Forming Nonelectrolytic Coating After Depositing Predominantly Single Metal Or Alloy Electrolytic Coating Patents (Class 205/191)
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Publication number: 20090173633Abstract: A process for forming a multilayer composite coating on a substrate is provided. The process includes forming an electrodeposition coating layer on the substrate by electrodeposition of a curable electrodepositable coating composition over at least a portion of the substrate. Optionally, the coated substrate is heated to a temperature and for a time sufficient to cure the electrodeposition coating layer. A basecoating layer is formed on the electrodeposition coating layer by depositing an aqueous curable basecoating composition directly onto at least a portion of the electrodeposition coating layer. Optionally, the basecoating layer is dehydrated. A top coating layer is formed on the basecoating layer by depositing a curable top coating composition which is substantially pigment-free directly onto at least a portion of the basecoating layer. The top coating layer, the basecoating layer, and, optionally, the electrodeposition coating layer are cured simultaneously.Type: ApplicationFiled: February 27, 2009Publication date: July 9, 2009Applicant: PPG Industries Ohio, Inc.Inventors: Sean Purdy, Dennis A. Simpson, Richard J. Foukes, David M. Aiken, James P. Rowley, Leigh Ann Humbert
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Patent number: 7543375Abstract: A process for producing an electronic component The electronic component includes a base material equipped with a core material and having a conductor layer on at least one surface thereof; a via hole formed through laser irradiation from the other surface side of the base material; a first plating layer formed by using the conductor layer as an electrode so as to cover the core material, which is exposed on an inner wall surface of the via hole; an electroless plating layer which is formed on the upper side of the first plating layer and which is in close contact with the inner wall surface of the via hole; and a second plating layer formed by using the conductor layer as an electrode so as to cover the electroless plating layer. A conductor part is formed in the via hole.Type: GrantFiled: March 18, 2004Date of Patent: June 9, 2009Assignee: TDK CorporationInventors: Masashi Gotoh, Kaoru Kawasaki, Hiroshi Yamamoto, Mutsuko Nakano
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Patent number: 7540950Abstract: An electrically conductive body, which in particular includes a metal and/or an alloy and/or a semiconductor, includes an adhesion promoter layer provided on at least one surface of the electrically conductive body. The adhesion promoter layer includes a metal, in particular zinc, and a porous, in particular platelike and/or needle-shaped and/or sponge-like, surface structure.Type: GrantFiled: December 30, 2005Date of Patent: June 2, 2009Assignee: Infineon Technologies, AGInventors: Edmund Riedl, Wolfgang Schober
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Publication number: 20090133745Abstract: The invention relates to a photovoltaic cell comprising a photovoltaically active semiconductor material, wherein the photovoltaically active semiconductor material is a p- or n-doped semiconductor material comprising a binary compound of the formula (I) or a ternary compound of the formula (II): ZnTe??(I) Zn1-xMnxTe??(II) where x is from 0.01 to 0.99, and a particular proportion of tellurium ions in the photovoltaically active semiconductor material has been replaced by halogen ions and nitrogen ions and the halogen ions are selected from the group consisting of fluoride, chloride and bromide and mixtures thereof.Type: ApplicationFiled: October 26, 2005Publication date: May 28, 2009Applicant: BASF AktiengesellschaftInventor: Hans-Josef Sterzel
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Patent number: 7504009Abstract: The invention relates to a method for achieving a good contact surface on an aluminium electrode support bar used in electrolysis. In the method the support bar is fabricated as a continuous bar and a highly electroconductive layer is formed on its end. The highly electroconductive layer forms a metallic bond with the support bar and can be achieved for example with thermal spray coating. The invention also relates to an electrode support bar, the end of which is coated with a highly electroconductive material.Type: GrantFiled: November 6, 2003Date of Patent: March 17, 2009Assignee: Outotec OyjInventors: Karri Osara, Veikko Polvi
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Patent number: 7473343Abstract: Provided are a method of manufacturing a rare-earth magnet with superior corrosion resistance, and a plating bath used for the method. A first protective film including nickel and a second protective film including nickel and sulfur are laminated in order on a magnet body including a rare-earth element. The first protective film is formed through electroplating with a first plating bath including a nickel source, a conductive salt and a pH stabilizer, and having a concentration of the nickel source of 0.3 mol/l to 0.7 mol/l on a nickel atom basis and a conductivity of 80 mS/cm or over. Thereby, a rare-earth-rich phase can be prevented from being leached out, and the production of pinholes can be reduced. Therefore, the corrosion resistance of the rare-earth magnet can be improved.Type: GrantFiled: March 1, 2004Date of Patent: January 6, 2009Assignee: TDK CorporationInventors: Takeshi Sakamoto, Yasuyuki Nakayama, Tatsuhiro Iwai, Tomomi Yamamoto
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Publication number: 20080251389Abstract: A method for making a metal laminate comprising at least one plating step and at least one cold roll bonding step. A metal laminate comprising a plurality of alternating structural layers and non-structural layers, where the structural layers contribute significantly to the overall strength of the metal laminate, while the non-structural layers do not contribute significantly to the overall strength of the metal laminate, but serve to bind the structural layers together.Type: ApplicationFiled: August 8, 2006Publication date: October 16, 2008Inventor: William Russell Kingston
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Patent number: 7425257Abstract: The disclosure relates to a method of obtaining a good current contact on the support bar of a cathode used in electrolysis. In this method a highly electroconductive layer is formed on the contact piece on the end of the support bar of the cathode, especially at the point that comes into contact with the electrolysis cell busbar. The electroconductive layer forms a metallic bond with the contact piece of the support bar. The disclosure also relates to the cathode support bar, wherein a highly electroconductive layer is formed to the contact piece on the end of said bar, in particular the area that touches the electrolysis cell busbar.Type: GrantFiled: November 6, 2003Date of Patent: September 16, 2008Assignee: Outotec OyjInventors: Karri Osara, Veikko Polvi
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Patent number: 7273538Abstract: A surface mountable laminated circuit protection device comprises a first metal layer including a first unit and a second unit, a first insulating layer disposed on the first metal layer, and a second metal layer disposed on the first insulated layer. There is also a composite electroplated layer containing carbon black disposed on the second metal layer, and a first conductive composite material having positive temperature coefficient (PTC) characteristics disposed on the composite electroplated layer containing carbon black. Above the first conductive composite material is a third metal layer. Furthermore, there is a first conducting mechanism for conducting the first metal layer and the second metal to each other; and a second conducting mechanism for conducting the third metal layer and the first metal layer to each other. The application of double-sided metal foil clad substrate simplifies the production process of the protection device and improves its structural strength and dimensional stability.Type: GrantFiled: September 25, 2003Date of Patent: September 25, 2007Assignee: Protectronics Technology CorporationInventors: Rei-Yian Chen, Chih-Yi Chang, Tung-Hsiang Liu
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Publication number: 20070138019Abstract: A turbine engine component has a substrate formed from a nickel based superalloy and a platinum modified NiCoCrAlY bondcoat applied to a surface of the substrate. Two methods for forming the platinum modified NiCoCrAlY bondcoat are described herein.Type: ApplicationFiled: December 21, 2005Publication date: June 21, 2007Inventor: Asumini Kasule
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Patent number: 7223323Abstract: Embodiments of the invention generally provide an electrochemical plating system. The plating system includes a substrate loading station positioned in communication with a mainframe processing platform, at least one substrate plating cell positioned on the mainframe, at least one substrate bevel cleaning cell positioned on the mainframe, and a stacked substrate annealing station positioned in communication with at least one of the mainframe and the loading station, each chamber in the stacked substrate annealing station having a heating plate, a cooling plate, and a substrate transfer robot therein.Type: GrantFiled: July 8, 2003Date of Patent: May 29, 2007Assignee: Applied Materials, Inc.Inventors: Michael X. Yang, Ming Xi, Russell C. Ellwanger, Eric B. Britcher, Bernardo Donoso, Lily L. Pang, Svetlana Sherman, Henry Ho, Anh N. Nguyen, Alexander N. Lerner, Allen L. D'Ambra, Arulkumar Shanmugasundram, Tetsuya Ishikawa, Yevgeniy Rabinovich, Dmitry Lubomirsky, Yeuk-Fai Edwin Mok, Son T. Nguyen
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Patent number: 7208074Abstract: A substrate processing apparatus fills a metal such as copper or the like in fine interconnection patterns or trenches defined in a semiconductor substrate. The substrate processing apparatus has a loading/unloading unit for placing a substrate cassette to allow a substrate to be loaded and unloaded, a substrate treating unit for treating a substrate, and a transfer robot for transferring a substrate between the loading/unloading unit and the substrate treating unit. The loading/unloading unit, the substrate treating unit, and the transfer robot are installed in a single facility. The loading/unloading unit has a rotary table which is horizontally rotatable for positioning the substrate cassette in a position to detect the substrate cassette placed in the loading/unloading unit and to remove the substrate from the substrate cassette with the transfer robot.Type: GrantFiled: December 22, 2003Date of Patent: April 24, 2007Assignee: Ebara CorporationInventors: Koji Mishima, Junji Kunisawa, Natsuki Makino, Norio Kimura, Hiroaki Inoue, Kenji Nakamura, Moriji Matsumoto, Takahiro Nanjo, Mitsuko Odagaki
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Patent number: 7204925Abstract: A structure and a method of preventing electrolytic corrosion for a magnesium alloy member (20), the structure wherein a first coated layer (11) formed by electro deposition and a second coated layer (12) formed by distributing PTFE particles on the first coated layer (11) are covered on the surface of a tightening member (1) at least on a surface coming into contact with the magnesium alloy member (20), whereby, the electrolytic corrosion of the magnesium alloy member can be prevented at a low cost by insulating a tightening member such as a steel bolt and a washer from the magnesium alloy member, and an adhesiveness therebetween can be sufficiently assured.Type: GrantFiled: August 20, 2002Date of Patent: April 17, 2007Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Sadaharu Matsumura, Tsuyoshi Kawabe, Tetsuya Saito, Katsumi Sakamoto, Ryosuke Kamegamori
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Patent number: 7153590Abstract: A composite copper foil (10) comprises a carrier foil (12) formed by electrodeposition onto a cathode, the carrier foil (12) having a cathode side formed in contact with the cathode and an opposite electrolyte side. A very thin release layer (14) is on the electrolyte side of said carrier foil (12). A thin functional foil (16) formed by deposition of copper has a front side in contact with the release layer (14) and an opposite back side. The electrolyte side of the carrier foil (12) has a surface roughness Rz less than or equal to 3.5 ?m. There is also presented a method for manufacturing such a composite copper foil.Type: GrantFiled: January 18, 2001Date of Patent: December 26, 2006Assignee: Circuit Foil Luxembourg Trading S.a.R.L.Inventors: Raymond Gales, René Lanners, Michel Streel, Akitoshi Suzuki
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Patent number: 7069641Abstract: The present invention discloses a method for preparing a conductive polymeric composite material having carbon black utilized to a structure for composite materials of a positive temperature coefficient thermistor. The method first provides a metal laminated material comprising a top metal layer and a bottom metal layer, an insulating layer between the top and the bottom metal layer, and a conducting through hole disposed between the top metal layer and the bottom metal layer. A composite electroplating process is then performed to form an composite electroplating layer on the surface of the top metal layer, wherein the composite electroplating layer is a continuous porous structure with a secondary aggregation of carbon black and electroplated metal.Type: GrantFiled: April 25, 2003Date of Patent: July 4, 2006Assignee: Protectronics Technology CorporationInventors: Ren-Haur Hwang, Der-Yang Liu, Chen-Ron Lin
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Patent number: 7011737Abstract: An electrical resistive device, including: an array of titania nanotubes open at an outwardly-directed end formed by anodizing at least a portion of a titanium layer; a plurality of palladium (or other noble metal) clusters having been deposited atop the nanotube array; and the nanotube array mechanically supported by an integral support member. The array of titania nanotubes may include a dopant. An exposure of titania nanotube array to radiant energy emitted within a range of frequencies from visible to ultraviolet, in the presence of oxygen, removes a contaminant, if present. The titanium layer may be deposited atop the integral support; or the unique doped titanium layer can be produced, prior to the anodizing thereof, by depositing titanium along with dopant atop the integral support member by a co-deposition process. Also, supported: method(s) of producing the electrical resistive devices.Type: GrantFiled: April 2, 2004Date of Patent: March 14, 2006Assignee: The Penn State Research FoundationInventors: Oomman K. Varghese, Gopal Mor, Maggie Paulose, Craig A. Grimes
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Patent number: 6998151Abstract: The present invention provides a method to coat an article using a plating process, either electroless or electrolytic, whereby nickel is plated on the article using a solution that includes a suspension of powders or containing one or more of the following elements: Ni, Cr, Al, Zr, Hf, Ti, Ta, Si, Ca, Fe, Y and Ga. Optionally, the coating is then heat treated at a temperature above about 1600° F. for an effective amount of time to allow to homogenize the coating by allowing effective interdiffusion between the species. The level of aluminum may be altered to produce a coating of the predominantly ? phase of the NiAl alloy composition. Optionally, a TBC layer is applied over the predominantly ? phase NiAl alloy composition metallic bond coat.Type: GrantFiled: May 10, 2002Date of Patent: February 14, 2006Assignee: General Electric CompanyInventors: Richard Grylls, Theodore Robert Grossman
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Patent number: 6942781Abstract: A method for electroplating a strip of foam having two opposite sides and an electrically conductive surface, including: (a) continuously applying the strip of foam onto a moving cathode immersed in an electroplating bath so that the strip travels through the bath in contact with the moving cathode to electroplate metal on the strip of foam, a first side of the strip of foam facing a working surface of the moving cathode, and (b) continuously removing the electroplated strip of foam from the moving cathode when metal has been plated to a desired thickness; A metal foil is continuously formed by electrodeposition on the working surface of the moving cathode in such a way that the strip of foam is applied at step (a) onto the moving cathode over the metal foil; and, after step (b), the metal foil is continuously removed from the moving cathode.Type: GrantFiled: September 12, 2001Date of Patent: September 13, 2005Assignee: Efoam S.A.Inventors: Marc Kuhn, Louis Masotti, Damien Michel, Liyan Yang
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Patent number: 6932897Abstract: A method for plating a titanium-containing metal, comprising the steps of: (a) surface treating the titanium-containing metal in a solution consisting essentially of an aqueous solvent and hydrochloric acid for a period of time sufficient to activate the surface of the titanium-containing metal; (b) plating the surface of the surface treated titanium-containing metal with a metallic coating in an electrolyte bath; and (c) non-oxidatively heat treating the plated titanium-containing metal for a period of time sufficient to cause diffusion bonding between the metallic coating and the titanium-containing metal. The present invention also provides parts made in accordance with the methods disclosed herein.Type: GrantFiled: March 3, 2003Date of Patent: August 23, 2005Assignee: Com Dev Ltd.Inventors: Florin Burca, John Darmon
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Patent number: 6923897Abstract: The invention relates to a method for producing an electrolytically coated cold rolled strip, preferably for use in the production of battery sheaths. The cold rolled strip is provided with a cobalt or a cobalt alloy layer by an electrolytic method. The aim of the invention is to provide a battery sheath with low values for the electric contact resistance between the cathode substance of the battery and the inner surface of the battery sheath. To this end, organic substances m added to the electrolyte during coating that produce decomposition products, said decomposition produces and/or reaction products of said decomposition products with other components of the electrolytic bath being deposited on the strip material as a brittle layer along with the cobalt or the cobalt alloy.Type: GrantFiled: October 13, 2000Date of Patent: August 2, 2005Assignee: Hille & Mueller GmbHInventors: Ferdinand Schmidt, Hans-Guenter Steinmann, Karlfried Pfeifenbring, Werner Olberding, Dagmar Petrick
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Patent number: 6866765Abstract: An R-T-B magnet (R is at least one kind of rare-earth elements including Y, and T is Fe or Fe and Co) has an electrolytic copper-plating film where the ratio [I(200)/I(111)] of the X-ray diffraction peak intensity I(200) from the (200) plane to the X-ray diffraction peak intensity I(111) from the (111) plane is 0.1-0.45 in the X-ray diffraction by CuKal rays. This electrolytic copper-plating film is formed by an electrolytic copper-plating method using an electrolytic copper-plating solution which contains 20-150 g/L of copper sulphate and 30-250 g/L of chelating agent and contains no agent for reducing copper ions and has a pH adjusted to 10.5-13.5.Type: GrantFiled: July 4, 2001Date of Patent: March 15, 2005Assignee: Hitachi Metals, Ltd.Inventors: Setsuo Ando, Minoru Endoh, Tsutomu Nakamura, Toru Fukushi
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Patent number: 6855376Abstract: Carbon nanotubes are directly grown on a substrate surface having three metal layers thereon by a thermal chemical vapor deposition at low-temperature, which can be used as an electron emission source for field emission displays. The three layers include a layer of an active metal catalyst sandwiched between a thick metal support layer formed on the substrate and a bonding metal layer. The active metal catalyst is iron, cobalt, nickel or an alloy thereof; the metal support and the bonding metal independently are Au, Ag, Cu, Pd, Pt or an alloy thereof; and they can be formed by sputtering, chemical vapor deposition, physical vapor deposition, screen printing or electroplating.Type: GrantFiled: September 10, 2002Date of Patent: February 15, 2005Assignee: Industrial Technology Research InstituteInventors: Chien-Liang Hwang, Jack Ting, Jih-Shun Chiang, Chuan Chuang
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Patent number: 6824665Abstract: Disclosed are methods for depositing a copper seed layer on a substrate having a conductive layer. Such methods are particularly suitable for depositing a copper seed layer on a substrate having small apertures, and preferably very small apertures.Type: GrantFiled: October 17, 2001Date of Patent: November 30, 2004Assignee: Shipley Company, L.L.C.Inventors: James G. Shelnut, David Merricks, Oleh B. Dutkewych, Charles R. Shipley
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Patent number: 6790481Abstract: A corrosion-resistant, copper-finned heat exchanger for a water heater is provided. The heat exchanger includes a conduit through which water runs, heat-transfer fins extending from the conduit and an anti-corrosive coating containing electroless nickel. The heat-transfer fins contain copper, and the coating is deposited directly onto at least one of the copper heat-transfer fins.Type: GrantFiled: January 21, 2003Date of Patent: September 14, 2004Assignee: AOS Holding CompanyInventors: Charles J. Bishop, Ming C. Kuo
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Patent number: 6783653Abstract: A new class of solar selective absorption coatings are disclosed. These coatings comprise a structured metallic overlayer such that the overlayer has a sub-micron structure designed to efficiently absorb solar radiation, while retaining low thermal emissivity for infrared thermal radiation. A sol-gel layer protects the structured metallic overlayer from mechanical, thermal, and environmental degradation. Processes for producing such solar selective absorption coatings are also disclosed.Type: GrantFiled: December 4, 2002Date of Patent: August 31, 2004Assignee: Sandia CorporationInventors: Alan R. Mahoney, Scott T. Reed, Carol S. Ashley, F. Edward Martinez
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Patent number: 6755958Abstract: A cooper or copper alloy electrical contact member is treated by electroplating a barrier layer on a contact surface of the member, the barrier layer having a thickness ranging from about 0.00001 inch to about 0.0001 inch, and the barrier layer is selected from the group consisting of cobalt, cobalt-nickel alloys, cobalt-tungsten alloys, cobalt-nickel-tungsten alloys, and rhodium. An outer finish layer is coated over the barrier layer, and the finish layer is selected from the group consisting of tin, gold, palladium, platinum, silver, and alloys thereof, so that the electrical contact resistance of the treated contact member does not exceed about 10 milliohms at 100 grams contact force over a period of at least 1000 hours, and at a temperature of at least 150 degrees C.Type: GrantFiled: December 11, 2001Date of Patent: June 29, 2004Assignee: Handy & HarmanInventor: Amit Datta
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Patent number: 6656339Abstract: Methods of forming a nano-supported catalyst on a substrate and at least one carbon nanotube on the substrate are comprised of configuring a substrate with an electrode (102), immersing the substrate with the electrode into a solvent containing a first metal salt and a second metal salt (104) and applying a bias voltage to the electrode such that a nano-supported catalyst is at least partly formed with the first metal salt and the second metal salt on the substrate at the electrode (106). In addition, the method of forming at least one carbon nanotube is comprised of conducting a chemical reaction process such as catalytic decomposition, pyrolysis, chemical vapor deposition, or hot filament chemical vapor deposition o grow at least one nanotube on the surface of the nano-supported catalyst (108).Type: GrantFiled: August 29, 2001Date of Patent: December 2, 2003Assignee: Motorola, Inc.Inventors: Albert A. Talin, Bernard F. Coll, Kenneth A. Dean, Matthew Stainer
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Patent number: 6652914Abstract: A gas turbine blade which has previously been in service is protected by cleaning the gas turbine blade, and then first depositing a platinum first layer on the airfoil and the platform of the gas turbine blade. Thereafter, a platinum second layer is deposited over the platform but not the airfoil. A platinum-aluminide protective coating is formed by depositing an aluminum-containing layer overlying both the platform and the airfoil and interdiffusing the platinum and the aluminum.Type: GrantFiled: September 27, 2002Date of Patent: November 25, 2003Assignee: General Electric Aviation Service Operation Pte. Ltd.Inventors: Nigel Brian Thomas Langley, Keng Nam Chen, Genfa Hu, Kwok Heng Yow
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Patent number: 6645549Abstract: A process for providing bond enhancement and an etch resist for a printed circuit board is provided. A sheet comprising at least a layer of copper is immerses in a first immersion tin solution comprising a tin metal and a complexing agent in an acidic medium for a time sufficient to deposit a first heavy tin deposit on the sheet. The sheet is then immersed in a second immersion tin solution comprising stannous tin ions and stannic tin ions and a complexing agent in an acidic medium for a time sufficient to deposit a second thin tin deposit on the sheet. The second thin tin deposit has a thickness less than a thickness of the first heavy tin deposit. A rough surface texture providing mechanical adhesion sites results. The board is then treated with a coupling agent, such as silane, for enhanced bonding to a subsequent epoxy or other polymer prepreg. Additionally, the first heavy tin deposit may serve as an etch resist in subsequent fabrication of the provided circuit board.Type: GrantFiled: October 11, 2001Date of Patent: November 11, 2003Assignee: Parlex CorporationInventors: Darryl J. McKenney, Arthur J. Demaso, Kathy A. Gosselin, Craig S. Wilson
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Patent number: 6632342Abstract: In a method of fabricating an array of microstructures, a substrate with an electrically-conductive portion is provided, an insulating mask layer is formed on the electrically-conductive portion of the substrate, a plurality of openings are formed in the insulating mask layer to expose the electrically-conductive portion, and a first plated or electrodeposited layer is deposited in the openings and on the insulating mask layer by electroplating or electrodeposition. A second plated layer is further formed on the first plated or electrodeposited layer and on the electrically-conductive portion by electroless plating to reduce a size distribution of microstructures over the array.Type: GrantFiled: March 24, 2000Date of Patent: October 14, 2003Assignee: Canon Kabushiki KaishaInventors: Takayuki Teshima, Takayuki Yagi, Yasuhiro Shimada, Takashi Ushijima
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Publication number: 20030186033Abstract: A voltage variable composite structure comprising: a first layer of metal; a second layer of low-loss dielectric material impregnated with an array of first metal vias; a third layer of a voltage variable dielectric material; a fourth layer of a patterned thin metallic film; a fifth layer of low-loss dielectric material impregnated with an array of second metal vias; and a sixth layer of metal.Type: ApplicationFiled: March 27, 2002Publication date: October 2, 2003Inventor: William H. Henderson
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Patent number: 6589414Abstract: Nitride layer formation includes a method wherein a material is electrodeposited on a substrate and converted, at least in part, to a layer comprising nitrogen and the electrodeposited material. The electrodepositing may occur substantially selective on a conductive portion of the substrate. Also, the converting may comprise exposing the electrodeposited material to a nitrogen-comprising plasma. Chromium nitride and chromium oxynitride are examples of nitrogen-comprising materials. Copper or gold wiring of an integrated circuit are examples of a substrate. The processing temperature during the electrodepositing and the converting may be selected not to exceed 500° C. The thickness and composition of the nitride layer may be effective to limit diffusion of the wiring through the nitride layer. A diffusion barrier forming method may include forming a patterned layer of integrated circuit copper wiring over a substrate.Type: GrantFiled: June 4, 2001Date of Patent: July 8, 2003Assignee: Micron Technology, Inc.Inventor: Rita J. Klein
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Publication number: 20030116441Abstract: From the time that they are immersed into a marine environment, bronze propellers are prone to attack by marine organisms, such as barnacles, coral and algae, which attach themselves to the bronze metallic surface, creating lumps on the propeller, which adversely affect its balance and cause impedance and vibration of the propeller and its boat in the water. Ant-fouling paints are either too toxic for the marine environment of lack smoothness on the surface. These problems have been overcome by a combination of known steps, namely, polishing the propeller to prepare it for electroplating, cleansing to remove all traces of dirt and grease, electroplating with copper to a depth of at least 0.005″ or 0.15 mm, followed by spraying with a standard solution (5%) of sodium hypochlorite and sodium chloride in a suitable container to form a firmly adhering conversion coating of basic cupric chloride and then sealing for at least twenty-four hours.Type: ApplicationFiled: January 30, 2003Publication date: June 26, 2003Inventor: Ronald Kempin
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Patent number: 6579568Abstract: This invention provides a copper foil for a printed wiring board, which comprises a copper foil, an alloy layer (A) comprising copper, zinc, tin and nickel which is formed on a surface of the copper foil, said surface to be brought into contact with a substrate for a printed wiring board, and a chromate layer which is formed on a surface of the alloy layer (A). The copper foil for a printed wiring board has the following features: even if a printed wiring board is produced using a long-term stored copper foil, the interface between the copper foil and the substrate is only slightly corroded with chemicals; even if the copper foil contacts a varnish containing an organic acid, e.g., a varnish for an acrylic resin, in the formation of a copper-clad laminate, the bond strength is sufficient.Type: GrantFiled: October 26, 2001Date of Patent: June 17, 2003Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Kazuhisa Fujiwara, Hiroshi Tan, Mitsuo Fujii, Masanobu Tsushima
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Patent number: 6565931Abstract: The present invention provides for an etch and mar resistant low VOC clear coating composition most suitable for use as a top clear coat in multi-layered OEM or refinish automotive coatings. The coating composition includes isocyanate, carbonate and melamine components. The isocyanate component includes an aliphatic polyisocyanate. The composition may be formulated as a two-pack or one-pack coating composition, wherein the isocyanate functionalities are blocked with a blocker such as a mono-alcohol.Type: GrantFiled: October 18, 2000Date of Patent: May 20, 2003Assignee: Rolls-Royce plcInventors: David S Rickerby, Richard AB McCall
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Patent number: 6521113Abstract: An electrolyte for use in electrolytic platinum plating that results in reduced Cl, S, or P contaminant production. The bath comprises 0.01 to 320 g/lit of platinum in the form of the platinum salt dinitrodiammine platinum, Pt(NH3)2(NO2)2 or variants thereof and 0.1 to 240 g/lit of alkali metal carbonate M2CO3 or bicarbonate MHCO3 where M is selected from a group comprising lithium (Li), sodium (Na), potassium (K), rubidium (Rb) and cesium (Cs). A method of improving oxidation resistance of a platinum modified aluminide diffusion coating on a substrate, comprises electroplating the substrate using this electrolyte and then aluminizing the electroplated substrate at an elevated temperature to grow a platinum modified aluminide diffusion coating.Type: GrantFiled: June 29, 2001Date of Patent: February 18, 2003Assignee: Honeywell International Inc.Inventors: Thomas E. Strangman, Derek Raybould, Alex Kozlov
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Publication number: 20030010645Abstract: A damascene process for introducing copper into metallization layers in microelectronic structures includes a step of forming an enhancement layer of a metal alloy, such as a copper alloy or Co—W—P, over the barrier layer, using PVD, CVD or electrochemical deposition prior to electrochemically depositing copper metallization. The enhancement layer has a thickness from 10&mgr; to 100&mgr; and conformally covers the discontinuities, seams and grain boundary defects in the barrier layer. The enhancement layer provides a conductive surface onto which a metal layer, such as copper metallization, may be applied with electrochemical deposition. Alternatively, a seed layer may be deposited over the enhancement layer prior to copper metallization.Type: ApplicationFiled: June 14, 2002Publication date: January 16, 2003Applicant: Mattson Technology, Inc.Inventors: Chiu H. Ting, Igor Ivanov
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Publication number: 20020162751Abstract: A process is provided for coating metallic workpieces with a bearing material, wherein the workpiece first receives a hard chromium plating having a pearl or columnar structure type surface. A predominantly silver layer is then galvanically deposited, which fills in and smooths the pearl or columnar structure type surface of the hard chromium plating. Optionally, additional hard chromium platings and predominantly silver-containing layers may be applied, preferably galvanically. The predominantly silver layer may advantageously contain a graphite component.Type: ApplicationFiled: May 2, 2002Publication date: November 7, 2002Applicant: Duralloy AGInventor: Marco Santini
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Patent number: 6475644Abstract: Radioactive coating solutions and sol-gels, and corresponding methods for making a substrate radioactive by the application of the radioactive coating solutions and sol-gels thereto. The radioactive coating solution comprises at least one carrier metal and a radioisotope, which may be soluble or insoluble, and may further comprise a reducing agent. The radioactive sol-gel comprises at least one metal alkoxide and a radioisotope, which may be soluble or insoluble. Methods of making a substrate radioactive by coating with radioactive coating solutions or sol-gels are also disclosed, including electrodeposition, electroless deposition, spin coating and dip coating. In a particular embodiment, the radioactive coating formed by the method is a composite coating. Radioactive substrates are also disclosed, comprising a substrate and one or more radioactive coatings, which coatings may be the same or different.Type: GrantFiled: August 31, 1999Date of Patent: November 5, 2002Assignee: Radiovascular Systems, L.L.C.Inventors: Janet M. Hampikian, Neal A. Scott
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Patent number: 6436265Abstract: A fabrication method of fabricating an array of microstructures is provided. The method includes the step of preparing a substrate with a surface including a usable region and a dummy region continuously set around the usable region, at least the usable region and the dummy region of the substrate are electrically conductive and have a conductive portion. The method also includes the steps of forming a first insulating layer on the conductive portion, and forming a plurality of openings in the first insulating layer, the openings being arranged in a predetermined array pattern. Additionally, the method includes the step of performing one of electroplating and electrodeposition using the conductive portion as an electrode to form a first plated or electrodeposited layer in the openings and on the first insulating layer in both the usable region and the dummy region.Type: GrantFiled: March 24, 2000Date of Patent: August 20, 2002Assignee: Canon Kabushiki KaishaInventors: Yasuhiro Shimada, Takayuki Yagi, Takayuki Teshima, Takashi Ushijima
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Publication number: 20020011418Abstract: Disclosed is a process of treating the surface of copper foil without using harmful elements such as arsenic, selenium and tellurium unlike in the prior art. It is possible to, in an easy way, obtain a uniform rough condition and low rougheness and produce a high adhesive strength to such resin base materials as polymide resin which is weak in adhesive strength. The process comprises a roughening treatment involving a cathodic electrolysis of at least one side of copper foil near or above the limiting current density in an electrolytic bath containing titanium ions and tungsten ions and prepared by adding sulfuric acid and copper sulfate so as to have copper protrusions deposited and then coating the depositions with copper or a copper alloy in a cathodic electrolysis, followed by giving to the surface of the above-mentioned copper or the copper alloy at least one of the following rust-proofing treatments—chromate treatment, organic rust-proofing treatment and silane coupling agent treatment.Type: ApplicationFiled: April 12, 2001Publication date: January 31, 2002Applicant: FUKUDA METAL FOIL & POWDER CO., LTD.Inventors: Hisanori Manabe, Masasto Takami, Masaru Hirose
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Publication number: 20020000371Abstract: A substrate processing apparatus fills a metal such as copper or the like in fine interconnection patterns or trenches defined in a semiconductor substrate. The substrate processing apparatus has a loading/unloading unit for placing a substrate cassette to load and unload a substrate, a substrate treating unit for treating a substrate, and a transfer robot for transferring a substrate between the loading/unloading unit and the substrate treating unit. The loading/unloading unit, the substrate treating unit, and the transfer robot are installed in a single facility. The loading/unloading unit has a rotary table which is horizontally rotatable for positioning the substrate cassette in a position to detect the substrate cassette placed in the loading/unloading unit and to remove the substrate from the substrate cassette with the transfer robot.Type: ApplicationFiled: May 25, 2001Publication date: January 3, 2002Inventors: Koji Mishima, Junji Kunisawa, Natsuki Makino, Norio Kimura, Hiroaki Inoue, Kenji Nakamura, Moriji Matsumoto, Takahiro Nanjo, Mitsuko Odagaki
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Publication number: 20010050100Abstract: A Cu plated ceramic substrate is used in a semiconductor. On a ceramic substrate layer, a thin-film Cr layer is put, and a thin-firm Au layer is put on the Cr layer. The Au layer is plated with Cu. By providing the Au and Cr layers between the ceramic plate and Cu layer, adhesibility is increased. A Pertier element which includes the Cu plated ceramic layer is employed in a semiconductor to absorb and generate heat efficiently.Type: ApplicationFiled: April 11, 2001Publication date: December 13, 2001Inventors: Iwao Numakura, Noriaki Tsukada
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Patent number: 6319190Abstract: The invention relates to radioactive ruthenium sources with a dosage rate of at least 1.5 Gy/min at a distance (water) of 2 mm, consisting of an activity carrier and an encapsulation of the carrier made of a material compatible with the human body. A multilayer system made of metals and/or alloys is galvanically applied on the carrier. At least two layers in said system are made of ruthenium 106 and inactive intermediate layers made of other metals or alloys are provided between the radioactive ruthenium layers. The activity carrier is encapsulated with a material compatible with the human body, for instance a metal or a plastic material. Encapsulation can be carried out by filing a capsule and subsequently sealing or galvanically depositing a top layer made, for instance of hard gold.Type: GrantFiled: February 14, 2000Date of Patent: November 20, 2001Assignee: Bebig Isotopentechnik und Umweltdiagnostik GmbHInventors: Werner Schmidt, Renate Freudenberger, Michael Andrassy, Jürgen Ziegler, Detlev Behrendt, Andre Hess
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Process for the multilayer coating of substrates with electrodeposition and powder coating materials
Publication number: 20010011639Abstract: The present invention relates to a process for the multilayer coating of substrates with electrodeposition and powder coating materials, in which electrodeposition is used to apply at least one coat (2) of electrodeposition coating material to the substrate (1), after deposition the substrate (1) is, if desired, wholly or partially air-dried, a coat of powder coating material (3) is then applied, and finally electrodeposition coating material and powder coating material are jointly baked.Type: ApplicationFiled: January 26, 2001Publication date: August 9, 2001Inventors: Udo Reiter, Rolf Boysen, Josef Rademacher, Thomas Brucken -
Patent number: 6269551Abstract: A method employed to dry a copper foil having been subjected to various surface treatments, which method comprises irradiating at least one surface-treated side of the copper foil with near infrared rays to dry the copper foil, and an apparatus suitable to the method. The drying of the copper foil having undergone surface treatments can be accomplished by a simple apparatus with low electric power while controlling the heating of the surface of the copper foil so that the drying temperature can be held at 100° C. or higher at which a eutectic alloying of rust preventive metal and copper foil, for example, alloying (brass formation) of zinc and copper on the surface of the copper foil is effected.Type: GrantFiled: July 16, 1999Date of Patent: August 7, 2001Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Nobuyuki Imada, Kazuhide Oshima
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Patent number: 6217737Abstract: A corrosion-resistant and electrically conductive connector shell includes a shell member formed of an aluminum alloy; an anodic surface coating formed on and extending into the shell member, having an approximate thickness between 0.0008 inch and 0.0018 inch; and a conductive metal plating covering and sealing the anodic surface coating. The metal plating can be a single layer of high purity aluminum having a thickness of 0.0002 inch. Alternatively, the metal plating can include a layer of a first metal on the anodic surface coating and having a thickness of at least approximately 0.00002 inch, and a layer of a second metal such as cadmium having a thickness of approximately 0.0002 inch on the layer of first metal.Type: GrantFiled: October 3, 1997Date of Patent: April 17, 2001Assignee: Hirel Connectors Inc.Inventor: Frederick B. B. Baumann
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Patent number: 6207035Abstract: A method for manufacturing a metal composite strip for the production of electrical contact components. A film made of tin or a tin alloy is first applied onto an initial material made of an electrically conductive base material. A film of silver is then deposited thereonto. Copper or a copper alloy is preferably used as the base material. The tin film can be applied in the molten state, and the silver film by electroplating. Furthermore, both the tin film and the silver film can be deposited by electroplating. A further alternative provides for manufacturing the tin film in the molten state and the silver film by cathodic sputtering. The diffusion operations which occur in the coating result in a homogeneous film of a tin-silver alloy. This formation can be assisted by way of a heat treatment of the composite strip.Type: GrantFiled: November 20, 1998Date of Patent: March 27, 2001Assignee: Stolberger Metallwerke GmbH & Co. KGInventors: Udo Adler, Klaus Schleicher
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Patent number: 6176994Abstract: A conductive electrode wire is passed through a molten salt bath maintained at a temperature above the melting point of the salts. A main electrical power supply passes an electric current between the electrode wire and an anode in the molten salt bath so that a metal coating layer is electrolytically deposited onto the core of the electrode wire. The high temperature of the molten salt bath ensures inter-diffusion of the metals of the core and the coating. This enables diverse coating structures to be obtained by choosing electrolysis and diffusion parameters.Type: GrantFiled: May 4, 1999Date of Patent: January 23, 2001Assignee: Thermocompact, societe anonymeInventor: Louis Lacourcelle
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Patent number: 6132589Abstract: This invention relates to a treated copper foil, comprising: a copper foil with a layer of zinc oxide adhered to the base surface of at least on side of said copper foil, said layer of zinc oxide having a thickness of about 3 .ANG. to about 80 .ANG.; and a layer of a trivalent chromium oxide adhered to said layer of zinc oxide. In one embodiment, the foil has a layer of a silane coupling agent adhered to the layer of trivalent chromium oxide. The invention also relates to a process for applying the layer of zinc oxide and the layer of trivalent chromium oxide to the copper foil. The invention also relates to laminates comprising a dielectric substrate and the foregoing copper foil adhered to the substrate. In one embodiment, the dielectric substrate is comprised of an epoxy resin made with a curing agent that is other than an amine curing agent.Type: GrantFiled: September 10, 1998Date of Patent: October 17, 2000Assignee: GA-TEK Inc.Inventors: Thomas J. Ameen, Edward Czapor