With Reactant Nitrogen Or Sulfur Compound Patents (Class 523/428)
  • Patent number: 6825315
    Abstract: A method of making a thermally-removable adhesive is provided where a bismaleimide compound, a monomeric furan compound, containing an oxirane group an amine curative are mixed together at an elevated temperature of greater than approximately 90° C. to form a homogeneous solution, which, when cooled to less than approximately 70° C., simultaneously initiates a Diels-Alder reaction between the furan and the bismaleimide and a epoxy curing reaction between the amine curative and the oxirane group to form a thermally-removable adhesive. Subsequent heating to a temperature greater than approximately 100° C. causes the adhesive to melt and allows separation of adhered pieces.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: November 30, 2004
    Assignee: Sandia Corporation
    Inventor: James H. Aubert
  • Patent number: 6805958
    Abstract: The present invention provides an epoxy resin composition containing (A) an epoxy resin having two or more epoxy groups in one molecule, (B) a phenolic curing agent, (C) a phenoxy resin containing a bisphenol S skeleton and having a weight average molecular weight of 5,000 to 100,000, and (D) a curing accelerator, wherein the epoxy resin (A) contains a phosphorus atom, and wherein 5 to 50 parts by weight of the phenoxy resin (C) and 0.05 to 10 parts by weight of the curing accelerator (D) are mixed with 100 parts by weight in total of the epoxy resin (A) and the phenolic curing agent (B).
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: October 19, 2004
    Assignee: Ajinomoto Co., Inc.
    Inventors: Shigeo Nakamura, Tadahiko Yokota
  • Patent number: 6770965
    Abstract: A wiring substrate includes (1) an insulating substrate having an opening, or a core substrate and a build-up layer wherein at least one of the core substrate and the build-up layer has an opening, (2) at least one electronic part disposed in the opening, and (3) an embedding resin comprising a thermoplastic resin, an acid anhydride curing agent, a curing accelerator, and a filler, wherein the embedding resin shows a viscosity of not higher than 85 Pa·s in a shear rate of 8.4 s−1 after allowing to stand for 24 hours at 25° C.±1° C.
    Type: Grant
    Filed: December 27, 2001
    Date of Patent: August 3, 2004
    Assignee: NGK Spark Plug Co., Ltd.
    Inventors: Hiroki Takeuchi, Toshifumi Kojima, Kazushige Ohbayashi, Hisahito Kashima
  • Patent number: 6713535
    Abstract: The present invention is directed to a low-friction coating composition, comprising: about 10 to about 30 wt % of an epoxy resin composition consisting essentially of 4-glycidyloxy-N,N′-diglycidylaniline; about 30 to about 60 wt % of an epoxide resin composition consisting essentially of bisphenol A diglycidyl ether polymer; and about 20 to about 40 wt % of an aromatic amine composition consisting essentially of 4,4′-sulfonyldianiline; wherein all weight percents are based on the total weight of the low-friction coating composition, and wherein the low-friction coating composition is substantially free of chromate. The invention is also directed to a substrate coated with the above low-friction coating composition, and methods of coating a substrate with the low-friction coating composition.
    Type: Grant
    Filed: February 28, 2002
    Date of Patent: March 30, 2004
    Assignee: Turbine Controls, Inc.
    Inventors: Stanley Orkin, Glenn Greenberg
  • Patent number: 6620510
    Abstract: An epoxy resin composition giving a cured resin plate which, after 60 hour standing at 150° C. and at the saturated vapor pressure, has a water absorption of 3.5% by weight or lower; a prepreg which comprises the epoxy resin composition and reinforcing fibers; and a fiber-reinforced resin roll which is 1) a laminate comprising fiber-reinforced resin layers each comprising reinforcing fibers and a matrix resin, wherein the matrix resin is a resin composition giving a cured resin plate which, after 60 hour standing at 150° C. and at the saturated vapor pressure, has a water absorption of 3.5% by weight or lower; or 2) a laminate comprising (i) at least one fiber-reinforced resin layer comprising long reinforcing fibers having an elastic modulus of 600˜800 Gpa and a resin composition and (ii) at least one fiber-reinforced resin layer comprising long reinforcing fibers having an elastic modulus of 140˜300 Gpa and a resin composition.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: September 16, 2003
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Masato Taguchi, Hisao Koba, Yutaka Yamaguchi
  • Patent number: 6613435
    Abstract: This invention relates to an article comprising a bio-supportive matrix comprising at least one bio-limiting agent and at least one nutritional source on a substrate. The invention also relates to the bio-supportive matrix and methods of using the matrix. The present invention can be used as a biological barrier to unwanted organisms, such as animals and plants, by producing allelochemicals that either kill or repel those organisms. The invention could be used as a coating on a vessel to prevent fouling of vessels. The invention may also be used to manufacture specific allelochemicals such as drugs or pharmaceuticals. The invention also relates to a method of preparing a bio-limiting ecological substrate useful as a means for producing allelochemicals, comprising the steps of providing a bio-supportive matrix as described above, and exposing the matrix to the environment, wherein the matrix is prepared to provide a biomass that produces the desired allelochemicals.
    Type: Grant
    Filed: October 26, 2000
    Date of Patent: September 2, 2003
    Inventor: Dennis A. Guritza
  • Patent number: 6518331
    Abstract: A multilayer printed circuit board having resinous insulating layers and conductor layers alternately superposed on a circuit board with ample adhesive strength, a method for the production thereof, and a curable resin composition useful for the formation of resinous insulating layers are disclosed. The manufacture of the multilayer printed circuit board is accomplished by applying the curable resin composition to the surface of conductor layer of the circuit board, thermally curing the applied layer thereby forming resinous insulating layer, then boring a through-hole in the circuit board, treating the resinous insulating layer with a coarsening agent thereby imparting undulating coarsened surface thereto, subsequently coating the surface of resinous insulating layer and the inner surface of the through-hole with a conductor layer as by electroless plating, and thereafter forming a prescribed circuit pattern in the conductor layer.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: February 11, 2003
    Assignee: Taiyo Ink Manufacturing Co., Ltd.
    Inventors: Akio Sekimoto, Shinichi Yamada
  • Patent number: 6489380
    Abstract: Compositions having high moisture resistance and flexibility comprise an organic component and a filler. The organic component comprises a long-chain cycloaliphatic epoxy resin, a short-chain cycloaliphatic epoxy resin, a cyanate ester, and a Lewis acid catalyst. Preferably the organic component further comprises a Bronsted acid co-catalyst and/or a flexibilizing modifier. The compositions are useful in various semiconductor applications, including as die attach adhesives, underfills, encapsulants, via fills, prepreg binders, polymer solder masks and polymer bumps on flip chip or BGA assemblies.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: December 3, 2002
    Assignee: Johnson Matthey Electronics, Inc.
    Inventors: Xiao-Qi Zhou, Henry Wevick, Nancy E. Iwamoto, Shao Wei Li, Alan Grieve
  • Patent number: 6482899
    Abstract: A latent curing agent is disclosed for epoxy resin, comprising a reaction product obtainable by allowing (A) an epoxy compound having more than one epoxy groups on the average in the molecule and (B) a compound having in the molecule both a tertiary amino group and at least one functional group selected from the group consisting of OH group, SH group, NH group, NH2 group, COOH group and CONHNH2 group, to react on each other in the presence of 0.05-5.0 equivalents of water per 1 equivalent of the epoxy group of Compound (A); and a curable epoxy resin composition comprising such curing agent and an epoxy compound having more than one epoxy group on the average in the molecule.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: November 19, 2002
    Assignee: Ajinomoto Co., Inc.
    Inventors: Junji Ohashi, Tetsuo Hinoma
  • Patent number: 6467961
    Abstract: A lubricating coating compound used for forming a thermosetting synthetic resin lubricating film, wherein a resin composition composed of an epoxy resin, a curing agent, a reactive silicone oil with an epoxy group, and a triazinethiol is dissolved in an organic solvent, wherein if the sum of the epoxy resin and the curing agent is set to 100 parts by weight, the sum of the reactive silicone oil with an epoxy group and the triazinethiol is 2 to 30 parts by weight.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: October 22, 2002
    Assignee: Oiles Corporation
    Inventors: Takashi Nakamaru, Yoshiaki Yamamoto, Namiko Kaneko
  • Patent number: 6458917
    Abstract: An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.
    Type: Grant
    Filed: August 1, 2001
    Date of Patent: October 1, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroyuki Morijiri, Seiichi Kobayashi, Koju Okazaki, Chitoshi Shimakawa, Akinori Ryu, Yoshinobu Kanemura
  • Publication number: 20020120035
    Abstract: A resin composition used in an electrodeposition coating composition and containing an amine-modified vinyl resin (A) prepared by addition reaction of a secondary amine to an epoxy group-containing vinyl copolymer obtained by copolymerizing 2 to 30 parts by weight of an epoxy group-containing polymerizable unsaturated monomer (a-1) and 70 to 98 parts by weight of other polymerizable unsaturated monomer (a-2) copolymerizable with the monomer (a-1) by a catalytic chain transfer polymerization and having a weight average molecular weight of 2,000 to 20,000, and a blocked polyisocyanate (B).
    Type: Application
    Filed: December 26, 2000
    Publication date: August 29, 2002
    Inventors: Hidenori Sawada, Akihiko Shimasaki
  • Patent number: 6441060
    Abstract: The subject invention relates to a foundry binder system which cures in the presence of a volatile amine curing catalyst comprising (a) an epoxy resin, (b) an acrylated organic polyisocyanate, (c) a reactive unsaturated acrylic monomer, acrylic polymer, or mixtures thereof, and (d) an oxidizing agent comprising a hydroperoxide. The foundry binders are used for making foundry mixes. The foundry mixes are used to make foundry shapes which are used to make metal castings.
    Type: Grant
    Filed: September 14, 2000
    Date of Patent: August 27, 2002
    Assignee: Ashland Inc.
    Inventors: Don Greg Hendershot, Edward Gerard Toplikar, Laurence G. Dammann, Vincent J. Pascarella
  • Patent number: 6417322
    Abstract: The room temperature polymerizable composition comprises at least one polymerizable monomer having at least one episulfide functionality and an effective amount of at least one (alkoxyphenyl)phosphine polymerization catalyst.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: July 9, 2002
    Assignee: Essilor International Compagnie General d'Optique
    Inventors: Aref Ben Ahmed Jallouli, Gabriel Keita, Steven Weber, Yassin Turshani
  • Patent number: 6417316
    Abstract: Curable epoxy resin compositions, which are obtainable by heating a composition containing at least one epoxy compound, which contains on average at least one, preferably more than one, 1,2-epoxy group and optionally also one or several hydroxyl groups in the molecule, in the presence of at least one Lewis acid as catalyst, wherein the Lewis acid is a salt of trifluoromethanesulfonic acid or of perchloric acid, the counterion of which carries a 2- to 6-fold positive charge, until the epoxy value, measured in equivalent epoxy/kg (Eq/kg) of the starting material, has been reduced by 1 to 60 percent, preferably by 5 to 50 percent; a process for their preparation, and their use for the preparation of fully cured moulded compositions or coatings.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: July 9, 2002
    Assignee: Vantico Inc.
    Inventors: Rolf Wiesendanger, Walter Fischer
  • Patent number: 6403221
    Abstract: Epoxy resin compositions which comprise, as essential components, (A) an epoxy resin having two or more epoxy groups in one molecule, (B) a phenolic curing agent, (C) a phenoxy resin containing a bisphenol S skeleton and having a weight average molecular weight of 5,000 to 100,000, and (D) a curing accelerator, are useful for making adhesive films formed by coating the epoxy resin composition on a supporting base film. Such compositions are also useful for making prepregs, by coating and/or impregnating a sheet-shaped reinforced base material made of a fiber with the resin composition, as well as multilayer printed-wiring boards made with such prepregs. Such epoxy resin compositions are also useful for forming conductor layers with excellent adhesiveness without requiring, in the insulating layer, a roughening component which deteriorates performance, as well as multilayer printed-wiring boards.
    Type: Grant
    Filed: October 11, 2000
    Date of Patent: June 11, 2002
    Assignee: Ajinomoto Co., Inc.
    Inventors: Shigeo Nakamura, Tadahiko Yokota
  • Publication number: 20020061942
    Abstract: The object of the present invention is to provide resin compositions conferring cured materials (a coating or the like) with excellent appearance, excellent mechanical properties, or the like. The present invention provides resin compositions containing a vinyl copolymer with an epoxy group and a branched glutaric acid.
    Type: Application
    Filed: September 25, 2001
    Publication date: May 23, 2002
    Inventors: Toshikazu Murayama, Shigeru Murata, Shohei Konishi, Junichi Yamada, Makoto Goto
  • Patent number: 6388009
    Abstract: A low dielectric constant composition used in electric circuit boards is disclosed. The composition includes (a) 20-99.9 parts by weight of a functionalized syndiotactic styrene/para-alkystyrene copolymer having microfoaming when being cured; (b) 0.01-80 parts by weight of a mixture of epoxy resins; and (c) less than 50 parts by weight of a curing agent.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: May 14, 2002
    Assignee: Industrial Technology Research Institute
    Inventors: Wei-Han Liao, Hsien-Yin Tsai, In-Mau Chen
  • Patent number: 6388163
    Abstract: A method for rendering nondetonble energetic materials, such as are contained in or removed from decommissioned ordnance. The energetic materials are either combined with epoxy hardener or are combined with other compounds, preferably amine compounds, to form a substance that functions as an epoxy hardener. According to the invention, energetic materials (including TNT, RDX and Composition B) that are treated according to the invention method yield a reaction product that is non-explosive, that serves to harden or cure conventional epoxy resin to form a stable, nonexplosive waste product. Epoxy hardener made using the method of the invention is also described.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: May 14, 2002
    Assignee: Sandia Corporation
    Inventor: Maher E. Tadros
  • Patent number: 6379799
    Abstract: Resin systems containing a dicyclopentadiene-based epoxy resin and an ortho-alkylated aromatic diamine hardener exhibit low moisture absorption, high Tg and good retention of properties under hot and wet conditions. These properties make the resin systems especially useful in aerospace applications.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: April 30, 2002
    Assignee: Cytec Technology Corp.
    Inventor: Gregory R. Almen
  • Patent number: 6376053
    Abstract: An inter-laminar adhesive composition containing: (A) a liquid epoxy resin; (B) a polyfunctional epoxy resin having a softening point higher than a lamination temperature of the adhesive and with two or more epoxy groups within the molecule; and (C) a latent epoxy curing agent initiating a reaction at a temperature higher than the lamination temperature; wherein the adhesive composition optionally contains a liquid resin other than component (A) and/or an organic solvent and wherein the liquid resin including component (A), the organic solvent or both constitute from 10 to 55% by weight of the composition, and the use of this interlaminar adhesive composition to prepare a multilayer printed wiring board, and the process for preparing the multilayer printed wiring board are provided.
    Type: Grant
    Filed: November 27, 2000
    Date of Patent: April 23, 2002
    Assignee: Ajinomoto Co., Inc.
    Inventors: Shigeo Nakamura, Tadahiko Yokota
  • Patent number: 6361879
    Abstract: A sealed semiconductor chip having a surface film of a sealed resin composition, wherein the resin composition has a linear expansion coefficient of 60×10−6/K or less at a temperature equal to or less than its glass transition point and 140×10−6/K or less at a temperature equal to or higher than its glass transition point; a semiconductor-sealing resin composition for sealing a semiconductor chip, which has a linear expansion coefficient of 60×10−6/K or less at a temperature equal to or less than its glass transition point and 140×10−6/K or less at a temperature equal to or higher than its glass transition point; the sealed semiconductor chip is chip size and has high reliability; the semiconductor-sealing resin composition creates a good seal on chip wafers and has high reliability; and the chip wafers sealed with a surface film of the resin composition warp little.
    Type: Grant
    Filed: September 23, 1999
    Date of Patent: March 26, 2002
    Assignees: Toray Industries, Inc., Fujitsu Limited
    Inventors: Yasuaki Tsutsumi, Masayuki Tanaka, Toshimi Kawahara, Yukio Takigawa
  • Patent number: 6362255
    Abstract: It is an object of the present invention to provide a cationic electrodeposition coating composition which is free of toxic rust-preventive pigments such as lead compounds and capable of giving coating films having high resistance to corrosion and rusting, even when applied to a substrate surface which is only insufficiently subjected, to a chemical conversion treatment. The present invention provides a cationic electrodeposition coating composition which comprises a rust inhibitor comprising at least one compound selected from the group consisting of compounds containing any of elemental metals belonging to the period 4, 5 or 6 of group 3 of the periodic table and a sulfonium- and propargyl group-containing resin composition. For, example, the content of said rust inhibitor is 0.03 to 10 weight parts in terms of the elemental metal in the rust inhibitor based on 100 weight parts of the solid resins in the resin composition.
    Type: Grant
    Filed: February 16, 2001
    Date of Patent: March 26, 2002
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hiroyuki Sakamoto, Takayuki Kokubun, Kenichi Yoshizawa, Toshitaka Kawanami, Yoshiaki Okumura, Ichiro Kawakami
  • Patent number: 6350796
    Abstract: Two-component systems based on aqueous dispersions of hydrophilic epoxy adducts Ah having hydroxyl groups as reactive groups and unblocked difunctional or polyfunctional isocyanates B, said hydrophilic epoxy adducts Ah being selected from cationically stabilized hydrophilic epoxy adducts Ak, anionically stabilized hydrophilic epoxy adducts Aa and also nonionically stabilized epoxy adducts An and zwitterionically stabilized epoxy-amine adducts Aak.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: February 26, 2002
    Assignee: Vianova Resins AG
    Inventors: Gert Dworak, Martin Gerlitz, Roland Feola, Manfred Weinberger
  • Patent number: 6337384
    Abstract: A method of making a thermally-removable epoxy by mixing a bis(maleimide) compound to a monomeric furan compound containing an oxirane group to form a di-epoxy mixture and then adding a curing agent at temperatures from approximately room temperature to less than approximately 90° C. to form a thermally-removable epoxy. The thermally-removable epoxy can be easily removed within approximately an hour by heating to temperatures greater than approximately 90° C. in a polar solvent. The epoxy material can be used in protecting electronic components that may require subsequent removal of the solid material for component repair, modification or quality control.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: January 8, 2002
    Assignee: Sandia Corporation
    Inventors: Douglas A. Loy, David R. Wheeler, Edward M. Russick, James R. McElhanon, Randall S. Saunders
  • Patent number: 6316528
    Abstract: The present invention provides a thermosetting resin composition useful as an underfilling sealing resin which enables a semiconductor device, such as a CSP/BGA assembly which includes a semiconductor chip mounted on a carrier substrate, to be securely connected to a circuit board by short-time heat curing and with good productivity, which demonstrates excellent heat shock properties (or thermal cycle properties), and permits the CSP/BGA assembly to be easily removed from the circuit board in the event of semiconductor device or connection failure.
    Type: Grant
    Filed: July 8, 1999
    Date of Patent: November 13, 2001
    Assignee: Loctite (R&D) Limited
    Inventors: Kazutoshi Iida, Jon Wigham
  • Patent number: 6300464
    Abstract: An optical resin prepared by curing a polymerizable composition comprising a (thio)epoxy compound having at least one intramolecular disulfide bond exhibits a considerably high refractive index while maintaining good optical properties and a high Abbe number. In addition, the above polymerizable composition to which is added primary and/or secondary amines as an yellowing inhibitor in a proportion of 0.001 to 0.5 of the total molar number of NH2 and NH groups in the amines to the total molar number of thioepoxy and epoxy groups in the (thio)epoxy compound having at least one intramolecular disulfide bond, can provide a transparent resin in which yellowing and reduction in heat resistance associated therewith are adequately prevented while maintaining a high refractive index.
    Type: Grant
    Filed: December 26, 2000
    Date of Patent: October 9, 2001
    Assignee: Mitsui Chemical, Inc.
    Inventors: Hiroyuki Morijiri, Seiichi Kobayashi, Koju Okazaki, Chitoshi Shimakawa, Akinori Ryu, Yoshinobu Kanemura
  • Patent number: 6288176
    Abstract: An agent for the single-stage full blocking of polyisocyanates comprises or consists of an alcohol mixture A) comprising a) furfuryl alcohol or substituted furfuryl alcohols in an amount corresponding to from 60 to 90, in particular from 65 to 85, mol % of hydroxyl groups and b) at least one monoalcohol in an amount corresponding to at least 2 mol % of hydroxyl groups, based in each case on the total amount of hydroxyl groups in components a) and b). In addition, the alcohol mixture A) may also include at least one aliphatic polyol c) of low molecular mass with a functionality of three and/or more in an amount corresponding to at least 5 mol % of hydroxyl groups, based on the total amount of hydroxyl groups in components a), b) and c). In this case component b) can have a molecular weight of <163 g/mol.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: September 11, 2001
    Assignee: BASF Coatings AG
    Inventors: Bing Hsieh, Silke Przybilla, Ingeborg Grempels, Walter Jouck, Hardy Reuter, Dagmar Schemschat, Oliver Johannpoetter, Walburga Kathmann, Adam Stals
  • Patent number: 6277903
    Abstract: The invention is a sprayable coating having noise vibration and harshness reduction or absorption properties. Such composition comprises from about 10 to about 60 percent of the flexible epoxy resin, from about 5 to about 40 percent by weight of a rigid epoxy resin formulation, and a curing agent for the epoxy moieties of the two resins. In another embodiment, the invention is a method of coating a substrate to reduce the impact of noise vibration and harshness on the substrate or users of the substrate, which process comprises spraying the above defined composition on to a substrate and curing the resin on such substrate. In yet another embodiment the invention is a coated substrate described herein before having enhanced noise vibration and harshness properties.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: August 21, 2001
    Assignees: The Dow Chemical Company, Essex Specialty Products, Inc.
    Inventors: Daniel P. Sophiea, Dwight K. Hoffman, Xiao Hong, Gloria Hsu
  • Patent number: 6274649
    Abstract: The present invention relates to an aqueous binder dispersion for cathodic electrodeposition coatings obtained A) by reacting I. a precursor prepared at temperatures of from 120 to 180° C. from a) a diepoxide compound or a mixture of diepoxide compounds and b) an aromatic or aliphatic compound hydroxyl, carboxyl, phenol and/or thiol groups, or a mixture of such compounds with reaction of the phenolic hydroxyl groups with epoxide groups, II. with at least one organic amine or a mixture of organic amines at a temperature between 60 and about 130° C. to give an epoxide/amine adduct; B) subsequently or simultaneously reacting at least one secondary hydroxyl group of the precursor with an unreacted epoxide group of the epoxide/amine adduct prepared in step A) at a temperatures of from about 110 to about 150° C.; C) adding a crosslinking agent at a temperature of less than about 150° C.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: August 14, 2001
    Assignee: BASF Coatings AG
    Inventors: Günther Ott, Hardy Reuter, Walter Jouck, Thierry Herning, Susanne Piontek, Ulrich Heimann, Karl-Heinz Grosse-Brinkhaus
  • Patent number: 6258919
    Abstract: A curable composition is described, comprising a) 10 to 90% by weight of at least one, optionally water-dilutable, water-emulsifiable or water-dispersible, epoxy resin having more than one epoxy group in the molecule; b) 90 to 10% by weight of at least one polyamine adduct which predominantly corresponds to the idealised formula (I) and which is prepared from an adduct of formula (A) and a polyamine of formula (XII), wherein the sum of the percentages by weight of components (a) and (b) is always 100%; c) optionally, at least one further aliphatic, cycloaliphatic, aromatic/aliphatic, aromatic or heteroaromatic mono- or polyamine which may optionally be modified by adduction; and d) optionally, at least one customary additive, R1 and R2 and also m and n and B being defined in more detail in the description. The novel compositions are used for the preparation of colourants and coatings.
    Type: Grant
    Filed: September 3, 1998
    Date of Patent: July 10, 2001
    Assignee: Vantico Inc.
    Inventors: Thomas Vogel, Alex Wegmann
  • Patent number: 6248204
    Abstract: The present invention provides a room-temperature curable, reinforced thermosetting epoxy resin composition. The composition includes an epoxy resin first component, and an epoxy resin hardener second component. The epoxy resin component includes an epoxy resin, and may further include an inorganic and/or organic filler component, such as a structural reinforcement component. The epoxy resin hardener component includes an amine-based hardener, and may further include an inorganic and/or organic filler component. Cured reaction products of the composition demonstrate at about room temperature an adhesive strength of at least about 6500 psi, such as about 8000 to about 10000, and a fracture toughness of at least about 10 in-lbs/in2, such as about 20 to about 35 in-lbs/in2. In addition, the cured reaction products of the composition demonstrate a creep resistance at about room temperature at least about 6000 psi of at least about 1 hour.
    Type: Grant
    Filed: May 14, 1999
    Date of Patent: June 19, 2001
    Assignee: Loctite Corporation
    Inventor: Charles F. Schuft
  • Patent number: 6245836
    Abstract: A lubricating coating compound used for forming a thermosetting synthetic resin lubricating film, wherein a resin composition composed of an epoxy resin, a curing agent, a reactive silicone oil with an epoxy group, and a triazinethiol is dissolved in an organic solvent, wherein if the sum of the epoxy resin and the curing agent is set to 100 parts by weight, the sum of the reactive silicone oil with an epoxy group and the triazinethiol is 2 to 30 parts by weight.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: June 12, 2001
    Assignee: Oiles Corporation
    Inventors: Takashi Nakamaru, Yoshiaki Yamamoto, Namiko Kaneko
  • Patent number: 6245828
    Abstract: The present invention is directed to polymerizable dental compositions containing a) 3 to 80 wt. % of cycloaliphatic epoxides; b) 0 to 80 wt. % of an epoxide or a mixture of epoxides which are different from a); c) 3 to 85 wt. % of a filer material; d) 0.01 to 25 wt. % of initiators, inhibitors and/or accelerators; e) 0 to 25 wt. % of auxiliary agents, the individual percentages of which are in relation to the total weight. The new polymerizable agents are particularly suited as dental material.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: June 12, 2001
    Assignee: ESPE Dental AG
    Inventors: Wolfgang Weinmann, Oswald Gasser, Rainer Guggenberger, Gunther Lechner, Wolfgang Soglowek, Joachim Zech
  • Patent number: 6235842
    Abstract: The present invention provides a phase-separation structure comprising a phenoxy resin modified with a carboxylated elastomer, prepared from a phenoxy resin and a carboxylated elastomer, the resin and the elastomer constituting a phase-separation structure, wherein the light transmittance of the structure in a 75 &mgr;m-thick film form at a wavelength of 500 nm is not less than 10% of the light transmittance of the air, which is useful as adhesives, film materials, and molding materials for encapsulating electronic components.
    Type: Grant
    Filed: June 7, 1999
    Date of Patent: May 22, 2001
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Atsushi Kuwano, Shinsuke Hagiwara
  • Patent number: 6225376
    Abstract: An emulsified reactive epoxy polymer composition which is readily dispersed in water and is particularly suited for use in a coating composition which may be cured at ambient temperatures. The emulsifiable epoxy composition incorporates a hydrophilic polyoxyalkylene segment.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: May 1, 2001
    Assignee: The Dow Chemical Company
    Inventors: Dieter H. Klein, Karin C. Joerg
  • Patent number: 6221980
    Abstract: A latent curing agent is disclosed for epoxy resin, comprising a reaction product obtainable by allowing (A) an epoxy compound having more than one epoxy groups on the average in the molecule and (B) a compound having in the molecule both a tertiary amino group and at least one functional group selected from the group consisting of OH group, SH group, NH group, NH2 group, COOH group and CONHNH2 group, to react on each other in the presence of 0.05-5.0 equivalents of water per 1 equivalent of the epoxy group of Compound (A); and a curable epoxy resin composition comprising such curing agent and an epoxy compound having more than one epoxy group on the average in the molecule.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: April 24, 2001
    Assignee: Ajinomoto Co., Inc.
    Inventors: Junji Ohashi, Tetsuo Hinoma
  • Patent number: 6207731
    Abstract: A cathodic electrocoating composition comprises an aqueous carrier, a film forming binder, comprising an epoxy-amine adduct and a blocked polyisocyanate crosslinking agent, dispersed in the carrier, and a novel additive comprising the reaction product of (1) a polyoxy alkylene di or monoamine; (2) a glycidoxy alkyl alkoxy silane; and (3) a glycidyl compound selected from the group consisting of a glycidyl ester of a carboxylic acid and an alkyl glycidyl ether, which reaction product is hydrolyzed in the presence of acid and water to convert alkoxysilane moieties to silanol moieties. The electrocoat composition produces coatings having a smoother appearance with better edge coverage and fewer craters.
    Type: Grant
    Filed: September 23, 1999
    Date of Patent: March 27, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Allisa Gam
  • Patent number: 6201074
    Abstract: Epoxy resin mixtures suitable for producing halogen-free flame-retardant composites by the injection process comprise the following components: (A) a phosphorus-free aliphatic and/or aromatic and/or heterocyclic epoxy resin; (B) an epoxide group-containing phosphorus compound; (C) a phosphorus-modified epoxy resin with an epoxide value of from 0.02 to 1 mol/100 g, obtained by reacting polyepoxy compounds having at least two epoxide groups per molecule with phosphinic anhydrides and/or phosphonic anhydrides or with phosphonic monoesters, followed by thermal elimination of alcohol; and (D) as hardener, at least one primary or secondary aliphatic polyamine with NH and/or NH2 groups.
    Type: Grant
    Filed: July 1, 1999
    Date of Patent: March 13, 2001
    Assignee: Siemens Aktiengesellschaft
    Inventors: Wolfgang Von Gentzkow, Dieter Heinl, Heinrich Kapitza, Michael Schreyer
  • Patent number: 6180753
    Abstract: An acidic substance is added to a mixture containing a compound having epithio structures and a catalyst for curing the compound and the mixture is solidified. The mixture containing a compound having epithio structures and a catalyst for curing the compound can be mildly solidified for disposal.
    Type: Grant
    Filed: August 12, 1999
    Date of Patent: January 30, 2001
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Akikazu Amagai, Motoharu Takeuchi
  • Patent number: 6176965
    Abstract: A bonded structure of an Al alloy pressed plate, in which another member is bonded onto the surface of the Al alloy pressed plate that has a lubricant layer by use of an epoxy resin based adhesive. The adhesive contains an epoxy resin, a dehydrated phosphate and a latent curing agent. The epoxy resin comprises a polyester type epoxy resin and at least one resin selected from the group consisting of a bisphenol epoxy resin, a rubber-modified bisphenol epoxy resin, and a urethane-modified epoxy resin.
    Type: Grant
    Filed: June 25, 1993
    Date of Patent: January 23, 2001
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Kazuyuki Okui, Makoto Shiokawa
  • Patent number: 6143809
    Abstract: A process to provide an aqueous dispersion is provided comprising the steps of:a) emulsifying a mixture comprisingi) water,ii) at least one epoxy resin having a functionality of greater than 0.8 epoxide group per molecule,iii) from 0.1 to 20 weight percent, based on the epoxy resin, of at least one polyoxyalkylene surfactant, andiv) optionally an acetone-free solvent solution to produce a resin-surfactant emulsion; andb) adding a solvent mixture to said resin-surfactant emulsion, said solvent mixture comprising i) acetone and ii) a non-volatile hydrophobic liquid resin or resin modifier to produce the aqueous dispersion.
    Type: Grant
    Filed: July 17, 1998
    Date of Patent: November 7, 2000
    Assignee: Shell Oil Company
    Inventors: Jimmy D. Elmore, Vincent James Maksymowski, Richard William Henning, Jr., Ernest Charles Galgoci, Jr.
  • Patent number: 6117953
    Abstract: A liquid epoxy resin composition comprising (A) an epoxy resin component which includes specific amounts of three specific epoxy resins, (B) a curing agent, (C) a curing accelerator, and (D) an inorganic filler has a low viscosity, high cure rate, ease of processing, reliability, and shelf stability. The composition can be used as a semiconductor device encapsulant to provide BGA packages having minimal warpage.
    Type: Grant
    Filed: January 21, 1999
    Date of Patent: September 12, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Nobuhiro Ichiroku, Toshio Shiobara
  • Patent number: 6087444
    Abstract: A water reducible polyurethane resin for use in coating compositions is provided with humidity resistance at relatively low cost by employing a urethane prepolymer which is the reaction product of (i) a polyisocyanate, (ii) a polyhydroxy compound which is the reaction product of an organic acid and an epoxy compound, at least one of which includes a hydrocarbon group of at least six carbon atoms, and (iii) a monomer having an anionic group and functionality reactive with isocyanate. Preferred embodiments employ C.sub.36 dimer diacid and the propylene oxide ester of neodecanoic acid to make the polyhydroxy compound.
    Type: Grant
    Filed: September 20, 1996
    Date of Patent: July 11, 2000
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Shanti Swarup, Anbazhagan Natesh, Gina M. Terrago, Cathy A. Taylor
  • Patent number: 6075082
    Abstract: A method for binding ceramic materials in aqueous media is disclosed. The method utilizes water-soluble cross-linked polyamides prepared by condensation polymerization for binding various classes of ceramic materials.
    Type: Grant
    Filed: September 29, 1998
    Date of Patent: June 13, 2000
    Assignee: Nalco Chemical Company
    Inventors: David P. Workman, Kristy M. Bailey, Kevin J. Moeggenborg
  • Patent number: 6060539
    Abstract: A flexible thermally-conductive epoxy-based adhesive composition and method for making the same are provided. The present adhesive composition comprises (a) a polymer mixture comprising at least one polyepoxide resin having a hardness not exceeding a durometer Shore D reading of about 45, when cured with a stoichiometric amount of diethylene triamine ("DETA"), and a substantially stoichiometric amount of at least one latent epoxy resin curing agent; and (b) a thermally-conductive filler. Optional components include secondary epoxy resins, non-reactive flexibilizers, diluents, and processing aids. The present adhesive composition is rheologically stable for weeks or even months at room temperature and is curable in less than one hour at a temperature ranging from about 100.degree. C. to 140.degree. C., whereupon the cured adhesive composition exhibits a durometer Shore A of less than about 90 and a thermal conductivity exceeding 0.4 BTU/hr-ft-.degree. F. (0.7 W/m-K).
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: May 9, 2000
    Assignee: Raytheon Company
    Inventors: Ralph D. Hermansen, Steven E. Lau
  • Patent number: 6057402
    Abstract: Compositions having high moisture resistance and flexibility comprise an organic component and a filler. The organic component comprises a long-chain cycloaliphatic epoxy resin, a short-chain cycloaliphatic epoxy resin, a cyanate ester, and a Lewis acid catalyst. Preferably the organic component further comprises a Bronsted acid co-catalyst and/or a flexibilizing modifier. The compositions are useful in various semiconductor applications, including as die attach adhesives, underfills, encapsulants, via fills, prepreg binders, polymer solder masks and polymer bumps on flip chip or BGA assemblies.
    Type: Grant
    Filed: August 12, 1998
    Date of Patent: May 2, 2000
    Assignee: Johnson Matthey, Inc.
    Inventors: Xiao-Qi Zhou, Henry Wevick, Nancy E. Iwamoto, Shao Wei Li, Alan Grieve
  • Patent number: 6054509
    Abstract: Provided by the invention is a thermosetting adhesive composition suitable for use in the preparation of metal foil-laminated base sheets of flexible printed circuit boards and laminated product related thereto such as coverlay films and bonding sheets. The adhesive composition is a uniform blend which comprises: (A) an epoxy resin including a brominated epoxy resin to exhibit flame retardancy; (B) a combination of two or three kinds of different nitrile rubbers distinguishable relative to the iodine value and content of carboxyl groups at the molecular chain ends in a specified weight proportion; (C) a curing agent for the epoxy resin; and (D) a curing accelerator, with optional admixture of (E) an inorganic filler; and/or (F) a vulcanizing agent for the nitrile rubbers.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: April 25, 2000
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hitoshi Arai, Masahiro Yuyama, Yoshitsugu Eguchi
  • Patent number: 6046257
    Abstract: A composition is useful as a prepreg containing reinforcing fibers comprises an epoxy resin, a thermoplastic elastomer of a polyamide and/or polyester block copolymer, a curing agent such as dicyandiamide, and optionally a thermoplastic resin such as a polyvinyl formal resin.
    Type: Grant
    Filed: March 18, 1996
    Date of Patent: April 4, 2000
    Assignee: Toray Industries, Inc.
    Inventors: Hiroki Oosedo, Shunsaku Noda
  • Patent number: 6045857
    Abstract: Unsaturated hydrophobic resins modified with labile hydrophillic groups exhibit reversible solubility in water. Beta-dialkyl amino carboxylate derivatives of novolak resins are useful to make baking enamels and resists.
    Type: Grant
    Filed: June 19, 1997
    Date of Patent: April 4, 2000
    Assignee: MacDermid Acumen, Inc.
    Inventor: Goutam Gupta