Plural Chemical Reaction Stages Patents (Class 422/170)
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Publication number: 20100021361Abstract: The present invention provides for methods for selectively removing CO2 from a multi-component gaseous stream to provide a CO2 depleted gaseous stream. In practicing the subject methods, an initial multi-component gaseous stream is contacted with an aqueous fluid under high-pressure CO2 hydrate-formation reaction conditions to produce a mixture of a CO2 hydrate slurry and a CO2 depleted gaseous stream. Aspects of the subject methods is that the mixture of the CO2 hydrate slurry and the CO2 depleted gaseous stream is transferred directly to a second step hydrate formation reactor in a one-stage, two-step process for further removal of CO2. Also provided are systems that find use in practicing the subject methods. The subject methods and systems find use in a variety of applications where it is desired to selectively remove CO2 from a multi-component gaseous stream.Type: ApplicationFiled: July 23, 2008Publication date: January 28, 2010Inventor: DWAIN F. SPENCER
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Patent number: 7648550Abstract: Disclosed are ceramic honeycomb articles, which are composed predominately of a crystalline phase cordierite composition. The ceramic honeycomb articles possess a microstructure characterized by a unique combination of relatively high total porosity of less than 54%, and relatively narrow pore size distribution having a d10 pore diameter of not less than 8 ?m, a d90 pore diameter of not greater than 35 ?m, and a value of df=(d50?d10)/d50 of less than 0.50. The articles exhibit high thermal durability and high filtration efficiency coupled with low pressure drop across the filter. Such ceramic articles are particularly well suited for filtration applications, such as diesel exhaust filters or DPFs. Also disclosed are methods for manufacturing the ceramic articles of the present invention.Type: GrantFiled: August 25, 2006Date of Patent: January 19, 2010Assignee: Corning IncorporatedInventors: Douglas Munroe Beall, Isabelle Marie Melscoet-Chauvel, Gregory Albert Merkel
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Patent number: 7648547Abstract: A honeycomb filter for purifying exhaust gases that is free from occurrence of cracks and coming-off of plugs and is superior in durability upon its use. The honeycomb filter includes a columnar body made of porous ceramics, which has a number of through holes placed in parallel with one another in the length direction with wall portion interposed therebetween, designed so that predetermined of the through holes are filled with plugs at one end of the columnar body, while the through holes not filled with the plugs at the one end are filled with plugs at the other end of the columnar body, and part of or the entire wall portion functions as a plug for collecting particles. A bending strength F? (MPa) of the honeycomb filter and a length L (mm) of the plug in the length direction of the through hole satisfy the relationship of F?×L?30.Type: GrantFiled: April 9, 2003Date of Patent: January 19, 2010Assignee: Ibiden Co., Ltd.Inventor: Kazushige Ohno
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Patent number: 7641876Abstract: One aspect of the invention relates to a method for removing contaminants from a flue gas stream (22). The method includes: removing fly ash from a flue gas stream (22) utilizing a particle collector (24); contacting the flue gas stream with an alkaline reagent in a wet scrubber (26); discharging a purge liquid (30) from the wet scrubber (26); and, combining at least a portion of the purge liquid with at least a portion of fly ash circulating within a dry circulating fluid bed scrubber (48) to form moistened fly ash (60).Type: GrantFiled: March 5, 2009Date of Patent: January 5, 2010Assignee: ALSTOM Technology LtdInventors: Kelly L. Barger, Gregg R. Doule, Michael G. Varner
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Patent number: 7638107Abstract: A multi-bed selective catalytic reduction system comprising a gas input duct, a first ammonia injection grid assembly located downstream from the gas input duct, a first selective catalytic reduction catalyst assembly located downstream from the first ammonia injection grid assembly, a second ammonia injection grid assembly located downstream from the first selective catalytic reduction catalyst assembly, a second selective catalytic reduction catalyst assembly located downstream from the second ammonia injection grid assembly, and an exhaust stack located downstream from the second selective catalytic reduction catalyst assembly.Type: GrantFiled: June 11, 2008Date of Patent: December 29, 2009Assignee: Callidus Technologies, LLCInventors: Jeffrey Philip Wirt, Dan W. Ott, Brian James Duck
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Publication number: 20090304563Abstract: The present invention provides a mercury removal system and method for effectively removing a mercury component, which is present in a gas stream in an extremely small amount in wet gas cleaning used for coal or heavy oil gasification, petroleum refining and the like. The mercury removal system in wet gas cleaning comprises a water washing tower for introducing therein a target gas containing a mercury component and transferring the mercury component into an absorbing solution, a flush drum (10) for flushing the absorbing solution discharged from the water washing tower to separate the absorbing solution into a gas component and waste water, an oxidation treatment means (1) for adding an oxidizing agent to the absorbing solution at the preceding stage of the flush drum, and a waste water treatment means for subjecting to coagulation sedimentation treatment the separated waste water containing the mercury component at the following stage of the flush drum to dispose of the mercury component as sludge.Type: ApplicationFiled: June 9, 2006Publication date: December 10, 2009Applicants: MITSUBISHI HEAVY INDUSTRIES, LTD., CLEAN COAL POWER R&D CO., LTD., HOKKAIDO ELECTRIC POWER COMPANY INC., TOHOKU ELECTRIC POWER CO., INC., THE TOKYO ELECTRIC POWER COMPANY INC., CHUBU ELECTRIC POWER CO., INC., HOKURIKU ELECTRIC POWER COMPANY, THE KANSAI ELECTRIC POWER CO., INC., THE CHUGOKU ELECTRIC POWER CO., INC., SHIKOKU ELECTRIC POWER CO., INC., KYUSHU ELECTRIC POWER CO., INC., ELECTRIC POWER DEVELOPMENT CO., LTD., CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRYInventors: Masahiro Harada, Makoto Susaki, Shintaro Honjo, Shuji Kameyama, Masaki Nakahara, Akira Kisei
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Patent number: 7625537Abstract: A process and system for removing sulfur oxide, other gases, and particulate from a flue gas. The process includes treating flue gas with a slurry formed from water, an alkaline reagent, and the purge stream from a wet scrubber in a spray dryer, thereby producing a dry by-product. The process further includes filtering the flue gas to remove at least a portion of the dry by-product, wet scrubbing the flue gas exiting the filter in a wet scrubber, adding a lime or limestone reagent to the wet scrubber, and producing gypsum. Activated carbon may be injected into the flue gas upstream of the filtering step and particulate may be removed from the flue gas upstream of the spray dryer.Type: GrantFiled: June 12, 2006Date of Patent: December 1, 2009Assignee: ALSTOM Technology LtdInventors: Philip C. Rader, Raymond R. Gansley
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Patent number: 7625528Abstract: A pre-reformer (10) comprises a non-electrically conducting gas tight duct (12) and an electrically conducting wire (14) arranged in the duct (12). The electrically conducting wire (14) is electrically isolated from the duct (12). The duct (12) has an inlet (16) for receiving a hydrocarbon fuel at a first end (18) and an outlet (20) for supplying a pre-reformed hydrocarbon fuel at a second end (22). At least the inner surface (24) of the duct (12) is chemically inert with respect to the hydrocarbon fuel. An electrical power supply (26) is electrically connected to the electrically conducting wire (14) and a control means (28) controls the supply of electrical current through the electrically conducting wire (14) to maintain the electrically conducting wire (14) at a temperature to provide selective thermal decomposition of higher hydrocarbons in the hydrocarbon fuel. The performer reduces coking in associated fuel cells and other parts of a fuel cell system.Type: GrantFiled: August 5, 2008Date of Patent: December 1, 2009Assignee: Rolls-Royce plcInventors: Gerard D Agnew, Robert H Cunningham, Gary J Saunders
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Patent number: 7622092Abstract: A mercury removing device includes a gasification unit that converts a non-gaseous-mercury-chlorinating agent, which is non-gaseous at room temperature and normal pressure, into gaseous-mercury-chlorinating agent by heating the non-gaseous-mercury-chlorinating agent with heat of hot air generated by using the exhaust gas or hot air generated by using an air heater installed in a flue that conveys the exhaust gas. The gaseous-mercury-chlorinating agent produced in this manner is supplied to the exhaust gas in the flue.Type: GrantFiled: May 14, 2007Date of Patent: November 24, 2009Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shintaro Honjo, Susumu Okino, Yasuhiro Takeuchi, Seiji Kagawa, Yoshio Nakayama
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Patent number: 7622096Abstract: A layered three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Engine exhaust treatment system and methods of using the same are also provided. In one or more embodiments, the catalyst supported on a carrier has three layers, where at least two of the layers are zoned to have an oxygen storage component being present in an upstream zone in an amount that is less than the oxygen storage component present in the downstream zone.Type: GrantFiled: August 9, 2007Date of Patent: November 24, 2009Assignee: BASF Catalysts LLCInventors: Michel Deeba, Knut Wassermann, Glenn Svoboda, Harold Rabinowitz, Stephan Slemund, Xinyi Wei
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Patent number: 7618604Abstract: An object of the present invention is to provide a method for removing gaseous mercury in flue gas that make it possible to remove mercury in flue gas extremely satisfactorily while handling is made easy and cost increases are kept under control. In order to accomplish the object, the present invention adopts the method of removing gaseous mercury in flue gas, in which, after water-insoluble mercury in the flue gas is converted into water-soluble mercury by placing the flue gas in contact with a solid catalyst formed by a metal oxide, wet-type absorption is performed on the water-soluble mercury.Type: GrantFiled: July 14, 2005Date of Patent: November 17, 2009Assignees: IHI Corporation, Central Research Institute of Electric Power IndustryInventors: Takashi Kiga, Noriyuki Iiyama, Kenji Takano, Akimasa Yamaguchi, Yoshihisa Tochihara, Shigeo Ito
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Patent number: 7611684Abstract: An effluent gas scrubber and a method of scrubbing effluent gases are provided. An inlet port receives an effluent gas. The gas passes through successive chambers in which it is sprayed with a scrubbing fluid. An oxidizer within the scrubbing fluid is effective to oxidize non-water soluble gases within the effluent gas. An oxidation-reduction potential probe measures the oxidation-reduction potential of the scrubbing fluid and adds the oxidizer to the scrubbing fluid as needed. A pH probe measures the pH of the scrubbing fluid and adds a base to the scrubbing fluid as needed to maintain the pH at or above a threshold such as pH 7, or pH 12.Type: GrantFiled: August 8, 2007Date of Patent: November 3, 2009Assignee: Airgard, Inc.Inventors: Mark Johnsgard, Kris Johnsgard
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Patent number: 7611561Abstract: A diesel exhaust filter construction includes a rectangular filter block, an elongated non-rectangular jacket with oval cross section, and support structure supporting the filter block in a center of the jacket. The support structure includes shielding components forming an insulating air gap with the jacket around the filter block (including a double-layered air gap in “hot” areas), and further includes support structure slidably supporting one end of the filter block to accommodate dissimilar thermal expansion. The structure further includes baffling components with angled surfaces directing input exhaust gases along efficient flow paths from an inlet cone into front, rear, and opposite sides of the filter block and further directing output exhaust gases from top and bottom sides of the filter block toward a longitudinally-centered outlet cone. Some components are identical is shape and size for use in different locations on the construction, thus simplifying tooling.Type: GrantFiled: July 18, 2007Date of Patent: November 3, 2009Assignee: Benteler Automotive CorporationInventors: Frederick B. Hill, Jr., Michael J. Remenar
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Patent number: 7611680Abstract: An engine exhaust catalyst containing precious metal nanoparticles is promoted with bismuth. The bismuth promotion improves the catalyst's CO oxidation performance. Also, by varying the amount of bismuth that is added, the NO conversion rate that can be realized with the catalyst can be controlled. The control over the NO conversion rate is important because the passive regenerative performance of a particulate filter used in engine exhaust systems is based on the amount NO2 that is present in the exhaust stream that reaches the particulate filter. The amount of NO2 being produced needs to be optimized (not necessarily maximized) so that adequate particulate filter regeneration performance can be maintained while avoiding unused, toxic NO2 from being exhausted into the atmosphere.Type: GrantFiled: January 9, 2007Date of Patent: November 3, 2009Assignee: Nanostellar, Inc.Inventors: Jifei Jia, Kyle L. Fujdala, Timothy J. Truex
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Publication number: 20090269262Abstract: An air pollutant control system comprises: a denitration apparatus that reduces nitrogen oxide in flue gas discharged from a coal combustion boiler, and that sprays hydrogen chloride into the gas to oxidize mercury, an air heater that recovers heat in gas, a dust collector that reduces dust in gas, a desulfurization apparatus that reduces sulfur oxide in gas from which the dust has been reduced, a hydrogen chloride vaporizer that evaporates concentrated hydrochloric acid to obtain the hydrogen chloride, and a hydrochloric acid neutralization tank where dilute hydrochloric acid discharged from the hydrogen chloride vaporizer or the concentrated hydrochloric acid is neutralized with an alkali agent. Neutralized chloride is supplied to a fuel feeder, mixed with a fuel, and then burned as a fuel in a boiler to produce hydrogen chloride in flue gas. Together with sprayed hydrogen chloride derived from the hydrogen chloride vaporizer, the mercury is reduced.Type: ApplicationFiled: January 30, 2009Publication date: October 29, 2009Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.Inventors: Moritoshi MURAKAMI, Nobuyuki UKAI, Tatsuto NAGAYASU
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Publication number: 20090255236Abstract: A method of reducing nitrogen oxides (NOx) in a flowing combustion exhaust gas to N2, which method comprising oxidising nitrogen monoxide to nitrogen dioxide on a transition metal/elite catalyst at catalyst bed temperatures below 50° C. and reducing NOx with the catalyst using an hydrocarbon (HC) reductant at catalyst bed temperatures below 150° C.Type: ApplicationFiled: January 12, 2007Publication date: October 15, 2009Applicant: Johnson Matthey Public Limited CompanyInventors: Jillian Elaine Collier, Philip Gerald Blakeman, Paul James Millington, Raj Rao Rajaram, Isabel Zoe Tingay, Andrew Peter Walker
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Patent number: 7597865Abstract: Provided in a catalyst system are: a first reaction part fitted with a first catalyst containing, as active constituents, at least, a complex oxide consisting of two or more oxides selected from among silica, alumina, titania, zirconia, and tungsten oxide, and a rare earth metal or transition metal (except Cu, Co, Ni, Mn, Cr, and V); and a second reaction part fitted with a second catalyst containing, as active constituents, at least, a noble metal and a silica-alumina type complex oxide.Type: GrantFiled: February 1, 2005Date of Patent: October 6, 2009Assignees: Tokyo Roki Co., Ltd, Nissan Diesel Motor Co., Ltd.Inventors: Takayuki Mori, Nobuya Iwami, Takayuki Kumagai, Isamu Kanaya, Hiroki Ueno, Kiminobu Hirata
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Patent number: 7595033Abstract: A process and device for purifying flue gases in refuse incineration plants during regeneration of a catalyst which serves for reducing nitrogen oxides, by, in a first step, removing acidic pollutant gases from the flue gas in a wet or dry manner, in a second step adding ammonia for reducing nitrogen oxides to the flue gas purified in the first step, in a third step feeding the flue gas admixed with the ammonia to a catalyst, where the catalyst is heated at a controlled heat-up rate for regeneration, which leads to liberation of ammonia, where the amount of ammonia added in the second step and the heat-up rate in the third step are controlled by the amount of a pollutant gas selected from the group of ammonia, and which the purified flue gas contains.Type: GrantFiled: June 21, 2007Date of Patent: September 29, 2009Assignee: Von Roll Umwelttechnik AGInventors: Ruedi Frey, Sandrine Person
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Patent number: 7591987Abstract: A method for treating an ammonia (NH3)-containing gas, which comprises causing the NH3-containing gas to pass through a catalyst tower (9) firstly with a pre-treatment catalyst layer (1) having, in parallel, a flow path involving a catalyst layer having the function of oxidizing NH3 to form NO and a flow path involving a catalyst layer not having the above function, and then, contacting the resultant gas with a catalyst layer (2) having in combination, the denitration function and the function of oxidizing NH3 to form NO; and an apparatus for practicing the method.Type: GrantFiled: November 12, 2004Date of Patent: September 22, 2009Assignee: Babcock-Hitachi Kabushiki KaishaInventor: Yasuyoshi Kato
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Patent number: 7560079Abstract: An exhaust gas-purifying apparatus includes an NOx sorbing-and-reducing first catalyst, a filter second catalyst, and an NOx sorbing-and-reducing third catalyst, which are disposed in an exhaust system in this order from a downstream side to an upstream side of a flow of exhaust gases. In the exhaust system, a liquid reducing agent is supplied into the exhaust gases intermittently. The first catalyst exhibits a remarkably high NOx purifying ability, because not only the third catalyst and the second catalyst gasify, crack and homogenize the reducing gas fully but also the reactions at the third and second catalysts elevate the temperature of exhaust gases. Thus, the exhaust gas-purifying apparatus can purify PMs and NOx efficiently.Type: GrantFiled: August 23, 2004Date of Patent: July 14, 2009Assignee: Toyota Jidosha Kabushiki KaishaInventor: Seiji Okawara
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Patent number: 7560084Abstract: A system for separating sulfur dioxide from a gas using an aqueous absorption liquid. The system includes a housing, an apertured plate, an outlet box, a distribution mechanism, a container, and a pump. The housing has an inlet and an outlet. The apertured plate is positioned between the inlet and the outlet and includes a lower side, an upper side, and apertures fluidly connecting the lower and upper sides. The outlet box includes a distribution mechanism that is arranged so that the absorption liquid draining from the outlet box contacts the gas from the inlet before the gas passes through the apertures in the apertured plate. The container contains the absorption liquid and is fluidly connected with the housing. The pump draws the absorption liquid from the container through the pump and through a conduit to the upper side of the apertured plate.Type: GrantFiled: March 30, 2007Date of Patent: July 14, 2009Assignee: Alstom Technology LtdInventors: Dennis J. Laslo, Michael Chiang, David J. Muraskin, Michael J. Rini, Michael G. Varner
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Patent number: 7560088Abstract: A compact sulfur recovery system is disclosed which includes an upflow orientation for the gases through a primary structure including a catalytic partial oxidation reaction zone, a first temperature-control zone, a first Claus catalytic reaction zone, a second temperature-control zone, a first liquid sulfur outlet, and a first effluent gas outlet. The upward flow of the gases puts the hottest gases in contact with the tubes and tube sheet in the waste heat boiler where there is greater confidence in having liquid water in most continuous therewith.Type: GrantFiled: June 4, 2007Date of Patent: July 14, 2009Assignee: ConocoPhillips CompanyInventors: Alfred E. Keller, Sriram Ramani, Nathan A. Hatcher, Joe D. Allison, Steven E. Lusk, Larry D. Swinney, Kerri J. Kirkendall, Gilbert E. Torres, Paul D. Stewart, Terry D. Pruitt
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Patent number: 7556781Abstract: A pre-reformer (10) comprises a non-electrically conducting gas tight duct (12) and an electrically conducting wire (14) arranged in the duct (12). The electrically conducting wire (14) is electrically isolated from the duct (12). The duct (12) has an inlet (16) for receiving a hydrocarbon fuel at a first end (18) and an outlet (20) for supplying a pre-reformed hydrocarbon fuel at a second end (22). At least the inner surface (24) of the duct (12) is chemically inert with respect to the hydrocarbon fuel. An electrical power supply (26) is electrically connected to the electrically conducting wire (14) and a control means (28) controls the supply of electrical current through the electrically conducting wire (14) to maintain the electrically conducting wire (14) at a temperature to provide selective thermal decomposition of higher hydrocarbons in the hydrocarbon fuel. The performer reduces coking in associated fuel cells and other parts of a fuel cell system.Type: GrantFiled: July 6, 2004Date of Patent: July 7, 2009Assignee: Rolls-Royce, PLLCInventors: Gerard D Agnew, Robert H Cunningham, Gary J Saunders
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Patent number: 7544338Abstract: Provided is a system for removing mercury from a mercury-containing exhaust gas, which contains a mercury chlorinating agent feed unit for feeding a mercury chlorinating agent to an flue exhaust gas containing nitrogen oxide, sulfur oxide and mercury, a reductive denitration unit for reducing the nitrogen oxide, and a desulfurization unit for removing the sulfur oxide, characterized in that the mercury chlorinating agent feed unit further comprises a heating unit for heating a non-gaseous agent for mercury chlorination which is in the non-gaseous form under normal temperature and normal pressure or a gasifying unit for obtaining a gaseous agent for mercury chlorination from the non-gaseous agent for mercury chlorination. The present invention makes it possible to provide a mercury removal process and system which have high reliability and can be operated at a low cost.Type: GrantFiled: December 12, 2006Date of Patent: June 9, 2009Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shintaro Honjo, Kenichi Okada, Susumu Okino, Yasuhiro Takeuchi, Satoru Sugita, Yoshio Nakayama
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Patent number: 7524470Abstract: One aspect of the invention relates to a method for removing contaminants from a flue gas stream (22). The method includes: removing fly ash from a flue gas stream (22) utilizing a particle collector (24); contacting the flue gas stream with an alkaline reagent in a wet scrubber (26); discharging a purge liquid (30) from the wet scrubber (26); combining at least a portion of the purge liquid (30) with at least a portion of the fly ash (48) to form moistened fly ash (60); and injecting at least a portion of the moistened fly ash (60) into the flue gas stream (22) upstream of the particle collector (24), whereby the moistened fly ash (60) removes at least a portion of contaminants present in the flue gas stream (22).Type: GrantFiled: July 13, 2006Date of Patent: April 28, 2009Assignee: Alstom Technology LtdInventors: Kelly L. Barger, Gregg Robert Doulé, Michael G. Varner
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Patent number: 7521033Abstract: The present invention is directed to an improved apparatus and method of minimizing catalyst poisoning from exhaust gas streams containing inorganic deposits and particulate matter. More specifically, the present invention is directed to an upstream metallic foam trap and a downstream monolithic precious metal catalyst, wherein the trap physically blocks inorganic deposits and particulate matter from poisoning the downstream catalyst. The present invention is also directed to a metallic foam trap containing a coat comprising a first metallic thermal arc sprayed layer and optionally a second refractory metal oxide.Type: GrantFiled: December 22, 2005Date of Patent: April 21, 2009Assignee: BASF Catalysts LLCInventors: Michael Patrick Galligan, Joseph Charles Dettling
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Patent number: 7521030Abstract: A material contaminated with a solvent is treated with a hydrofluorocarbon to remove the contaminant. A preferred hydrofluorocarbon is tetrafluoroethane. Apparatus for carrying out the process is also described.Type: GrantFiled: December 5, 2005Date of Patent: April 21, 2009Assignee: Glaxo Group LimitedInventor: Mazin Nicola
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Patent number: 7521031Abstract: A method for treating exhaust gas includes: adsorbing target components in the exhaust gas with an adsorbent (5); introducing a nitrogen gas with an oxygen concentration of 10 vol % or less and a purity of 90 vol % or more into the adsorbent (5); and applying (6, 7, 8) nonthermal plasma to the adsorbent (5). After the adsorbent (5) adsorbs the target components in the exhaust gas, the nitrogen gas is introduced into the adsorbent (5), and then an electric discharge is generated so that the nonthermal plasma of the nitrogen gas is applied to the adsorbent (5) and causes desorption of the target components and regeneration of the adsorbent (5). This method can remove the target components effectively from oxygen-containing exhaust gas by using nitrogen gas plasma with high activity as a result of ionization of a nitrogen gas and combining adsorption, desorption by the nitrogen gas plasma, and nitrogen plasma treatment.Type: GrantFiled: October 6, 2004Date of Patent: April 21, 2009Assignee: Osaka Industrial Promotion OrganizationInventors: Masaaki Okubo, Toshiaki Yamamoto, Tomoyuki Kuroki
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Patent number: 7506504Abstract: The present invention is directed to an emission treatment system for the treatment and/or conversion of engine emissions and particulate matter from diesel engines. The emission treatment system of the present invention comprises an upstream oxidation catalyst, a particulate filter or soot filter section and optionally a downstream catalytic element or clean-up catalyst for the treatment and/or conversion of any remaining emission gas stream contaminants.Type: GrantFiled: December 21, 2005Date of Patent: March 24, 2009Assignee: BASF Catalysts LLCInventor: Sanath V. Kumar
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Patent number: 7501104Abstract: A discharge gas treatment apparatus and method which lower treatment cost and which attain efficient removal of mercury contained in a discharge gas are provided. The discharge gas treatment apparatus, includes a cooling apparatus for controlling the temperature of the discharge gas to a predetermined temperature in accordance with the hydrogen chloride concentration of the discharge gas; an NOx removal catalyst unit for reducing nitrogen oxide contained in the discharge gas and for causing reaction between mercury and hydrogen chloride contained in the discharge gas, the discharge gas having been controlled to the predetermined temperature and having been introduced to the apparatus, with ammonia being added thereto; and a wet-format desulfurization apparatus, disposed on the downstream side with respect to the NOx removal catalyst unit, for removing sulfur oxide and mercury chloride contained in the discharge gas through dissolving sulfur oxide and mercury chloride in a liquid absorbent.Type: GrantFiled: August 30, 2006Date of Patent: March 10, 2009Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Yoshiaki Obayashi, Kozo Iida, Toshio Koyanagi
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Patent number: 7501111Abstract: Claus sulfur recovery plants that include one or more single-stage or multi-stage compact tubular Claus catalytic reactor-heat exchanger units are disclosed. In some instances, these new or improved Claus plants additionally include one or more compact heat exchanger containing cooling tubes that are filled with a heat transfer enhancement medium. The new compact tubular Claus catalytic reactor-heat exchanger units and HTEM-containing heat exchangers are also disclosed. A process for recovering sulfur from a hydrogen sulfide-containing gas stream, employing the new tubular Claus catalytic reactor-heat exchanger unit, and in some instances a HTEM-containing heat exchanger, are also disclosed.Type: GrantFiled: August 25, 2006Date of Patent: March 10, 2009Assignee: Conoco Phillips CompanyInventors: Alfred E. Keller, Sriram Ramani, Joe D. Allison, Steven E. Lusk, Nathan A. Hatcher, Larry D. Swinney, Rebecca S. Shaver
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Patent number: 7498009Abstract: A method for reducing or substantially eliminating oxides of nitrogen from an effluent gas stream, that includes providing a source of ultraviolet radiation with a precise wavelength, adding ammonia or an ammonia based reagent to the effluent stream, upstream of the ultraviolet radiation source, controllably operating the ultraviolet radiation source to irradiate the effluent stream flowing in the duct and substantially reducing or eliminating oxides of nitrogen by promotion a reaction of ammonia with the oxides of nitrogen to produce N2 and H2O, and also thereby destroying any surplus ammonia. This process can also be modified to oxidize carbon monoxide and VOC's to CO2 and H2O.Type: GrantFiled: August 11, 2005Date of Patent: March 3, 2009Assignee: Dana UV, Inc.Inventors: James T. Leach, Michael Lee Fraim
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Patent number: 7494634Abstract: Systems and methods of removing at least nitrogen oxides from an exhaust fluid generally include dividing a flow of an exhaust fluid comprising a concentration of nitric oxide into three types of flow-through cells. The first flow-through cell comprises a catalyst configured to reduce the nitric oxide with a reductant to form a first feedstream comprising nitrogen containing species derived therefrom. The second flow-through cell comprises a catalyst configured to oxidize nitric oxide to form a second feedstream comprising nitrogen dioxide. The third flow-through cell does not change the nitric oxide concentration and form a third feedstream comprising nitric oxide. After flowing through the three different types of cells, the feedstreams are mixed to form a homogenous mixture and then fed to a catalyst bed configured to convert the nitrogen containing species, the nitric oxide, and the nitrogen dioxide to a fluid comprising nitrogen gas and water.Type: GrantFiled: January 10, 2007Date of Patent: February 24, 2009Assignee: General Electric CompanyInventors: Frederic Vitse, Dan Hancu, Benjamin Hale Winkler
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Patent number: 7494625Abstract: Regenerative selective catalytic reduction (RSCR) systems and process are provided whereby NOx levels in gases are reduced by mixing the gas with a reactant and then introducing the gas into an RSCR apparatus for treatment that entails heating the gas, causing the gas to undergo one or more catalytic reactions, and then directing the gas through a heat transfer area, to which the gas provides heat for use in connection with successive cycles of the RSCR process.Type: GrantFiled: November 12, 2007Date of Patent: February 24, 2009Assignee: Babcock Power Environmental Inc.Inventor: Richard F. Abrams
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Patent number: 7488461Abstract: An exhaust gas treatment system is provided that can sufficiently remove pollutants such as SO3 contained in combustion exhaust gas at low cost. In the exhaust gas treatment system for removing pollutants such as SO3 contained in combustion exhaust gas, there is provided dissolved salt aqueous solution sprays 35A, 35B, and 35C, that spray an Na2SO4 aqueous solution obtained from desulfurization effluent of a wet desulfurization system, into a flue though which the combustion exhaust gas flows.Type: GrantFiled: April 19, 2006Date of Patent: February 10, 2009Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Hiromitsu Nagayasu, Yasutoshi Ueda, Morio Kagami, Toshihide Noguchi
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Patent number: 7488462Abstract: Catalyst systems and methods provide benefits in reducing the content of nitrogen oxides in a gaseous stream containing nitric oxide (NO), hydrocarbons, carbon monoxide (CO), and oxygen (O2). The catalyst system comprises an oxidation catalyst comprising a first metal supported on a first inorganic oxide for catalyzing the oxidation of NO to nitrogen dioxide (NO2), and a reduction catalyst comprising a second metal supported on a second inorganic oxide for catalyzing the reduction of NO2 to nitrogen (N2).Type: GrantFiled: April 26, 2006Date of Patent: February 10, 2009Assignee: The Ohio State UniversityInventors: Umit S. Ozkan, Erik M. Holmgreen, Matthew M. Yung
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Publication number: 20090035192Abstract: By using catalytic partial oxidation or autothermal reforming process, a catalytic oxidizer installed in the engine's Exhaust Gas Recycle (EGR) line can be used to produce from fossil fuels or bio-fuels a reformate gas containing H2 and CO for an IC engine or a gas turbine. Thus, a system consisting of an EGR Oxidizer and an IC engine/gas turbine can be used by itself as a driving device, or can be combined with an electric generator and a battery bank to produce, store and transmit electricity to be used in stationary or mobile power generation, transportation and utility etc. The Oxidizer can also be used to provide reducing gases to regenerate the NOx or diesel particulate traps, so that the traps can continuously be used for reducing emissions from IC engine, diesel truck, gas turbine, power plant etc.Type: ApplicationFiled: July 1, 2008Publication date: February 5, 2009Inventor: Herng Shinn Hwang
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Patent number: 7485272Abstract: A first aspect of the present disclosure includes a method of controlling nitric oxides emissions. The method may include producing an exhaust gas stream containing NOx and supplying the exhaust gas stream to an exhaust passage. The method may further comprise supplying ammonia to the exhaust passage at a location upstream of a first selective catalytic reduction catalyst, wherein the amount of ammonia supplied at the first location is less than about 90% of the effective amount of ammonia needed for reduction of all NOx at the first location. Further, ammonia may be supplied to the exhaust passage at a second location downstream of the first selective catalytic reduction catalyst and upstream of a second selective catalytic reduction catalyst.Type: GrantFiled: November 30, 2005Date of Patent: February 3, 2009Assignee: Caterpillar Inc.Inventors: James Joshua Driscoll, David M. Milam
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Patent number: 7485271Abstract: A catalyst structure for treating exhaust gas from a lean burn internal combustion engine comprises a substrate monolith comprising a lean NOX catalyst (LNC) composition associated with at least one partial oxidation catalyst (POC), wherein the LNC composition is selected from the group consisting of: (a) silver or a silver compound supported on alumina; and (b) at least one metal selected from the group consisting of copper (Cu), iron (Fe), cobalt (Co) and cerium (Ce) supported on at least one zeolite, and wherein the at least one POC is selected from the group consisting of: (i) a bulk oxide, a bulk composite oxide or a bulk mixed oxide comprising at least one metal selected from the group consisting of manganese (Mn), iron (Fe), cerium (Ce) and praseodymium (Pr); and (ii) at least one of rhodium (Rh) and palladium (Pd) disposed on at least one inorganic oxide support.Type: GrantFiled: August 9, 2004Date of Patent: February 3, 2009Assignee: Johnson Matthey Public Limited CompanyInventors: Stanislaw Edmund Golunski, Valerie Marie Renee Houel, Andrea Hawkings, David William James, Stephen David Pollington, Stephen Poulston, Raj Rao Rajaram
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Patent number: 7465429Abstract: This invention relates to a technique for removing nitrogen oxides (NOx) present in exhaust gases discharged from boilers and the like. When the temperature of the exhaust gas is 100° C. or below, a heat-treated active carbon produced by heat-treating a raw active carbon at 600 to 1,200° C. in a non-oxidizing atmosphere so as to remove oxygen-containing functional groups present at the surfaces thereof and thereby reduce the atomic surface oxygen/surface carbon ratio to 0.05 or less is preferably used. When the temperature of the exhaust gas exceeds 100° C., a heat-treated active carbon produced by heat-treating a raw active carbon at 600. to 1,200° C. in a non-oxidizing atmosphere and activating the surfaces thereof with sulfuric acid or nitric acid to impart oxidizing oxygen-containing functional groups thereto is preferably used.Type: GrantFiled: February 25, 2002Date of Patent: December 16, 2008Assignees: Osaka Gas Company Limited, Mitsubishi Jukogyo Kabushiki KaishaInventors: Isao Mochida, Akinori Yasutake, Toshihiko Setoguchi, Norihisa Kobayashi, Takahiro Kasuh, Masaaki Yoshikawa
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Patent number: 7462339Abstract: The present invention is directed to an improved apparatus and method of minimizing catalyst poisoning by inorganic deposits from lube oil additives and particulate matter, especially in aircraft. More specifically, the present invention is directed to an air purification system comprising an upstream metallic foam trap and downstream converter, wherein the trap physically blocks inorganic deposits and particulate matter from poisoning the downstream catalysts. The present invention is also directed to a metallic foam trap containing a coat comprising a first metallic thermal arc sprayed layer and optionally a second refractory metal oxide.Type: GrantFiled: December 29, 2005Date of Patent: December 9, 2008Assignee: BASF Catalysts LLCInventors: Michael Patrick Galligan, Rudolph H. Lechelt
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Patent number: 7462340Abstract: The disclosure involves a method for reducing the content of NOx and N2O in gases. The method includes the conduction of a gas containing N2O and NOX over a series of two catalyst beds containing of one or more zeolites charged with iron followed by the: addition of a reduction agent for NOX between the catalyst beds. The first catalyst bed reaction zone is used to degrade the N2O and the catalyst bed second reaction zone reduces the NOX and breaks down at least part of the remaining N2O. The inventive device comprises at least one radially traversed catalyst bed.Type: GrantFiled: June 10, 2003Date of Patent: December 9, 2008Assignee: Unde GmbHInventors: Meinhard Schwefer, Michael Groves, Rolf Siefert, Rainer Maurer
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Patent number: 7455818Abstract: A method treats a flow gas that is guided via a catalytic adsorber module to oxidize contaminants carried in the flow gas. The method reliably purifies the flow gas using equipment that is held to a comparatively low level of complexity. To this end, the flow gas is guided in a first purification step via a first catalytic adsorber module to oxidize contaminants carried along therewith, during which molecular or atomic oxygen is added to the flow gas, and the flow gas mixed with the added oxygen is guided in a second purification step via an oxidation catalyst. The flow gas flowing away from the oxidation catalyst is guided in a third purification step via a second catalytic adsorber module to reduce excessive oxygen.Type: GrantFiled: April 4, 2005Date of Patent: November 25, 2008Assignee: Areva NP GmbHInventor: Axel Hill
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Patent number: 7442346Abstract: As a device for the purification of exhaust gas, a three-way catalyst A purifying hydrocarbon, carbon monoxide and nitrogen oxide in the vicinity of theoretical air-fuel ratio is disposed at an upstream side of the exhaust gas and an adsorption catalyst B provided with zeolite effective for the adsorption of hydrocarbon is disposed at a downstream side of the exhaust gas.Type: GrantFiled: December 1, 1994Date of Patent: October 28, 2008Assignee: Nissan Motor Co., Ltd.Inventors: Takuya Ikeda, Maki Kamikubo
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Publication number: 20080260610Abstract: The invention, in at least one embodiment, relates to a reverse platinum group metal zoned lean NOx trap system included in a vehicle and its method of use. One embodiment of the trap system is in a vehicle exhaust system operable during lean and rich periods. The trap system may include a first trap having a first substrate supporting a quantity of platinum and a second trap, positioned downstream of the first trap, and having a second substrate supporting a quantity of platinum and a quantity of rhodium. The total loading of platinum plus rhodium on the second trap is greater than or equal to the platinum on the first trap. In at least one embodiment, the second trap has a higher overall NOx conversion at a low temperature and the first trap has a higher overall NOx conversion at a high temperature.Type: ApplicationFiled: March 14, 2008Publication date: October 23, 2008Applicant: FORD GLOBAL TECHNOLOGIES, LLCInventors: Joseph Robert Theis, Robert Walter McCabe, Justin Anthony Ura
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Multi-stage heat absorbing reactor and process for SCR of NOx and for oxidation of elemental mercury
Patent number: 7438876Abstract: A selective catalytic reduction apparatus has at least first and last catalyst layers in series for reducing nitrogen oxides in a flue gas, at least one interstage heat exchanger located after the first layer and before the last layer, that lowers flue gas temperature, and that acts as a mixing body to lower the standard deviation of the NH3/NO ratio entering catalyst layers after the first catalyst layer, thus providing better consumption of both ammonia and NOx in the reactor than would be achieved in the absence of the at least one interstage heat exchanger.Type: GrantFiled: August 27, 2004Date of Patent: October 21, 2008Inventor: J. Edward Cichanowicz -
Patent number: 7431905Abstract: A catalyst system for the reduction of NOx. is provided. The system comprises a catalyst in a first zone comprising a catalyst support, a catalytic metal comprising gallium, and at least one promoting metal selected from the group consisting of silver, gold, vanadium, zinc, tin, bismuth, cobalt, molybdenum, tungsten, indium and mixtures thereof; a catalyst in the second zone comprising a second catalyst support, a second catalytic metal selected from the group consisting of indium, copper, manganese, tungsten, molybdenum, titanium, vanadium, iron, cerium and mixtures thereof The catalyst system further comprises a gas stream comprising an organic reductant. The catalyst system may further comprise a catalyst in a third zone; the catalyst comprising a third catalyst support and a third catalytic metal selected from the group consisting of platinum, palladium, and mixtures thereof. A method for reducing NOx utilizing the catalyst system is also provided.Type: GrantFiled: October 4, 2005Date of Patent: October 7, 2008Assignee: General Electric CompanyInventors: Dan Hancu, Jonathan Lloyd Male, Jennifer Kathleen Redline, Stanlee Teresa Buddle, Teresa Grocela Rocha, Alison Liana Palmatier, Benjamin Rue Wood, Job Thomas Rijssenbeek
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Publication number: 20080241030Abstract: Methods and apparatus utilizing chlorine dioxide and hydrogen peroxide are useful to reduce emissions of NOx, SOx, and heavy metals, e.g., mercury, emissions from combustion flue gas streams.Type: ApplicationFiled: March 28, 2007Publication date: October 2, 2008Applicant: U.S.A. Represented by the Administrator of the National Aeronautics and Space AdministrationInventors: Clyde F. Parrish, Landy Chung
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Publication number: 20080241031Abstract: Disclosed herein are sorbents and devices for controlling sulfur oxides emissions as well as systems including such sorbents and devices. Also disclosed are methods for making and using the disclosed sorbents, devices and systems. In one embodiment the disclosed sorbents can be conveniently regenerated, such as under normal exhaust stream from a combustion engine, particularly a diesel engine. Accordingly, also disclosed are combustion vehicles equipped with sulfur dioxide emission control devices.Type: ApplicationFiled: March 30, 2007Publication date: October 2, 2008Inventors: Liyu Li, David L. King
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Patent number: 7429365Abstract: A method for continuously removing mercury from a supply of combustion gas is provided. The method includes introducing SO3 into the supply of combustion gas to oxidize at least a portion of elemental mercury within the supply of combustion gas into ionic mercury. A turbulent flow of combustion gas is produced to suspend particulate matter including fly ash contained in the supply of combustion gas. A substantial portion of the mercury is absorbed within the particulate matter. The supply of combustion gas is filtered to remove the particulate matter from the mercury. The introduction of SO3 into the combustion gas is controlled based at least partially on at least one of an oxidation rate of mercury and an absorption rate of mercury.Type: GrantFiled: November 18, 2005Date of Patent: September 30, 2008Assignee: General Electric CompanyInventor: Robert W. Taylor