Plural -c(=o)o- Groups Attached To Each Other Directly Or Indirectly By Nonionic Bonding (e.g., Polyesters, Half Ester-half Acid Compounds, Etc.) Patents (Class 44/389)
  • Patent number: 6802874
    Abstract: The invention disclosed herein relates to linear compounds in the form of oligomers or polymers containing unsubstituted or substituted phenol units and unsubstituted or substituted salicylic acid units. These compounds are useful as additives for lubricants and fuels. Metal salts of these compounds are useful as lubricant additives. A process for making these compounds is disclosed.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: October 12, 2004
    Assignee: The Lubrizol Corporation
    Inventors: David John Moreton, Rodney John McAtee
  • Patent number: 6793695
    Abstract: A fuel composition exhibiting improved anti-static properties, comprises a liquid fuel which contains less than 500 parts per million by weight sulfur; 0.001 to 1 ppm of a hydrecarbyl monoamine or hydrocarbyl-substituted poly(alkylenieamine); and 10 to 500 ppm of at least one fatty acid containing 8 to 24 carbon atoms, or an ester thereof.
    Type: Grant
    Filed: August 28, 2002
    Date of Patent: September 21, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Mark F. Wilkes, David A. Duncan, Shaun P. Carney
  • Patent number: 6780209
    Abstract: The disclosed invention relates to a composition comprising a partially dehydrated product made by: (I) reacting (A) a hydrocarbyl substituted succinic acid or anhydride with (B) a polyol, a polyamine, a hydroxyamine, or a mixture of two or more thereof, to form a first intermediate product comprising: an ester, partial ester or mixture thereof when (B) is a polyol; an amide, imide, salt, amide/salt, partial amide or mixture of two or more thereof when (B) is a polyamine; or an ester, partial ester, amide, partial amide, amide/salt, imide, ester/salt, salt or a mixture of two or more thereof when (B) is a hydroxyamine, a mixture of a polyol and a polyamine, a mixture of a polyol and a hydroxyamine, a mixture of a polyamine and a hydroxyamine, or a mixture of a polyol, a polyamine and a hydroxyamine; the hydrocarbyl substituent of said acid or anhydride having an average of about 8 to about 200 carbon atoms; and (II) heating said first intermediate product at an effective temperature to form a second interme
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: August 24, 2004
    Assignee: The Lubrizol Corporation
    Inventors: Brian B. Filippini, Richard M. Lange, Bryan A. Grisso, Bryn Hird
  • Patent number: 6767374
    Abstract: Hydrogenated block copolymers are used as a component in a cold flow additive composition.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: July 27, 2004
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Dhanesh Gordon Goberdhan, Robert Dryden Tack, Kenneth Lewtas, Andrew Matthew McAleer, Lewis John Fetters, John Huang
  • Patent number: 6730138
    Abstract: The present invention relates to emulsion compositions for starting a reformer of a fuel cell system. In particular, the invention includes emulsion compositions comprising hydrocarbon fuel, water and alkyl polyglycerol surfactants for starting a reformer of a fuel cell system.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: May 4, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ramesh Varadaraj, Paul Joseph Berlowitz
  • Publication number: 20040065003
    Abstract: Embodiments of the present invention are directed toward systems and methods of providing a low-emissions diesel fuel for use in cold climates. Such fuels may be prepared by a Fischer-Tropsch process and include a pour point depressant. Furthermore, the fuel is used in conjunction with a heated fuel delivery system so that low cloud points are not necessary. Fuels prepared according to embodiments of the present invention may be produced in higher yields than otherwise possible because a higher paraffin wax content can be tolerated, thus obviating the need to remove or exclude the wax. These fuels are characterized by a sulfur content less than 1 ppm, a cetane number greater than 60, an aromatics content less than 1 wt %, and a difference between the cloud and pour points that is greater than about 5° C. The present fuel may be prepared by a Fischer-Tropsch synthesis from any number of carbon-containing sources such natural gas, coal, petroleum products, and combinations thereof.
    Type: Application
    Filed: October 4, 2002
    Publication date: April 8, 2004
    Inventor: Dennis J. O'Rear
  • Patent number: 6712867
    Abstract: A process for the esterification of a triglyceride. The process comprises forming a single phase solution of said triglyceride in an alcohol selected from methanol and ethanol, the ratio of alcohol to triglyceride being 15:1 to 35:1. The solution further comprises a co-solvent in an amount to effect formation the single phase and a base catalyst for the esterification reaction. After a period of time, ester is recovered from the solution. Esterification is rapid and proceeds essentially to completion. The esters may be used as biofuel or biodiesel.
    Type: Grant
    Filed: August 16, 2000
    Date of Patent: March 30, 2004
    Assignee: Biox Corporation
    Inventor: David Gavin Brooke Boocock
  • Patent number: 6652610
    Abstract: The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formula  in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is hydrogen or an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or C1-C20-alkyl, and B) 5 to 95% by weight of a terpolymer containing from 10 to 35 mol % of structural units derived from the vinyl ester of a carboxylic acid having 2 to 4 carbon atoms, from 1 to 15 mol % of structural units derived from the vinyl ester of a neocarboxylic acid having 8 to 15 carbon atoms, and structural units of ethylene to 100 mol %, having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: November 25, 2003
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann
  • Publication number: 20030196372
    Abstract: A fuel additive package is disclosed that prevents degradation of hydrocarbon fuels upon storage and permits extended use of such motor fuels without intake-valve deposit formation in vehicle motors. The additive contains an antioxidant, metal deactivator, corrosion inhibitor, and detergent. The corrosion inhibitor, preferably a carboxylic acid containing a carbon number equal to or less than 18 and the detergent component, preferably a polyisobutylene diamine are selected to avoid antagonistic effects with the antioxidant and metal deactivator components while the antioxidant and metal deactivator components are used in markedly reduced amounts to avoid antagonistic effects resulting in increased intake-valve deposits.
    Type: Application
    Filed: April 23, 2002
    Publication date: October 23, 2003
    Inventor: Leslie R. Wolf
  • Publication number: 20030177691
    Abstract: An alternative fuel source, preferably for use in a boiler, is provided. The fuel source is comprised of a partially hydrogenated vegetable oil and diesel fuel. Preferably, the partially hydrogenated vegetable oil has a Iodine Value (IV) ranging from approximately 50 to approximately 120.
    Type: Application
    Filed: March 19, 2002
    Publication date: September 25, 2003
    Applicant: Bunge North America, Inc.
    Inventors: Wilbur J. Stewart, Billy R. Coles, Sarah Michalek, Susan Gleissner
  • Publication number: 20030167681
    Abstract: Procedure to generate biodiesel fuels with improved properties at low temperature by the transesterification of triglycerides with alcohols such as methanol or ethanol, optionally in the presence of methyl or ethyl acetates of fatty acids and an inert solvent, to produce methyl or ethyl esters of fatty acids, glycerine and, where appropriate, glycerine triacetate, followed by the separation of crude glycerine that is reacted with aldehydes, ketones and/or acetic acid or methyl or ethyl acetates to produce acetals, glycerine cetals and/or glycerine acetates. The acetals, glycerine cetals and/or glycerine acetates are mixed with methyl or ethyl esters of fatty acids in concentrations of approximately 0.5-20% by weight to obtain a biodiesel with improved properties at low temperatures.
    Type: Application
    Filed: December 23, 2002
    Publication date: September 11, 2003
    Applicant: INDUSTRIAL MANAGEMENT, S.A.
    Inventor: Juan Delgado Puche
  • Patent number: 6596038
    Abstract: The invention disclosed herein relates to linear compounds in the form of oligomers or polymers containing unsubstituted or substituted phenol units and unsubstituted or substituted salicylic acid units. These compounds are useful as additives for lubricants and fuels. Metal salts of these compounds are useful as lubricant additives. The process for making these compounds involves reacting phenol units and salicylic acid units in an organic solvent.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: July 22, 2003
    Assignee: The Lubrizol Corporation
    Inventors: David John Moreton, Rodney John McAtee
  • Patent number: 6583093
    Abstract: A cyclic compound comprising m units of the formula Ia: and n units of the formula (Ib): joined together to form a ring, wherein Y and Y2 are divalent bridging groups which may be the same or different in each unit; R0 is H or (C1-C6) alkyl or is a metal or ammonium cation; R5 is H or (C1-C60) alkyl or OH group; j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydrocarbyl group; each of R1, R2 and R4, which may be the same or different, is hydroxyl, hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, with the provisos that i) at least one of R1, R2, R4 is hydroxyl, and m+n is 4 to 20, m is 1-8 and n is at least 3, and ii) in formula Ia at least one OH group is in the meta or para position to the COOR0 group and/or at least one R5 group is OH.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: June 24, 2003
    Assignee: BP Oil International Limited
    Inventors: Spencer Edwin Taylor, Michael John Wilson
  • Patent number: 6579329
    Abstract: A mixture suitable as fuel additive and lubricant additive and comprising essentially (A) at least one amine which carries a hydrocarbon radical having an average molecular weight of from 500 to 10,000, (B) at least one hydrocarbon polymer which has an average molecular weight of from 300 to 10,000 and may be present in unhydrogenated or hydrogenated form and (C) at least one conventional carrier oil has a weight ratio of component A to component B of from 80:20 to 60:40.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: June 17, 2003
    Inventors: Jürgen Thomas, Harald Schwahn, Peter Schreyer
  • Patent number: 6511520
    Abstract: The invention concerns an additive for motive fuel additive, in particular with low sulphur content not more than 500 ppm, consisting for the most part of a combination comprising 5 to 95 wt. % of a glycerol monoester R1—C(O)—O—CH2—CHO—CH2OH or R1—C(O)—O—CH(CH2OH)2, R1 being an alkyl chain containing 8 to 60 carbon atoms, or a monocyclic or polycyclic group comprising 8 to 60 carbon atoms, and from 5 to 95 wt % of a compound of formula R2—C(O)—X, R2 being an alkyl chain containing 8 to 24 carbon atoms, or a monocyclic or polycyclic group comprising 8 to 60 carbon atoms, and X being selected among (i) the groups OR0, R0 being a hydrocarbon radical comprising 1 to 8 carbon atoms, optionally substituted by one or several esters; and (ii) the groups derived from primary or secondary amines and alkanolamines with aliphatic hydrocarbon chain, comprising 1 to 18 carbon atoms.
    Type: Grant
    Filed: October 28, 1999
    Date of Patent: January 28, 2003
    Assignee: Elf Antar France
    Inventors: Daniele Eber, Laurent Germanaud, Paul Maldonado
  • Patent number: 6482243
    Abstract: The present invention is directed to a composition for use in a combustion engine either as a fuel additive or as an additive for a crankcase lubricant. The composition may include a polyunsaturated aliphatic or alicyclic compound having at least three, but no more than six, double bonds to improve the combustion process by acting as pseudo-catalyst in the combustion reaction. The composition may further include a derivative of dihydrobenzo-gamma-pyrane to improve the combustion process by acting as pseudo-catalyst in the combustion reaction. The composition may further include surfactants such as polyethylene glycol and/or one or more polyoxyalkene derivatives of either polypropylene glycol, polyethylene glycol or sorbitol. A media of fatty acid esters is provided to dilute the combustion promoters, surfactants and other ingredients allowing accurate concentrations of these ingredients to be introduced into the fuel chamber.
    Type: Grant
    Filed: March 22, 2001
    Date of Patent: November 19, 2002
    Assignee: J.T. Granatelli Lubricants, Inc.
    Inventor: Vladimir Y. Podlipskiy
  • Patent number: 6475250
    Abstract: The invention relates to additives for improving cold-flow and lubricating properties of fuel oils, comprising A) 5-95% by weight of at least one oil-soluble amphiphile of the formulae in which R1 is an alkyl, alkenyl, hydroxyalkyl or aromatic radical having 1 to 50 carbon atoms, X is NH, NR3, O or S, y is 1, 2, 3 or 4, R2 is an alkyl radical carrying hydroxyl groups and having 2 to 10 carbon atoms and R3 is an alkyl radical carrying nitrogen and/or hydroxyl groups and having 2 to 10 carbon atoms or a C1-C20-alkyl radical, and B) 5 to 95% by weight of a terpolymer of ethylene, the vinyl ester of one or more aliphatic, linear or branched monocarboxylic acids which contain 2 to 20 carbon atoms in the molecule and a C5-C7-olefin containing from 9 to 18 mol % of vinyl ester and from 0.5 to 5 mol % of olefin (based in each case on the terpolymer), having a melt viscosity, measured at 140° C., of from 20 to 10,000 mPas.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: November 5, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Werner Reimann
  • Patent number: 6468319
    Abstract: This invention is a fuel composition comprising a major amount of base fuel and at least 3% w/w of an ester additive mixture derivable by reacting together either (a) (i) a saturated, aliphatic polyhydric alcohol having three or more primary alcohol groups, (ii) a C2-C15 saturated, aliphatic branched chain monohydric alcohol and (iii) a saturated, aliphatic C4-C10 dicarboxylic acid, or (b) a saturated aliphatic polyhydric alcohol having three or more primary alcohol groups with a C6-C15 saturated, aliphatic straight chain or branched chain monocarboxylic acid, or (c) a C2-C15 branched chain saturated aliphatic alcohol with a saturated, aliphatic dicarboxylic acid having 6-10 carbon atoms. The ester additive has a boiling point ≧150° C., a molecular weight ≧200 and an oxygen content ≧13% by weight of said ester additive mixture. The additive significantly reduces particulate emissions from the exhausts of diesel powered engines.
    Type: Grant
    Filed: July 13, 2000
    Date of Patent: October 22, 2002
    Assignee: ExxonMobil Research and Engineering Co.
    Inventors: Lisa I. Yeh, Richard H. Schlosberg
  • Patent number: 6458173
    Abstract: The invention provides the use of a poly(hydroxy-carboxylic acid)amide or -ester derivative of general formula I: wherein R is the residue of an amine, an aminoalcohol or a polyol linked to the or each poly(hydroxycarboxylic acid) via an amide or ester linkage; R1 is hydrogen or optionally substituted hydrocarbyl group containing up to 50 carbon atoms; A is an optionally substituted hydrocarbyl group; n is from 1-100, preferably 1-10 and p is from 1-5, as a fuel additive acting as a detergent and as a lubricity additive in fuel compositions. Moreover, the invention provides a fuel oil composition comprising of a major amount of a fuel oil, and a minor amount of an the additive as well as a additive concentration for use in a fuel oil composition.
    Type: Grant
    Filed: August 18, 2000
    Date of Patent: October 1, 2002
    Assignee: Infineum International Ltd.
    Inventor: Jian Lin
  • Publication number: 20020107153
    Abstract: A cyclic compound comprising m units of the formula Ia.
    Type: Application
    Filed: April 1, 2002
    Publication date: August 8, 2002
    Applicant: BP OIL INTERNATIONAL LIMITED
    Inventors: Spencer Edwin Taylor, Michael John Wilson
  • Publication number: 20020077254
    Abstract: A cyclic compound comprising m units of the formula Ia.
    Type: Application
    Filed: December 11, 2000
    Publication date: June 20, 2002
    Inventors: Spencer Edwin Taylor, Michael John Wilson
  • Patent number: 6371998
    Abstract: Liquid energy sources, e.g., liquid fuels comprising lipid vesicles having fuel additives such as water are disclosed herein. The liquid energy sources, methods for preparation, and methods of enhancing engine performance disclosed herein employing the lipid vesicles result in enhanced fuel efficiency and/or lowered engine emissions. The invention further relates to liquid energy sources containing such additives which further comprise a polymeric dispersion assistant, which reduces the interfacial tension and coalescence of vesicles during dispersion process and storage, and thereby provide transparent looks to the liquid energy source.
    Type: Grant
    Filed: June 26, 2000
    Date of Patent: April 16, 2002
    Assignee: IGEN, Inc.
    Inventor: Rajiv Mathur
  • Patent number: 6364918
    Abstract: Oil-soluble copolymers having an OH number of from 10 to 250 and a molecular weight of from 1000 to 100,000 g/mol, obtained from the reaction of a copolymer precursor which comprises structural units of A) from 5 to 95 mol-% of an olefinically unsaturated carboxylic acid or a derivative of such an acid, B) from 5 to 95 mol-% of an olefinically unsaturated compound having at least one hydrocarbon radical containing at least 6 carbon atoms, and, if desired, C) from 0 to 40 mol-% of further structural units selected from the group consisting of C1-C6-alkyl (meth)acrylates, C1-C6-alkyl vinyl esters and C2-C6-olefins, with a reagent, which must carry at least one OH group and which, apart from this OH group, has at least one further functional group which is capable of reacting with the carboxylic acid or the derivative of a carboxylic acid as in component A), where the residual acid number is set to a value below 50 mg of KOH/g of copolymer by addition of the reagent.
    Type: Grant
    Filed: June 9, 2000
    Date of Patent: April 2, 2002
    Assignee: Clariant GmbH
    Inventors: Matthias Krull, Waltraud Nagel
  • Patent number: 6293977
    Abstract: Products formed from polycarboxylic acids and epoxides form useful lubricity additives.
    Type: Grant
    Filed: September 22, 1998
    Date of Patent: September 25, 2001
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Rinaldo Caprotti, Christophe Ledeore
  • Patent number: 6284008
    Abstract: The lubricity of low sulfur fuels is enhanced by incorporation of a cold flow improver.
    Type: Grant
    Filed: January 14, 2000
    Date of Patent: September 4, 2001
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Rinaldo Caprotti
  • Patent number: 6280488
    Abstract: An additive composition comprising: (a) an ashless dispersant comprising an acylated nitrogen compound; and (b) a carboxylic acid, or an ester of the carboxylic acid and an alcohol wherein the acid has from 2 to 50 carbon atoms and the alcohol has one or more carbon atoms provides an improvement in the lubricity of fuel oils and exhibits improved solubility in the fuel oil.
    Type: Grant
    Filed: January 7, 1999
    Date of Patent: August 28, 2001
    Assignee: Exxon Chemical Patents INC
    Inventors: Brid Dillworth, Rinaldo Caprotti
  • Patent number: 6258135
    Abstract: Specific substituted aromatic ester compounds are useful as lubricity additives for middle distillate fuel oils.
    Type: Grant
    Filed: July 15, 1999
    Date of Patent: July 10, 2001
    Assignee: Exxon Chemical Patents Inc
    Inventors: Rinaldo Caprotti, Christophe Le Deore
  • Patent number: 6239298
    Abstract: There is disclosed a fuel lubricity additive, made by a two-step process wherein the first step is co-reacting an unsaturated base oil, predominantly from vegetable oil sources, and a compound having a diene structure and a carboxylic acid group, wherein the second step is esterifying or amidifying the free carboxylic acid group of anhydride group with a poly-hydroxy-containing compound or poly-amine compound to form the final fuel lubricity additive useful in diesel fuels. The inventive fuel lubricity additive also is useful as a dispersant.
    Type: Grant
    Filed: May 26, 1998
    Date of Patent: May 29, 2001
    Assignee: International Lubricants Inc.
    Inventors: Will F. Williamson, Phillip S. Landis, Blaine N. Rhodes
  • Patent number: 6224642
    Abstract: This invention relates to a composition, comprising: (A) a compound represented by the formula RO(C4H8O)nCH2CH2CH2NH2  (I) wherein in formula (I), R is an aliphatic hydrocarbyl group of about 8 to about 30 carbon atoms, an n is a number in the range of about 12 to about 30; and (B) a compound selected from the group consisting of: a fatty acid; a fatty acid amide; a fatty acid ester; an amide, imide or ester derived from a hydrocarbyl substituted succinic acid or anhydride wherein the hydrocarbyl substituent has about 8 to about 30 carbon atoms; an alkoxylated amine, and mixtures of two or more thereof. The invention also relates to concentrates and fuels containing the foregoing composition.
    Type: Grant
    Filed: November 23, 1999
    Date of Patent: May 1, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Daniel T. Daly, Paul E. Adams, Mitchell M. Jackson
  • Patent number: 6203584
    Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline range and a fuel consumption reducing amount of a fuel additive composition comprising: (a) at least one amine compound selected from the group consisting of: (1) a fuel-soluble aliphatic hydrocarbyl-substituted amine having at least one basic nitrogen atom where the hydrocarbyl group has a number average molecular weight of about 700 to 3,000, and (2) a poly(oxyalkylene)amine having at least one basic nitrogen atom and a sufficient number of oxyalkylene units to render the poly(oxyalkylene)amine soluble in hydrocarbons boiling in the gasoline range; and (b) an ester of a carboxylic acid and a polyhydric alcohol, wherein the carboxylic acid has from one to about four carboxylic acid groups and from about 8 to about 50 carbon atoms and the polyhydric alcohol has from about 2 to about 50 carbon atoms and from about 2 to about 6 hydroxy groups.
    Type: Grant
    Filed: March 31, 1998
    Date of Patent: March 20, 2001
    Assignee: Chevron Chemical Company LLC
    Inventors: Peter A. Fuentes-Afflick, Jeffrey A. Gething
  • Patent number: 6200936
    Abstract: This invention relates to a cyclic compound comprising m units of formula (Ia) and n units of the formula (Ib) joined together to form a ring, wherein each Y is a divalent bridging group which may be the same or different in each unit; R0 is H or an alkyl group of 1 to 6 carbon atoms; R5 is H or an alkyl group of 1 to 60 carbon atoms; j is 1 or 2; R3 is hydrogen, a hydrocarbyl or a hetero-substituted hydorcarbyl group; either R1 is hydroxy and R2 and R4 are independently either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl, or R2 and R4 are hydroxyl and R1 is either hydrogen, hydrocarbyl or hetero-substituted hydrocarbyl; m is from 1 to 8; n is at least 3, and m +n is 4 to 20. This invention also relates to metal salts of the foregoing compound, especially overbased metal salts. The invention also relates to additive compositions, finished lubricating oil compositions and fuel compositions containing the foregoing compound or metal salt thereof.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: March 13, 2001
    Assignee: The Lubrizol Corporation
    Inventor: David John Moreton
  • Patent number: 6117197
    Abstract: A fuel composition comprising a major amount of hydrocarbons boiling in the gasoline or diesel range and a fuel additive composition comprising (a) about 15 to 2,000 parts per million by weight of an aromatic ester of a polyalkylphenoxyalkanol, (b) about 30 to 2,000 parts per million by weight of a poly(oxyalkylene) amine, and (c) about 30 to 2,000 parts per million by weight of an aromatic di- or tri-carboxylic acid ester; wherein the total amount of components (a) and (b) is at least about 70 parts per million by weight, and further wherein the weight ratio of component (c) to the total amount of components (a) and (b) is at least about 0.25 to 1. The fuel compositions of this invention are useful for the prevention and control of engine deposits.
    Type: Grant
    Filed: November 25, 1998
    Date of Patent: September 12, 2000
    Assignee: Chevron Chemical Company LLC
    Inventor: Keith Robert Houser
  • Patent number: 6096105
    Abstract: The lubricity of low sulphur fuels is enhanced by incorporation of a cold flow improver.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: August 1, 2000
    Assignee: Exxon Chemical Patents Inc
    Inventor: Rinaldo Caprotti
  • Patent number: 6080211
    Abstract: Liquid energy sources, e.g., liquid fuels comprising lipid vesicles having fuel additives such as water are disclosed herein. The liquid energy sources, methods for preparation, and methods of enhancing engine performance disclosed herein employing the lipid vesicles result in enhanced fuel efficiency and/or lowered engine emissions. The invention further relates to liquid energy sources containing such additives which further comprise a polymeric dispersion assistant, which reduces the interfacial tension and coalescence of vesicles during dispersion process and storage, and thereby provide transparent looks to the liquid energy source.
    Type: Grant
    Filed: February 19, 1999
    Date of Patent: June 27, 2000
    Assignee: Igen, Inc.
    Inventor: Rajiv Mathur
  • Patent number: 6080212
    Abstract: Diesel fuels, particularly low sulfur diesel fuels, contain additives which increase the lubricity in the fuel and reduce the amount of smoke in the exhaust. These additives are esters having a viscosity of 3.0 cSt to 20.0 cSt at 100.degree. C. and a smoke index of at least 75.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: June 27, 2000
    Assignee: Henkel Corporation
    Inventors: Bruce J. Beimesch, Eugene R. Zehler
  • Patent number: 6054420
    Abstract: Synthetic biodegradable lubricants and functional fluids containing 45-94 wt. % of an ester of a C.sub.5 -C.sub.10 acid as the base oil, 5-18% of a polyol ester of a C.sub.12 -C.sub.28 acid as a lubricity additive, and 1-35 wt. % of an additive package for lubricants and functional fluids.
    Type: Grant
    Filed: February 11, 1999
    Date of Patent: April 25, 2000
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Rolfe J. Hartley, Carolyn B. Duncan, George Mortimer Tiffany, III
  • Patent number: 6051039
    Abstract: This invention relates to a diesel fuel composition containing an additive composition made by admixing at least two components: A) at least one dicarboxylic acid having about 8 to about 500 carbon atoms or a reactive equivalent thereof; and B) at least one amine having about 6 to about 80 carbon atoms. In one embodiment, the additive composition also contains: C) at least one monocarboxylic acid of about 8 to about 28 carbon atoms or a reactive equivalent thereof. The additive composition is useful as a lubricity additive for diesel fuel, especially low sulfur diesel fuel and provide excellent storage stability, rust-inhibiting and anti-wear performance to diesel fuel.
    Type: Grant
    Filed: September 14, 1998
    Date of Patent: April 18, 2000
    Assignee: The Lubrizol Corporation
    Inventor: Shigeru Sugimoto
  • Patent number: 6010545
    Abstract: The lubricity of low sulphur fuels is enhanced by incorporation of a lubricity enhancing additive in combination with a polyoxyalkylene compound.
    Type: Grant
    Filed: August 1, 1996
    Date of Patent: January 4, 2000
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Brian William Davies, Rinaldo Caprotti, Brid Dilworth
  • Patent number: 5993498
    Abstract: A polyol ester distillate fuel additive exhibits improved lubricity and friction and wear performance. The ester has between about 1% and about 35% unconverted hydroxyl groups and is characterized as having a hydroxyl number from about 5 to about 180.
    Type: Grant
    Filed: April 3, 1998
    Date of Patent: November 30, 1999
    Assignee: Exxon Research and Engineering Co.
    Inventors: Elisavet P. Vrahopoulou, Richard Henry Schlosberg, David Wayne Turner
  • Patent number: 5986119
    Abstract: The present invention relates to a series of "reconstituted castor oils". The term reconstituted as used hereon refers to a process in which castor oil and one or more oils of natural origin are transesterified under conditions of high temperature and catalyst to make a "reconstituted product" having an altered alkyl distribution and consequently altered chemical and physical properties.
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: November 16, 1999
    Assignee: Hansotech Inc.
    Inventor: Anthony J. O'Lenick, Jr.
  • Patent number: 5976202
    Abstract: Reaction products of polyolefins having predominantly a terminal double bond and a number average molecular weight of from 250 to 10,000, which possess an aliphatic hydrocarbon skeleton which is straight-chain or carries C.sub.1 -C.sub.4 -alkyl side chains, with from 1 to 10 mol, per equivalent of double bond, of one or more vinyl esters I ##STR1## are obtainable by reacting the stated polyolefins with the vinyl esters I in the presence of a free radical initiator at from 80 to 200.degree. C., it being possible for these reaction products subsequently to have been hydrolyzed to the corresponding alcohols or converted into the corresponding amines by reductive amination with amines II ##STR2## .
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: November 2, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Hans Peter Rath, Helmut Mach, Harald Schwahn, Hans-Joachim Muller, Wolfgang Reif, Thomas Ruhl
  • Patent number: 5942474
    Abstract: A two-cycle oil which is 10 to 20% of an ester of technical grade pentaerythriol with a mixture of (a) branched C8 and (b) mixed linear C8 and C10 monocarboxylic acids, having a viscosity of 6 to 8 cSt at 100.degree. C., 18 to 30% of an oxo alcohol ester of a dicarboxylic acid having a viscosity of 3 to 10 cSt at 100.degree. C., 30 to 40% of a polybutene having an Mn of 300-1500, 15 to 35% of a normally liquid solvent having a boiling point up to 300.degree. C., 0 to 5% of other lubricating oil additives.
    Type: Grant
    Filed: May 19, 1998
    Date of Patent: August 24, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventors: George Mortimer Tiffany, Eric Lewis, George C L'Heureux
  • Patent number: 5882364
    Abstract: Fuel oil compositions containing specific mixtures of esters of unsaturated monocarboxylic acids show improved lubricity properties.
    Type: Grant
    Filed: November 24, 1997
    Date of Patent: March 16, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Brid Dilworth
  • Patent number: 5880075
    Abstract: Synthetic biodegradable lubricants and functional fluids containing 45-94 wt. % of an ester of a C.sub.5 -C.sub.10 acid as the base oil, 5-18% of a polyol ester of a C.sub.12 -C.sub.28 acid as a lubricity additive, and 1-35 wt. % of an additive package for lubricants and functional fluids.
    Type: Grant
    Filed: September 22, 1997
    Date of Patent: March 9, 1999
    Assignee: Exxon Chemical Patents Inc
    Inventors: Rolfe J. Hartley, Carolyn B. Duncan, George Mortimer Tiffany, III
  • Patent number: 5855629
    Abstract: This invention provides alkoxy acetic acid derivatives of general formula I: ##STR1## wherein R is the residue of an amine, an aminoalcohol or a polyol linked to the or each --CHR'--CO-- moiety via an amide or ester linkage;R' is hydrogen or a C.sub.1-4 alkyl group;R.sup.1 is an optionally substituted hydrocarbyl group of 1 to 300 carbon atoms;one of R.sup.2 and R.sup.3 is independently selected from hydrogen and optionally substituted hydrocarbyl of 1 to 10 carbon atoms, the other of R.sup.2 and R.sup.3 being independently selected from optionally substituted hydrocarbyl of 1 to 10 carbon atoms;m is from 3 to 200;n is from 0 to 20, provided that m/n is at least 1; andp is from 1 to 5; a process for their preparation; and their incorporation in additive concentrates and fuel compositions for internal combustion engines.
    Type: Grant
    Filed: April 25, 1997
    Date of Patent: January 5, 1999
    Assignee: Shell Oil Company
    Inventors: Michael John Grundy, David Roy Kendall, Thomas Webster Naisby, Andrew Czeslaw Sutkowski
  • Patent number: 5855628
    Abstract: A gas oil composition having improved lubricity which can reduce wear of metallic surfaces which the composition contacts comprises a gas oil having a low sulfur content, and a glycerol/monofatty acid ester and a glycerol/difatty acid ester which have a specific fatty acid residue composition
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: January 5, 1999
    Assignee: Kao Corporation
    Inventors: Jiro Hashimoto, Junzo Ito, Masahiro Fukuda
  • Patent number: 5772705
    Abstract: The lubricity of low sulphur fuels is enhanced by incorporation of a cold flow improver.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: June 30, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Rinaldo Caprotti
  • Patent number: 5755832
    Abstract: An additive concentrate has at least one nitrogen-containing deposit control additive, a solvent, and at least one tagging material. The tagging material has a number average molecular weight of at least 15,000 and a weight average to number average molecular weight ratio of less than 1.5. The tagging material has a molecular weight distribution that is sufficiently different from the molecular weight distribution of the deposit control additive so as to be distinguishable from the deposit control additive. The amount of each tagging material is less than 1 weight % of the additive concentrate.
    Type: Grant
    Filed: November 7, 1996
    Date of Patent: May 26, 1998
    Assignee: Chevron Chemical Company
    Inventors: Jeffrey J. Toman, Wilton R. Biggs
  • Patent number: 5752989
    Abstract: A diesel fuel additive composition comprising a mixture of a dispersant and a carrier, preferably a liquid carrier fluid. The dispersant comprises at least one member of the group consisting of polyalkylene succinimides and polyalkylene amines, the polyalkylene succinimides being the reaction product of polyalkylene succinic anhydride and a polyamine, the polyalkylene amine being the reaction product of a polyalkylene moiety and amine selected from the group consisting of monoamine and polyamine. The carrier comprises at least one oxygenate selected from the group consisting of polyalkoxylated ether, polyalkoxylated phenol, polyalkoxylated ester and polyalkoxylated amine. The additive composition reduces injector deposits in internal combustion-compression ignition engines.
    Type: Grant
    Filed: November 21, 1996
    Date of Patent: May 19, 1998
    Assignee: Ethyl Corporation
    Inventors: Timothy J. Henly, Dennis J. Malfer
  • Patent number: 5730029
    Abstract: A fuel composition is disclosed which comprises(A) at least one low sulfur diesel fuel; and(B) esters from the transesterification of at least one animal fat or vegetable oil triglyceride of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are aliphatic hydrocarbyl groups having at least 60 percent monounsaturated character and containing from about 6 to about 24 carbon atoms with an alcohol or phenol R.sup.4 OH wherein R.sup.4 is an aliphatic group containing from 1 to about 22 carbon atoms or an aromatic or substituted aromatic group containing from 6 to about 50 carbon atoms.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: March 24, 1998
    Assignee: The Lubrizol Corporation
    Inventors: Stephen H. Stoldt, Harshida Dave