Co-, Fe-, Or Ni-base Components, Alternative To Each Other Patents (Class 428/678)
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Patent number: 5441804Abstract: A magneto-optical recording medium has on the substrate a recording layer made of a multi-layered metallic thin film comprising a first unit layer and a second unit layer. The first unit layer is composed of (Fe.sub.x Co.sub.1-x).sub.1-y M.sub.y where M represents at least one metal selected from the group consisting of Pt, Pd and Au, 0.5.ltoreq..times..ltoreq.1.0, and 0.01.ltoreq.y.ltoreq.0.1. The second unit layer is composed of a% least one metal selected from the group consisting of Nd, Dy, Gd and Tb. The first and second unit layers are superimposed alternately one on another.Type: GrantFiled: August 4, 1994Date of Patent: August 15, 1995Assignee: Mitsubishi Plastics Industries LimitedInventors: Toshiyuki Akitake, Shingetsu Yamada
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Patent number: 5432012Abstract: A magnetic thin-film media with high coercivity and low noise characteristics is disclosed. The medium has a gradient-composition thin-film magnetic layer in which a lowermost stratum is composed of a first alloy, preferably, having relatively low noise and low magnetic remanence characteristics, and an uppermost stratum composed of a second alloy having relatively high noise and high magnetic remanence characteristics. The medium is characterized by a coercivity which is substantially greater, and a media noise which is substantially less than that of a similar medium whose magnetic thin-film layer is composed of either the first or second alloy alone. Also disclosed is a method of producing such a medium.Type: GrantFiled: June 30, 1992Date of Patent: July 11, 1995Assignee: HMT Technology CorporationInventors: Brij B. Lal, Tadashi Shinohara
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Patent number: 5429883Abstract: An alloy having excellent corrosion resistance and abrasion resistance, is provided comprising a matrix metal phase comprised of at least one member selected from an Fe-base alloy, a Co-base alloy and a Ni-base alloy and, present in the matrix metal phase, 10 to 65%, in terms of the area, of a substantially homogeneously crystallized and/or precipitated VC particle phase having a particle diameter of 5 .mu.m or less.A surface-modified metallic member, is also provided comprising a metallic member and the above-described alloy, the alloy being integrally coated on the surface of the metallic member at its desired portion.Type: GrantFiled: May 20, 1993Date of Patent: July 4, 1995Assignees: Toshiba Kikai Kabushiki Kaisha, Daido Steel Co., Ltd.Inventors: Kyoichi Sasaki, Yoshihisa Kato
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Patent number: 5427866Abstract: A coated article comprises a base article having a substrate made of a material selected from the group consisting of a nickel-base alloy and a cobalt-base alloy, an intermediate metallic coating structure, and a thermal barrier coating. The intermediate metallic coating structure may be a protective layer of platinum, rhodium, or palladium on the base article, with no bond coat. The intermediate metallic coating may also be a bond coat, either oxidized or unoxidized, with a protective layer of platinum, rhodium, or palladium thereon. The protective layer typically partially interdiffuses with the underlying metallic structure.Type: GrantFiled: March 28, 1994Date of Patent: June 27, 1995Assignee: General Electric CompanyInventors: Bangalore A. Nagaraj, William B. Connor, Richard W. Jendrix, David J. Wortman, Larry W. Plemmons
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Patent number: 5418059Abstract: A magnetic recording medium having a nonmagnetic substrate, a first magnetic layer which is formed on a surface of the substrate, has an axis of easy magnetization slanting from a normal line of a layer plane, contains cobalt and oxygen in an amount of not more than 40 atomic % and has a thickness of not larger than 0.15 .mu.m, and a second magnetic layer which is formed on a surface of the first magnetic layer, contains cobalt, has an axis of easy magnetization slanting from a normal line of a layer plane, contains oxygen in an amount of not larger than 37 atomic % and from 61 % to 99 % of the oxygen concentration in the first layer, and has a thickness of not larger than 0.15 .mu.m, which medium has a large S/N ratio.Type: GrantFiled: June 4, 1993Date of Patent: May 23, 1995Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Ryuji Sugita, Kiyokazu Tohma, Tatsuaki Ishida, Yasuaki Ban
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Patent number: 5403669Abstract: An article coated with a thermal barrier coating system for high temperature use, has its thermal cyclic spallation life improved by the application of an aluminide to the outer portion of a bonding coating disposed on a substrate. The bond coating has a surface roughness in the range of about 200-600 microinches Ra prior to application of covering thermal barrier coating.Type: GrantFiled: March 28, 1994Date of Patent: April 4, 1995Assignee: General Electric CompanyInventors: Bhupendra K. Gupta, Jim D. Reeves, Bangalore A. Nagaraj
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Patent number: 5370932Abstract: A magnetic recording medium excellent in electromagnetic properties is disclosed, which comprises a non-magnetic support and at least two magnetic layers formed thereon, each of which is mainly composed of a magnetic substance and a binder, in which a first magnetic layer (a lower layer) has a coercive force of 450 to 660 Oe, a residual magnetic flux density (Br) of 1,950 gausses or more and a thickness of 1.5 to 5 .mu.m, a second magnetic layer (an upper layer) has a coercive force of 700 to 900 Oe, a residual magnetic flux density of 1,500 gausses or more and a thickness of 1.5 to 3 .mu.m, the difference in coercive force between the first magnetic layer and the second magnetic layer is 150 to less than 300 Oe, the difference in residual magnetic flux density between the first magnetic layer and the second magnetic layer is within 600 gausses, and the total thickness of magnetic layers on the non-magnetic support is 3 to 7 .mu.m.Type: GrantFiled: February 8, 1993Date of Patent: December 6, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroo Inaba, Masatoshi Takahashi, Kazuaki Taga, Keiji Mori
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Patent number: 5370928Abstract: A magnetic recording medium providing a high reproducing output and a high C/N over a wide recording frequency region is disclosed. The magnetic recording medium comprises a non-magnetic substrate and a lower magnetic layer, a non-magnetic intermediate layer and an upper magnetic layer on the substrate in this order so that the ratio of the non-magnetic intermediate layer thickness (t) to the upper magnetic layer thickness (d), i.e., (t/d), is within the range of 0.1/1 to 0.3/1.Type: GrantFiled: January 27, 1992Date of Patent: December 6, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Makoto Funabashi, Naoto Abe, Koji Sasazawa
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Patent number: 5322733Abstract: A metal thin-film magnetic recording medium has a non-magnetic base and a ferromagnetic metal thin-film formed on the non-magnetic base and containing therein Co as a major component. The ratio of the area of 130 plane of CoOOH of the metal thin-film to that of 111 plane of CoO of the same obtained by thin-film X-ray diffraction method is not smaller than 0.003 and is smaller than 0.1.Type: GrantFiled: September 6, 1991Date of Patent: June 21, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroaki Doushita, Tadashi Yasunaga
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Patent number: 5320919Abstract: A copper foil for an inner layer circuit of a multi-layered printed circuit board, which comprises a black metal plated layer formed on at least the rough surface which becomes a surface of an inner layer circuit of a copper foil having both sides roughened in advance, in order to enhance the bonding strength to a prepreg, make it safe from haloing and facilitate optical checking of the copper foil.Type: GrantFiled: May 28, 1991Date of Patent: June 14, 1994Assignees: Sumitomo Bakelite Company Limited, Circuit Foil Japan Co., Ltd.Inventors: Keiji Azuma, Kimikazu Katoh, Ryoichi Oguro, Takashi Inada
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Patent number: 5316631Abstract: A magnetic recording medium which comprises, on a substrate, a Cr undercoat layer and a Co alloy thin film formed on the substrate in this order. The coercive force of the medium is significantly improved by incorporating oxygen either in the Cr undercoat layer or in the Co alloy thin film.Type: GrantFiled: August 11, 1992Date of Patent: May 31, 1994Assignee: Victor Company of Japan, Ltd.Inventors: Toshio Ando, Toshikazu Nishihara
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Patent number: 5316866Abstract: A superalloy component includes a substrate article of a superalloy, and a strengthenable, adherent coating on the substrate. The coating is preferably a nickel-base superalloy that is strengthened by the formation of gamma and gamma-prime phases. The coating is stronger than conventional MCrAlX coatings, and, therefore, more resistant to thermal fatigue. One operable coating has a composition, in weight percent, of about 7.5 percent cobalt, about 9 percent chromium, about 6 percent aluminum, about 1 percent titanium, about 1.5 percent molybdenum, about 4 percent tantalum, about 3 percent tungsten, about 3 percent rhenium, about 0.5 percent hafnium, about 0.3 percent yttrium, about 0.5 percent columbium, about 0.05 percent carbon, about 0.015 percent boron, about 0.015 percent zirconium, and balance nickel.Type: GrantFiled: September 9, 1991Date of Patent: May 31, 1994Assignee: General Electric CompanyInventors: Edward H. Goldman, Ramgopal Darolia
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Patent number: 5292596Abstract: A method is disclosed for protecting a force-transmitting or force-receiving surface of titanium from fretting fatigue. The method constitutes coating the surface with a coating of an alloy of nickel, cobalt, and iron.Type: GrantFiled: August 19, 1992Date of Patent: March 8, 1994Assignees: United Technologies Corporation, The United States of America as represented by the Secretary of the Air ForceInventors: Hugh M. Privett, III, Shiro Fujishiro
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Patent number: 5292592Abstract: In an optical information recording medium comprising a substrate (11) of polycarbonate, a recording layer, and a reflecting layer (14) covering the reflecting layer and containing Al, an alloy layer (17) of a Ni-Cr alloy is deposited on the reflecting layer to sufficiently protect transmission of moisture into the reflecting layer. A covering layer (18) of ultraviolet curable resin may be deposited on the alloy layer. The recording layer is formed on the substrate and includes a magneto-optical layer (13) sandwiched between first and second interference layers (15, 16). For protecting transmission of moisture into the substrate, it is preferable that an additional layer (21) of SiO.sub.2 is deposited on the substrate opposite to the recording layer.Type: GrantFiled: May 8, 1992Date of Patent: March 8, 1994Assignee: NEC CorporationInventor: Masaki Itoh
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Patent number: 5268238Abstract: A method of protecting and a protective coating for metal components formed of nickel or cobalt-based superalloys are disclosed. The protective coating essentially consists of the following constituents (in percent by weight):1 to 20% rhenium,15 to 50% chromium,0 to 15% aluminum, the share of chromium and aluminum taken together being at least 25% and at most 53%,0.3 to 2% in total of at least one reactive element from the group consisting of the rare earths, and0 to 3% silicon,impurities, as well as the following elective components:0 to 5% hafnium,0 to 12% tungsten,0 to 10% manganese,0 to 15% tantalum,0 to 5% titanium,0 to 4% niobium, and0 to 2% zirconium,the total share of the elective components being from 0 to a maximum of 15%, and a remainder primarily being at least one of the elements iron, nickel, and cobalt. The protective coating is primarily suited for use with metal components in gas turbines and aircraft engines.Type: GrantFiled: December 2, 1992Date of Patent: December 7, 1993Assignee: Siemens AktiengesellschaftInventors: Norbert Czech, Friedhelm Schmitz
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Patent number: 5254182Abstract: A thin film of an amorphous alloy comprising (i) at least one element selected from Fe and Co, (ii) at least one element selected from Pt and Pd and (iii) at least one element selected from (a) 3d transition elements other than Fe and Co, (b) 4d transition elements other than Pd, (c)5d transition elements other than Pt, (d) light rare earth elements, (e)Group III B elements, (f)Group IV B elements, (g)Group V B elements, and (h)Group VI B elements, and the film having an easy axis of magnetization perpendicular to the film face. The thin film has excellent magnetooptical characteristics including increased coercive force and large Kerr-rotation angle and Faraday-rotation angle, and is excellent in resistance to oxidation and In consequence the coercive force and Kerr-angle of the film do not substantially change with time. The film has a high reflectance as well.Type: GrantFiled: August 8, 1990Date of Patent: October 19, 1993Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Kunihiko Mizumoto, Koichi Haruta, Hirokazu Kajiura
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Patent number: 5246786Abstract: A steel product (or copper-plated steel product) with heat-resistant, corrosion-resistant plating layers which are composed of a 0.2-10 .mu.m thick nickel plating layer formed on said steel product, a zinc plating layer formed on said nickel plating layer, and a chromate film formed on said zinc plating layer.Type: GrantFiled: June 22, 1992Date of Patent: September 21, 1993Assignee: Usui Kokusai Sangyo Kaisha Ltd.Inventor: Masayoshi Usui
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Patent number: 5240491Abstract: A series of braze materials for brazing superalloy substrates at effective brazing temperatures above about 2300.degree. F. is described. The braze materials are formulated as mixtures of cobalt- and nickel-base alloy powders. Each such braze material contains at least two components, one of which is predominantly liquid at the effective brazing temperature, and one of which remains substantially solid at that temperature. The brazing materials solidify by an isothermal solidification process. Unless otherwise limited by the temperature capability of the superalloy substrate being joined, these brazing alloys provide joints that have useful strength at temperatures significantly higher than joints made with prior art brazing alloys.Type: GrantFiled: July 8, 1991Date of Patent: August 31, 1993Assignee: General Electric CompanyInventors: David E. Budinger, Stephen J. Ferrigno, Wendy H. Murphy
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Patent number: 5236791Abstract: A magnetic recording medium that uses, as a protective coating layer provided on a magnetic layer for magnetically recording signals, a layer made of a nonmagnetic material consisting of two ore more elements of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W, and one or more elements of N, C, O, and B, or made of a magnetic material consisting of one or more elements of Co, Fe, Ni, and Gd, one or more elements of Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W, and one or more elements of N, C, O, B, and Si is excellent in sliding endurance. When the protective coating layer is made of the nonmagnetic material, the magnetic recording medium is also excellent in corrosion resistance, and when the protective coating layer is made of the magnetic material, the spacing between a magnetic head and the magnetic recording medium can advantageously be made large. Both the cases are high in reliability, and suitable for high density magnetic recording.Type: GrantFiled: August 28, 1989Date of Patent: August 17, 1993Assignee: Hitachi, Ltd.Inventors: Yotsuo Yahisa, Yoshihiro Shiroishi, Sadao Hishiyama, Tomoyuki Ohno, Shinichiro Saitoh, Suzuki Hiroyuki, Yoshibumi Matsuda, Norikazu Tsumita, Masaki Ohura, Noriyuki Shige, Kazumasa Takagi
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Patent number: 5232789Abstract: A structural component made of a base metal composition on a nickel or cobalt basis is provided with a protective coating against oxidation, corrosion, and thermal fatigue. The protective coating and the base metal are made of chemically the same or identical material, whereby the bonding of the protective coating is increased, the tendency to crack is reduced, and the resistance to thermal fatigue is improved. The grain size of the coating is substantially smaller than the grain size of the base metal composition.Type: GrantFiled: March 2, 1992Date of Patent: August 3, 1993Assignee: MTU Motoren- und Turbinen-Union Muenchen GmbHInventors: Albin Platz, Klaus Schweitzer, Peter Adam
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Patent number: 5225289Abstract: There is disclosed an opto-magnetic recording medium which comprises a substrate, a first magnetic layer of a Gd-Fe-Co amorphous alloy formed on the substrate and having iron group sublattice magnetization superiority, saturated magnetization of which falls within the range of 25 to 125 emu/cm.sup.3, and a second magnetic layer of an R-Fe-Co (wherein R is at least one element selected from the group consisting of Tb and Dy) amorphous alloy having a higher coercive force than that of the first magnetic layer, a lower Curie point than that, and rare earth group sublattice magnetization superiority, saturated magnetization of which falls within the range of 25 to 175 emu/cm.sup.3, and in which second magnetic layer is exchange-coupled with the first magnetic layer.Type: GrantFiled: February 3, 1992Date of Patent: July 6, 1993Assignee: Canon Kabushiki KaishaInventor: Tadashi Kobayashi
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Patent number: 5213907Abstract: A dense, smooth, ductile, hard, highly reflective, corrosion-resistant, temperature resistant, and wear-resistant crystalline alloy of nickel, cobalt and boron. The alloy is epitaxially electrodeposited on an activated substrate using a pulsed square wave current. The epitaxial deposition occurs in an electrolytic bath containing nickel ions, cobalt ions, complexing agents, and an amino borane compound at a moderately low pH level and moderate temperature. An insoluble, solid catalyst, preferably palladium, causes the alloy to diffuse into the surface of the substrate and become bonded by a polar-covalent bond to it. Implements coated with the alloy, as well as plating solutions and methods for making the alloy are also disclosed.Type: GrantFiled: October 9, 1990Date of Patent: May 25, 1993Assignee: Diamond Technologies CompanyInventor: Luis X. Caballero
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Patent number: 5198302Abstract: Silicon nitride reinforcing fibers provided with a protective surface coating comprising a boron nitride base layer and, optionally, an alumina overcoating, and fiber-reinforced ceramic matrix composite products incorporating the protectively-coated fibers, are disclosed. The composites offer significantly improved high temperature strength in combination with low dielectric constant and low dielectric loss characteristics.Type: GrantFiled: April 23, 1990Date of Patent: March 30, 1993Assignee: Corning IncorporatedInventors: Kenneth Chyung, Steven B. Dawes, Dale R. Wexell
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Patent number: 5196265Abstract: A magnetic recording medium comprising a non-magnetic support having thereon a magnetic layer containing a ferromagnetic powder and a binder, the non-magnetic support comprising polyethylene naphthalate in which Young's modulus in the transversal direction is at least 700 kg/mm.sup.2 and Young's modulus in the mechanical direction is less than 800 kg/mm.sup.2, the ferromagnetic powder being magnetic metal powder, and the total thickness of the magnetic recording material being not more than 11 .mu.m.Type: GrantFiled: October 7, 1991Date of Patent: March 23, 1993Assignee: Fuji Photo Film Co., Ltd.Inventors: Katsumi Ryoke, Yutaka Kakuishi, Toshiyuki Kitahara
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Patent number: 5194222Abstract: An alloy exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises, in weight percent, not more than 0.05% C, 0.02-0.5% Si, 0.02-0.5% Mn, 15-35% Cr, 0.5-4% Mo, 10-40% Co, 5-15% Fe, 0.5-5% W, 0.0003-0.005% Ca and the remainder of Ni at a content of not less than 4% and unavoidable impurities, provided that Cr (%)+0.5Ni (%)+3Mo (%).gtoreq.30 (%) and Ni (%)+0.5Co (%).gtoreq.Cr (%)+Mo (%)+W (%). A composite steel tube exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises an inner tube constituted of Cr-containing boiler tube and an outer tube constituted of the alloy.Type: GrantFiled: December 20, 1991Date of Patent: March 16, 1993Assignee: Nippon Steel CorporationInventors: Hiroyuki Ogawa, Tetsuo Ishitsuka, Kozo Denpo, Akihiro Miyasaka, Michihisa Ito, Mizuo Sakakibara
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Patent number: 5192625Abstract: New cobalt-base wrought alloys containing 24-32% chromium, 14-22% nickel, 2-8% tantalum, 0.02-0.75% cerium and 0.03%-0.10% carbon have an unique combination of high temperature strength, hot corrosion resistance, oxidation-resistance and resistance to thermal fatigue cracking are useful in making weld repairs of cracked nozzles of gas turbine engines, as protective coatings for hot stage components of such engines and other similar purposes.Type: GrantFiled: February 28, 1990Date of Patent: March 9, 1993Assignee: General Electric CompanyInventor: Marvin Fishman
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Patent number: 5190832Abstract: An alloy exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises, in weight percent, not more than 0.05% C, 0.02-0.5% Si, 0.02-0.5% Mn, 15-35% Cr, 0.5-4% Mo, more than 40% but not more than 60% Co, 5-15% Fe, 0.5-5% W, 0.0003-0.005% Ca and the remainder of Ni at a content of not less than 4% and unavoidable impurities, provided that Cr (%)+0.5Ni (%)+3Mo (%).gtoreq.30 (%). A composite steel tube exhibiting corrosion resistance in a combustion environment where V, Na, S and Cl are present comprises an inner tube constituted of Cr-containing boiler tube and an outer tube constituted of the alloy.Type: GrantFiled: December 20, 1991Date of Patent: March 2, 1993Assignee: Nippon Steel CorporationInventors: Hiroyuki Ogawa, Tetsuo Ishitsuka, Kozo Denpo, Akihiro Miyasaka, Koichi Takeda, Satoshi Araki
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Patent number: 5187022Abstract: To construct a magnetic recording medium to be used for an encoder adapted for detection of an angular or linear displacement of a mobile object such as a robot arm, a substrate is at least partly covered with a Sm-Co alloy thin layer bearing magnetic information with a magnetization pitch which is at least three times as large as the crystal diameter of the magnetic particles in the alloy. A resultant high coercive force obtained with that alloy allows detection with an enlarged detective distance, and the above-mentioned proper ratio of crystal diameter with respect to the magetization pitch allows detection with low percentage of output variation, thereby enabling easy assembly of the encoder and detection with high precision.Type: GrantFiled: March 8, 1990Date of Patent: February 16, 1993Assignee: Yamaha CorporationInventors: Mutsumi Harada, Nobuji Kato, Yoshinori Hayashi, Toshiharu Hoshi, Kenzaburo Iijima
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Patent number: 5158833Abstract: A magnetic recording medium having high recording density and being capable of obtaining excellent over-write characteristics by having a magnetic layer including Co and Ni as its principal components on a non-magnetic substrate, the Ni content of the magnetic layer is greater at portions closer to the surface of the magnetic layer in the direction of its thickness; the Ni content at portions closer to the surface of the magnetic layer is 20.about.50 at %; and the portion closer to the surface of the magnetic layer has at least one element selected from the group consisting of Zr, Ti, Pt, Ru, Ta, Rh, V, Nb, Cr and Pd.Type: GrantFiled: February 26, 1990Date of Patent: October 27, 1992Assignee: Hitachi, Ltd.Inventors: Shinya Matsuoka, Masaki Ohura, Takaaki Shirakura, Yoshihiro Shiraisi
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Patent number: 5153044Abstract: A method for manufacturing a disk includes the step of forming a first nickel-phosphorus alloy layer on an aluminum substrate, e.g., by electroless plating. A second nickel-phosphorus layer is then sputtered onto the first nickel-phosphorus layer, and a magnetic alloy is sputtered onto the second nickel-phosphorus layer. The magnetic alloy is typically sputtered immediately after the second nickel-phosphorus layer is formed without removing the disk from the sputtering apparatus between the time the second nickel-phosphorus layer is formed and the time the magnetic alloy is formed. Because of this, contaminants are not capable of lodging on or affecting the surface of the disk prior to formation of the magnetic alloy. The second nickel-phosphorus layer is typically amorphous and therefore masks any nonuniformities in the surface of the first nickel-phosphorus layer.Type: GrantFiled: October 21, 1991Date of Patent: October 6, 1992Assignee: Komag, Inc.Inventors: Tu Chen, Tsutomu T. Yamashita
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Patent number: 5118564Abstract: The invention discloses a magnetic recording medium used for recording and reproducing information in combination with a magnetic head. The magnetic recording medium in accordance with the present invention comprises a substrate made of a non-magnetic material, an underlayer which is formed on the substrate and has a thickness of 300 to 1000 .ANG. and which consists of a chromium metal or a chromium alloy, and a magnetic recording layer which is formed on the underlayer by vacuum evaporation, which consists essentially of 5 to 15 at% of Cr, 1 to 8 at% of Ta and the balance substantially being Co, and which has a direction of easy magnetization within the surface parallel to the surface of the substrate.Type: GrantFiled: April 17, 1990Date of Patent: June 2, 1992Assignee: Hitachi Metals, Ltd.Inventors: Tadashi Shinohara, Koji Ichikawa, Shigeo Fujii
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Patent number: 5110690Abstract: A nickel coating and an aluminum layer are formed in this order on an inexpensive thin steel sheet made of a low-carbon steel, a low-chromium steel or a low-nickel steel. Then the nickel- and aluminum-plated thin steel sheet is subjected to a diffusion penetration treatment to form a mutually diffused layer over the entire surface of the thin steel sheet, thus providing a thin steel band which is excellent in heat-resistance, corrosion-proofness at high temperature and rigidity.Type: GrantFiled: February 7, 1991Date of Patent: May 5, 1992Assignee: Usui Kokusai Sangyo Kabushiki KaishaInventors: Masayoshi Usui, Haruo Serizawa
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Patent number: 5103870Abstract: A carbon deposition preventive double-layered tube for handling carbon compounds at not less than 500.degree. C., the double-layered tube comprising:(a) the layer to be exposed to the carbon compounds, constructed from an alloy which is composed of Cr, Ni, and Fe in porportions shown within a triangular region I of an equilibrium diagram (FIG.Type: GrantFiled: June 26, 1989Date of Patent: April 14, 1992Assignee: JGC CorporationInventors: Kunio Ishii, Naohiko Kagawa, Takahiro Iijima
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Patent number: 5091266Abstract: Disclosed is a soft-magnetic film having high saturation magnetic-flux density. The soft-magnetic film is made of an alloy containing as its main components Fe, Co and Ni in the proportion: 20%<Fe<75%, 5%<Co<45% and 20%<Ni<70% (at %) and has a structure in which (110) or (111) planes of a face-centered cubic-lattice structure are given to its thin-film surface, as a preferred crystallographic orientation. The thin-film alloy may contain less than 5% of Cr, Ti, Zr, Hf or the like. The thin film of this alloy is formed by evaporation, electroplating or the like.Type: GrantFiled: August 30, 1989Date of Patent: February 25, 1992Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Yuuji Omata
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Patent number: 5082750Abstract: A magnetic recording medium having excellent noise characteristics and comprising a metal magnetic film formed on a nonmagnetic substrate and made of (1) a Co-Cr-Nb alloy, or (2) a Co-Cr-Ni-Nb alloy. The alloys (1) and (2) are represented respectively by the following formulae:Co.sub.1-x-z Cr.sub.x Nb.sub.z (1)Co.sub.1-x-y-z Cr.sub.x Ni.sub.y Nb.sub.z (2)wherein x, y and z each represent an atomic ratio, x is 0.08 to 0.15, y is 0.05 to 0.25 and z is 0.03 to 0.10.Type: GrantFiled: October 20, 1989Date of Patent: January 21, 1992Assignee: Kubota Ltd.Inventors: Toshiaki Morichika, Toshio Tani, Chiaki Sakai, Hideo Koshimoto, Tatsuhiko Kadowaki
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Patent number: 5079100Abstract: Engine components of steel or superalloy subject to wear from alternating friction at medium temperatures in the region of 700.degree. C. are provided with a protective wear-resistant coating bya) electrophoretic deposition of a metal-ceramic structure comprising a mixture of from 85% to 50% of metallic powder and from 15% to 50% of ceramic powder, the metallic powder being a cobalt-based superalloy of type KC 25 NW or of M Cr Al Y wherein M represents at least one metal chosen from the group consisting of Ni, Co and Fe with the possible addition of Ta, and the ceramic powder being an oxide such as Al.sub.2 O.sub.3 or Cr.sub.2 O.sub.3, a carbide such as SiC or Cr.sub.3 C.sub.2, a nitride such as BN or TiN, or a boride such as TiB.sub.2 ;b) electrolytic pre-nickeling said deposit in an electrolysis bath at a pH between 6 and 8, andc) electrolytic nickeling said pre-nickeled deposit in an acid bath of sulphamate type.Type: GrantFiled: November 9, 1989Date of Patent: January 7, 1992Assignee: Societe Nationale d'Etude et de Construction de Motors d'AviationInventors: Martine Descamp, Yves C. L. A. Honnorat, Michel M. Ruimi
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Patent number: 5077140Abstract: Coatings that provide substantial oxidation protection for titanium substrates are comprised of a continuous coating of ductile MCrAl or ductile MCr alloys where M is at least one metal selected from the group consisting of iron, nickel, and cobalt. Ductile MCrAl alloys are comprised of, by weight percent: about 10 to 40 percent chromium, about 4 to 10 percent aluminum, and the balance substanitally iron; about 8 to 40 percent chromium, about 4 to 10 percent aluminum, and the balance substantially nickel; or about 10 to 25 percent chromium, about 4 to 5.5 percent aluminum, and the balance substantially cobalt. Ductile MCr alloys are comprised of, by weight percent: about 20 to 40 percent chromium, and the balance substantially iron; about 20 to 50 percent chromium, and the balance substantially nickel; or about 15 to 35 percent chromium, and the balance substantially cobalt.Type: GrantFiled: April 17, 1990Date of Patent: December 31, 1991Assignee: General Electric CompanyInventors: Krishan L. Luthra, Douglas W. McKee
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Patent number: 5077141Abstract: Disclosed are novel nickel base single crystal alloy compositions consisting essentially of, by weight, about 4.0-10.0% chromium, 1.5-6.0% cobalt, 1.0-12.0% molybdenum, 3.0-10.0% tungsten, 2.5-7.0% titanium, 2.5-7.0% aluminum, 3.0-10.0% tantalum, about 0.02%-1.5% of hafnium and/or about 0.02%-1.0% silicon, from about 0.02%-1.0% each of yttrium and/or lanthanum, from about 0.3% to about 8.0% rhenium; from about 0.2% to about 4.0% vanadium and/or from about 0.2% to about 4.0% niobium; from about 0.02% to about 3% platinum; from about 0 to about 1.0% boron, the balance nickel, and the balance nickel.Methods of thermal treatment and coating of the novel alloys to enhance their mechanical properties are also disclosed, as are articles produced by such methods.Type: GrantFiled: November 29, 1989Date of Patent: December 31, 1991Assignee: Avco CorporationInventors: Subhash K. Naik, Vinod K. Nangia
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Patent number: 5066552Abstract: An improved CoPt alloy magnetic recording disk for horizontal recording has a magnetic recording layer which includes oxygen, the oxygen being present preferably in the range of approximately 5 to 30 atomic percent. The resulting disk structure has substantially decreased intrinsic media noise at high linear recording density.Type: GrantFiled: August 16, 1989Date of Patent: November 19, 1991Assignee: International Business Machines CorporationInventors: James K. Howard, Randall G. Simmons, Tadashi Yogi
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Patent number: 5062938Abstract: A cobalt alloy disk for horizontal magnetic recording has both high coercivity and low noise at high recording density. The magnetic layer in the disk contains, in addition to the cobalt alloy material, an oxide of one or more "impurity" elements which have both a relatively low solubility in cobalt and a high affinity for oxygen. Such elements include yttrium (Y), silicon (Si), the rare earth elements, hafnium (Hf), germanium (Ge), tin (Sn) and zirconium (Zr). The disk may be formed by co-sputtering the cobalt alloy material and the impurity element(s), and thereafter oxidizing the impurity element(s). The oxidation may occur by heating the disk while the magnetic layer is exposed to oxygen or air, or by exposure of the magnetic layer to an argon-oxygen plasma.Type: GrantFiled: January 16, 1990Date of Patent: November 5, 1991Assignee: International Business Machines CorporationInventor: James K. Howard
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Patent number: 5035958Abstract: There is provided by the present invention an alloy which is mechanically and chemically compatible with advanced nickel-base superalloys and nickel-base eutectic superalloys and which possesses excellent resistance to high temperature oxidation. The alloy of the invention is, therefore, particularly useful as a protective environmental coating for the external surfaces of hot-stage aircraft gas turbine engine components, e.g., rotating blades and stationary vanes, made from such advanced superalloys.Type: GrantFiled: October 11, 1989Date of Patent: July 30, 1991Assignee: General Electric CompanyInventors: Melvin R. Jackson, Mark L. Prugar, Swe-Wong Yang, John R. Rairden, III, Michael F. X. Gigliotti, Jr.
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Patent number: 5034273Abstract: A nitrogen-containing magnetic alloy film composed of T-M-X amorphous alloy film and (T-M-X)N nitride film, and another film having a composition represented by (T-M-X)N and being compositionally modulated (In both cases T is at least one element selected from the group of Fe, Co, Ni and Mn, M is at least one element selected from the group of Ti, Zr, Hf, Nb, Ta, Cr, Mo, W, Re and Ru, X is at least one element selected from the group of B, Si, Ge and Al, and N is nitrogen.) show excellent characteristics for magnetic head cores such as soft magnetic property and wear resistance.Type: GrantFiled: April 5, 1988Date of Patent: July 23, 1991Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Hiroshi Sakakima, Koichi Osano, Yuji Omata
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Patent number: 5024903Abstract: A magnetic recording medium which comprises a non-magnetic substrate, a Cr undercoat layer formed on the substrate, and a quaternary alloy layer formed on the undercoat layer. The alloy layer consists of the following composition by atomic percent1.ltoreq.Cr.ltoreq.182.ltoreq.Ta.ltoreq.973.ltoreq.Co.ltoreq.971.ltoreq.Pt.ltoreq.10provided that the atomic percent of Cr, Ta and Co is 100 in total and the atomic percent of Pt is based on the total of Cr, Ta and Co.Type: GrantFiled: April 3, 1989Date of Patent: June 18, 1991Assignee: Victor Company of Japan, Ltd.Inventor: Makoto Mizukami
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Patent number: 5019461Abstract: A thin film, solid state device includes a conductive thin film formed on a substrate, with a resistive layer overlying the conductive thin film and with electrical contacts formed on the upper surface of the resistive layer. Electrical current flows between the electrical contacts through the resistive overlayer and the conductive thin film. The resistivity and dimensions of the resistive layer are such that, preferably, only a small fraction of any current flowing between the electrical contacts will flow solely within the resistive layer, yet the magnitude of the current will not be reduced below a desired signal level due to the presence of the resistive layer. The resistive layer is comprised of material which will not diffuse into the thin film conductive layer during device processing. Nitrogen doped tantalum is the preferred material for the resistive layer.Type: GrantFiled: December 8, 1986Date of Patent: May 28, 1991Assignee: Honeywell Inc.Inventor: James A. Schuetz
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Patent number: 5013616Abstract: A magnetic recording medium having a low noise level and comprising a magnetic film made of a Co-Ni-Cr-P alloy. The Co-Ni-Cr-P alloy has a composition represented by the formula(Co.sub.100-a Ni.sub.a).sub.100-b-c Cr.sub.b P.sub.cwherein a, b and c each represent atomic percent, and 3.ltoreq.a.ltoreq.40, 2.ltoreq.b.ltoreq.10 and 2.ltoreq.c.ltoreq.7.Type: GrantFiled: September 12, 1990Date of Patent: May 7, 1991Assignee: Kubota Ltd.Inventors: Toshiaki Morichika, Toshio Tani, Nobuhiko Tanaka, Tatsuhiko Kadowaki
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Patent number: 5009966Abstract: The invention discloses a coated substrate product comprised of a titanium of titanium alloy substrate, at least one thin interlayer composed of a non-reactive noble metal and a hard outer coating selected from the group comprised of a ceramic, a hard metal, a hard metal compound and a diamond-like carbon, wherein at least the non-reactive noble metal interlayer which is immediately adjacent to the titanium or titanium alloy substrate is deposited onto the substrate by means of an electroless plating procedure, and the hard outer coating is deposited onto the non-reactive interlayer(s) by means of known chemical and physical vapor deposition techniques. The invention also discloses a method for making these coated substrate products.Type: GrantFiled: September 19, 1989Date of Patent: April 23, 1991Inventors: Diwakar Garg, Carl F. Mueller, Leslie E. Schaffer, Paul N. Dyer
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Patent number: 5006388Abstract: Disclosed are magnetic discs having (A) a Cr-layer, as a lower layer, which has a composition comprising (1) substantially Cr or (2) 10% by weight or less of one or more selected from Cu, Nb, Ti, V, Zr, Mo, Zn, W and Ta, and a balance of being substantially Cr, and (B) a magnetic recording medium layer, as an upper layer, which has a composition comprising (1) substantially Co, (2) 30% by weight or less of Ni and a balance of being substantially Co, (3) 10% by weight or less of one or more selected from Y, La, Ce, Pr, Nd, Sm, Gd, Tb and Dy, and a balance of being substantially Co, (4) 30% by weight or less of Ni, 10% by weight or less of one or more selected from Y, La, Ce, Pr, Nd, Sm, Gd, Tb and Dy, and a balance of being substantially Co, (5) 10% by weight or less of one or more selected from Cu, Nb, Ti, V, Cr, Zr, Mo, Zn, W and Ta, and a balance of being substantially Co, (6) 30% by weight or less of Ni, 10% by weight or less of one or more selected from Cu, Nb, Ti, V, Cr, Zr, Mo, Zn, W and Ta, and a balanType: GrantFiled: August 3, 1988Date of Patent: April 9, 1991Assignee: Sumitomo Metal Mining Company LimitedInventors: Ryuichi Kuzuo, Atsushi Kawamoto, Junya Tada, Kenji Ohmori, Hiroko Sekiya
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Patent number: 5002839Abstract: Improved valve components and methods of repairing and manufacturing valve components are provided by this invention. The valve component includes a valve seat including a buttering layer of austenitic stainless steel and a cobalt-containing, hardfacing layer disposed on the buttering layer. This combination of materials provides a relatively, defect-free welding deposit or repair.Type: GrantFiled: October 16, 1989Date of Patent: March 26, 1991Assignee: Westinghouse Electric Corp.Inventors: Javaid I. Qureshi, William A. Gavilan
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Patent number: RE33767Abstract: This invention is a method for depositing on an article a coating containing at least one member of the group metals and metal alloys plus particulate dispersed diamond comprising contacting the surface of the article with a stable electroless plating bath consisting essentially of an aqueous solution of soluble constituents of the group, electroless reducing agent therefor, a suspension of diamond particles therein and a stabilizer, and maintaining the diamond particles in suspension throughout the bath during the coating of the article for a time sufficient to produce a preselected depth of coating on the article, and the coated article pe se.This is a reissue of a patent which was the subject of a reexamination certificate No. B1 Re. 29,285, dated July 5, 1983, Request No. 90/000,120, Dec. 3, 1981.Type: GrantFiled: August 15, 1989Date of Patent: December 10, 1991Assignee: Surface Technology, Inc.Inventors: Theodore P. Christini, Albert L. Eustice, Arthur H. Graham
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Patent number: RE33876Abstract: Adherent, thermal shock-resistant protective coatings for nickel base super alloys are obtained by applying to the base metal a thin bond coat of an alloy of chromium aluminum and yttrium with materials selected from the group consisting of iron, cobalt, nickel and nickel-cobalt and applying thereover a continuously graded mixture of this material with a zirconia-based ceramic, the concentration of zirconia-based ceramic increasing from the bond coat to the outer layer. The zirconia ceramic may be stabilized by the addition thereto of amounts of magnesium oxide or other materials.Type: GrantFiled: October 10, 1989Date of Patent: April 7, 1992Assignee: United Technologies CorporationInventors: George W. Goward, Delton A. Grey, Richard C. Krutenat