Publication number: 20240109835
Abstract: A method for preparing-3,3?-diaminobenzidine, the method comprising the following steps: subjecting 4,4?-biphenol and N,N-dimethylsulfamoyl chloride to an esterification reaction in a specified solvent at 40-70° C. to obtain 4,4?-biphenyl bis(N,N-dimethylaminosulfonate) as a first intermediate; subjecting the 4,4?-biphenyl bis(N,N-dimethylaminosulfonate) to a chlorination reaction with a chlorinating reagent under acidic conditions to obtain 3,3?-dichloro-4,4?-biphenyl bis(N,N-dimethylaminosulfonate) as a second intermediate; subjecting the second intermediate 3,3?-dichloro-4,4?-biphenyl bis(N,N-dimethylaminosulfonate) to an ammonolysis reaction with anammoniation reagent in the presence of a combined catalyst to obtain a crude product of 3,3?,4,4?-tetraaminobiphenyl, wherein the combined catalyst is a mixture of proline, a cuprous salt and a phase transfer catalyst; and subjecting the crude product of 3,3?,4,4?-tetraaminobiphenyl to a post-treatment to obtain a purified 3,3?,4,4?-tetraaminobiphenyl product.
Type:
Application
Filed:
January 12, 2022
Publication date:
April 4, 2024
Applicants:
HUBEI HUIDA HIGH-TECH CO., LTD., BORUN HIGH-TECH CO., LTD.
Inventors:
Yun LING, Yongfang LI, Kun WANG, Lizhu CHEN, Wei YIN, Jinying ZHANG