Gate Comprising Layer With Ferroelectric Properties (epo) Patents (Class 257/E21.436)
  • Patent number: 11424253
    Abstract: An illustrative device disclosed herein includes a semiconductor substrate. The substrate includes a source region, a drain region and a channel region. The channel region is arranged between the source region and the drain region. A gate insulation layer is provided over the channel region. A floating gate electrode is provided over the gate insulation layer. A layer of a ferroelectric material is provided over the floating gate electrode. A top electrode is provided over the layer of ferroelectric material. A projected area of the top electrode onto a plane that is perpendicular to a thickness direction of the semiconductor substrate is smaller than a projected area of the floating gate electrode onto the plane.
    Type: Grant
    Filed: January 8, 2018
    Date of Patent: August 23, 2022
    Assignees: NaMLab gGmbH, Fraunhofer-Gesellschaft zur Foerderung der angewandten Forschung e.V.
    Inventors: Johannes Mueller, Stefan Mueller, Stefan Flachowsky
  • Patent number: 10707319
    Abstract: A method of manufacturing a semiconductor device and a novel semiconductor device are disclosed herein. An exemplary method includes sputtering a capping layer in-situ on a gate dielectric layer, before any high temperature processing steps are performed. The method includes depositing a dielectric layer on a substrate, followed by deposition of a capping layer in-situ over the dielectric layer prior to any high temperature processing.
    Type: Grant
    Filed: March 10, 2016
    Date of Patent: July 7, 2020
    Assignee: Intel Corporation
    Inventors: Gilbert Dewey, Mark L. Doczy, Suman Datta, Justin K. Brask, Matthew V. Metz
  • Patent number: 8822234
    Abstract: A method of fabricating a miniaturized semiconductor device so as to form MTJ elements therein include the steps of depositing a magnetic tunnel junction (MTJ) precursor layer on a substrate and planarizing the precursor layer; forming a sacrificial and patternable dielectric layer on the MTJ precursor layer; patterning the sacrificial dielectric layer in accordance with predetermined placements and shapes of a to-be-formed hard mask, the patterning forming corresponding openings in the sacrificial dielectric layer; depositing an etch-resistant conductive material such as Cu in the openings for example by way of plating, and selectively removing the sacrificial dielectric layer so as to leave behind the etch-resistant conductive material in the form of a desired hard mask. Using the hard mask to etch and thus pattern the MTJ precursor layer so as to form MTJ elements having desired locations, sizes and shapes.
    Type: Grant
    Filed: December 20, 2012
    Date of Patent: September 2, 2014
    Assignees: Semiconductor Manufacturing International (Beijing) Corporation
    Inventors: Xinpeng Wang, Haiyang Zhang
  • Patent number: 8809971
    Abstract: A semiconductor component comprising a semiconductor body, a channel zone in the semiconductor body, a channel control electrode adjacent to the channel zone, and a dielectric layer between the channel zone and the channel control electrode, wherein the dielectric layer has a relative dielectric constant ?r with a negative temperature coefficient.
    Type: Grant
    Filed: August 23, 2010
    Date of Patent: August 19, 2014
    Assignee: Infineon Technologies Austria AG
    Inventors: Hans-Joachim Schulze, Frank Pfirsch
  • Patent number: 8748957
    Abstract: A coherent spin field effect transistor is provided by depositing a ferromagnetic base like cobalt on a substrate. A magnetic oxide layer is formed on the cobalt by annealing at temperatures on the order of 1000° K to provide a few monolayer thick layer. Where the gate is cobalt, the resulting magnetic oxide is Co3O4(111). Other magnetic materials and oxides may be employed. A few ML field of graphene is deposited on the cobalt (III) oxide by molecular beam epitaxy, and a source and drain are deposited of base material. The resulting device is scalable, provides high on/off rates, is stable and operable at room temperature and easily fabricated with existing technology.
    Type: Grant
    Filed: January 5, 2012
    Date of Patent: June 10, 2014
    Assignee: Quantum Devices, LLC
    Inventors: Jeffry Kelber, Peter Dowben
  • Patent number: 8729614
    Abstract: The present disclosure relates to a flexible nonvolatile ferroelectric memory device, a 1T-1R (1Transistor-1Resistor) flexible ferroelectric memory device, and a manufacturing method for the same.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: May 20, 2014
    Assignee: Sungkyunkwan University Foundation for Corporate Collaboration
    Inventors: Jong-Hyun Ahn, Jonghyun Rho
  • Patent number: 8698218
    Abstract: A magnetoresistive memory element has a free layer, and a write current path aligned with a free layer plane. The memory element has a pinned layer with a magnetization direction aligned with that of the free layer. A barrier layer is disposed between the free layer and the pinned layer. The free, barrier and pinned layers together form a layer stack that has a read current path that extends through the layer stack and that is not aligned with the write current path in the free layer.
    Type: Grant
    Filed: October 13, 2010
    Date of Patent: April 15, 2014
    Assignee: Seagate Technology LLC
    Inventor: Mark William Covington
  • Publication number: 20130175588
    Abstract: A coherent spin field effect transistor is provided by depositing a ferromagnetic base like cobalt on a substrate. A magnetic oxide layer is formed on the cobalt by annealing at temperatures on the order of 1000° K to provide a few monolayer thick layer. Where the gate is cobalt, the resulting magnetic oxide is Co3O4 (111). Other magnetic materials and oxides may be employed. A few ML field of graphene is deposited on the cobalt (III) oxide by molecular beam epitaxy, and a source and drain are deposited of base material. The resulting device is scalable, provides high on/off rates, is stable and operable at room temperature and easily fabricated with existing technology.
    Type: Application
    Filed: January 5, 2012
    Publication date: July 11, 2013
    Applicant: QUANTUM DEVICES CORP.
    Inventors: JEFFRY KELBER, PETER DOWBEN
  • Patent number: 8476721
    Abstract: A transistor device includes a magnetic field source adapted to deflect a flow of free electron carriers within a channel of the device, between a source region and a drain region thereof. According to preferred configurations, the magnetic field source includes a magnetic material layer extending over a side of the channel that is opposite a gate electrode of the transistor device.
    Type: Grant
    Filed: April 18, 2011
    Date of Patent: July 2, 2013
    Assignee: Seagate Technology LLC
    Inventors: Yang Li, Insik Jin, Harry Liu, Song S. Xue, Shuiyuan Huang, Michael X. Tang
  • Patent number: 8455935
    Abstract: A ferroelectric film comprising polyaminodifluoroborane (PADFB). Also a memory device utilizing the ferroelectric film, a method of fabricating a ferroelectric polymer and a ferroelectric solution.
    Type: Grant
    Filed: May 29, 2009
    Date of Patent: June 4, 2013
    Assignees: Sony Corporation, Agency for Science, Technology, and Research
    Inventors: Takehisa Ishida, Sunil Madhukar Bhangale, Han Hong, Christina Li Lin Chai
  • Patent number: 8361858
    Abstract: The growth rate in a selective epitaxial growth process for depositing a threshold adjusting semiconductor alloy, such as a silicon/germanium alloy, may be enhanced by performing a plasma-assisted etch process prior to performing the selective epitaxial growth process. For example, a mask layer may be patterned on the basis of the plasma-assisted etch process, thereby simultaneously providing superior device topography during the subsequent growth process. Hence, the threshold adjusting material may be deposited with enhanced thickness uniformity, thereby reducing overall threshold variability.
    Type: Grant
    Filed: January 25, 2010
    Date of Patent: January 29, 2013
    Assignee: Advanced Micro Devices, Inc.
    Inventors: Stephan Kronholz, Andreas Naumann, Gunda Beernink
  • Publication number: 20120056253
    Abstract: A semiconductor memory device according to the present embodiment includes a semiconductor substrate, a select transistor, a lower electrode, a magnetic tunnel junction element, a first protection film, an upper electrode, and a second protection film. The select transistor is formed on the semiconductor substrate. The lower electrode is electrically connected to one diffusion layer of the select transistor. The magnetic tunnel junction element is provided on the lower electrode. The first protection film is provided on a side surface of the magnetic tunnel junction element. The upper electrode is provided on the magnetic tunnel junction element and the first protection film. The second protection film is provided on side surfaces of the upper electrode, the first protection film, and the lower electrode.
    Type: Application
    Filed: November 10, 2010
    Publication date: March 8, 2012
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Masayoshi IWAYAMA, Hiroyuki Kanaya
  • Publication number: 20110316059
    Abstract: The present disclosure relates to a flexible nonvolatile ferroelectric memory device, a 1T-1R (1Transistor-1Resistor) flexible ferroelectric memory device, and a manufacturing method for the same.
    Type: Application
    Filed: May 25, 2011
    Publication date: December 29, 2011
    Applicant: Sungkyunkwan University Foundation for Corporate Collaboration
    Inventors: Jong-Hyun Ahn, Jonghyun Rho
  • Publication number: 20110207279
    Abstract: Provided is a high-k metal gate structure formed over a semiconductor fin. A nitride layer is formed over the gate structure and the semiconductor fin, using two separate deposition operations, the first forming a very thin nitride film. Implantation operations such as an LDD or a PKT implant, are carried out in between the two nitride film deposition operations. The first nitride film may be SiNx or SiCNx and the second nitride film is SiCNx with a low wet etch rate in H3PO4 and dilute HF acid. The nitride films may be combined to form low wet etch rate spacers enabling further processing operations to be carried out without damaging underlying structures and without requiring the formation of further dummy spacers. Further processing operations include epitaxial silicon/SiGe processing sequences and source/drain implanting operations carried out with the low etch rate spacers intact.
    Type: Application
    Filed: February 25, 2010
    Publication date: August 25, 2011
    Applicant: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
    Inventors: Chia-Pin LIN, Wen-Sheh HUANG, Tian-Choy GAN, Chia-Lung HUNG, Hsien-Chin LIN, Shyue-Shyh LIN
  • Patent number: 7932547
    Abstract: A nonvolatile ferroelectric memory device using a silicon substrate includes an insulating layer formed in an etching region of the silicon substrate, a bottom word line formed in the insulating layer so as to be enclosed by the insulating layer, a floating channel layer formed over the bottom word line, an impurity layer formed at both ends of the floating channel layer and including a source region formed over the insulating layer and a drain region formed over the silicon substrate, a ferroelectric layer formed over the floating channel layer, and a word line formed over the ferroelectric layer.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: April 26, 2011
    Assignee: Hynix Semiconductor Inc.
    Inventor: Hee Bok Kang
  • Patent number: 7825445
    Abstract: A magnetoresistive memory element has a free layer, and a write current path aligned with a free layer plane. The memory element has a pinned layer with a magnetization direction aligned with that of the free layer. A barrier layer is disposed between the free layer and the pinned layer. The free, barrier and pinned layers together form a layer stack that has a read current path that extends through the layer stack and that is not aligned with the write current path in the free layer.
    Type: Grant
    Filed: November 29, 2007
    Date of Patent: November 2, 2010
    Assignee: Seagate Technology LLC
    Inventor: Mark William Covington
  • Patent number: 7816150
    Abstract: A method for fabricating a semiconductor device includes the steps of forming a first ferroelectric film over a lower electrode, crystallizing the first ferroelectric film, forming a second ferroelectric film in an amorphous state over the first ferroelectric film so as to fill voids existing on a surface of the first ferroelectric film, and forming an upper electrode over the second ferroelectric film of the amorphous state, wherein the crystallizing step of the first ferroelectric film is conducted by a thermal annealing process at a temperature of 585° C. or higher.
    Type: Grant
    Filed: November 1, 2007
    Date of Patent: October 19, 2010
    Assignee: Fujitsu Semiconductor Limited
    Inventor: Ko Nakamura
  • Patent number: 7759713
    Abstract: A tunneling element includes a thin film layer of ferroelectric material and a pair of dissimilar electrically-conductive layers disposed on opposite sides of the ferroelectric layer. Because of the dissimilarity in composition or construction between the electrically-conductive layers, the electron transport behavior of the electrically-conductive layers is polarization dependent when the tunneling element is below the Curie temperature of the layer of ferroelectric material. The element can be used as a basis of compact 1R type non-volatile random access memory (RAM). The advantages include extremely simple architecture, ultimate scalability and fast access times generic for all ferroelectric memories.
    Type: Grant
    Filed: March 6, 2006
    Date of Patent: July 20, 2010
    Assignee: UT-Battelle, LLC
    Inventors: Sergei V. Kalinin, Hans M. Christen, Arthur P. Baddorf, Vincent Meunier, Ho Nyung Lee
  • Publication number: 20100178715
    Abstract: An MRAM is disclosed that has a MTJ comprised of a ferromagnetic layer with a magnetization direction along a first axis, a super-paramagnetic (SP) free layer, and an insulating layer formed therebetween. The SP free layer has a remnant magnetization that is substantially zero in the absence of an external field, and in which magnetization is roughly proportional to an external field until reaching a saturation value. In one embodiment, a separate storage layer is formed above, below, or adjacent to the MTJ and has uniaxial anisotropy with a magnetization direction along its easy axis which parallels the first axis. In a second embodiment, the storage layer is formed on a non-magnetic conducting spacer layer within the MTJ and is patterned simultaneously with the MTJ. The SP free layer may be multiple layers or laminated layers of CoFeB. The storage layer may have a SyAP configuration and a laminated structure.
    Type: Application
    Filed: March 16, 2010
    Publication date: July 15, 2010
    Inventors: Po-Kang Wang, Yimin Guo, Cheng T. Horng, Tai Min, Ru-Ying Tong
  • Publication number: 20100176427
    Abstract: A method of manufacturing a semiconductor device. The method comprises fabricating a ferroelectric capacitor. The capacitor's fabrication includes forming conductive and ferroelectric material layers on a semiconductor substrate, forming a hardmask layer on the conductive and ferroelectric material layers, forming an organic bottom antireflective coating layer on the hardmask layer, and, patterning the organic bottom antireflective coating layer. Seasoning in a hardmask etching chamber is substantially unaffected by the patterning.
    Type: Application
    Filed: January 13, 2009
    Publication date: July 15, 2010
    Applicant: Texas Instruments Incorporated
    Inventor: Francis Gabriel Celii
  • Patent number: 7645617
    Abstract: A nonvolatile ferroelectric memory device using a silicon substrate includes an insulating layer formed in an etching region of the silicon substrate, a floating channel layer formed over the bottom word line, an impurity layer formed at both ends of the floating channel layer and including a source region formed over the insulating layer and a drain region formed over the silicon substrate, a ferroelectric layer formed over the floating channel layer, and a word line formed over the ferroelectric layer.
    Type: Grant
    Filed: March 14, 2007
    Date of Patent: January 12, 2010
    Assignee: Hynix Semiconductor, Inc.
    Inventor: Hee Bok Kang
  • Patent number: 7605436
    Abstract: A method contains the steps of (a) heating a silicon substrate in a reaction chamber; and (b) supplying film-forming gas containing source gas, nitridizing gas, and nitridation enhancing gas to a surface of the heated silicon substrate, to deposit on the silicon substrate an Hf1-xAlxO:N film (0.1<x<0.3) having a higher specific dielectric constant than that of silicon oxide, and incorporating N, by thermal CVD. The method can form an oxide film of Hf1-xAlxO (0<x<0.3) having desired characteristics, as a gate insulation film.
    Type: Grant
    Filed: July 3, 2008
    Date of Patent: October 20, 2009
    Assignee: Fujitsu Limited
    Inventor: Masaomi Yamaguchi
  • Patent number: 7524727
    Abstract: A method of manufacturing a semiconductor device and a novel semiconductor device are disclosed herein. An exemplary method includes sputtering a capping layer in-situ on a gate dielectric layer, before any high temperature processing steps are performed.
    Type: Grant
    Filed: December 30, 2005
    Date of Patent: April 28, 2009
    Assignee: Intel Corporation
    Inventors: Gilbert Dewey, Mark L. Doczy, Suman Datta, Justin K. Brask, Matthew V. Metz
  • Patent number: 7517702
    Abstract: A method for making an electronic device may include forming a poled superlattice comprising a plurality of stacked groups of layers and having a net electrical dipole moment. Each group of layers of the poled superlattice may include a plurality of stacked semiconductor monolayers defining a base semiconductor portion and at least one non-semiconductor monolayer thereon. The at least one non-semiconductor monolayer may be constrained within a crystal lattice of adjacent base semiconductor portions, and at least some semiconductor atoms from opposing base semiconductor portions may be chemically bound together through the at least one non-semiconductor monolayer therebetween. The method may further include coupling at least one electrode to the poled superlattice.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: April 14, 2009
    Assignee: MEARS Technologies, Inc.
    Inventors: Samed Halilov, Xiangyang Huang, Ilija Dukovski, Jean Augustin Chan Sow Fook Yiptong, Robert J. Mears, Marek Hytha, Robert John Stephenson
  • Patent number: 7449346
    Abstract: A method of manufacturing a ferroelectric thin film with good crystallinity and improved surface roughness includes: forming on a substrate a metal nitride-based precursor layer containing one selected from the group consisting of TiN, ZrxTi(1-x)N (0<x<1), FeN, and NbN; forming on the metal nitride-based precursor layer a mixed gas atmosphere containing oxygen (O2) and one reactive gas selected from the group consisting of PbO(g), Bi2O3(g), and K2O(g); annealing the metal nitride-based precursor layer in the mixed gas atmosphere and forming a ferroelectric thin film containing one selected from the group consisting of PbTiO3, PbZrxTi(1-x)O3 (0<x<1), Bi2Ti2O7, Bi4Ti3O12, BiFeO3, and KNbO3.
    Type: Grant
    Filed: September 8, 2006
    Date of Patent: November 11, 2008
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Simon Buehlmann
  • Patent number: 7432150
    Abstract: A method of manufacturing a magnetoelectronic device includes providing an electrically conducting material and an electrically insulating material adjacent to at least a portion of the electrically conducting material, and implanting a magnetic material into the electrically insulating material. The magnetic material increases the magnetic permeability of the electrically insulating material. The implant may be a blanket or a targeted implant.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: October 7, 2008
    Assignee: EverSpin Technologies, Inc.
    Inventors: Mark A. Durlam, Gloria J. Kerszykowski, Nicholas D. Rizzo, Eric J. Salter, Loren J. Wise
  • Patent number: 7410812
    Abstract: A method contains the steps of (a) heating a silicon substrate in a reaction chamber; and (b) supplying film-forming gas containing source gas, nitridizing gas, and nitridation enhancing gas to a surface of the heated silicon substrate, to deposit on the silicon substrate an Hf1-xAlxO:N film (0.1<x<0.3) having a higher specific dielectric constant than that of silicon oxide, and incorporating N, by thermal CVD. The method can form an oxide film of Hf1-xAlxO (0<x<0.3) having desired characteristics, as a gate insulation film.
    Type: Grant
    Filed: March 25, 2005
    Date of Patent: August 12, 2008
    Assignee: Fujitsu Limited
    Inventor: Masaomi Yamaguchi
  • Patent number: 7390679
    Abstract: A method for manufacturing a ferroelectric capacitor, includes the steps of: forming a ferroelectric capacitor layer having a lower electrode layer, a ferroelectric layer and an upper electrode layer on a base substrate; forming a titanium oxide layer on the ferroelectric capacitor layer; patterning the titanium oxide layer by high-temperature etching between 200° C. and 500° C. to thereby form a mask pattern; and etching the ferroelectric capacitor layer by using the mask pattern as a mask, to thereby form a ferroelectric capacitor having a lower electrode, a ferroelectric film and an upper electrode.
    Type: Grant
    Filed: March 1, 2007
    Date of Patent: June 24, 2008
    Assignee: Seiko Epson Corporation
    Inventor: Mamoru Miyaji
  • Patent number: 7329548
    Abstract: A method of fabricating a conductive metal oxide gate ferroelectric memory transistor includes forming an oxide layer a substrate and removing the oxide layer in a gate area; depositing a conductive metal oxide layer on the oxide layer and on the exposed gate area; depositing a titanium layer on the metal oxide layer; patterning and etching the titanium layer and the metal oxide layer to remove the titanium layer and the metal oxide layer from the substrate except in the gate area; depositing, patterning and etching an oxide layer to form a gate trench; depositing and etching a barrier insulator layer to form a sidewall barrier in the gate trench; removing the titanium layer from the gate area; depositing, smoothing and annealing a ferroelectric layer in the gate trench; depositing, patterning and etching a top electrode; and completing the conductive metal oxide gate ferroelectric memory transistor.
    Type: Grant
    Filed: August 30, 2005
    Date of Patent: February 12, 2008
    Assignee: Sharp Laboratories of America, Inc.
    Inventors: Tingkai Li, Sheng Teng Hsu, Bruce D. Ulrich
  • Patent number: 7291530
    Abstract: A method of manufacturing a semiconductor storage device having a capacitive element having a dielectric layer having a perovskite-type crystal structure represented by general formula ABO3 and a lower electrode and an upper electrode disposed so as to sandwich the dielectric layer therebetween; in the method are carried out forming, on a lower electrode conductive layer, using a MOCVD method, an initial nucleus containing at least one metallic element the same as a metallic element in the dielectric layer, forming, on the initial nucleus, using a MOCVD method, a buffer layer containing at least one metallic element the same as the metallic element contained in both the initial nucleus and the dielectric layer, in a higher content than the content of this metallic element contained in the initial nucleus, and forming, on the buffer layer, using a MOCVD method, the dielectric layer having a perovskite-type crystal structure.
    Type: Grant
    Filed: August 12, 2005
    Date of Patent: November 6, 2007
    Assignee: NEC Electronics Corporation
    Inventors: Takashi Nakagawa, Takashi Hase
  • Publication number: 20070228432
    Abstract: The invention relates to a semiconductor element used for a nonvolatile semiconductor storage device or the like, a semiconductor storage device using the same, a data writing method thereof, a data reading method thereof and a manufacturing method of those, and has an object to provide a semiconductor element in which scaling and integration of cells are possible, storage characteristics of data are excellent, and reduction in power consumption is possible, a semiconductor storage device using the same, a data writing method thereof, a data reading method thereof, and a manufacturing method of those.
    Type: Application
    Filed: January 9, 2007
    Publication date: October 4, 2007
    Applicant: FUJITSU LIMITED
    Inventors: Hiroshi Ishihara, Kenji Maruyama, Tetsuro Tamura, Hiromasa Hoko
  • Publication number: 20070178637
    Abstract: A method of fabricating a gate of a semiconductor device using an oxygen-free ashing process is disclosed. The method includes forming a high-k dielectric film, having a dielectric constant higher than a silicon oxide film, on a semiconductor substrate including an NMOS region and a PMOS region, forming an etching target film on the high-k dielectric film, forming a photoresist pattern to expose any one region of the two regions, on the etching target film, etching the etching target film using the photoresist pattern as an etching mask, and removing the photoresist pattern using plasma formed in the presence of an oxygen-free reactive gas.
    Type: Application
    Filed: January 30, 2007
    Publication date: August 2, 2007
    Inventors: Hyung-suk Jung, Cheol-kyu Lee, Jong-ho Lee, Sung-kee Han, Yun-seok Kim
  • Publication number: 20070026547
    Abstract: A method and apparatus for process integration in manufacture of a gate structure of a field effect transistor are disclosed. The method includes assembling an integrated substrate processing system having a metrology module and a vacuumed processing platform to perform controlled and adaptive plasma processes without exposing the substrate to a non-vacuumed environment.
    Type: Application
    Filed: September 13, 2006
    Publication date: February 1, 2007
    Applicant: Applied Materials, Inc.
    Inventors: Ajay Kumar, Ramesh Krishnamurthy
  • Patent number: 7151001
    Abstract: A fabrication method of a self-aligned ferroelectric gate transistor using a buffer layer of high etching selectivity is disclosed. A stacked structure is formed with a buffer layer with high etching selectivity inserted between a silicon substrate and a ferroelectric layer, and etching is performed on a portion where a source and a drain will be formed and then stopped at the buffer layer, thereby fabricating a self-aligned ferroelectric gate transistor without damage to the silicon thin film, and thus, an integration degree of a chip can be improved.
    Type: Grant
    Filed: August 23, 2004
    Date of Patent: December 19, 2006
    Assignee: Korea Institute of Science and Technology
    Inventors: Yong-Tae Kim, Seong-Il Kim, Chun-Keun Kim, Sun-Il Shim