Two Or More Carbon Atoms Patents (Class 524/300)
  • Patent number: 5486561
    Abstract: There is disclosed a polypropylene resin composition which comprises (a) polypropylene; (b) ethylene/.alpha.-olefin copolymer elastomer having a specific range of Mooney viscosity; (c) modified polyolefin having a specific functioal group at either or both end thereof; and (d) specific compound such as stearic acid monoglyceride, stearyl diethanolamine, N-diethanol stearylamide and N-diethanol dodecanaeamide. The above composition is excellent in elasticity, peeling strength and recoating properties, can be painted immediately after degreasing without pretreatment with trichloroethane, etc. and is well suited for polypropylene bumper materials to be painted, etc.
    Type: Grant
    Filed: April 21, 1993
    Date of Patent: January 23, 1996
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Koki Hirano, Ryuichi Ohki, Yutaka Kobayashi
  • Patent number: 5449711
    Abstract: Blooming on the surface of products molded from an olefinic thermoplastic elastomer composition containing an olefinic thermoplastic elastomer and one or more additives which promotes such blooming is prevented by compounding into the elastomer one or more compounds selected from the group consisting of esters of polyhydric alcohols, alkylalkanolamines, alkylalkanolamides, fatty acid amides, higher alcohols, aliphatic amines, fatty acids and adducts of alkylene oxides to these compounds. The composition thus can be advantageously used as interior materials of automobiles and materials for electronic instruments.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: September 12, 1995
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Nobuo Saito, Yoshihiro Shigemori, Mitsuo Noda, Jun-ichi Itou
  • Patent number: 5436288
    Abstract: A conductive silicone rubber composition comprising (A) an organopolysiloxane, (B) conductive carbon black, and (C) an organic peroxide is improved in shelf stability by adding (D) a fatty acid or an acid anhydride thereto. The composition is subject to atmospheric hot air vulcanization to form a conductive silicone rubber having improved conductivity and physical properties.
    Type: Grant
    Filed: July 20, 1992
    Date of Patent: July 25, 1995
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masaharu Takahashi, Tomiyoshi Tsuchida
  • Patent number: 5432220
    Abstract: It is herein disclosed a process for stabilizing freshly prepared polyketone polymer comprising the step of contacting said polymer with a stabilizing agent selected from the group consisting of acidic water and an inorganic phosphate compound in water. The inventive process results in stabilized polyketone polymers having and exhibiting improved thermal oxidative and melt stability properties.
    Type: Grant
    Filed: August 13, 1993
    Date of Patent: July 11, 1995
    Assignee: Shell Oil Company
    Inventor: Carlton E. Ash
  • Patent number: 5420185
    Abstract: A bow-tie tree resistant electrical insulating composition comprises 100 parts by weight of at least one polymer selected from polyolefins and ethylene copolymers, 0.005-1.0 part by weight of a metal salt of a fatty acid containing a hydroxyl group in the molecule, and 0.005-1.0 part by weight of a fatty acid or a derivative thereof.
    Type: Grant
    Filed: September 14, 1994
    Date of Patent: May 30, 1995
    Assignee: Hitachi Cable Ltd.
    Inventors: Kiyoshi Watanabe, Takanori Yamazaki, Hideki Yagyu, Mamoru Kanaoka, Katsutoshi Hanawa, Chuki Ikeda
  • Patent number: 5399611
    Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.
    Type: Grant
    Filed: September 27, 1993
    Date of Patent: March 21, 1995
    Assignee: The Sherwin-Williams Company
    Inventor: John Mathai
  • Patent number: 5399192
    Abstract: Aluminum or aluminum alloy substrates are coated with primer coating chemicals and topcoating chemicals for forming a cured primer coat having lubricating and hydrophilic properties. The primer coating chemicals contains a thermosetting water-soluble or water-dispersible resin component (A), and the topcoating chemicals contains a resin component (C) containing a carboxymethylcellulose derivative and N-methylolacrylamide. At least one of them further contains a lubricant (B) selected from the group consisting of a higher aliphatic acid lubricant and an inorganic lubricant.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: March 21, 1995
    Assignee: Nippon Paint Co., Ltd.
    Inventor: Katsuyoshi Yamasoe
  • Patent number: 5397823
    Abstract: A functional film-forming paste composition is disclosed, comprising (a) at least one metal-containing organic compound and at least one of (b) an acrylic resin, (c) an unsaturated fatty acid, and (d) an organic acid ester or phosphoric ester, the components (a) to (d) being dissolved in an organic solvent. The paste composition can be calcined at a low temperature, undergoes no change with time, can be printed by any printing method, exhibits good adhesion to a substrate, and gives a film free from unevenness in thickness and from defects such as cracks and pinholes.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: March 14, 1995
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Kaoru Torikoshi
  • Patent number: 5395870
    Abstract: There are disclosed a vinyl resin composition which comprises a resin composition comprising a vinyl polymer, a polyamideimide elastomer obtained by reacting a mixture of caprolactam, an aromatic polycarboxylic acid and a specified polyoxyethylene glycol, with 0-0.5 mole of a diamine, etc., per 1 mole of glycol contained in said mixture, the glycol component being present in a proportion of 85-30% by weight in said elastomer and the relative viscosity of the elastomer being at least 1.5 (at 30.degree. C.), and an electrolyte added as desired, and articles molded from the composition.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: March 7, 1995
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Yoshio Suzuki, Masashi Sakamoto
  • Patent number: 5371177
    Abstract: A process is provided for preparing polysuccinimides by forming a polymerization mixture of poly(alkylene glycol), maleamic acid and, optionally one or more other amic acids, heating the mixture to an elevated temperature, and maintaining the mixture at the elevated temperature to form polysuccinimides.
    Type: Grant
    Filed: July 10, 1992
    Date of Patent: December 6, 1994
    Assignee: Rohm and Haas Company
    Inventors: Yi H. Paik, Ethan S. Simon, Graham Swift
  • Patent number: 5350790
    Abstract: This invention provides a polycarbonate resin composition for optical use and an optical disc substrate manufactured therefrom. Polycarbonate resin is mixed with at least one kind of carboxylic acid selected from aliphatic carboxylic acids having 1 to 10 carbon atoms in which hydrogen atoms of aliphatic group may be substituted by hydroxyl groups; or aromatic carboxylic acids in which hydrogen atoms of the aromatic ring may be substituted by low alkyl groups, hydroxyl groups, or halogen atoms.The amount of the carboxylic acids is 5 to 1000 ppm based on the polycarbonate resin.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: September 27, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshitomi Urabe, Hironori Hayashida, Yoshiaki Ohtani
  • Patent number: 5346737
    Abstract: Incorporation of at least one lubricant and an ethylene-based polymer of the formula E/X/Y wherein E is ethylene, X is methyl acrylate, butyl acrylate, or ethyl acrylate, and Y is glycidyl methacrylate, glycidyl acrylate, or glycidyl vinyl ether into polyacetal compositions results in compositions having good wear resistance and good melt processing thermal stability. The compositions are useful, for example, when molded into parts to be used in sliding applications, such as gears, cams, and conveyor chains.
    Type: Grant
    Filed: July 16, 1993
    Date of Patent: September 13, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Tatsu-Hiro Takahashi, Toshikazu Kobayashi
  • Patent number: 5306566
    Abstract: The method of inhibiting the reduction of the bond strength by water of a metal-thermoplastic polymer-metal sandwich, where the thermoplastic core contains carbon to carbon double bonds, by incorporating 0.01 to 1.0% of a fatty acid component which comprises at least one fatty acid as an additive.
    Type: Grant
    Filed: October 8, 1992
    Date of Patent: April 26, 1994
    Assignee: Hoogovens Groep B.V.
    Inventor: Jan Bottema
  • Patent number: 5296522
    Abstract: Carboxylic acids of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 independently of one another are each hydrogen, hydroxyl, carboxyl or C.sub.1 -C.sub.6 -alkyl and x, y and z independently of one another are each 0 or an integer of from 1 to 6, and/or their anhydrides can permanently suppress the formation of water trees in electrical medium and high voltage cables which contain electrically insulating and/or electrically semiconductive layers based on ethylene homopolymers and/or copolymers, even when the relevant layers contain water-soluble basic salts. Accordingly, polymeric mixtures based on ethylene homopolymers and/or copolymers which contain the above-mentioned carboxylic acids I and/or their anhydrides are very useful for the production of electrically insulating and electrically semiconductive layers as used in electrical medium and high voltage cables.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: March 22, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Heinz Vogt, Ingolf Hennig, Johannes Schlag, Thomas Muehlenbernd
  • Patent number: 5270370
    Abstract: Evolution of phosphine from red phosphorus is reduced by means of acyclic, aliphatic compounds having at least one carbon-to-carbon double bond, in the alpha-position relative to an electron-withdrawing group. A preferred example of such a compound is trans-cinnamaldehyde.
    Type: Grant
    Filed: September 21, 1992
    Date of Patent: December 14, 1993
    Assignee: Albright & Wilson Limited
    Inventors: Colin A. Chilles, Tom Dutton, Mohsen Zakikihani, Simon J. Oakley
  • Patent number: 5254614
    Abstract: This invention provides a polycarbonate resin composition for optical use and an optical disc substrate manufactured therefrom. Polycarbonate resin is mixed with at least one kind of carboxylic acid selected from aliphatic carboxylic acids having 1 to 10 carbon atoms in which hydrogen atoms of aliphatic group may be substituted by hydroxyl groups; or aromatic carboxylic acids in which hydrogen atoms of the aromatic ring may be substituted by low alkyl groups, hydroxyl groups, or halogen atoms.The amount of the carboxylic acids is 5 to 1000 ppm based on the polycarbonate resin.
    Type: Grant
    Filed: May 22, 1991
    Date of Patent: October 19, 1993
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshitomi Urabe, Hironori Hayashida, Yoshiaki Ohtani
  • Patent number: 5248717
    Abstract: This invention relates to novel hydroxy-functional polyester diluents, and more particularly, to acrylic-modified hydroxy-functional polyester reactive diluents useful for blending with a variety of thermosetting or thermoplastic film-forming polymers. More specifically, the hydroxy-functional polyester reactive diluents are essentially low molecular weight polyesters derived from triols, and a combination of unsaturated monocarboxylic acids and saturated monocarboxylic acids. These hydroxy-functional polyester diluents may be copolymerized with one or more acrylic monomers, i.e. hydroxy-functional acrylic monomers, and blended with a variety of thermosetting or thermoplastic film-forming polymers. These blends of the film-forming polymers and the hydroxy-functional polyester diluents can be crosslinked with conventional crosslinking agents such as isocyanates and used in the formulation of low VOC paint compositions particularly useful as automotive topcoats.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: September 28, 1993
    Assignee: The Sherwin-Williams Company
    Inventor: John Mathai
  • Patent number: 5238986
    Abstract: The composition of the present invention is composed of finely divided solid refractory material suspended in a nonaqueous liquid slip composition. The nonaqueous liquid slip composition consists essentially of a deflocculent composed of a vinyl chloride and vinyl acetate resin dissolved in an organic solvent. The composition may be slip cast or cold formed into a low density article which is then sintered into a dense product.
    Type: Grant
    Filed: February 21, 1992
    Date of Patent: August 24, 1993
    Assignee: Praxair S.T. Technology, Inc.
    Inventor: Lionel C. Montgomery
  • Patent number: 5213898
    Abstract: Method for surface modifying substrates characterized in adsorbing on the surface of a solid substrate a polyamine of a high average molecular weight and cross-linking this with crotonaldehyde either simultaneously or by addition in separate steps to produce amino groups on the surface of the substrate, and optionally adsorbing one or several alternating layers of an anionic polysaccharide and of the said polyamine being cross-linked with crotonaldehyde, and optionally finally adsorbing the said polyamine, not cross-linked, to produce free primary amino groups by which chemical entities having a biological activity may be bound by covalent or ionic bonding.
    Type: Grant
    Filed: June 14, 1991
    Date of Patent: May 25, 1993
    Assignee: Norsk Hydro a.s.
    Inventors: Karl O. P. Larm, Lars A. Adolfsson, Kjell P. Olsson
  • Patent number: 5214092
    Abstract: Impact-resistant compositions based on vinyl chloride polymers and their use for profile extrusion, comprising, by way of vinyl chloride polymers: (a) from 40 to 60 parts of graft copolymer of vinyl chloride with lightly crosslinked polybutyl acrylate, (b) from 10 to 50 parts of graft copolymer of vinyl chloride with an ethylene/vinyl acetate copolymer and (c) from 10 to 50 parts of unmodified vinyl chloride polymer per 100 parts by weight in total of vinyl chloride polymers, as well as, by way of a reinforcing filler, (d) from 4 to 10 parts of calcium carbonate in fatty acid-coated particles of average diameter less than 1 .mu.m per 100 parts by weight of vinyl chloride polymers.
    Type: Grant
    Filed: January 28, 1992
    Date of Patent: May 25, 1993
    Assignee: Solvay S.A.
    Inventors: Daniel Gloesener, Philippe Lamberty
  • Patent number: 5212223
    Abstract: An extrudable composition comprised of waste polyolefins and an alkali metal bicarbonate salt/solid, saturated fatty acid foaming agent system, and a method for extruding such extrudable composition wherein the fatty acid/bicarbonate foaming agent system foams the waste polyolefins during the extrusion to produce end products which have qualities closely simulating natural lumber suitable for use as construction materials.
    Type: Grant
    Filed: March 5, 1991
    Date of Patent: May 18, 1993
    Assignee: Polymerix, Inc.
    Inventors: Wolfgang A. Mack, Peter J. Canterino
  • Patent number: 5196469
    Abstract: A semi-aqueous ethylene-vinyl alcohol coating composition that is a stable, homogeneous solution which is capable of being easily applied to a substrate to form a multi-layer structure at room temperature, by spray, rod, gravure, or other mechanical means. Upon evaporation of the volatile components, this coating solution leaves a clear, homogeneous film comprising EVOH. The film resists degradation and discoloration during the lifetime of the structure, and upon incineration or recycling does not evolve harmful acids into the environment.
    Type: Grant
    Filed: March 28, 1991
    Date of Patent: March 23, 1993
    Assignee: Mica Corporation
    Inventors: Virginia P. Cushing, Daniel Siegel
  • Patent number: 5194474
    Abstract: Provided are compositions comprising a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 20 to 80 mol % and a saponification degree of vinyl acetate component of at least 95 mol %, said composition containing 20 to 200 ppm as converted to alkali metal of an alkali metal acetate, 30 to 250 ppm of acetic acid, and 5 to 500 ppm as converted to phosphate ion of phosphoric acid or an alkali metal hydrogenphosphate, and having a content ratio of acetic acid/alkali metal acetate of 0.1 to 1 and the flow characteristic that the extrusion rate does not substantially increase for at least 10 hours in the relationship between the heating time and the extrusion rate with a capillary rheometer (Koka Flow Tester) at at least one temperature 10.degree. to 80.degree. C. above the melting point.
    Type: Grant
    Filed: February 27, 1990
    Date of Patent: March 16, 1993
    Assignee: Kuraray Co., Ltd.
    Inventors: Akimasa Aoyama, Tetsuya Katayama, Takeshi Moritani, Junnosuke Yamauchi, Satoshi Hirofuji
  • Patent number: 5182323
    Abstract: A pressure sensitive hot melt adhesive contains thermoplastic rubber such as styrene isoprene copolymer, a copolymer of vinylpyrrolidone and vinylacetate, fatty acid and, usually, tackifying resin. The composition is water soluble or water dispersible which facilitates removal of labels by washing and recycling of scrap material in label production. The composition gives better properties, especially peel strength, than other water-soluble or dispersible hot melt compositions.
    Type: Grant
    Filed: May 28, 1991
    Date of Patent: January 26, 1993
    Assignee: ISP Investments Inc.
    Inventor: Gary S. Russell
  • Patent number: 5164437
    Abstract: The water leaching of ammonium polyphosphate from compositions comprising organic polymer and particles of ammonium polyphosphate is reduced if the ammonium polyphosphate is surface-modified with anionic surfactant selected from fatty acids containing from about 12 to about 32 carbon atoms, bivalent metal salts of such fatty acids, trivalent metal salts of such fatty acids, and mixtures thereof.
    Type: Grant
    Filed: October 30, 1990
    Date of Patent: November 17, 1992
    Assignee: PPG Industries, Inc.
    Inventors: Paritosh M. Chakrabarti, Kenneth J. Sienkowski
  • Patent number: 5118744
    Abstract: A methacrylic resin cast plate having an excellent antistatic property comprises (A) 100 weight parts of a polymer comprising 50 to 100 weight % of methyl methacrylate units and 0 to 50 weight % of copolymerizable monomer units and (B) 0.1 to 20 weight parts of a polymer comprising 20 to 100 weight & of units derived from a monomer having a quaternary ammonium base, which is represented by the formula (I): ##STR1## wherein R.sub.1 is H or CH.sub.3, R.sub.2 through R.sub.4 are H or (C1-9) alkyl which may have a substituent, m is from 1 to 10 and X.sup.- is an anion of a quaternizing agent, and 0 to 80 weight % of copolymerizable monomer units. The cast plate is obtained by polymerizing methyl methacrylate, a monomer mixture comprising at least 50 weight & of methyl methacrylate and up to 50 weight % of a copolymerizable monomer or a partial polymerization product thereof in the presence of the polymer (B).
    Type: Grant
    Filed: March 26, 1990
    Date of Patent: June 2, 1992
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Kiyotaka Azegami, Suehiro Tayama, Naoki Yamamoto, Akira Yanagase, Hiroki Hatakeyama
  • Patent number: 5118743
    Abstract: This invention provides an ethylene-vinyl alcohol copolymer composition having specific flow characteristics in the relationship between the heating time and the extrusion rate measured with a capillary rheometer (Koka Flow Tester), and a multilayered structure utilizing the same.From the EVOH composition according to the present invention, can be obtained a molded article, particularly a multilayered structure, having an excellent appearance; more particularly, in a continuous melt molding operation over a long period, a molded article, particularly a multilayered structure, having an excellent appearance can always be obtained without worsening the appearance with running time.
    Type: Grant
    Filed: August 31, 1988
    Date of Patent: June 2, 1992
    Assignee: Kuraray Co., Ltd.
    Inventors: Kiyoshi Yonezu, Akimasa Aoyama, Takuji Okaya, Satoshi Hirofuji, Yukio Ozeki
  • Patent number: 5112894
    Abstract: A composition comprises a carboxylic acid compound which contains at least three carbon atoms together with an organic sulphur-containing acid or salt of such an acid. The carboxylic acid may be an aliphatic diacid such as succinic acid. The sulphur-containing acid may be a sulphonic acid or sulphuric acid derivative such as the sodium salt of an alkyl sulphonic acid or of sulpho-succinic acid or of a carboxylic acid ester derivative of sulpho-succinic acid. The composition may be incorporated into an olefin polymer. The composition may be obtained by conventional powder blending or, for a polymer composition, melt blending techniques. Preferred polymer compositions have an increased clarity and a reduced level of haze compared to the polymer alone or the polymer containing only the carboxylic acid.
    Type: Grant
    Filed: October 16, 1990
    Date of Patent: May 12, 1992
    Assignee: Imperial Chemical Industries PLC
    Inventor: Colin Bath
  • Patent number: 5106897
    Abstract: A method for improving the low temperature impact strength of a thermoplastic polyblend of PETG and SAN which method comprises incorporating therein an effective amount of a dispersant selected from the group consisting of mono- and di-carboxylic acids containing 6 to 36 carbon atoms; alkali and alkaline-earth metal salts and amides of such acids; and aliphatic alcohols containing 6 to 36 carbon atoms.
    Type: Grant
    Filed: February 20, 1990
    Date of Patent: April 21, 1992
    Assignee: Monsanto Company
    Inventors: James Y. Chen, Donald B. Baldridge
  • Patent number: 5086106
    Abstract: A methacrylic resin cast plate having an excellent antistatic property comprises (A) 100 weight parts of a polymer comprising 50 to 100 weight % of methyl methacrylate units and 0 to 50 weight % of copolymerizable monomer units and (B) 0.1 to 20 weight parts of a polymer comprising 20 to 100 weight % of units derived from a monomer having a quaternary ammonium base, which is represented by the formula (I): ##STR1## wherein R.sub.1 is H or CH.sub.3, R.sub.2 through R.sub.4 are H or (Cl-9)alkyl which may have a substituent, m is from 1 to 10 and X.sup.- is an anion of a quaternizing agent,and 0 to 80 weight % of copolymerizable monomer units. The cast plate is obtained by polymerizing methyl methacrylate, a monomer mixture comprising at least 50 weight % of methyl methacrylate and up to 50 weight % of a copolymerizable monomer or a partial polymerization product thereof in the presence of the polymer (B).
    Type: Grant
    Filed: October 17, 1989
    Date of Patent: February 4, 1992
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Kiyotaka Azegami, Suehiro Tayama, Naoki Yamamoto, Akira Yanagase, Hiroki Hatakeyama
  • Patent number: 5066694
    Abstract: This invention relates to a pressure sensitive adhesive compositions which include an emulsion of a metal neutralized sulfonated copolymer of isoprene/sodium styrene sulfonate, wherein the neutralized sulfonated copolymer has about 5 to about 250 meq. of neutralized sulfonate groups per 100 grams of the neutralized sulfonated copolymer, and less than about 50 parts by weight of an emulsion of a preferential polar plasticizer, and less than about 300 parts by weight of an emulsion of a hydrocarbon tackifying resin of a petroleum or coal tar distillate, having about 4 to 12 carbon atoms, wherein the hydrocarbon resin is composed of aliphatic dienes and monoolefins per 100 parts by weight of the neutralized sulfonated copolymer.
    Type: Grant
    Filed: September 27, 1990
    Date of Patent: November 19, 1991
    Assignee: Exxon Research and Engineering Company
    Inventors: Pawan K. Agarwal, Thomas Pugel
  • Patent number: 5028641
    Abstract: A thermosetting resin composition formed of a polyaminobismaleimide resin, which is composed of a bismaleimide compound and a diamine compound, and a powdery inorganic filler. The composition has excellent heat resistance as well as superb mechanical properties at high temperature not to mention room temperature, and is expected to find wide-spread commercial utility in electric and electronic components such as sealing materials, sockets and connectors and other applications.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: July 2, 1991
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5017636
    Abstract: A rubber composition for tire having improved processability, wear resistance, rebound resilience and heat build-up comprises 20.about.70 parts by weight of a specified butadiene polymer, 30.about.80 parts by weight of at least one rubber selected from natural rubber, high cis-1,4 polyisoprene rubber and styrene-butadiene copolymer rubber, and 0.about.30 parts by weight of high cis-1,4 polybutadiene and/or low cis-1,4 polybutadiene, and contains 35.about.100 parts by weight of carbon black, 0.about.50 parts by weight of process oil, 0.5.about.5 parts by weight of aliphatic carboxylic acid and 0.1.about.3 parts by weight of sulfur based on 100 parts by weight of the above rubber components.
    Type: Grant
    Filed: May 10, 1990
    Date of Patent: May 21, 1991
    Assignees: Japan Synthetic Rubber Co., Ltd., Bridgestone Corporation
    Inventors: Iwakazu Hattori, Noboru Shimada, Noboru Oshima, Mitsuhiko Sakakibara, Hiroshi Mouri, Tatsuo Fujimaki, Tatsuro Hamada
  • Patent number: 4966925
    Abstract: Objects which are designed to be submerged in a marine environment are prcted from fouling for an extended period of time by the use of elastomeric based covering materials which are characterized by a constant delivery rate of the incorporated organometallic polymer toxicant from the formulation.
    Type: Grant
    Filed: June 9, 1988
    Date of Patent: October 30, 1990
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Vincent J. Castelli, William L. Yeager
  • Patent number: 4962135
    Abstract: Self polishing anti-fouling marine paint compositions, that can be prepared free of organotin, comprise: (i) at least one sparingly soluble organic compound that is an organic acid or an organic acid salt preferably selected from rosin-based compounds, metal salts of saturated fatty acids, either branched-chain or alicyclic; (ii) a copolymer prepared from at least one acrylic monomer, at least one monomer selected from C.sub.1 -C.sub.4 alkyl methacrylates and styrene, and at least one monomer selected from cyclic tertiary amides or imides having an alkenyl group; (iii) at least one sparingly soluble metalliferous pigment; (iv) at least one marine biocide which can also function as the pigment; and optionally (iv) one or more highly insoluble pigments.
    Type: Grant
    Filed: April 28, 1988
    Date of Patent: October 9, 1990
    Assignee: Labofina, S.A.
    Inventors: Jozef Braeken, Jean-Paul Dekerk, Hendrik van der Poel, Jozef Verborgt, Peter Haak
  • Patent number: 4959405
    Abstract: It has been discovered that by adding one or more strong organic carboxylic acids to conventional acrylate and/or methacrylate based adhesive compositions, the bonding characteristics thereof change dramatically.Thermoplastic materials whose bondability is most dramatically enhanced by the compositions of the present invention are nylon and blends of nylon and nylon-like materials with other polymers.Thermoset materials which exhibit dramatically enhanced bondability comprise homogeneous materials such as epoxies, and composite materials such as polyesters, urethanes, and/or epoxies, containing glass, minerals, and the like, which are polar or have hydrogen bonding capability.The present invention thus utilizes acrylate and/or methacrylate based adhesive compositions as a base material. To this base material is added an effective amount of one or more strong organic carboxylic acids, e.g., acids having a relatively high dissociation constant (K.sub.d or K.sub.ld).
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: September 25, 1990
    Assignee: Illinois Tool Works, Inc.
    Inventors: Paul C. Briggs, Donald E. Gosiewski
  • Patent number: 4943613
    Abstract: The photocurable organopolysiloxane composition is curable by irradiation with ultraviolet light into a rubbery elastomer which is excellently adhesive to the surface of the substrate on which it has been cured. The composition comprises an organopolysiloxane having, in a molecule, at least one acryloxy-functional group represented by the general formula[CH.sub.2 .dbd.CR.sup.1 --CO--O--(CH.sub.2).sub.a --SiR.sub.2 --O--].sub.b (R).sub.3-b Si--R.sup.2 --,in which R.sup.1 is a hydrogen atom or a methyl group, each R is a monovalent hydrocarbon group, R.sup.2 is an oxygen atom or a divalent hydrocarbon group and each of the subscripts a and b is 1, 2 or 3, as the principal ingredient together with an acryloxy-containing trialkoxy silane represented by the general formula(R.sup.3 O).sub.3 Si--R.sup.4 --(NH--CO--O--R.sup.4).sub.c --O--CO--CR.sup.1 .dbd.CH.sub.2,in which each R.sup.3 is a monovalent hydrocarbon group, each R.sup.4 is a divalent hydrocarbon group having 1 to 20 carbon atoms, R.sup.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: July 24, 1990
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Masatoshi Arai, Kazutoshi Fujioka, Masaharu Satou
  • Patent number: 4939197
    Abstract: A composition for injection molding a ceramic powder to make ceramic shapes is described. The composition comprises a ceramic powder and a binder system. The binder system comprises a distilled thermosetting polycarbosilane containing from about 0.4 to about 0.7 weight percent of a cross-linking inhibitor, a surfactant, and with or without a lubricant. The cross-linking inhibitor is selected from the group consisting of p-benzoquinone, benzophenone, and mixtures thereof.
    Type: Grant
    Filed: October 3, 1988
    Date of Patent: July 3, 1990
    Assignee: GTE Laboratories Incorporated
    Inventor: Sophia R. Su
  • Patent number: 4927871
    Abstract: Disclosed is a process for producing a modified ultrahigh-molecular-weight polyolefin composition, which comprises mixing a powder of an ultrahigh-molecular-weight polyolefin (A) having an intrinsic viscosity of at least 5 dl/g, a flowability improver (B) having a melting point lower than the melting point of the ultrahigh-molecular-weight polyolefin (A), a monomer (C) having an olefinically unsaturated bond and a radical initiator (D) with stirring at the melting point of the flowability improver (B) or a higher temperature but below the melting point of the ultrahigh-molecular-weight polyolefin (A), and then melt-kneading them at the melting point of the ultrahigh-molecular-weight polyolefin (A) or a higher temperature to react the monomer (C) with the ultrahigh-molecular-weight polyolefin (A).
    Type: Grant
    Filed: July 15, 1988
    Date of Patent: May 22, 1990
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoshiji Ohori, Hirofumi Harazoe
  • Patent number: 4923944
    Abstract: A release agent composition which manifests almost no silicone migration and a very low slickness while nevertheless having a low release value is achieved by means of a release agent composition which is based on a methylalkenylpolysiloxane, an alkylhydrogenpolysiloxane crosslinker for the methylalkenylpolysiloxane, an organopolysiloxane containing monovalent hydrocarbon groups which lacks aliphatically unsaturated bonds and which contains 6 to 18 carbon atoms which functions to lighten the releaseability of the cured film, to check silicone migration, and to reduce the slickness, and a catalytic quantity of a platinum-type catalyst.
    Type: Grant
    Filed: November 22, 1988
    Date of Patent: May 8, 1990
    Assignee: Toray Silicone Company, Ltd.
    Inventors: Takateru Yamada, Shosaku Sasaki
  • Patent number: 4919724
    Abstract: Stabilized aqueous emulsions of ketene dimer and nonreactive hydrophobe and method for sizing unbleached fibers and undigested wood chips for use in building products are provided.
    Type: Grant
    Filed: January 17, 1989
    Date of Patent: April 24, 1990
    Assignee: Hercules Incorporated
    Inventors: Marco F. Cenisio, Vido J. Vareika
  • Patent number: 4908166
    Abstract: A composite useful in thermal energy storage, said composite being formed of a polyolefin matrix having a phase change material such as a crystalline alkyl hydrocarbon incorporated therein. The composite is useful in forming pellets, sheets or fibers having thermal energy storage characteristics; methods for forming the composite are also disclosed.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: March 13, 1990
    Assignee: University of Dayton
    Inventor: Ival O. Salyer
  • Patent number: 4898902
    Abstract: A binder composition for injection molding of at least one of metal powder and ceramic powder which comprises polyoxyethylene/polyoxypropylene condensation polyether as the main component together with from 10 to 100 parts by weight of at least one auxiliary component selected from the group consisting of natural waxes, synthetic waxes, fatty acids and esters per 100 parts of said polyoxyethyene/polyoxypropylene condensation polyether.
    Type: Grant
    Filed: June 27, 1988
    Date of Patent: February 6, 1990
    Assignees: Adeka Fine Chemical Co., Ltd., Asahi Denka Kogyo Kabushiki Kaisha
    Inventors: Tomoaki Nagai, Hideyuki Yamanashi, Hideo Hachimori
  • Patent number: 4863987
    Abstract: A deodorizing coating formulation is composed of a white or substantially colorless deodorizing agent, a binder resin and a liquid medium. The deodorizing agent may preferably be composed of 10-90 parts by weight of a zinc compound and 90-10 parts by weight of an aliphatic polycarboxylic acid, aromatic polycarboxylic acid, acidic polymer or a sulfate of aluminum, or a salt thereof. A deodorizing sheet can be obtained by coating and/or impregnating a base sheet with the deodorizing coating formulation and then drying the resulting base sheet. The deodorizing sheet can shield a flavor or odor from external flavors or odors while maintaining air permeability, it is suitable for wrapping foods having strong flavors or odors.
    Type: Grant
    Filed: November 10, 1986
    Date of Patent: September 5, 1989
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Akira Hoshino, Mikio Saji, Shigeaki Fujii
  • Patent number: 4822836
    Abstract: Novel compatibilized polyphenylene ether-polyamide compositions are provided by this invention, comprising polyphenylene ether resin, polyamide resin, a compatibilizing agent, and a melt flow-improving compound. The compatibilizing agent may be selected from a wide variety of materials, such as saturated aliphatic polycarboxylic acids or derivatives thereof; various silane compounds; and functionalized polyphenylene ethers. A specific example of a compatibilizer is citric acid. Specific examples of melt flow-improving compounds are stearic acid, oleic acid, and linolenic acid.
    Type: Grant
    Filed: September 18, 1987
    Date of Patent: April 18, 1989
    Assignee: General Electric Company
    Inventor: Ronald J. Wroczynski
  • Patent number: 4816508
    Abstract: The present invention is directed to an admixture, comprising:(A) a cationic acrylate or methacrylate polymer and(B) 0.1 to 5.0%, by weight, based on the weight of said polymer, of an acidic buffering compound.The present invention is also directed to a method for improving the stability of cationic acrylate polymers, comprising adding 0.1 to 5.0%, by weight, based on the weight of the polymer, of an acidic buffering compound.
    Type: Grant
    Filed: April 18, 1988
    Date of Patent: March 28, 1989
    Assignee: Calgon Corporation
    Inventor: Shih-Ruey T. Chen
  • Patent number: 4781948
    Abstract: An acidic water-based film-forming coating composition suitable for the protection of ferrous surfaces by application thereto and drying at ambient temperature wherein said composition contains at least one acid of defined formula, such as lactic or tartaric acid, which prevents or reduces general yellow/brown staining.
    Type: Grant
    Filed: June 5, 1986
    Date of Patent: November 1, 1988
    Assignee: Imperial Chemical Industries PLC
    Inventor: David Caldwell
  • Patent number: 4762896
    Abstract: The intrinsic viscosity of a high molecular weight aromatic polycarbonate resin is reduced and the melt processability is concomitantly enhanced by the inclusion of a small amount of a fatty acid or acids. The mixture of polymer and acid is more readily extrudable, without detriment to other desirable physical and chemical properties.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: August 9, 1988
    Assignee: General Electric Company
    Inventors: Daniel W. Fox, Andrew A. Martin, Edward N. Peters
  • Patent number: 4704421
    Abstract: Propylene polymers produced by high-activity support based coordination catalysts are effectively nucleated with benzoic acid and adipic acid, yielding molding resins of high clarity.
    Type: Grant
    Filed: August 6, 1985
    Date of Patent: November 3, 1987
    Assignee: El Paso Products Company
    Inventor: Frederick M. Teskin
  • Patent number: 4670503
    Abstract: Aqueous, pasty coating compositions containing a fluorine-containing copolymer formed from tetrafluoroethylene, vinylidene fluoride and hexafluoropropene and a polyacrylate thickener which is composed of an essentially noncrosslinked copolymer of acrylic acid or methacrylic acid and which has a viscosity of 4 to 40 mPa s in a 1% strength by weight solution in aqueous ammonia at a pH of 9 at a shear rate of 1,000 s.sup.-1 are described. The coating compositions are particularly suitable for application to textile substrates by means of the brushing process.
    Type: Grant
    Filed: September 19, 1986
    Date of Patent: June 2, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Wolfgang Neumann, Hans-Jurgen Hendriock