Silica Or Silicate Containing Catalyst Patents (Class 208/118)
  • Patent number: 6942784
    Abstract: Zeolite microsphere FCC catalysts having a novel morphology comprising a porous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. The catalysts are formed from microspheres containing a metakaolin and an alumina source other than kaolin having a high pore volume.
    Type: Grant
    Filed: February 3, 2004
    Date of Patent: September 13, 2005
    Assignee: Engelhard Corporation
    Inventors: David M. Stockwell, Stephen H. Brown, Ji-Yong Ryu
  • Patent number: 6930219
    Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 ? to about 30 ? and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2?. The catalyst is contacted with an organic feed under reaction conditions wherein the treating process is selected from alkylation, acylation, oligomerization, selective oxidation, hydrotreating, isomerization, demetalation, catalytic dewaxing, hydroxylation, hydrogenation, ammoximation, isomerization, dehydrogenation, cracking and adsorption.
    Type: Grant
    Filed: December 6, 2002
    Date of Patent: August 16, 2005
    Assignee: ABB Lummus Global Inc.
    Inventors: Zhiping Shan, Jacobus Cornelius Jansen, Chuen Y. Yeh, Philip J. Angevine, Thomas Maschmeyer, Mohamed S. Hamdy
  • Patent number: 6908544
    Abstract: The present invention relates to a cracking catalyst comprising layered clays and a process for cracking hydrocarbon oils using said catalyst. Said catalyst is prepared by the process comprising the following steps: mixing and slurrying an expandable clay, a modifier component, pseudo-boehmite and water for 0.1-10 h to obtain a slurry, aging the slurry at 50-85° C. for 0.1-10 h, then drying and forming the slurry to obtain a formed material, water washing and aging the solid, and finally drying and calcining the solid, and said modifier being one or more selected from the group consisting of hydroxyl polymers of silicon, aluminum, zirconium or titanium, and substances comprising one or more of said hydroxyl polymers.
    Type: Grant
    Filed: December 24, 2002
    Date of Patent: June 21, 2005
    Assignees: China Petroleum & Chemical Corporation, Research Institute of Petroleum Processing,
    Inventors: Zhiqing Yu, Zhijian Da, Zhenyu Chen, Enze Min, Jun Long, Caiying Li, Zhiqing Huang
  • Patent number: 6908602
    Abstract: Method for producing hydrogen and a hydroprocessed product from a hydrocarbonaceous feedstock by subjecting it to a catalytic hydrocracking treatment using hydrogen which has been at least partly produced from hydrocracked feedstock and subjecting at least pan of the hydrocracked feedstock, after having subjected it to a separation treatment in the event that hydroprocessed product is to be recovered, to a treatment to produce hydrogen in a single operation which hydrogen is at least partly recovered as product.
    Type: Grant
    Filed: May 9, 2000
    Date of Patent: June 21, 2005
    Assignee: Shell Oil Company
    Inventors: Johan Willem Gosselink, Michiel Jan Groeneveld, Andreas Karl Nowak, Antonius Adrianus Maria Roovers
  • Patent number: 6858129
    Abstract: There is provided a zeolite bound zeolite catalyst which does not contain significant amount of non-zeolitic binder and can be tailored to optimize its performance and a process for converting hydrocarbons utilizing the zeolite bound zeolite catalyst. The zeolite bound zeolite catalyst comprises core crystals containing first crystals of a first zeolite and optionally second crystals of a second zeolite having a composition, structure type, or both that is different from said first zeolite and binder crystals containing third crystals of a third zeolite and optionally fourth crystals of a fourth zeolite having a composition, structure type, or both that is different from said third zeolite. If the core crystals do not contain the second crystals of the second zeolite, then the binder crystals must contain the fourth crystals of the fourth zeolite. The zeolite bound zeolite finds application in hydrocarbon conversion processes, e.g.
    Type: Grant
    Filed: August 6, 2003
    Date of Patent: February 22, 2005
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Gary David Mohr, Kenneth Ray Clem, Wilfried Jozef Mortier, Machteld Maria Mertens, Xiaobing Feng, Marc H. Anthonis, Bart Schoofs
  • Patent number: 6776899
    Abstract: The present invention relates to a cracking catalyst composition comprising a physical mixture of 10-90 weight % of a cracking catalyst A and 90-10 weight % of a cracking catalyst B, whereby catalyst A is a zeolite-containing cracking catalyst, and catalyst B is a catalyst having a higher average pore volume in the pore diameter range of 20-200 Å than catalyst A in the same pore diameter range and not containing M41S material. These compositions can suitably used for the fluid catalytic cracking of hydrocarbon feeds with high metal concentrations.
    Type: Grant
    Filed: February 20, 2002
    Date of Patent: August 17, 2004
    Assignees: Akzo Nobel N.V., Petroleo Brasileiro S.A.
    Inventors: Yiu Lau Lam, Anselmo Da Silva Santos, Rodolfo Eugenio Roncolatto, Marcelo Andre Torem, Edisson Morgado, Jr., Paul O'Connor
  • Patent number: 6730208
    Abstract: Chips, and methods of manufacturing thereof, comprising a base having a surface, and a plurality of components integrated in the base. Each component is coupled to at least one individual electrode disposed on the surface and to a counter-electrode. Each component operates as an electric generator, when activated by a power supply external to the chip. The counter-electrode is disposed such that each activated component creates a polarization voltage and/or a polarization current between that at least one individual electrode and the counter-electrode, when a medium is brought into contact with the surface.
    Type: Grant
    Filed: November 26, 2001
    Date of Patent: May 4, 2004
    Assignee: Commissariat a l'Energie Atomique
    Inventor: Michel Bruel
  • Patent number: 6722618
    Abstract: A foldable support frame for supporting a cutting machine comprises two opposing pairs of leg frames each of which comprises a pair of first crossed legs and second crossed legs that are pivotally connected together. Where the first and second crossed legs cross, two stopper means are positioned for supporting each pair of the first and second crossed legs and limiting the inclination of each of the first and second crossed legs. Each first and second crossed leg comprises an upper slide rod and a support leg, and each slide rod can slide within a respective support leg to adjust the total length of each first and second crossed leg. Thus, the foldable support frame can be easily folded or retracted in for storage and transport and unfolded or extended for supporting the cutting machine or other similar machines.
    Type: Grant
    Filed: November 11, 2002
    Date of Patent: April 20, 2004
    Assignee: Chervon International Trading Co., Ltd.
    Inventor: Shuming Wu
  • Patent number: 6716338
    Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and optionally spinel, or mullite, or both spinel and mullite made via kaolin which has been calcined through its characteristic exotherm. Calcination of the hydrous clay to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: April 6, 2004
    Assignee: Engelhard Corporation
    Inventors: Rostam Madon, David H. Harris, Mingting Xu, David Stockwell, Bruce Lerner, Glenn W. Dodwell
  • Patent number: 6673235
    Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and a particular kaolin which has been calcined through its characteristic exotherm and which produces a catalyst having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. Calcination of the hydrous kaolin to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.
    Type: Grant
    Filed: June 6, 2002
    Date of Patent: January 6, 2004
    Assignee: Engelhard Corporation
    Inventors: David H. Harris, Mingting Xu, David Stockwell, Rostam J. Madon
  • Patent number: 6656345
    Abstract: The invention provides a method for converting a hydrocarbon feedstock to propylene comprising: contacting an olefinic hydrocarbon feedstock boiling in the naphtha range with a catalyst comprising a zeolitic catalyst selected from the group consisting of medium pore zeolites having a ratio of silica to alumina above 200 and pore diameter less than 0.7 nm under cracking conditions to selectively produce propylene. The preferred catalyst comprises of a zeolite having an 8, 10, or 12 membered ring pore structure. The preferred catalysts are selected from the group consisting of zeolites from the families MFI, MEL, MTW, TON, MTT, FER, MFS, and the zeolites ZSM-21, ZSM-38 and ZSM-48. Preferably the method is carried out to produce propylene with greater than 50% specificity, more preferably, the propylene to butylene ratio is at least 2:1 or a propylene to ethylene ratio of at least 4:1. The olefinic hydrocarbon feedstock consists essentially of hydrocarbons boiling within the range of 18° to 220° C.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: December 2, 2003
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Tan-Jen Chen, Mechilium (Marcel) Johannes Gerardus Janssen, Luc Roger Marc Martens, Machteld Maria Mertens, Philip Andrew Ruziska, Lynn L. Zhao, Jannetje Maatje van den Berge
  • Patent number: 6656347
    Abstract: Zeolite microsphere FCC catalysts having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. The catalysts are formed from microspheres containing a metakaolin and kaolin calcined through its exotherm, the latter calcined kaolin being derived from a kaolin having a high pore volume. Kaolin having a high pore volume can be a pulverized ultrafine kaolin or a kaolin which has been pulverized to have an incipient slurry point less than 57% solids.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: December 2, 2003
    Assignee: Engelhard Corporation
    Inventors: David M. Stockwell, Randall P. Brown, Stephen H. Brown
  • Patent number: 6646176
    Abstract: A process for the catalytic cracking of an olefin-containing feedstock which is selective towards light olefins in the effluent, the process comprising contacting a hydrocarbon feedstock containing at least one olefin with a MFI-type crystalline silicate catalyst having a silicon/aluminum atomic ratio of at least about 180, which has been obtained by pretreating so as to increase the silicon/aluminum atomic ratio thereof by heating the catalyst in steam and de-aluminating the catalyst by treating the catalyst with a complexing agent for aluminum, at an inlet temperature of from 500 to 600° C. and at an olefin partial pressure of from 0.1 to 2 bars to produce an effluent with an olefin content of lower molecular weight than that of the feedstock.
    Type: Grant
    Filed: December 5, 1998
    Date of Patent: November 11, 2003
    Assignee: Fina Research S.A.
    Inventors: Jean-Pierre Dath, Luc Delorme, Jacques-François Grootjans, Xavier Vanhaeren, Walter Vermeiren
  • Patent number: 6646175
    Abstract: A process for the catalytic cracking of at least one olefin in an olefinic stream containing impurities, the cracking process being selective towards light olefins in the effluent, the process comprising contacting a feedstock olefinic stream containing at least one sulphur-, nitrogen- and/or oxygen-derivative impurity with a crystalline silicate catalyst of the MFI-type, the catalyst having a silicon/aluminum atomic ratio of at least about 180, to produce an effluent stream having substantially the same olefinic content by weight as, but a different olefin distribution than, the feedstock stream.
    Type: Grant
    Filed: December 5, 1998
    Date of Patent: November 11, 2003
    Assignee: Fina Research S.A.
    Inventors: Jean-Pierre Dath, Luc Delorme, Jacques-François Grootjans, Xavier Vanhaeren, Walter Vermeiren
  • Publication number: 20030173254
    Abstract: A catalytic cracking process is disclosed for feedstock containing hydrocarbons having at least 5 carbon atoms. The feedstock is contacted, under catalytic cracking conditions, with a 9-member ring catalyst composition and, optionally, a large pore molecular sieve, such as zeolite Y.
    Type: Application
    Filed: November 4, 2002
    Publication date: September 18, 2003
    Inventors: Ten-Jen Chen, Paul F. Keusenkothen, John Scott Buchanan, Kirk D. Schmitt
  • Patent number: 6605207
    Abstract: A catalyst suitable for use in fluid catalytic cracking of petroleum feedstock in the form of particulate of crystalline zeolite having a coating on it6s surface comprising bayerite phase alumina.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: August 12, 2003
    Assignee: W. R. Grace & Co. - Conn.
    Inventors: Wu-Cheng Cheng, Xinjin Zhao, Philip Stephen Deitz
  • Publication number: 20030136707
    Abstract: A fluid catalytic cracking catalyst made from microspheres that initially contain kaolin, a dispersible boehmite alumina and a sodium silicate or silica sol binder. The kaolin portion contains hydrous kaolin and a particular kaolin which has been calcined through its characteristic exotherm and which produces a catalyst having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. Calcination of the hydrous kaolin to metakaolin and formation of in-situ zeolite by treatment with sodium silicate yields a catalyst containing Y-faujasite and transforms the dispersible boehmite into a transitional alumina. The catalyst can be used to crack resid or resid-containing feeds as the alumina phase formed from the dispersible boehmite passivates nickel and vanadium contaminants.
    Type: Application
    Filed: June 6, 2002
    Publication date: July 24, 2003
    Applicant: ENGELHARD CORPORATION
    Inventors: David H. Harris, Mingting Xu, David Stockwell, Rostam J. Madon
  • Publication number: 20030127358
    Abstract: The present invention provides a catalytic cracking reactor system and process in which a riser reactor is configured to have two sections of different radii in order to produced improved selectivity to propene and butenes as products.
    Type: Application
    Filed: January 10, 2002
    Publication date: July 10, 2003
    Inventor: Warren S. Letzsch
  • Patent number: 6562231
    Abstract: A composition comprises silicon, aluminum, zirconium, and boron. A process for producing the composition comprises contacting a silicon compound, an aluminum compound, a zirconium compound, and a boron compound under a condition sufficient to effect the production of a composition comprising silicon, aluminum, zirconium, and boron. Also disclosed is a process for catalytically cracking a hydrocarbon-containing fluid which comprises contacting said hydrocarbon-containing fluid with a catalyst composition which comprises silicon, aluminum, zirconium, and boron.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: May 13, 2003
    Assignee: ConocoPhillips Company
    Inventors: Lyle R. Kallenbach, Dwayne R. Senn
  • Patent number: 6538169
    Abstract: An FCC process for obtaining light olefins comprises contacting a hydrocarbon feed stream with blended catalyst comprising regenerated catalyst and coked catalyst. The catalyst has a composition including a first component and a second component. The second component comprises a zeolite with no greater than medium pore size wherein the zeolite comprises at least 1 wt-% of the catalyst composition. The contacting occurs in a riser to crack hydrocarbons in the feed stream and obtain a cracked stream containing hydrocarbon products including light olefins and coked catalyst. The cracked stream is passed out of an end of the riser such that the hydrocarbon feed stream is in contact with the blended catalyst in the riser for less than or equal to 2 seconds on average.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: March 25, 2003
    Assignee: UOP LLC
    Inventors: Rusty M. Pittman, Lawrence L. Upson
  • Patent number: 6495028
    Abstract: A process for catalytic conversion of hydrocarbon feedstock to produce isobutane and isoparaffin-enriched gasoline which comprises two different reactions, the preheated feedstock is contacted with hot regenerated catalyst in the lower part of a reactor with the result that catalytic cracking reaction takes place, and the mixture of vapors and the coke deposited catalyst are up-flowed and enter into a suitable reaction environment with the result that isomerization and hydrogen transfer reaction take place. The produced LPG has an isobutane content of about 20 wt % to about 40 wt % and the produced gasoline contains isoparaffin content of about 30 wt % to about 45 wt % and olefin content of less than 30 wt %. RON and MON of the gasoline are 90˜93 and 80˜84 respectively.
    Type: Grant
    Filed: April 21, 2000
    Date of Patent: December 17, 2002
    Assignees: China Petroleum Corporation, Research Institute of Petroleum Processing
    Inventors: Youhao Xu, Jiushun Zhang, Yinan Yang, Jun Long, Xieqing Wang, Zaiting Li, Raichi Zhang
  • Publication number: 20020179489
    Abstract: The present invention relates to a method for gas-solid contacting in a bubbling fluidized bed reactor by:
    Type: Application
    Filed: March 26, 2001
    Publication date: December 5, 2002
    Applicant: COUNCIL OF SCIENTIFIC & INDUSTRIAL RESEARCH
    Inventors: Vasant Ramchandra Choudhary, Tushar Vasant Choudhary
  • Patent number: 6489530
    Abstract: A process for producing polymers from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha feedstream is contacted in the reaction zone with a catalyst under catalytic conversion concditions. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone. A stream rich in C4 and/or C5 olefins is recycled to the stripping zone.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: December 3, 2002
    Assignee: Exxon Mobile Chemical Patents Inc.
    Inventor: Gordon F. Stuntz
  • Publication number: 20020170848
    Abstract: There is provided a process for converting hydrocarbons using a catalyst comprising macrostructures having a three-dimensional network of particles comprised of porous inorganic material. The particles of the macrostructures occupy less than 75% of the total volume of the macrostructures and are joined together to form a three-dimensional interconnected network comprised of pores having diameters greater than about 20 Å. The macrostructures can be made by forming an admixture containing a porous organic ion exchanger and a synthesis mixture capable of forming the porous inorganic material; converting the synthesis mixture to the porous inorganic material; and removing the porous organic ion exchanger from the inorganic material.
    Type: Application
    Filed: April 25, 2002
    Publication date: November 21, 2002
    Inventors: Gary David Mohr, Wilfried Jozef Mortier, Xiaobing Feng, Per Johan Sterte, Lubomira Borislavova Tosheva
  • Patent number: 6420621
    Abstract: A process for hydrocarbon conversion to prepare lower olefins such as ethylene, propylene, etc., and light aromatics by bringing hydrocarbons into contact with a solid granular catalyst. In order to optimize the reaction conditions and product structure and save the capital and operating costs, a piston flow reactor is used in this process and multiple groups of feed inlets, which allow hydrocarbons with different properties to enter the device from different feed inlets and proceed pyrolysis under different operation conditions, are set on the reactor. This process is usable for individual pyrolysis or co-feed pyrolysis of hydrocarbons from refinery gases, liquid hydrocarbons, to heavy residues.
    Type: Grant
    Filed: October 19, 1998
    Date of Patent: July 16, 2002
    Assignees: China Petro-Chemical Corp., Luoyang Petrochemical Engineering Corporation SINOPEC
    Inventors: Yingxun Sha, Zhongqiang Cui, Guoliang Wang, Mingdang Wang
  • Patent number: 6419819
    Abstract: This invention relates to a new synthetic porous crystalline material, designated MCM-67, a method for its preparation and use thereof in catalytic conversion of organic compounds. MCM-67 appears to be closely related in structure to VPI-8 and SSZ-41 but is synthesized without zinc and in the presence of manganese and/or cobalt ions.
    Type: Grant
    Filed: October 12, 2000
    Date of Patent: July 16, 2002
    Assignee: ExxonMobil Oil Corporation
    Inventors: Sandeep Singh Dhingra, Charles T. Kresge, Robin P. Ziebarth
  • Patent number: 6419891
    Abstract: This invention relates to a new synthetic crystalline material comprising acidic surface silanol groups, designated MCM-69, a method for its preparation and use thereof in catalytic conversion of organic compounds.
    Type: Grant
    Filed: October 18, 1999
    Date of Patent: July 16, 2002
    Assignee: ExxonMobil Oil Corporation
    Inventors: Carrie L. Kennedy, Gordon J. Kennedy, Stephen L. Lawton, Louis D. Rollmann, John L. Schlenker
  • Patent number: 6409911
    Abstract: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions and high catalytic cracking activity a method for their preparation and their use as FCC catalysts. More particularly, the new SAPOs have a high silica:alumina ratio and favorable Si atom distribution. The new SAPOs may have a small crystal size and may be synthesized from a single-phase synthesis solution.
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: June 25, 2002
    Assignee: ExxonMobil Chemical Patents, Inc.
    Inventors: Karl G. Strohmaier, David E. W. Vaughan, Tan Jen Chen, Philip A. Ruziska, Brian Erik Henry, Gordon F. Stuntz, Stephen M. Davis
  • Patent number: 6388161
    Abstract: A process for cracking an olefin-rich hydrocarbon feedstock which is selective towards propylene in the effluent, the process comprising contacting a hydrocarbon feedstock containing one or more olefinic components of C4 or greater with a crystalline silicate catalyst to produce an effluent having a second composition of one or more olefinic components of C3 or greater, the feedstock and the effluent having substantially the same olefin content by weight therein characterized in that ethylene is added to the feedstock before the feedstock contacts the catalyst.
    Type: Grant
    Filed: June 15, 2000
    Date of Patent: May 14, 2002
    Assignee: Fina Research, S.A.
    Inventors: Jean-Pierre Dath, Walter Vermeiren
  • Patent number: 6388152
    Abstract: A process for producing polymers from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500° to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: May 14, 2002
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Paul K. Ladwig, John E. Asplin, Gordon F. Stuntz, Tan-Jen Chen
  • Patent number: 6342153
    Abstract: Pillared clay catalysts for converting heavy oil or residual feedstock into maximum ethylene, propylene and butylene products comprises 30-75 wt % special pillared clays prepared by aluminum pillaring agents of high alkaline degree, 10-40 wt % inorganic oxide bonding agents, 0-30 wt % ZRP series high silicon zeolites with pentasil structure or Y-type zeolites, 0-10 wt % modified compositions of Mg, Al, K, P, Sn and polyethylene gycol, or 0-50 wt % Kaolinite matrix. The catalysts are prepared by mixing slurries, spray drying to form microspheric shapes, pillaring reaction and adding modified components. The catalysts have high catalytic activities, good light olefin selectivities and attrition resistance index.
    Type: Grant
    Filed: December 23, 1998
    Date of Patent: January 29, 2002
    Assignees: China Petrochemical Corporation, Research Institute of Petroleum Processing
    Inventors: Jingjie Guan, Xieqing Wang, Zhiqing Yu, Zhengyu Chen, Qinglin Liu, Yi Liao
  • Patent number: 6339180
    Abstract: A process for producing polypropylene from olefins selectively produced from a catalytically cracked or thermally cracked naphtha stream is disclosed herein. The naphtha stream is contacted with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures from about 500° C. to 650° C. and a hydrocarbon partial pressure from about 10 to 40 psia.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: January 15, 2002
    Assignee: ExxonMobil Chemical Patents, Inc.
    Inventors: Paul K. Ladwig, John E. Asplin, Gordon F. Stuntz, William A. Wachter, B. Erik Henry
  • Publication number: 20010056216
    Abstract: A process for hydrocarbon conversion to prepare lower olefins such as ethylene, propylene, etc., and light aromatics by bringing hydrocarbons into contact with a solid granular catalyst. In order to optimize the reaction conditions and product structure and save the capital and operating costs, a piston flow reactor is used in this process and multiple groups of feed inlets, which allow hydrocarbons with different properties to enter the device from different feed inlets and proceed pyrolysis under different operation conditions, are set on the reactor. This process is usable for individual pyrolysis or co-feed pyrolysis of hydrocarbons from refinery gases, liquid hydrocarbons, to heavy residues.
    Type: Application
    Filed: October 19, 1998
    Publication date: December 27, 2001
    Inventors: YINGXUN SHA, ZHONGQIANG CUI, GUOLIANG WANG, MINGDANG WANG
  • Patent number: 6319393
    Abstract: A modified alumina is useful as metals passivator in fluidizable catalytic cracking catalysts. The modified alumina is prepared from a hydrated alumina, e.g., gibbsite, which is reacted with a low-molecular weight organic acid, e.g., acetic acid, forming aluminum salts. Calcination of the modified alumina results in decomposition of the aluminum salt.
    Type: Grant
    Filed: March 27, 1995
    Date of Patent: November 20, 2001
    Assignee: Petroleo Brasiliero S.A., Petrobras
    Inventor: Jose Carlos Duarte Macedo
  • Patent number: 6288298
    Abstract: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions, a method for their preparation and their use as catalysts for the catalytic cracking of hydrocarbon feedstocks. More particularly, the new SAPOs have a high silica:alumina ratio, and are prepared from microemulsions containing surfactants.
    Type: Grant
    Filed: May 20, 1999
    Date of Patent: September 11, 2001
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Javier Agundez Rodriguez, Joaquin Perez Pariente, Antonio Chica Lara, Avelino Corma Canos, Tan Jen Chen, Philip A. Ruziska, Brian Erik Henry, Gordon F. Stuntz, Stephen M. Davis
  • Patent number: 6231751
    Abstract: A process for making a calcined, oxide material by at least partially delaminating a swollen, layered oxide material prior to calcination, and the product thereof having an increased active surface area that corresponds to an adsorption capacity for 1,3,5-trimethylbenzene of at least 0.50 mmol/g at a temperature of 42° C. and a pressure of 173.3 Pa. The calcined, oxide material retains a porous shape although non-pillared.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: May 15, 2001
    Assignee: Universidad Politecnica de Valencia
    Inventors: Avelino Corma Canos, Vicente Fornes Segui, Sibelle Berenice Castella Pergher
  • Patent number: 6225255
    Abstract: An additive catalyst for the cracking of heavy oil, characterized in that the additive catalyst includes: (i) a mixed metal oxide composed of an acidic metal oxide and a basic metal oxide, in which the proportion of the basic metal oxide is from 5 to 50 mole %, (ii) clay, and (iii) silica.
    Type: Grant
    Filed: June 8, 1998
    Date of Patent: May 1, 2001
    Assignee: Exxon Research and Engineering Company
    Inventors: Masato Shibasaki, Nobuo Ootake, Kaori Nakamura
  • Patent number: 6214211
    Abstract: A catalytic cracking catalyst composition comprising (a) a spherical boehmite gel alumina, (b) a zeolite, (c) a clay mineral and (d) a binder; a catalytic cracking catalyst produced by spray-drying a slurry containing the catalytic cracking catalyst composition to obtain a spherical catalyst, and then calcining the spherical catalyst; a method of catalytically cracking a heavy oil comprising catalytically cracking a heavy oil in the presence of the catalytic cracking catalyst.
    Type: Grant
    Filed: April 15, 1999
    Date of Patent: April 10, 2001
    Assignee: Idemitsu Kosan Co., LTD
    Inventor: Toshio Itoh
  • Patent number: 6210562
    Abstract: A catalytic pyrolysis process for production of ethylene and propylene from heavy hydrocarbons, comprises that heavy hydrocarbons are contacted with a pillared interlayered clay molecular sieve and/or phosphorus and aluminum or magnesium or calcium modified high silica zeolite having a structure of pentasil contained catalysts in a riser or downflow transfer line reactor in the presence of steam and catalytically pyrolysed at a temperature of 650° C. to 750° C. and a pressure of 0.15 to 0.4 MPa for a contact time of 0.2 to 5 seconds, a weight ratio of catalyst to feedstock of 15:1 to 40:1 and a weight ratio of steam to feedstock of 0.3:1 to 1:1. The yields of ethylene and propylene by the present invention are over 18 wt %.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: April 3, 2001
    Assignees: China Petrochemical Corporation, Research Institute of Petroleum Processing, SINOPEC
    Inventors: Chaogang Xie, Zaiting Li, Wenyuan Shi, Xieqing Wang
  • Publication number: 20010000066
    Abstract: Disclosed are silicoaluminophosphates (SAPOs) having unique silicon distributions, a method for their preparation and their use as catalysts for the catalytic cracking of hydrocarbon feedstocks. More particularly, the new SAPOs have a high silica:alumina ratio, and are prepared from microemulsions containing surfactants.
    Type: Application
    Filed: November 30, 2000
    Publication date: March 29, 2001
    Inventors: Javier Agundez Rodriguez, Joaquin Perez Pariente, Antonio Chica Lara, Avelino Corma Canos, Tan Jen Chen, Philip A. Ruziska, Brian Erik Henry, Gordon F. Stuntz, Stephen M. Davis
  • Patent number: 6200464
    Abstract: An FCC catalyst containing zeolite particles at least 50% of the outer surface of which is coated with a layer of pre-formed inorganic oxide is used in fluidized catalytic cracking of hydrocarbon feeds. The inorganic oxide layer has a thickness in the range of 10 nm to 5 &mgr;m and the ratio between the particle size of the oxide and the mean particle size of the zeolite particles is in the range of 0.001:1 to 0.5:1. The zeolite particles may be coated by contacting uncoated zeolite particles having a mean particle size in the range of 0.1 to 10 &mgr;m with an aqueous medium containing particles of the oxide having a particle size in the range of 10 to 5,000 nm, after which the particles are optionally dried or calcined. The oxide is preferably alumina. The FCC catalysts are less rapidly deactivated by contaminant metals present in heavy feeds and are less susceptible to blocking of the zeolite pores by coke.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: March 13, 2001
    Assignee: Akzo Nobel N.V.
    Inventors: Franciscus Wilhelmus van Houtert, Hendrik Gerard Bruil, Johannes Ebregt, Nicolaas Gerardus Bader
  • Patent number: 6172273
    Abstract: A composition is prepared by a method which comprises mixing a first solid material comprising a platinum group metal, a rhenium component, a porous carrier material and, optionally, a halogen component and a second solid material comprising silica and bismuth. The thus-obtained composition is employed as a catalyst in the conversion of hydrocarbons to aromatics. In an alternate embodiment, hydrocarbons are converted to aromatics by sequentially contacting the hydrocarbons with the first solid material and then the second solid material.
    Type: Grant
    Filed: February 23, 2000
    Date of Patent: January 9, 2001
    Assignee: Phillips Petroleum Company
    Inventors: An-hsiang Wu, Charles A. Drake
  • Patent number: 6165351
    Abstract: A silica-containing bayerite alumina is prepared by reacting aluminum sulfate, sodium aluminate and sodium silicate at a pH of about 10.5 to 11.5, preferably in the presence of finely divided magnesium hydroxide "seeds". The silica-containing bayerite is heated to obtain a hydrothermally stable silica "stabilized" eta alumina which may be used in the preparation of catalytic compositions.
    Type: Grant
    Filed: February 23, 1994
    Date of Patent: December 26, 2000
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Norman Raymond Laine, John Allen Rudesill, Wu-Cheng Cheng
  • Patent number: 6165349
    Abstract: The nature of the process consists in that the low-grade organic substances are subject, at a temperature of 150.degree. C. to 700.degree. C. and at a pressure of 0.1 MPa to 2.5 MPa, to the action of a moving bed of solid particles of a substance which perform whirling motion, whereby the solid particles of a substance constituting the moving bed are set to whirling motion by intensive agitation.The device consists of a reaction chamber (1) with a rotation mechanism (2) which rotation mechanism (2), located rotably in the faces of the reaction chamber (1), consists of a shaft (3) to which vanes (5) are symetrically attached by means of driving discs (4). The vanes (5) may be arranged in 3 to 10 rows, and they may be provided with openings (5.1) or cut-outs (5.2) of various geometrical shapes, and they may be divided into individual segments (5.3). Also the driving discs (4) may be provided with openings (4.1) of various geometrical shapes.
    Type: Grant
    Filed: June 1, 1999
    Date of Patent: December 26, 2000
    Inventor: Ivan Madar
  • Patent number: 6160191
    Abstract: A process for converting hydrocarbons by contacting a hydrocarbon feedstream under hydrocarbon conversion conditions with a large crystal zeolite catalyst. The large crystal zeolite of the catalyst used in the hydrocarbon conversion process is made by heating an aqueous zeolite synthesis mixture under agitation to a temperature equal to or less than the effective nucleation temperature of the synthesis mixture. After this step, the aqueous synthesis mixture is heated in the absence of agitation to a temperature equal to or greater than the effective nucleation temperature of the aqueous zeolite synthesis mixture. The process finds particular application in hydrocarbon conversion processes where reduced non-selective acidity is important for reaction selectivity and/or the maintenance of catalyst activity, e.g., toluene disproportionation, dealkylation, alkylation, and transalkylation.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: December 12, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Robert Scott Smith, Johannes Petrus Verduijn, deceased, by Jannetje Maatje van den Berge, executrix, Gary David Mohr, Thomas Herman Colle
  • Patent number: 6139721
    Abstract: The invention relates to a fluid catalytic cracking process for the preparation of good quality hydrocarbon fractions with a high octane number starting from heavy hydrocarbon fractions of a poorer quality characterized in that the heavy hydrocarbon fraction is put in contact, under cracking conditions, with a catalytic composition comprising a conventional FCC catalyst and a quantity of between 3-60% of a hydrothermally stable microporous material containing titanium.
    Type: Grant
    Filed: March 17, 1998
    Date of Patent: October 31, 2000
    Assignee: Agip Petroli S.p.A.
    Inventors: Franco Baldiraghi, Paolo Ferrarini, Giovanni Faraci, Mario Lorenzo Occelli, Sergio Leoncini
  • Patent number: 6093867
    Abstract: A process for selectively producing C.sub.3 olefins from a catalytically cracked or thermally cracked naphtha stream. The naphtha stream is introduced into a process unit comprised of a reaction zone, a stripping zone, a catalyst regeneration zone, and a fractionation zone. The naphtha feedstream is contacted in the reaction zone with a catalyst containing from about 10 to 50 wt. % of a crystalline zeolite having an average pore diameter less than about 0.7 nanometers at reaction conditions which include temperatures ranging from about 500.degree. to 650.degree. C. and a hydrocarbon partial pressure from about 10 to 40 psia. Vapor products are collected overhead and the catalyst particles are passed through the stripping zone on the way to the catalyst regeneration zone. Volatiles are stripped with steam in the stripping zone and the catalyst particles are sent to the catalyst regeneration zone where coke is burned from the catalyst, which is then recycled to the reaction zone.
    Type: Grant
    Filed: May 5, 1998
    Date of Patent: July 25, 2000
    Assignee: Exxon Research and Engineering Company
    Inventors: Paul K. Ladwig, John Ernest Asplin, Gordon F. Stuntz, Tan-Jen Chen
  • Patent number: 6090271
    Abstract: The invention provides a process for improving the conversion of a hydrocarbon feedstock to light olefins comprising mixing a hydrocarbon feedstock with a diolefin to form a mixture; and thereafter contacting the mixture with a zeolite cracking catalyst. Preferably the catalyst is contacted at a reaction temperature within the range of about 500.degree. C. to about 750.degree. C. and the feedstock flows at a weight hourly space velocity in the range of about 0.1 Hr.sup.-1 WHSV to about 100 Hr.sup.-1 WHSV. The diolefin can be a straight, branched, or cyclic hydrocarbon having at least two II bonds. Preferably diolefin is a hydrocarbon of 4 to 20 carbons.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: July 18, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Joseph Francis Carpency, Tan-Jen Chen, Shun Chong Fung, Andrew Brennek
  • Patent number: 6090272
    Abstract: A process for producing catalyst compositions for converting a cracked gasoline feedstock to a product comprising incremental aromatics and lower olefins. The catalyst compositions produced thereby. A process for converting a cracked gasoline feedstock to a product comprising incremental aromatics and lower olefins.
    Type: Grant
    Filed: December 28, 1998
    Date of Patent: July 18, 2000
    Assignee: Phillips Petroleum Company
    Inventors: Charles A. Drake, An-hsiang Wu
  • Patent number: 6063263
    Abstract: A particular arrangement of an FCC unit creates an immediate and sustained gravity separation of catalyst and hydrocarbon vapors in short contact time cracking operation. A transverse feed contactor ejects the mixture of catalyst and hydrocarbon vapors transversely into a central portion of a separation vessel for vertical disengagement of catalyst from vapors. The vapors travel upwardly in the vessel into an inertial separator that quickly segregates entrained catalyst from the hydrocarbon vapors and collects separated catalyst at a higher elevation for stripping of adsorbed hydrocarbons from the catalyst.
    Type: Grant
    Filed: March 16, 1999
    Date of Patent: May 16, 2000
    Assignee: UOP LLC
    Inventor: Paolo Palmas