With Saturated Phenolic Reactant Or Polymer Thereof; Or With Solid Copolymer Derived From At Least One Phenolic Reactant Wherein At Least One Of The Reactants Forming The Solid Copolymer Is Saturated; Or With Spfi Wherein At Least One Of The Necessary Ingredients Is A Phenolic Reactant Or With A Reaction Product Thereof; Or With A Sicp Containing A Phenolic Group Si-h Or Si-c Bond Patents (Class 525/132)
  • Patent number: 5541240
    Abstract: Blends of thermotropic liquid crystalline polymers and isotropic melt-processable polymers are made by extruding a molten stream of either a thermotropic liquid crystalline polymer or an isotropic polymer through a heated mixing zone and feeding the other of the two polymers into the stream of the first polymer in the mixing zone. The polymers are mixed under shearing conditions for a time sufficient to yield a uniform blend. Blends made according to this method exhibit improved properties in comparison with blends obtained by feeding the two polymers simultaneously into a heated mixing zone.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: July 30, 1996
    Assignee: Hoechst Celanese Corp.
    Inventors: Subhash Makhija, George L. Lundberg, James B. Stamatoff
  • Patent number: 5541257
    Abstract: A method of enhancing the drainage of residual aqueous rinse from the external surfaces of plastic parts is disclosed. The method employs an aqueous solution of a tannin compound, which when applied to the surface of plastic parts will not rinse off during subsequent rinse stages and will remain on the plastic parts.
    Type: Grant
    Filed: March 21, 1995
    Date of Patent: July 30, 1996
    Assignee: Betz Laboratories, Inc.
    Inventors: Barry P. Gunagan, Jeffrey I. Melzer
  • Patent number: 5504158
    Abstract: There is provided in accordance with the present invention polyphenylene ether/polyalkyleneterephthalamide compositions of high dimensional stabilities that are suitable for high temeprature applications comprising from about 20 to about 70 weight % of a functionalized polyphenylene ether; from about 20 to about 70 weight % of a polyalkyleneterephthalamide, wherein the polyalkyleneterephthalamide is derived from terephthalic acid and an .alpha.,.omega.-alkanediamine having 10 to 14 methylene groups; and from about 0 to about 20 weight % of a functionalized elastomeric polymer, wherein the blend absorbs less than 2 wt % of moisture and has a dimensional growth in water of less than 0.5%.
    Type: Grant
    Filed: January 10, 1995
    Date of Patent: April 2, 1996
    Assignee: AlliedSignal Inc.
    Inventors: Murali K. Akkapeddi, Jeffrey H. Glans
  • Patent number: 5492946
    Abstract: A molded article having improved weld line strength, fabricated from a polymer blend composition comprising at least one liquid crystalline polymer and at least one additional polymer, wherein the composition has a crystallization rate lower than said at least one liquid crystalline polymer.
    Type: Grant
    Filed: July 28, 1994
    Date of Patent: February 20, 1996
    Assignee: Amoco Corporation
    Inventors: Paul J. Huspeni, John F. Petry, Roger W. Nelson, Steven R. Dunkle
  • Patent number: 5491031
    Abstract: A coating composition for application to primed metal substrates as a topcoat is disclosed. The coating composition is especially useful on metal closures for vacuum-packed food products. The coating composition is free of a halide-containing vinyl polymer and comprises: (a) an epoxy novolac resin, (b) a phenolic resin, (c) a polyester, and (d) an elastomer, in (e) a nonaqueous carrier.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: February 13, 1996
    Assignee: The Dexter Corporation
    Inventor: Lawrence P. Seibel
  • Patent number: 5482999
    Abstract: The invention relates to a mixture of a polyphenylene ether resin and a styrene-containing polymer or copolymer, in which at least a part of the polyphenylene ether resin is modified with reactive groups of a first type and at least a part of the styrene-containing polymer or copolymer is modified with reactive groups of a second type which are capable of reacting with the reactive groups of the first type. The invention further relates to articles formed from the said mixture, which have a good combination of low surface gloss and mechanical properties.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: January 9, 1996
    Assignee: General Electric Company
    Inventors: Sarah E. Morgan, Charles F. Pratt, Cinzia A. R. di Fede, Julia A. J. M. Verdult-van Aert
  • Patent number: 5478888
    Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: December 26, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Naoya Ogata, Takehisa Nakanishi, Tadashi Asanuma
  • Patent number: 5475054
    Abstract: A resin composition comprising (A) a polyphenylene ether resin, (B) a polyolefin resin, and optionally (C) an elastomer, and (D) an aliphatic polycarboxylic acid derivative represented by the following general formula:(R.sub.1 O).sub.m R(COOR.sub.2).sub.n (CORN.sub.3 R.sub.4).sub.swherein R represents a saturated hydrocarbon group having 2 to 20 carbon atoms with a linear or branched chain; R.sub.1 represents a hydrogen atom or an alkyl, aryl, acyl or carbonyldioxy group having 1 to 10 carbon atoms; each R.sub.2 represents a hydrogen atom or an alkyl or aryl group having 1 to 20 carbon atoms; R.sub.3 and R.sub.4 each represents a hydrogen atom or an alkyl or aryl group having 1 to 10 carbon atoms; m represents a number equal to 1 or 2; (n+s) is larger than or equal to 2 and, n and s are each larger than or equal to 0; (OR.sub.1) is in an alpha or beta position with respect to a carbonyl group, and in which at least two carbonyl groups are separated by 2 to 6 carbon atoms.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: December 12, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroomi Abe, Kenji Nagaoka, Takashi Sanada
  • Patent number: 5461096
    Abstract: There are disclosed polyphenylene ether resin-based compositions containing high molecular weight polyethylene resin and polyphenylene ether flame-retarded resins which have been rendered non-dripping through the inclusion of a drip-inhibiting amount of high molecular weight polyethylene resin. Still more particularly, there are disclosed flame retardant modified polyphenylene ether resins, such as those containing high impact polystyrene, rendered non-dripping through the inclusion of a drip-inhibiting amount of high molecular weight polyethylene resin which has a weight-average molecular weight (M.sub.w) of greater than about 100,000.
    Type: Grant
    Filed: November 8, 1993
    Date of Patent: October 24, 1995
    Assignee: General Electric Company
    Inventors: Richard C. Bopp, Kim G. Balfour
  • Patent number: 5449722
    Abstract: Disclosed is a thermoplastic resin composition comprising:30 to 97% by weight of at least one of (a) a crystalline thermoplastic resin component and (b) a non-crystalline thermoplastic resin component, 3 to 70% by weight of (c) a rubbery polymer component which is ununiformly mixed with at least one of Component (a) and Component (b) and 0 to 40% by weight of (d) an inorganic filler,wherein Component (c) forms a network and at least one of the ratio of flexural modulus of Component (a) to Component (c) and that of Component (b) to Component (c) is 5 or more.
    Type: Grant
    Filed: March 18, 1994
    Date of Patent: September 12, 1995
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Koji Nishida, Kiyoji Takagi, Hironari Sano, Motohiro Seki
  • Patent number: 5439607
    Abstract: Oleaginous compositions, particularly lubricating oil compositions, exhibiting improved antioxidant properties containing a viscosity index improving amount of a viscosity index improver-dispersant comprised of the reaction products of: (a) an oil soluble ethylene copolymer comprising from about 15 to 90 wt. % ethylene and from about 10 to 85 wt. % of at least one C.sub.3 to C.sub.28 alpha-olefin, having a number average molecular weight of from about 20,000 to 500,000, grafted with an ethylenically unsaturated carboxylic acid material having 1 or 2 acid or anhydride moieties; (b) an organic polyamine having at least two primary amino groups; (c) an aldehyde; (d) a hydroxy aromatic reactant having at least one --OH-- group attached to the aromatic ring; and, optionally, (e) an amount effective to provide a V.I. improver-dispersant exhibiting improved low temperature viscometric properties of high functionality long chain hydrocarbyl substituted dicarboxylic acid material having a functionality of at least 1.
    Type: Grant
    Filed: December 30, 1993
    Date of Patent: August 8, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Abhimanyu O. Patil
  • Patent number: 5434220
    Abstract: A polyphenylene ether resin composition containing (A) 100 parts by weight of a polyphenylene-ether-base resin composed of 100-60 wt. % of a polyphenylene ether resin and 0-40 wt. % of a polystyrene resin and (B) 1-40 parts by weight of a dicarboxylic acid ester copolymer obtained from a vinyl monomer and an unsaturated dicarboxylic acid ester as copolymerizable components. The dicarboxylic acid ester copolymer has a weight average molecular weight not greater than 60,000. The polyphenylene ether resin composition, if necessary, can further comprise (C) 1-40 parts by weight of conductive carbon or an A-B-A' type or A-B'-B" type block copolymer elastomer. Owing to its excellent mechanical properties, heat resistance and moldability, the resin composition is useful in the fields of automotive vehicles, home electronic or electric appliances and industrial parts or components.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: July 18, 1995
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Masaji Yoshimura, Kazuharu Kanezaki, Takashi Satoh, Tomoyuki Nakata, Minoru Takiguchi
  • Patent number: 5428091
    Abstract: A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5 % by weight of at least one polyolefinresin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95 % by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: June 27, 1995
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Hiroomi Abe, Takeshi Fujii, Masashi Yamamoto, Shinichi Yachigo, Hideo Nagasaki, Naoki Inui
  • Patent number: 5418262
    Abstract: A dispersion for producing an adhesive, waterproof and hydrolysis-resistant bonding layer for bonding metal, ceramics, glass and for polymer-plastic bonds, including a phenol resin-methacrylate dispersion containing phenol with free methylol groups, one or more mono- or multifunctional methacrylate compounds, dispersed acrylate, water and acetone.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: May 23, 1995
    Assignee: Heraeus Kulzer GmbH
    Inventor: Roland Gobel
  • Patent number: 5418275
    Abstract: There are disclosed a polystyrene composition which comprises 100 parts by weight of a syndiotactic polystyrene (SPS)(a) and 1 to 100 parts by weight of a high molecular compound comprising 5 to 95% by weight of polyphenylene ether (PPO) and/or modified PPO and 95 to 5% by weight of a rubbery elastomer (b) and optionally, 1 to 350 parts by weight of an inorganic filler (d) and also a polystyrene composition which comprises 100 parts by weight of the component (a), 0.1 to 30 parts by weight of the component (b) and 1 to 100 parts by weight of a rubbery elastomer (c) and optionally, 1 to 350 parts by weight of the component (d). The above compositions are greatly improved in impact resistance, elongation and retention of physical properties during recycling without detriment to heat resistance and modulus of elasticity.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: May 23, 1995
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Akihiko Okada, Nobuyuki Sato
  • Patent number: 5418287
    Abstract: A resin composition comprising the following component A, component B and component C:component A of polyphenylene ether resin; component B of crystalline polyolefin resin; and component C of graft modified copolymer in which an unsaturated copolymer consisting of ethylene or at least one of .alpha.-olefins having 3 to 12 carbon atoms and at least one of chain nonconjugated dienes of the following general formula is modified with a monomer capable of radical polymerization such as styrene. ##STR1## This resin composition has an improved impact strength, keeping heat resistance and mechanical strength characteristic of polyphenylene ether resins, and molding properties and resistance to organic solvents characteristic of polyolefin resins.
    Type: Grant
    Filed: January 10, 1994
    Date of Patent: May 23, 1995
    Assignee: Mitsubishi Petrochemical Company, Ltd.
    Inventors: Tomohiko Tanaka, Hiroshi Nakano, Hiroyuki Satoh, Shiroh Gotoh
  • Patent number: 5414046
    Abstract: Novel thermally stable resins comprising halogens and not epoxide termination groups are described. The thermally stable resins may be employed in polymer systems to yield flame retardant polymer compositions.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: May 9, 1995
    Assignee: General Electric Company
    Inventor: Gary C. Davis
  • Patent number: 5410000
    Abstract: Copolyester compositions are provided which comprise the reaction product of at least one straight chain, branched, or cycloaliphatic C.sub.2 -C.sub.10 alkane diol or a chemical equivalent thereof, a mixture of at least two cycloaliphatic diacids or chemical equivalents thereof, the mixture comprising predominantly a trans-enantiomer, and at least one aromatic diacid or a chemical equivalent thereof. These copolyesters have superior ductility to the homopolymers of the diol component and either of the diacid components.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: April 25, 1995
    Assignee: General Electric Company
    Inventor: Willem F. H. Borman
  • Patent number: 5408002
    Abstract: An azlactone-functional thermoplastic composition is disclosed. The composition is a blend of an azlactone-functional composition and a thermoplastic polymer. A method of making azlactone-functional homopolymers by bulk homopolymerization is disclosed, optionally also concurrent or sequential blending of a thermoplastic polymer. A method of blending azlactone-functional compositions and thermoplastic polymers is disclosed. Molded articles and adduct molded articles formed from the thermoplastic composition are disclosed.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: April 18, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Patrick L. Coleman, Steven M. Heilmann, Steven L. Kangas, Robert H. Menzies, Jerald K. Rasmussen, Richard J. Rolando, Jennifer J. Sahlin, Julie B. Stahl
  • Patent number: 5405902
    Abstract: A novel thermoplastic resin composition excellent in heat resistance, mechanical properties and processability is provided which comprises a composition containing (A) a dispersing phase of polyphenylene ether obtained by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon residue and at least one of them is a hydrogen atom and (B) a crystalline thermoplastic resin matrix phase and (C) a mutual compatibilizer compatible with (A) and/or (B), an average particle diameter in said dispersing phase having of 0.01-10.mu..
    Type: Grant
    Filed: December 15, 1993
    Date of Patent: April 11, 1995
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Taichi Nishio, Takashi Sanada, Satoru Hosoda, Kenji Kagaoka, Takayuki Okada
  • Patent number: 5405932
    Abstract: Oil-soluble, phenolic resin-modified natural resinic acid esters, which are able to form self-gelling mineral oil solutions and in the form of gel varnishes can advantageously be used as binder resins in printing inks for offset printing and letterpress printing, and also processes for their preparation from natural resins, phenols, aldehydes, condensation catalyst, esterifying agents and modifiers by reaction of the components at temperatures in the range from 80.degree. to 300.degree. C., individual components preferably being initially introduced and the other components being metered in, the combined use of a magnesium compound as condensation catalyst and the continuous removal of the water of reaction during the condensation reaction by azeotropic distillation with co-use of an inert organic solvent as distillative entraining agent being necessary and decisive for the self-gelling property of the process product.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: April 11, 1995
    Assignee: Hoechst AG
    Inventors: Albert Bender, Walter Hilker, Lothar Bothe
  • Patent number: 5397838
    Abstract: The present inventions provides polyphenylene ether (PPE)/polyamide (PA) resin compositions having excellent dimensional stability when they absorb moisture, and good mechanical and other properties. Resin compositions of (A) 10-80 wt. parts PPE resins and (B) 90-20 wt. parts PA resins, in which the PA resins (a) are polymers formed by condensation of linear aliphatic diamines with linear aliphatic dicarboxylic acids and aromatic dicarboxylic acids, and (b) have terminal amino group contents of at least 0.4 mequiv/g.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: March 14, 1995
    Assignee: General Electric Company
    Inventors: Takashi Ohtomo, Hiromi Ishida, Hidekazu Kabaya
  • Patent number: 5384360
    Abstract: There are provided melt extruded blends of polyphenylene ether and diene based rubber containing an effective amount of a dialkylamine which has been found effective as a stabilizer for the diene based rubber. Additional diene based rubber stability can be achieved by using preextruded polyphenylene ether. The resulting melt extruded blends have been found to enjoy increased resistance to change in impact values when recycled in the molded state.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: January 24, 1995
    Assignee: General Electric Company
    Inventors: William D. Richards, James E. Pickett
  • Patent number: 5382627
    Abstract: A polyphenylene ether resin composition containing (A) 100 parts by weight of a polyphenylene-ether-base resin composed of 100-60 wt. % of a polyphenylene ether resin and 0-40 wt. % of a polystyrene resin and (B) 1-40 parts by weight of a dicarboxylic acid ester copolymer obtained from a vinyl monomer and an unsaturated dicarboxylic acid ester as copolymerizable components. The dicarboxylic acid ester copolymer has a weight average molecular weight not greater than 60,000. The polyphenylene ether resin composition, if necessary, can further comprise (C) 1-40 parts by weight of conductive carbon or an A-B-A' type or A-B'-B" type block copolymer elastomer. Owing to its excellent mechanical properties, heat resistance and moldability, the resin composition is useful in the fields of automotive vehicles, home electronic or electric appliances and industrial parts or components.
    Type: Grant
    Filed: August 2, 1993
    Date of Patent: January 17, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Masaji Yoshimura, Kazuharu Kanezaki, Takashi Satoh, Tomoyuki Nakata, Minoru Takiguchi
  • Patent number: 5380796
    Abstract: Graft copolymers are prepared by the reaction of an olefin polymer such as polyethylene or polypropylene with an ethylenically unsaturated t-alkylcarbamate compound. Said graft copolymers are capable of reaction with functionalized polyphenylene ethers to produce compatibilized polyphenylene ether-olefin polymer compositions.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: January 10, 1995
    Assignee: General Electric Company
    Inventors: John R. Campbell, James R. Presley
  • Patent number: 5380801
    Abstract: Compatible polymer blends containingA) 0.5-99.5 wt. %, preferably 50 to 90 wt. % of a polyphenylene ether, synthesized from units of formula (I) ##STR1## where R.sub.1 stands for an optionally substituted (cyclo)alkyl group or alkoxyl group having 1 to 8 carbon atoms or an optionally substituted aryl group having 6 to 10 carbon atoms or for chlorine,where R.sub.2 stands for an optionally substituted (cyclo)alkyl group or alkoxyl group having 1 to 8 carbon atoms or an optionally substituted aryl group having 6 to 10 carbon atoms or for chlorine, andB) 99.5-0.5 wt. %, preferably 50 to 10 wt. % of a polyaryl(meth)acrylate containing 20-100 wt. % of monomers of the formula (II) ##STR2## where R.sub.3 stands for hydrogen or methyl, Q stands for an alkylidene group having 1 to 6 carbon atoms or a group --(CH.sub.2).sub.m --O--, where m denotes a number from 2 to 6,x stands for zero or 1 andR.sub.
    Type: Grant
    Filed: January 8, 1993
    Date of Patent: January 10, 1995
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Jens-Dieter Fischer, Werner Siol
  • Patent number: 5376724
    Abstract: Improved thermoplastic compositions based on polyphenylene ether are disclosed. These compositions contain a resinous additive derived from a mixture which comprises aromatic monomers, such as a mixture of styrene and alpha methyl styrene. The compositions are characterized by improved melt flow, along with the substantial maintenance of other important properties, such as impact strength and heat distortion temperature.
    Type: Grant
    Filed: January 10, 1994
    Date of Patent: December 27, 1994
    Assignee: General Electric Company
    Inventors: Christian M. E. Bailly, William R. Haaf
  • Patent number: 5376718
    Abstract: Disclosed herein is a flame-retardant resin composition comprising 100 parts by weight of a styrene based polymer, 10 to 40 parts by weight of a brominated bisphenol epoxy resin or a resin in which at least one of the epoxy terminals of the brominated bisphenol epoxy resin is blocked with a brominated phenol, 1 to 10 parts by weight of antimony trioxide, and 0.3 to 5 parts by weight of a methacrylate polymer with a methacrylate unit content of not less than 25 wt %.
    Type: Grant
    Filed: September 23, 1993
    Date of Patent: December 27, 1994
    Assignee: Monsanto Kasei Company
    Inventor: Mitsuyuki Yada
  • Patent number: 5369177
    Abstract: Thermoplastic molding materials containA) from 40 to 99.69% by weight of a polyoxymethylene homo- or copolymer,B) from 0.1 to 2% by weight of at least one stabilizer selected from the group consisting of benzotriazole derivatives or benzophenone derivatives or aromatic benzoate derivatives,C) from 0.1 to 2% by weight of at least one sterically hindered amino compound,D) from 0.005 to 2% by weight of a polyamide,E) from 0 to 2% by weight of an epoxy-containing compound,F) from 0 to 50% by weight of a toughened polymer andG) from 0 to 50% by weight of a fibrous or particulate filler or of a mixture thereof.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: November 29, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Sabine Kielhorn-Bayer, Hartmut Zeiner, Heiner Goerrissen, Dietrich Saenger
  • Patent number: 5362809
    Abstract: A polymer blend of a polyglutarimide and liquid crystalline copolyester polymer or benzimidazole polymer. The blend is a melt-compoundable polymer blend.
    Type: Grant
    Filed: October 22, 1992
    Date of Patent: November 8, 1994
    Assignee: Rohm and Haas Company
    Inventors: Michael P. Hallden-Abberton, Newman M. Bortnick, William J. Work
  • Patent number: 5356992
    Abstract: Polymer compositions containing a polyphenylene etherpolyolefin copolymer are obtained by reactive melt mixing olefin-(alkyl)acrylic acid copolymer with a polyphenylene ether and a carboxylic anhydride. The compositions are used in many commercial applications requiring high temperature resistance including formation of films, fibers and molded articles with excellent surface appearance.
    Type: Grant
    Filed: February 26, 1993
    Date of Patent: October 18, 1994
    Assignee: Enichem S.p.A.
    Inventors: Steve G. Cottis, Kavilipalayam M. Natarajan
  • Patent number: 5332621
    Abstract: A composite article is prepared by intimately bonding a latex foam with a thermoplastic molded part containing polyphenylene ether, the latex consisting of the following components, relative to its total rubber content:I. 20-100% by weight of SBR latex with a minimum proportion of more than 15% by weight of styrene in the solid polymer, andII. 80-0% by weight of natural-rubber latex or other, synthetic latexes.The combination is vulcanized to form a product which exhibits cohesive rupture within the foam body, when the foam body is subjected to separation.
    Type: Grant
    Filed: March 12, 1993
    Date of Patent: July 26, 1994
    Assignee: Huels Aktiengesellschaft
    Inventors: Friedrich-Georg Schmidt, Herbert Knipp, Wilhelm Munninghoff
  • Patent number: 5328945
    Abstract: A polyphenylene ether/polyamide resin composition comprising:(A) polyphenylene ether modified with an unsaturated carboxylic acid having (a) an ethylenically unsaturated double bond and (b) either a carboxyl group or an acid anhydride group,(B) 6,6-nylon,(C) 6-nylon, and optionally(D) a montanic acid metal salt.This composition is possesses good flowability, heat resistance, solvent resistance, dimensional stability, and moreover good releasability from a mold and recyclability on the basis of advantages of polyphenylene ether (PPE) and polyamide, and can be used for manufacturing automobile parts such as wheel caps, fenders, bumpers and spoilers, or housings for office automation machines, etc.
    Type: Grant
    Filed: December 14, 1992
    Date of Patent: July 12, 1994
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yasumasa Norisue, Goro Shimaoka, Hideo Uno
  • Patent number: 5324795
    Abstract: The present invention relates to a polymer blend composition for melt molding which is a composition obtained by adding a thickener to a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer, characterized in that the melt viscosity of the composition determined at a molding temperature at a shear rate of 1000 sec.sup.-1 is the same or higher than the melt viscosity of said non-liquid crystal polymer determined under the same conditions.According to the present invention, a polymer blend for melt molding having improved properties, whereby problems observed in prior arts upon molding a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer (for example, insufficient alignment of the liquid crystal polymer and difficulties in extrusion, because of excessively low melt viscosity) can be solved, is obtained.
    Type: Grant
    Filed: May 12, 1993
    Date of Patent: June 28, 1994
    Assignee: Unitika Ltd.
    Inventor: Jun-ichi Suenaga
  • Patent number: 5321087
    Abstract: The present invention relates to a process for the preparation of a thermoplastic resin composite comprising conducting polycondensation of a monomer material in a solution of an organic solvent containing an organic solvent soluble polymer to form an aromatic condensation polymer which is insoluble in said organic solvent and a thermoplastic resin composite prepared by the process.
    Type: Grant
    Filed: July 22, 1992
    Date of Patent: June 14, 1994
    Assignee: Mitsui Toatsu Chemicals, Incorporated
    Inventors: Naoya Ogata, Takehisa Nakanishi, Tadashi Asanuma
  • Patent number: 5314954
    Abstract: A process is disclosed for preparing of aromatic polyester-polystyrene block copolymers which comprises subjecting preferentially styrene polymers (A) having terminal functional groups reactive with acid chloride groups and an excess of aromatic dicarboxylic acid dihalides (C) to condensation and then subjecting continuously the resultant mixture and aromatic dihydroxy compounds (B) to interfacial polymerization at the ratio (A)/[(B)+(C)] by weight of 5/95 to 80/20, without separating reaction products of styrene polymers (A) and aromatic dicarboxylic acid dihalides (C), and the block copolymers thus prepared contain a small amount of uncopolymerized styrene polymers, have long aromatic polyester segments, show low birefringence, good transparency, exceptionally low birefringence, low melt viscosity, and good mechanical strength, and are particularly useful as materials for optical instruments.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: May 24, 1994
    Assignees: Unitika Ltd., Nippon Steel Corporation, Nippon Steel Chemical Co. Ltd.
    Inventors: Hiroshi Ohishi, Shinji Inaba, Masao Kimura, Koichi Fujishiro, Masanao Kawabe, Takumi Tanaka, Keizo Kyuda, Souichiro Kishimoto, Takamasa Owaki, Akio Motoyama
  • Patent number: 5310804
    Abstract: The morphology of a polymer alloy displaying miscibility over some region of composition and temperature may be varied by thermodynamically altering the miscibility, such as raising the temperature for an LCST system, to phase separate the components then quenching the alloy below the glass transition temperature of the matrix phase. Such phase separated alloys have improved toughness.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: May 10, 1994
    Assignee: Novacor Chemicals (International) S.A.
    Inventors: Gregory Beaucage, Richard S. Stein
  • Patent number: 5310776
    Abstract: There is disclosed a process for preparing a thermoplastic resin composition which comprises melting and kneading(A) 100 parts by weight of a resin comprising 100% by weight in total of:(a) 5 to 95% by weight of a non-crystalline thermoplastic resin,(b) 95 to 5% by weight of a crystalline thermoplastic resin,(c) 0 to 50% by weight of a compatibilizer and(d) 0 to 40% by weight of an impact modifierand(B) 1.0 part by weight or more of an organic solvent in a kneader equipped with vent ports each having a vacuum device while maintaining each vent port at reduced pressure to make an organic solvent content in a final composition less than 1.0% by weight.
    Type: Grant
    Filed: April 30, 1993
    Date of Patent: May 10, 1994
    Assignee: Mitsubishi Petrochemical Co., Ltd.
    Inventors: Kiyoji Takagi, Yoshihiro Kurasawa, Koji Nishida, Shigekazu Ohi, Kenji Mori, Tsukasa Sato, Tosio Itou
  • Patent number: 5310792
    Abstract: An improved thermoplastic resin composition obtained by subjecting a mixture of at least an engineering plastic and a rubber material containing an .alpha.,.beta.-unsaturated carboxylic acids or their derivatives, to dynamic heat treatment in the presence of a carbon radical inducing agent. The thermoplastic resin composition of the invention excels in thermal resistance, rigidity, impact resistance, and moldability.
    Type: Grant
    Filed: December 30, 1991
    Date of Patent: May 10, 1994
    Assignee: Nippon Petrochemicals Company, Limited
    Inventor: Toshio Inoue
  • Patent number: 5306562
    Abstract: The preparation and properties of xanthenylamide handles for use in peptide synthesis is disclosed. The compounds, omega-(9-(9-fluorenylmethyloxycarbonyl)aminoxanthan-2-oxy)alkanoic acid derivatives, are used as peptide handles in the solid-phase synthesis of peptide amides.
    Type: Grant
    Filed: May 15, 1992
    Date of Patent: April 26, 1994
    Assignee: Regents of the University of Minnesota
    Inventor: George Barany
  • Patent number: 5304600
    Abstract: Process for the manufacture of modified polyphenyl ether or structurally related polymers comprising the reaction of said compound with a para substituted phenylsulphonyl halide, in the presence of a substituted pyridine derivative as catalyst and an acid neutralizing agent, and in a vinyl substituted aromatic monomer as solvent; modified polyphenylene ethers or structurally related polymers so obtained and use of them for the manufacture of modified high temperature rigid poly(vinyl substituted aromatic) polymer compositions.
    Type: Grant
    Filed: September 30, 1992
    Date of Patent: April 19, 1994
    Assignee: Shell Research Limited
    Inventors: Laurentius N. I. H. Nelissen, Henricus C. M. Timmermans, Johannes M. Zijderveld
  • Patent number: 5302429
    Abstract: Vinyl aromatic polymers having a minimum molecular weight of about 500,000, and preferably of about 1,500,000, are blended at levels of from about 1 to about 25% with thermoplastic resins to improve the melt rheology of the thermoplastic resins and facilitate blow molding, thermoforming, extrusion and similar processes.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: April 12, 1994
    Assignee: Rohm and Haas Company
    Inventor: Nazir A. Memon
  • Patent number: 5300568
    Abstract: A thermoplastic resin composition which comprises 100 parts by weight of a composition comprising 95-5% by weight of at least one polyolefin-resin (A) selected from homopolymers of ethylene or .alpha.-olefin or copolymers thereof and these homopolymers or copolymers modified with a polyfunctional compound (E) and/or an unsaturated monomer (L) and 5-95% by weight of at least one polyphenylene-ether-resin (B) selected from polyphenylene ether, modified polyphenylene ether with the above (E) and/or (L) and a composition comprising the polyphenylene or modified polyphenylene ether and an aromatic vinyl polymer resin (M) and 0.001-10 parts by weight of a dinitrodiamine (D) of the following formula (I). ##STR1## (wherein X represents a divalent chain aliphatic group, a cyclic aliphatic group or an aromatic group which may contain a halogen or an oxygen atom, R.sup.1 represents a hydrogen atom, a chain aliphatic group, a cyclic aliphatic group or an aromatic group and when both of X and R.sup.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: April 5, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroomi Abe, Takeshi Fujii, Masashi Yamamoto, Shinichi Yachigo, Hideo Nagasaki, Naoki Inui
  • Patent number: 5300573
    Abstract: Thermoplastic elastomer compositions comprise a blend of polyester resin and a covalently-crosslinked acrylate rubber. Such compositions can be prepared by dynamic vulcanization of the rubber in admixture with the polyester and can exhibit high temperature dimensional stability and low oil swell.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: April 5, 1994
    Assignee: Advanced Elastomer Systems, L.P.
    Inventor: Raman Patel
  • Patent number: 5294667
    Abstract: In order to prepare thermoplastic molding materials from pulverulent polyphenylene ethers and aromatic vinyl polymers by melt extrusion, the pulverulent polyphenylene ether is first of all compacted and/or sintered under pressure and if necessary with the addition of heat, preferably under a pressure corresponding to a nip pressure of from 1 to 100 kN/cm, to form a porous compact. The compact is then fed in the form of agglomerates having a particle size of from about 0.5 mm to about 20 mm into an extruder or the like, mixed with the aromatic vinyl polymer and if desired further components, and melted. In this way the proportion of the fines in the polyphenylene ether is considerably reduced, with the result that there is virtually no further danger of dust explosions. Further advantages include improved ease of metering and reduced electrostatic charge of the agglomerates. The extruded molding materials have good mechanical properties and also high thermal stability.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: March 15, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Robert Weiss, Axel Gottschalk, Klaus Muehlbach, Carola Hedtmann-Rein, Robert Heinz
  • Patent number: 5286793
    Abstract: Polymer compositions containing a polyphenylene etherpolyolefin copolymer obtained by melt mixing an ethylene/(alkyl)acrylic acid copolymer with a polyphenylene ether or an ester end-capped polyphenylene ether. The compositions are used in many commercial applications requiring high temperature resistance including formation of films, fibers and molded articles with excellent surface appearance.
    Type: Grant
    Filed: June 15, 1992
    Date of Patent: February 15, 1994
    Assignees: Istituto Guido Donegani, Enichem America, Inc.
    Inventors: Steve G. cottis, Kavilipalayam M. Natarajan
  • Patent number: 5283291
    Abstract: It is desirable to increase the modulus of rubbers utilized in a wide variety of applications. This invention discloses a technique for preparing high modulus rubber compositions. By utilizing this technique, high modulus can be attained without sacrificing other properties, such as processability. The subject invention more specifically relates to a process for preparing a high modulus rubber composition which comprises: (1) polymerizing at least one diacid or diacid halide with at least one member selected from the group consisting of diols and diamines in a polymer cement of a rubbery elastomer under conditions which result in the formation of a rubber cement having a polyester or a polyamide dispersed therein; and (2) recovering the high modulus rubber composition from the rubber cement. It is highly desirable to make the high modulus rubber composition by interfacial polymerization.
    Type: Grant
    Filed: June 19, 1991
    Date of Patent: February 1, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Bruce R. Hahn, Wen-Liang Hsu, Douglas D. Callander, Adel F. Halasa
  • Patent number: 5281665
    Abstract: A thermoplastic resin composition is here provided which comprising99 to 50% by weight of at least one of engineering plastics (A) and1 to 50% by weight of an ethylene copolymer (B) having at least one of carbon-carbon unsaturated double bonds, and1 to 200 parts by weight, based on 100 parts by weight of the resin (A)+(B), of at least one selected from the group consisting of a rubber-like elastomer (C) and/or an olefin polymer or copolymer (D).
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: January 25, 1994
    Assignee: Nippon Petrochemicals Co., Ltd.
    Inventors: Hirofumi Fukui, Katsufumi Suga
  • Patent number: 5281659
    Abstract: Provided are polyester compositions having thermally stable colorants copolymerized therein, said colorants comprised of at least one electron-rich aromatic moiety attached to a negatively substituted 2,5-dioxypyrrolin-3-yl moiety and containing at least one, and preferably, two polyester reactive groups. Also provided are polyester color concentrates and blends of the colored polyester compositions with other thermoplastic polymers and shaped or formed articles comprised of same.
    Type: Grant
    Filed: November 2, 1992
    Date of Patent: January 25, 1994
    Assignee: Eastman Kodak Company
    Inventors: Max A. Weaver, Clarence A. Coates, William W. Parham, Samuel D. Hilbert, James J. Krutak, Wayne P. Pruett
  • Patent number: 5276089
    Abstract: There is disclosed a blend of certain polyesters and polymers that are miscible with polystyrene, such as polyphenylene oxide. The blend is characterized by the presence of a compatibilizing amount of a copolymer having repeating units derived from an aromatic vinyl compound monomer and a vinylphenol monomer. The polyester is thermoplastic and is characterized in that the diacid component of the polyester includes aromatic groups and the diol component comprises at least about 20 percent by weight of a noncyclic, aliphatic diol.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: January 4, 1994
    Assignee: Eastman Kodak Company
    Inventors: Ralph H. Colby, Christine J. T. Landry, Michael R. Landry, Timothy E. Long, Dennis J. Massa, David M. Teegarden