Flip-Chip Light Emitting Diode and Fabrication Method
A flip-chip light emitting diode (LED) includes: a substrate having a P-type pad electrode and an N-type pad electrode; a light-emitting epitaxial layer flip-chip mounted over the substrate, including, from top down, an n-type semiconductor layer, an active layer, and a p-type semiconductor layer. The n-type semiconductor layer is divided into a light-emitting region, an isolation region, and an electrode region. The light-emitting region and the electrode region are electrically isolated by the isolation region. The active layer and the p-type semiconductor layer are below the light-emitting region. The p-type semiconductor layer connects with the P-type pad electrode. The electrode region of the n-type semiconductor layer connects with the N-type pad electrode. A conductive connection portion on the n-type semiconductor layer connects the electrode region of the n-type semiconductor layer and the light-emitting region, realizing vertical current injection into the light-emitting epitaxial layer when an external power is connected.
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The present application is a continuation of, and claims priority to, PCT/CN2013/079843, filed Jul. 23, 2013, which claims priorities to Chinese Patent Application No. CN 201210314573.2, filed Aug. 30, 2012. The disclosures of the above applications are hereby incorporated by reference in their entirety.
BACKGROUNDAmong solid-state light emitting devices, light-emitting diodes (LEDs) have electrical and optical advantages such as low energy consumption, long service life, good stability, small size, fast response, and stable luminous wave length. LEDs and related light-emitting systems are widely used in fields such as illumination, household appliances, displays and signage. This type of light-emitting devices and systems have had remarkable progress in improved lighting efficiency and service life, and therefore are promising to become the mainstream for a new generation of lighting.
To improve light-emitting efficiency of the LED, a substrate transfer technology has been developed in recent years. The transfer processes may include: depositing a GaN-based thin film over a sapphire substrate via MOCVD, bonding the GaN-based thin film to the semiconductor or metal base using wafer bonding technology or electroplating technique, and removing the sapphire substrate using laser lift-off (LLO) method; and fabricating the device into a vertical structure.
To solve the above problems, the present disclosure provides a light emitting diode (LED) of which the light-emitting surface has no pad electrode and fabrication method. In comparison to traditional vertical LED, the N electrode is dropped-down to the support substrate, which is good for packing and wire bonding and for improving wire bonding stability. Since the pad electrode is not on the light-emitting surface, the light blocking problems of the N-type electrode in traditional structure can be solved.
In accordance with a first aspect of the present disclosure, a flip-chip LED, comprising a substrate, on which distributed a P-type pad electrode and an N-type pad electrode; a light-emitting epitaxial layer flip-chip mounted on the substrate, comprising top-down an n-type semiconductor layer, an active layer and a p-type semiconductor layer, in which, the n-type semiconductor layer is divided into a light-emitting region, an isolation region and an electrode region, wherein, the light-emitting region and the electrode region are electrically isolated via the isolation region; the active layer and the p-type semiconductor layer are below the light-emitting region; the p-type semiconductor layer connects with the P-type pad electrode; and the electrode region of the n-type semiconductor layer connects with the N-type pad electrode; and a conductive connection portion on the n-type semiconductor layer, which connects the electrode region of the n-type semiconductor layer and the light-emitting region, thereby realizing vertical current injection into the light-emitting epitaxial layer when the external power is connected.
Preferably, the isolation region forms around the electrode region to ensure complete electrical isolation between the electrode region and the light-emitting region.
Preferably, the isolation region of the n-type semiconductor layer forms an insulation portion via ion injection to realize electrical isolation between the light-emitting region and the electrode region.
Preferably, the n-type semiconductor layer in the electrode region connects with the N-type pad electrode on the substrate via a bonding metal layer.
Preferably, the p-type semiconductor layer corresponding to the bottom of the n-type semiconductor layer in the electrode region forms short circuit connection with the active layer, so as to connect the n-type semiconductor layer in the electrode region and the N-type pad electrode on the substrate.
Preferably, the conductive connection portion is a transparent conductive layer. Further, a current expansion structure can be formed on the transparent conductive layer to further control even distribution of current. Further, a low-refraction passivation layer can be fabricated on the transparent conductive layer to protect the transparent conductive layer and to eliminate total reflection of light emitting, which is good for light to escape from the device. Further, a light-extraction structure can be fabricated on the surface of the n-type semiconductor layer. The transparent conductive layer forms on the light-extraction structure, which can further improve luminous efficiency.
Preferably, an electrode expansion structure can be formed on the surface of the n-type semiconductor layer of the light-emitting region via ion injection to effectively promote even distribution of current.
In accordance with a second aspect of the present disclosure, a fabrication for a flip-chip LED, comprising: 1) providing a growth substrate, on which growing a light-emitting epitaxial layer via epitaxial growth, which comprises bottom-up an n-type semiconductor layer, an active layer and a p-type semiconductor layer; 2) dividing the n-type semiconductor layer into a light-emitting region, an isolation region and an electrode region. Insulate the n-type semiconductor layer in the isolation region via ion injection to realize electrical isolation between the light-emitting region and the electrode region; 3) fabricating an N-type bonding metal layer on the n-type semiconductor layer in the electrode region and a P-type bonding metal layer on the p-type semiconductor layer; 4) providing a substrate, on which, fabricating a P-type pad electrode and an N-type pad electrode; 5) bonding the light-emitting epitaxial layer over the substrate, wherein, the N-type bonding metal layer connects with the N-type pad electrode and the P-type bonding metal layer connects with the P-type pad electrode; 6) removing the growth substrate and exposing the surface of the n-type semiconductor layer; 7) fabricating a conductive connection portion on the surface of the n-type semiconductor layer, which connects the electrode region of the n-type semiconductor layer and the light-emitting region, thereby realizing vertical current injection into the light-emitting epitaxial layer when the external power is connected.
In this fabrication method, the N-type bonding metal layer in Step 3) is of same height with the P-type bonding metal layer. When removing the growth substrate, take surface acid pickling, fabrication of current expansion structure, roughening, dry etching and other operations for the n-type semiconductor layer over the n-type surface.
In comparison to traditional vertical structure chip, embodiments disclosed herein may have one or more advantages such as that the light-emitting surface has no pad electrode and the uniplanar P electrode and the N electrode are on the insulating substrate, which effectively improves packing, die bonding and wire bonding yield; in addition, by fabricating the current blocking layer, roughening the n-type epitaxial surface and adding the passivation layer over the light-emitting surface, the external quantum efficiency of the grain can be further improved.
In the drawings:
100: conductive substrate; 110: high-reflection P-type conductive bonding layer; 121: p-type semiconductor layer; 122: active layer; 123: n-type semiconductor layer, 131: N electrode; 132: back electrode; 200: growth substrate; 211: p-type semiconductor layer; 212: active layer; 213: n-type semiconductor layer; 213a: electrode region; 213b: isolation region; 213c: light-emitting region; 221: P-type bonding metal layer; 222: N-type bonding metal layer; 230: insulation and transmitting material; 240: substrate; 241: 242: metal bonding layer; 250: transparent conductive layer; 260: current expansion structure; 271: P-type pad electrode; 272: N-type pad electrode; 280: passivation layer.
DETAILED DESCRIPTIONThe following embodiments disclose a light emitting diode (LED) of which the light-emitting surface has no pad electrode and fabrication method, in which, the n-type semiconductor layer is divided into a light-emitting region, an isolation region and an electrode region, wherein, the light-emitting region and the electrode region are electrically isolated via the isolation region. In some preferable embodiments, part of the n-type semiconductor layer can be insulated via ion injection to isolate the electrode region from the light-emitting region. The light-emitting surface of the light-emitting element can be exposed via die bonding, LLO, etc. A transparent conductive layer can be adopted to connect two ends of the insulating isolation region of ion injection to enable the current to flow into the active regions according to the set structure, thus forming a light emitting diode (LED) of which the light-emitting surface has no pad electrode.
Detailed description will be given to the present invention in combination with the embodiments.
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The permanent substrate 240 is an insulating substrate, on which distributed metal bonding layer patterns 241, 242, a P-type pad electrode 271 and an N-type pad electrode 273, wherein, the metal bonding layer 241 connects with the P-type pad electrode 271 and the metal bonding layer 242 connects with the N-type pad electrode 272. In general, an insulating isolation layer can be filled in the metal bonding layer patterns, the height of which is same with the metal bonding layer.
The n-type semiconductor layer 213 is divided into an electrode region 213a, an isolation region 213b and a light-emitting region 213c, wherein, the isolation region 213b locates around the electrode region 213a to guarantee complete electrical isolation between the electrode region 213a and the light-emitting region 213c. The p-type semiconductor layer 211 and the active layer 212 are below the n-type semiconductor layer 213c of the light-emitting region. The p-type semiconductor layer 211 is bonded with the substrate 240 via the high-reflection P-type bonding metal layer 221 and the metal bonding layer 241. The n-type semiconductor layer 213a in the electrode region is bonded with the substrate 240 via the N-type bonding metal layer 222 and the metal bonding layer 242. An insulation and transmitting material 230 can be filled around the N-type bonding metal layer 222 to assist the bonding metal in supporting the entire epitaxial layer and guaranteeing electrical isolation between the N-type bonding metal layer 222 and the p-type semiconductor layer 211 as well as between the active layer 212 and the P-type bonding metal layer 221.
The transparent conductive layer 250, made up of transparent conducting material (e.g., ITO), forms over the n-type semiconductor layer 213 and connects with the electrode region 213a and the light-emitting region 213c, realizing electrical connection between the n-type semiconductor layer in the main light-emitting region and the n-type semiconductor layer in the electrode region, thereby guaranteeing vertical current injection into the light-emitting epitaxial layer.
Detailed descriptions will be given to the fabrication method for the flip-chip LED as shown in
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Provide a permanent insulating substrate 240, on which grow an insulating layer 243 via PECVD, which may be SiO2, SiNx, SiOxNy or any of their combinations. The thickness is not less than 0.5 um and the preferable thickness is 1 um; Pattern the insulating material via photomask patterning and etch the insulating material via chemical wet etching. Evaporate bonding metal layers 241, 242 as thick as the insulating layer 130 via EBE evaporation coating. The metal layer may comprise Cr, Ag, Ni, Al, Pt, Au, Ti or any of their combinations. Wherein, the bonding metal layer 241 is isolated from the bonding metal layer 242 via the insulating layer 130, forming electrical isolation; fabricate a P-type pad electrode 271 over the bonding metal layer 241 and an N-type pad electrode 272 over the bonding metal layer 242.
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In the LED device of this embodiment, vertical injection of current into the light-emitting epitaxial layer effectively eliminates the current blocking problem in horizontal structure LED device. Further, the light-emitting surface has no pad electrode, which eliminates the electrode light absorption; in addition, the uniplanar P electrode and the N electrode are on the insulating substrate, which effectively improves packing, die bonding and wire bonding yield.
Although specific embodiments have been described above in detail, the description is merely for purposes of illustration. It should be appreciated, therefore, that many aspects described above are not intended as required or essential elements unless explicitly stated otherwise. Various modifications of, and equivalent acts corresponding to, the disclosed aspects of the exemplary embodiments, in addition to those described above, can be made by a person of ordinary skill in the art, having the benefit of the present disclosure, without departing from the spirit and scope of the disclosure defined in the following claims, the scope of which is to be accorded the broadest interpretation so as to encompass such modifications and equivalent structures.
Claims
1. A flip-chip light emitting diode (LED), comprising:
- a substrate having a P-type pad electrode and an N-type pad electrode disposed thereon;
- a light-emitting epitaxial layer flip-chip mounted over the substrate, including an n-type semiconductor layer, an active layer, and a p-type semiconductor layer, wherein the n-type semiconductor layer has a light-emitting region, an isolation region, and an electrode region, wherein the light-emitting region and the electrode region are electrically isolated by the isolation region; wherein the active layer and the p-type semiconductor layer are below the light-emitting region; wherein the p-type semiconductor layer is coupled with the P-type pad electrode; and the electrode region of the n-type semiconductor layer is coupled with the N-type pad electrode; and
- a conductive connection portion disposed over the n-type semiconductor layer and coupled with the electrode region of the n-type semiconductor layer and the light-emitting region, thereby realizing vertical current injection into the light-emitting epitaxial layer upon application of an external power.
2. The LED of claim 1, wherein: in the n-type semiconductor layer, the isolation region is formed around the electrode region to ensure complete electrical isolation between the electrode region and the light-emitting region.
3. The LED of claim 1, further comprising a current expansion structure distributed at the n-type semiconductor layer in the light-emitting region.
4. The LED of claim 1, wherein the conductive connection portion is a transparent conductive layer.
5. The LED of claim 4, further comprising a current expansion structure distributed in the transparent conductive layer.
6. The LED of claim 4, further comprising a passivation layer over the transparent conductive layer.
7. The LED of claim 1, wherein: the isolation region of the n-type semiconductor layer is formed by an insulation portion via ion injection to realize electrical isolation between the light-emitting region and the electrode region.
8. The LED of claim 1, wherein the n-type semiconductor layer in the electrode region is coupled with the N-type pad electrode on the substrate via a bonding metal layer.
9. The LED of claim 1, wherein the p-type semiconductor layer corresponding to and below the n-type semiconductor layer in the electrode region forms a short circuit connection with the active layer, so as to connect the n-type semiconductor layer in the electrode region and the N-type pad electrode on the substrate.
10. The LED of claim 1, wherein the n-type semiconductor layer in the light-emitting region and the n-type semiconductor layer in the electrode region are epitaxial layers of a same material.
11. A fabrication method for a flip-chip light emitting diode (LED), comprising:
- providing a growth substrate, over which growing a light-emitting epitaxial layer via epitaxial growth, which comprises an n-type semiconductor layer, an active layer, and a p-type semiconductor layer;
- dividing the n-type semiconductor layer into a light-emitting region, an isolation region, and an electrode region; forming an insulation portion in the n-type semiconductor layer as the isolation region via ion injection to realize electrical isolation between the light-emitting region and the electrode region;
- fabricating an N-type bonding metal layer over the n-type semiconductor layer in the electrode region and a P-type bonding metal layer over the p-type semiconductor layer;
- providing a substrate, over which fabricating a P-type pad electrode and an N-type pad electrode;
- bonding the light-emitting epitaxial layer over the substrate, wherein the N-type bonding metal layer is coupled with the N-type pad electrode, and the P-type bonding metal layer is coupled with the P-type pad electrode;
- removing the growth substrate, and exposing a surface of the n-type semiconductor layer; and
- fabricating a conductive connection portion over the surface of the n-type semiconductor layer, which connects the electrode region of the n-type semiconductor layer and the light-emitting region, thereby realizing vertical current injection into the light-emitting epitaxial layer upon application of an external power.
12. A light emitting system comprising a plurality of flip-chip light emitting diodes (LEDs), each LED including:
- a substrate having a P-type pad electrode and an N-type pad electrode disposed thereon;
- a light-emitting epitaxial layer flip-chip mounted over the substrate, including an n-type semiconductor layer, an active layer, and a p-type semiconductor layer, wherein the n-type semiconductor layer has a light-emitting region, an isolation region, and an electrode region, wherein the light-emitting region and the electrode region are electrically isolated by the isolation region; wherein the active layer and the p-type semiconductor layer are below the light-emitting region; wherein the p-type semiconductor layer is coupled with the P-type pad electrode; and the electrode region of the n-type semiconductor layer is coupled with the N-type pad electrode; and
- a conductive connection portion disposed over the n-type semiconductor layer and coupled with the electrode region of the n-type semiconductor layer and the light-emitting region, thereby realizing vertical current injection into the light-emitting epitaxial layer upon application of an external power.
13. The system of claim 12, wherein: in the n-type semiconductor layer, the isolation region is formed around the electrode region to ensure complete electrical isolation between the electrode region and the light-emitting region.
14. The system of claim 12, each LED further comprising a current expansion structure distributed at the n-type semiconductor layer in the light-emitting region.
15. The system of claim 12, wherein the conductive connection portion is a transparent conductive layer.
16. The system of claim 15, each LED further comprising a current expansion structure distributed in the transparent conductive layer.
17. The system of claim 15, further comprising a passivation layer over the transparent conductive layer.
18. The system of claim 12, wherein: the isolation region of the n-type semiconductor layer is formed by an insulation portion via ion injection to realize electrical isolation between the light-emitting region and the electrode region.
19. The system of claim 12, wherein the n-type semiconductor layer in the electrode region is coupled with the N-type pad electrode on the substrate via a bonding metal layer.
20. The system of claim 12, wherein the p-type semiconductor layer corresponding to and below the n-type semiconductor layer in the electrode region forms a short circuit connection with the active layer, so as to connect the n-type semiconductor layer in the electrode region and the N-type pad electrode on the substrate, and wherein the n-type semiconductor layer in the light-emitting region and the n-type semiconductor layer in the electrode region are epitaxial layers of a same material.
Type: Application
Filed: Dec 25, 2014
Publication Date: Apr 30, 2015
Patent Grant number: 9190569
Applicant: XIAMEN SANAN OPTOELECTRONICS TECHNOLOGY CO., LTD. (Xiamen)
Inventors: XIAOQIANG ZENG (Xiamen), SHUNPING CHEN (Xiamen), QUNFENG PAN (Xiamen), SHAOHUA HUANG (Xiamen)
Application Number: 14/583,185
International Classification: H01L 33/20 (20060101); H01L 27/15 (20060101); H01L 33/00 (20060101); H01L 33/36 (20060101);