Silica Or Silicate Containing Catalyst Patents (Class 208/109)
  • Patent number: 6984309
    Abstract: The invention pertains to a catalyst that consists of a substrate made of at least one matrix and at least one zeolite that is selected from the group composed of the zeolites ZSM-48, EU-11, and ZBM-30, whereby, at the level of the zeolite, at least one noble metal of Group VIII is deposited on said substrate. The noble metal is preferably located on the outer surfaces of the zeolite crystals, and more preferable at the mouths of pores. The invention also pertains to a process for preparing the catalyst and utilizing the catalyst to treat hydrocarbon feedstocks, and especially for improving their pour points.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: January 10, 2006
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George, Johan Martens, Marion Claude
  • Patent number: 6908602
    Abstract: Method for producing hydrogen and a hydroprocessed product from a hydrocarbonaceous feedstock by subjecting it to a catalytic hydrocracking treatment using hydrogen which has been at least partly produced from hydrocracked feedstock and subjecting at least pan of the hydrocracked feedstock, after having subjected it to a separation treatment in the event that hydroprocessed product is to be recovered, to a treatment to produce hydrogen in a single operation which hydrogen is at least partly recovered as product.
    Type: Grant
    Filed: May 9, 2000
    Date of Patent: June 21, 2005
    Assignee: Shell Oil Company
    Inventors: Johan Willem Gosselink, Michiel Jan Groeneveld, Andreas Karl Nowak, Antonius Adrianus Maria Roovers
  • Publication number: 20040112793
    Abstract: A process for cracking an olefin-rich hydrocarbon feedstock which is selective towards light olefins in the effluent, the process comprising contacting a hydrocarbon feedstock containing olefins having a first composition of one or more olefinic components with a crystalline silicate catalyst to produce an effluent having a second composition of one or more olefinic components, the feedstock and the effluent having substantially the same olefin content by weight therein, the feedstock contacting the catalyst in the presence of hydrogen for enhancing the stability of the catalyst.
    Type: Application
    Filed: November 21, 2003
    Publication date: June 17, 2004
    Inventors: Jean-Pierre Dath, Walter Vermeiren
  • Patent number: 6740226
    Abstract: In a hydrocracking unit, the flash gases from the high-pressure separator are fed to the bottom of an absorption zone where the entering gases are counter-currently contacted with a lean solvent. The lean solvent absorbs away the contained methane, ethane, propane, butanes and pentanes (C1+) from the contained hydrogen. The overhead gas stream from the absorption zone typically contains hydrogen at a purity of 90 to 98 mol %, or even higher, which is fed to the recycle gas stream to provide hydrogen purity in the range of 96 to 99 mol %, thereby providing an increase in the overall efficiency of the hydroprocessor unit. The process can also be employed with hydrotreating, hydrodesulfurization, hydrodenitrogenation and hydrodealkylation reactors.
    Type: Grant
    Filed: January 16, 2002
    Date of Patent: May 25, 2004
    Assignee: Saudi Arabian Oil Company
    Inventors: Yuv Raj Mehra, Ali Hassan Al-Abdulal
  • Patent number: 6736959
    Abstract: The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which the feed to be treated is brought into contact with a catalyst. The catalyst comprises at least one dioctahedral 2:1 phyllosilicate, preferably synthesised in a fluoride medium in the presence of the acid HF and/or a further source of fluoride anions, and preferably having an interplanar spacing of at least 20×10−10 m (2 nm) and comprising pillars based on at least one oxide of elements from groups IVB, VB, VIB, VIII, IB, IIB, IIA or IVA or any combination of these oxides, and preferably selected from the group SiO2, Al2O3, TiO2, ZrO2 and V2O5, or any combination of these latter. The catalyst further comprises at least one hydrodehydrogenating element in the metallic form. The process is carried out at a temperature in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and at an hourly space velocity in the range 0.
    Type: Grant
    Filed: July 23, 2001
    Date of Patent: May 18, 2004
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George
  • Patent number: 6709570
    Abstract: A method for preparing a catalyst comprising a zeolite and a low acidity refractory oxide binder which is essentially free of alumina which method comprises: (a) preparing an extrudable mass comprising a substantially homogenous mixture of zeolite, water, a source of the low acidity refractory oxide binder present which comprises an acid sol, and an amine compound, (b) extruding the extrudable mass resulting from step (a), (c) drying the extrudate resulting from step (b); and, (d) calcining the dried extrudate resulting from step (c).
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: March 23, 2004
    Assignee: Shell Oil Company
    Inventors: Maria Barbara Hendrica Van Crijnen-Beers, Jean-Paul Darnanville, Carolus Matthias Anna Maria Mesters, Thomas Joris Remans
  • Publication number: 20040040888
    Abstract: This invention relates to an improved process for hydrocracking into a stage of hydrocarbon feedstocks, using in a first reaction zone a pretreatment catalyst that exhibits a low acidity according to a standard activity test and an amorphous acid catalyst for hydrocracking that is free of zeolite in a second reaction zone that is located downstream from the first.
    Type: Application
    Filed: June 6, 2003
    Publication date: March 4, 2004
    Inventors: Eric Benazzi, Patrick Bourges, Christophe Gueret, Tivadar Cseri, Hugues Dulot
  • Publication number: 20040031727
    Abstract: Cationic layered materials, a process for their preparation and their use in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking. Cationic layered materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel. The new preparation process avoids the use of metal salts and does not require the formation of anionic clay as an intermediate.
    Type: Application
    Filed: June 24, 2003
    Publication date: February 19, 2004
    Inventors: Paul O'Conner, William Jones, Dennis Stamires
  • Publication number: 20030168379
    Abstract: A process for isomerization dewaxing of a hydrocarbon feed which includes contacting the hydrocarbon feed with a large pore size, small crystal size, crystalline molecular sieve and an intermediate pore size, small crystal size, crystalline molecular sieve to produce a dewaxed product with a reduced pour point and a reduced cloud point. In a preferred embodiment, the feed is contacted with the molecular sieves sequentially, first with the large pore sieve followed by the intermediate pore sieve.
    Type: Application
    Filed: April 26, 2001
    Publication date: September 11, 2003
    Inventors: Thomas F. Degnan, Philip J. Angevine
  • Publication number: 20030132138
    Abstract: In a hydrocracking unit, the flash gases from the high-pressure separator are fed to the bottom of an absorption zone where the entering gases are counter-currently contacted with a lean solvent. The lean solvent absorbs away the contained methane, ethane, propane, butanes and pentanes (C1+) from the contained hydrogen. The overhead gas stream from the absorption zone typically contains hydrogen at a purity of 90 to 98 mol %, or even higher, which is fed to the recycle gas stream to provide hydrogen purity in the range of 96 to 99 mol %, thereby providing an increase in the overall efficiency of the hydroprocessor unit. The process can also be employed with hydrotreating, hydrodesulfurization, hydrodenitrogenation and hydrodealkylation reactors.
    Type: Application
    Filed: January 16, 2002
    Publication date: July 17, 2003
    Inventors: Yuv Raj Mehra, Ali Hassan Al-Abdulal
  • Patent number: 6576120
    Abstract: The invention relates to a process for the catalytic dewaxing of a hydrocarbon feed containing waxy molecules by contacting the hydrocarbon feed under catalytic dewaxing conditions with a catalyst composition having metallosilicate crystallites, a binder and a hydrogenation component, wherein the weight ratio of the metallosilicate crystallites and the binder is between 5:95 and 35:65. The invention also relates to a catalyst composition having at least a low acidity refractory oxide binder, which binder is essentially free of aluminum, metallosilicate crystallites and a hydrogenation component, wherein the weight ratio of the metallosilicate crystallites and the binder is between 5:95 and 35:65.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: June 10, 2003
    Assignee: Shell Oil Company
    Inventors: Carolus Maria Van Ballegoy, Edward Julius Creyghton, Jean-Paul Darnanville, Eric Duprey, Laurent Georges Huve, Carolus Matthias Anna Maria Mesters, Thomas Joris Remans, Maria Barbara Hendrica Crijnen-Van Beers
  • Publication number: 20030075479
    Abstract: A catalyst support including a zeolite having an Al/Si atomic ratio of 0.01-0.1 and mesopores having a pore diameter in the range of 5-30 nm, and ultrafine particles composited to inside walls of the mesopores. The superfine particles are those of an oxide of a metal selected from Ti, Zr and Hf.
    Type: Application
    Filed: June 5, 2001
    Publication date: April 24, 2003
    Applicant: JAPAN COOPERATION CENTER, PETROLEUM
    Inventors: Kosaku Honna, Yasuhiro Araki, Yasuo Miki, Hiromichi Shimada
  • Patent number: 6544407
    Abstract: Process for the preparation of a middle distillate having good properties at low temperatures, which can be used as fuel, starting from a mixture of substantially linear hidrocarbons, without sulfur and containing at least 20% of a high-boiling fraction having a distillation temperature exceeding 370° C., comprising, as single reactive step, a “hydrocracking” step on said mixture of linear hydrocarbons, at a temperature ranging from 250 to 450° C. and a total pressure of 0.5 to 15 MPa, in the presence of a supported catalyst comprising: (A) a carrier of an acid nature consisting of a calcined gel of silica-alumina amorphous to X-rays having a molar ratio between silica and alumina within the range of 30 and 500, a surface area within the range of 500 and 1000 m2/g, with a porosity within the range of 0.2 and 0.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: April 8, 2003
    Assignees: Agip Petroli S.p.A., Enitecnologie S.p.A.
    Inventors: Vincenzo Calemma, Stefano Peratello, Carlo Perego, Silvia Pavoni, Silvia Guanziroli
  • Patent number: 6533923
    Abstract: The present invention relates to stevensite or kerolite type trioctahedral phyllosilicates 2:1 containing fluorine, fluorinated in synthesis in an acid medium and modified post-synthesis to bring about Si/Al and/or Mg/Al substitutions which impart acid properties to the solid. These phyllosilicates may be incorporated in the composition of catalysts used to convert hydrocarbons, in particular for hydrocracking.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: March 18, 2003
    Assignee: Institut Francais du Pétrole
    Inventors: Sylvie Lacombe, Véronique Schlussel, Jacques Baron, Ronan Le Dred
  • Publication number: 20020179490
    Abstract: The invention pertains to a carrier composition comprising (a) at least 30 wt % of a synthetic cracking component, based on the total weight of the carrier composition, which comprises oxidic compounds of one or more trivalent metallic elements, tetravalent metallic elements, and divalent metallic elements, said cracking component comprising elemental clay platelets with an average diameter of 1 &mgr;m or less and an average degree of stacking of 20 platelets per stack or less, and/or comprising a cogel with a saponite content CA of less than 60 %, in which the total of sodium and potassium amounts to less than 1 wt %, based on the total weight of the cogel, and (b) 1 −25 wt % of a zeolite Y, based on the total weight of the carrier composition, with a unit cell size below 24.35 å. The invention further pertains to a catalyst comprising said carrier composition and at least a hydrogenation metal, and a process for converting heavy feedstock into middle distillates using said catalyst.
    Type: Application
    Filed: January 31, 2001
    Publication date: December 5, 2002
    Inventors: Jan Nieman, Johannes Wilhelmus Maria Sonnemans, Bas De Kroes
  • Publication number: 20020179489
    Abstract: The present invention relates to a method for gas-solid contacting in a bubbling fluidized bed reactor by:
    Type: Application
    Filed: March 26, 2001
    Publication date: December 5, 2002
    Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Vasant Ramchandra Choudhary, Tushar Vasant Choudhary
  • Publication number: 20020170847
    Abstract: The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which the feed to be treated is brought into contact with a catalyst comprising at least one dioctahedral 2:1 phyllosilicate, preferably synthesised in a fluoride medium in the presence of the acid HF and/or a further source of fluoride anions, and preferably wherein the interplanar spacing is at least 20×10−10 m (2 nm) and comprising pillars based on at least one oxide of elements from groups IVB, VB, VIB, VIII, IB, IIB, IIA or IVA or any combination of these oxides, preferably selected from the group formed by SiO2, Al2O3, TiO2, ZrO2 and V2O5, or any combination of these latter, and at least one hydrodehydrogenating element in the metallic form. The process is carried out at a temperature in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and at an hourly space velocity in the range 0.
    Type: Application
    Filed: July 23, 2001
    Publication date: November 21, 2002
    Applicant: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George
  • Patent number: 6464857
    Abstract: Molecular sieves comprising (1) phosphorus oxide; (2) a first oxide comprising an oxide of silicon, germanium or mixtures thereof; and (3) a second oxide comprising an oxide of aluminum, boron or mixtures thereof, said molecular sieve having a mole ratio of the first oxide to the second oxide of greater than 1, containing at least about 10 weight percent phosphorus oxide in the crystal framework, and having pores greater than 5 Å in diameter are useful as catalysts in hydrocarbon conversion reactions.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: October 15, 2002
    Assignee: Chevron U.S.A. Inc.
    Inventor: Stephen J. Miller
  • Patent number: 6416654
    Abstract: Nitrogenous compounds especially bases such as ammonia vapor are used to control the operation of a hydrocracker or catalytic dewaxer. Catalyst activity and selectivity may be controlled by addition of the base to the feed, for example, to control the balance between isomerization and hydrocracking in an operation using a zeolite beta catalyst. Runaway conditions may be controlled by the addition of nitrogenous compounds to regulate the temperature profile within the reactor.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: July 9, 2002
    Assignee: Mobil Oil Corporation
    Inventors: Tai-Sheng Chou, Nai Yuen Chen, Grant G. Karsner, Clinton R. Kennedy, Rene B. LaPierre, Melcon G. Melconian, Richard J. Quann, Stephen S. Wong
  • Patent number: 6409986
    Abstract: The present invention relates to zeolithic materials having a characteristic X ray diffraction pattern, and its preparation method, characterized by the relatively low pH of the synthesis medium and the use of F− anions as mineralizing agent. The invention also claims the use of the obtained material in catalytic processes for the transformation of hydrocarbons and in oxidation process. The method comprises heating at 363-473° K a reaction mixture which contains a source of at least one tetravalent element T(IV), optionally a source of an element T(III), optionally H2O2, a structure director organic cation, a source of anions F− and water, the presence of alkaline cations is not necessary.
    Type: Grant
    Filed: June 19, 2000
    Date of Patent: June 25, 2002
    Assignee: Consejo Superior de Investigaciones Cientificas Universidad Politecnica de Valencia
    Inventors: Miguel-Angel Camblor Fernandez, Avelino Corma Canos, Susana Valencia Valencia
  • Patent number: 6388161
    Abstract: A process for cracking an olefin-rich hydrocarbon feedstock which is selective towards propylene in the effluent, the process comprising contacting a hydrocarbon feedstock containing one or more olefinic components of C4 or greater with a crystalline silicate catalyst to produce an effluent having a second composition of one or more olefinic components of C3 or greater, the feedstock and the effluent having substantially the same olefin content by weight therein characterized in that ethylene is added to the feedstock before the feedstock contacts the catalyst.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: May 14, 2002
    Assignee: Fina Research, S.A.
    Inventors: Jean-Pierre Dath, Walter Vermeiren
  • Patent number: 6355159
    Abstract: A heavy hydrocarbon is rendered pipelineable by hydroconverting the heavy hydrocarbon under conditions sufficient to obtain a product oil of lowered viscosity and an API gravity suitable for pipelining and thereafter adding a diluent modified hydrocarbon to the product oil in an amount sufficient to stabilize the product oil against asphaltene phase separation and when phase separated asphaltene is present to dissolve the phase separated asphaltenes.
    Type: Grant
    Filed: August 4, 2000
    Date of Patent: March 12, 2002
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ronald Damian Myers, Mainak Ghosh, Michelle A. Young, Tapan Chakrabarty, Bruce M. Sankey, Irwin Andrew Wiehe
  • Patent number: 6344135
    Abstract: The invention concerns a hydrocracking process using a catalyst comprising at least one matrix, an IM-5 zeolite, at least one metal selected from the group formed by metals from group VIB and group VIII of the periodic table, optionally at least one element selected from the group formed by phosphorous, boron and silicon, and optionally at least one group VIIA and/or at least one group VIIB and/or at least one group VB element (in particular niobium). The invention also concerns a catalyst containing at least one matrix, an IM-5 zeolite, at least one metal from groups VIII and/or VIB and at least one promoter element which is boron and/or silicon. The catalyst can also contain at least one group VIIA element and/or at least one group VIIB element and/or at least one group VB element.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: February 5, 2002
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Slavik Kasztelan
  • Patent number: 6340430
    Abstract: A hydrotreating process is presented for both dewaxing the diesel fraction and reducing the aromatic content of kerosene fraction of a distillate boiling range feed stream. The feed stream is flashed to generate vapor and liquid phase streams. The portion which comprises most of the heavy diesel is passed into a dewaxing zone. The vapor-phase stream, preferably rich in kerosene and light diesel, is used to quench the effluent of the dewaxing zone before it is passed into a downstream aromatics hydrogenation zone. Depending on the composition of the feed to the process, a second flashing step performed in the presence of added hydrogen may be employed to produce the feed to the dewaxing zone. PNA's may be hydrogenated prior to recycling to a hydrocracking zone.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: January 22, 2002
    Assignee: UOP LLC
    Inventor: Brian Murray Wood
  • Patent number: 6334947
    Abstract: The invention pertains to a catalyst at least comprising a hydrogenation metal component and a swelling synthetic clay consisting of elemental clay platelets, with the average diameter of the clay platelets not exceeding 1 micron and the average degree of stacking of the clay platelets not exceeding 20 platelets per stack. The catalyst is especially suitable for the hydroprocessing of hydrocarbon feeds, the term “hydroprocessing” encompassing all processes in which a hydrocarbon feed is treated with hydrogen. The clays which are suitable for use in the catalyst according to the invention may be prepared as described in Netherlands patent application No. 9401433.
    Type: Grant
    Filed: May 6, 1997
    Date of Patent: January 1, 2002
    Assignee: Akzo Nobel NV
    Inventors: Mark De Boer, Eelco Titus Carel Vogt, Robertus Gerardus Leliveld, John Wilhelm Geus, Roland Jacobus Martinus Josephus Vogels
  • Patent number: 6294081
    Abstract: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions, a method for their preparation and their use as catalysts for the hydroprocessing of hydrocarbon feedstocks. More particularly, the new SAPOs have a high silica:alumina ratio, and are prepared from microemulsions containing surfactants.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: September 25, 2001
    Assignee: ExxonMobil Chemical Patents, Inc.
    Inventors: Javier Agundez Rodriguez, Joaquin Perez Pariente, Antonio Chica Lara, Avelino Corma Canos, Ian A. Cody, William J. Murphy, Sandra J. Linek
  • Patent number: 6238550
    Abstract: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions, a method for their preparation and their use as catalysts for the hydroprocessing of hydrocarbon feedstocks. More particularly, the new SAPOs have a high silica:alumina ratio, and may be prepared from single phase synthesis solutions or from microemulsions containing surfactants.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: May 29, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Karl G. Strohmaier, David E. W. Vaughan, William J. Murphy, Ian A. Cody, Sandra J. Linek
  • Patent number: 6187708
    Abstract: The invention relates to a process for the sulfurization of hydroconversion catalysts, whereby said catalyst contains at least one element of group VIII of the periodic table and optionally an element of group VI, whereby said metal is present in the oxide state. Said process comprises at least one stage that is carried out in a hydrotreatment zone in the presence of at least one thionic compound and at least one nitrogenous compound. This process is carried out in such a way that before the final sulfurization temperature is reached, at least 130% of the stoichiometric amount of sulfur that is necessary for complete sulfurization of the catalyst is injected in said catalyst.
    Type: Grant
    Filed: May 5, 1999
    Date of Patent: February 13, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Samuel Mignard, Virginie Harle, Slavik Kasztelan, Nathalie Marchal-George
  • Patent number: 6171475
    Abstract: A method for converting a polymer or oligomer derived from an ethylenically unsaturated monomer into alkanes or into a hydrocarbon fraction or a lower oligomer fraction by controlled hydrocracking, wherein the polymer or oligomer is exposed to a catalyst based on a metal hydride or an organometallic complex supported on a mineral carrier, the complex having at least one hydrocarbon ligand and optionally at least one hydride ligand, and the resulting mixture is reacted with hydrogen to cause catalytic hydrocracking of the polymer or oligomer. The polymer or oligomer is broken down into reclaimable products with a lower molecular weight for use, e.g., in the field of polymers, particularly controlled molecular weight polymers, fuels or lubricants.
    Type: Grant
    Filed: January 12, 1998
    Date of Patent: January 9, 2001
    Assignee: CPE-Lyon-FCR
    Inventors: V{acute over (e)}ronique Dufaud, Jean-Marie Basset
  • Patent number: 6165349
    Abstract: The nature of the process consists in that the low-grade organic substances are subject, at a temperature of 150.degree. C. to 700.degree. C. and at a pressure of 0.1 MPa to 2.5 MPa, to the action of a moving bed of solid particles of a substance which perform whirling motion, whereby the solid particles of a substance constituting the moving bed are set to whirling motion by intensive agitation.The device consists of a reaction chamber (1) with a rotation mechanism (2) which rotation mechanism (2), located rotably in the faces of the reaction chamber (1), consists of a shaft (3) to which vanes (5) are symetrically attached by means of driving discs (4). The vanes (5) may be arranged in 3 to 10 rows, and they may be provided with openings (5.1) or cut-outs (5.2) of various geometrical shapes, and they may be divided into individual segments (5.3). Also the driving discs (4) may be provided with openings (4.1) of various geometrical shapes.
    Type: Grant
    Filed: June 1, 1999
    Date of Patent: December 26, 2000
    Inventor: Ivan Madar
  • Patent number: 6160191
    Abstract: A process for converting hydrocarbons by contacting a hydrocarbon feedstream under hydrocarbon conversion conditions with a large crystal zeolite catalyst. The large crystal zeolite of the catalyst used in the hydrocarbon conversion process is made by heating an aqueous zeolite synthesis mixture under agitation to a temperature equal to or less than the effective nucleation temperature of the synthesis mixture. After this step, the aqueous synthesis mixture is heated in the absence of agitation to a temperature equal to or greater than the effective nucleation temperature of the aqueous zeolite synthesis mixture. The process finds particular application in hydrocarbon conversion processes where reduced non-selective acidity is important for reaction selectivity and/or the maintenance of catalyst activity, e.g., toluene disproportionation, dealkylation, alkylation, and transalkylation.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: December 12, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Robert Scott Smith, Johannes Petrus Verduijn, deceased, by Jannetje Maatje van den Berge, executrix, Gary David Mohr, Thomas Herman Colle
  • Patent number: 6139719
    Abstract: The invention relates to dioctahedral phyllosilicates 2:1 whose basal spacing is at least equal to 2.0.times.10.sup.-9 m and which in the interlayer space comprise pillars based on at least one of the compounds that is selected from the group that is formed by SiO.sub.2, Al.sub.2 O.sub.3, TiO.sub.2, ZrO.sub.2, V.sub.2 O.sub.5, or any combination of the latter. Preferably, they contain fluorine. The invention also relates to a process for their preparation that includes treatment with a surfactant, followed by treatment with a primary or secondary amine and at least one alkoxide of an element that is selected from the group that is formed by the elements Si, Al, Zr, Ti and V. The invention also relates to a catalyst that comprises said phyllosilicate, at least one matrix, and optionally a zeolite Y. The invention also relates to a process for converting hydrocarbons with this catalyst, and in particular a hydrocracking process.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: October 31, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Jocelyne Brendle, Ronan Le Dred, Jacques Baron, Daniel Saehr, Nathalie Georges-Marchal, Sylvie Lacombe
  • Patent number: 6136179
    Abstract: This invention relates to a process of catalytic hydroconversion of a heavy hydrocarbon oil containing a substantial portion of components having an atmospheric boiling point above 565.degree. C. to give a product hydrocarbon oil containing components having a boiling point below about 565.degree. C. The process includes steps of mixing a heavy hydrocarbon oil with an oil soluble molybdenum compound, introducing the resulting mixture into a hydroconversion zone, introducing a reactor feed gas into the hydroconversion zone, and recovering the product hydrocarbon oil from the hydroconversion zone.
    Type: Grant
    Filed: June 19, 1998
    Date of Patent: October 24, 2000
    Assignee: Texaco Inc.
    Inventors: David Edward Sherwood, Jr., Michael Kevin Porter
  • Patent number: 6123831
    Abstract: The invention concerns a hydrocracking catalyst comprising at least one amorphous or poorly crystallised matrix of oxide type, at least one element from group VB, preferably niobium, at least one zeolite selected from the group formed by zeolites NU-85, NU-86 and NU-87, and at least one element selected among boron and silicon, optionally P, optionally at least one element selected from the elements from group VIB and group VIII, and/or optionally at least one element from group VIIA. The invention also concerns the use of that catalyst in the hydrocracking of hydrocarbon charges.
    Type: Grant
    Filed: May 27, 1999
    Date of Patent: September 26, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie Marchal-George, Fabrice Diehl, Slavik Kasztelan
  • Patent number: 6106698
    Abstract: The invention provides a hydrocracking catalyst comprising at least one matrix, a zeolite selected from the group formed by NU-85, NU-86 and NU-87 zeolites, at least one metal selected from the group formed by metals from group VIB and VIII of the periodic table, at least one element selected from the group formed by boron and silicon, optionally phosphorous, optionally at least one group VIIA element, and optionally at least one group VIIB element. The invention also relates to the use of the catalyst for hydrocracking hydrocarbon feeds.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: August 22, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie George-Marchal, Slavik Kasztelan
  • Patent number: 6096192
    Abstract: A bitumen is rendered pipelineable by partially hydroconverting the bitumen and then adding sufficient diluent to the partially hydroconverted bitumen to provide a mixture having an API gravity at 15.degree. C. of at least 19.degree. and a viscosity at 40.degree. C. in the range of about 35 to about 60 cP.
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: August 1, 2000
    Assignee: Exxon Research and Engineering Co.
    Inventors: Ronald Damian Myers, John Brenton MacLeod, Mainak Ghosh, Tapan Chakrabarty
  • Patent number: 6096191
    Abstract: A catalytic hydrocracking process wherein a hydrocarbonaceous feedstock and a liquid recycle stream having a temperature greater than about 500.degree. F. and saturated with hydrogen is contacted with hydrogen and a metal promoted hydrocracking catalyst in a hydrocracking reaction zone at elevated temperature and pressure to obtain conversion to lower boiling hydrocarbons. The resulting hot, uncooled effluent from the hydrocracking reaction zone is hydrogen stripped in a stripping zone maintained at essentially the same pressure as the hydrocracking zone to produce a first gaseous hydrocarbonaceous stream and a first liquid hydrocarbonaceous stream. At least a portion of the first gaseous hydrocarbonaceous stream is condensed to produce a second liquid hydrocarbonaceous stream and a second hydrogen-rich gaseous stream. At least a portion of the first liquid hydrocarbonaceous stream is recycled to the hydrocracking reaction zone.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: August 1, 2000
    Assignee: UOP LLC
    Inventor: Tom N. Kalnes
  • Patent number: 6045687
    Abstract: A catalyst support comprising at least one matrix, at least one Y zeolite with a lattice parameter which is in the range 24.15 .ANG. to 24.38 .ANG. (1 nm=10 .ANG.) and at least one Y zeolite with a lattice parameter of more than 24.38 .ANG. and less than or equal to 24.51 .ANG.. The invention also concerns a catalyst comprising said support and at least one hydro-dehydrogenating element, and a conventional hydroconversion process for petroleum cuts using said catalyst.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: April 4, 2000
    Assignee: Institut Francais du Petrole
    Inventors: Samuel Mignard, Nathalie George-Marchal, Eric Benazzi, Slavik Kasztelan
  • Patent number: 5989410
    Abstract: The invention relates to a process for improving the pour point of a feedstock that comprises paraffins of more than 10 carbon atoms, in which the feedstock that is to be treated is brought into contact with a catalyst that comprises the IM-5 zeolite and at least one hydro-dehydrogenating element, at a temperature of between 170 and 500.degree. C., a pressure of between 1 and 250 bar, and an hourly volume velocity of between 0.05 and 100 h.sup.-1, in the presence of hydrogen at a ratio of 50 to 2000 l/l of feedstock. The oils that are obtained have good pour points and high viscosity indices (VI). The process can also be applied to gas-oils and other feedstocks whose pour points need to be lowered.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: November 23, 1999
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Nathalie George-Marchal, Christophe Gueret, Patrick Briot, Alain Billon, Pierre Marion
  • Patent number: 5932088
    Abstract: The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which process the feed to be treated is brought into contact with a catalyst comprising NU-86 zeolite, preferably dealuminated, and at least one hydro-dehydrogenating element, at a temperature which is in the range 170.degree. C. to 500.degree. C., a pressure in the range 1 to 250 bar and an hourly space velocity in the range 0.05 to 100 h.sup.-1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed. The product from heavy feeds is fractionated to produce at least one cut including at least one middle distillate with a reduced pour point, and a residue including oil bases with a reduced pour point and a high viscosity index.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: August 3, 1999
    Assignee: Institut Fran.cedilla.ais du Petrole
    Inventors: Eric Benazzi, Nathalie George-Marchal
  • Patent number: 5853566
    Abstract: The present invention provides a catalyst composition, and a hydrocarbon conversion process in which it is used, comprising as first cracking component a zeolite beta having a silica to alumina molar ratio of at least 20 which is in the form of crystals less than 100 nm in size; a second cracking component selected from (i) crystalline molecular sieves having pores with diameters greater than 0.6 nm, (ii) crystalline, mesoporous aluminosilicates having pores with diameters of at least 1.3 nm, and (iii) clays; and at least one hydrogenation component.
    Type: Grant
    Filed: November 25, 1996
    Date of Patent: December 29, 1998
    Assignee: Shell Oil Company
    Inventors: Bettina Kraushaar-Czarnetzki, Johannes Wijnbelt
  • Patent number: 5851378
    Abstract: The invention relates to a hydrocracking catalyst containing at least one hydrogenation metal component, and particles of a cracking component of which at least 50% of the outer surface is coated with a layer of a pre-formed oxide, which layer has a thickness in the range of 10 nm to 5 .mu.m. The cracking component is either a zeolitic cracking component or an amorphous cracking component or a mixture of both. The particles may be coated with oxide by contacting uncoated particles having a mean particle size in the range of 0.1 to 10 .mu.m with an aqueous medium containing particles of the oxide to be provided as the coating having a particle size in the range of 10-5000 nm, with the ratio between the oxide particle size and the mean particle size of the cracking component particles being in the range of 0.001:1 to 0.5:1. The coating oxide is preferably alumina or silica/alumina.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: December 22, 1998
    Assignee: Akzo Nobel NV
    Inventors: Eelco Titus Carel Vogt, Hendrik Gerard Bruil
  • Patent number: 5846400
    Abstract: The present invention relates to new crystalline zeolite SSZ-42 prepared by processes for preparing crystalline molecular sieves, particularly large pore zeolites, using an organic templating agent selected from the group consisting of N-benzyl-1,4-diazabicyclo?2.2.2!octane cations and N-benzyl-1-azabicyclo?2.2.2!octane cations.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: December 8, 1998
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stacey I. Zones, Andrew Rainis
  • Patent number: 5804058
    Abstract: A process is disclosed for the catalytic dewaxing of a hydrocarbon oil feed comprising waxy molecules, which process comprises:contacting a feed under catalytic dewaxing conditions with a catalyst composition comprising a molecular sieve containing crystallites covalently bound alumina moieties in its framework and having pores with a diameter in the range of from 0.35 to 0.80 nm and recovering a product having a reduced pour point, wherein the molecular sieve has been modified to reduce the mole percentage of alumina by coating the surface of the crystallites with a refractory inorganic oxide which is essentially free of alumina.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: September 8, 1998
    Assignee: Shell Oil Company
    Inventors: Pierre Grandvallet, Laurent Georges Huve, Theodorus Ludovicus Michael Maesen
  • Patent number: 5762902
    Abstract: The invention concerns a composition comprising at least one matrix, at least one faujasite type zeolite and at least one TON type zeolite. The TON type zeolite can be Nu-10, THETA-1, KZ-2, or ISI-1. The catalyst also contains at least one hydrogenating element from groups VIII and VI.The catalyst is particularly for use for hydrocracking to maximize the yield of middle distillates (kerosine and gas oil).
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: June 9, 1998
    Assignee: Institut Francais du Petrole
    Inventors: Eric Benazzi, Samuel Mignard, Nathalie George-Marchal, Slavik Kasztelan
  • Patent number: 5730858
    Abstract: The wax-containing hydrocarbon feedstocks are pre-treated by contacting them with a homogeneous solution containing 1-5 vol. % of an acid diluted in an alcohol/water mixture (preferably containing 60-90 vol. % alcohol). The pre-treated feedstock is then contacted, in the presence of hydrogen, with at least two catalysts in sequence and with no intermediate separation, comprising at least one hydrodewaxing catalyst and one hydrocracking catalyst, to recover high-grade middle distillates.
    Type: Grant
    Filed: March 18, 1997
    Date of Patent: March 24, 1998
    Assignee: Fina Research, S.A.
    Inventors: Catherine Olivier, Jacques Grootjans
  • Patent number: 5656149
    Abstract: The present invention relates to new crystalline zeolite SSZ-41 which comprises oxides of (1) silicon or a mixture of silicon and germanium, and (2) zinc, said zinc being present in an amount from about 2 wt % to about 5 wt % of zinc metal based on the total weight of metals in said zeolite. Zeolite SSZ-41 may also optionally contain oxides of aluminum, iron, gallium or mixtures thereof. Zeolite SSZ-41 has the X-ray diffraction lines of Table I and has an argon adsorption capacity of at least about 0.06 cc/gm at 87.degree. K. Also disclosed are methods of making and using zeolite SSZ-41.
    Type: Grant
    Filed: May 21, 1996
    Date of Patent: August 12, 1997
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stacey I. Zones, Donald S. Santilli
  • Patent number: 5641393
    Abstract: A crystalline zeolite high-silica SSZ-37 is prepared using a N,N-dimethyl-4-azoniatricyclo [5.2.2.0.sup.(2,6) ] undec-8-ene cation as a template wherein said zeolite is used in hydrocarbon conversion processes.
    Type: Grant
    Filed: August 8, 1995
    Date of Patent: June 24, 1997
    Assignee: Chevron U.S.A. Inc.
    Inventor: Yumi Nakagawa
  • Patent number: 5603822
    Abstract: Raffinate is catalytically hydrodewaxed to lube basestock in a mixture containing between 0.01 and 1 weight percent of pour point depressants comprising the copolymer residue of a mixture of 1-alkene comonomers selected from the group consisting of C.sub.3 -C.sub.28 1-alkenes. The mixture is contacted with hydrogen and shape selective metallosilicate catalyst particles under mild hydrodewaxing conditions to produce an increased yield of lube basestock having a pour point below -25.degree. F. and viscosity index greater than 100.
    Type: Grant
    Filed: November 3, 1995
    Date of Patent: February 18, 1997
    Assignee: Mobil Oil Corporation
    Inventors: Thomas R. Forbus, Jr., David S. Shihabi
  • Patent number: 5500109
    Abstract: There is provided a method for preparing an alumina bound, zeolite catalyst, wherein a zeolite of low silanol content is used as the source of zeolite used to prepare the catalyst. A particular zeolite used in this catalyst is zeolite Y. This catalyst may be combined with at least one hydrogenation component and used to hydrocrack hydrocarbons, such as gas oils. In particular, an NiW/USY/alumina catalyst may be used in a hydrocracking reaction to produce distillate boiling range hydrocarbons from higher boiling hydrocarbons.
    Type: Grant
    Filed: October 17, 1994
    Date of Patent: March 19, 1996
    Assignee: Mobil Oil Corp.
    Inventors: Kathleen M. Keville, Hye K. C. Timken, Robert A. Ware