Plural Chemical Reaction Stages Patents (Class 422/170)
  • Publication number: 20110002828
    Abstract: A mercury reduction system according to the present embodiment is a mercury reduction system that reduces NOx and Hg in flue gas discharged from a boiler, and includes a chemical supplying unit that mixes an NH4Cl solution, an NH3 solution, and an HCl solution in liquid states, and supplies a mixed solution into a flue provided downstream of the boiler, a reduction denitration apparatus that includes a denitration catalyst reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus that reduces Hg oxidized in the reduction denitration apparatus with limestone-gypsum slurry.
    Type: Application
    Filed: December 17, 2009
    Publication date: January 6, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Publication number: 20110002827
    Abstract: A mercury reduction system includes an NH4Cl supplying unit that sprays an NH4Cl solution into a flue of the boiler, a reduction denitration apparatus that includes a denitration catalyst for reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus for reducing Hg oxidized in the reduction denitration apparatus with limestone-gypsum slurry. The NH4Cl supplying unit includes an NH4Cl solution feed pipe that supplies the NH4Cl solution into the flue in a liquid state, a blow pipe that is inserted into the flue so as to surround the NH4Cl solution feed pipe and through which air is injected into the flue, and a two-fluid nozzle that is fitted to an end of the NH4Cl solution feed pipe and through which the NH4Cl solution is injected. Through the two-fluid nozzle, the NH4Cl solution is injected and sprayed in fine liquid droplets.
    Type: Application
    Filed: December 17, 2009
    Publication date: January 6, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Publication number: 20110002829
    Abstract: A mercury reduction system according to the present embodiment is a mercury reduction system that reduces NOx and Hg in flue gas discharged from a boiler, and includes an NH4Cl solution spraying unit that sprays an NH4Cl solution into a flue of the boiler in a liquid state, a mixed gas spraying unit that is provided downstream of the NH4Cl solution spraying unit and sprays mixed gas containing NH3 gas and HCl gas into the flue, a reduction denitration apparatus that includes a denitration catalyst reducing NOx in the flue gas with NH3 and oxidizing Hg in the presence of HCl, and a wet desulfurization apparatus that reduces Hg oxidized in the reduction denitration apparatus with a limestone-gypsum slurry.
    Type: Application
    Filed: December 17, 2009
    Publication date: January 6, 2011
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Nobuyuki Ukai, Moritoshi Murakami, Susumu Okino, Tatsuto Nagayasu, Seiji Kagawa
  • Patent number: 7862789
    Abstract: A circulating fluidized bed power plant 100 includes; a circulating fluidized bed boiler 110 which generates flue gases, a flash dry absorber scrubber 140 configured to receive the flue gases from the circulating fluidized bed boiler 110, and a lime feed 150 configured to introduce lime into the flash dry absorber scrubber 140.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: January 4, 2011
    Assignee: Alstom Technology Ltd.
    Inventors: Lawrence H. Gatton, Jr., George D. Mylchreest
  • Patent number: 7858050
    Abstract: A catalytic converter unit includes walls defining a treatment zone, first and second transfer zones and at least one through-flow zone, which zones are adjacent each other. The walls include a partition wall that divides the treatment zone into first and second segments. The first transfer zone is plugged upstream of the partition wall and the second transfer zone is plugged downstream of the partition wall. A catalytic converter element is disposed in the first segment of the treatment zone, spaced from the partition wall. The first segment of the treatment zone is in flow communication with the first transfer zone and the second segment of the treatment zone is in flow communication with the second transfer zone.
    Type: Grant
    Filed: May 16, 2007
    Date of Patent: December 28, 2010
    Assignee: Wärtsilä Finland Oy
    Inventors: Ulf Grandlund, Ulf Nordmyr
  • Patent number: 7846406
    Abstract: A scrubber for scrubbing at least one pollutant from flue gas includes a first stage configured to provide a chemical oxidant to a stream of flue gas, and a second stage configured to provide a chemical or chemicals to the stream of flue gas, a scrubbing medium recirculation feature configured to continuously recirculate a slurry used in the second stage, and a by-product processing portion configured to remove a by-product from a stream of slurry withdrawn from the scrubber. The by-product includes reaction products of at least one pollutant.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: December 7, 2010
    Inventors: Kevin P. Furnary, William Ellison
  • Patent number: 7842264
    Abstract: A multiple stage apparatus and process using aerodynamic reactors and aero-coalescers in sequence for the selective capture and removal of purified carbon dioxide gas, the sequential capture and removal of mercury, metal and particulate aerosols by a recycling chemical generation-regeneration system using alkali metal chloride solution following multiple oxidations of mercury vapor, and nitric oxide in sequence, selective capture and removal of sulfur dioxide and nitrogen dioxide by two stage absorption by a recycling chemical generation-regeneration system using alkali metal hydroxide-carbonate-bicarbonate solution together with sequential oxidation to alkali metal sulfate and alkali metal nitrate compounds through evaporation and crystallization. Carbon dioxide capture and recovery is achieved in sequence by selective thermal decarbonation from an alkaline liquid followed by recovery as a purified gas stream.
    Type: Grant
    Filed: April 2, 2008
    Date of Patent: November 30, 2010
    Assignee: Cefco, LLC
    Inventors: Hal B. H. Cooper, Robert E. Tang, Donald E. Degling, Thomas K. Ewan, Sam M. Ewan
  • Patent number: 7842265
    Abstract: Disclosed is a method for the reduction of mercury emissions from an industrial plant utilizing a cement or minerals kiln that has a high level of mercury. The invention allows for the repeated treatment of a gas stream to reduce the level of mercury and other pollutants through reduction steps, allowing targeted treatment of specific compounds. The invention utilizes multiple sorbent injections for the step-wise reduction in pollutants. Utilizing the multiple stages of reaction, very high levels of mercury emissions may be controlled to greater reduction percentages than existing methods.
    Type: Grant
    Filed: June 12, 2009
    Date of Patent: November 30, 2010
    Assignee: FLSmidth A/S
    Inventor: Peter T. Paone, III
  • Publication number: 20100296989
    Abstract: Molecular conversion processing of greenhouse gases of global warming effect and conversion units employing a solid particle trap. This is an industrial process capable of changing the chemical composition of the greenhouse gases from any source, such as the internal combustion engine, factory chimney and others, through the conversion of gas molecules to form new compounds such as clean gases. This is done by molecular conversion processing conversion unit with a solid particle trap, consisting of a plasma conversion chamber (II) that produces a plasma jet, and an electrostatic filter (III) for the collection of solid particles.
    Type: Application
    Filed: May 15, 2007
    Publication date: November 25, 2010
    Inventors: Ivan Gonçalves de Souza, Nito Angelo Debacher
  • Publication number: 20100296993
    Abstract: The present invention relates to a method for cleaning off-gas comprising the following steps: 1. sulphur dioxide is separated from the off-gas by way of at least one first scrubber stage (c) by means of ammonia or ammonium compounds, 2. the off-gas is transferred into a second scrubber stage (d) and 3. in the second scrubber stage the sulphur dioxide not separated in the first scrubber stage (c), is oxidised to sulphuric acid and separated in at least one scrubber (d) and simultaneously, the ammonia released in the first scrubber stage (d) is separated by means of the formed sulphuric acid, whereby ammonium sulphate is formed, 4. the separated stream of the second scrubber stage (d) is transferred into the first scrubber stage (c).
    Type: Application
    Filed: August 22, 2008
    Publication date: November 25, 2010
    Inventors: Hans Hunsinger, Martin Karlssson, Sven Andersson, Ulf Hägg
  • Patent number: 7837962
    Abstract: A method of reducing particulate matter and mercury emissions in a combustion flue gas includes, in an exemplary embodiment, combusting a fuel resulting in generation a flue gas flow, cooling the flue gas flow within a duct, positioning a flow conditioning apparatus within the duct, enhancing a reaction rate of the mercury and carbon-containing fly ash particles by directing the flue gas flow through the flow conditioning apparatus to mix the carbon-containing fly ash particles and mercury within the flue gas flow and to facilitate at least one of oxidation of the mercury and binding the mercury to the carbon-containing fly ash particles, collecting a portion of the carbon-containing fly ash particles in the flow conditioning apparatus, and directing the flue gas flow to a particulate collection device to remove the remaining portion of the fly ash particles from flue gas flow.
    Type: Grant
    Filed: March 24, 2008
    Date of Patent: November 23, 2010
    Assignee: General Electric Company
    Inventors: Boris Nikolaevich Eiteneer, Robert Warren Taylor, Vitali Lissianski, James Easel Roberts
  • Publication number: 20100290963
    Abstract: A method of converting nitrogen oxides in a gas to nitrogen by contacting the nitrogen oxides with a nitrogenous reducing agent in the presence of a zeolite catalyst containing at least one transition metal, wherein the zeolite is a small pore zeolite containing a maximum ring size of eight tetrahedral atoms, wherein the at least one transition metal is selected from the group consisting of Cr, Mn, Fe, Co, Ce, Ni, Cu, Zn, Ga, Mo, Ru, Rh, Pd, Ag, In, Sn, Re, Ir and Pt.
    Type: Application
    Filed: April 24, 2008
    Publication date: November 18, 2010
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Paul Joseph Andersen, Jillian Elaine Bailie, John Leonello Casci, Hai-Ying Chen, Joseph Michael Fedeyko, Rodney Kok Shin Foo, Raj Rao Rajaram
  • Publication number: 20100290965
    Abstract: Combustion flue gas containing NOX and SOX is treated to remove NOX in a multistep system in which NOX is reduced in the flue gas stream via selective catalytic reduction or selective non-catalytic reduction with ammonia or an ammonia-forming compound, followed treatment with hydrogen peroxide to remove residual ammonia and, optionally, treatment with an alkali reagent to reduce residual NOX in the flue gas stream. The NOX-depleted flue gas stream may also be subjected to a desulfurization treatment for removal of SOX.
    Type: Application
    Filed: May 12, 2010
    Publication date: November 18, 2010
    Applicant: FMC CORPORATION
    Inventors: Henry A. Pfeffer, David E. Smith
  • Patent number: 7833501
    Abstract: A method and apparatus for treating an exhaust gas comprising heavy metals, wherein the apparatus comprises a heat recovery unit, recovering exhaust gas heat at an exit of the air preheater; a precipitator, collecting soot/dust contained in an exhaust gas at an exit of the heat recovery unit; a wet flue gas desulfurizer, removing sulfur oxides contained in the exhaust gas at the exit of the precipitator; and a reheater, heating the exhaust gas at the exit of the wet flue gas desulfurizer. Each of the heat recovery unit and the reheater has a heat exchanger tube, and a circulation line is disposed to connect the heat exchanger tubes. A sulfur trioxide (SO3) removing agent is supplied to the upstream side of the heat recovery unit, and the temperature of the exhaust gas at the exit of the heat recovery unit is adjusted to not more than a dew point of sulfur trioxide.
    Type: Grant
    Filed: December 24, 2007
    Date of Patent: November 16, 2010
    Assignee: Babcock-Hitachi Kabushiki Kaisha
    Inventors: Kazuki Kobayashi, Hirofumi Kikkawa, Hiroshi Ishizaka, Goki Sasaki, Hiroyuki Nosaka
  • Publication number: 20100284866
    Abstract: A system for reducing a carbon compound of a heat engine includes: an outlet pipe transferring and outputting an exhaust gas from the heat engine; a removal reacting tank connected to the outlet pipe, the removal reacting tank generating a strong alkaline solution by a reaction of a resource material and a water and removing the carbon compound from the exhaust gas by a contact of the carbon compound and the strong alkaline solution; a sludge storing tank storing a sludge generated by a removal reaction in the removal reacting tank; and a decomposing tank generating the resource material for the removal reacting tank by decomposing the sludge from the sludge storing tank with a heat. Accordingly, since the carbon compound such as carbon dioxide is effectively removed from the exhaust gas emitted from a heat engine equipped in an industrial plant and a vehicle, atmospheric environmental pollution is prevented and regulation on carbon dioxide emission is satisfied.
    Type: Application
    Filed: December 29, 2008
    Publication date: November 11, 2010
    Inventors: Yong-Sik Jang, Byung Chan Lee
  • Publication number: 20100247396
    Abstract: A Selective Catalytic Reduction (SCR) filter is provided for use in emission control systems, for example, on the exhaust gas from an internal combustion engine. The SCR filter has a substrate constructed using bonded fiber structures, which cooperate to form a highly uniform open cell network, as well as to provide a uniform arrangement of pores. The substrate typically is provided as a wall-flow honeycomb structure, and in one example, is manufactured using an extrusion process. In this way, the substrate has many channel walls, each having an inlet surface and an outlet surface. The inlet surface has a uniform arrangement of pores that form a soot capture zone, where soot and other particulate matter is captured from an exhaust gas. A NOx conversion catalyst is disposed inside the channel wall, where NOx and ammonia in the exhaust gas are reacted to less harmful substances.
    Type: Application
    Filed: April 5, 2010
    Publication date: September 30, 2010
    Applicant: GEO2 TECHNOLOGIES, INC.
    Inventor: Bilal Zuberi
  • Patent number: 7802420
    Abstract: A power generation system and method of operating a power generation system which comprises a diesel engine which produces lean exhaust which passed to an exhaust after treatment system comprising an exhaust line which is in communication with a controller, reformer, lean NOx trap and SCR has been taught wherein the reformer comprises oxidation and reforming catalyst is a composition which comprises a catalyst wash coat comprising a ZrO2 refractory metal oxide support, a LnxOy distributed on the surface of the refractory metal oxide in an amount to form a monolayer over the refractory metal oxide support wherein Ln is selected from the group consisting of La, Nd and mixtures thereof and Rh distributed over the catalyst surface in an effective amount to catalyze steam reforming at 650° C.
    Type: Grant
    Filed: July 26, 2007
    Date of Patent: September 28, 2010
    Assignee: Eaton Corporation
    Inventors: Damodara M. Poojary, Ralph Albert Dalla Betta, Jon Gilbert McCarty
  • Publication number: 20100239480
    Abstract: The present invention is a method of treating nitrogen oxides using an ozone and catalyst hybrid system, as well as an apparatus, specifically relating to a method of treating nitrogen oxide using an ozone and catalyst hybrid system comprising: 1) removing moisture from the nitrogen oxide polluted air to be treated; 2) contacting the moisture-removed nitrogen oxide polluted air with ozone to oxidize NO in said polluted air to NO2; 3) reacting the residual ozone with a catalyst to generate oxygen radicals and then, reacting the oxygen radicals with the nitrogen oxide polluted air from step 2) to oxidize NO2 in the polluted air to NO3?. The nitrogen oxide treatment method and apparatus according to the present invention can effectively treat harmful nitrogen oxides, such as NO, NO2, using an ozone and catalyst hybrid system at room temperature without requiring a high temperature reaction or an ammonia gas as a reducing agent.
    Type: Application
    Filed: December 16, 2009
    Publication date: September 23, 2010
    Inventors: Jong Soo Jurng, Ju Young Jeong, Sung Min Chin
  • Patent number: 7799297
    Abstract: This combustion exhaust gas processing device comprises a dust collector collecting dust in combustion exhaust gas, a wet dust collector collecting water soluble components and dust in the combustion exhaust gas passed through the dust collector, and a catalyst tower decomposing and removing NOx and/or dioxins in the combustion exhaust gas passed through the wet dust collector. The device also comprises a reheater heating the combustion exhaust gas discharged from the wet dust collector at the front stage of the catalyst tower, an oxidizer adding device adding an oxidizer to the combustion exhaust gas passed through the dust collector, a solid/liquid separator separating slurry discharged from the wet dust collector into solid and liquid phases, a mercury adsorbing tower adsorbing mercury in liquid separated in the solid/liquid separator, and a heat recovering device heating the combustion exhaust gas discharged from the catalyst tower at the rear stage thereof.
    Type: Grant
    Filed: June 28, 2004
    Date of Patent: September 21, 2010
    Inventor: Shinichiro Saito
  • Patent number: 7794678
    Abstract: An effluent gas scrubber and a method of scrubbing effluent gases are provided. An inlet port receives an effluent gas. The gas passes through successive chambers in which it is sprayed with a scrubbing fluid. An oxidizer within the scrubbing fluid is effective to oxidize non-water soluble gases within the effluent gas. An oxidation-reduction potential probe measures the oxidation-reduction potential of the scrubbing fluid and adds the oxidizer to the scrubbing fluid as needed. A pH probe measures the pH of the scrubbing fluid and adds a base to the scrubbing fluid as needed to maintain the pH at or above a threshold such as pH 7, or pH 12.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: September 14, 2010
    Assignee: Airgard, Inc.
    Inventors: Mark Johnsgard, Kris Johnsgard
  • Patent number: 7790127
    Abstract: A method of reducing NOx in a lean burn engine exhaust stream from a hydrocarbon burning engine may be first passing the exhaust stream over a thrifted diesel oxidation catalyst that substantially completes the oxidation of carbon monoxide to carbon dioxide and the oxidation of hydrocarbons (HC) to carbon dioxide and water. Next, separate additions of ozone and ammonia or urea may be introduced to the exhaust gas stream upstream of the catalytic reduction reactor at temperatures below 250 degrees Celsius. The additions of ozone and ammonia or urea modify the exhaust gas composition to improve the performance of NOx reduction catalysts in the catalytic reduction reactor. At temperatures above 250 degrees, the ozone addition may be reduced or eliminated, while the ammonia addition can be controlled as a function of the amount of NOx in the exhaust stream and the temperature of the catalytic reduction reactor.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: September 7, 2010
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Jong H. Lee, Byong Kwon Cho
  • Publication number: 20100221164
    Abstract: A method of reducing NOx in a lean burn engine exhaust stream from a hydrocarbon burning engine may be first passing the exhaust stream over a thrifted diesel oxidation catalyst that substantially completes the oxidation of carbon monoxide to carbon dioxide and the oxidation of hydrocarbons (HC) to carbon dioxide and water. Next, separate additions of ozone and ammonia or urea may be introduced to the exhaust gas stream upstream of the catalytic reduction reactor at temperatures below 250 degrees Celsius. The additions of ozone and ammonia or urea modify the exhaust gas composition to improve the performance of NOx reduction catalysts in the catalytic reduction reactor. At temperatures above 250 degrees, the ozone addition may be reduced or eliminated, while the ammonia addition can be controlled as a function of the amount of NOx in the exhaust stream and the temperature of the catalytic reduction reactor.
    Type: Application
    Filed: March 2, 2009
    Publication date: September 2, 2010
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS, INC.
    Inventors: JONG H. LEE, BYONG KWON CHO
  • Patent number: 7785548
    Abstract: Disclosed is a fuel filter for removing sulfur containing compounds from an internal combustion fuel stream. In one embodiment, the fuel filter comprises at least one column comprising an adsorbent. In one exemplary embodiment the adsorbent is capable of removing sulfur containing compounds, especially sulfur containing aromatic compounds, from fuels used in internal combustion engines, especially diesel fuels. Also disclosed is an apparatus for extending the life cycle of a post combustion emission control device. In one exemplary embodiment, the apparatus comprises a fuel filter for removing sulfur containing compounds from an internal combustion fuel stream and an emission control device. Finally, a method for removing sulfur containing compounds from an internal combustion fuel stream is disclosed.
    Type: Grant
    Filed: July 22, 2008
    Date of Patent: August 31, 2010
    Assignee: Honeywell International Inc.
    Inventors: Ronald P. Rohrbach, Peter D. Unger, Gary B. Zulauf, Daniel E. Bause, Russ Johnson, David R. Rockwell
  • Patent number: 7780942
    Abstract: A catalytic method for treating an H2S/SO2 mixture for producing liquid sulphur including the following steps: a) at least one step of heating the mixture containing H2S/SO2 to a temperature Tc; b) at least one step of catalytically reacting the heated mixture obtained in a) in the presence of at least one catalyst and at least one step of recovering the exiting mixture containing gaseous sulphur; and c) at least one step of converting the gaseous sulphur contained in the exiting mixture obtained at step b) into liquid sulphur, wherein between step b) and step c), the temperature Ts of said exiting mixture and the dew point Tr of the gaseous sulphur contained in said exiting mixture are measured and in that the heating temperature Tc of step a) is adjusted so that the temperature Ts is 5° C. to 30° C. above the dew point Tr.
    Type: Grant
    Filed: February 19, 2007
    Date of Patent: August 24, 2010
    Assignee: Total Raffinage Marketing
    Inventor: Pierre Kaplan
  • Patent number: 7767163
    Abstract: An exhaust emission control system can include a reformer a fuel source disposed upstream of and in fluid communication with the reformer, and a NOx adsorber disposed downstream of and in fluid communication with the reformer. The NOx adsorber can include a NOx adsorber catalyst having an acid adsorber disposed on the substrate and a base adsorber disposed over the acid adsorber.
    Type: Grant
    Filed: April 20, 2004
    Date of Patent: August 3, 2010
    Assignee: Umicore AG & Co. KG
    Inventors: William J. LaBarge, Kenneth Price, Joseph V. Bonadies, Joachim Kupe
  • Patent number: 7767177
    Abstract: The present invention describes a new device which permits a reduction of NOx emissions contained in the fumes from FCC regenerators. The device consists essentially of a conveyance conduit which connects the two regeneration stages and which has an outlet opening into the dilute phase of the second stage.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: August 3, 2010
    Assignee: Institut Francais du Petrole
    Inventors: Thierry Gauthier, Romain Roux, André Nicolle
  • Patent number: 7762063
    Abstract: A housing for an exhaust gas purification component encloses an interior space in which at least one receptacle is formed by the housing at the outside. An exhaust system includes at least one first exhaust line section and the housing having the exhaust gas purification component. The first exhaust line section is in engagement with the receptacle, and the first exhaust line section and the receptacle are connected to one another in a materially integral manner. A motor vehicle having the exhaust system is also provided.
    Type: Grant
    Filed: August 31, 2007
    Date of Patent: July 27, 2010
    Assignees: Emitec Gesellschaft fuer Emissionstechnologie mbH, Benteler Automobiltechnik GmbH
    Inventors: Joachim Diringer, Friedrich-Wilhelm Kaiser, Jörg Gutowski, Christian Smatloch, Christian Howe, Elmar Grussmann
  • Patent number: 7758830
    Abstract: The invention relates to a mercury removing apparatus and a mercury removing method in which a mercury removing ratio is improved with low cost, the mercury removing apparatus removes mercury from exhaust gas generated by coal combustion, an acidic solution spraying nozzle for spraying sulfuric acid into exhaust gas is provided on the down stream side of an absorption tower for removing sulfur oxide from the exhaust gas.
    Type: Grant
    Filed: December 22, 2008
    Date of Patent: July 20, 2010
    Assignee: IHI Corporation
    Inventors: Toshiyuki Naito, Hiroyuki Kamata, Shunichiro Ueno
  • Patent number: 7758818
    Abstract: Disclosed is a scrubber for processing semiconductor waste gas produced in a semiconductor fabricating process, wherein the scrubber burns the waste gas with a flame of a high temperature, filters and captures particles produced after the waste gas is burnt, and discharges particle-filtered waste gas to the atmosphere.
    Type: Grant
    Filed: September 1, 2006
    Date of Patent: July 20, 2010
    Assignee: Clean Systems Korea Inc.
    Inventors: Young Chan Lee, Hyung Geuk Kim, Sang Keun Lee
  • Patent number: 7758819
    Abstract: A waste gases-neutralizing device comprises a filter installation with at least one filter unit with an inlet and an outlet between which a filter is received to remove undesired components from the waste gases. The installation has a modular construction and comprises a number of filter units which are placed in series in a flow path of the waste gases and/or a reactor vessel provided with a nozzle with mixing chamber in which waste gases are at least partially removed with a mixture of at least one neutralizing compound and oxygen under pressure. The filter units each comprise a filter adapted to a specific component or group of components to be removed from the waste gases. The waste gases-neutralizing device preferably also comprises, in addition to the filter installation, a neutralizing unit 21 comprising a neutralizing liquid bath or a fixed connection impregnated with a neutralizing liquid.
    Type: Grant
    Filed: April 17, 2001
    Date of Patent: July 20, 2010
    Assignee: Stichting Rechtenbeheer Knauf
    Inventor: Gerrit Johannes Nagelhout
  • Patent number: 7754935
    Abstract: Methods of dehydrogenating hydrocarbons to yield unsaturated compounds are described. Reactor configurations useful for dehydrogenation are also described. Hydrocarbons can be dehydrogenated, for relatively long periods of time-on-stream, in a reaction chamber having a dimension of 2 mm or less to produce H2 and an olefin. Techniques have been developed that reduce coke and allow stable, relatively long-term operation in small reactors.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: July 13, 2010
    Assignee: Velocys
    Inventors: John H. Brophy, Gary Roberts, G. Bradley Chadwell, Matthew B. Schmidt, Anna Lee Tonkovich
  • Patent number: 7749464
    Abstract: A plate type catalytic reactor in which components of a starting material gas react comprises a plurality of pairs of heat transfer plates, each pair being formed of two sheets of corrugated plates joined to each other and each pair having a plurality of interior heat transfer medium flow passages, that are arranged so that projected surface parts and recessed surface parts of the corrugated plates of adjacent heat transfer plates are opposed to each other and so that the plurality of pairs of corrugated plates placed in contiguous non-contacting relationship define a plurality of catalyst bed regions in which catalyst material is placed, each having an inlet for the flow of starting gas material and an outlet for the egress of reaction product, wherein the direction of flow of the heat transfer medium through the passages is perpendicular to the direction of flow of starting material gas through the plurality of catalyst regions.
    Type: Grant
    Filed: June 1, 2005
    Date of Patent: July 6, 2010
    Assignees: Mitsubishi Chemical Corporation, Mitsubishi Chemical Engineering Corporation
    Inventors: Yasuyuki Sakakura, Youji Kawatani, Teruo Saitou
  • Patent number: 7749938
    Abstract: A catalyst for nitrogen oxide removal, which catalytically reduces nitrogen oxides in an exhaust gas in the presence of ammonia, comprises: a first component comprising an oxide of titanium, an oxide of tungsten, and an oxide of vanadium; and a second component comprising an oxide of manganese, or an oxide of manganese and an oxide of copper.
    Type: Grant
    Filed: September 19, 2007
    Date of Patent: July 6, 2010
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Yoshiaki Obayashi, Akira Hattori, Masanori Demoto
  • Publication number: 20100166630
    Abstract: A small scale, but effective, reactive chemical containment system includes apparatus and methods for reaction of process gases exhausted from reaction furnaces with a reactant gas in a non-combustible manner to produce and contain particulate or powder byproducts, thereby removing the process gas from the exhaust gas flow. The apparatus provides process gas inlet, treatment reactive gas diffusion, process gas and treatment reactive gas pre-mixing, primary containment, secondary containment, and outlet zones.
    Type: Application
    Filed: December 22, 2009
    Publication date: July 1, 2010
    Applicant: MKS INSTRUMENTS, INC.
    Inventors: Youfan Gu, Paul Dozoretz
  • Patent number: 7740811
    Abstract: A hydrogen generator having double burners and a method of operating the samewhere the hydrogen generator includes a housing, a barrier wall to divide a space in the housing into a first chamber and a second chamber, a fuel reformer installed in the first chamber, a first burner installed in the first chamber to heat a fuel reformer, a shift reactor installed in the second chamber, a second burner mounted in the barrier wall to heat the shift reactor, and a first igniter and a second igniter respectively ignite the first burner and the second burner.
    Type: Grant
    Filed: August 22, 2006
    Date of Patent: June 22, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Tae-sang Park, Dong-woo Lee, Soon-ho Kim, Doo-hwan Lee, Hyun-chul Lee
  • Patent number: 7731924
    Abstract: A group of at least two gas-flow reactors (21, 22, 2?2, . . . , 2n, 2?n) preferably with an ascending gas flow (3), are supplied in parallel with gas and with a chemical neutralization and/or sorption agent of the pulverulent material type capable of adsorbing effluents present in the gas flow by bringing the chemical neutralization and/or sorption agent in contact with the gas flow, the at least two reactors having elements (10) for collecting the chemical neutralization and/or sorption agent after contact with the gas flow. At least one of the two reactors has elements (11) for discharging the chemical neutralization and/or or sorption agent, after contact with the gas flow, these discharge elements being connected to the collecting elements, and members (7, 16) for injecting the chemical neutralization and/or sorption agent into at least one other of the at least two reactors.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: June 8, 2010
    Assignee: Solios Environnement
    Inventors: Bernard Cloutier, Thierry Malard
  • Publication number: 20100135865
    Abstract: Methods of sequestering carbon dioxide (CO2) are provided. Aspects of the methods include precipitating a storage stable carbon dioxide sequestering product from an alkaline-earth-metal-containing water and then disposing of the product, e.g., by placing the product in a disposal location or using the product as a component of a manufactured composition. Also provided are systems for practicing methods of the invention.
    Type: Application
    Filed: February 2, 2010
    Publication date: June 3, 2010
    Inventors: Brent R. Constantz, Andrew Youngs, Philip Brian Tuet, Sidney Omelon, Kasra Farsad, Ryan J. Gilliam, Valentin Decker, Donald W. Kirk, Douglas J. Way, Allen J. Bard, Robert Danziger, Miguel Fernandez, Cecily Ryan
  • Patent number: 7722845
    Abstract: Catalysts, methods, and systems for treating diesel engine exhaust streams are described. In one or more embodiments, the catalyst comprises platinum, a second metal from one of the groups VB, VIB, VIIB, VIIIB, IB, or IIB of the periodic table, a refractory metal oxide, and a zeolite, the oxidation catalyst already being effective to remove ammonia at temperatures less than about 300° C. and exhibiting no significant decrease in ammonia oxidation efficiency upon hydrothermal aging. A method aspect includes first passing a vehicle's engine exhaust stream through a NOx abatement catalyst; and passing the exhaust stream exiting the NOx abatement catalyst and containing ammonia through the ammonia oxidation catalyst. Systems including such catalysts are also provided.
    Type: Grant
    Filed: February 27, 2008
    Date of Patent: May 25, 2010
    Assignee: Basf Corporation
    Inventors: Matthew T. Caudle, Martin Deiterle, Stanley A. Roth, Wen-Mei Xue
  • Patent number: 7718141
    Abstract: An automatic VOC concentration control apparatus is capable of adjusting the concentration of VOC in a catalytic device under a predetermined value. The automatic VOC concentration control apparatus includes a housing having an inlet port and an outlet port for introducing and discharging VOC vapor, respectively, one or more cooling tubes for cooling the VOC vapor introduced through the inlet port, and one or more porous members for holding droplets of VOC liquid thereon as the VOC vapor is condensed into liquid.
    Type: Grant
    Filed: September 13, 2005
    Date of Patent: May 18, 2010
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Woong-jae Chang
  • Patent number: 7708966
    Abstract: A selective catalytic reduction (SCR) system includes an on-board ammonia generation system that produces nitrogen from air and hydrogen from a source of a hydrogen-containing compound, and generates an ammonia product from the nitrogen and hydrogen to provide the ammonia product into an exhaust from a NOx generator to reduce the NOx in the exhaust. Oxygen from one or both of the nitrogen generator and the hydrogen generation cell can be supplied to the NOx generator for cleaner combustion or to a particulate filter for cleaning the filter. H2O from the NOx generator can at least partially provide a water source for the hydrogen generation cell.
    Type: Grant
    Filed: February 4, 2008
    Date of Patent: May 4, 2010
    Assignee: Ceramatec, Inc.
    Inventor: Ashok V. Joshi
  • Patent number: 7709414
    Abstract: An engine exhaust catalyst exhibits improved CO oxidation performance relative to conventional engine exhaust catalysts and includes a first supported catalyst comprising platinum and a second supported catalyst comprising palladium and gold species in close contact. The first supported catalyst may be a platinum catalyst, a platinum—palladium catalyst, or a platinum catalyst promoted with bismuth, and the second supported catalyst preferably has a palladium to gold weight ratio of about 0.85:1.0. To improve aged catalyst performance, the first and second supported catalysts are coated onto different layers, zones, or monoliths of the substrate for the engine exhaust catalyst.
    Type: Grant
    Filed: January 17, 2007
    Date of Patent: May 4, 2010
    Assignee: NanoStellar, Inc.
    Inventors: Kyle L. Fujdala, Timothy J. Truex, Jifei Jia
  • Patent number: 7704472
    Abstract: An air pollutant control system comprises: a denitration apparatus that reduces nitrogen oxide in flue gas discharged from a coal combustion boiler, and that sprays hydrogen chloride into the gas to oxidize mercury, an air heater that recovers heat in gas, a dust collector that reduces dust in gas, a desulfurization apparatus that reduces sulfur oxide in gas from which the dust has been reduced, a hydrogen chloride vaporizer that evaporates concentrated hydrochloric acid to obtain the hydrogen chloride, and a hydrochloric acid neutralization tank where dilute hydrochloric acid discharged from the hydrogen chloride vaporizer or the concentrated hydrochloric acid is neutralized with an alkali agent. Neutralized chloride is supplied to a fuel feeder, mixed with a fuel, and then burned as a fuel in a boiler to produce hydrogen chloride in flue gas. Together with sprayed hydrogen chloride derived from the hydrogen chloride vaporizer, the mercury is reduced.
    Type: Grant
    Filed: January 30, 2009
    Date of Patent: April 27, 2010
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Moritoshi Murakami, Nobuyuki Ukai, Tatsuto Nagayasu
  • Publication number: 20100080745
    Abstract: Carbon dioxide is purified by processes employing NOx-rich sulfuric acid that can be formed by removal of SO2 from the carbon dioxide.
    Type: Application
    Filed: September 22, 2009
    Publication date: April 1, 2010
    Inventors: Nick Joseph Degenstein, Minish Mahendra Shah, Ravi Kumar
  • Patent number: 7674444
    Abstract: A sulfur species-containing feed gas is processed in a treatment plant in which COS is hydrolyzed, and in which so produced hydrogen sulfide and other sulfur species are absorbed in a lean hydrocarbon liquid. The sulfur species in the so formed rich hydrocarbon liquid are then subjected to catalytic conversion into disulfides, which are subsequently removed from the rich solvent. Most preferably, sulfur free lean solvent is regenerated in a distillation column and/or refinery unit, and light components are recycled from the rich hydrocarbon liquid to the absorber.
    Type: Grant
    Filed: January 23, 2007
    Date of Patent: March 9, 2010
    Assignee: Fluor Technologies Corporation
    Inventor: John Mak
  • Patent number: 7670404
    Abstract: This structure (11) comprises first and second filtering elements (15A, 15B) extending essentially parallel to a longitudinal axis (X-X?) of the structure (11) between an admission region (21) of the gases into the structure (11) and an evacuation region (23) of the gases from the structure, and comprises a seal (17) for joining these elements (15A, 15B). The seal (17) comprises at least one downstream pat (43) which has a thermal mass per unit length greater than the thermal mass per unit length of an upstream part (41) of the seal (17). The invention is for use in particulate filters for the exhaust gases of a motor vehicle diesel engine.
    Type: Grant
    Filed: September 2, 2005
    Date of Patent: March 2, 2010
    Assignee: Saint-Gobain Centre de Recherches Et d'Etudes Europeen
    Inventors: Sébastien Bardon, Anthony Briot, Vincent Gleize
  • Patent number: 7661265
    Abstract: An exhaust gas system for an internal combustion engine, comprising an oxidation catalytic converter disposed in a first exhaust gas manifold section with which the exhaust gas outlets of a first portion of the cylinders communicate, and a hydrolysis catalytic converter disposed in a second exhaust gas manifold section with which the exhaust gas outlets of the remaining portion of the cylinders communicate. The hydrolysis catalytic converter, together with the oxidation catalytic converter that annularly surrounds it, are installed in a common housing. A tubular portion of the second exhaust gas manifold section extends into the housing and accommodates the hydrolysis catalytic converter in its end portion. A tubular portion of a first exhaust gas manifold section surrounds the tubular portion of the second exhaust gas manifold section, resulting in an annular in-flow chamber for the oxidation catalytic converter that simultaneously serves as a heating chamber.
    Type: Grant
    Filed: May 4, 2007
    Date of Patent: February 16, 2010
    Assignee: MAN Nutzfahrzeuge Osterreich AG
    Inventor: Thomas Baumgartner
  • Patent number: 7662204
    Abstract: A vehicle exhaust gas purification device has a multipart outer housing (10) including a tube (12) and end walls (14) that have been reshaped into funnels. The tube (12) and the end walls (14) are fitted into each other and brazed, soldered or welded to each other.
    Type: Grant
    Filed: July 28, 2005
    Date of Patent: February 16, 2010
    Assignee: Emcon Technologies LLC
    Inventors: Erich Forster, Peter Kroner, Otto Steinhauser
  • Patent number: 7662352
    Abstract: A biomass feeding unit feeds biomass to a boiler. A hydrogen-chlorine monitoring unit measures hydrogen-chloride content in flue gas fed to a desulfurization equipment. A mercury monitoring unit measures mercury content in treated flue gas emitted from the desulfurization equipment. A feed-amount instruction unit instructs proper feed amount of the biomass to the biomass feeding unit based on measurement values obtained by the hydrogen-chlorine monitoring unit and the mercury monitoring unit.
    Type: Grant
    Filed: February 23, 2006
    Date of Patent: February 16, 2010
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Yasuhiro Takeuchi, Yoshio Nakayama, Satoru Sugita, Susumu Okino, Shintaro Honjo
  • Patent number: 7658906
    Abstract: Novel sulfur recovery plants, and processes utilizing these plants are disclosed. These apparatuses eliminate the use of a condenser between the waste heat boiler and first Claus catalytic reactors, and also eliminate the use of reheaters in between Claus catalytic reactors.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: February 9, 2010
    Assignee: ConocoPhillips Company
    Inventors: Alfred E. Keller, Nathan A. Hatcher, Sriram Ramani, Larry D. Swinney
  • Patent number: 7655203
    Abstract: A catalyst system for the reduction of NOx is disclosed. One embodiment of the catalyst system is based on a catalyst in a first zone, including a catalyst support, gallium, and at least one promoting metal; and a catalyst in the second zone following the first zone. The second-zone catalyst includes a second catalyst support and a zeolite material. The catalyst system further includes a gas stream comprising an organic reductant, such as a hydrocarbon material or a compound containing oxygen or nitrogen. A method for reducing NOx, utilizing the catalyst system, is also described.
    Type: Grant
    Filed: September 5, 2008
    Date of Patent: February 2, 2010
    Assignee: General Electric Company
    Inventors: Dan Hancu, Benjamin Hale Winkler, Benjamin Rue Wood, Daniel George Norton