11, 2011
    Applicant: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Publication number: 20110192076
    Abstract: The present invention describes a fuel oil composition comprising at least one biodiesel oil and at least one additive for improving the filterability.
    Type: Application
    Filed: February 5, 2010
    Publication date: August 11, 2011
    Applicant: EVONIK ROHMAX ADDITIVES GMBH
    Inventors: Brian HESS, Robert Cybert, Marie Malitsky, Frank-Olaf Maehling, Rene Koschabek, Ronny Sondjaja
  • Publication number: 20110195485
    Abstract: A method for producing biofuels is provided. A method of making biofuels includes dewatering substantially intact algal cells to make an algal biomass, extracting neutral lipids from the algal biomass, and esterifying the neutral lipids with a catalyst in the presence of an alcohol. The method also includes separating a water soluble fraction comprising glycerin from a water insoluble fraction comprising fuel esters and distilling the fuel esters under vacuum to obtain a C16 or shorter fuel esters fraction, a C16 or longer fuel ester fraction, and a residue comprising carotenoids and omega-3 fatty acids. The method further includes hydrogenating and deoxygenating at least one of (i) the C16 or shorter fuel esters to obtain a jet fuel blend stock and (ii) the C16 or longer fuel esters to obtain a diesel blend stock.
    Type: Application
    Filed: April 6, 2011
    Publication date: August 11, 2011
    Applicant: Heliae Development, LLC
    Inventor: Aniket KALE
  • Publication number: 20110179698
    Abstract: The present invention relates to a process for producing clean petroleum fuel by reducing sulfur content, and raising the Cetane Number to a value above 50, in a process that may be carried out at one atmospheric pressure.
    Type: Application
    Filed: January 2, 2011
    Publication date: July 28, 2011
    Inventor: Hassan Agha
  • Publication number: 20110179699
    Abstract: Process for the extraction of fatty acids from algal biomass comprising: producing an aqueous suspension of algal biomass; subjecting the aqueous suspension of algal biomass to acid hydrolysis and extraction by the addition of at least one non-polar organic solvent and at least one inorganic acid to said aqueous suspension of algal biomass, so as to obtain the following three phases: (i) a semisolid phase comprising a slurry of the algal biomass; (ii) an aqueous phase comprising inorganic compounds and hydrophilic organic compounds; (iii) an organic phase comprising fatty acids and hydrophobic organic compounds other than said fatty acids.
    Type: Application
    Filed: June 19, 2009
    Publication date: July 28, 2011
    Applicant: ENI S.P.A.
    Inventors: Ezio Nicola D'Addario, Federico Capuano, Edoardo D'Angeli, Roberto Medici
  • Patent number: 7976590
    Abstract: Embodiments of a composition useful as a fuel or fuel additive are provided. Certain disclosed embodiments of the composition comprise mid to low flash point naptha, at least one alcohol having a ratio of between about 1 to about 4 carbon atoms to 1 hydroxyl functional group, at least one lubricating oil, and at least one oxygenated natural aromatic compound, wherein the oxygenated natural aromatic compound has a flash point between about 60° C. and about 160° C., has at least one oxygenated functional group, and is soluble in the composition.
    Type: Grant
    Filed: November 8, 2007
    Date of Patent: July 12, 2011
    Assignee: Global Terralene Inc.
    Inventors: Hubert Boux, Anne Moya Flanagan
  • Patent number: 7972392
    Abstract: The invention relates to a fuel preparation for use in diesel engines consisting of plant oil mono-alcohol esters and up to 20 weight percent linear and branched paraffins and olefins of chain length C5-C11 and alcohols of chain length C2-C8, whereby the paraffins, olefins and alcohols are obtained by means of gasification of biomass and subsequent Fischer-Tropsch synthesis not involving any processing of the Fischer-Tropsch fraction by means of hydrogenating procedures and the preparation has a flash point >55° C. and a density >820 kg/m3.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: July 5, 2011
    Assignee: Choren Industries GmbH
    Inventors: Christian Eichhorn, Anton Althapp, Dietmar Rüger, Olaf Schulze
  • Publication number: 20110154728
    Abstract: A diesel fuel formulation with improved lubricity is provided containing (i) a fatty alcohol ester, (ii) an acid-based lubricity additive and (iii) an additional diesel fuel component. The ester (i) has the formula R1-C(O)—O—R2, in which R1 is for example either hydrogen or methyl and R2 is for example a C6 to C14 alkyl group.
    Type: Application
    Filed: December 17, 2010
    Publication date: June 30, 2011
    Inventors: Allison FELIX-MOORE, George Robert Lee, Richard John Price
  • Publication number: 20110154724
    Abstract: Compositions containing unsaturated fatty esters may be stabilized against atmospheric oxidation by the addition of an antioxidant package containing at least one nitroxide free-radical scavenger and at least one alkylalkanolamine. Compositions treated in this manner show good resistance to atmospheric oxidation and resultant viscosity increase. An advantage of the nitroxide free-radical scavenger is that it stops the oxidation of the unsaturated fatty esters already during the initiation stage. Moreover, it is much less volatile than for example the known alkylhydroxylamine oxygen scavengers. By the use of a nitroxide free-radical scavenger, the composition can thus be stabilized for a longer period of time. The stability period is moreover less affected by the supply of oxygen to the composition. The solubility problem of the nitroxide in the fatty ester component can be solved by dissolving the nitroxide first in the alkylalkanolamine.
    Type: Application
    Filed: August 28, 2009
    Publication date: June 30, 2011
    Applicant: TAMINCO
    Inventors: Nicholas M. Martyak, Daniel Alford, Conor M. Dowling, Michael D. Gernon
  • Publication number: 20110146136
    Abstract: The present invention is a polymer having structural units, units of formula I, units of formula II and units of either formula IIIa or formula IIIb: The polymer improves the low-temperature properties of fuel oils from petroleum sources and especially from vegetable or animal sources.
    Type: Application
    Filed: December 17, 2010
    Publication date: June 23, 2011
    Inventors: Carl Waterson, Christopher J. Booth