With Reactant Nitrogen Or Sulfur Compound Patents (Class 523/428)
  • Patent number: 8741426
    Abstract: The present invention provides a blend comprising one or more epoxy resins and a mixture which comprises 0.3 to 0.9 amine equivalent, per equivalent of epoxide of the epoxy resin used, of a hardener component a) and as hardener component b) a compound of the formula I, a process for preparing this blend, the use of the blend of the invention for producing cured epoxy resin, and an epoxy resin cured with the blend of the invention.
    Type: Grant
    Filed: July 17, 2009
    Date of Patent: June 3, 2014
    Assignee: BASF SE
    Inventors: Lars Wittenbecher, Michael Henningsen, Gregor Daun, Dieter Flick, Joerg-Peter Geisler, Juergen Schillgalies, Erhard Jacobi
  • Patent number: 8686069
    Abstract: The solvent resistance of epoxy resins toughened with polyethersulfone is improved by using low molecular weight polyethersulfone. The resulting thermoplastic toughened epoxy resins are useful for making prepreg for aerospace applications.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: April 1, 2014
    Assignee: Hexcel Corporation
    Inventor: Yen-Seine Wang
  • Publication number: 20140069583
    Abstract: Epoxy resin compositions contain (i) a polyepoxide resin; (ii) a benzofuran diol component, a benzofuran di-epoxide component, or mixture thereof; and (iii) a curing agent, which upon curing, provides a cured resin exhibiting improved chemical and physical characteristics. The epoxy resin composition may also contain a toughening agent to further enhance the cured resin's physical characteristics.
    Type: Application
    Filed: May 4, 2012
    Publication date: March 13, 2014
    Inventors: Derek Scott Kincaid, Dong Le, David Lanham Johnson
  • Patent number: 8668983
    Abstract: The present invention provides an epoxy resin composition for a fiber reinforced composite material comprising an epoxy resin (A) comprising an epoxy resin (a1) having a weight average molecular weight of up to 1,000 and an epoxy resin (a2) having a weight average molecular weight of 10,000 to 100,000 which contains at least 20% by weight of the basic skeleton of the epoxy resin (a1), a thermoplastic resin (B), and a curing agent (C). The cured composition has a co-continuous phase of the epoxy resin (A) and the thermoplastic resin (B) and/or a continuous phase of the thermoplastic resin (B). A cured product having a high toughness can be obtained from this epoxy resin composition.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: March 11, 2014
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Masayuki Kawazoe, Hiroyuki Okuhira, Koichiro Miyoshi, Tomohiro Ito, Takashi Kousaka, Mitsuhiro Iwata
  • Patent number: 8663803
    Abstract: A varnish composition includes composition (A): an epoxy resin, composition (B): a hardener, composition (C): an accelerator, composition (D): phosphor-containing flame retardant, and composition (E): fillers, wherein composition (A) includes composition (A-1): phosphor-containing epoxy resin, phosphor-containing and silicon-containing epoxy resin, or a mixture thereof; composition (A-2): dicyclopentadiene epoxy resin; and composition (A-3): oxazolidone epoxy resin.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: March 4, 2014
    Assignee: ITEQ Corporation
    Inventors: Li-Chun Chen, Chun-Chieh Huang
  • Patent number: 8657413
    Abstract: A die attach composition is used for bonding a silicon chip on a flat substrate. The die attach composition includes a cross-linkable epoxy resin having a rigid backbone, an epoxy siloxane resin, a fumed silica filler, an amine curing agent, and a silane coupling agent. The die attach composition is particularly useful in bonding silicon heater chips on flat ceramic substrate in forming an inkjet printhead assembly. The die attach composition allows accurate placement of silicon heater chips on flat ceramic substrate and exhibits good ink resistance.
    Type: Grant
    Filed: January 18, 2011
    Date of Patent: February 25, 2014
    Assignee: Funai Electric Co., Ltd.
    Inventors: David Graham, Jeanne Marie Saldanha Singh, Richard D. Wells, Joel Provence
  • Patent number: 8642709
    Abstract: The subject matter of the present Application is two-component compositions whose first component is a mixture of reactive epoxy resins and optionally further formulation constituents which contains, based on the mass of all epoxy resins, a) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with polypropylene glycol which has an epoxy equivalent weight of at least 250 g/eq, and b) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with a novolac resin which has an epoxy equivalent weight of at least 175 g/eq, and whose second component contains at least one thiol group-containing hardener for epoxy resins.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: February 4, 2014
    Assignees: Henkel AG & Co. KGaA, Henkel US IP LLC
    Inventors: Pablo Walter, Mustapha Benomar, Stefen Kreiling, Angelika Troll, Rainer Schoenfeld, Timothy Walsh
  • Publication number: 20140011918
    Abstract: A polymeric formulation comprising at least one first epoxy resin having a density between 100 and 10,000 Pa·s, a blocked isocyanate, a polymer comprising hydroxy functional groups, a thermoplastic resin and a cross-linking agent, the polymer comprising hydroxyl functional groups with a hydroxyl content in the range 0.65 to 0.95 meq/g, the isocyanate-equivalents-to-polymer-OH-equivalents rate being in the range 0.60 to 1.1. The first epoxy resin is substantially semisolid at room temperature, the formulation comprising at least one second epoxy resin substantially liquid at room temperature, the first and second epoxy resins being present in a weight ratio from 60:40 to 80:20. These formulations are advantageously used for manufacturing prepregs and articles of composite material according to a dry winding process. By virtue of improved stability, a higher glass transition temperature, and a rheological profile result which can be chemically tailored to the needs of the impregnation/dry winding process.
    Type: Application
    Filed: March 29, 2012
    Publication date: January 9, 2014
    Inventors: Bruno D'Andrea, Anna DiCosmo, Valeria Vinti
  • Patent number: 8614266
    Abstract: A potting material for an electronic component, an electronic component, and a process for positioning ferrites in an electronic material are disclosed. The potting material is formed by curing a mixture. The mixture includes an epoxy component, an organic amine hardener, a viscosity-controlling agent, and a silica. The potting material has a coefficient of thermal expansion between an inorganic ferrite coefficient of thermal expansion and an organic substrate coefficient of thermal expansion of the electronic component. The potting material includes a rigidity permitting via drilling by one or more of mechanical drilling and laser burning.
    Type: Grant
    Filed: May 5, 2011
    Date of Patent: December 24, 2013
    Assignee: Tyco Electronics Services GmbH
    Inventors: Haiying Li, William Lee Harrison
  • Publication number: 20130337203
    Abstract: The invention relates to compositions that can be used as coatings for the inner lining of cargo tanks. The compositions comprise a mixture of epoxy resins, a curing agent, an accelerator or mixture of accelerator(s), and one or more filler(s) or pigment(s), wherein the mixture of epoxy resins comprises 60-80 wt. % of an RDGE epoxy resin and 20-40 wt. % of an epoxy novolac resin, wherein the wt. % is based upon the total weight of the mixture of epoxy resins.
    Type: Application
    Filed: March 5, 2012
    Publication date: December 19, 2013
    Applicant: AKZO NOBEL COATINGS INTERNATIONAL BV
    Inventors: Paul Anthony Jackson, Peter Robert Jones
  • Patent number: 8604102
    Abstract: The disclosure provides a thermosetting composition, including: (a) about 1-35 wt % of an oligomer, wherein the oligomer is obtained by reacting a liquid epoxy resin with an aromatic primary amine having four active hydrogen atoms, and the liquid epoxy resin and the primary amine have an equivalent mole ratio of 1:0.15-1:2.50; (b) about 5-10 wt % of a long chain resin; (c) about 50-80 wt % of an epoxy resin having at least two functional groups; and (d) about 5-15 wt % of a plasticizer.
    Type: Grant
    Filed: May 23, 2011
    Date of Patent: December 10, 2013
    Assignee: Industrial Technology Research Institute
    Inventors: Tien-Shou Shieh, Pei-Ching Liu
  • Publication number: 20130310485
    Abstract: Embodiments of the present disclosure include an epoxy-adduct hardening agent formed as a reaction product of a first adduct formed as a reaction product of a first epoxy resin and a polyether monoamine and second adduct formed as a reaction product of an ethyleneamine and a glycidyl ether. Embodiments include a curable composition having an epoxy resin and the epoxy-adduct hardening agent.
    Type: Application
    Filed: October 17, 2011
    Publication date: November 21, 2013
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Markus Schrötz, Christina Fritsche, Marcus Pfarherr, Juergen Gaebel
  • Publication number: 20130295381
    Abstract: A curing agent for epoxy resins that is comprised of the reaction product of an amine, an epoxy resin, and an elastomer-epoxy adduct; compositions containing the curing agent and an epoxy resin; the compositions are useful in electronic displays, circuit boards, semi conductor devices, flip chips and other applications.
    Type: Application
    Filed: July 5, 2013
    Publication date: November 7, 2013
    Inventors: Yurong Ying, John J. McNamara, Jing Liang, Rong-Chang Liang
  • Publication number: 20130261228
    Abstract: A curable composition or system including (a) at least one divinylarene dioxide, (b) at least one polythiol compound curing agent; and (c) at least one catalyst; wherein the resulting curable composition may be cured at ambient conditions to provide durable cured material.
    Type: Application
    Filed: October 19, 2011
    Publication date: October 3, 2013
    Applicant: Dow Global Technologies LLC
    Inventor: Maurice J. Marks
  • Patent number: 8545667
    Abstract: This invention relates to compositions useful as adhesives and more particularly to the preparation of heat-curable epoxy-based adhesive compositions that are capable of being easily pumped under high shear at temperatures around room temperature but are resistant to being washed off substrate surfaces prior to being cured.
    Type: Grant
    Filed: June 4, 2010
    Date of Patent: October 1, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Olaf Lammerschop, Scott Hartsell, Rajat K. Agarwal
  • Patent number: 8524807
    Abstract: Compounds VB of the formula (I) or (II), said compounds being particularly suitable as curing agents for epoxide resins. The compounds can be produced easily and rapidly. They can be used in the form of aqueous curing agents and form stabile aqueous emulsions in particular. This facilitates the formulation of ECC compounds for use primarily as coatings.
    Type: Grant
    Filed: June 12, 2009
    Date of Patent: September 3, 2013
    Assignee: Sika Technology AG
    Inventor: Pierre-André Bütikofer
  • Patent number: 8524857
    Abstract: A new class of compounds, namely diamino alcohols, is described, along with a process for their production and their use as hardeners, or curing agents, for epoxy resin systems, some of which have high glass transition temperatures, Tgs, such as greater than about 120° C.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: September 3, 2013
    Assignees: Dow Global Technologies LLC, ANGUS Chemical Company
    Inventors: Asghar Akber Peera, Ian Tomlinson
  • Publication number: 20130225725
    Abstract: Curable compositions, cured compositions, and articles that include the cured compositions are described. The curable composition contains a) an epoxy resin, b) a curing agent, c) a reactive liquid modifier, and d) a toughening agent. The cured compositions can be used as structural adhesives. The reactive liquid modifier is an acetoacetate ester of a dimer alcohol. The cured compositions can be used as adhesives such as structural adhesives or as polymeric coatings.
    Type: Application
    Filed: November 8, 2011
    Publication date: August 29, 2013
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Christopher J. Campbell, Kevin M. Lewandowski, Kwame Owusu-Adom
  • Patent number: 8518208
    Abstract: Thermosetting adhesive compositions formed from an epoxy resin containing nano-sized core-shell particles, one or more thermoplastic toughening agent containing an amine-terminated polyethersulfone, and at least one multi-functional epoxy resin, together with at least one amine curing agent to allow full cure of the adhesive composition up to 400° F. are provided herein. Such compositions are useful for forming adhesive films that can bond composite/metal/honeycomb structures for aerospace including bonding of aircraft leading or trailing edges, acoustic nacelle structures, horizontal and vertical tail, and various other structures, as well as for other high performance industrial applications.
    Type: Grant
    Filed: August 26, 2010
    Date of Patent: August 27, 2013
    Assignee: Cytec Technology Corp.
    Inventor: Dalip Kohli
  • Publication number: 20130217806
    Abstract: The subject matter of the present invention relates to a blend comprising an epoxy resin, a cyclic carbonate, and a hardener comprising a polyalkoxypolyamine, another amine, and a catalyst, to a process for producing said blend, to the use of the blend of the invention for producing cured epoxy resin, and also to an epoxy resin cured with the blend of the invention, and in particular to fiber-reinforced cured epoxy resins for use in rotor blades for wind turbines.
    Type: Application
    Filed: February 21, 2013
    Publication date: August 22, 2013
    Inventors: Lionel Gehringer, Gregor Daun, Michael Henningsen, Rainer Klopsch, Olivier Fleischel
  • Patent number: 8486518
    Abstract: An epoxy resin composition suitably used for a prepreg which can complete curing in a short time even at a low temperature and secure a sufficient usable period under preservation at room temperature, in comparison with conventional epoxy resin compositions. An epoxy resin composition comprising at least one of an epoxy resin, an amine compound having at least one sulfur atom in the molecule thereof, and a reaction product of an epoxy resin and an amine compound having at least one sulfur atom in the molecule thereof, and an amine compound having at least one sulfur atom in the molecule thereof, and a urea compound and a dicyandiamide, wherein each of the contents of the sulfur atom and the urea compound in the epoxy resin composition is respectively 0.2 to 7% by mass and 1 to 15% by mass.
    Type: Grant
    Filed: March 27, 2008
    Date of Patent: July 16, 2013
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Tsuneo Takano, Akitada Yanase, Tadashi Sakai, Kiharu Numata, Akihiro Ito, Masato Taguchi, Junichi Muramatsu, Kazuya Goto, Kazuki Koga
  • Patent number: 8470435
    Abstract: An epoxy resin composition suitably used for a prepreg which can complete curing in a short time even at a low temperature and secure a sufficient usable period under preservation at room temperature, in comparison with conventional epoxy resin compositions. An epoxy resin composition comprising at least one of an epoxy resin, an amine compound having at least one sulfur atom in the molecule thereof, and a reaction product of an epoxy resin and an amine compound having at least one sulfur atom in the molecule thereof, and an amine compound having at least one sulfur atom in the molecule thereof, and a urea compound and a dicyandiamide, wherein each of the contents of the sulfur atom and the urea compound in the epoxy resin composition is respectively 0.2 to 7% by mass and 1 to 15% by mass.
    Type: Grant
    Filed: March 27, 2008
    Date of Patent: June 25, 2013
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Tsuneo Takano, Akitada Yanase, Tadashi Sakai, Kiharu Numata, Akihiro Ito, Masato Taguchi, Junichi Muramatsu, Kazuya Goto, Kazuki Koga
  • Publication number: 20130158159
    Abstract: The present invention relates to stable, zero or low VOC epoxy-containing polysiloxane oligomer compositions that provide for a high degree of chemical resistance to compositions containing organic resins, while at the same time, maintaining or improving the flexibility of these organic resin-containing compositions, to processes for preparing epoxy-containing polysiloxane oligomer compositions, and to uses in coatings, sealants, adhesives, and composites containing the same.
    Type: Application
    Filed: December 19, 2011
    Publication date: June 20, 2013
    Applicant: MOMENTIVE PERFORMANCE MATERIALS INC.
    Inventors: Narayana Padmanabha Iyer, Lesley Hwang, Vikram Kumar, Christian Geismann, Constantine Kondos, Shiu-Chin Su
  • Publication number: 20130149934
    Abstract: A surfacing film is formed from a curable resin composition containing an epoxy novolac resin, a tri-functional or tetra-functional epoxy resin, ceramic microspheres, an amine-based curing agent, particulate inorganic fillers; and a toughening component. The surfacing film exhibits high Tg and high cross-linked density after curing, as well as high resistance to paint stripper solutions. The surfacing film is suitable for co-curing with fiber-reinforced resin composite materials. The surfacing film may optionally contain electrically conductive additives to provide sufficient conductivity for lightning strike protection (LSP) or electromagnetic interference (EMI) shielding.
    Type: Application
    Filed: December 6, 2012
    Publication date: June 13, 2013
    Applicant: CYTEC TECHNOLOGY CORP.
    Inventor: CYTEC TECHNOLOGY CORP.
  • Publication number: 20130137796
    Abstract: Room temperature curing epoxy adhesives that show good adhesion to plastic substrates are described. The adhesives contain an epoxy resin component comprising a first epoxy resin and a second epoxy resin; a first amine curing agent having an equivalent weight of at least 50 grams per mole of amine equivalents; a second amine curing agent having an equivalent weight of no greater than 45 grams per mole of amine equivalents; an acetoacetoxy-functionalized compound; a metal salt catalyst; and a multifunctional acrylate.
    Type: Application
    Filed: July 19, 2011
    Publication date: May 30, 2013
    Applicant: 3M INNOVATIVE PROPERTIES COMPANY
    Inventor: Michael A. Kropp
  • Patent number: 8450433
    Abstract: Provided are a resin composition for the manufacture of marble chips including a halogenated epoxy resin binder and showing high heat resistance, high chemical resistance, high impact resistance, high specific gravity and high transparency, a marble chip manufacturing method using the resin composition and an artificial marble made from marble chips.
    Type: Grant
    Filed: August 13, 2010
    Date of Patent: May 28, 2013
    Inventor: Young-Min Kim
  • Publication number: 20130122766
    Abstract: Embodiments of the present disclosure include a curable composition including an epoxy compound selected from the group consisting of aromatic epoxy compounds, alicyclic epoxy compounds, aliphatic epoxy compounds, and combinations thereof, a curing agent selected from the group consisting of novolacs, amines, anhydrides, carboxylic acids, phenols, thiols, and combinations thereof, and a phosphono-methyl-glycine.
    Type: Application
    Filed: July 19, 2011
    Publication date: May 16, 2013
    Applicant: DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Sudhakar Balijepalli, Michael J. Mullins, Irina Graf, Raymond J. Thibault, Ashwin Bharadwaj, Anteneh Worku
  • Patent number: 8440746
    Abstract: Curable, one-package, stable adhesive compositions are provided comprising: (a) a resin component comprising a polyepoxide, (b) a polyamine having at least two primary amine, secondary amine, and/or ketimine functional groups; and (c) a curing component comprising dicyandiamide and an accelerator. At least a portion of the polyepoxide in the resin component is reacted with carboxy-terminated butadiene acrylonitrile polymer. The accelerator comprises a reaction product comprising a renewable polyol, a diisocyanate, and a dialkyl monoamine containing alkyl groups with at least two carbon atoms each. The compositions are suitable for use as adhesive compositions over a wide temperature range.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: May 14, 2013
    Assignee: PPG Industries Ohio, Inc
    Inventors: Shanti Swarup, Masayuki Nakajima, Umesh C. Desai, Tien-Chieh Chao, Charles M. Kania, Britt Minch
  • Patent number: 8431224
    Abstract: Disclosed is a halogen-free resin composition for printed wiring board production, which is remarkably reduced in quality deterioration due to moisture absorption of a semi-cured resin film (layer). Also disclosed is a copper film with resin or the like. The resin composition is characterized by containing a component A (one or more resins selected from the group consisting of bisphenol-A epoxy resins, bisphenol-F epoxy resins and bisphenol-AD epoxy resins, which have an epoxy equivalent of not more than 200, while being in a liquid state at 25 DEG C.), a component B (a linear polymer having a crosslinkable functional group), a component C (a crosslinking agent), a component D (an imidazole-based epoxy resin curing agent) and a component E (a phosphorus-containing epoxy resin). The resin composition is also characterized by containing 0.5-3.0% by weight of phosphorus atoms per 100% by weight of the resin composition. In the copper foil with resin, a resin layer is formed by using the resin composition.
    Type: Grant
    Filed: March 21, 2008
    Date of Patent: April 30, 2013
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Tetsuro Sato, Toshifumi Matsushima
  • Publication number: 20130069465
    Abstract: There are provided an adhesive resin composition for a hard disk drive (HDD) motor and a HDD motor fabricated by using the same. The adhesive resin composition for a HDD motor adheres fixed members and rotating members of the HDD motor to each other and includes 100 parts by weight of a first resin, 25 to 80 parts by weight of a second resin, a hardness of which after hardening is lower than that of the first resin, and 40 to 100 parts by weight of a hardener. The HDD motor is fabricated by using the adhesive resin composition for a HDD motor including a flexible epoxy resin, whereby reliability of the motor against external impacts may be improved.
    Type: Application
    Filed: December 21, 2011
    Publication date: March 21, 2013
    Inventors: Kun KIM, Sang Hyun Kwon, Myung Hwa Choi
  • Publication number: 20130023603
    Abstract: The subject matter of the present Application is two-component compositions whose first component is a mixture of reactive epoxy resins and optionally further formulation constituents which contains, based on the mass of all epoxy resins, a) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with polypropylene glycol which has an epoxy equivalent weight of at least 250 g/eq, and b) at least 10 wt % of an epoxy group-containing reaction product of epichlorohydrin with a novolac resin which has an epoxy equivalent weight of at least 175 g/eq, and whose second component contains at least one thiol group-containing hardener for epoxy resins.
    Type: Application
    Filed: September 21, 2012
    Publication date: January 24, 2013
    Applicants: Henkel AG & Co. KGaA, Henkel Corporation
    Inventors: Henkel Corporation, Henkel AG & Co. KGaA
  • Patent number: 8309631
    Abstract: It is an object of the present invention to provide a fiber reinforced composite material combining good properties such as toughness and impact resistance and to provide an epoxy resin composition to obtain this. This object is achieved by the an epoxy resin composition comprising the following [A], [B], [C], and [D]: [A] a diglycidyl ether-type epoxy resin having a molecular weight of 1,500 or more; [B] an epoxy resin in which an SP value of a structural unit thereof is greater by 1.5 to 6.5 than an SP value of a structural unit of [A]; [C] a diglycidyl ether-type epoxy resin having a molecular weight of 500 to 1,200; and [D] an epoxy resin curing agent, in a ratio that satisfies the following formulas (1) to (4): 0.2?A/(A+B+C+E)?0.6;??(1), 0.2?B/(A+B+C+E)?0.6;??(2), 0.15?C/(A+B+C+E)?0.4; and??(3), 0?E/(A+B+C+E)?0.2,??(4) wherein A, B, and C represent weights of [A], [B], and [C], respectively, and E represents a weight of an epoxy resin other than [A], [B], and [C].
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: November 13, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Nobuyuki Tomioka, Shiro Honda, Yuki Mitsutsuji, Maki Mizuki, Takayuki Imaoka
  • Patent number: 8309632
    Abstract: The invention provides an epoxy nanocomposite material for dental therapy, which can be applied to direct or indirect clinical restoration, dental core-post system, and dental brace etc. The epoxy nanocomposite filling material provided by the invention can be polymerized with various curing agents to form the polymer with low shrinkage.
    Type: Grant
    Filed: February 5, 2010
    Date of Patent: November 13, 2012
    Assignee: National Taiwan University
    Inventors: Wei-Fang Su, Sheng-Hao Hsu, Yun-Yuan Tai, Min-Huey Chen
  • Patent number: 8304473
    Abstract: A carbon/epoxy resin composition and a method of producing a carbon-epoxy dielectric using the same. The carbon/epoxy resin composition includes about 45 volume percent (volume %) to about 50 volume % of an epoxy composition, the epoxy composition including a bisphenol-based epoxy compound and an alicyclic epoxy compound, based on a total volume of the carbon/epoxy resin composition, about 2.0 volume % to about 3.1 volume % of carbon black, based on a total volume of the carbon/epoxy resin composition, about 80 parts by volume to about 104 parts by volume of an acid anhydride-based curing agent, based on 100 parts by volume of the epoxy composition, and about 1 part by volume to about 3 parts by volume of a tertiary alkylamine-based curing catalyst, based on 100 parts by volume of the epoxy composition.
    Type: Grant
    Filed: July 27, 2009
    Date of Patent: November 6, 2012
    Assignees: Samsung Electronics Co., Ltd., Samsung Electro-Mechanics Co., Ltd.
    Inventors: Yoo-Seong Yang, Eun-Sung Lee, Sang-Soo Jee, Soon-Jae Kwon
  • Publication number: 20120259041
    Abstract: An adhesive composition includes a first part comprising about 15 to about 60 wt % of an epoxy compound, about 35 to about 80 wt % of an epoxy novolac, and about 5 to about 25 wt % of an epoxy-based reactive diluent based on the total weight of epoxy compound, epoxy novolac, and reactive diluent; and a second part comprising less than about 20 wt % of a hydroxyaromatic solvent, about 80 to about 99 wt % of a Mannich base, and about 1 to about 20 wt % of a tertiary amine, based on the total weight of hydroxyaromatic solvent, Mannich base, and tertiary amine, the first and second parts being present in a volume ratio of about 0.8:1 to about 1.2:1. Additives to further enhance the properties may be included. A method of forming an adhesive layer includes applying the adhesive composition to a surface.
    Type: Application
    Filed: March 13, 2012
    Publication date: October 11, 2012
    Applicant: POWERS PRODUCTS III, LLC
    Inventor: James E. Surjan
  • Patent number: 8278398
    Abstract: Two-component epoxy-based structural adhesives are disclosed which exhibit excellent impact resistance, even when cured at approximately room temperature. The adhesives include an epoxy resin component which includes an epoxy resin and a reactive tougher. The adhesives also include a hardener component, which includes from 15 to 50 weight percent of an amine-terminated polyether, from 4 to 40 weight percent of an amine terminated rubber having a glass transition temperature of ?40° C. or below, and from 10 to 30 weight percent of an amine-terminated polyamide having a melting temperature of no greater than 50° C.
    Type: Grant
    Filed: August 12, 2008
    Date of Patent: October 2, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Andreas Lutz, Beda Steiner
  • Patent number: 8263216
    Abstract: Disclosed is a fiber-reinforced composite material that is high in heat resistance and strength while being low in the content of volatile matter that volatilizes during curing. Also disclosed are an epoxy resin composition for production thereof, and a prepreg produced from the epoxy resin composition. Specifically the invention provides an epoxy resin composition comprising: [A] an epoxy resin comprising two or more ring structures each consisting of four or more members, and at least one amine type or ether type glycidyl group directly connected to the ring structures, [B] a tri- or more-functional epoxy resin, and [C] a curing agent, and also provides a prepreg produced by impregnating reinforcing fiber with the epoxy resin composition and a fiber-reinforced composite material produced by curing the prepreg.
    Type: Grant
    Filed: January 13, 2010
    Date of Patent: September 11, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Atsuhito Arai, Hiroaki Sakata, Kenichi Yoshioka, Hiroshi Taiko, Jiro Nakatani, Kotaro Ono, Michiya Ishikawa
  • Publication number: 20120182355
    Abstract: A die attach composition is used for bonding a silicon chip on a flat substrate. The die attach composition includes a cross-linkable epoxy resin having a rigid backbone, an epoxy siloxane resin, a fumed silica filler, an amine curing agent, and a silane coupling agent. The die attach composition is particularly useful in bonding silicon heater chips on flat ceramic substrate in forming an inkjet printhead assembly. The die attach composition allows accurate placement of silicon heater chips on flat ceramic substrate and exhibits good ink resistance.
    Type: Application
    Filed: January 18, 2011
    Publication date: July 19, 2012
    Inventors: David Graham, Jeanne Marie Saldanha Singh, Richard D. Wells, Joel Provence
  • Patent number: 8198381
    Abstract: Disclosed is a phenol aralkyl epoxy resin having a structure wherein at least a phenol or a naphthol is bound by using an aralkyl group as a linking group and a structure represented by formula (1) below, while satisfying the condition 1 below. This epoxy resin is excellent in workability during production of a composition and is easy to control quality. Condition 1: The following relation (?) is satisfied with A being the hydroxyl equivalent (as measured in accordance with JIS K 0070) of a phenol-modified epoxy resin obtained by adding an equivalent molar amount of phenol relative to the epoxy equivalent of the epoxy resin, and B being the epoxy equivalent of the epoxy resin. 50?1000×(A?B)/B?250 (?).
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: June 12, 2012
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Masataka Nakanishi, Katsuhiko Oshimi, Kazuyuki Ohhashi, Toru Kurihashi
  • Publication number: 20120128987
    Abstract: A resin component for a one- or two-component adhesive, a matrix resin, or a structural foam, comprising: C1) at least one epoxy resin, having an average of more than one epoxy group per molecule, that does not correspond to the definition of component C2); C2) at least one oligomeric or polymeric urethane-group-free polyether compound. A one- or two-component epoxy adhesive, structural foam, or matrix material for composites, comprising the aforesaid resin components.
    Type: Application
    Filed: January 30, 2012
    Publication date: May 24, 2012
    Inventors: Rainer Schoenfeld, Emilie Barriau, Stefan Kreiling, Pablo Walter
  • Patent number: 8178598
    Abstract: A curing agent for epoxy resin, and a coating composition using the curing agent curing agent that delivers excellent recoatability and overcoatability after a long time exposure. (A) An epoxy curing agent that is derived by adduction between amide-type reactants from polyamine compounds comprising from 25-75 mol % of a polyoxyalkylene-polyamine and carboxylic acids or a mixture thereof and glycidyl ether compound; (B) An epoxy curing agent of the mixture of (B1) amide-type reactants prepared through polyoxyalkylene-polyamine and carboxylic acids or a mixture thereof, and (B2) a reactant is derived by adduction between other aliphatic polyamines or a mixture thereof and glycidyl ether compound. Coating composition comprising the epoxy curing agent of the above described A or B.
    Type: Grant
    Filed: June 12, 2007
    Date of Patent: May 15, 2012
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Keisuke Hakuya, Michael Ian Cook, Kouichi Sakasegawa, Yoshimi Hasegawa
  • Publication number: 20120071584
    Abstract: Core-shell rubbers are incorporated into epoxy adhesives. The adhesives are structural type adhesives that contain an epoxy resin and a toughener, and may contain a liquid rubber in addition to the core-shell rubber. The adhesives have good modulus and tensile strength, which are obtained without loss of elongation and adhesive properties.
    Type: Application
    Filed: November 30, 2011
    Publication date: March 22, 2012
    Inventors: Andreas Lutz, Jeannine Fluckiger, Cathy Grossnickel
  • Publication number: 20120070571
    Abstract: Coating composition comprising a liquid first phase comprising one or more polymer binder components having functional groups capable of cross-linking by electron pair exchange, and a second phase which is a powder material, such as sand, comprising one or more compounds capable of activating crosslinking of the binder components in the liquid phase after the second phase is exposed to the first phase. The activating compound in the second phase may include a Lewis acid or Lewis base. Method of applying a coating composition curable by cross-linking chemistry based on electron pair exchange, wherein after application of a layer of the coating composition on a substrate, a powder material comprising one or more cross-linking activating compounds is sprinkled over the wet layer. After sprinkling the powder material over the coating layer, a second coating layer is applied.
    Type: Application
    Filed: September 23, 2011
    Publication date: March 22, 2012
    Applicant: AKZO NOBEL COATINGS INTERNATIONAL B.V.
    Inventor: Franciscus Hubertus Maria STAPPERS
  • Patent number: 8133941
    Abstract: Curable, aqueous epoxy resin composition, comprising a) an epoxy compound, b) an aminic curing agent which is an aqueous solution of a product from the reaction between i) an adduct between a polyamine and a liquid glycidyl ether which is not a glycidyl ether of a polyalkylene glycol, and ii) an epoxidized polyalkylene glycol, and c) from 0.5 to 15 wt.-%, based on the sum of the components b) and c), of a compound of the general formula (I) whereby R1=—H or —C4H9, and x=1, 2, 3 or 4, providing due to the presence of component c) an adjustable and recognizable end of pot life during application, for example coating, adhesive, as flooring, casting, tooling or encapsulating.
    Type: Grant
    Filed: March 4, 2008
    Date of Patent: March 13, 2012
    Assignee: Huntsman International LLC
    Inventors: Alwin Krotzek, Joerg Volle
  • Publication number: 20120016057
    Abstract: It is an object of the present invention to provide an adhesive for electronic components that prevents warpage of electronic components and reflow cracks even in the case of bonding thin electronic components. The present invention relates to an adhesive for electronic components, comprising: an epoxy compound having an aliphatic polyether backbone and a glycidyl ether group; an epoxy group-containing acrylic polymer; an episulfide compound; and a curing agent, wherein the amount of the episulfide compound is 1 parts by weight or more, and less than 30 parts by weight relative to 100 parts by weight of the epoxy compound having an aliphatic polyether backbone and a glycidyl ether group.
    Type: Application
    Filed: January 29, 2010
    Publication date: January 19, 2012
    Inventors: Akinobu Hayakawa, Hideaki Ishizawa, Kohei Takeda, Ryohei Masui
  • Patent number: 8097665
    Abstract: A cationic electrodeposition coating composition including amino group-containing modified epoxy resin (A), blocked polyisocyanate curing agent (B), metal compound (C), and nitrogen oxide ion (E), wherein metal compound (C) is contained in an amount of 10 to 10,000 ppm calculated as metal, and nitrogen oxide ion (E) is contained in an amount of 50 to 10,000 ppm relative to the mass of the cationic electrodeposition coating composition. A coated article in which an electrodeposition coating film is formed on an untreated steel sheet exhibits excellent corrosion resistance, in particular, excellent hot salt water immersion resistance at 55° C.; and a multilayer coating film formed by a 3-coat 1-bake coating method on the electrodeposition coating film, which is formed on the untreated steel sheet, exhibits excellent corrosion resistance in a combined corrosion cycle test.
    Type: Grant
    Filed: September 1, 2010
    Date of Patent: January 17, 2012
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Shigeo Nishiguchi, Akihiko Shimasaki
  • Patent number: 8097664
    Abstract: A cationic electrodeposition coating composition including amino group-containing modified epoxy resin (A), blocked polyisocyanate curing agent (B), phenol resin (C), metal compound (D), and nitrogen oxide ion (E), wherein the metal compound (D) is contained in an amount of 10 to 10,000 ppm calculated as metal and the nitrogen oxide ion (E) is contained in an amount of 50 to 10,000 ppm, relative to the mass of the cationic electrodeposition coating composition. The cationic electrodeposition coating composition exhibits excellent anti-corrosion properties when coated onto untreated steel sheets.
    Type: Grant
    Filed: July 29, 2010
    Date of Patent: January 17, 2012
    Assignee: Kansai Paint Co., Ltd.
    Inventors: Shigeo Nishiguchi, Akihiko Shimasaki
  • Publication number: 20110288201
    Abstract: A masterbatch composition, a method for the preparation of a masterbatch composition, a method for the preparation of a powder coating composition, a powder coating composition obtainable by said method as well as the use of a masterbatch composition for a powder coating composition or for increasing the opacity of a cured powder coating is disclosed.
    Type: Application
    Filed: January 28, 2010
    Publication date: November 24, 2011
    Applicant: Huntsman International LLC
    Inventor: Philippe Gottis
  • Patent number: 8063157
    Abstract: Curing agent for epoxy resins, consisting of A) 1%-99% by weight of an adduct obtainable by reacting a1) a polyethylene polyamine having up to six nitrogens in the molecule with a2) a monoglycidyl ether, the adduct of a1) and a2) preferably being isolated by removal of the excess polyethylene polyamine, and B) 99%-1% by weight of an adduct obtainable by reacting b1) a diamine or polyamine with b2) styrene, and also curable compositions further comprising an epoxide compound, and the use of these curable compositions for producing moldings and sheetlike structures, and also for applications in the adhesives and sealants sector and for epoxy-resin mortars.
    Type: Grant
    Filed: June 20, 2005
    Date of Patent: November 22, 2011
    Assignee: Huntsman Advanced Materials Americas LLC
    Inventors: Jörg Volle, Michael Vogel
  • Patent number: 8062467
    Abstract: Two-component adhesives (K), which includes two components K1 and K2. Component K1 includes at least one epoxy resin A with more than one epoxy group per molecule on average; at least one epoxy adduct B with more than one epoxy group per molecule on average that is an epoxy adduct of type B1 and optionally combined with an epoxy adduct of type B2; at least one reaction product F between an epoxy adduct B and a compound C, which has at least two isocyanate groups, in addition to at least one curing agent D for epoxy resins, which is activated by increased temperature. The component K2 comprises a compound E, which includes at least two isocyanate groups.
    Type: Grant
    Filed: February 25, 2005
    Date of Patent: November 22, 2011
    Assignee: Sika Technology
    Inventors: Peter Merz, Jurgen Finter