Plural -c(=o)o- Groups Attached To Each Other Directly Or Indirectly By Nonionic Bonding (e.g., Polyesters, Half Ester-half Acid Compounds, Etc.) Patents (Class 44/389)
  • Patent number: 5686398
    Abstract: There are herein disclosed an additive for a lubricant or a fuel which comprises at least one selected from the group consisting of substituted hydroxyaromatic ester derivatives represented by the general formulae (I) and (II) ##STR1## wherein R.sup.1 to R.sup.5 are each an organic group having 6 or more carbon atoms, a, b, d, e, k and m are from 1 to 3, c, f, g, i and j are from 0 to 3, and h is from 0 to 4, but (f+g) is from 1 to 3, and (h+i) is from 1 to 6, an additive composition for a lubricant or a fuel, and a lubricating oil composition or a fuel composition containing the above-mentioned additive.The above-mentioned additive for the lubricant or the fuel is desirable as an ashless detergent excellent in high-temperature stability in place of a metal detergent, and the lubricating oil composition or the fuel composition containing this additive can suitably be used as the lubricant or the fuel for an internal combustion engine which can comply with future exhaust gas controls.
    Type: Grant
    Filed: December 6, 1995
    Date of Patent: November 11, 1997
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Tomiyasu Minokami, Hiroaki Koshima, Harutomo Ikeda, Masahisa Gotoh
  • Patent number: 5632785
    Abstract: A method for reducing fuel consumption in an internal combustion engine comprises operating said engine on a fuel composition comprising a major amount of fuel and a minor amount of an additive comprising an ester of a polyhydric polyether having ether oxygens and free and esterified hydroxyl groups in the polyhydric polyether backbone. One such ester additive is decaglycerol tetraoleate, which is an ester of decaglycerol and oleic acid containing an average of four adducted oleic acid units and 10-12 free hydroxyl groups.
    Type: Grant
    Filed: December 1, 1995
    Date of Patent: May 27, 1997
    Assignee: Exxon Research & Engineering Company
    Inventor: Anne M. Culotta
  • Patent number: 5622532
    Abstract: Polylactone aromatic esters having the formula: ##STR1## wherein R.sub.1 is a hydrocarbyl group having a sufficient number of carbon atoms to render the compound soluble in hydrocarbons boiling in the gasoline or diesel fuel range;R.sub.2 is an alkylene group of about 2 to 5 carbon atoms;R.sub.3 and R.sub.4 are each independently hydrogen, hydroxy, nitro, amino, N-alkylamino having 1 to 6 carbon atoms in the alkyl group, or N,N-dialkylamino having 1 to 6 carbon atoms in each alkyl group, provided that R.sub.3 and R.sub.4 may not both be hydrogen;and x is an integer from 1 to 25.The polylactone aromatic esters of formula I are useful as fuel additives for the prevention and control of engine deposits.
    Type: Grant
    Filed: June 20, 1996
    Date of Patent: April 22, 1997
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5562867
    Abstract: A biodegradable two-cycle oil composition which comprises a C.sub.13 oxo alcohol adipate in admixture with a dispersant and a lubricity agent; it is especially useful for outboard marine engines.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: October 8, 1996
    Assignee: Exxon Chemical Patents Inc
    Inventors: George M. Tiffany, III, Beth A. Morgan, George C. L'Heureux, Lewis H. Gaines, William H. Stover
  • Patent number: 5538521
    Abstract: A fuel additive having the formula: ##STR1## wherein A.sub.1 is a thioether, a sulfoxide, a sulfone, a sulfonic acid, a sulfonamide, a nitrile, a carboxylic acid or ester, or a carboxamide; R.sub.1 and R.sub.2 are independently hydrogen, hydroxy, lower alkyl or lower alkoxy; R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl; n is an integer from 0 to 100; and when n is 0 to 10, R.sub.5 is polyalkyl having an average molecular weight of 450 to 5,000; and when n is 5 to 100, R.sub.5 is hydrogen, alkyl, phenyl, aralkyl, alkaryl or an acyl group having the formula: ##STR2## wherein R.sub.6 is alkyl, phenyl, aralkyl or alkaryl; R.sub.7 and R.sub.8 are independently hydrogen, hydroxy, lower alkyl or lower alkoxy; A.sub.2 is a thioether, a sulfoxide, a sulfone, a sulfonic acid, a sulfonamide, a nitrile, a carboxylic acid or ester, or a carboxamide; and x and y are independently integers from 0 to 10; with the proviso that when n and x are both 0, then A.sub.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: July 23, 1996
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5476521
    Abstract: The present invention is directed to a fuel additive comprising at least one adduct of (A) a polyolefin of 300 to 10,000 number average molecular weight substituted with at least 0.3 (e.g., from about 1 to 4) mono- or dicarboxylic acid producing moieties (preferably acid or anhydride moieties) per polyolefin molecule, (B) an amido-amine or thioamido-amine characterized by being a reaction product of at least a polyamine and an alpha, beta-unsaturated compound of the formula: ##STR1## wherein X is sulfur or oxygen, Y is --OR.sup.4, --SR.sup.4, or --NR.sup.4 (R.sup.5), and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are the same or different and are hydrogen or substituted or unsubstituted hydrocarbyl.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: December 19, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Antonio Gutierrez, Robert D. Lundberg
  • Patent number: 5462567
    Abstract: A fuel additive composition comprising:(a) a poly(oxyalkylene) hydroxyaromatic ester having the formula: ##STR1## or a fuel-soluble salt thereof; where R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is hydrogen, alkyl having 1 to 30 carbon atoms, phenyl, aralkyl or alkaryl having 7 to 36 carbon atoms, or an acyl group having the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, or aralkyl or alkaryl having 7 to 36 carbon atoms; R.sub.7 and R.sub.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: October 31, 1995
    Assignee: Chevron Chemical Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5441653
    Abstract: Two-stroke cycle engine lubricant and lubricant fuel composition comprise a composition prepared by reacting an aromatic compound of the formula ##STR1## with a carboxylic reactantR.sup.1 CO(CR.sup.2 R.sup.3).sub.x COOR.sup.10and optionally, ammonia or amines.In another embodiment the 2-stroke cycle lubricants contain a carboxylic composition of the formula ##STR2## wherein the various groups are defined herein.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: August 15, 1995
    Assignee: The Lubrizol Corporation
    Inventors: William K. S. Cleveland, Paul E. Adams, Marvin B. De Tar
  • Patent number: 5405418
    Abstract: A fuel additive composition comprising:(a) a fuel-soluble aliphatic hydrocarbyl-substituted amine having at least one basic nitrogen atom wherein the hydrocarbyl group has a number average molecular weight of about 700 to 3,000;(b) a polyolefin polymer of a C.sub.2 to C.sub.6 monoolefin, wherein the polymer has a number average molecular weight of about 350 to 3,000; and(c) an aromatic di- or tri-carboxylic acid ester of the formula: ##STR1## wherein R is an alkyl group of 4 to 20 carbon atoms, and x is 2 or 3.
    Type: Grant
    Filed: May 2, 1994
    Date of Patent: April 11, 1995
    Assignee: Chevron Chemical Company
    Inventors: Matthew H. Ansarie, Richard E. Cherpeck, Randy G. Chevalier, Jeffrey J. Toman
  • Patent number: 5378249
    Abstract: A biodegradable two-cycle engine oil composition comprises about (a) 20 to 85 wt. % of a heavy ester or a mixture of heavy ester oils characterized by a kinematic viscosity of at least about 7.0 cSt at 100.degree. C., (b) 10 to 85 wt. % of a light ester oil or a mixture of light ester oils characterized by a kinematic viscosity of less than about 6.0 cSt at 100.degree. C., and optionally an additive, wherein the composition has a biodegradability of at least about 66% as measured by the CEC L-33-T-82 method.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: January 3, 1995
    Assignee: Pennzoil Products Company
    Inventor: David S. Morrison
  • Patent number: 5366519
    Abstract: A fuel additive composition comprising:(a) a poly(oxyalkylene) hydroxyaromatic ester having the formula: ##STR1## or a fuel-soluble salt thereof; where R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is hydrogen, alkyl having 1 to 30 carbon atoms, phenyl, aralkyl or alkaryl having 7 to 36 carbon atoms, or an acyl group having the formula: ##STR2## where R.sub.6 is alkyl having 1 to 30 carbon atoms, phenyl, or aralkyl or alkaryl having 7 to 36 carbon atoms; R.sub.7 and R.sub.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: November 22, 1994
    Assignee: Chevron Research and Technology Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5330545
    Abstract: The cold flow properties of distillate petroleum fuel are improved by adding a polymer or copolymer containing at least 25 wt. % of an n-alkyl ester of the general formula ##STR1## wherein R.sub.1 and R.sub.2 are hydrogen or a C.sub.1 alkyl group, e.g., methyl, R.sub.4 is COOR.sub.3, hydrogen or a C.sub.1 to C.sub.4 alkyl group preferably COOR.sub.3 and R.sub.3 has an average number of carbon atoms from 12 to 20 and contains a methyl branch at the 1 and/or 2 position.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: July 19, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Kenneth Lewtas, Kenneth W. Bartz
  • Patent number: 5300126
    Abstract: A method is disclosed for the pretreatment of olefinic hydrocarbon feedstock to remove conjugated dienes and/or basic nitrogen compounds that deactivate acidic catalyst particles used in olefin conversion processes by reacting the dienes with one or more dienophiles to form the corresponding Diels-Alder adduct, followed by catalytic conversion of the olefinic hydrocarbon feedstock containing the adduct. The formation of the Diels-Alder adduct essentially eliminates the role of dienes in the feedstock as catalyst deactivating agents. When maleic anhydride (MA) is employed as the dienophile, basic nitrogen reacts with maleic anhydride, or with the tetrahydrophthalic anhydride adduct, to lower the amount of catalyst deactivating basic nitrogen compounds in the feedstock. Where the olefin conversion process comprises etherification of isoolefins with alkanol in a C.sub.4 + or C.sub.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: April 5, 1994
    Assignee: Mobil Oil Corporation
    Inventors: Stephen H. Brown, Quang N. Le, Lawrence B. Alemany
  • Patent number: 5296003
    Abstract: Poly(oxyalkylene) hydroxyaromatic ethers having the formula: ##STR1## or a fuel-soluble salt thereof; where n is an integer from 5 to 100; x is an integer from 0 to 10; R.sub.1 and R.sub.2 are each independently hydrogen, hydroxy, lower alkyl having 1 to 6 carbon atoms, or lower alkoxy having 1 to 6 carbon atoms; R.sub.3 and R.sub.4 are each independently hydrogen or lower alkyl having 1 to 6 carbon atoms; R.sub.5 is an acyl group of the formula: ##STR2## wherein y is 1, 2 or 3; R.sub.6 is a divalent hydrocarbyl radical, when y is 1, a trivalent hydrocarbyl radical, when y is 2, or tetravalent hydrocarbyl radical, when y is 3, said hydrocarbyl radicals having 1 to about 20 carbon atoms; and each Z is independently selected from the group consisting of: ##STR3## where each R.sub.7 is independently alkyl having 1 to 30 carbon atoms, phenyl, aralkyl having 7 to 36 carbon atoms or alkaryl having 7 to 36 carbon atoms.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: March 22, 1994
    Assignee: Chevron Research and Technology Company
    Inventor: Richard E. Cherpeck
  • Patent number: 5284494
    Abstract: Additives which improve the low-temperature properties of distillate fuels are oligomeric/polymeric reaction products consisting of cross-linked anhydride and cross-linked epoxide (or their corresponding acid/diol equivalents), with optional termonomers.
    Type: Grant
    Filed: September 17, 1992
    Date of Patent: February 8, 1994
    Assignee: Mobil Oil Corporation
    Inventors: David J. Baillargeon, Angeline B. Cardis, Dale B. Heck, Susan W. Johnson
  • Patent number: 5281346
    Abstract: This invention relates to lubricants for two-cycle engines comprising a major amount of at least one oil of lubricating viscosity and a minor amount of at least one compound of the general formulaA.sup.y- M.sup.y+ (I)wherein M represents one or more metal ions, y is the total valence of all M and A represents one or more anion containing groups having a total of about y individual anionic moieties and each anion containing group is a group of the formula ##STR1## wherein T is selected from the group consisting of ##STR2## Additive concentrates and lubricant-fuel mixtures for two cycle engines are also disclosed as well as methods for operating two-cycle engines.
    Type: Grant
    Filed: April 16, 1992
    Date of Patent: January 25, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Paul E. Adams, William K. S. Cleveland
  • Patent number: 5246469
    Abstract: Distillate fuel is stabilized against degradation during storage by inserting into storage tanks solid materials containing polar sites to enable polar condensation of the fuel constituents active in degradation. Polyether or polyester polyurethane open cell foams are the prime solid stabilizers proposed.
    Type: Grant
    Filed: February 29, 1988
    Date of Patent: September 21, 1993
    Assignee: The Commonwealth of Australia
    Inventors: William Arfelli, Alan Power, Richard Solly
  • Patent number: 5242469
    Abstract: A gasoline additive composition comprising an ester; and at least one dispersant component chosen from the group consisting of a specified monosuccinimide, a specified bissuccinimide, an alkylamine of average molecular weight 500-5000 having a polyolefine polymer as an alkyl group and a specified benzylamine derivative of average molecular weight 500-5000. It can contain a polyoxyalkylene glycol or its derivative. It can further contain a lubricant oil fraction of viscosity in the range 3-35 mm.sup.2 /s (100.degree. C.) It prevents undesired deposits on the surfaces of intake valves of an automobile engine.
    Type: Grant
    Filed: May 30, 1991
    Date of Patent: September 7, 1993
    Assignee: Tonen Corporation
    Inventors: Tadamori Sakakibara, Yutaka Hasegawa, Fumio Oohashi, Kiyomi Adachi
  • Patent number: 5215548
    Abstract: Distillate fuel compositions containing an amine salt of a sulfonic acid and a low volatility carrier fluid are effective in reducing the formation of intake valve deposits in internal combustion engines. Gasoline containing diamine salts in combination with a polyol ester carrier fluid is a particularly preferred distillate fuel composition.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: June 1, 1993
    Assignee: Exxon Research and Engineering Company
    Inventors: Thomas L. Ashcraft, Alan M. Schilowitz, Larry D. Talley, Paul J. Berlowitz
  • Patent number: 5211721
    Abstract: Motor fuel compositions comprising gasoline are improved to control octane requirement increase (ORI) by including an ester of a carboxylic acid and a polyether polyol, preferably a polyether polyol including oxyethylene, oxypropylene and oxybutylene segments.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: May 18, 1993
    Assignee: Texaco Inc.
    Inventors: Rodney L. Sung, Daniel T. Daly
  • Patent number: 5160506
    Abstract: The invention relates to a liquid fuel mixture, comprising a C.sub.3 and/or at least a C.sub.4 -alkane, at least one oil component and optionally at least one additive, a process for its preparation and its use for two-stroke engines.
    Type: Grant
    Filed: July 13, 1990
    Date of Patent: November 3, 1992
    Inventors: Hans Schur, Werner Angerer, Friedrich Sprugel
  • Patent number: 5147413
    Abstract: The flame luminosity of a methanol fuel is appreciably enhanced by the addition thereto of at least one azo dye flame luminosity enhancing agent.
    Type: Grant
    Filed: July 20, 1989
    Date of Patent: September 15, 1992
    Assignee: The Standard Oil Company
    Inventors: Thomas E. Kiovsky, Wendy L. Clark
  • Patent number: 5131921
    Abstract: Motor fuel compositions comprising gasoline are improved to control octane requirement increase (ORI) by including an ester of an N-acyl sarcosinate acid or salt and a polyether polyol including oxyalkylene units selected from oxypropylene and/or oxybutylene.
    Type: Grant
    Filed: October 9, 1990
    Date of Patent: July 21, 1992
    Assignee: Texaco Inc.
    Inventors: Rodney L. Sung, Daniel T. Daly
  • Patent number: 5112507
    Abstract: Novel copolymers of unsaturated acidic reactants and high molecular weight olefins wherein at least 20 percent of the total high molecular weight olefin comprises the alkylvinylidene isomer are useful as dispersants in lubricating oils and fuels and also may be used to prepare polysuccinimides and other post-treated additives useful in lubricating oils and fuels.
    Type: Grant
    Filed: September 29, 1989
    Date of Patent: May 12, 1992
    Assignee: Chevron Research and Technology Company
    Inventor: James J. Harrison
  • Patent number: 4992605
    Abstract: There is described a process for producing hydrocarbon products in the diesel boiling range, comprising mainly C.sub.15 -C.sub.18 paraffins and being highly effective as diesel fuel ignition improvers. The process comprises hydroprocessing vegetable oils such as canola, sunflower, soybean and rapeseed oils or some fatty acids in hydroprocessing temperatures (350.degree.-450.degree. C.), pressures (4.8-15.2 MPa) and liquid hourly space velocity (LHSV) of 0.5-5.0 hr.sup.-1 depending on the type and purity of the feedstock. Commercially available hydroprocessing catalysts may be used.
    Type: Grant
    Filed: January 27, 1989
    Date of Patent: February 12, 1991
    Inventors: Wayne K. Craig, Douglas W. Soveran