Abstract: A component made of superalloy is provided with a localized coating formed from three layers by a brazing heat treatment, the layers comprising an outer layer having a composition adapted to the specific surface properties sought, an inner layer having a composition which includes flux elements, and an intermediate layer obtained by the deposition of a mixture of the materials used for the other two layers.

Abstract: Stable nuclei of a conductive material are formed on a substrate in a first PVD process either by the adsorption of a nucleus forming gas onto the substrane surface and the subsequent deposition of the conductive material, or by the deposition of the conductive material at a partial pressure of a nucleus forming gas of less than 10.sup.-8 Torr, and afterward, a thin and continuous film of the conductive material is formed in a second PVD process. The substrate temperature is controlled so as not to exceed room temperature in the first PVD process, and so as to substantially exceed room temperature in a second PVD process. A thin and continuous film of a conductive material is also obtained by interrupting the deposition of the conductive material on a substrate provided with via-holes of small size by a PVD process, annealing the deposit, and then re-depositing the conductive material to obtain a continuous film.

Abstract: The present invention describes a process for protecting aluminum nitride circuit substrates during electroless plating using a sol-gel technique. The aluminum nitride substrate is coated with a metal. The coated substrate is etched to form a circuit pattern thereby exposing the aluminum nitride. The etched substrate is placed in a solution of tetraethylorthosilicate and withdrawn. The substrate is dried in air and then baked in an oven to remove all of the organic solvents leaving a stoichio metric film of silica on the exposed substrate. The substrate is then placed in an electroless plating solution and the circuit pattern is plated to a predetermined thickness.

Abstract: A heat transfer insulated part including a heat transfer substrate formed of a sintered metal of Cu-W or Cu-Mo, an insulating ceramic layer for electrically insulating the heat transfer substrate, formed of ceramic such as Al.sub.2 O.sub.3, SiO.sub.2 and Si.sub.3 N.sub.4, and a barrier layer provided between the heat transfer substrate and an insulating ceramic layer composed of at least either one of metal layers of W and Mo. Furthermore, preferably, an intermediate layer composed of titanium carbide and/or titanium nitride and so forth for enhancing the adhesive property between the insulating ceramic layer and the barrier layer is provided.

Abstract: A method for manufacturing a rotary anode for use in an X-ray tube is proposed. The method has the step of forming, on a graphite substrate plate, an intermediate layer of rhenium by subjecting a metallic chloride to the thermal decomposition CVD process at a substrate temperature of 1200.degree. C. or more. The method further has the step of forming, on the intermediate layer, an X-ray generating layer of tungsten or tungsten-rhenium alloy by subjecting a metallic fluoride to the hydrogen reduction thermal CVD process.

Abstract: A gas discharge tube using a tunnel effect type electron emitting device as a cathode is provided. The electron emitting device comprises a conductive metal base and a dielectric film formed preferably of a material containing MgO as a main component on the metal base. The dielectric film faces an anode and is exposed to a gas in the tube. In the cathode of this structure, discharge is effected at a relatively low DC voltage.

Abstract: Superalloy articles are made more oxidation resistant by a process which includes heat treating the article in the presence of foreign chemical species, at a temperature at which the foreign chemical species reacts with and modifies any oxide film present on the article surface. The heat treatment is best carried out at a temperature above the gamma prime solvus temperature of the article and below the incipient melting temperature of the article. Alternatively, the heat treatment may be carried out within the range defined by the incipient melting temperature of the article and about 150.degree. C. below the incipient melting temperature of the article. At such temperatures the foreign chemical species reacts with and modifies the oxide film on the article surface. Sulfur is then able to diffuse through such modified film, and a more oxidation resistant component is produced.

Abstract: A coated metal substrate with a ceramic composition and method which involves applying several layers of the following materials:a. stainless steelb. thermal shock resistant ceramic coating; andc. abrasion resistant ceramic material.Each layer of each material is applied by flame spray means to the metallic substrate which is at a temperature above 250.degree. F. but below 500.degree. F., which is then cooled to a temperature below 250.degree. F. before applying the next layer. Zirconium oxide is a preferred thermal shock resistant ceramic coating and aluminum oxide is the preferred abrasion resistant ceramic material.

Abstract: A heat resistant stainless steel coated by diffusion of aluminum and a method of aluminum diffusion coating for heat resistant stainless steels containing nickel and chromium. The stainless steel is buried in a diffusion coating pack powder composed of an aluminum source, an activator and inert filler materials. The coating is heat treated to form a chromium-rich intermediate layer without forming an interdiffusion layer containing aluminide precipitates under an aluminide layer.

Abstract: A process for tinning plated wire involves first the placing of the wire in a suitable chemical flux for a period of time, the wire is then immersed for a period of time into a static solder pot having molten solder therein, the wire is then re-immersed into the chemical flux for a period of time, and finally the wire is immersed for a period of time into an ultrasonic solder pot having molten solder therein, the wire when removed from the ultrasonic pot being sufficiently tinned such that the solder has formed a suitable intermolecular bond to the plating in accordance with typical bonding criteria.

Abstract: An improved process is disclosed for depositing a layer of metal on a semiconductor wafer wherein a shadow ring normally engages the end edge of the front surface of the wafer to inhibit deposition of the metal on the backside of the wafer and a barrier or nucleation layer is deposited on the unshielded portion of the front surface of the wafer prior to the deposition of the metal layer thereon, and wherein gases used to form the metal layer may contact and react with underlying materials on the front surface of the wafer beneath the shadow ring.

Abstract: Gases such as hydrogen/hydrocarbon may be separated by a separating membrane of a Group VIII noble metal on a deposit of non-noble Group VIII metal which is supported on a porous silver or a porous carbon body.

Abstract: The method for manufacturing the printed wiring board having a shield layer of the present invention is characterized in that, in a method for manufacturing a printed wiring board wherein a printed wiring circuit is provided on one or both sides of an insulating board and a shield layer is provided on the printed wiring circuit through an insulating layer, a shield layer and an earth circuit are formed on the insulating layer while injecting under pressure a coating for shield from a filling nozzle through a mask.

Abstract: A process for protecting aluminum nitride circuit substrates during electroless plating using surface oxidation. The aluminum nitride substrate is coated with a metal stack. The coating on the substrate is etched to form a circuit pattern. The patterned substrate is then fired in an oxidizing atmosphere at a temperature and time sufficient to convert the exposed aluminum nitride to aluminum oxide. After this conversion, the substrate is plated in an electroless solution forming a microwave circuit ready for component attachment and packaging.

Abstract: A cell employing a cup-shaped terminal that has a concave surface coated by electrodeposition of a metal such that the deposited metal contacts the cell's anodic mixture so that the anodic mixture can be made with little or no mercury. A method for producing cup-shaped terminals with a metal electrodeposited on only one side is also disclosed.

Abstract: A method of forming thallium, barium, calcium, copper oxide films with smooth surfaces and chemical uniformity by sequentially depositing layers and annealing in the absence of a separate source of Tl.

Abstract: The present invention provides a method for producing a highly corrosion resistant organic composite-plated steel sheet which is inhibited from liberation of chromium, which comprises forming a chromate film comprising a composition of the following (A) as a first layer at a coating amount of 5-150 mg/m.sup.2 as a solid film on the surface of a zinc or zinc alloy plated or zinc composite alloy plated steel sheet and then, coating on the first layer an organic solvent coating composition of the following (B) as a second layer at a thickness of 0.3-5 .mu.m as a solid film.(A) coating type chromate bath composition1 Cr.sup.6+ : 1-30 g/l,2 Cr.sup.3+ : 1-30 g/l,3 Cr.sup.6+ /Cr.sup.3+ weight ratio: 0.2-2.0,4 HF+H.sub.3 PO.sub.4 : 1-60 g/l,5 HF+H.sub.3 PO.sub.4 /Cr.sup.3+ weight ratio: 0.5-3.5, and6 silane coupling agent/Cr.sup.6+ molar ratio: 0.05-0.

Abstract: The present invention provides a methodology for forming an electrically conductive contact on the external surface of superconductive materials. The methodology is employed using any Noble metal to form the conductive contact; and is used with any superconductive material conventionally known. The resulting conductive contact provides a low electrical resistance and firm point of electrical junction for the superconductor with any conductive material in any electrical circuit or use.

Abstract: An improved process is provided for forming a multilayer structure (18) suitable for tape automated bonding thereto or for forming contacts. In the process, a first layer (12) of aluminum is formed on a substrate (10), a second layer (14) of a TiW alloy is formed on the first layer of aluminum, and a third layer (16) of gold is formed on the second layer of the TiW alloy, to which third layer of gold bonding is done. The improvement comprises annealing the second layer of the TiW alloy in an inert atmosphere at a temperature less than about 500.degree. C. for a period of time sufficient to form a film of an Al--TiW phase (20), believed to comprise TiAl.sub.3, at the interface between the first layer of aluminum and the second layer of the TiW alloy. The annealing is done prior to forming the third layer of gold on the second layer of the TiW alloy.

Abstract: The invention is directed to a method for forming a metal coating on a substrate by applying an oxalate of a Group VIII element from the Periodic Table of the Elements to the substrate. The oxalate is selected so that it will decompose to a complex of a zero valent Group VIII element or a Group VIII element on exposure to an energy source. Microelectronic circuits, etch masks or metal contacts on superconductors can be formed by the method when the oxalate coating is exposed to an energy source through a mask or the energy source beamed at the oxalate to trace a pattern on it.The metal thus obtained can be subsequently coated by electroless compositions especially where the Group VIII element is a catalyst for electroless coatings such as palladium. Additionally, the metal coating may be coated by an electrolytic composition.

Abstract: A miniature zinc-air cell employing an anode cup that has an inner indium layer deposited over a copper layer on a conductive substrate such that the indium layer contacts the anodic mixture of the cell so that the anodic mixture can be made with little or no mercury. A method for producing anode cups is also disclosed.

Abstract: The oxidation resistance of MCrAlY-type overlay coatings is improved by incorporating small discrete oxide particles into the coating. The particles are preferably yttrium oxide, and the coating is applied by simultaneously plasma spraying MCrAlY-type powder particles and oxide particles onto a substrate in a nonoxidizing atmosphere. Improvements in resistance to rumpling has also been observed in coatings applied according to this invention.

Abstract: An extremely hard, fine grained tungsten carbide produced by thermochemical deposition is described. The tungsten carbide consists primarily of substantially pure tungsten carbide wherein the tungsten carbide consists of WC.sub.1-x, where x is 0 to about 0.4. The disclosed tungsten carbide is free of columnar grains and consists essentially of extremely fine, equiaxial crystals. Also disclosed is a method of producing the disclosed material.

Abstract: A structural component made of an iron-base alloy is protected against corrosion by a coating which is produced to have three layers. First, a primary coating or first layer is applied, and then a top coating or second layer is applied. An intermediate layer is formed by a reaction between the first and second layers. Specifically, the intermediate layer is formed after application of the primary coating and of the top coating, by a heat treatment within a reaction temperature range in which intermetallic nickel aluminum or cobalt aluminum compounds are formed. A fourth sealing coat is optional. The primary coating is a nickel or cobalt coating. The intermediate layer comprises intermetallic compounds of nickel aluminide or cobalt aluminide formed by the reaction. The top coating is an aluminum base or aluminum alloy base high-temperature lacquer including a binder. Such a combination coating is especially resistant to fretting, oxidation and etching corrosion.

Abstract: A method of protecting and a protective coating for metal components formed of nickel or cobalt-based superalloys are disclosed. The protective coating essentially consists of the following constituents (in percent by weight):1 to 20% rhenium,15 to 50% chromium,0 to 15% aluminum, the share of chromium and aluminum taken together being at least 25% and at most 53%,0.3 to 2% in total of at least one reactive element from the group consisting of the rare earths, and0 to 3% silicon,impurities, as well as the following elective components:0 to 5% hafnium,0 to 12% tungsten,0 to 10% manganese,0 to 15% tantalum,0 to 5% titanium,0 to 4% niobium, and0 to 2% zirconium,the total share of the elective components being from 0 to a maximum of 15%, and a remainder primarily being at least one of the elements iron, nickel, and cobalt. The protective coating is primarily suited for use with metal components in gas turbines and aircraft engines.

Abstract: A method for making a tin-coated steel sheet useful in manufacture of drawn and ironed cans eliminates the annealing step used in other manufacturing processes. The steel sheet comprises a steel slab having specified trace amounts of carbon, silicon, manganese, sulphur, aluminum, nitrogen and phosphorus, and has excellent formability and corrosion resistance.

Abstract: A metal electrode formed on an oxide superconductor for electric connection to the oxide superconductor, includes a first layer of Ag in direct contact with the oxide superconductor, and a second layer formed on the first layer. The second layer is formed of noble metal excluding Ag. The metal electrode can be formed by forming a first layer of Ag to cover a whole surface of the oxide superconductor layer, and forming a second layer of noble metal excluding Ag, to cover a whole surface of the first layer, thereby to form a double metal layer, and patterning the double metal layer so as to form a metal electrode composed of the double metal layer.

Abstract: An article is coated with a thermal barrier coating system to increase its thermal cyclic spallation life. A single layer bond coating is applied to the surface of the article to a surface roughness in the range of 200 to 600 microinches RA by low pressure plasma spraying of coarse MCrAlY alloy particles into the surface. A metal selected from aluminum and its alloys is applied to the bond coating by aluminiding and is diffused into the bond coating to provide an aluminum-rich bond coating metal outer surface, while substantially retaining the surface roughness of about 2300 to 600 microinches RA. A metal oxide thermal barrier coating layer is then applied onto the aluminum-rich bond coating outer surface.

Abstract: A printed-wiring board shielded from electromagnetic wave radiation is made by forming a conductive circuit pattern on an insulating substrate, disposing a first insulating layer over the circuit pattern, forming a jumper wire over the first insulating layer and between connecting terminals of the conductive pattern, forming a second insulating layer covering the jumper wire and the first insulating layer, and disposing an electromagnetic wave shielding layer over the conductive pattern. The jumper wire is formed by a printing process using a conductive paste containing a conductive metal such as silver, carbon or copper. The shield layer is formed by a printing process using a conductive metal resin paste such as copper. The shield layer is protected by providing an overcoat layer over the shield layer.

Abstract: An article comprising a non-conductive substrate having a sub-micron thickness of an oxidizable conductive first metal coating thereon, and a second (promoter) metal which is galvanically effective to promote the corrosion of the first metal, discontinuously coated on the first metal coating. Optionally, the second metal-doped, first metal-coated substrate may be further coated with a salt, to accelerate the galvanic corrosion reaction by which the conductive first metal coating is oxidized. Also disclosed is a related method of forming such articles, comprising chemical vapor depositing the first metal on the substrate and chemical vapor depositing the second metal on the applied first metal coating, and of optionally applying a salt by salt solution contacting of the second metal-doped, first metal-coated substrate. When utilized in a form comprising fine-diameter substrate elements such as glass or ceramic filaments, the resulting product may be usefully employed as an evanescent chaff.

Abstract: Monatomic layers each formed of a single metal are sequentially formed on a substrate using a molecular-beam epitaxy to form a multilayered metal film consisting of a plurality of types of metals, and sequentially with formation the monatomic layers, nitrogen dioxide gas as an oxidizer is supplied to oxidize the multilayered metal film. The same operation is repeatedly performed a predetermined number of times to form an oxide high-temperature superconductor thin film having a predetermined thickness.

Abstract: There is provided a process for improving the resistance to corrosion of stainless steel by ion plating process, the process comprising coating a component-adjusted stainless steel having an Mn/S ratio of less than 100 as substrate with a Ti-layer for surface preparation, coating directly the resulting Ti-layer or indirectly a TiC-layer, which has been coated onto the Ti-layer in advance as intermediate, with a TiN-layer in a total thickness of 1 to 3 .mu.m.The TiN-coated stainless steel according to the present invention may be widely used as corrosion-resistant metallic materials for preparing articles which can be employed under wet conditions such as tableware.

Abstract: A membrane for extracting hydrogen from gaseous and gaseous-liquid mixtures at low temperature makes use of a palladium or palladium alloy substrate and permits reduction of the surface resistance of the substrate. The membrane includes combined coatings including vacuum-deposited palladium ions driven into the substrate with inert gas ions and an electrochemically applied catalyst coating in the form of palladium or palladium/platinum black. A method for fabricating the membrane and a method for using the membrane to separate ultra-pure hydrogen are also disclosed.

Abstract: The invention relates to materials for coating metal alloys or metals, which materials are intended to improve the performance of said alloys or metals.These materials have a composition which corresponds to the general formula Al.sub.a Cu.sub.b Fe.sub.c X.sub.d I.sub.e, wherein X represents one or more elements chosen from V, Mo, Ti, Zr, Nb, Cr, Mn, Ru, Rh, Ni, Mg, W, Si and the rare earths, and I represents the inevitable manufacturing impurities, e.ltoreq.2, 14.ltoreq.b.ltoreq.30, 7.ltoreq.c.ltoreq.20, O.ltoreq.d.ltoreq.10, with c+d.ltoreq.10 and a+b+c+d+e=100% of the number of atoms, and they contain at least 40% by mass of an icosahedral quasi-crystalline phase and/or a decagonal quasi-crystalline phase and have a grain size greater than 1,000 nm in the quasi-crystalline phase.These materials are useful, in particular, for coating copper, aluminium alloys or copper alloys in the manufacture of cooking utensils, anti-friction bearings, anti-wear surfaces and reference surfaces.

Abstract: A method and apparatus for automatically grit blasting and metal spraying a wall of a cylindrical vessel utilizing a pair of rails with arms slidably disposed thereon, which rotate 180.degree. in unison about the axis of the vessel and then reverse and are moved incrementally along the rails upon completion of each 180.degree. of rotation until the wall of the vessel is grit blasted by a grit blasting nozzle on each arm and then sprayed with multiple thin layers of molten metal by a molten metal sprayer on each arm. The grit blasting nozzle and molten metal sprayer may be interchangeably mounted on the arms or may be both installed and operated separately.

Abstract: The method of forming a high temperature resistant copper coating on a ceramic and/or enamel substrate, includes the steps of chemically depositing a copper layer having a thickness of at least 3 .mu.m on the substrate, heating the copper layer formed thereon at a temperature of from 200.degree. to 450.degree. C., mechanically treating the copper layer with brush and polishing means to consolidate an upper surface thereof and galvanically depositing an additional copper layer having a thickness of 3 .mu.m on the upper surface. The high temperature resistant copper coating for the ceramic or enamel substrate can stand a higher thermal load for a longer time than similar conventional coatings and can act to rapidly dissipate heat generated by electronic components.

Abstract: A metal fastener, suitable for use in connection with wood construction and coated with a polymeric residue produced by removing water from an aqueous dispersion of a film-forming, thermoplastic, predominantly aliphatic polyurethane resin, so as to thereby reduce penetration force, increase withdrawal force, and protect against corrosion, is disclosed. Before the polyurethane coating is applied, a zinc layer is applied so as to coat the fastener, and a chromate conversion layer is applied so as to coat the zinc layer.

Abstract: A metal fuel for producing power for propulsion is disclosed. The fuel is made up of a metal core, a metal barrier and an oxidizer layer. The combination of materials disclosed provides a means for melting the metal core so that it can be oxidized in an exothermic reaction to produce power. The metal fuel may also be stabilized with respect to auto-ignition by adding a binder layer. A method for producing the metal fuel is also described herein.

Abstract: Poppet valves are manufactured by rotating a metal spray deposition nozzle relative to a rod or tube about the longitudinal axis of the rod or tube to deposit metal at a localized region intermediate the ends of the rod or tube so as to form a flange-like accretion on the rod or tube, and subsequently cutting through the rod or tube and the accretion at the center of the localized region to form two poppet valve preforms which are then subjected to finishing treatments. Metals having differing properties of heat, wear and corrosion resistance may be coated upon one another in forming said accretion.

Abstract: A dry film lubricant is selectively applied to the plated, anodized, or conversion coated aluminum base material of an electrical connector part so as to maximize the corrosion protection on exposed surfaces while maintaining electrical conductivity on mating surfaces.

Abstract: A steel substrate is provided first with an aluminum intermediate layer and then, by a CVD process, with an outer layer of boron.

Abstract: Disclosed are a sliding material comprising a backing metal having a porous metal layer formed on the surface thereof in which pores are defined and a composition for impregnation coating impregnated and coated to the pores and the surface thereof, wherein the composition for impregnation coating is a composition composed of (a) 5-30 vol % of metal lead having a relative surface area of 1,000-8,500 cm.sup.2 /g in an average particle size, and the remaining portion substantially composed of PTFE, a sliding material comprising a backing metal having porous metal layer formed on the surface thereof in which pores are defined and a composition for impregnation coating impregnated and coated to the pores and the surface thereof, wherein the composition for impregnation coating is a composition composed of (b) 5-30 vol % of metal lead having a relative surface area of 1,000-8,500 cm.sup.2 /g in an average particle size, 0.

Abstract: A process for the production of a composition modulated alloy having a predetermined concentration is disclosed, in which alternating layers of at least two metals are successively deposited upon a substrate by electrodeposition, vacuum deposition, vapor deposition, or sputtering. The individual thicknesses of at least one metal's layers are varied in a predetermined manner. Pulsed galvanostatic electrodeposition using a tailored waveform is preferred. A copper-nickel concentration graded alloy is disclosed. Concentration graded alloys of predetermined concentration having at least one region of local homogeneity are also disclosed. The region of local homogeneity has a thickness corresponding to the thickness of two adjacent layers of different metals which have been diffusion annealed together. A pulsed electrodeposition/diffusion anneal process for production of such alloys is also disclosed.

Abstract: The present invention is designed to improve a method of deposition of coatings upon a metal or alloy substrate. The coating comprises aluminum or aluminide material interdiffused with a transition metal deposited by chemical vapor deposition which utilizes organometallic precursors to facilitate the deposition of the transition metal. The improvement permits better control of the process and permits coating of complex substrates including those with internal passages or holes. In the embodiment involving a first deposition of aluminum or aluminide coating, applicants have achieved deposition thereon of the transition metal. Platinum is the preferred transition metal to be used in the subject method. A product is taught. This product can be a component from a gas turbine engine.

Abstract: Free metals are electrolessly deposited in the presence of a latex of a polymer. Sols or gels containing metal-containing ions are mixed with a latex and the resulting sol/latex subsequently contacted with a reducing agent. The presence of the reducing agent with the latex at appropriate deposition conditions converts the metallic ions to free metal. The free metal is deposited in the form of a surface coating composition onto substrates for such purposes as decoration of substrates and electrically conductive coatings.

Abstract: A surgical prosthetic device for implant in a patient and method for making said device, the device comprising a composite structure having a solid metal substrate and a porous coating with multiple sintered layers. The porous coating has an external layer to accept bone ingrowth. An intermediate layer bonds the external porous layer to the substrate. The layers are applied in a process of multiple sintering, whereby each successive layer is individually sintered to the substrate or to the proceeding layer, as applicable. This process provides a porous area having increased strength of attachment between the substrate and the external porous layer. An acid etch solution promotes adhesion between the substrate and the intermediate layer thus increasing the consistency of the process. The initial sintering is held at elevated temperature for less time than the sintering of the external layer. At the end of each sintering step, the prosthesis is quick cooled using an inert gas, preferably helium.

Abstract: A structural component of titanium or titanium alloy is provided with a protective coating made substantially of an oxidation resistant and diffusion inhibiting base layer (2), an intermediate layer (3) forming a titanium fire inhibiting layer, and a cover layer (4) forming a passivating sealing layer. These layers are applied by various methods.

Abstract: A shaving razor has a blade provided with a sputtered hard coating of the boron carbide and with a fluoropolymer lubricant coating overlying the boron carbide coating and adhering directly thereto. The razor provides good durability and good shave performance.

Abstract: This invention relates to a method for manufacturing a vessel for storing radioactive waste, and to a method for manufacturing a vessel which withstands the heat generated by the radioactive waste without deforming and a method for manufacturing the vessel. A method for manufacturing a stainless steel vessel for radioactive waste according to the present invention comprises eliminating impurities on the surface of the stainless steel, stirring copper plating solution while filling the vessel therewith in order to keep the solution at a constant temperature, thereby precipitating the copper and plating the surface of the stainless steel vessel, and then filling the vessel with lead.

Abstract: Abradable wall structures for high temperature applications, such as in turbine housings and the like. The wall structures comprise a superalloy metal base plate supporting a superalloy metallic cellular structure, the cells of which are filled to a substantial extent with at least one ceramic core material providing high heat resistance, oxygen barrier and low thermal expansion properties. The invention involves the application of a porous or pore-forming surface composition to provide a corrosion-resistant, erosion-resistant abradable outer surface layer, the softness or porosity of which can be tailored to improve the abradability of the wall structure, while imparting oxidation-, corrosion- and erosion-resistance to the structure. The surface layer composition may comprise metal superalloy, ceramic or cermet base compositions containing fugitive or retained inert filler materials.