Silicon Oxide Or Glass Patents (Class 438/743)
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Patent number: 6933236Abstract: A method for forming a photoresist pattern with minimally reduced transformations through the use of ArF photolithography, including the steps of: forming an organic anti-reflective coating layer on a an etch-target layer already formed on a substrate; coating a photoresist for ArF on the organic anti-reflective coating layer; exposing the photoresist with ArF laser; forming a first photoresist pattern by developing the photoresist, wherein portions of the organic anti-reflective coating layer are revealed; etching the organic anti-reflective coating layer with the first photoresist pattern as an etch mask and forming a second photoresist pattern by attaching polymer to the first photoresist pattern, wherein the polymer is generated during etching the organic anti-reflection coating layer with an etchant including O2 plasma; and etching the etch-target layer by using the second photoresist pattern as an etch mask.Type: GrantFiled: November 27, 2002Date of Patent: August 23, 2005Assignee: Hynix Semiconductor Inc.Inventors: Sung-Kwon Lee, Sang-Ik Kim, Weon-Joon Suh
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Patent number: 6930035Abstract: The present invention provides an auxiliary semiconductor device fabrication method that forms wiring 113 by using the wiring groove 108 that is formed in the sacrificial oxide film 104. An interlayer insulating film is formed by removing, by means of etching, the sacrificial oxide film that is used as a mold for the wiring layer formation and then allowing the porous Low-k film to fill the region from which the sacrificial oxide film has been removed.Type: GrantFiled: December 30, 2003Date of Patent: August 16, 2005Assignee: Oki Electric Industry Co., Ltd.Inventor: Toyokazu Sakata
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Patent number: 6927134Abstract: A trench transistor with lower leakage current and higher gate rupture voltage. The gate oxide layer of a trench transistor is grown at a temperature above about 1100° C. to reduce thinning of the oxide layer at the corners of the trench. In a further embodiment, a conformal layer of silicon nitride is deposited over the high-temperature oxide layer, and a second oxide layer is formed between the silicon nitride layer and the gate polysilicon. The first gate oxide layer, silicon nitride layer, and second oxide layer form a composite gate dielectric structure that substantially reduces leakage current in trench field effect transistors.Type: GrantFiled: February 14, 2002Date of Patent: August 9, 2005Assignee: Fairchild Semiconductor CorporationInventors: Brian Sze-Ki Mo, Duc Chau
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Patent number: 6905943Abstract: In one embodiment, a method for forming a semiconductor structure in manufacturing a semiconductor device includes providing a pad layer on a surface of a substrate, providing a nitride layer on the pad layer, and providing a sacrificial oxide layer on the nitride layer. In a first etching step, at least the sacrificial oxide and nitride layers are etched to define opposing substantially vertical surfaces of at least the sacrificial oxide and nitride layers. In a second etching step, the nitride layer is etched such that the opposing substantially vertical surfaces of the nitride layer are recessed from the opposing substantially vertical surfaces of the sacrificial oxide layer, the sacrificial oxide layer substantially preventing the nitride layer from decreasing in thickness as a result of the etching of the nitride layer. In a third etching step, the substrate is etched to form a trench extending into the substrate for purposes of defining one or more isolation regions adjacent the trench.Type: GrantFiled: November 6, 2003Date of Patent: June 14, 2005Assignee: Texas Instruments IncorporatedInventors: Juanita DeLoach, Freidoon Mehrad, Brian M. Trentman, Troy A. Yocum
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Patent number: 6878612Abstract: A semiconductor device manufacturing method that assures required size of flat areas at a wiring overlay nitride film, and forms an SAC structure wherein selectivity is not lowered at corners. A first etching process wherein an insulating film is etched under conditions for forming a vertical opening (vertical conditions) is used to open up the insulating film to a point near the wiring overlay nitride film 105. A second etching process is used wherein the insulating film is opened until the wiring overlay nitride film becomes exposed, by etching under conditions assuring a high ratio of selectivity relative to the wiring overlay nitride film (SAC conditions). Then, a third etching process is used wherein the insulating film located between first and second electrodes is removed by etching under conditions with a low ratio of selectivity relative to the wiring overlay nitride film (SAC conditions).Type: GrantFiled: September 16, 2002Date of Patent: April 12, 2005Assignee: Oki Electric Industry Co., Ltd.Inventors: Takeshi Nagao, Atsushi Yabata
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Patent number: 6875704Abstract: A method for forming a pattern using a printing process is disclosed in the present invention. The method includes forming a resist layer on a substrate having an etching layer thereon, locating a master having a convex pattern over the substrate, pressing the master against the substrate until the convex pattern of the master directly contacts the etching layer, and removing a portion of the resist layer to expose a surface over the substrate, the removed portion of the resist layer having a width substantially the same as the convex portion of the master.Type: GrantFiled: September 30, 2003Date of Patent: April 5, 2005Assignee: LG.Philips LCD Co., Ltd.Inventors: Myoung-Kee Baek, Kwon-Shik Park
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Patent number: 6875688Abstract: A method for implementing dual damascene processing includes forming a first hardmask layer over an interlevel dielectric layer, and forming a second hardmask layer over the first hardmask layer. A trench pattern is opened within a third hardmask layer formed over the second hardmask. A first etch process is implemented so as to define a via pattern completely through the second hardmask layer and partially through the first hardmask layer, and a second etch process is implemented to transfer the trench pattern and the via pattern into the interlevel dielectric layer.Type: GrantFiled: May 18, 2004Date of Patent: April 5, 2005Assignee: International Business Machines CorporationInventors: William G. America, Kaushik A. Kumar
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Patent number: 6869542Abstract: Form an opening in a dielectric layer formed on a substrate comprises depositing a hard mask composed of an etch resistant material over a dielectric layer, e.g. a silicon oxide. Use a photoresist mask to expose the hard mask. Use a fluorocarbon plasma to etch through the window to form an opening through the hard mask. Then etch through the hard mask opening to pattern the dielectric layer. The hard mask comprises an RCH/RCHX material with the structural formula R:C:H or R:C:H:X, where R is selected from Si, Ge, B, Sn, Fe, Ti and X is selected from O, N, S and F. The plasma etching process employs a) a gas mixture comprising N2; fluorocarbon (CHF3, C4F8, C4F6, CF4, CH2F2, CH3F); an oxidizer (O2, CO2), and a noble diluent (Ar, He); b) a high DC bias (500-3000 Volts bias on the wafer); 3) medium pressure (20-100 mT.; and d) moderate temperatures (?20 to 60°).Type: GrantFiled: March 12, 2003Date of Patent: March 22, 2005Assignee: International Business Machines CorporationInventors: Sadanand V. Desphande, David Dobuzinsky, Arpan P. Mahorowala, Tina Wagner, Richard Wise
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Patent number: 6852472Abstract: The removal of defect particles that may be created during polysilicon hard mask etching, and that are embedded within the polysilicon layer, is disclosed. Oxide is first grown in the polysilicon layer exposed through the patterned hard mask layer, so that the defect particle becomes embedded within the oxide. Oxide growth may be accomplished by rapid thermal oxidation (RTO). The oxide is then exposed to an acidic solution, such as hydrofluoric (HF) acid, to remove the oxide and the embedded defect particle embedded therein.Type: GrantFiled: October 17, 2002Date of Patent: February 8, 2005Assignee: Taiwan Semiconductor Manufacturing Co., LTDInventors: Chu-Sheng Lee, Tou-Yu Chen
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Patent number: 6849193Abstract: An oxide etching process, particularly useful for selectively etching oxide over a feature having a non-oxide composition, such as silicon nitride and especially when that feature has a corner that is prone to faceting during the oxide etch. The invention uses a heavy perfluorocarbon, for example, hexafluorobutadiene (C4F6) or hexafluorobenzene (C6F6). The fluorocarbon together with a substantial amount of a noble gas such as argon is excited into a high-density plasma in a reactor which inductively couples plasma source power into the chamber and RF biases the pedestal electrode supporting the wafer. A more strongly polymerizing fluorocarbon such as difluoromethane (CH2F2) is added in the over etch to protect the nitride corner. Oxygen or nitrogen may be added to counteract the polymerization. The same chemistry can be used in a magnetically enhanced reactive ion etcher (MERIE) or with a remote plasma source.Type: GrantFiled: May 13, 2002Date of Patent: February 1, 2005Inventors: Hoiman Hung, Joseph P Caulfield, Hongqing Shan, Ruiping Wang, Gerald Zheyao Yin
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Patent number: 6838369Abstract: A method for forming a contact hole of a semiconductor device, wherein a polymer residual on a bottom surface of the contact hole is treated with plasma of mixture gas containing oxygen to convert the polymer residual into a pure silicon oxide film free of carbon and fluorine for easy removal in a subsequent washing process is disclosed. The method comprises (a) sequentially forming a capping layer and a planarized interlayer insulating film on a semiconductor substrate having a predetermined lower structure; (b) selectively etching the interlayer insulating film to expose a predetermined region of the capping layer; (c) removing the exposed capping layer; (d) subjecting the resulting structure to a plasma treatment using a mixture gas containing oxygen; and (e) performing a cleaning process.Type: GrantFiled: June 30, 2003Date of Patent: January 4, 2005Assignee: Hynix Semiconductor Inc.Inventors: Ho Seok Lee, Dong Sauk Kim, Jin Woong Kim
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Patent number: 6838391Abstract: A method for the production of semiconductor components which includes applying masking layers and components on epitaxial semiconductor substrates within the epitaxy reactor without removal of the substrate from the reactor. At least one of the masking layers is HF soluble such that a gas etchant may be introduced within the reactor so as to etch a select number and portion of masking layers. This method may be used for production of lateral integrated components on a substrate wherein the components may be of the same or different type. Such types include electronic and optoelectronic components. Numerous masking layers may be applied, each defining particular windows intended to receive each of the various components. In the reactor, the masks may be selectively removed, then the components grown in the newly exposed windows.Type: GrantFiled: July 22, 2003Date of Patent: January 4, 2005Assignee: Osram Opto Semiconductors GmbH & Co. oHGInventor: Volker Härle
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Patent number: 6831005Abstract: A process for the formation of structures in microelectronic devices such as integrated circuit devices. Vias, interconnect metallization and wiring lines are formed using single and dual damascene techniques wherein dielectric layers are treated with a wide electron beam exposure.Type: GrantFiled: October 17, 2000Date of Patent: December 14, 2004Assignee: Allied Signal, Inc.Inventor: Matthew F. Ross
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Patent number: 6831019Abstract: In one implementation, a plasma etching method comprises forming a GexSey chalcogenide comprising layer over a substrate. A mask comprising an organic masking material is formed over the GexSey chalcogenide comprising layer. The mask comprises a sidewall. At least prior to plasma etching the GexSey comprising layer, the sidewall of the mask is exposed to a fluorine comprising material. After exposing, the GexSey chalcogenide comprising layer is plasma etched using the mask and a hydrogen containing etching gas. The plasma etching forms a substantially vertical sidewall of the GexSey chalcogenide comprising layer which is aligned with a lateral outermost extent of the sidewall of the mask.Type: GrantFiled: August 29, 2002Date of Patent: December 14, 2004Assignee: Micron Technology, Inc.Inventors: Li Li, Terry L. Gilton, Kei-Yu Ko, John T. Moore, Karen Signorini
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Patent number: 6828252Abstract: A chemical vapor deposition method includes providing a semiconductor substrate within a chemical vapor deposition chamber. At least one liquid deposition precursor is vaporized with a vaporizer to form a flowing vaporized precursor stream. The flowing vaporized precursor stream is initially bypassed from entering the chamber for a first period of time while the substrate is in the deposition chamber. After the first period of time, the flowing vaporized precursor stream is directed to flow into the chamber with the substrate therein under conditions effective to chemical vapor deposit a layer over the substrate. A method of etching a contact opening over a node location on a semiconductor substrate is disclosed.Type: GrantFiled: April 21, 2004Date of Patent: December 7, 2004Assignee: Micron Technology, Inc.Inventors: Mark E. Jost, Chris W. Hill
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Patent number: 6825121Abstract: A method of manufacturing a capacitor having increased capacitance using a single photo-lithographic step to form two holes of different sizes in the insulating layers, wherein a first insulating layer, an etching stop layer, and a second insulating layer are sequentially deposited on a semiconductor substrate, a preliminary hole is formed by etching a predetermined portion of the second insulating layer, the preliminary hole is expanded so as to form a first hole, a second hole is formed extending from the bottom of the first hole and having an etched area narrower than an etched area of the first hole, a first conductive layer pattern is formed on the sidewalls of the first and second holes and at the bottom surface of the second hole without burying the second hole, thereby increasing the storage capacitance of the capacitor while simplifying the manufacturing process.Type: GrantFiled: March 4, 2002Date of Patent: November 30, 2004Assignee: Samsung Electronics Co., Ltd.Inventors: Sung-Un Kwean, Jae-Seung Hwang
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Patent number: 6824697Abstract: Three fundamental and three derived aspects of the present invention are disclosed. The three fundamental aspects each disclose a process sequence that may be integrated in a full process. The first aspect, designated as “latent masking”, defines a mask in a persistent material like silicon oxide that is held abeyant after definition while intervening processing operations are performed. The latent oxide pattern is then used to mask an etch. The second aspect, designated as “simultaneous multi-level etching (SMILE)”, provides a process sequence wherein a first pattern may be given an advanced start relative to a second pattern in etching into an underlying material, such that the first pattern may be etched deeper, shallower, or to the same depth as the second pattern. The third aspect, designated as “delayed LOCOS”, provides a means of defining a contact hole pattern at one stage of a process, then using the defined pattern at a later stage to open the contact holes.Type: GrantFiled: November 2, 2001Date of Patent: November 30, 2004Assignee: Kionix, Inc.Inventors: James E. Moon, Timothy J. Davis, Gregory J. Galvin, Kevin A. Shaw, Paul C. Waldrop, Sharlene A. Wilson
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Patent number: 6808920Abstract: A microchip device for chemotaxis observation according to the present invention is provided with the first well in which chemotactic factors are to be filled, and the second well in which chemotactic cells are to be filled. There is provided a channel between the first well and the second well. The channel has a plurality of paths. A sidewall surfaces of the path is substantially perpendicular to a bottom surface, as formed by anisotropic dry etching.Type: GrantFiled: January 28, 2003Date of Patent: October 26, 2004Assignee: Yamatake CorporationInventors: Yasuhiro Goshoo, Takaaki Kuroiwa
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Patent number: 6809038Abstract: Formed is a lamination structure of a silicon oxide layer, a silicon nitride layer and a silicon oxide layer as an intermediate insulating film between a floating gate and a control gate. A silicon nitride film above the control gate is removed by dry etching. In this event, CH3F gas, CH2F2 gas or a mixed gas thereof and O2 gas are used as an etching gas, a pressure inside a reaction chamber is set in the range of 10.6 to 13.3 Pa (80 to 100 mTorr), and a flow rate of the O2 gas is set five times that of the CH3F gas, CH2F2 gas or mixed gas thereof or more.Type: GrantFiled: February 12, 2003Date of Patent: October 26, 2004Assignee: Fujitsu LimitedInventor: Tatsuichiro Maki
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Patent number: 6800213Abstract: An oxide etching recipe including a heavy hydrogen-free fluorocarbon having F/C ratios less than 2, preferably C4F6, an oxygen-containing gas such as O2 or CO, a lighter fluorocarbon or hydrofluorocarbon, and a noble diluent gas such as Ar or Xe. The amounts of the first three gases are chosen such that the ratio (F—H)/(C—O) is at least 1.5 and no more than 2. Alternatively, the gas mixture may include the heavy fluorocarbon, carbon tetrafluoride, and the diluent with the ratio of the first two chosen such the ratio F/C is between 1.5 and 2.Type: GrantFiled: June 7, 2002Date of Patent: October 5, 2004Inventors: Ji Ding, Hidehiro Kojiri, Yoshio Ishikawa, Keiji Horioka, Ruiping Wang, Robert W. Wu, Hoiman (Raymond) Hung
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Patent number: 6797189Abstract: A plasma etching process, particularly useful for selectively etching oxide over a feature having a non-oxide composition, such as silicon nitride and especially when that feature has a corner that is prone to faceting during the oxide etch. A primary fluorine-containing gas, preferably hexafluorobutadiene (C4F6), is combined with a significantly larger amount of the diluent gas xenon (Xe) enhance nitride selectivity without the occurrence of etch stop. The chemistry is also useful for etching oxides in which holes and corners have already been formed, for which the use of xenon also reduces faceting of the oxide. For this use, the relative amount of xenon need not be so high. The invention may be used with related heavy fluorocarbons and other fluorine-based etching gases.Type: GrantFiled: March 25, 1999Date of Patent: September 28, 2004Inventors: Hoiman (Raymond) Hung, Joseph P. Caulfield, Hongqing Shan, Michael Rice, Kenneth S Collins, Chunshi Cui
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Patent number: 6777333Abstract: A method for fabricating a semiconductor device includes the steps of: forming an insulating film on a conductive pattern formed on a substrate; forming a resist pattern on the insulating film; performing etching to the insulating film using the resist pattern as a mask to form in the insulating film an opening at which part of the surface of the conductive pattern is exposed; forming an antioxidant layer on the part of surface of the conductive pattern exposed while removing the resist pattern; and depositing a conductive film on the conductive pattern from which the antioxidant layer has been removed.Type: GrantFiled: August 27, 2003Date of Patent: August 17, 2004Assignee: Matsushita Electric Industrial Co., Ltd.Inventor: Masahiro Joei
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Patent number: 6767794Abstract: A semiconductor device having gate oxide with a first thickness and a second thickness is formed by initially implanting a portion of the gate area of the semiconductor substrate with nitrogen ions and then forming a gate oxide on the gate area. Preferably the gate oxide is grown by exposing the gate area to an environment of oxygen. A nitrogen implant inhibits the rate of SiO2 growth in an oxygen environment. Therefore, the portion of the gate area with implanted nitrogen atoms will grow or form a layer of gate oxide, such as SiO2, which is thinner than the portion of the gate area less heavily implanted or not implanted with nitrogen atoms. The gate oxide layer could be deposited rather than growing the gate oxide layer. After forming the gate oxide layer, polysilicon is deposited onto the gate oxide. The semiconductor substrate can then be implanted to form doped drain and source regions. Spacers can then be placed over the drain and source regions and adjacent the ends of the sidewalls of the gate.Type: GrantFiled: January 5, 1998Date of Patent: July 27, 2004Assignee: Advanced Micro Devices, Inc.Inventors: Mark I. Gardner, Michael Allen, H. James Fulford
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Patent number: 6762127Abstract: The present invention provides a novel etching technique for etching a layer of C-doped silicon oxide, such as a partially oxidized organo silane material. This technique, employing CH2F2/Ar chemistry at low bias and low to intermediate pressure, provides high etch selectivity to silicon oxide and improved selectivity to organic photoresist. Structures including a layer of partially oxidized organo silane material (1004) deposited on a layer of silicon oxide (1002) were etched according to the novel technique, forming relatively narrow trenches (1010, 1012, 1014, 1016, 1030, 1032, 1034 and 1036) and wider trenches (1020, 1022, 1040 and 1042). The technique is also suitable for forming dual damascene structures (1152, 1154 and 1156). In additional embodiments, manufacturing systems (1410) are provided for fabricating IC structures of the present invention. These systems include a controller (1400) that is adapted for interacting with a plurality of fabricating stations (1420, 1422, 1424, 1426 and 1428).Type: GrantFiled: August 23, 2001Date of Patent: July 13, 2004Inventors: Yves Pierre Boiteux, Hui Chen, Ivano Gregoratto, Chang-Lin Hsieh, Hoiman Hung, Sum-Yee Betty Tang
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Patent number: 6759286Abstract: A method of fabricating a gate structure of a field effect transistor, comprising forming a hard mask, etching a gate electrode, and contemporaneously forming a gate dielectric and removing the hard mask.Type: GrantFiled: September 16, 2002Date of Patent: July 6, 2004Inventors: Ajay Kumar, Padmapani C. Nallan
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Patent number: 6759336Abstract: Methods for reducing contamination of semiconductor substrates after processing are provided. The methods include heating the processed substrate to remove absorbed chemical species from the substrate surface by thermal desorption. Thermal desorption can be performed either in-situ or ex-situ. The substrate can be heated by convection, conduction, and/or radiant heating. The substrate can also be heated by treating the surface of the processed substrate with an inert plasma during which treatment ions in the plasma bombard the substrate surface raising the temperature thereof. Thermal desorption can also be performed ex-situ by applying thermal energy to the substrate during transport of the substrate from the processing chamber and/or by transporting the substrate to a transport module (e.g., a load lock) or to a second processing chamber for heating. Thermal desorption during transport can be enhanced by purging an inert gas over the substrate surface.Type: GrantFiled: November 18, 2002Date of Patent: July 6, 2004Assignee: Lam Research CorporationInventors: Robert Chebi, David Hemker
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Publication number: 20040121614Abstract: A method for forming a pattern using a printing process is disclosed in the present invention. The method includes forming a resist layer on a substrate having an etching layer thereon, locating a master having a convex pattern over the substrate, pressing the master against the substrate until the convex pattern of the master directly contacts the etching layer, and removing a portion of the resist layer to expose a surface over the substrate, the removed portion of the resist layer having a width substantially the same as the convex portion of the master.Type: ApplicationFiled: September 30, 2003Publication date: June 24, 2004Applicant: LG. Philips LCD Co., Ltd.Inventors: Myoung-Kee Baek, Kwon-Shik Park
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Patent number: 6746615Abstract: An in-process microelectronics device is treated by applying a heated liquid to the surface of the in-process microelectronics device, removing a portion of the liquid from the surface of the in-process microelectronics device and applying anhydrous HF gas to the surface of the in-process microelectronics device.Type: GrantFiled: September 14, 2000Date of Patent: June 8, 2004Assignee: FSI International, Inc.Inventor: Christina Ann Ellis
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Patent number: 6740247Abstract: The invention provides HF vapor process conditions that can be precisely controlled with a high degree of reproducibility for a wide range of starting wafer conditions. These HF vapor processes for, e.g., etching oxide on a semiconductor substrate, cleaning a contaminant on a semiconductor substrate, removing etch residue from a metal structure on a semiconductor substrate, and cleaning a metal contact region of a semiconductor substrate. In the HF vapor process, a semiconductor substrate having oxide, a contaminant, metal etch residue, or a contact region to be processed is exposed to hydrofluoric acid vapor and water vapor in a process chamber held at temperature and pressure conditions that are controlled to form on the substrate no more than a sub-monolayer of etch reactants and products produced by the vapor as the substrate is processed by the vapor.Type: GrantFiled: February 4, 2000Date of Patent: May 25, 2004Assignee: Massachusetts Institute of TechnologyInventors: Yong-Pil Han, Herbert H. Sawin
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Publication number: 20040089908Abstract: A Schottky diode is fabricated by a sequence of fabrication by a sequence of fabrication steps. An active region of a semiconductor substrate is defined in which a Schottky diode is fabricated. At least first and second layers of insulating material are applied over the active area. A first layer of insulating material, having a first etching rate, is applied over the active area. A second layer of insulating material having a second, greater, etch rate is applied over the first layer of insulating material to a thickness that is about twice the thickness of the first layer of insulating material. The insulating material is patterned and a window is etched through the layers of insulating material to the semiconductor substrate. Metal is applied and unwanted metal is etched away leaving metal in the window forming a Schottky contact therein. One or more barrier layers may be employed.Type: ApplicationFiled: October 29, 2003Publication date: May 13, 2004Inventors: John Charles Desko, Michael J. Evans, Chung-Ming Hsieh, Tzu-Yen Hsieh, Bailey R. Jones, Thomas J. Krutsick, John Michael Siket, Brian Eric Thompson, Steven W. Wallace
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Patent number: 6720273Abstract: A device and a method capable of being carried out therewith for, preferably, anisotropically etching a substrate (10), in particular, a patterned silicon body, with the assistance of a plasma (14), is proposed. In the process, the plasma (14) is produced by a plasma source (13) to which a high-frequency generator (17) is connected for applying a high-frequency power. Moreover, this high-frequency generator is in communication with a first means which periodically changes the high-frequency power applied to the plasma source (13). Besides, provision is preferably made for a second means which adapts the output impedance of the high-frequency generator (17) to the prevailing impedance of the plasma source (13) which changes as a function of the high-frequency power.Type: GrantFiled: April 20, 2001Date of Patent: April 13, 2004Assignee: Robert Bosch GmbHInventors: Volker Becker, Franz Laermer, Andrea Schilp, Thomas Beck
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Publication number: 20040065957Abstract: A method of fabricating a semiconductor device includes the step of depositing a second insulating film on a first insulating film, patterning the second insulating film to form an opening therein, and etching the first insulating film while using the second insulating film as an etching mask, wherein a low-dielectric film is used for the second insulating film.Type: ApplicationFiled: April 21, 2003Publication date: April 8, 2004Inventors: Kaoru Maekawa, Masahito Sugiura
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Patent number: 6716324Abstract: Provided is a method of forming a transparent, conductive film on a semiconductor layer formed on a substrate, by sputtering, wherein voltages are applied independently of each other to both a target and the substrate, respectively, and a bias voltage appearing in the substrate is controlled so as to form the transparent, conductive film on only a portion except for a defective region of the semiconductor layer, thereby restraining shunting of the transparent, conductive film and achieving excellent appearance thereof. Also provided are a defective region compensation method of a semiconductor layer, a photovoltaic element, and a method of producing the photovoltaic element.Type: GrantFiled: January 30, 2002Date of Patent: April 6, 2004Assignee: Canon Kabushiki KaishaInventors: Toshihiro Yamashita, Yasuyoshi Takai, Hiroshi Izawa
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Patent number: 6716763Abstract: A method for controlling striations and CD loss in a plasma etching method is disclosed. During the etching process, the substrate of semiconductor material to be etched is exposed first to plasma under a low power strike and subsequently to a conventional high power strike. CD loss has been found to be reduced by about 400 Angstroms and striations formed in the contact holes are reduced.Type: GrantFiled: November 26, 2001Date of Patent: April 6, 2004Assignee: Micron Technology, Inc.Inventors: Li Li, Bradley J. Howard
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Patent number: 6709976Abstract: The invention describes an improved method of fabricating trench structures. This method enhances trench structure reliability by reducing dielectric breakdown in high voltage applications, for example. The invention uses etching and thermal oxidation techniques to round and smooth the corners at the bottom of the trench structure. The smoothing of the trench corners reduces the electrical fields that cause insulator breakdown.Type: GrantFiled: July 29, 2002Date of Patent: March 23, 2004Assignee: The United States of America as represented by the Secretary of the NavyInventors: Nackieb M. Kamin, Stephen D. Russell, Stanley R. Clayton, Shannon D. Kasa
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Publication number: 20040053490Abstract: A semiconductor device manufacturing method that makes it possible to assure the required size of flat areas at the wiring overlay nitride film and to form an SAC structure in which the selectivity is not lowered at corners is provided. The method comprises a first etching process in which an insulating film 106 is etched under conditions for forming a vertical opening (vertical conditions) to open up the insulating film 106 to a point near a wiring overlay nitride film 105, a second etching process in which the insulating film 106 is opened until 105 becomes exposed by etching the insulating film 106 a under conditions assuring a high ratio of selectivity relative to the wiring overlay nitride film 105 (SAC conditions (1)) and a third etching process in which an insulating film 106a located between a first electrode G and a second electrode G is removed by etching the insulating film under conditions with a low ratio of selectivity relative to the wiring overlay nitride film 105 (SAC conditions (2)).Type: ApplicationFiled: September 16, 2002Publication date: March 18, 2004Inventors: Takeshi Nagao, Atsushi Yabata
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Patent number: 6706200Abstract: Three fundamental and three derived aspects of the present invention are disclosed. The three fundamental aspects each disclose a process sequence that may be integrated in a full process. The first aspect, designated as “latent masking”, defines a mask in a persistent material like silicon oxide that is held abeyant after definition while intervening processing operations are performed. The latent oxide pattern is then used to mask an etch. The second aspect, designated as “simultaneous multi-level etching (SMILE)”, provides a process sequence wherein a first pattern may be given an advanced start relative to a second pattern in etching into an underlying material, such that the first pattern may be etched deeper, shallower, or to the same depth as the second pattern. The third aspect, designated as “delayed LOCOS”, provides a means of defining a contact hole pattern at one stage of a process, then using the defined pattern at a later stage to open the contact holes.Type: GrantFiled: November 2, 2001Date of Patent: March 16, 2004Assignee: Kionix, Inc.Inventors: James E. Moon, Timothy J. Davis, Gregory J. Galvin, Kevin A. Shaw, Paul C. Waldrop, Sharlene A. Wilson
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Publication number: 20040048489Abstract: A semiconductor device capable of compatibly suppressing a microloading effect (irregular etching) and over-etching also in formation of a fine contact hole requiring a high aspect ratio is obtained. This semiconductor device comprises a first conductive part, an insulator film having an opening formed on the first conductive part and a second conductive part electrically connected with the first conductive part through the opening. The insulator film includes an upper insulator film and a lower insulator film, stacked/formed at least around a connection part between the first conductive part and the second conductive part, consisting of different materials.Type: ApplicationFiled: July 23, 2003Publication date: March 11, 2004Applicant: SANYO ELECTRIC CO., LTD.Inventors: Yoshinari Ichihashi, Takashi Goto
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Patent number: 6703314Abstract: Provided is a method for forming a self aligned contact (SAC) of a semiconductor device that can minimize the loss of gate electrodes and hard mask. The method includes the steps of: providing a semiconductor substrate on which a plurality of conductive patterns are formed; forming a first insulation layer along the profile of the conductive patterns on the substrate; forming a second insulation layer on the substrate and simultaneously forming voids between the conductive patterns; forming a third insulation layer on the first insulation layer; and forming contact holes that expose the surface of the substrate between the conductive patterns by etching the third insulation layer and the second insulation layer covering the voids.Type: GrantFiled: December 3, 2002Date of Patent: March 9, 2004Assignee: Hynix Semiconductor Inc.Inventors: Sung-Kwon Lee, Sang-Ik Kim, Chang-Youn Hwang, Weon-Joon Suh, Min-Suk Lee
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Patent number: 6702950Abstract: Three fundamental and three derived aspects of the present invention are disclosed. The three fundamental aspects each disclose a process sequence that may be integrated in a full process. The first aspect, designated as “latent masking”, defines a mask in a persistent material like silicon oxide that is held abeyant after definition while intervening processing operations are performed. The latent oxide pattern is then used to mask an etch. The second aspect, designated as “simultaneous multi-level etching (SMILE)”, provides a process sequence wherein a first pattern may be given an advanced start relative to a second pattern in etching into an underlying material, such that the first pattern may be etched deeper, shallower, or to the same depth as the second pattern. The third aspect, designated as “delayed LOCOS”, provides a means of defining a contact hole pattern at one stage of a process, then using the defined pattern at a later stage to open the contact holes.Type: GrantFiled: November 2, 2001Date of Patent: March 9, 2004Inventors: James E. Moon, Timothy J. Davis, Gregory J. Galvin, Kevin A. Shaw, Paul C. Waldrop, Sharlene A. Wilson
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Patent number: 6680258Abstract: An opening through an insulating layer between a first layer and a second layer of a semiconductor device is formed where the second layer is a polysilicon or amorphous silicon hard mask layer. The polysilicon or amorphous silicon hard mask layer is etched to form at least one opening through the polysilicon or amorphous silicon hard mask layer using a patterning layer as a mask having at least one opening. The insulating layer is etched to form the opening through the insulating layer using the etched polysilicon or amorphous silicon hard mask layer as a mask. The etched polysilicon or amorphous silicon hard mask layer is nitridized prior to subsequent processing.Type: GrantFiled: October 2, 2002Date of Patent: January 20, 2004Assignee: ProMOS Technologies, Inc.Inventors: Yuan-Li Tsai, Yu-Piao Wang
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Patent number: 6677248Abstract: Disclosed is a coaxial type signal line that solves problems associated with signal interference and the connection of signal lines that are generated in a radio frequency (RF) electrical system. A method for manufacturing the coaxial type signal line includes the steps of forming a groove on a substrate, forming a first ground line on a surface of the groove and a plain surface of the substrate, forming a first dielectric layer including dielectric material on the first ground line formed on the surface of the groove, forming a signal line on the first dielectric layer the signal line for transmitting signals, forming a second dielectric layer including dielectric material on the signal line and the first dielectric layer, and forming a second ground line on the first ground line and the second dielectric layer.Type: GrantFiled: November 8, 2001Date of Patent: January 13, 2004Assignee: Dynamic Solutions International, Inc.Inventors: Young-Se Kwon, In-Ho Jeong
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Patent number: 6677247Abstract: A method of forming a contact in an integrated circuit between a first metalization layer and a silicon substrate. In one embodiment the method comprises forming a premetal dielectric layer over the silicon substrate, etching a contact hole through the premetal dielectric layer and then forming a thin silicon nitride layer on an outer surface of the contact hole. The silicon nitride layer reduces overetching that may otherwise occur when oxidation build-up is removed from the silicon interface within the contact hole by a preclean process. After the preclean process, the contact hole is then filled with one or more conductive materials. In various embodiments the silicon nitride layer is formed by exposing the contact hole to a nitrogen plasma, depositing the layer by a chemical vapor deposition process and depositing the layer by an atomic layer deposition process. In other embodiments, the method is applicable to the formation of vias through intermetal dielectric layers.Type: GrantFiled: January 7, 2002Date of Patent: January 13, 2004Assignee: Applied Materials Inc.Inventors: Zheng Yuan, Steve Ghanayem, Randhir P. S. Thakur
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Patent number: 6673253Abstract: Three fundamental and three derived aspects of the present invention are disclosed. The three fundamental aspects each disclose a process sequence that may be integrated in a full process. The first aspect, designated as “latent masking”, defines a mask in a persistent material like silicon oxide that is held abeyant after definition while intervening processing operations are performed. The latent oxide pattern is then used to mask an etch. The second aspect, designated as “simultaneous multi-level etching (SMILE)”, provides a process sequence wherein a first pattern may be given an advanced start relative to a second pattern in etching into an underlying material, such that the first pattern may be etched deeper, shallower, or to the same depth as the second pattern. The third aspect, designated as “delayed LOCOS”, provides a means of defining a contact hole pattern at one stage of a process, then using the defined pattern at a later stage to open the contact holes.Type: GrantFiled: November 2, 2001Date of Patent: January 6, 2004Assignee: Kionix, Inc.Inventors: James E. Moon, Timothy J. Davis, Gregory J. Galvin, Kevin A. Shaw, Paul C. Waldrop, Sharlene A. Wilson
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Patent number: 6667245Abstract: A microelectromechanical (MEM) switch is fabricated inexpensively by using processing steps which are standard for fabricating multiple metal layer integrated circuits, such as CMOS. The exact steps may be adjusted to be compatible with the process of a particular foundry, resulting in a device which is both low cost and readily integrable with other circuits. The processing steps include making contacts for the MEM switch from metal plugs which are ordinarily used as vias to connect metal layers which are separated by a dielectric layer. Such contact vias are formed on either side of a sacrificial metallization area, and then the interconnect metallization is removed from between the contact vias, leaving them separated. Dielectric surrounding the contacts is etched back so that they protrude toward each other. Thus, when the contacts are moved toward each other by actuating the MEM switch, they connect firmly without obstruction.Type: GrantFiled: December 13, 2001Date of Patent: December 23, 2003Assignee: HRL Laboratories, LLCInventors: Lap-Wai Chow, Tsung-Yuan Hsu, Daniel J. Hyman, Robert Y. Loo, Paul Ouyang, James H. Schaffner, Adele Schmitz, Robert N. Schwartz
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Patent number: 6656843Abstract: A single mask process is described for making a trench type fast recovery process. The single mask defines slots in a photoresist for locally removing strips of nitride and oxide from atop silicon and for subsequently etching trenches in the silicon. A boron implant is carried out in the bottoms of the trenches to form local P/N junctions. The oxide beneath the nitride is then fully stripped in the active area and only partly stripped in the termination area in which the trenches are wider spaced than in the active area. Aluminum is then deposited atop the active area and in the trenches, but is blocked from contact with silicon in the active area by the remaining nitride layer.Type: GrantFiled: April 25, 2002Date of Patent: December 2, 2003Assignee: International Rectifier CorporationInventor: Igor Bol
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Patent number: 6651678Abstract: A method of etching a semiconductor device preventing tapering of a gate electrode edge includes a main etching of an electrode or wiring material supported by a dielectric film at a semiconductor substrate surface to expose the dielectric film. After the main etching step, residues of the electrode or the wiring material by sequentially etching utilizing a first gas mixture including a halogen-containing gas and an additive gas suppressing etching of the dielectric film by the halogen-containing gas, and in a second gas mixture gas including the halogen-containing gas and the additive gas and having the additive gas amount in a larger concentration than the first gas mixture.Type: GrantFiled: April 18, 2002Date of Patent: November 25, 2003Assignee: Mitsubishi Denki Kabushiki KaishaInventors: Kenji Shintani, Mutumi Tuda, Junji Tanimura, Takahiro Maruyama, Ryoichi Yoshifuku
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Patent number: 6649533Abstract: A method and an apparatus for forming an under bump metallurgy layer over a contact pad area on an interconnect formed over a semiconductor substrate are provided which eliminate a pretreatment process for removing native oxide on the contact pad area prior to the deposition of the under bump metallurgy layer. In one embodiment, the removal of a cap layer which insulates the contact pad area and the deposition of the under bump metallurgy layer are carried out without leaving a vacuum environment.Type: GrantFiled: May 5, 1999Date of Patent: November 18, 2003Assignee: Advanced Micro Devices, Inc.Inventor: John A. Iacoponi
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Patent number: 6642121Abstract: A method of controlling the quantity and uniformity of distribution of bonded oxygen atoms at the interface between the polysilicon and the monocrystalline silicon includes carrying out, after having loaded the wafer inside the heated chamber of the reactor and evacuated the chamber of the LPCVD reactor under nitrogen atmosphere, a treatment of the wafer with hydrogen at a temperature generally between 500 and 1200° C. and at a vacuum generally between 0.1 Pa and 60000 Pa. The treatment is performed at a time generally between 0.1 and 120 minutes, to remove any and all the oxygen that may have combined with the silicon on the surface of the monocrystalline silicon during the loading inside the heated chamber of the reactor even if it is done under a nitrogen flux. After such a hydrogen treatment, another treatment is carried out substantially under the same vacuum conditions and at a temperature generally between 700 and 1000° C. with nitrogen protoxide (N2O) for a time generally between 0.Type: GrantFiled: December 18, 2001Date of Patent: November 4, 2003Assignee: STMicroelectronics S.r.l.Inventors: Cateno M. Camalleri, Simona Lorenti, Denise Cali′, Patrizia Vasquez, Giuseppe Ferla
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Patent number: 6638848Abstract: A method of rapid etching of an insulating film including an organic-based dielectric film without forming a damage layer or causing decline of the throughput, including the steps of forming an insulating film including an organic-based dielectric film such as a stacked film having a polyarylether film or other organic-based dielectric film and a silicon oxide-based dielectric film or other insulating film, forming a mask layer by patterning above the insulating film, and when etching the organic-based dielectric film portion, using ions or radicals containing NH group generated by gaseous discharge in a mixed gas of hydrogen gas and nitrogen gas or a mixed gas of ammonia gas for etching using the mask layer as an etching mask, to etch the insulating layer and form openings etc. while generating reaction products containing CN group.Type: GrantFiled: March 2, 2000Date of Patent: October 28, 2003Assignee: Sony CorporationInventors: Masanaga Fukasawa, Shingo Kadomura