Polymer Mixture Of Two Or More Solid Polymers Derived From Ethylenically Unsaturated Reactants Only; Or Mixtures Of Said Polymer Mixture With A Chemical Treating Agent; Or Products Or Processes Of Preparing Any Of The Above Mixtures Patents (Class 525/191)
  • Patent number: 8288480
    Abstract: This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 ?,?-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.
    Type: Grant
    Filed: December 15, 2009
    Date of Patent: October 16, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Kevin R. Squire, Charles J. Ruff, Cesar A. Garcia-Franco
  • Patent number: 8288479
    Abstract: Propylene-based polymers (A) are provided which, when used as pressure-sensitive adhesives to various adherends, show a desired initial adhesion and will not contaminate the adherends and which have excellent pellet handling properties. Pellets of the invention contain the propylene-based polymers (A). Pressure-sensitive adhesives of the invention contain the propylene-based polymers (A). The propylene-based polymer (A) includes 65 to 80 mol % of a structural unit derived from propylene, 5 to 10 mol % of a structural unit derived from ethylene and 15 to 25 mol % of a structural unit derived from a C4-20 ?-olefin (wherein these percentages are calculated based on 100 mol % of the total of the structural unit derived from propylene, the structural unit derived from ethylene and the structural unit derived from a C4-20 ?-olefin) and has a heat of crystal fusion of 5 to 45 (J/g) as measured by DSC. Compositions of the invention contain the propylene-based polymers (A).
    Type: Grant
    Filed: February 14, 2008
    Date of Patent: October 16, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Ikuo Akai, Hiroshi Hoya, Yoji Hayakawa, Koji Matsunaga
  • Patent number: 8288481
    Abstract: Novel polyolefin compositions comprising (A) a first propylene-ethylene random copolymer and (B) a second propylene-ethylene random copolymer, wherein the polyolefin composition has an ethylene content CMAB of 1-10 wt % and an MFR(AB) of 3-20 g/10 min with the proviso that CMAB>CMA and MFR(A)/MFR(AB)>1.45 and where the polyolefin composition further has a randomness R of the ethylene distribution in the polymer chain of ?0.945. Articles made from the novel polyolefin compositions have excellent optical properties even after subjecting them to a heat sterilization step.
    Type: Grant
    Filed: August 26, 2008
    Date of Patent: October 16, 2012
    Assignee: Borealis Technology Oy
    Inventors: Joachim Fiebig, Markus Gahleitner, Pirjo Jääskeläinen, Bo Malm, Tonja Schedenig
  • Patent number: 8288487
    Abstract: The present invention provides a polymerization process utilizing a dual metallocene catalyst system for the production of broad or bimodal molecular weight distribution polymers, generally, in the absence of added hydrogen. Polymers produced from the polymerization process are also provided, and these polymers can have a Mn in a range from about 9,000 to about 30,000 g/mol, and a short chain branch content that decreases as molecular weight increases.
    Type: Grant
    Filed: July 6, 2010
    Date of Patent: October 16, 2012
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Qing Yang, Max P. McDaniel, Tony R. Crain, Youlu Yu
  • Patent number: 8283415
    Abstract: A resin composition comprising at least 0.1% by weight of poly(hydroxy carboxylic acid) and at least 50% by weight of polyethylene prepared with a single-site catalyst, preferably a metallocene.
    Type: Grant
    Filed: February 22, 2010
    Date of Patent: October 9, 2012
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Jean-Michel Brusson, Leen De Groof
  • Patent number: 8283418
    Abstract: Polypropylene composition comprising a) an isotactic polypropylene (iPP) produced in the presence of a single-site catalyst and said isotactic polypropylene (iPP) has a mean isotactic block length between two structural chain defects, as a statistical average, greater than 70, and b) an atactic polypropylene (aPP) with an absorbance ratio of the absorption band at 998 cm?1 to the absorption band at 973 cm?1 [A998/A973] below 0.80 wherein the weight ratio of said atactic polypropylene to the sum of said atactic polypropylene and said isotactic polypropylene (aPP/(aPP+iPP)) is at least 0.50 wt.-%.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: October 9, 2012
    Assignee: Borealis Technology Oy
    Inventors: Werner Posch, Manfred Stadlbauer, Stefan Schiesser
  • Patent number: 8278391
    Abstract: Oriented films and methods of forming the same are discussed herein. The oriented films generally include a propylene based polymer and an additive selected from fluoropolymers, fluoroelastomers and combinations thereof, wherein the additive is present in an amount of from about 50 ppm to about 20,000 ppm.
    Type: Grant
    Filed: June 17, 2010
    Date of Patent: October 2, 2012
    Assignee: Fina Technology, Inc.
    Inventors: Fengkui Li, Ryan Albores, John Ashbaugh, Luyi Sun
  • Patent number: 8278393
    Abstract: According to one aspect, the present invention relates to a low-density polyethylene having a melt index MFR2 of 2.5 to 10.0 g/10 min, a density of 910 to 935 kg/m3, and a dynamic viscosity ?0.05 at a shear rate of 0.05 rad/s and a dynamic viscosity ?300 at a shear rate of 300 rad/s which satisfy the following relationship: ?300?108 Pa*s+0.0253*?0.05. According to a second aspect, the present invention relates to a low-density polyethylene having a melt index MFR2 of 2.5 to 10.0 g/10 min, a density of 910 to 935 kg/m3, and a phase shift ?0.5 at a frequency of 0.5 rad/s and a phase shift ?300 at a frequency of 300 rad/s, which satisfy the following relationship: tan ?300?0.45+0.164*tan ?0.5.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: October 2, 2012
    Assignee: Borealis Technology Oy
    Inventors: Auli Nummila-Pakarinen, Oivind Moen, Pertti Mikkola, Janne Jamsen
  • Publication number: 20120245257
    Abstract: This invention provides a pellet derived from recycled waste products in particular from a mixture of two or more of cellulose fibers, recyclable plastic, glass and ceramics and other recyclable products such as tetra paks. The pellets can be used to make a variety of extruded or injection molded products including household trim and moldings, decking, shutters, etc.
    Type: Application
    Filed: August 26, 2010
    Publication date: September 27, 2012
    Applicant: GLOBAL PATENTED TECHNOLOGIES INC.
    Inventor: Carlo Fascio
  • Patent number: 8273826
    Abstract: Impact modified compositions having good impact performance can be made from a thermoplastic (e.g., a polyolefin such as polypropylene or HDPE) and a multi-block ethylene/?-olefin interpolymer. The compositions are easily molded and often have particular utility in making, for example, automotive facia, parts and other household articles.
    Type: Grant
    Filed: March 26, 2010
    Date of Patent: September 25, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Kim L. Walton, Gary R. Marchand, Shrikant Dhodapkar, Mridula Kapur, Shaofu Wu
  • Patent number: 8273821
    Abstract: The present invention relates to an adhesive composition comprising a mixture of multi-block copolymers, in particular, an adhesive composition comprising a block copolymer represented by Formula 1, a hydrocarbon adhesive resin and a plasticizer. The adhesive composition according to the present invention can be easily processed due to its low melting point and shows improved adhesive properties such as loop tack, 180° peel strength and holding power.
    Type: Grant
    Filed: November 27, 2009
    Date of Patent: September 25, 2012
    Assignee: Korea Kumho Petrochemical Co., Ltd.
    Inventors: Jae Yun Kim, Ok Kil Mun, Eun Kyung Noh
  • Patent number: 8273827
    Abstract: Disclosed is an adhesive composition having adhesion properties, high-speed curing properties and moisture resistance. Also disclosed is an adhesion method. Specifically disclosed is a composition which comprises: a first preparation comprising (A) a nitrile-butadiene rubber, (B) a (meth)acrylic composition, (C) a compound having an enal structure, and (F) a radical polymerization initiator; and a second preparation comprising (A) the nitrile-butadiene rubber, (B) the (meth)acrylic composition, (D) a compound having an amine structure, and (E) a compound containing copper. Also disclosed is a composition which comprises: a first preparation comprising (A) a nitrile-butadiene rubber, (B) a (meth)acrylic composition, (D) a compound having an amine structure, and (F) a radical polymerization initiator; and a second preparation comprising (A) the nitrile-butadiene rubber, (B) the (meth)acrylic composition, (C) a compound having an enal structure, and (E) a compound containing copper.
    Type: Grant
    Filed: October 8, 2009
    Date of Patent: September 25, 2012
    Assignee: Denki Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yuki Hisha, Kimihiko Yoda, Kazuhiro Oshima
  • Patent number: 8268927
    Abstract: A water redispersible polymer powder is produced by drying an aqueous mixture of a high Tg carboxylated styrene butadiene polymer and a low Tg carboxylated styrene butadiene polymer, where the ratio of the mean or average particle size of the high Tg polymer to the particle size of the low Tg polymer is from 1:1 to 5:1, preferably from 1:1 to 3:1, and the amount of the high Tg polymer is from 20 wt. % to 35 wt. %, preferably from 25 wt. % to 30 wt. %, based upon the total weight of the high Tg polymer and the low Tg polymer. Cement compositions such as mortars, which contain the redispersible polymer powder exhibit unexpectedly superior high bond strength and high impact resistance.
    Type: Grant
    Filed: June 23, 2011
    Date of Patent: September 18, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Robert Baumann, Juergen Dombrowski, Hartmut Kuehn, Etienne Lazarus, Gerold A Lohmuller, Margarita Perello, Yafei Zhu
  • Patent number: 8268425
    Abstract: The invention relates to a polyethylene molding composition which has a multimodal molar mass distribution and is particularly suitable for producing external sheathing of electric or information transmission cables. The molding composition has a density at a temperature of 23° C. in the range from 0.94 to 0.95 g/cm3 and an MFI190/5 in the range from 1.2 to 2.1 dg/min. It comprises from 45 to 55% by weight of a low molecular weight ethylene homopolymer A, from 30 to 40% by weight of a high molecular weight copolymer B of ethylene and another olefin having from 4 to 8 carbon atoms and from 10 to 20% by weight of an ultra high molecular weight ethylene copolymer C. The invention also relates to an electric or information transmission cable having an external sheath of the polyethylene molding composition which has a thickness in the range from 0.2 to 3 cm.
    Type: Grant
    Filed: November 17, 2005
    Date of Patent: September 18, 2012
    Assignee: Basell Polyolefine GmbH
    Inventors: Heinz Vogt, Joachim Berthold
  • Patent number: 8263706
    Abstract: An acrylic polymeric composition comprising a melt blend of a thermoplastic high molecular weight acrylic material (HMWA) and a thermoplastic low molecular weight acrylic material (LMWA) is described. At least 70% w/w of the HMWA and the LMWA comprises an alkyl (alk)acrylate (co)polymer. The HMWA has a weight average molecular weight (Mw) of between 40 k Daltons and 1000 k Daltons and the LMWA has a weight average molecular weight (Mw) of between the entanglement molecular weight (Me) (expressed in k Daltons) and 250 k Daltons. A method of producing an acrylic polymeric composition and the use of an acrylic polymeric composition are described together with thick section molded products.
    Type: Grant
    Filed: April 18, 2006
    Date of Patent: September 11, 2012
    Assignee: Lucite International UK Limited
    Inventors: Ian Fraser, Ian Robinson
  • Patent number: 8263707
    Abstract: The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C.
    Type: Grant
    Filed: April 3, 2008
    Date of Patent: September 11, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Charles L. Sims, Peijun Jiang, Abdelhadi Sahnoune, Derek W. Thurman
  • Patent number: 8258240
    Abstract: The present invention provides a water-dispersed acrylic PSA composition suitable for forming a PSA sheet. The PSA composition contains 0.5 to 15 parts by weight of an acrylic copolymer (polymer H) with a Tg of 30° C. to 120° C. in relation to 100 parts by weight of an acrylic copolymer (polymer L) with a Tg of ?70° C. to ?50° C. The polymer L is obtained by polymerization of a monomer starting material comprising 60 wt % or more of an alkyl (meth)acrylate with a C8-C12 alkyl group; and 0.5 to 10 wt % of a radical polymerizable monomer with a carboxyl group.
    Type: Grant
    Filed: October 14, 2009
    Date of Patent: September 4, 2012
    Assignee: Nitto Denko Corporation
    Inventors: Toshihide Suzuki, Kenichi Yamamoto, Yutaka Tosaki, Akiko Takahashi
  • Patent number: 8252397
    Abstract: This invention relates to film used to manufacture pouches and bags for containing flowable material. The film is made of low density polyethylene and can be formed into a monofilm or a multi-layer film that can be used to produce packages that exhibit improved flex crack resistance.
    Type: Grant
    Filed: April 26, 2007
    Date of Patent: August 28, 2012
    Assignee: Liqui-Box Corporation
    Inventor: Alan Keith Breck
  • Patent number: 8247496
    Abstract: The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one halogen group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.
    Type: Grant
    Filed: December 5, 2005
    Date of Patent: August 21, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Walter Harvey Waddell, David Yen-Lung Chung, Robert Christopher Napier, Donald Sheley Tracey
  • Patent number: 8247495
    Abstract: Elastomeric polymer blends and processes for their production are described. Specifically, the polymer blends comprise a first polymer and a second polymer, where the first polymer comprises from about 70 wt % to about 90 wt % units derived from propylene and from about 10 wt % to about 30 wt % units derived from ethylene and/or a C4-C10 alpha-olefin, and the second polymer comprises from about 88 wt % to about 98 wt % units derived from propylene and from about 2 wt % to about 12 wt % units derived from ethylene and/or a C4-C10 alpha-olefin. The elastomeric polymer blends are further characterized by having two or more of the following properties: an overall propylene content of between about 75 wt % and about 90 wt %, a melting point between about 110° C. and about 145° C., a Vicat softening point greater than about 45° C.
    Type: Grant
    Filed: January 27, 2011
    Date of Patent: August 21, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Rainer Kolb, John W. Chu, Gabor Kiss, Robert P. Reynolds, Jr., Jean-Roch Schauder, Thomas T. Sun
  • Patent number: 8247494
    Abstract: A rubber composition comprising: a cured rubber; and thermoplastic resin, where the thermoplastic resin is in the form of discrete domains dispersed within a continuous phase of the cured rubber, and where the cured rubber includes silicon-containing crosslinks.
    Type: Grant
    Filed: November 8, 2010
    Date of Patent: August 21, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Edward J. Blok, Maria D. Ellul, Sunny Jacob, Alfred V. Pickett
  • Patent number: 8236898
    Abstract: A melt-mixed composition of non-melt flowable polytetrafluoroethylene (PTFE) and melt-fabricable perfluoropolymer is provided that exhibits thixotropy at increasing shear rate in the molten state and high elongation at break even at PTFE concentrations well above 4 wt %, based on the combined weight of the PTFE and the perfluoropolymer, e.g. at least 200% up to at least 30 wt % PTFE, the composition also exhibiting the structure of a dispersion of submicrometer-size particles of the PTFE in a continuous phase of the melt-fabricable perfluoropolymer.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: August 7, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Heidi Elizabeth Burch, Sundar Kilnagar Venkataraman, Ralph Munson Aten
  • Patent number: 8236896
    Abstract: Disclosed are a powdery processing aid for polyolefin resins, containing an alkyl methacrylate polymer which has alkyl methacrylate units having an alkyl group with 2 to 6 carbon atoms as a main component and has a mass average molecular weight of 150,000 to 20,000,000, having good handling properties as a powder, having good dispersibility in polyolefin resins, and being able to improve shaping processability of polyolefin resins; and a polyolefin resin composition having improved shaping processability, which contains a powdery processing aid for polyolefin resins and a polyolefin resin.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: August 7, 2012
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Youko Hatae, Masaaki Kiura, Hideo Aoki, Osamu Okunaka, Toshihiro Kasai
  • Patent number: 8232350
    Abstract: Adhesive encapsulating compositions for use in electronic devices such as organic electroluminescent devices, touch screens, photovoltaic devices, and thin film transistors are disclosed herein. The adhesive encapsulating compositions include pressure sensitive adhesives comprising one or more polyisobutylene resins, in combination with optional multifunctional (meth)acrylate monomers and/or optional tackifiers.
    Type: Grant
    Filed: April 28, 2009
    Date of Patent: July 31, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Jun Fujita, Nami Kobori, Vivek Bharti, Fred B. McCormick, Serena L. Mollenhauer
  • Patent number: 8227552
    Abstract: The invention generally provides for methods for controlling polymer properties. In particular, invention provides for methods for controlling the comonomer composition distribution of polyolefins such as ethylene alpha-olefin copolymers by altering at least one or more of the following parameters: the molar ratio of hydrogen to ethylene, the molar ratio of comonomer to ethylene, the partial pressure of ethylene, and the reactor temperature without substantially changing the density and/or the melt index of the copolymer.
    Type: Grant
    Filed: October 19, 2011
    Date of Patent: July 24, 2012
    Assignee: Univation Technologies, LLC
    Inventors: Rainer Kolb, James M. Farley, John F. Szul, Mark P. Ossowski
  • Patent number: 8227550
    Abstract: Filled polyolefin compositions comprising: A) from 15% to 55% by weight of a polypropylene component; B) from 20% to 80% by weight of a filler; C) from 4% to 25% of an elastomeric polymer or polymer composition; wherein the percentages of A), B) and C) are referred to the sum of A) B) and C), and A) is selected from the following compositions: a) a polypropylene composition containing from 20% to 80% by weight of a polypropylene fraction AI) having a Melt Flow Rate L (MFRI) value of 500 g/10 min. or more, and from 20% to 80% by weight of a polypropylene fraction AII) having a Melt Flow Rate L (MFRII) value of from 0.1 to 30 g/10 min., the said percentages of AI) and AII) being referred to the sum of AI) and AII); or b) a polypropylene composition containing from 15% to 72% by weight of a polypropylene fraction AI) having a Melt Flow Rate L (MFRI) value of 500 g/10 min. or more, from 15% to 70% by weight of a polypropylene fraction AII) having a Melt Flow Rate L (MFRII) value of from 0.1 to 30 g/10 min.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: July 24, 2012
    Assignee: Basell Poliolefine Italia s.r.l.
    Inventors: Enrico Masarati, Enrico Costantini, Marco Consalvi
  • Patent number: 8227547
    Abstract: This invention relates to a foamable blend comprising an in-reactor polymer blend comprising: (a) a first propylene polymer component comprising 90 to 100 wt % propylene and from 0 to less than 10 wt % comonomer, said first propylene component having a Tm of 120° C. or more; and (b) a second propylene polymer component comprising from 30 to 90 wt % propylene and 70 to 10 wt % comonomer, said second propylene polymer having an Mw of 30,000 g/mol or more, and said second propylene-containing polymer having a crystallinity different by at least 5% from the first polymer, wherein the polymer blend, prior to combination with a foaming agent, has: (i) a Tm of at least 120° C.; (ii) a MFR of 10 dg/min or more; (iii) a tensile strength of at least 8 MPa; (iv) an elongation at break of at least 200%, and (v) a ratio of elongational viscosity at break to linear viscosity of 5 or more when the elongational viscosity is measured at a strain rate of 1 sec?1 and temperature of 180° C.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: July 24, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Abdelhadi Sahnoune, Armenag Dekmezian
  • Patent number: 8227546
    Abstract: Multi-layer elastic air quenched blown film structures are disclosed which include: a first layer incorporating a propylene-based copolymer and optionally, a linear low density polyethylene or a low density polyethylene; and at least one second layer incorporating a linear low density polyethylene copolymer and optionally, a propylene-based copolymer and/or a low density polyethylene. Alternatively the second layer of the film structures may contain an in-reactor blend of a substantially linear polyethylene (or a homogeneously branched linear polyethylene) and a linear low density polyethylene. The film structures show an excellent balance of Dart impact, Elmendorf tear (in both the machine direction and cross direction), elastic holding force and elastic recovery.
    Type: Grant
    Filed: October 6, 2006
    Date of Patent: July 24, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Shaun S. Parkinson, Martin M. Hill, John Garnett
  • Publication number: 20120178879
    Abstract: The present invention relates to a process for recycling product streams that have been separated from a hydrocarbon-containing feed stream comprising olefin monomer, olefin co-monomer, hydrocarbon diluent and components such as H2, N2, O2, CO, CO2, and formaldehyde. In accordance with the present process a hydrocarbon-containing feed stream is separated into a) a first side stream comprising hydrocarbon diluent and olefin monomer; b) a second side stream which is substantially hydrogen-free and comprises hydrocarbon diluent and olefin monomer, c) a bottom stream comprising substantially olefin-free hydrocarbon diluent, and d) an overhead vapor stream comprising olefin monomer, hydrocarbon diluent and components such as formaldehyde, H2, N2, O2, CO and CO2. The present process further includes recycling said first and said second side streams in a polymerization process for preparing bimodal polyolefin.
    Type: Application
    Filed: September 10, 2010
    Publication date: July 12, 2012
    Applicant: TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Denis Mignon, David Vandewiele, Bernard Van Der Schrick, Camille Vercruysse
  • Patent number: 8217117
    Abstract: An optical film having at least one layer formed of a polyolefin based resin composition containing 8 to 30 wt % of a component (A) defined below and 92 to 70 wt % of a component (B) defined below, with the proviso that the total of the component (A) and the component (B) is 100 wt %: component (A): an olefin based polymer with which neither a crystal fusion peak having a crystal fusion heat of 30 J/g or more nor a crystallization peak having a crystallization heat of 30 J/g or more to be observed in the range of ?50 to 200° C. is observed in a differential scanning calorimetry measurement according to JIS K 7122; and component (B): a propylene based polymer with which a crystal fusion peak having a crystal fusion heat larger than 30 J/g or a crystallization peak having a crystallization heat larger than 30 J/g to be observed in the range of ?50 to 200° C. is observed in a differential scanning calorimetry measurement according to JIS K 7122.
    Type: Grant
    Filed: September 18, 2008
    Date of Patent: July 10, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kyoko Hino, Hiroaki Takahata, Ayako Yada
  • Patent number: 8217116
    Abstract: The present disclosure describes a polypropylene resin composition useful for the preparation of buried structures such as corrugated, non-pressure pipe.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: July 10, 2012
    Assignee: Braskem America, Inc.
    Inventor: Antonios Doufas
  • Patent number: 8211981
    Abstract: Disclosed is a poly(4-methyl-1-pentene) resin composition having an excellent balance between micropore formability and toughness, which can sufficiently form fine pores by drawing and does not cause a break during drawing. The poly(4-methyl-1-pentene) resin composition contains 0-90 parts by mass of a 4-methyl-1-pentene homopolymer (A) and 10-100 parts by mass of a 4-methyl-1-pentene copolymer (B) having a structural unit derived from 4-methyl-1-pentene and a structural unit derived from a C2-20 ?-olefin other than 4-methyl-1-pentene. The content of the structural unit derived from a C2-20 ?-olefin other than 4-methyl-1-pentene is 0.1-2.1% by mass relative to the total amount of the homopolymer (A) and the copolymer (B). The poly(4-methyl-1-pentene) resin composition also contains 0.1-800 ppm of a nucleator (C) relative to the total weight of the homopolymer (A) and the copolymer (B).
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: July 3, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tooru Tanaka, Youhei Houtani, Atsushi Morita
  • Patent number: 8207269
    Abstract: A terpolymer containing: a) from 90% to 50% by weight; preferably from 90% to 70% by weight of ethylene derived units; b) from 5% to 40% by weight; preferably from 5% to 20% by weight of derived units of alpha olefin of formula CH2?CHA wherein A is a C1-C20 alkyl radical; c) from 2% to 30% by weight, preferably from 5% to 20% by weight of cycloolefins derived units. Said terpolymer being characterized by the following features i) distribution of molecular weight Mw/Mn lower than 3.5; preferably lower than 3; more preferably lower than 2.7 ii) solubility in xylene at 25° C. higher than 99%.
    Type: Grant
    Filed: November 26, 2008
    Date of Patent: June 26, 2012
    Assignee: Basell Polyolefine GmbH
    Inventors: Fabiana Fantinel, Shahram Mihan
  • Patent number: 8207270
    Abstract: Provided are thermoplastic elastomer compositions, many dynamically vulcanized, with superior crystallization kinetics, methods for making the compositions and articles made therefrom. The thermoplastic elastomer compositions comprise at least a propylene polymer thermoplastic, a rubber and a crystallization additive. The processes for preparation of the thermoplastic elastomer compositions comprises dynamic vulcanization of mixture of a propylene polymer thermoplastic, a rubber and a cure agent followed by addition of a crystallization additive. Further, preparation of articles from the thermoplastic elastomer compositions may be accomplished through traditional thermoforming operations useful with conventional thermoplastics.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: June 26, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Randal Howard Kerstetter, III, Gary Keith Lawrence
  • Patent number: 8207267
    Abstract: A partly cross-linked thermoplastic elastomer polyolefin composition intended to be converted by any plastics processing technique into a molded part, such as a cover for housing a vehicle's safety airbag, comprises an olefin polymer of polypropylene type, at least one copolymer of ethylene-alpha-olefin type, at least one cross-linking agent and a free radicals formation agent characterized in that a) the olefin polymer of polypropylene type is chosen from the group of polypropylene/ethylene or polypropylene/?-olefin copolymers and selected from those having an impact resistance of at least 40 kJ/m2 when measured using the notched Izod impact resistance test at 23° C. in accordance with ISO standard 180. b) at least one copolymer of the ethylene-?-olefin type is selected from the group formed by those having a density at least equal to 0.870 g/cm3 in accordance with ISO standard 1183. c) at least one thermoplastic elastomer is introduced into the composition.
    Type: Grant
    Filed: December 22, 2005
    Date of Patent: June 26, 2012
    Assignee: Multibase SA
    Inventors: Alexis Von Tschammer, Daniel Milesi
  • Patent number: 8202941
    Abstract: A heat-shrinkable film. The film comprising at least one layer having at least one propylene-based polymer comprising 60 wt % to 98 wt % propylene derived units and 2 wt % to 40 wt % one or more other alpha olefins, the propylene-based polymer having: a triad tacticity of 70% or more, a heat of fusion of less than 80 J/g, a weight average molecular weight (Mw) as measured by GPC of from 70,000 to 250,000. The layer also comprises at least one thermoplastic resin and at least one hydrocarbon resin.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: June 19, 2012
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventors: Jay K. Keung, Peijun Jiang
  • Patent number: 8202943
    Abstract: A fluidity-improving agent containing 0.5 to 99.5 parts by mass of a polymer (A) which is obtained by polymerizing a monomer mixture (a) containing 0.5 to 99% by mass of (a1) an aromatic vinyl monomer, 0.5 to 99% by mass of (a2) a phenyl(meth)acrylate or a phenyl(meth)acrylate containing a substituent in a phenyl group, and 0.5 to 5% by mass of (a3) a vinyl monomer including a functional group (X), and 0.5 to 99.5 parts by mass of a polymer (B) which is obtained by polymerizing a monomer mixture (b) containing (b1) a phenyl(meth)acrylate or a phenyl(meth)acrylate containing a substituent in a phenyl group with a compound including a functional group (Y) reactive with the functional group (X), where the total of the polymer (A) and the polymer (B) is 100 parts by mass.
    Type: Grant
    Filed: December 25, 2007
    Date of Patent: June 19, 2012
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Shinji Matsuoka, Yasuhiko Nabeshima
  • Patent number: 8202940
    Abstract: Bimodal polyethylene compositions and methods for making the same are provided. In at least one specific embodiment, the bimodal polyethylene composition can include a high molecular weight component having a weight average molecular weight (Mw) of from about 400,000 to about 950,000. The bimodal polyethylene composition can also include a low molecular weight component having a weight average molecular weight (Mw) of from about 3,000 to about 100,000. The high molecular weight component can be present in an amount ranging from about 25 wt % to about 40 wt % of the bimodal polyethylene composition. The bimodal polyethylene composition can also have a percent die swell of less than about 80%.
    Type: Grant
    Filed: November 23, 2009
    Date of Patent: June 19, 2012
    Assignee: Univation Technologies, LLC
    Inventors: Stephen P. Jaker, Sun-Chueh Kao, Dongming Li, Daniel P. Zilker, Jr., Ching-Tai Lue
  • Patent number: 8202942
    Abstract: The present invention relates to fibers and nonwovens made from plasticized polyolefin compositions comprising a polyolefin and a non-functionalized hydrocarbon plasticizer.
    Type: Grant
    Filed: June 1, 2011
    Date of Patent: June 19, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Wen Li, Chon-Yie Lin, Bryan R. Chapman, Michael B. Kelly
  • Patent number: 8198373
    Abstract: Plastic toughened plastics include a polymer composition having a polypropylene component and a second polymer component. The polypropylene component is present in an amount from about 50 to about 95 weight percent based on the total weight of the blend. The second polymer component is present in an amount from about 5 to about 50 weight percent based on the total weight of the blend, is a BOCD or BCD blend of at least two ssPE components, and has an overall density greater than about 0.90 g/cm3. Optionally, the plastic toughened plastics include one or more third polymer component selected from propylene-olefin elastomers and ethylene-propylene rubbers, which are present in an amount from about 1 to about 50 weight percent, based on the total weight of the blend.
    Type: Grant
    Filed: October 2, 2006
    Date of Patent: June 12, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Patrick Brant, Bryan R. Chapman, Narayanaswami Raja Dharmarajan, Prasadarao Meka
  • Patent number: 8198200
    Abstract: An extruded web is disclosed. The extruded web can be either a nonwoven material of a films. The web comprises a plasto-elastic material where the plasto-elastic material is a combination of a first polyolefin and a second polyolefin (either a polymeric blends or a polymeric mixture). The claimed combination of polyolefins results in a material that has substantially plastic properties when a sample taken from said web is subjected to an initial strain cycle (such that the web is provided with a set of at least 30% by an initial strain cycle) and substantially elastic properties when a sample taken from the web is subjected to at least a second strain cycle.
    Type: Grant
    Filed: March 23, 2005
    Date of Patent: June 12, 2012
    Assignee: The Procter & Gamble Company
    Inventors: Jean-Philippe Marie Autran, Donald Carroll Roe
  • Patent number: 8193273
    Abstract: A thermoplastic elastomer (TPE) is disclosed which has excellent compression set and adhesion to both polyamide 6 and polyamide 6,6 for use in two-part component polymer structures.
    Type: Grant
    Filed: May 17, 2007
    Date of Patent: June 5, 2012
    Assignee: Polyone Corporation
    Inventors: Charles Page, Dirk von Falkenhayn
  • Patent number: 8188189
    Abstract: A resin composition, comprising (a) 50 to 99% by weight of a crystalline polypropylene resin, and (b) 1 to 50% by weight of a propylene copolymer comprising 50 to 85% by mol of a propylene unit and 15 to 50% by mol of a C8-12 ?-olefin unit, the propylene copolymer having (1) no meting point in a range of ?100 to 200° C., or a melting point of 50° C. or lower in that temperature range, (2) an isotactic selectivity of 90% or higher, (3) a molecular weight distribution of 3 or smaller, and (4) an intrinsic viscosity of 0.1 to 10 dl/g.
    Type: Grant
    Filed: April 14, 2009
    Date of Patent: May 29, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Sogoh, Katsuhiro Yamada, Hisakatsu Hama, Masaaki Tsutsubuchi
  • Patent number: 8188190
    Abstract: A method of modifying the rheology of a thermoplastic resin that includes the steps of providing a thermoplastic resin and blending interpolymer resin particles with the thermoplastic resin. The interpolymer resin contains a styrenic polymer intercalated within a polyolefin, such that the thermoplastic resin is present as a continuous phase and the interpolymer resin is present as a dispersed phase. The method provides a rheology modified thermoplastic resin with improved physical characteristics.
    Type: Grant
    Filed: October 21, 2011
    Date of Patent: May 29, 2012
    Assignee: NOVA Chemicals Inc.
    Inventor: Eric Vignola
  • Patent number: 8188187
    Abstract: The present invention relates to a composition comprising thermoplastic materials and crosslinked microgels which are not crosslinked by high-energy radiation, processes for its preparation, its use for the production of thermoplastically processable shaped articles and shaped articles produced from the composition.
    Type: Grant
    Filed: September 23, 2004
    Date of Patent: May 29, 2012
    Assignees: LANXESS Deutschland GmbH, Rhein Chemie Rheinau GmbH
    Inventors: Ludger Heiliger, Thomas Früh, Volker Müller, Heiko Tebbe, Werner Obrecht, Robert Hans Schuster, Martin Müller
  • Patent number: 8188188
    Abstract: A thermoplastic resin composition production method wherein melt-kneading is performed in a stretched flow when producing a thermoplastic resin composition as specified in the paragraph (I) or (II) below: (I) a thermoplastic resin composition comprising a Thermoplastic resin (A) and a Resin (B) with a reactive functional group; (II) a thermoplastic resin composition comprising a Thermoplastic resin (A), a Thermoplastic resin (C) that is different from the Thermoplastic resin (A), and a Compound (D) with a reactive functional group.
    Type: Grant
    Filed: March 25, 2009
    Date of Patent: May 29, 2012
    Assignee: Toray Industries, Inc.
    Inventors: Sadayuki Kobayashi, Hideo Matsuoka, Makiko Saito, Masaru Akita
  • Patent number: 8183323
    Abstract: A molding material and a molded article for laser welding are provided, which comprise a thermoplastic resin (A) comprising a rubber-reinforced resin (A1) obtained by polymerizing a vinyl monomer in a presence of a rubber-like polymer (a), or a composition (A2) of the rubber-reinforced resin (A1) and a (co)polymer (b) of a vinyl monomer, and which have a light transmittance at a wavelength of 808 nm in a range of 5% or higher when molded into a 4 mm-thick sample piece. The rubber-like polymer (a) dispersed in the thermoplastic resin (A) preferably has a weight average particle size of 50 to 220 nm, and preferably comprises particles of 300 nm or larger in diameter in an amount of 0 to 20 wt % relative to 100 wt % of the component (a). A laser light can transmit the molding material and the molded article, and allow the molding material and the molded article to be laser-welded with various resin moldings.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: May 22, 2012
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Ryoichi Motoshige, Wataru Kakuno
  • Publication number: 20120122359
    Abstract: Adhesive (co)polymers of this disclosure comprise: a) an isobutylene copolymer having pendent succinate groups and optionally a tackifier. The pendent succinic acid groups ionically crosslinks the isobutylene copolymer by hydrogen boding with adjacent pendent succinic acid groups.
    Type: Application
    Filed: October 27, 2011
    Publication date: May 17, 2012
    Inventors: Hae-Seung Lee, Joon Chatterjee, Gregg A. Caldwell, Babu N. Gaddam
  • Patent number: 8178623
    Abstract: The present invention relates to polypropylene impact copolymer compositions which exhibit improved stiffness without degrading the impact resistance performance. The polypropylene impact copolymer comprises a matrix and a dispersed phase. The matrix comprises a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which comprises more than 50 wt. % of units derived from propylene monomer. The matrix should have a relatively high crystallinity, preferably 50% or greater. The polypropylene homopolymer or a propylene/alpha-olefin random copolymer preferably has a MWD between 4 and 8, such as typically obtained using Ziegler-Natta catalysts. The dispersed phase in the impact copolymer comprises an ethylene-propylene copolymer which comprises from 45 to 70 wt. % of units derived from an ethylene monomer. Preferably the dispersed phase comprises from 20 to 50 percent by weight of the polypropylene impact copolymer.
    Type: Grant
    Filed: June 10, 2010
    Date of Patent: May 15, 2012
    Assignee: Dow Global Technologies LLC
    Inventor: Chai-Jing Chou
  • Patent number: 8177239
    Abstract: In order to make an elastomeric sealing element available which is also suitable, in particular, for sealing tasks, with which the highest thermal and chemical resistance is partially required, and at the same time to save on costs and resources it is suggested that the elastomeric sealing element comprise a first and a second sealing section, wherein the first sealing section is produced with the use of a first elastomeric material containing a first cross-linking system, wherein the second sealing section is produced with the use of a second elastomeric material containing a second cross-linking system, wherein the first and the second sealing sections border directly on one another in a seam area and their elastomeric materials are materially joined to one another, and wherein at least one of the two cross-linking systems comprises, in addition, a cross-linking agent for the respectively other elastomeric material.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: May 15, 2012
    Assignee: ElringKlinger AG
    Inventor: Roy Hornig