Metal Base Patents (Class 427/405)
  • Patent number: 5730853
    Abstract: A method for plating a graphite aluminum metal matrix composite material with nickel and gold utilizes the steps of: cleaning a surface of the metal matrix composite material so as to substantially remove grease and particulates therefrom; forming a layer of copper upon the surface of the metal matrix composite material; heating the copper layer to drive out entrapped fluids; applying acid to the copper layer to remove oxidation therefrom; forming a layer of nickel upon at least a portion of the layer of copper; heating the nickel layer to relieve stress therein; and electrolytically forming a layer of gold upon at least a portion of the layer of nickel.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: March 24, 1998
    Assignee: Northrop Grumman Corporation
    Inventors: Carl R. Smith, Marvin J. Back, Breton Johnson, John R. De Valle, Lawrence J. Maher
  • Patent number: 5725905
    Abstract: A method for selectively protecting a component made of an iron-base alloy, cobalt-base alloy or nickel-base alloy with a protective arrangement which protects select areas of the component from aluminizing or chromizing during gas diffusion coating, wherein a first layer acts as an interlayer and a second layer acts as a getter layer for reaction gases. The method comprises the steps of depositing a first layer of slip cast material comprising oxide ceramic particles carried in a low-carbon, halide free, liquid vehicle; depositing a second layer comprising metal or a metallic slip, which comprises at least 50% by weight of the base metal of the component and all major alloy constituents of the component; aluminizing or chromizing by gas diffusion coating; and removing the protective arrangement from the component.
    Type: Grant
    Filed: February 26, 1996
    Date of Patent: March 10, 1998
    Assignee: MTU Motoren- Und Turbinen-Union
    Inventors: Heinrich Walter, Horst Pillhofer, Michael Strasser, Frank Brungs, Ralph Kropp, Martin Schaipp
  • Patent number: 5725907
    Abstract: A metal material characterized in that the material comprises a substrate metal, a film comprising a nickel fluoride layer and formed on the substrate metal, and a film comprising a carbon layer and formed on the film.
    Type: Grant
    Filed: October 16, 1996
    Date of Patent: March 10, 1998
    Assignees: Hashimoto Chemical Co., Ltd., Mitsubishi Aluminum Co., Ltd.
    Inventors: Tadahiro Ohmi, Kazuo Chiba, Hideo Kume, Yutaka Mikasa, Matagoro Maeno, Yoshinori Nakagawa, Hiroto Izumi, Kazuhito Yamane
  • Patent number: 5721061
    Abstract: Si-Fe-Cr base coating alloys that significantly promote the oxidation resistance of niobium-base alloys and intermetallic materials when deposited and reaction bonded to the niobium-base material. The coating alloys are deposited and then reaction bonded to a niobium-base material to yield an oxidation-resistant coating comprising an interaction layer containing at least one oxidation-resistant Si-Fe-Nb-Cr intermetallic phase.
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: February 24, 1998
    Assignee: General Electric Company
    Inventors: Melvin Robert Jackson, Ann Melinda Ritter
  • Patent number: 5718950
    Abstract: The present invention provides a process for forming a multilayer film, by applying, onto a substrate, the following three coatings: (A) a coloring base coating containing a titanium white pigment and an aluminum flake and capable of forming a film having a value of N 7 to N 9 in Munsell's color system, (B) a white-pearl-like or silver-pearl-like base coating containing a scaly mica powder coated with titanium oxide, and (C) a clear coating in this order without substantially curing the resulting films of the coatings (A), (B) and (C); as necessary conducting preliminary drying at 50.degree.-100.degree. C. between the application of the coating (A) and the application of the coating (B) and/or between the application of the coating (B) and the application of the coating (C); and heating the three films to crosslink and cure them simultaneously. The multilayer film has excellent high white-iridescent appearance, color stability, etc.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: February 17, 1998
    Assignees: Kansai Paint Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Yoshiharu Komatsu, Tokio Suzuki, Mituru Muramoto
  • Patent number: 5705283
    Abstract: A rocket engine component is formed as a tungsten-copper composite substrate, and a functionally-gradient material coating overlying and contacting the substrate. The functionally-gradient material coating has a composition that varies nonlinearly through a thickness of the coating so as to minimize thermal stresses through the coating, and such that the functionally-gradient material coating is tungsten adjacent to the substrate and is rhenium remote from the substrate. In a preferred form, the functionally-gradient material coating includes a tungsten sublayer overlying and contacting the substrate, a tungsten-rhenium sublayer overlying and contacting the tungsten sublayer; and a rhenium sublayer overlying and contacting the tungsten-rhenium sublayer. The functionally-gradient material coating is preferably applied by a low-temperature deposition technique such as plasma enhanced chemical vapor deposition.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: January 6, 1998
    Assignee: Hughes Electronics
    Inventor: Kamleshwar Upadhya
  • Patent number: 5683756
    Abstract: A method for plating zinc substrates with 24K gold. The method includes precleaning the substrate; applying a paint base coat electrostatically; curing the base coat; plating the gold by vacuum metallization; applying a clear paint top coat; and curing the top coat.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: November 4, 1997
    Assignee: Batesville Casket Company, Inc.
    Inventors: James W. Tanner, Todd Dennis, Tim Chaffee
  • Patent number: 5674560
    Abstract: A method of forming a coating film, involving the steps of: (i) forming an electrodeposition coat on a substrate; (ii) forming thereon an impact resistant primer coat formed of (A) a polyolefin resin grafted with an acid component and (B) a butylated melamine resin, wherein the weight ratio (A/B) of the polyolefin resin to the melamine resin is 90 to 50 parts by weight of the polyolefin resin:10 to 50 parts by weight of the melamine resin; (iii) forming an intermediate coat thereon; and (iv) forming a top coat thereon. A laminated coating film may be obtained by the method disclosed.
    Type: Grant
    Filed: February 14, 1995
    Date of Patent: October 7, 1997
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hajime Tanigami, Kazuto Abe
  • Patent number: 5672394
    Abstract: A method of preparing electrodes is now described, which electrodes have enhanced adhesion of subsequently applied coatings combined with excellent coating service life. In the method, a substrate metal, such as a valve metal as represented by titanium, is provided with a highly desirable rough surface characteristic for subsequent coating application. This can be achieved by various operations including etching to ensure a roughened surface morphology. In subsequent operations, a barrier layer is provided on the surface of enhanced morphology. This may be achieved by operations including heating, as well as including thermal decomposition of a layer precursor. Subsequent coatings provide enhanced lifetime even in the most rugged commercial environments.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: September 30, 1997
    Assignee: Eltech Systems Corporation
    Inventors: Kenneth L. Hardee, Lynne M. Ernes, Richard C. Carlson
  • Patent number: 5670216
    Abstract: The present invention comprises a method for preparing a surface for application of a non-stick coating, the method wherein the surface to be prepared for non-stick coating is prepared by thermally spraying a stainless steel alloy containing at most 6.0% aluminum, and is substantially free of Nickel. The present invention further includes a cooking utensil having a substrate to which an intermediate layer, for receiving the non-stick coating, is prepared by thermally spraying the stainless steel alloy containing at most 6.0% aluminum, and is substantially free of Nickel.
    Type: Grant
    Filed: July 25, 1994
    Date of Patent: September 23, 1997
    Assignee: Regal Ware, Inc.
    Inventors: Albert Charley Oak, Leonard C. Brumbaugh, Daryl E. Crawmer
  • Patent number: 5667663
    Abstract: A ceramic thermal barrier coating layer for a superalloy article is caused to adhere to the superalloy article by applying platinum to the superalloy article and heat treating at a temperature of 1100.degree. C. to 1200.degree. C. for one hour. This causes aluminum to diffuse from the superalloy article into the platinum to form a platinum enriched outer layer which generally includes a platinum enriched gamma phase and a platinum enriched gamma prime phase. An alumina layer is formed between the platinum enriched outer layer and a ceramic coating. The platinum enriched gamma phase and the platinum enriched gamma prime phase in the outer layer reduces the migration of transition metal elements to the ceramic coating to enable a very pure alumina layer to be formed.
    Type: Grant
    Filed: December 19, 1995
    Date of Patent: September 16, 1997
    Assignees: Chromalloy United Kingdom Limited, Rolls-Royce plc
    Inventors: David S. Rickerby, Stanley R. Bell, Rodney G. Wing
  • Patent number: 5667843
    Abstract: The protection against black and white rust on zinciferous surfaces by a conventional chromating treatment is improved by drying into place on the zinciferous surface before chromating a pre-treatment composition that contains hexavalent chromium ion plus one or more salts of nickel and cobalt, in an amount to produce an add-on of 0.5 to 100 mg/m.sup.2 of metal.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: September 16, 1997
    Assignee: Henkel Corporation
    Inventors: Noriaki Yoshitake, Kensuke Mizuno, Takao Ogino
  • Patent number: 5660886
    Abstract: An improved protective coating system for metal substrates is described. Nickel-aluminide duplex coatings are improved by adding an effective amount of boron in the nickel coating step and by retaining the boron during the aluminization step. An unexpected result of the retained boron is its non-deleterious effect on oxidation protection. During aluminization, the boron surprisingly migrates to the coating/substrate interface, forming a diffusion barrier in situ. The barrier inhibits both inward diffusion of the nickel-aluminide coating and outward diffusion of substrate impurities. The process enables thinner, less expensive coatings.
    Type: Grant
    Filed: April 24, 1995
    Date of Patent: August 26, 1997
    Inventors: Douglas J. Peterman, Joan E. Deffeyes, James E. O'Neal
  • Patent number: 5658614
    Abstract: A method of improving the oxidation resistance of a platinum modified aluminide coating formed on a nickel base superalloy substrate, comprises providing a platinum layer on the substrate, heating the substrate in a coating retort to a temperature of at least about 1000.degree. C., forming external of the coating retort a high purity coating gas comprising hydrogen and aluminum trichloride, and introducing the coating gas into the coating retort to contact the heated substrate to form an outwardly grown, single phase [(Ni,Pt)]Al] platinum modified aluminide coating having reduced concentration of at least one of a substrate substitutional alloying element and a surface active tramp element selected from at least one of B, P, and S in said coating as compared to a platinum modified aluminide coating formed at a lower temperature.
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: August 19, 1997
    Assignee: Howmet Research Corporation
    Inventors: William C. Basta, David C. Punola, Bruce M. Warnes
  • Patent number: 5645893
    Abstract: A coated article includes a superalloy substrate, an intermediate bond coat and a thermal barrier coating. The bond coat may include a platinum aluminide layer underlying a thin oxide layer. The thin oxide layer may include alumina. The coated article has high strength and durability at high temperatures over extended periods of time and thus is especially useful in the form of, e.g., a turbine blade or turbine vane.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: July 8, 1997
    Assignees: Rolls-Royce plc, Chromalloy United Kingdom Limited
    Inventors: David S. Rickerby, Daniel K. White, Stanley R. Bell
  • Patent number: 5643531
    Abstract: Disclosed is a manufacture and coating method of mechanical products using ferrous alloy in order to improve wear, corrosion, and heat resistances of the mechanical products which are exposed to friction and wear environments with or without lubricating conditions. The mechanical products of the invention include rotation contact parts such as bush and shaft in the inside of caterpillar roller, mechanical seal under high surface pressure, and drawing dice and plug under sliding friction stress. A ferrous alloy composition used for coating in the invention comprises Cr:18.0-42.0 wt %, Mn: 1.0-3.2 wt %, B:3.0-4.5 wt %, Si: 1.0-3.0 wt %, C: less than 0.3 wt %, inevitably incorporated impurities, and Fe for the rest of content. A ferrous alloy composition used for manufacturing bush type product comprises C: less than 4.5%, Si:2.5%, Mn:less than 2%, Cr:0.5-35%, and Fe for the rest of content.
    Type: Grant
    Filed: November 16, 1994
    Date of Patent: July 1, 1997
    Assignee: Samsung Heavy Industry Co., Ltd.
    Inventors: Kang-Hyung Kim, Maeng-Roh Park, Seung-Ho Yang, Yong-Kwon Chi
  • Patent number: 5629269
    Abstract: Disclosed is a process for forming a super-conducting film, which a multi-layer metal film (buffer film) is formed at a specific temperature on a ceramic substrate and a superconducting film is formed at a specific temperature on the multi-layer metal film. According to this process, a superconducting film having a high critical temperature can be formed over the ceramic substrate while controlling or suppressing the occurrence of a chemical reaction between the substrate and the superconducting film, and required superconducting performances can be manifested or exhibited.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: May 13, 1997
    Assignee: Fujitsu Limited
    Inventors: Kazunori Yamanaka, Takuya Uzumaki, Nobuo Kamehara, Koichi Niwa
  • Patent number: 5626909
    Abstract: Tool inserts are produced that can be brazed in air at temperatures as low as 700.degree. C. The tool compact, such as a polycrystalline diamond compact or a cubic boron nitride compact, has a multilayer coating comprising a metal bonding layer and a protective layer. Once coated with the bonding layer and the protective layer, the tool insert can be air brazed to a tool support in a manufacturing environment using a standard braze without a vacuum furnace or special atmosphere. A method for manufacturing the tool insert is also disclosed.
    Type: Grant
    Filed: December 7, 1994
    Date of Patent: May 6, 1997
    Assignee: General Electric Company
    Inventor: Charles D. Iacovangelo
  • Patent number: 5624712
    Abstract: Aluminum surfaces are protected with increased corrosion resistance by anodize, and sealing with a liquid fatty acid free of flammable solvents, suitably in the presence of a heterocyclic aromatic azole treating agent where the aluminum surface is of a copper containing aluminum alloy.
    Type: Grant
    Filed: June 8, 1995
    Date of Patent: April 29, 1997
    Assignee: Alumitec Products Corp.
    Inventor: Garson P. Shulman
  • Patent number: 5624721
    Abstract: A thermal barrier coating for superalloy turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes a ceramic layer applied to an aluminide or MCrAlY bond coat by electron beam physical vapor deposition. The ceramic layer has a first portion having unstabilized porosity, a second portion, overlying the first portion, with stabilized porosity, and an outer portion wherein the pores are coated with a noble metal. The stabilized porosity portion along with the noble metal coating reduce the thermal conductivity of the ceramic layer. Stabilizing the porosity renders it more resistant to sintering densification at high temperatures.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: April 29, 1997
    Assignee: AlliedSignal Inc.
    Inventor: Thomas E. Strangman
  • Patent number: 5616362
    Abstract: A process for coating metal substrates including cleaning, degreasing and activating the substrate wherein a strongly adhering bonding agent layer is deposited on the substrate. The bonding agent layer comprises a thickness of aluminum. The bonding agent layer is deposited at a temperature not exceeding 300.degree. C.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: April 1, 1997
    Assignee: Andritz-Patentverwaltungs-Gesellschaft m.b.H.
    Inventors: Gerhard Goldschmied, Gerhard Priesch
  • Patent number: 5607564
    Abstract: The invention relates to a method of producing a microporous, gas permeable electrode structure, and to a corresponding electrode structure. According to the method, on a substrate (2) by means of a vacuum evaporation process is formed a first microporous electrode layer (4) using an angle (.alpha.) between the substrate (2) and the evaporation source (1) smaller than 90.degree.. According to the invention, on the first microporous layer (4) is formed another microporous layer (5) of a precious metal using essentially the same evaporation angle (.alpha.) as in the fabrication step of the first microporous layer (4).
    Type: Grant
    Filed: January 11, 1995
    Date of Patent: March 4, 1997
    Assignee: Vaisala OY
    Inventor: Lars Stormbom
  • Patent number: 5605724
    Abstract: A method for minimizing reaction between metal conductors and other metals to minimize change in sheet resistance of the conductors upon heat treatment which includes providing a substrate. The substrate is preferably one of a dielectric, a metal or a semiconductor. A metallic diffusion barrier layer, preferably one of TiN, TiW or TiWN and preferably having a thickness of from about 10 nanometers to about 100 nanometers, is deposited on the substrate, preferably by one of sputtering, electron beam evaporation or chemical vapor deposition. The exposed surface of the metallic diffusion barrier layer is treated with a plasma, preferably an oxygen plasma, a nitrous oxide plasma or a plasma of an oxygen-containing species. An electrical conductor, preferably one of aluminum, aluminum-metal alloys, copper or copper-metal alloys and preferably having a thickness of from about 100 nanometers to about 1200 nanometers, is then deposited on the plasma-treated surface of the metallic diffusion barrier layer.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: February 25, 1997
    Assignee: Texas Instruments Incorporated
    Inventors: Qi-Zhong Hong, Robert H. Havemann
  • Patent number: 5595831
    Abstract: Steam or gas turbine components comprising chromium steel have their fluid directing surfaces protected from corrosion by a surface layer coating consisting essentially of major weight amount of nickel and minor weight amounts of zinc, optionally with boron added, over a nickel preplate which limits deleterious diffusion of zinc into the surface substrate.
    Type: Grant
    Filed: May 15, 1995
    Date of Patent: January 21, 1997
    Inventor: Eugene V. Clark
  • Patent number: 5582863
    Abstract: A process for forming a reflective surface, comprises the steps of: providing at least a part of at least one unanodized surface which has a peak-to-valley height Ra of equal to or less than 1 micron. The unanodized surface is selected from the group consisting of (1) refined aluminum with a degree of purity equal to or greater than 98.3% by weight aluminum and (2) aluminum alloys with at least one element selected from the group consisting of Si, Mg, Mn, Cu, Zn, Fe. The unanodized surface is in a form selected from the group consisting of rolled foil, rolled sheets, and rolled strips and said unanodized surface is used as a substrate. The process further includes depositing at least two layers from the gas phase on the unanodized surface, wherein the two layers include a ceramic adhesive layer from the gas phase and at least one reflecting layer from the gas phase on said adhesive layer for the reflection of radiation with wavelengths in the optical range.
    Type: Grant
    Filed: December 8, 1994
    Date of Patent: December 10, 1996
    Assignee: Alusuisse-Lonza Services Ltd.
    Inventors: Marcus Textor, Roman Fuchs, Volkmar Gillich, Erich Simon
  • Patent number: 5580669
    Abstract: A method is taught for preparing titanium alloys having high temperature oxidation resistance, whereby a coating of a copper bronze containing up to 10 percent aluminum and up to 6 percent silicon is applied to the titanium substrate by cathodic arc deposition or ion vapor deposition.
    Type: Grant
    Filed: October 20, 1995
    Date of Patent: December 3, 1996
    Assignee: United Technologies Corporation
    Inventors: Russell A. Beers, Douglas M. Berczik, Allan A. Noetzel
  • Patent number: 5580291
    Abstract: In a method for manufacturing a glow cathode for an electron tube, a layer of an alloy, such as iridium-lanthanum (Ir.sub.2 La), is produced on a substrate by coating the substrate, such as in a number of layers, with the components of the alloy by deposition from the vapor phase, such that the components of the alloy are present in the stoichiometrically correct ratio on the substrate, and in that the substrate is heated for a time duration adequate for alloy formation to a temperature that is lower than the melting temperature of the phase of the alloy having the lowest melting point.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: December 3, 1996
    Assignee: Siemens Aktiengesellschaft
    Inventors: Thomas Redel, Clemens Fiebiger
  • Patent number: 5578187
    Abstract: A process is provided for plating zinc die cast substrates with an electroless nickel coating comprising depositing an electrolytic zinc layer on the substrate followed by depositing a first electroless nickel layer on the electrolytic zinc layer using a first alkaline electroless nickel bath and then depositing a finish electroless nickel layer on the first electroless nickel layer using an acidic electroless nickel bath. In a preferred embodiment, a second electroless nickel layer is deposited on the first electroless nickel layer using a second alkaline electroless nickel bath. It is preferred that at least one and preferably all of the electroless nickel baths contain an effective amount of antimony ions to enhance bath stability and metal to metal adhesion. Mechanical cleaning of the zinc die casting before plating is preferred.
    Type: Grant
    Filed: October 19, 1995
    Date of Patent: November 26, 1996
    Assignee: Enthone-Omi, Inc.
    Inventors: Mark W. Zitko, John H. Commander, Victor J. Waldman
  • Patent number: 5556578
    Abstract: Sprayable fireproofing compositions for structural members such as steel columns are provided. The compositions comprise a cementitious binder such as Portland cement, and a hard aggregate containing water of hydration. Such hard aggregates contribute not only to the strength of the fireproofing composition, but also contribute thermally. The product is produced by dry blending a mixture of the cementitious binder and hard aggregate, as well as other optional additives. Upon the addition of water, sprayable slurries are formed which can be pumped to the point of application. An accelerator is added in close proximity to the point of injection. Other additives may also be included, such as starch, adhesives and cement strength enhancers. The slurries adhere to the structural member in the slurried state and after setting to provide excellent fire and heat protection.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: September 17, 1996
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Philip L. Berneburg, Antone J. Freitas, Ralph Pisaturo
  • Patent number: 5554411
    Abstract: A beta-double prime aluminum oxide solid electrolyte (24) is prepared for wetting by a liquid electrode material. The method includes mechanically rubbing an asperity-filling metal against the surface (32) of the solid electrolyte (24) until the solid electrolyte (24) turns gray in color, which fills in asperities (34) in the surface (32) of the electrolyte (24). The electrolyte (24) and deposited asperity-filling metal (36) are heated to a temperature above the melting point of sodium, and sodium is de posited onto the electrolyte surface (32) and permitted to wick along the surface (32).
    Type: Grant
    Filed: December 6, 1994
    Date of Patent: September 10, 1996
    Assignee: Hughes Aircraft Company
    Inventors: Lin R. Higley, Janet L. Dalke
  • Patent number: 5534083
    Abstract: A method for processing a reinforcing stainless steel wire--aluminum alloy composite structure, includes carbon nitriding the surface of a stainless steel wire and coating the treated stainless steel wire with an aluminum alloy, and a product thereof.
    Type: Grant
    Filed: May 4, 1995
    Date of Patent: July 9, 1996
    Assignee: Hyundai Motor Co., Ltd.
    Inventors: Bum-Goo Chung, Myung-Ho Kim
  • Patent number: 5522955
    Abstract: The present invention provides a novel process and apparatus for coating electrically conductive substrate with alkali metal by vacuum metallizing. Novel methods and apparatus are provided to protect the alkali metal surface against atmospheric degradation. The alkali metal coated substrate prepared according to this invention can be used as an anode in electrochemical batteries.
    Type: Grant
    Filed: July 7, 1994
    Date of Patent: June 4, 1996
    Inventor: Ralph J. Brodd
  • Patent number: 5520959
    Abstract: A surface which has excellent adhesivity to paint, good corrosion resistance, and low friction may be obtained on drawn and iron tin plated cans by spraying the can surface for a time between 5 and 60 seconds at a temperature between 40.degree. and 60.degree. C. with an aqueous treating liquid having a pH between 4 and 6 and comprising (i) orthophosphoric acid and/or condensed phosphoric acids and (ii) a concentration of at least 0.1 w/o of a water soluble oligomer according to the general formula: ##STR1## wherein n is a number with a value between 10 and 30 and each of X and Y independently represents hydrogen or a group Z, wherein Z has a chemical composition conforming to the general formula: ##STR2## wherein each of R.sub.1 and R.sub.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: May 28, 1996
    Assignee: Henkel Corporation
    Inventors: Shigeo Tanaka, Tomoyuki Aoki, Masayuki Yoshida
  • Patent number: 5518769
    Abstract: It is an object to provide a process for manufacturing galvannealed steel sheets exhibiting excellent anti-powdering property when press formed, and uniform frictional properties in a coil. A steel strip is galvanized in a bath having a low aluminum content after entering it at a high temperature as defined in relation to the aluminum content of the both, so that the formation of a .zeta. phase may be promoted. Then, the strip is heated for alloying in a high-frequency induction heating furnace so as to have a temperature not exceeding 495.degree. C. when leaving the furnace to yield a plated steel strip having a coating containing a uniformly distributed .zeta. phase. After such heat treatment and cooling, the strip can be plated with an iron or iron-alloy top coating having an iron content of at least 50% and a coating weight of at least 1 g/m.sup.2 to achieve an improved press formability.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: May 21, 1996
    Assignee: NKK Corporation
    Inventors: Masaru Sagiyama, Masaki Abe, Junichi Inagaki, Akira Hiraya, Masaya Morita
  • Patent number: 5516586
    Abstract: Protection of a metal surface is carried out by applying a coating of vitreous enamel to the surface so that the enamel forms a strong bond with the metal and then spraying a coating of an atomized protective metal on the enamel. Preferably a peening operation is carried out on the surface of the sprayed metal simultaneously with or immediately after the spraying of the metal. The method is particularly advantageous in protecting steel marine structures against corrosion and, where the protective metal is cupro-nickel, fouling by marine creatures. The vitreous enamel forms an electrically insulating layer preventing galvanic action between the steel and the cupro-nickel in the presence of sea water.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: May 14, 1996
    Assignee: Sprayforming Developments
    Inventors: Alfred R. E. Singer, Allen D. Roche, Gordon I. Davies
  • Patent number: 5512321
    Abstract: The invention is directed to a process for coating elongated metallic matal, particularly strip or wire, with multiple layers by applying different layers of metallic coating materials while the material to be coated travels continuously through an installation having a plurality of dip baths of molten coating materials which are arranged one after the other.In order to produce new corrosion-resistant coatings with improved properties and improved surfaces, the invention provides that the elongated metallic material is guided in a straight line through the installation so as to be regulated in temperature via the adjustable bath temperatures of the different molten coating materials. The device used for this purpose is characterized by a plurality of treatment tanks (4a, 4b) arranged in series and having through-ducts (12) for the elongated metallic material (B) below the surface (h) of the dip bath, the through-ducts (12) being closed by magnetohydrodynamic seals (13).
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: April 30, 1996
    Assignees: Mannesmann Aktiengesellschaft, I.P. Bardin Central Research Institute of Iron and Steel Industry, SKB MGD, Institute of Physics
    Inventors: Vladimir A. Paramonov, Anatolij I. Tychinin, Anatolij I. Moroz, Boris L. Birger
  • Patent number: 5500252
    Abstract: A multiplex protective MCrAlY-based coating system for an M-based superalloy base material, where M is at least one of iron, cobalt and nickel, has a surface layer containing aluminides of platinum and the M constituent of the coating. There may be a single surface layer (FIG. 2) containing platinum modified aluminide, or alternatively a double surface layer (FIG. 3) in the form of a top layer containing platinum modified aluminide and a sub-surface layer containing aluminides substantially without platinum modification. The surface layer may also have extra chromium in solid solution in the M constituent of the coating, the chromium content in the surface layer of the coating being not more than about 40 wt. %, preferably 35 to 40 wt. %. The process for production of such a system involves deposition of an MCrAlY coating, optionally chrimizing it, and then aluminising and platinising it using appropriate amounts of platinum and appropriate heat treatments to obtain the desired variant of the coating system.
    Type: Grant
    Filed: May 10, 1995
    Date of Patent: March 19, 1996
    Assignee: Rolls-Royce plc
    Inventor: Mehar C. Meelu
  • Patent number: 5500248
    Abstract: A diamond article, for example, a sheet-form diamond tool insert brazable in air. The diamond sheet has a dual layer coating, a WTi bonding layer and a protective braze compatible overcoat, such as a Ag overcoat. The interface between the WTi layer and the diamond substrate includes sufficient metal carbide component to provide adhesion. Once coated with the WTi layer and the protective overcoat, the dual-coated diamond insert may be air brazed to a tool substrate in a manufacturing environment using a standard braze without a vacuum furnace or special atmosphere. A method for manufacturing the diamond insert is also disclosed. The diamond insert is coated and heat treated in an oxygen- and nitrogen-free atmosphere to create metal carbide at the diamond-coating interface.
    Type: Grant
    Filed: August 4, 1994
    Date of Patent: March 19, 1996
    Assignee: General Electric Company
    Inventors: Charles D. Iacovangelo, Elihu C. Jerabek
  • Patent number: 5490911
    Abstract: A method for synthesizing hard ceramic materials such as carbides, borides nd aluminides, particularly in the form of coatings provided on another material so as to improve the wear and abrasion performance of machine tools, for example. The method involves the sputter deposition of alternating layers of reactive metals with layers of carbon, boron, or aluminum and the subsequent reaction of the multilayered structure to produce a dense crystalline ceramic. The material can be coated on a substrate or formed as a foil which can be coild as a tape for later use.
    Type: Grant
    Filed: November 26, 1993
    Date of Patent: February 13, 1996
    Assignee: The United States of America as represented by the Department of Energy
    Inventors: Daniel M. Makowiecki, Joseph B. Holt
  • Patent number: 5482731
    Abstract: This document discloses a method for bonding a calcium phosphate coating to stainless steels or cobalt base alloys for bioactive fixation of artificial implants. The method consists essentially of the following successive steps: applying and thermally diffusing a layer of titanium or its alloys into the stainless steel or cobalt base alloy substrates, applying a calcium phosphate coating and thermally diffusing Ca.sup.2+ and PO.sub.4.sup.-3 ions of the calcium phosphate into the intermediate layer of the titanium or its alloys and finally, the hydrothermal processing of the calcium phosphate coating.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: January 9, 1996
    Assignee: Centro de Investigacion y de Estudios Avanzados Del IPN
    Inventors: Gregorio Vargas-Gutierrez, Manuel Mendez-Nonell, Juan Mendez-Nonell, Armando Salinas-Rodriguez
  • Patent number: 5482578
    Abstract: Process for producing novel nickel superalloy bodies having increased resistance of to oxidation and corrosion at high temperatures. The process comprises applying a thin layer of a platinum-group metal and heating to an elevated temperature to diffuse or integrate the platinum-group metal into the surface of the metal superalloy. Then the superalloy body is packed into a container filled with a diffusion powder composition containing sources of aluminum and chromium metals and heated in a hydrogen gas atmosphere to an elevated temperature to codeposit and diffuse aluminum and chromium into the platinum-group metal-treated surface. Finally, the superalloy body is removed from the diffusion coating container and heated to the solvus temperature to form a ductile surface having an outer zone microstructure comprising a normally brittle PtAl.sub.2 which has been ductilized by the solutioning therein of beta chromium. This ductilized PtAl.sub.
    Type: Grant
    Filed: March 14, 1994
    Date of Patent: January 9, 1996
    Assignee: Walbar Inc.
    Inventors: Bernard R. Rose, John K. Willis
  • Patent number: 5468518
    Abstract: A process for manufacturing a metallized part comprises the following steps. A part is provided made from a substrate material selected from the group consisting of thermoplastic urethane (TPU), TPU alloys, polyester alloys, nylon, thermoplastic olefins (TPO) and aluminum. A single protective layer (combined primer/basecoat) is spray deposited, flashed and cured over the substrate. Over the combined primer/basecoat layer, a layer of corrosion prone metal is vacuum deposited to form a discontinuous film covering the combined primer/basecoat layer. A layer of clear resinous protective dielectric topcoat is spray deposited and cured to completely cover the layer of vacuum deposited corrosion prone metal material and fill channels formed in the discontinuous film layer.
    Type: Grant
    Filed: May 25, 1994
    Date of Patent: November 21, 1995
    Assignee: Davidson Textron Inc.
    Inventors: Maureen M. Lein, Richard C. Eisfeller, Alfred T. Poliquin, Mark Burns, John T. Russell
  • Patent number: 5445720
    Abstract: A process for fabricating a substrate includes the steps of (a) immersing a molding article having an electrically conductive molding surface in an electrodeposition liquid comprising polymer particles and a nucleating material; (b) electrodepositing a coating on the molding article; and (c) coalescing the coating to form a substrate containing the nucleating material. The process may further include exposing the substrate to an electroless metal plating bath to form a metal layer on the substrate. A process for fabricating an electrostatographic imaging member includes electrolessly depositing metal on a substrate. A process for fabricating a belt comprises electrolessly depositing metal on an endless substrate. An electrostatographic imaging member comprises a substrate including polymer and nucleating material and a metal layer. An endless belt includes polymer and nucleating material.
    Type: Grant
    Filed: March 2, 1993
    Date of Patent: August 29, 1995
    Assignee: Xerox Corporation
    Inventors: Donald S. Sypula, Joseph Mammino, Bela Richter
  • Patent number: 5424093
    Abstract: A thick layer of electrode material paint is formed on a flat surface. A film of the electrode material paint is formed on an element by dipping the element into the layer. In the next step, a thinner layer of the electrode material paint than the aforementioned layer is formed on a flat surface. Into the thinner layer of the electrode material paint, the film of the electrode material paint formed on the element is dipped. Alternatively, the element may first be dipped into a thinner layer of the electrode material paint so that a thin film of the electrode material paint is formed on the element. The film formed on the element is then dipped into a thick layer of the electrode material paint and then again into a thin layer of the electrode material paint in such order. By firing the film of the electrode material paint obtained in this manner, an electronic element having external electrodes of a uniform thickness can be obtained.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: June 13, 1995
    Assignee: Murata Mfg. Co., Ltd.
    Inventors: Koichi Nitta, Michio Kaeriyama, Kazuma Kabuta, Haruo Hori, Masami Yamaguchi, Tadahiro Nakagawa
  • Patent number: 5415077
    Abstract: A wobble plate in a wobble plate compressor has a bevel gear positioned at a central portion thereof. The bevel gear is provided with a centered ball seat. A second bevel gear is supported on the cylinder block and also has a centered ball seat. A bearing ball is seated in both of the ball seats so that the wobble plate nutates about the ball. At least one of the bevel gears is coated with electroless composite plating layer having a self-lubricative material, such as polytetrafluoroethylene (PTFE), dispersed therein. Consequently, the bevel gears have low frictional resistance, high hardness and improved anti-seizure characteristics.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: May 16, 1995
    Assignee: Sanden Corporation
    Inventor: Tokihito Ono
  • Patent number: 5405646
    Abstract: The manufacture of thin film magnetic disks in which a non-magnetic layer is deposited on the disk substrate to bind to the substrate and nucleates the electroless plating of a nickel alloy which supports the thin magnetic layer.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: April 11, 1995
    Inventor: Leonard Nanis
  • Patent number: 5395650
    Abstract: Gold can be selectively deposited onto a catalytically-activated region on a surface of a workpiece in the presence of a catalytically-inactive region on the surface by a chemical vapor deposition method. The method involves placing the workpiece in a vacuum chamber and evacuating the vacuum chamber to a base pressure equal to or less than a catalyst-activity-preserving upper pressure limit to eliminate effectively gaseous catalyst-deactivating contaminants from the chamber. The surface composition of at least one region of a target surface of the workpiece is altered to produce a catalytically-activated region on the target surface. At least one region of the target surface disjoint from the catalytically-activated region is a catalytically-inactive region. A gaseous alkylated (trialkylphosphine)gold compound is introduced into the vacuum chamber to expose the target surface of the workpiece to the compound.
    Type: Grant
    Filed: November 19, 1993
    Date of Patent: March 7, 1995
    Assignee: International Business Machines Corporation
    Inventors: Mark M. B. Holl, Steven P. Kowalczyk, Fenton R. McFeely, Paul F. Seidler
  • Patent number: 5389436
    Abstract: A surface-treated metal sheet which excels in workability, electrical conductivity and corrosion resistance has a metal sheet which has been plated as required, a chromate layer as a first layer formed on at least one side of the metal sheet, with a deposition amount of about 5 to 200 mg/m.sup.2 as calculated on the basis of Cr, and a second layer formed on the first layer from organic lubricant particles, with a deposition amount of from about 5 to 1000 mg/m.sup.2, such that the area coated by the organic lubricant particles to the entire area of the metal sheet surface is below about 50%. The second layer is preferably applied with a roll coater, a spin coater or a dip coater, a dispersion liquid or an emulsion containing about 0.1 to 40 wt. % of the organic lubricant particles so as to provide a wet film thickness of about 0.2 to 10 .mu.m.
    Type: Grant
    Filed: November 30, 1993
    Date of Patent: February 14, 1995
    Assignee: Kawasaki Steel Corporation
    Inventors: Nobuo Totsuka, Masaki Mabuchi, Katsuhei Kikuchi, Yoshihiro Naruse
  • Patent number: 5384161
    Abstract: An aluminum object is manufactured by a process including chromate conversion coating of the aluminum object; sequentially applying a primer coat to the outer surface and thereafter applying a dielectric substrate basecoat; vacuum metallizing a corrosion prone metal, namely indium, on the dielectric substrate basecoat to form "islands" of the indium that are top coated with a clear resinous layer to encapsulate and insulate the islands, one from another. The indium islands are less than one thousand angstroms thick and have an average diameter of less than three thousand angstroms. The island structure is etched following the growth of the metal as it is deposited between the nucleation stage and the stage of channelization of formation of an electrically conductive film. The etchant is selected to clear channels between island structures to improve adhesion of a dielectric resinous top coat to the dielectric substrate by order of magnitude to adhesion to the islands.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: January 24, 1995
    Assignee: Davidson Textron Inc.
    Inventors: Richard C. Eisfeller, John Clark
  • Patent number: 5374449
    Abstract: A monolithic piezoelectric key structure having a piezoelectric layer adherently connected between two conductive areas. The piezoelectric layer is applied as a fluid on the base conductive area and transformed into a coherent solid adhering to the base conductive area. The other conductive area is adherently formed on the piezoelectric layer. The monolithic structure is polarized.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: December 20, 1994
    Assignee: Algra Holding AG
    Inventors: Albert Buhlmann, Hans Schenk