Polymer Mixture Of Two Or More Solid Polymers Derived From Ethylenically Unsaturated Reactants Only; Or Mixtures Of Said Polymer Mixture With A Chemical Treating Agent; Or Products Or Processes Of Preparing Any Of The Above Mixtures Patents (Class 525/191)
  • Patent number: 8173748
    Abstract: Provided is a heat-seal resin. The resin includes 5 wt % to 95 wt % of a first copolymer and 95 wt % to 5 wt % of a second copolymer based on the total weight of the resin. The first copolymer and the second copolymer together are 90 wt % or more of the total weight of the resin. The first copolymer includes a first monomer of an alphaolefin of 2 to 4 carbon atoms and a second monomer selected from a second monomer of an alphaolefin of 2 to 8 carbon atoms. The first monomer and the second monomer of the first copolymer are different. The first copolymer has an MFR of from 5 to 1000 g/10 minutes and a Tfm of 66° C. to 80° C. The second copolymer includes a first monomer of an alphaolefin of 2 to 4 carbon atoms and a second monomer selected from a second monomer of an alphaolefin of 2 to 8 carbon atoms. The first monomer and the second monomer of the second copolymer are different. The second copolymer has an MFR of from 0.5 to 5 g/10 minutes and a Tfm of 45° C. to 66° C.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: May 8, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: David John Lohse, Thomas Tungshi Sun, Aspy K. Mehta, Gabor Kiss, Robert Patrick Reynolds, Jr., John W. Chu, Manika Varma-Nair
  • Patent number: 8173750
    Abstract: A polymer composition comprising star macromolecules is provided. Each star macromolecule has a core and five or more arms, wherein the number of arms within a star macromolecule varies across the composition of star molecules. The arms on a star are covalently attached to the core of the star; each arm comprises one or more (co)polymer segments; and at least one arm and/or at least one segment exhibits a different solubility from at least one other arm or one other segment, respectively, in a reference liquid of interest.
    Type: Grant
    Filed: October 27, 2010
    Date of Patent: May 8, 2012
    Assignee: ATRP Solutions, Inc.
    Inventors: Wojciech Jakubowski, Patrick McCarthy, Nicolay Tsarevsky, James Spanswick
  • Patent number: 8173747
    Abstract: The present invention relates to a heterophasic polypropylene composition which is sterilizable and has a high impact strength as well as improved optical properties both before and after a step of heat sterilization. Furthermore, the present invention relates to a film comprising said heterophasic polypropylene composition, and to the use of said composition for the production of a film. Finally, the present invention is directed to the use of such a film as a packaging material for medicals and/or food. The heterophasic polypropylene composition comprises a matrix resin which comprises (A) a propylene homopolymer and (B) a propylene random copolymer; and a dispersed phase which comprises (C) an ethylene-propylene rubber wherein (i) the melting point of the heterophasic polypropylene composition is at least 145° C. and (ii) the content of comonomer in the matrix resin is at least 0.5 wt % based on the entire matrix resin without any additives.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: May 8, 2012
    Assignee: Borealis Technology Oy
    Inventors: Christelle Grein, Tonja Schedenig
  • Patent number: 8173746
    Abstract: A method for producing an olefinic thermoplastic elastomer comprising mixing 100 parts by weight of an olefin copolymer rubber (A) obtained by polymerizing ethylene, an ?-olefin having 3 to 20 carbon atoms and a non-conjugated polyene, and based on 100 parts by weight of the olefin copolymer rubber (A), 11 to 50 parts by weight of a volatile organic solvent (B) and 5 to 150 parts by weight of an olefin resin (C), and removing from the mixture the volatile organic solvent (B) while kneading in an extruder.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: May 8, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kazuyoshi Fuse, Hironobu Shigematsu, Takeshi Tominaga
  • Patent number: 8168722
    Abstract: A polymer composition that includes from 0.1 to 60 percent by weight of interpolymer resin particles containing a styrenic polymer intercalated within a polyolefin and from 40 to 99.9 percent by weight of at least one second polymer. The polyolefin is present at from 20% to 80% by weight based on the weight of the particles, has a VICAT softening temperature greater than 60° C. and a melt index of from 0.3 to 15 g/10 minutes (190° C./2.16 kg). The styrenic polymer is present at from 20% to 80% by weight based on the weight of the particles. The interpolymer resin particles have a gel content ranging from 0 to 5% by weight based on the weight of said interpolymer resin particles, a VICAT softening temperature ranging from 85° C. to 115° C., and a melt index value ranging from 0.1 to 6.0 (230° C./5.0 kg).
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: May 1, 2012
    Assignee: NOVA Checmials Inc.
    Inventors: Steven M. Krupinski, Eric Vignola
  • Patent number: 8168274
    Abstract: The present invention relates to a film comprising at least one layer comprising an ethylene homo- or copolymer which has a complex viscosity at 5 kPa shear stress eta5 of 200,000 or less and a shear thinning index SHI(5/300) measured at 190° C. as the ratio between the complex viscosity at 5 kPa shear stress and the complex viscosity at 300 kPa shear stress of 120 or more.
    Type: Grant
    Filed: March 29, 2006
    Date of Patent: May 1, 2012
    Assignee: Borealis Technology Oy
    Inventors: Irene Helland, Svein Stall Eggen, Remko van Marion
  • Patent number: 8163845
    Abstract: The invention relates to a biaxially oriented electrical insulating film which contains a mixture from a polypropylene P1 and a polypropylene P2 which is different therefrom. The polypropylene P1 is a linear polypropylene and has an Mw/Mn>5 and a mesopentadene isotactic index of at least 95% and the polypropylene P2 has a long-chain branching.
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: April 24, 2012
    Assignees: Treofan Germany GmbH & Co. KG, Borealis Technology Oy
    Inventors: Detlef Busch, Thilo Mohr, Joachim Fiebig, Franck Jacobs, Yvo Daniels
  • Patent number: 8153243
    Abstract: The present invention relates to compositions and processes of making and using interpolymers having a controlled molecular weight distribution. Multilayer films and film layers derived from novel ethylene/?-olefin interpolymers are also disclosed.
    Type: Grant
    Filed: June 13, 2007
    Date of Patent: April 10, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Rajen M. Patel, David W. Fuchs, Pradeep Jain, Seema Karande, Mehmet Demirors, Mark Grant Spencer, Kim L. Walton, Angela N. Taha, Phillip D. Hustad, Roger L. Kuhlman, Anthony J. Castelluccio
  • Patent number: 8148472
    Abstract: This invention relates to a polymer composition comprising a blend comprising: (a) greater than 30 wt (based upon the weight of the composition) of a cyclic olefin polymer having a Tg greater than 60° C.
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: April 3, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Lisa Saunders Baugh, Bryan R. Chapman, Enock Berluche
  • Patent number: 8143349
    Abstract: A method for producing an olefinic thermoplastic elastomer comprising the steps of kneading an olefin copolymer rubber (A) obtained by polymerizing ethylene, an ?-olefin having 3 to 20 carbon atoms and a non-conjugated polyene, a volatile organic solvent (B) and, an olefin resin (C) in an extruder, removing the volatile organic solvent (B) while kneading, then adding a crosslinking agent (E) and further removing the volatile organic solvent (B) while kneading in the extruder to obtain the olefinic thermoplastic elastomer.
    Type: Grant
    Filed: December 19, 2007
    Date of Patent: March 27, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kazuyoshi Fuse, Hironobu Shigematsu, Takeshi Tominaga
  • Patent number: 8143352
    Abstract: A process for fluid phase in-line blending of polymers.
    Type: Grant
    Filed: December 17, 2007
    Date of Patent: March 27, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, Jr., Robert Charles Portnoy, David B. Dunaway
  • Publication number: 20120071606
    Abstract: Methods of forming polycarbonate graft copolymers are provided. In particular, a polycarbonate polymer or copolymer containing allyl groups provides the backbone for the graft copolymer, and pendant chains are attached to the copolymer through the allyl groups. The graft copolymers exhibit a combination of high transparency, good graft levels, good scratch resistance, and/or good anti-fog properties.
    Type: Application
    Filed: September 17, 2010
    Publication date: March 22, 2012
    Inventors: Rubin Huang, Andre van Zyl, Jan Pleun Lens, Theodorus Lambertus Hoeks, Hans-Peter Brack, Jan Henk Kamps
  • Patent number: 8138264
    Abstract: A bimodal polyethylene having a high density ranging from about 0.955 to about 0.959 g/cc, an improved environmental stress cracking resistance (ESCR) of from about 400 to about 2500 hours, and an improved 0.4% flexural modulus of from about 180,000 to about 260,000 psi (1,200 MPa to about 1,800 MPa) may be formed using a Ziegler-Natta polymerization catalyst using two reactors in series. The bimodal polyethylene may have a high load melt index (HLMI) of from about 2 and about 30 dg/min and may be optionally made with a small amount of alpha-olefinic comonomer in the second reactor. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
    Type: Grant
    Filed: May 4, 2007
    Date of Patent: March 20, 2012
    Assignee: Fina Technology, Inc.
    Inventors: Tim J. Coffy, Gerhard Guenther, Steven D. Gray
  • Patent number: 8138269
    Abstract: Isotactic polypropylene ethylene-propylene copolymer blends and in-line processes for producing them. The blends may have between 1 and 50 wt % of isotactic polypropylene with a melt flow rate of between 0.5 and 20,000 g/10 min and a melting peak temperature of 145° C. or higher, and wherein the difference between the DSC peak melting and the peak crystallization temperatures is less than or equal to 0.5333 times the melting peak temperature minus 41.333° C., and between 50 and 99 wt % of ethylene-propylene copolymer including between 10 wt % and 20 wt % randomly distributed ethylene with a melt flow rate of between 0.5 and 20,000 g/10 min, wherein the copolymer is polymerized by a bulk homogeneous polymerization process, and wherein the total regio defects in the continuous propylene segments of the copolymer is between 40 and 150% greater than a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: March 20, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, Jr., Aspy K. Mehta, Manika Varma-Nair, John W. Chu, Steven P. Rucker
  • Patent number: 8138267
    Abstract: The invention relates to a novel polyolefin composition which is suitable for producing drawn tapes, fibres and filaments which have improved mechanical properties. The composition comprises A) 2 30 wt % of a propylene copolymer which comprises a a) random propylene copolymer having a content of ethylene and/or C 4-C 8a-olefin of 0.5 to 12 wt % and optionally an b) ethylene-a-olefin rubber, B) 70 98 wt % of a high density polyethylene having a density of 930 to 965 kg/m3 and a MFR (190° C./2.16 kg) of 0.3 to 20 g/10 min.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: March 20, 2012
    Assignee: Borealis Technology Oy
    Inventors: Henk Van Paridon, Bert Broeders
  • Patent number: 8129472
    Abstract: The invention provides compositions for blow molding applications and other applications, where such compositions comprise a high molecular weight ethylene interpolymer and a low molecular weight ethylene polymer, and where the high molecular weight ethylene interpolymer has a density from 0.920 g/cm3 to 0.950 g/cm3, and an I21 from 0.05 to 1 dg/min, and where the low molecular weight ethylene polymer has density from 0.965 g/cm3 to 0.985 g/cm3, and an I2 from 600 to 2000 dg/min. The composition has a density from 0.950 g/cm3 to 0.970 g/cm3, and comprises greater from 45 to 80 weight percent of the high molecular component, and from 20 to 55 weight percent of the low molecular weight component, based on the sum weight of the high molecular weight component and the low molecular weight component. The invention also provides for methods of preparing said compositions and for articles prepared from the same.
    Type: Grant
    Filed: April 3, 2007
    Date of Patent: March 6, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Michael D. Turner, Mridula (Babli) Kapur
  • Patent number: 8129465
    Abstract: The present invention is directed to a polymeric material, particularly a thermoplastic material, the includes thermoplastic polyolefin and an elastomer.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: March 6, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: James Thomas Seliskar, James David Oelberg
  • Patent number: 8129473
    Abstract: A polymer blend includes a first random copolymer of propylene and one or more C2-C20 ?-olefins other than propylene having a melting point of above 116° C. and up to about 145° C. and which constitutes from about 60 weight percent to about 95 weight percent of the composition, and a second random copolymer of propylene and one or more C2-C20 ?-olefins other than propylene having a melting point of from about 70° C. to no more than 116° C. and which constitutes from about 5 weight percent to about 40 weight percent of the composition. The polymer blend includes a xylene soluble fraction having a weight average molecular weight of above about 100 kg/mol and an intrinsic viscosity of above about 1.0 dl/g.
    Type: Grant
    Filed: May 10, 2004
    Date of Patent: March 6, 2012
    Assignee: Lummus Novolen Technology GmbH
    Inventors: Ralph-Dieter Maier, Vassilios Galiatsatos, Dean Anthony Roessner, Susan Patricia Setty
  • Patent number: 8129471
    Abstract: A composition comprising: a polycarbonate comprising units derived from a bisphenol cyclohexylidene of the formula: wherein Rc1 and Rd1 are each independently C1-12 alkyl, Rc2 and Rd2 are each independently hydrogen or C1-12 alkyl, Rg is C1-12 alkyl or halogen, and t is 0 to 10; and a poly(ether-ester) copolymer comprising 40 to 60 wt % of polyester hard block units derived from a C6-C24 aromatic dicarboxylic acid or a C6-C24 alicyclic dicarboxylic acid and at least one glycol component, wherein when the C6-C24 aromatic dicarboxylic acid comprises terephthalic acid, isophthalic acid groups are present in an amount from 0 to 30 mole %, based on the total moles of isophthalic acid groups and terephthalic acid groups in the hard block units, and 40 to 60 wt % of polyether soft block units derived from poly(oxytetramethylene) glycol, wherein the molecular weight of the poly(oxytetramethylene) glycol groups is 300 to 1800 Daltons.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: March 6, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Shreyas Chakravarti, Christopher Luke Hein, Peter Hendrikus Theodorus Vollenberg
  • Patent number: 8124702
    Abstract: A stabilizer containing a copolymer (A) obtained by polymerizing an unsaturated monomer mixture including 1 to 50 parts by mass of ethylenically unsaturated monomer (a) (formula (I)) having a piperidyl group in a molecule, 50 to 99 parts by mass of at least one monomer (b) (isobutyl methacrylate, an alkyl (meth)acrylate having an alkyl group with 6 to 13 carbon atoms, or an aromatic vinyl monomer), and 0 to 20 parts by mass of ethylenically unsaturated monomer (c) other than the monomers (a) and (b), where the total of the monomers (a), (b), and (c) is 100 parts by mass: wherein R1 represents H or an alkyl group having 1 to 2 carbon atoms, X represents an oxygen atom or an imino group, Y represents H or an alkyl or alkoxyl group each having 1 to 20 carbon atoms, and Z represents H or a cyano group.
    Type: Grant
    Filed: November 22, 2007
    Date of Patent: February 28, 2012
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Masaaki Kiura, Takahiro Mukuda
  • Patent number: 8119738
    Abstract: There are provided a polypropylene resin composition and a molded article thereof, the composition comprising: 60 to 85% by weight of a propylene homopolymer; and 15 to 40% by weight of an ethylene-?-olefin random copolymer containing 45 to 70 parts by mol of ethylene units, and 30 to 55 parts by mol of ?-olefin units, and satisfying the following requirements (1) to (5), (1) the propylene homopolymer has a melting temperature of 163 to 170° C.; (2) the propylene homopolymer contains 0.01% or less of regio defects resulted from a 2,1-insertion and a 1,3-insertion in all propylene units; (3) the polypropylene resin composition has a ratio B/A of 0.9 or more, provided that A (% by weight) is an amount of the ethylene-?-olefin random copolymer contained in the polypropylene resin composition, and B (% by weight) is an amount of soluble parts in xylene at a room temperature contained in the polypropylene resin composition; (4) the ethylene-?-olefin random copolymer has a molecular weight distribution of 2.
    Type: Grant
    Filed: December 14, 2007
    Date of Patent: February 21, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yasuki Fujiwara, Shuichi Kimata, Hideki Oshima
  • Patent number: 8119581
    Abstract: The invention relates to the use of microgels for modifying the temperature behavior of non-crosslinkable organic media, in particular in high temperature applications at least about 100° C., for example in engine oils, gear oils, etc.
    Type: Grant
    Filed: March 13, 2006
    Date of Patent: February 21, 2012
    Assignees: Rhein Chemie Rheinau GmbH, LANXESS Deutschland GmbH
    Inventors: Achim Fessenbecker, Patrick Galda, Torsten Ziser, Thomas Früh, Werner Obrecht
  • Patent number: 8114522
    Abstract: Disclosed is a resin composition forming an adhesive layer between a polylactic acid resin substrate layer and a polyolefin resin substrate layer. The resin composition includes a modified polyolefin resin (A) and a terpene resin (B), and the mass ratio (A)/(B) between the both resins (A) and (B) is 20/80 to 99/1. Alternatively, the resin composition may be a resin composition including 10 to 90% by mass of a polylactic acid resin (C), 5 to 89% by mass of the modified polyolefin resin (A) and 1 to 80% by mass of a hydrogenated petroleum resin (D), with the total amount of these resins constrained to be 100% by mass.
    Type: Grant
    Filed: February 16, 2009
    Date of Patent: February 14, 2012
    Assignee: Unitika Ltd.
    Inventors: Yuji Kitora, Mitsuhiro Kawahara, Kazue Ueda
  • Patent number: 8110628
    Abstract: Porous particles are prepared using a first water-in-oil emulsion comprising a first marker material in a first aqueous phase that is dispersed in a first oil phase containing a polymer and a first organic solvent, and a second water-in-oil emulsion comprising a second marker material in a second aqueous phase that is dispersed in a second oil phase. The first and second marker materials are detectably different. The two water-in-oil emulsions can be used to form a third water-in-oil emulsion containing distinct droplets of the first and second aqueous phases. This third water-in-oil emulsion is dispersed in a third aqueous phase containing a surface stabilizing agent to form a water-in-oil-in-water emulsion containing droplets of the third water-in-oil emulsion. The organic solvents are removed from the water-in-oil-in-water emulsion to form porous particles comprising first and second discrete pores that are isolated from each other.
    Type: Grant
    Filed: January 4, 2011
    Date of Patent: February 7, 2012
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, Tamara K. Jones, Daniel L. Kapp
  • Patent number: 8110633
    Abstract: A seal for a valve for use in a pharmaceutical dispensing device, which seal is formed from a blend comprising: a thermoplastic elastomer including a propylene component with isotactic crystallinity; and a polymer selected from one or more of polypropylene, polyethylene and copolymers thereof.
    Type: Grant
    Filed: September 4, 2007
    Date of Patent: February 7, 2012
    Assignee: Consort Medical PLC
    Inventor: Daljit Ohbi
  • Patent number: 8106127
    Abstract: An in-reactor polymer blend comprises (a) a propylene-containing first polymer; and (b) an ethylene-containing second polymer such that the polymer blend comprises between about 50 wt % and about 80 wt % units derived from ethylene and between about 50 wt % and about 20 wt % units derived from propylene. The blend is substantially free of dienes and the content of ethylene in the second polymer in the form of ethylene-ethylene-ethylene triads is at least 40%. The second polymer contains at least 0.1 branch having 8 or more carbon atoms per 10,000 carbons. In addition, the blend has a strain hardening index of at least 1.8, a shear thinning slope in the plot of log(dynamic viscosity) versus log(frequency) of less than ?0.2 and exhibits at least two peaks when subjected to Differential Scanning Calorimetry (first melt) corresponding to a first melting point of at least 150° C. and a second melting point of at least 40° C.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 31, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Carlos U. De Gracia, Kevin R. Squire, Peijun Jiang, Armenag H. Dekmezian, Beverly J. Poole, Cesar A. Garcia-Franco
  • Patent number: 8105694
    Abstract: The invention provides a PTFE-containing aqueous dispersion composition which is excellent in mechanical stability and scarcely allows the formation of agglomerates due to fibrillation of the PTFE resin during transportation or processing thereof. This invention is a polytetrafluoroethylene-containing aqueous dispersion composition comprising a polytetrafluoroethylene resin (A), a hydrocarbon-derived nonionic compound (B) and a water-soluble high-molecular compound (C) having no oxygen atom in the main chain thereof.
    Type: Grant
    Filed: March 9, 2006
    Date of Patent: January 31, 2012
    Assignee: Daikin Industries, Ltd.
    Inventors: Yasukazu Nakatani, Toshirou Miura, Yasuhiko Sawada, Hiroshi Torii
  • Patent number: 8101685
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3, wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%. Specifically this invention relates to an in-reactor polymer blend comprising: (a) a first ethylene polymer comprising 90 to 100 wt % ethylene and from 0 to less than 10 wt % comonomer, said first ethylene polymer component having density of greater than 0.920 g/cm3, an Mw of 20,000 g/mol or more; and (b) a second ethylene polymer comprising from 70 to 90 wt % ethylene and 30 to 10 wt % comonomer, said second ethylene polymer having a density of 0.910 g/cm3 or less, wherein the polymer blend has: (a) a Tm of at least 100° C. over a density ranging from 0.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 24, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Patent number: 8101684
    Abstract: A material which is excellent in mechanical strength, solar cell sealing properties, transparency, etc., even in an uncrosslinked state and is used in producing a sheet for solar cell sealing. The thermoplastic resin composition for solar cell sealing comprises (A) 0-70 wt. % propylene polymer having a melting point of 100° C. or higher and (B) 30-100 wt. % propylene copolymer satisfying the following requirements (b). (b) The copolymer has an MFR (230° C., 2.16-kg load) in the range of 0.01-100 g/10 min and satisfies at least one of the following requirements (b-1) and (b-2): (b-1) the rr content is 60% or higher; and (b-2) the copolymer comprises 55-90 mol % structural units derived from propylene and 10-45 mol % structural units derived from a C2-20 ?-olefin (excluding propylene) and has an intrinsic viscosity [?] (dL/g) (measured in 135° C. decalin) satisfying a specific relationship with the MFR.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: January 24, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventor: Hiroshi Hoya
  • Patent number: 8101686
    Abstract: Interpolymer resin particles comprised of 20% to 60% by weight of uncross-linked polyolefin e.g. polyethylene, polypropylene, and from 40% to 80% by weight based on the weight of the particles of a vinyl aromatic monomer, e.g. styrene, that is polymerized in a suspension process to form an interpenetrating network of polyolefin with polymerized vinyl aromatic monomer particles and having a gel content of 0 to 1.5% by weight based on the weight of the particles for improved processability in end-use applications and improved ESCR properties. The interpolymer resin particles have a VICAT softening temperature from about 90° C. to about 115° C., and a melt index from 0.2 to 35.0 g/10 minutes (Condition G). The particles can be mixed with a blowing agent to form extruded foam articles, such as foam board, and can be used in extrusion, injection molding, rotomolding, and thermoforming processes to form a layer, e.g.
    Type: Grant
    Filed: February 4, 2011
    Date of Patent: January 24, 2012
    Assignee: NOVA Chemicals Inc.
    Inventor: Steven M Krupinski
  • Patent number: 8097678
    Abstract: The present invention relates to a polyethylene composition, comprising a base resin which comprises (i) a first fraction which is an ethylene homo- or copolymer, and (ii) a second fraction which is an ethylene copolymer, wherein the first fraction (i) has a lower weight average molecular weight than the second fraction (ii), and the base resin has a density of less than 0.940 g/cm3 and a shear thinning index SHI2.7/210 of at least 25.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: January 17, 2012
    Assignee: Borealis Technology OY
    Inventors: Remko Van Marion, Roger Carlsson, Hans Eklind, Irene Helland
  • Patent number: 8097679
    Abstract: A 1-butene polymer composition comprising: a) from 10% to 90% by weight of an isotactic 1-butene polymer having the following features: i) isotactic pentad (mmmm) measured by 13C-NMR, higher than 90%; ii) melting point (TmII) higher than 90° C.; and iii) intrinsic viscosity (IV) measured in tetrahydronaphthalene (THN) at 135° C. comprised between 0.5 dl/g and 5.0 dl/g. b) from 90% to 10% by weight of a copolymer of 1-butene and at least a C8-C12 alpha-olefin derived units, containing from 0% to 10% by mole of propylene or pentene derived units, and/or containing from 0% to 5% by mole of ethylene derived units having a content of C8-C12 alpha-olefin derived units higher than 4.0% by mol and lower than 20.0% by mol; endowed with the following features: i) isotactic pentad mmmm higher than or equal to 90%; pentads (mmrr+mrrm) lower than 4 and pentad rmmr not detectable by C NMR. ii) intrinsic viscosity (IV) measured in tetrahydronaphthalene at 135° C. comprised between 0.8 and 5.
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: January 17, 2012
    Assignee: Basell Poliolefine Italia
    Inventors: Luigi Resconi, Davide Balboni
  • Patent number: 8093335
    Abstract: This invention relates to a molded article comprising an in-reactor polymer blend comprising: (a) a first propylene polymer comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 135° C. or more; and (b) a second propylene polymer comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend has: (a) a Tm of at least 135° C., (b) a melt flow rate of at least 70 dg/min, (c) a tensile strength of at least 8 MPa, (d) an elongation at break of at least 200%, (e) a tensile strength at break of 10 MPa or more, and (f) a GME 60280 scratch resistance of less than 1.2 DL at a scratching load of 5 Newtons.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: January 10, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Joseph Gustaaf M. Flendrig
  • Patent number: 8088871
    Abstract: A method of polymerizing olefins with catalyst systems, such as, for example, a multimodal catalyst system, wherein the catalyst system is stored at a controlled temperature to minimize loss of catalyst system productivity.
    Type: Grant
    Filed: November 13, 2007
    Date of Patent: January 3, 2012
    Assignee: Univation Technologies, LLC
    Inventors: Natarajan Muruganandam, Jeevan Abichandani, Kersten A. Terry, Hemant G. Patel, George Rodriguez
  • Patent number: 8088866
    Abstract: The present invention relates to a polyethylene composition comprising a base resin which comprises (a) an ethylene homo- or copolymer fraction (A); and (b) an ethylene homo- or copolymer fraction (B), wherein (i) fraction (A) has a lower weight average molecular weight than fraction (B); (ii) the base resin has a density of 932 to 938 kg/m3; (iii) the polyethylene composition has an MFR5 of 0.1 to 0.6 g/10 min; and (iv) the polyethylene composition has a shear stress ?2.7 kPa of 85 to 230 kPas. Furthermore, the present invention relates to an article, preferably a pipe comprising said composition and to the use of said composition for the production of an article, preferably a pipe.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: January 3, 2012
    Assignee: Borealis Technology OY
    Inventors: Mats Bäckman, Lars-Erik Ahlstrand, Per-Ola Hagstrand, Magnus Palmlof
  • Patent number: 8088865
    Abstract: Provided is a method for producing a resin composition by melt-kneading a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200° C. and a flexible polymer (B) having a glass transition temperature of 0° C. or lower, wherein a part of the cyclic olefin polymer (A) is previously melt-kneaded with the flexible polymer (B) and a radical initiator (C) and then the remaining cyclic olefin polymer (A) is added thereto and melt-kneaded. The cyclic olefin polymer (A) is divided into two portions and added separately at two times, and accordingly, the mixture having a crosslinked structure may be diluted with the cyclic olefin polymer (A) not having a crosslinked structure, and the increase in the melt viscosity of the resin composition may be thereby prevented. A composition having good abrasion resistance and good melt shapability can be obtained.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: January 3, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kazuyoshi Kaneko, Toshiyuki Hirose
  • Patent number: 8084019
    Abstract: The present invention is directed to bimodal polymer compositions and personal care fixatives containing bimodal polymer compositions. The present invention includes a bimodal polymer composition having a first polymer with anionic character and a second polymer with cationic character and wherein the polymers form an interpenetrating polymer network. In one embodiment, the present invention also includes personal care fixatives (e.g., health care, hygiene or cosmetic compositions) containing the bimodal polymer composition. The present invention also includes methods for forming bimodal polymer compositions.
    Type: Grant
    Filed: September 16, 2010
    Date of Patent: December 27, 2011
    Assignee: Interpolymer Corporation
    Inventors: Norwin W. Wolff, Timothy L. Martin, Thomas L. Hiff
  • Patent number: 8084547
    Abstract: The invention relates to processes for the production of microgel-containing rubber mixtures, to rubber mixtures obtainable by the processes, to processes for the production of vulcanizates, and also to vulcanizates after the vulcanization process, in particular in the form of tires, parts of tires, or industrial rubber items.
    Type: Grant
    Filed: April 17, 2008
    Date of Patent: December 27, 2011
    Assignee: LANXESS Deutschland GmbH
    Inventor: Werner Obrecht
  • Patent number: 8080610
    Abstract: A monomer recycle process for fluid phase in-line blending of polymers is provided.
    Type: Grant
    Filed: March 4, 2008
    Date of Patent: December 20, 2011
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gabor Kiss, Alan Anthony Galuska, James Richardson Lattner
  • Patent number: 8080308
    Abstract: Disclosed is a moisture curable sealant composition that includes silane functional poly-?-olefin polymer, thermoplastic elastomer, and tackifying agent.
    Type: Grant
    Filed: March 11, 2003
    Date of Patent: December 20, 2011
    Assignee: H.B. Fuller Company
    Inventors: Bing Wang, John E. Greenzweig
  • Patent number: 8080616
    Abstract: Polyolefin composition comprising, in percent by weight: A) 50-75% of a blend of polymers (PP) and (ECI), wherein (PP) is selected from the group consisting of: (i) propylene homopolymers; (ii) copolymers of propylene; (iii) combinations of said homopolymers (i) and copolymers (ii); (EC1) is a copolymer of ethylene and propylene or CH2?CHR alpha-olefin(s), where R is a 2-8 carbon alkyl radical, or a copolymer of ethylene, propylene and the said CH2?CHR alpha-olefin(s), containing from 20 to 35%, of ethylene; and B) 25-50% of a copolymer (ECII) of ethylene and propylene or CH2?CHR alpha-olefin(s), where R is a 2-8 carbon alkyl radical, or a copolymer of ethylene, propylene and the said CH2?CHR alpha-olefin(s), containing from 40 to 60% of ethylene; in which composition the copolymer component (ECI) is present in amounts from 23 to 45% with respect to the total weight of (A), and the intrinsic viscosity [?tot] of the fraction XS soluble in xylene at room temperature, referred to the total weight of (A)+(B), is
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: December 20, 2011
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Giampaolo Pellegatti, Paolo Goberti, Letizia Baraldi, Kazuhiko Minowa, Yukihiro Hisanaga
  • Patent number: 8080607
    Abstract: The present invention is directed to a polymeric material, particularly a thermoplastic material, the includes thermoplastic polyolefin and an elastomer.
    Type: Grant
    Filed: January 11, 2007
    Date of Patent: December 20, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: James Thomas Seliskar, James David Oelberg
  • Patent number: 8080191
    Abstract: A polymer blend has a base and blend components. The base and blend components could be a branched slow crystallizing PET and a faster crystallizing PET, respectively. The ratio of base and blend components result in a block copolymer, the melt processing time and branching or chain extender levels can be can be tailored to impart the polymer blend with sufficient melt strength and crystallization rates, such that it is slow enough during the blow molding process to produce a clear article and yet fast enough during the subsequent PET recycling process making it suitable for extrusion processes as well as for recycling. The combination of materials can be used to form monolayer or multilayer articles.
    Type: Grant
    Filed: October 19, 2007
    Date of Patent: December 20, 2011
    Assignee: PepsiCo, Inc.
    Inventors: Clarence Sequeira, Said Farha
  • Patent number: 8076421
    Abstract: Film layers made from formulated polymer compositions are disclosed. Film layers made from such formulated compositions have surprisingly good (for example, low) water vapor transmission rates and are particularly useful for packaging dry goods such as cereal. The polymer compositions preferably have at least one homogeneous ethylene homopolymer and at least one heterogeneously branched ethylene polymer. The homogeneous ethylene homopolymer has a molecular weight much higher than that of the heterogeneously branched ethylene polymer, although the density of each is preferably higher than about 0.95 g/cm3.
    Type: Grant
    Filed: March 18, 2005
    Date of Patent: December 13, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Mridula Kapur, David A. Eversdyk, Wenbin Liang, Kenneth S. Laverdure, David T. Gillespie
  • Patent number: 8076416
    Abstract: A thermoplastic vulcanizate comprising a dynamically cured rubber, and from about 20 to about 400 parts by weight of a thermoplastic resin per 100 parts by weight rubber, where said thermoplastic resin includes at least 0.1 percent by weight and less than 5.0 percent by weight, based upon the entire weight of said thermoplastic resin, of a long-chain branched polyolefin, with the remainder of said thermoplastic resin including a non-long-chain branched thermoplastic resin, where said long-chain branched polyolefin includes one or more polymers or copolymers having a viscosity average branching index <gN>vis of less than 0.9 and deriving from monomer selected from the group consisting of ethylene and mono-?-olefins, and where said non-long-chain thermoplastic resin includes one or more polymers or copolymers having a viscosity average branching index <gN>vis of 0.9 or more.
    Type: Grant
    Filed: February 4, 2005
    Date of Patent: December 13, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Maria Dolores Ellul
  • Patent number: 8076415
    Abstract: A molding material and a molded article for laser welding are provided, which comprise a thermoplastic resin (A) comprising a rubber-reinforced resin (A1) obtained by polymerizing a vinyl monomer in a presence of a rubber-like polymer (a), or a composition (A2) of the rubber-reinforced resin (A1) and a (co)polymer (b) of a vinyl monomer, and which have a light transmittance at a wavelength of 808 nm in a range of 5% or higher when molded into a 4 mm-thick sample piece. The rubber-like polymer (a) dispersed in the thermoplastic resin (A) preferably has a weight average particle size of 50 to 220 nm, and preferably comprises particles of 300 nm or larger in diameter in an amount of 0 to 20 wt % relative to 100 wt % of the component (a). A laser light can transmit the molding material and the molded article, and allow the molding material and the molded article to be laser-welded with various resin moldings.
    Type: Grant
    Filed: January 29, 2004
    Date of Patent: December 13, 2011
    Assignee: Techno Poly,er Co., Ltd.
    Inventors: Ryoichi Motoshige, Wataru Kakuno
  • Patent number: 8076419
    Abstract: Disclosed is a propylene impact copolymer comprising a first polypropylene having an MFR1 within the range from 15 to 40 dg/min; a second polypropylene having an MFR2 within the range from 50 to 190 dg/min; an elastomeric polymer; and wherein the propylene impact copolymer has an MFRICP within the range from 6 to 18 dg/min; a 1% Secant Flexural Modulus of greater than 150 kpsi (1030 MPa); and an Izod Impact at 25° C. of greater than 10 ft-lbs/in (530 J/m). The impact copolymer may be produced in a two or three tandem-reactor system wherein the catalyst composition used in the second reactor to produce the second polypropylene is different from the catalyst composition used in the first reactor to produce the first polypropylene.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: December 13, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Prasadarao Meka, Kevin Wayne Lawson
  • Patent number: 8076420
    Abstract: Dimercaptan terminated polythioether polymers are disclosed, as are methods for making and using the same.
    Type: Grant
    Filed: November 15, 2010
    Date of Patent: December 13, 2011
    Assignee: PRC DeSoto International, Inc
    Inventors: Suresh G. Sawant, Chandra B. Rao, Michael A. Cosman
  • Patent number: 8076417
    Abstract: The present invention relates to crosslinked, olefin elastic fibers where the olefin materials are specifically selected to provide a more robust fiber with higher tenacity and greater temperature stability. Such fibers will be less subject to breakage during fiber spinning and post-spinning (downstream processing) operations including spool formation and unwinding. The specific olefin material used is a blend having an overall melt index (I2) of less than 2.5 g/10 min before crosslinking with a density in the range of 0.865 to 0.885 g/cm3. One component of the blend will be characterized as having either a density in the range of from 0.855 to 0.88 g/cm3 or a residual crystallinity at 80° C. of greater than 9 percent but not both. The at least one other component will meet at least whichever characteristic the first component does not meet.
    Type: Grant
    Filed: February 7, 2007
    Date of Patent: December 13, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: Shih-Yaw Lai, Yuen-Yuen D Chiu, Ashish Sen, Stephane Costeux
  • Patent number: 8075967
    Abstract: Disclosed is a blended composition comprising a humidity-dependent composition having a ratio of wet cup permeance to dry cup permeance greater than 10 and a crystallizable polymer sufficiently permeable to oxygen, carbon dioxide and water vapor, exhibiting an increase in permeability to at least one of oxygen and carbon dioxide by a factor of at least 2.5 over a temperature range of 10° C. between 0° C. and 40° C. Also disclosed are packaging materials comprising the blended composition and methods for storing respiring materials using the packaging materials.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: December 13, 2011
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: John Chu Chen