Of Group Viii (i.e., Iron Or Platinum Group) Patents (Class 502/185)
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Patent number: 7799246Abstract: The present invention relates to a process for preparing CNTs by bringing a carbon source into contact with a multivalent metal and/or metal-oxide-based catalyst deposited on an inorganic substrate having a BET specific surface area of greater than 50 m2/g. The CNTs obtained may be used as agents for improving the mechanical and electrical conductivity properties in polymeric compositions.Type: GrantFiled: February 3, 2006Date of Patent: September 21, 2010Assignee: Arkema FranceInventors: Serge Bordere, Daniel Cochard, Eric Dutilh, Patrice Gaillard, Dominique Plee
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Publication number: 20100234210Abstract: An object of the present invention is to provide a fuel cell electrode catalyst which offers an improved durability while inhibiting the degradation of an initial catalytic activity to exhibit a stably high catalytic activity over a long period. The present invention provides a fuel cell electrode catalyst having an alloy carried by carbon, the alloy consisting of platinum and a platinum-family metal other tha platinum, characterized in that a composition ratio of platinum to platinum-family metal other than platinum to carbon is 1:(0.03 to 1.5):(0.46 to 2.2) (wt ratio).Type: ApplicationFiled: March 27, 2007Publication date: September 16, 2010Inventors: Tetsuo Kawamura, Hiroaki Takahashi, Susumu Enomoto, Tomoaki Terada, Takahiro Nagata
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Publication number: 20100233070Abstract: The present teachings are directed to preparation of carbon-supported CoSe2 nanoparticles via an in situ surfactant free method, and use of the same for oxygen reduction and hydrogen evolution reactions. The CoSe2 nanoparticles have two kinds of structure after heat treatment at different temperatures: orthorhombic at 300° C. and cubic at 400° C. The latter structure has higher oxygen reduction activity and hydrogen evolution activity than the former in 0.5 M H2SO4. Electron transfers of about 3.5- and about 3.7-electrons were observed for 20 wt. % CoSe2/C nanoparticles, after heat treatment at 300° C. and 400° C., per oxygen molecule during the oxygen reduction process, respectively.Type: ApplicationFiled: February 18, 2010Publication date: September 16, 2010Inventors: Nicolas Alonso-Vante, Yongjun Feng, Ting He
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Publication number: 20100234477Abstract: A catalyst and process is described for the conversion of hydrogen and one or more oxides of carbon in which the catalyst comprises an elemental carbon-containing support. Also described is a process for reducing agglomeration in carbon nanotubes, in which carbon nanotubes are suspended in a liquid and simultaneously treated by ultrasound and agitation. The method can be used to prepare carbon nanotube-supported catalysts that show high activity towards the conversion of feedstocks comprising hydrogen and one or more oxides of carbon.Type: ApplicationFiled: February 16, 2006Publication date: September 16, 2010Applicant: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian China BP P.L.C.Inventors: Xinhe Bao, Wei Chen, Xiulian Pan, Zhongli Fan, Yunjie Ding, Hongyuan Luo
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Publication number: 20100224535Abstract: A supported carbon having high surface area, high pore volume containing (i) molybdenum (ii) a metal of non noble Group VIII, (iii) phosphorous, is used for hydrometallization of heavy crude oil and residue. The catalyst contains about 6 to 15 wt % molybdenum as MoO3, about 1 to 6 wt % cobalt or nickel as CoO or NiO and phosphorus as phosphorous oxide. One characteristic of the catalyst is the portion of pores having pore diameter in the range of 200 to 2000 Angstrom of 20 percent or more. The catalyst prepared by chelating agent has higher hydrodesulfurization activity assuming that more dispersed active metals are present on this catalyst. Long run activity studies show that catalyst having only molybdenum supported on activated carbon has good stability with time-on-stream and very high metal retention capacity.Type: ApplicationFiled: March 3, 2010Publication date: September 9, 2010Applicants: INSTITUTO MEXICANO DEL PETROLEO, TOYO ENGINEERING CORPORATIONInventors: Samir Kumar Maity, Jorge Ancheyta Juárez, Fernando Alonso Martínez, Hidetsugu Fukuyama, Satoshi Terai, Masayuki Uchida
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Publication number: 20100222211Abstract: A method for producing nanoparticles on a substrate using a metal precursor in an ionic liquid and microwave heating is described. The composite compositions are useful as catalysts for chemical reactions, fuel cell, supercapacitor and battery components, and the like.Type: ApplicationFiled: April 30, 2010Publication date: September 2, 2010Applicant: Board of Trustees of Michigan State UniversityInventors: Lawrence T. Drzal, In-Hwan Do, Hiroyuki Fukushima
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Publication number: 20100216056Abstract: A non-noble metal based catalyst includes a compound represented by Formula 1: ZraMbOxNy??[Formula 1] where M is at least one element selected from Group 4 elements through Group 12 elements, a is a number in the range of about 1 to about 8, b is a number in the range of 1 to 8, x is a number in the range of about 0.2 to about 32, and y is a number in the range of about 0.2 to about 16. A fuel cell electrode and fuel cell may be formed using the non-noble metal based catalyst.Type: ApplicationFiled: February 19, 2010Publication date: August 26, 2010Applicant: Samsung Electronics Co., Ltd.Inventors: Duckyoung YOO, Gang Liu, Huamin Zhang, Hong Jin, Ting Xu, Yuanwei Ma, Hexiang Zhong
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Publication number: 20100215960Abstract: A hollow carbon sphere having a carbon shell and an inner core is disclosed. The hollow carbon sphere has a total volume that is equal to a volume of the carbon shell plus an inner free volume within the carbon shell. The inner free volume is at least 25% of the total volume. In some instances, a nominal diameter of the hollow carbon sphere is between 10 and 180 nanometers.Type: ApplicationFiled: February 24, 2009Publication date: August 26, 2010Applicants: Toyota Motor Engineering & Manufacturing North America, Inc., Los Alamos National LabInventors: Claudia Luhrs, Jonathan Phillips, Monique N. Richard, Angela Michelle Knapp
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Publication number: 20100216632Abstract: High-stability, self-protecting particles encapsulated by a thin film of a catalytically active noble metal are described. The particles are preferably nanoparticles comprising a passivating element having at least one metal selected from the group consisting of columns IVB, VB, VIB, and VIIB of the periodic table. The nanoparticle is preferably encapsulated by a Pt shell and may be either a nanoparticle alloy or a core-shell nanoparticle. The nanoparticle alloys preferably have a core comprised of a passivating component alloyed with at least one other transition metal. The core-shell nanoparticles comprise a core of a non-noble metal surrounded by a shell of a noble metal. The material constituting the core, shell, or both the core and shell may be alloyed with one or more passivating elements. The self-protecting particles are ideal for use in corrosive environments where they exhibit improved stability compared to conventional electrocatalyst particles.Type: ApplicationFiled: February 22, 2010Publication date: August 26, 2010Applicant: Brookhaven Science Associates, LLCInventors: Radoslav Adzic, Miomir Vukmirovic, Weiping Zhou
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Publication number: 20100210454Abstract: The present invention is generally directed to a nanocomposite catalyst material for electrochemical devices such as fuel cells, comprising metal nanoparticles impregnated on a conductive support that is coated with a transition metal compound. The metal nanoparticles may comprise platinum; the metal phosphate may comprise tantalum oxyphosphate, niobium oxyphosphate, tantalum oxide, niobium oxide, or any combination thereof; and the conductive support may comprise carbon. In addition, the present invention provides for a method of making the catalyst material.Type: ApplicationFiled: February 12, 2010Publication date: August 19, 2010Inventors: Albert Epshteyn, Andrew P. Purdy, Yannick Garsany, Karen Swider-Lyons
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Publication number: 20100210453Abstract: A method for the preparation of materials comprises the steps of: a) taking a first material comprising a compound of a first metal or of a first metal alloy, b) inserting said first material into an electrochemical cell as a first electrode, the electrochemical cell including a second electrode including a second metal different from a metal incorporated in the first material and an electrolyte adapted to transport the second metal to the first electrode and insert it into the first material by a current flowing in an external circuit resulting in the formation of a compound of the second metal in the first electrode material, the method being characterized by the step of treating the first electrode material after formation of the compound of the second metal to chemically remove at least some of the compound of the second metal to leave a material with a nanoporous structure.Type: ApplicationFiled: March 29, 2007Publication date: August 19, 2010Applicant: Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.Inventors: Yong-Sheng Hu, Yu-Guo Guo, Palani Balaya, Joachim Maier, Sarmimala Hore
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Publication number: 20100210881Abstract: A supported noble metal catalyst comprising palladium salts enveloped by colloids applied to the support is produced by hydrolysing a palladium salt solution by means of a base and applying the colloidal suspension to a support. The catalyst can be used in hydrogenations.Type: ApplicationFiled: March 10, 2008Publication date: August 19, 2010Applicant: EVONIK DEGUSSA GMBHInventors: Konrad Mobus, Tracy Dunn, Baoshu Chen
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Patent number: 7776781Abstract: The invention relates to a carbon-supported PtRu anode catalyst for direct methanol fuel cells (DMFC) which has a platinum/ruthenium content in the range from 80 to 98 wt. %, preferably in the range from 85 to 98 wt. %, particularly preferably in the range from 85 to 95 wt. % (based on the total weight of the catalyst), on a carbon-based electrically conductive support material and has a mean particle size of less than 3 nm. The catalyst is prepared using a carbon black support material having a specific surface area (measured by the BET method) in the range from 1000 to 2000 m2/g by means of a reduction process using chemical reducing agents with addition of organic acids. Electrodes and membrane-electrode units containing the catalyst according to the invention having a high precious metal loading have an electrode layer thickness of less than 80 ?m at a PtRu loading per unit area of the electrode of from 6 to 12 mg of PtRu/cm2 and lead to improved electric power in direct methanol fuel cells.Type: GrantFiled: August 13, 2005Date of Patent: August 17, 2010Assignee: Umicore AG & Co. KGInventors: Marco Lopez, Peter Biberbach
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Patent number: 7776782Abstract: A textured catalyst having a hydrothermally-stable support, a metal oxide and a catalyst component is described. Methods of conducting aqueous phase reactions that are catalyzed by a textured catalyst are also described. The invention also provides methods of making textured catalysts and methods of making chemical products using a textured catalyst.Type: GrantFiled: January 8, 2007Date of Patent: August 17, 2010Assignee: Battelle Memorial InstituteInventors: Todd Werpy, John G. Frye, Jr., Yong Wang, Alan H. Zacher
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Patent number: 7776779Abstract: A method of preparing a mesoporous carbon includes mixing a mesophase pitch, a carbon precursor, an acid, and a solvent to obtain a carbon precursor mixture; impregnating an ordered mesoporous silica (OMS) with the carbon precursor mixture; heat-treating and carbonizing the impregnated OMS to form an OMS-carbon composite; and removing the OMS from the OMS-carbon composite. The mesoporous carbon uses the mesophase pitch and the carbon precursor to reduce sheet resistance, and thus can efficiently transfer electric energy. Such mesoporous carbon can be used as a conductive material of electrodes for fuel cells. When the mesoporous carbon is used as a support for catalysts of electrodes, a supported catalyst containing the support can be used to manufacture a fuel cell having high efficiency.Type: GrantFiled: June 2, 2006Date of Patent: August 17, 2010Assignee: Samsung SDI Co., Ltd.Inventors: Sang Hoon Joo, Chan-ho Pak
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Publication number: 20100203428Abstract: A supported catalyst for fuel cell includes a conductive carrier and platinum supported on the conductive carrier. A 90% particle diameter D90 on a cumulative particle size curve obtained by determining a particle size distribution of the supported catalyst by a light scattering method is 28 ?m or less.Type: ApplicationFiled: April 15, 2010Publication date: August 12, 2010Applicants: CATALER CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Toshiharu TABATA, Tomoaki Terada, Takahiro Nagata, Mikihiro Kataoka, Hiroaki Takahashi, Nobuaki Mizutani, Yousuke Horiuchi
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Patent number: 7771860Abstract: A fuel cell catalyst includes a carbon-containing core, and an active metal shell attached to the carbon core by an ionomer. The catalyst has a high catalyst utility, and facilitates a highly efficient and high power fuel cell. The ionomer is disposed between the active metal and the carbon core. The carbon core and the active metal are present in a mixing ratio ranging from 0.0001:99.9999 wt % to 0.05:99.95 wt %.Type: GrantFiled: June 12, 2007Date of Patent: August 10, 2010Assignee: Samsung SDI Co., Ltd.Inventor: In-Hyuk Son
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Publication number: 20100196789Abstract: A platinum alloy catalyst PtX, wherein the atomic percent of platinum in the bulk alloy is from 5 to 50 at %, the remaining being X, characterised in that the atomic percent of platinum at the surface of the alloy is from 10 to 80 at %, the remainder being X, provided that the at % of platinum at the surface of the alloy is at least 25% greater than the at % of platinum in the bulk alloy is disclosed.Type: ApplicationFiled: July 22, 2008Publication date: August 5, 2010Inventors: Janet Mary Fisher, David Thompsett
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Patent number: 7767615Abstract: A method for producing aligned carbon nanotubes and/or nanofibres comprises providing finely divided substrate particle having substantially smooth faces with radii of curvature of more than 1 ?m and of length and breadth between 1 ?m and 5 mm and having catalyst material on their surface and a carbon-containing gas at a temperature and pressure at which the carbon-containing gas will react to form carbon when in the presence of the supported catalyst, and forming aligned nanotubes and/or nanofibres by the carbon-forming reaction.Type: GrantFiled: November 13, 2003Date of Patent: August 3, 2010Assignee: Cambridge University Technical Services LimitedInventors: Ian Kinloch, Charanjeet Singh, Milo Sebastian Peter Shaffer, Krzysztof K. K. Koziol, Alan Windle
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Patent number: 7767616Abstract: A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein.Type: GrantFiled: March 3, 2006Date of Patent: August 3, 2010Assignee: UChicago Argonne, LLCInventors: Di-Jia Liu, Junbing Yang, Xiaoping Wang
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Publication number: 20100190639Abstract: A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust.Type: ApplicationFiled: January 27, 2010Publication date: July 29, 2010Inventors: Marcus A. Worsley, Thomas Yong-Jin Han, Joshua D. Kuntz, Octavio Cervantes, Alexander E. Gash, Theodore F. Baumann, Joe H. Satcher, JR.
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Publication number: 20100184590Abstract: A honeycomb body, in particular a catalyst carrier body, includes metallic foil of high-temperature corrosion-resistant steel with connecting points and an oxide layer with a thickness of 60 to 80 or 70 to 75 nm on each surface. The foil is composed of steel with chromium and aluminum components, particularly 1 to 5% aluminum. The oxide layer is substantially aluminum oxide or ?-aluminum oxide with a uniform thickness having a tolerance of less than 10% or less than 5% on all surfaces. The oxide layer may be on a rolled foil having a mean surface roughness of greater than 0.3 or 0.5 ?m or approximately 0.6 ?m in rolling direction and/or transversely thereto. The honeycomb body is durable under high loads and has defined connecting points. A foil having an oxide coat and a method for producing an oxide coat on a metallic foil are also provided.Type: ApplicationFiled: March 8, 2010Publication date: July 22, 2010Applicant: EMITEC GESELLSCHAFT FUR EMISSIONSTECHNOLOGIE MBHInventors: Kait Althöfer, Jan Hodgson, Sven Schepers
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Patent number: 7759276Abstract: The invention relates to a formed body comprising an at least partially amorphous inorganic supporting structure and an adsorption agent, which adsorption agent is disposed on and/or in the amorphous inorganic supporting structure. The invention further relates to a process for the production of same and to the use of said formed body in a filtering system, preferably in a motor vehicle.Type: GrantFiled: July 21, 2005Date of Patent: July 20, 2010Assignee: helsa-Automotive GmbH & Co. KGInventor: Thomas Wolff
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Patent number: 7759277Abstract: The present invention provides a catalyst having high activity and excellent stability, a process for preparation of the catalyst, a membrane electrode assembly, and a fuel cell. The catalyst of the present invention comprises an electronically conductive support and catalyst fine particles. The catalyst fine particles are supported on the support and are represented by the formula (1): PtuRuxGeyTz (1). In the formula, u, x, y and z mean 30 to 60 atm %, 20 to 50 atm %, 0.5 to 20 atm % and 0.5 to 40 atm %, respectively. When the element represented by T is Al, Si, Ni, W, Mo, V or C, the content of the T-element's atoms connected with oxygen bonds is not more than four times as large as that of the T-element's atoms connected with metal bonds on the basis of X-ray photoelectron spectrum (XPS) analysis.Type: GrantFiled: March 19, 2009Date of Patent: July 20, 2010Assignee: Kabushiki Kaisha ToshibaInventors: Taishi Fukazawa, Wu Mei, Yoshihiko Nakano, Tsuyoshi Kobayashi, Itsuko Mizutani, Hiroyasu Sumino
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Publication number: 20100177462Abstract: High-surface-area carbon nanostructures coated with a smooth and conformal submonolayer-to-multilayer thin metal films and their method of manufacture are described. The preferred manufacturing process involves the initial oxidation of the carbon nanostructures followed by immersion in a solution with the desired pH to create negative surface dipoles. The nanostructures are subsequently immersed in an alkaline solution containing non-noble metal ions which adsorb at surface reaction sites. The metal ions are then reduced via chemical or electrical means and the nanostructures are exposed to a solution containing a salt of one or more noble metals which replace adsorbed non-noble surface metal atoms by galvanic displacement. Subsequent film growth may be performed via the initial quasi-underpotential deposition of a non-noble metal followed by immersion in a solution comprising a more noble metal.Type: ApplicationFiled: February 22, 2010Publication date: July 15, 2010Applicant: Brookhaven Science Associates, LLCInventors: Radoslav Adzic, Alexander Harris
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Patent number: 7754644Abstract: The present invention provides a noble metal particle with an improved methanol-oxidation property. This noble metal particle has a platinum particle and ruthenium particles deposited on only part of the surface of the platinum particle. This noble metal particle suitably can be produced by precipitating the ruthenium particles out of the solution so that the ruthenium particles are deposited on only part of the surface of the platinum particle by further adding a ruthenium salt into the solution and reducing the ruthenium salt after the reduction of the platinum salt in the solution essentially is completed. This noble metal particle is suitable as a catalyst to be supported on an electrode of a polymer electrolyte fuel cell typified by a direct methanol fuel cell.Type: GrantFiled: September 1, 2006Date of Patent: July 13, 2010Assignee: Nippon Sheet Glass Company, LimitedInventor: Ryohei Ogawa
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Patent number: 7749935Abstract: A catalyst carrier, being characterized in that a catalyst metal for promoting an oxidation-reduction reaction is carried on a vapor-grown carbon fiber having an average outer diameter of from 2 nm to 500 nm, which has been subjected to a crushing treatment so as to have a BET specific surface area of from 4 m2/g to 100 m2/g and an aspect ratio of from 1 to 200, and exhibiting high activity per unit amount of a catalyst metal, a low reaction resistance and an improved output density, and is useful for a fuel cell; a production method thereof and a fuel cell using the catalyst carrier.Type: GrantFiled: January 26, 2005Date of Patent: July 6, 2010Assignee: Showa Denko K.K.Inventors: Ken-ichiro Ota, Akimitsu Ishihara, Satoshi Iinou, Akinori Sudoh
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Publication number: 20100167918Abstract: A catalyst for an electro-chemical oxygen reduction reaction (ORR) of a bundle of longitudinally aligned carbon nanotubes having a catalytically active transition metal incorporated longitudinally in said nanotubes. A method of making an electro-chemical catalyst for an oxygen reduction reaction (ORR) having a bundle of longitudinally aligned carbon nanotubes with a catalytically active transition metal incorporated throughout the nanotubes, where a substrate is in a first reaction zone, and a combination selected from one or more of a hydrocarbon and an organometallic compound containing an catalytically active transition metal and a nitrogen containing compound and an inert gas and a reducing gas is introduced into the first reaction zone which is maintained at a first reaction temperature for a time sufficient to vaporize material therein.Type: ApplicationFiled: March 3, 2006Publication date: July 1, 2010Applicant: The University of ChicagoInventors: Di-Jia Liu, Junbing Yang, Xiaoping Wang
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Publication number: 20100167915Abstract: A nano-supported hydrodesulphurization (HDS) catalyst is prepared for hydrodesulphurization of hydrocarbonaceous feed stock. The catalyst can be prepared through different methods and also used under milder conditions than those required for conventionally used HDS catalysts, but can also function under other hydrodesulphurization operating conditions.Type: ApplicationFiled: December 2, 2009Publication date: July 1, 2010Applicant: RESEARCH INSTITUTE OF PETROLEUM INDUSTRY (RIPI)Inventors: Ali Mohajeri, Alimorad Rashidi, Kheirollah Jafari Jozani, Payman Khorami, Bahman Amini, Dorsa Parviz, Mansour Kalbasi
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Publication number: 20100167106Abstract: An ordered mesoporous carbon (OMC) composite catalyst includes an OMC; and metal particles and at least one component selected from a group consisting of nitrogen and sulfur included in the OMC. The ordered mesoporous carbon composite catalyst may be formed by impregnating an ordered mesoporous silica with a mixture of at least one selected from the group consisting of a nitrogen-containing carbon precursor, and a sulfur-containing carbon precursor, a metal precursor, and a solvent; drying and heat-treating the impregnated OMS; carbonizing the dried and heat-treated OMS to obtain a carbon-OMS composite; and removing the OMS from the carbon-OMS composite. A fuel cell may contain the OMC composite catalyst.Type: ApplicationFiled: December 31, 2009Publication date: July 1, 2010Applicant: Samsung Electronics Co., Ltd.Inventors: Chan-ho Pak, Hyuk Chang, Ji-Man Kim, Jeong-kuk Shon
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Publication number: 20100158775Abstract: Air treatment catalyst systems and methods for treating the air in the aircraft cabin environment are provided. The catalyst system and method remove ozone, volatile organic compounds, NOx and other pollutants. The catalyst system used to treat the cabin air comprises a plurality of discrete substrates having an ozone abatement catalyst loaded thereon and arranged in a stacked configuration between a source of the air stream and the passenger cabin, the at least the first two substrates adjacent the source of the air stream comprise an iron-based alloy.Type: ApplicationFiled: December 18, 2008Publication date: June 24, 2010Applicant: BASF Catalysts LLCInventors: Michael P. Galligan, Mark Buelow, Martin Volland, Pascaline Harrison Tran, Bruce J. Frishberg
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Publication number: 20100152031Abstract: An electrocatalyst for an electrode comprises (i) an electrically conductive particulate support comprising one or more electrocatalytically active metals and (ii) an electrically conductive material which is substantially free of electrocatalytically active metals and has an electroconductivity which is higher than the electroconductivity of (i). This Abstract is not intended to define the invention disclosed in the specification, nor intended to limit the scope of the invention in any way.Type: ApplicationFiled: December 12, 2008Publication date: June 17, 2010Applicant: MORE ENERGY LTD.Inventors: Nino Borchtchoukova, Gilles Chriqui, Shimshon Kogan, Gennadi Finkelshtain, Igor Barsukov
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Publication number: 20100143821Abstract: A composition comprising an admixture of at least platinum particles and metal nanoparticles of metal that, when in admixture with the platinum particles, beneficially alters the characteristics of the platinum, including metals selected from one or more of the metals in groups 3-16, lanthanides, combinations thereof, and/or alloys thereof. The composition could be used to form an ink that further comprises an ionically conductive material, such as a polymer, capable of ionic networking throughout the ink composition so as to create a substantially structurally coherent mass without significantly impacting the reactivity of a substantial number of the nanoparticles. In one application, the ink may be used to form a catalyst whereby the ink is applied to an electrically conductive backing material, such as carbon paper or fibers.Type: ApplicationFiled: July 23, 2007Publication date: June 10, 2010Applicant: QuantumSphere, Inc.Inventors: Kimberly McGrath, R. Douglas Carpenter
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Patent number: 7731867Abstract: The invention is directed to conductive polymer compositions, catalytic ink compositions (e.g., for use in screen-printing), electrodes produced by deposition of an ink composition, as well as methods of making, and methods of using such compositions and electrodes. An exemplary ink material comprises a metal catalyst (e.g., platinum black and/or platinum-on-carbon), graphite as a conducting material, a polymer binding material, and an organic solvent. In one aspect, the polymer binding material comprises a polymer binder blend comprising first and second polymers, wherein the first polymer has a glass transition temperature higher than the second polymer. In a second aspect, the polymer binding material comprises a hydrophilic acrylic polymer, copolymer, or terpolymer. The conductive polymer compositions of the present invention may be used, for example, to make electrochemical sensors. Such sensors may be used, for example, in a variety of devices to monitor analyte amount or concentrations in subjects.Type: GrantFiled: January 23, 2007Date of Patent: June 8, 2010Assignee: Animas Technologies, LLCInventors: Huawen Li, Michael J. Tierney
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Patent number: 7727381Abstract: In a process of hydrocracking heavy oil with a catalyst in petroleum refining, asphaltene contained in heavy oil, and impurities including heavy metals such as nickel and vanadium, are efficiently removed with activated carbon, whereby the reduction in catalyst activity or formation of coke by the impurities can be prevented. The invention provides a hydrocracking catalyst comprising activated carbon extrudate as a carrier activated with steam and having a high distribution of pores having pore sizes in the range of 20 to 200 nm.Type: GrantFiled: January 3, 2007Date of Patent: June 1, 2010Assignee: Toyo Engineering CorporationInventors: Hidetsugu Fukuyama, Satoshi Terai, Masayuki Uchida
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Publication number: 20100130774Abstract: This invention relates to the field of heterogeneous catalysis, and more particularly to oxidation catalysts including carbon supports having deposited thereon a noble metal and one or more optional promoters and to methods for their preparation. The invention further relates to the field of heterogeneous catalytic oxidation reactions, including the preparation of secondary amines by the catalytic oxidation of tertiary amines, such as the oxidation of an N-(phosphonomethyl)iminodiacetic acid to produce an N-(phosphonomethyl)glycine product.Type: ApplicationFiled: September 15, 2005Publication date: May 27, 2010Applicant: MONSANTO TECHNOLOGY LLCInventors: Kam-To Wan, Mark A. Leiber, Kerry Brethauer, Jingyue Liu
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Publication number: 20100130788Abstract: The invention relates to a process for preparing aromatic amines by catalytic hydrogenation of the corresponding nitro compounds, in particular for preparing toluenediamine by hydrogenation of dinitrotoluene, wherein hydrogenation catalysts in which a mixture of nickel, palladium and an additional element selected from the group consisting of cobalt, iron, vanadium, manganese, chromium, platinum, iridium, gold, bismuth, molybdenum, selenium, tellurium, tin and antimony is present as active component on a support are used.Type: ApplicationFiled: May 5, 2008Publication date: May 27, 2010Applicant: BASF SEInventors: Joana Coelho Tsou, Ekkehard Schwab, Petr Kubanek, Wolfgang Mackenroth, Steffen Oehlenschlaeger, Hartwig Voss, Sameul Neto
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Patent number: 7713910Abstract: The present invention provides a method for manufacture of supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method is based on the use of polyol solvents as reaction medium and comprises of a two-step reduction process in the presence of a support material. In the first step, the first metal (M1=transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (M2=noble metal; e.g. Pt, Pd, Au and mixtures thereof) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. Due to this two-step method, an uniform reduction occurs, resulting in noble metal based catalysts with a high degree of alloying and a small crystallite size of less than 3 nm. Due to the high degree of alloying, the lattice constants are lowered.Type: GrantFiled: October 29, 2004Date of Patent: May 11, 2010Assignee: Umicore AG & Co KGInventors: Dan V. Goia, Marco Lopez, Tapan Kumar Sau, Mihaela-Ortansa Jitianu
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Patent number: 7713902Abstract: The present invention provides methods of preparing an improved platinum catalyst for use in fuel cells. The method includes preparing a platinum-loaded template of mesoporous alumina, and preparing a platinum catalyst using said alumina template. To prepare the template, a platinum solution and an aluminum alkoxide-butanol solution are combined to form a mixture and the mixture is then subjected to hydration and condensation reactions. To prepare the platinum catalyst, the template and carbon precursors are subjected to polymerization, and the resultant composite subjected to heat treatment. Due to the uniform platinum particle size and high specific surface area achieved, the method of the invention can produce a platinum catalyst with high catalytic activity and thermal stability and in turn improve the performance of the fuel cell in which the catalyst is used.Type: GrantFiled: December 5, 2005Date of Patent: May 11, 2010Assignee: Hyundai Motor CompanyInventors: Jongheop Yi, Pil Kim, Heesoo Kim
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Publication number: 20100113260Abstract: The present invention is directed to methods for making metal oxide compositions, specifically, metal oxide compositions having high surface area, high metal/metal oxide content, and/or thermal stability with inexpensive and easy to handle materials. In one embodiment, the present invention is directed to methods of making metal and/or metal oxide compositions, such as supported or unsupported catalysts. The method includes combining a metal precursor with an organic acid to form a mixture and calcining the mixture for a period of time sufficient to form a metal oxide material.Type: ApplicationFiled: November 1, 2007Publication date: May 6, 2010Applicant: Symyx Technologies, Inc.Inventor: Alfred Hagemeyer
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Publication number: 20100113259Abstract: An activated catalyst capable of selectively growing single-walled carbon nanotubes when reacted with carbonaceous gas is provided. The activated catalyst is formed by reducing a catalyst that comprises a complex oxide. The complex oxide may be of formula AxByOz, wherein x/y?2 and z/y?4, A being a Group VIII element and B being an element such that an oxide of element B is not reducible in the presence of hydrogen at a temperature less than or equal to about 900° C. Methods of making, uses for and carbon fibril-containing product made with these activated catalysts are also provided.Type: ApplicationFiled: February 7, 2006Publication date: May 6, 2010Applicant: Hyperion Catalysis International, Inc.Inventors: Jun Ma, David Moy
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Publication number: 20100104926Abstract: The invention relates to the preparation of a catalytic composition that comprises a carbonated structuring material (MSC) associated with a catalyst (CAT). The invention comprises mixing a solution of a first solvent (SOL1) including the carbonated structuring material (MSC) and a solution of a second solvent (SOL2) including the catalyst (CAT), and agitating (AGM) the resulting mixture up to the precipitation if the catalyst on the carbonated structuring material. According to one aspect, the catalyst and the structuring material are not soluble in the mixture of the first and second solvents. The composition thus obtained can be used after filtration as a material for an electrode in a fuel cell.Type: ApplicationFiled: June 25, 2008Publication date: April 29, 2010Inventors: Bertrand Baret, Henri-Christian Perez, Pierre-Henri Aubert
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Patent number: 7700521Abstract: The present invention is directed to a composition for use as a catalyst in, for example, a fuel cell, the composition comprising platinum and copper, wherein the concentration of platinum is greater than 50 atomic percent and less than about 80 atomic percent, and further wherein the composition has a particle size which is less than 35 angstroms. The present invention is further directed to various methods for preparing such a composition.Type: GrantFiled: August 18, 2004Date of Patent: April 20, 2010Assignees: Symyx Solutions, Inc., Honda Giken Kogyo Kabushiki KaishaInventors: Daniel M. Giaquinta, Peter Strasser, Alexander Gorer, Martin Devenney, Hiroyuki Oyanagi, Kenta Urata, Hiroichi Fukuda, Keith James Cendak, Konstantinos Chondroudis
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Publication number: 20100092834Abstract: Noble metal catalysts and methods for producing the catalysts are provided. The catalysts are useful in applications such as fuel cells. The catalysts exhibit reduced agglomeration of catalyst particles as compared to conventional noble metal catalysts.Type: ApplicationFiled: January 16, 2008Publication date: April 15, 2010Inventor: KOSTANTINOS KOURTAKIS
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Publication number: 20100093522Abstract: Bulk catalysts that include a Group VI metal, a Group VIII metal, and at least 10-60% of an organic compound based component are formed. The bulk catalysts have increased stability through the use of a stabilizer in the organic compound based component, the use of an improved gas phase sulfidation, or a combination thereof. The bulk catalysts are suitable for hydroprocessing of hydrocarbon feeds.Type: ApplicationFiled: October 5, 2009Publication date: April 15, 2010Inventors: Jean W. Beeckman, Stephen J. McCarthy, Chuansheng Bai, William G. Borghard, Sanket K. Desai, Hyung S. Woo
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Patent number: 7696121Abstract: The invention provides an electrode comprising an electrically conductive material having a surface capable of producing surface enhanced Raman scattering of incident light from an adsorbate material adsorbed on the surface of the electrode. The adsorbate is substantially reducible and not substantially oxidizable. The surface of the electrode can be microroughened and include, for example, a plurality of adatoms or clusters of adatoms of a metallic material. The adatoms or clusters of adatoms form sites for photocatalysis of electroreduction when the electrode is irradiated with a light source. The invention also includes a method for making the electrode, and a method of generating electricity using the electrode. In accordance with a further aspect of the invention, a fuel cell is provided including the electrode of the invention.Type: GrantFiled: March 30, 2006Date of Patent: April 13, 2010Assignee: Fordham UniversityInventor: John J. McMahon
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Patent number: 7687427Abstract: The present invention discloses a novel process for the fabrication of a class of conductive supported electrocatalysts based on transition metals. The electrocatalysts are formed by pyrolysis of an organometallic polymer complex precursor which is the reaction product of transition metal salts and a templating polymer. The electrocatalysts has enhanced catalytic activity, and are useful in the preparation of supercapacitor and fuel cell electrodes, auto-thermal fuel reformer catalysts, oxygen and hydrogen sensors, zinc-air battery electrode and oxidation catalysts.Type: GrantFiled: June 13, 2006Date of Patent: March 30, 2010Assignee: Enerage, Inc.Inventor: Mark Y. Wu
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Patent number: 7687424Abstract: The invention provides an electrode comprising an electrically conductive material having a surface capable of producing surface enhanced Raman scattering of incident light from a complex adsorbed at the surface of the electrode, the complex including the electrically conductive material combined with a second material that is substantially reducible and not substantially oxidizable. The surface of the electrode can be microroughened. The invention also includes a method for making various embodiments of the electrode, and a method of generating electricity using the electrode. In accordance with a further aspect of the invention, a fuel cell is provided including the electrode of the invention.Type: GrantFiled: June 28, 2007Date of Patent: March 30, 2010Assignee: Fordham UniversityInventor: John J. McMahon
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Patent number: 7670985Abstract: The invention provides an activated carbon supported cobalt based catalyst for directly converting of synthesis gas to mixed linear alpha-alcohols and paraffins, comprising cobalt, an activated carbon carrier, a metal promoter which is at least one selected from the group consisting of a zirconium component, a lanthanum component, a cerium component, a chromium component, a vanadium component, a titanium component, a manganese component, a rhenium component, a potassium component, a ruthenium component, a magnesium component and a mixture thereof, wherein the cobalt and the promoter are deposited on the activated carbon carrier or substantially uniformly dispersed therein, and the metal promoter is present in the form of a metal, an oxide or a combination thereof.Type: GrantFiled: August 9, 2007Date of Patent: March 2, 2010Assignees: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, CNOOC New Energy Investment Co., Ltd.Inventors: Yunjie Ding, Hejun Zhu, Tao Wang, Guiping Jiao, Yuan Lv
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Patent number: 7666812Abstract: An improved gas diffusion electrode composed of a perovskite-type oxide dispersed in a mixture of carbon black and a hydrophobic binder polymer. An improved catalyst for use in the electrochemical reduction of oxygen comprising a perovskite-type compound having alpha and beta sites, and having a greater molar ratio of cations at the beta site. A particularly good reduction catalyst is a neodymium calcium manganite. An improved method of dispersing the catalysts with carbon in a reaction layer of the electrode improves performance of the electrode and the oxygen reduction process. This is provided by adding carbon black to an aqueous solution of metal salts before it is heated to a gel and then to a char and then calcined. Optionally, a quantity of the desired oxide catalyst can be premixed with a portion the carbon before adding the carbon to an aqueous solution of the metal salts to be heated.Type: GrantFiled: August 10, 2007Date of Patent: February 23, 2010Assignee: Ceramatec, Inc.Inventors: John Howard Gordon, Hachiya Toshinori, Shekar Balagopal, Sai Bhavaraju