Solid Polymer Derived Solely From Phenolic Reactants Wherein None Of The Reactants Contains A Plurality Of Methylol Groups Or Derivatives Thereof Patents (Class 525/390)
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Patent number: 8470930Abstract: The present invention relates to novolak resins prepared with, inter alia, one or more alkylphenols. The invention further relates to compositions comprising the novolak resins, such as vulcanizable rubber compositions, and to products obtained therewith.Type: GrantFiled: September 10, 2008Date of Patent: June 25, 2013Assignee: SI Group, Inc.Inventors: L. Scott Howard, Todd M. Aube, Timothy Edward Banach, James J. Lamb
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Publication number: 20130158147Abstract: Disclosed are random copoly(phosphonate carbonate)s with the high molecular weight and narrow molecular weight distribution exhibiting a superior combination of properties compared to prior art.Type: ApplicationFiled: February 11, 2013Publication date: June 20, 2013Applicants: BAYER MATERIAL SCIENCE AG, FRX POLYMERS, INC.Inventors: FRX Polymers, Inc., Bayer Material Science AG
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Publication number: 20130115440Abstract: Embodiments include methods of forming a composite. The methods can include providing a foam core, wherein the foam core includes a foam having a softening point of 90° C. to 110° C., covering a portion of the foam core with a prepreg, contacting the prepreg that covers the portion of the foam core with a curable composition, and curing the prepreg and the curable composition to form the composite, wherein the prepreg insulates the foam core during the curing so that the foam maintains a temperature that is below the softening point. Embodiments include a composite obtained by curing the prepreg and the curable composition. Embodiments include B-stageable formulation having a resin component and a hardener component.Type: ApplicationFiled: May 27, 2011Publication date: May 9, 2013Inventors: Bernd Hoevel, Martine M. Rousse, Alain M. Sagnard, Marvin L. Dettloff, Radhakrishnan Karunakaran
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Patent number: 8436108Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.Type: GrantFiled: May 3, 2012Date of Patent: May 7, 2013Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8415450Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues, 2,2,4,4-tetramethyl-l,3-cyclobutanediol, and 1,4-cyclohexanedimethanol, wherein the inherent viscosity of said polyester is from 0.55 to 0.68 dL/g as determined in 60/40(wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a Tg from 110 to 160° C.; wherein the polyester composition comprises no polycarbonate; wherein the melt viscosity of the polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.; and wherein the polyester has a notched Izod impact strength, of at least 7.5 ft-lb/in.ch at 23° C. according to ASTM D256 with a 10-mil notch in a ? inch thick bar. The polyesters may be manufactured into articles of manufacture as fibers, films, bottles or sheets.Type: GrantFiled: January 12, 2012Date of Patent: April 9, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20130052462Abstract: The invention provides networked polymeric nanofibers having a structure in which amorphous polymeric fibers are branched at multiple sites and having a diameter of from 1 nanometer to 100 nanometers. A solution of a polymer such as polystyrene in a good solvent thereof is rapidly frozen to form a nanoscale phase-separation structure of the polymer and the frozen solvent. The networked polymeric nanofibers can then be obtained upon removing the frozen solvent.Type: ApplicationFiled: February 14, 2011Publication date: February 28, 2013Applicant: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Izumi Ichinose, Xinsheng Peng, Sadaki Samitsu, Rui Zhang
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Patent number: 8372916Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.Type: GrantFiled: May 3, 2012Date of Patent: February 12, 2013Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8367755Abstract: There are provided a thermoplastic resin composition excellent in a balance between fluidity and low outgassing, and a molded product and a sheet including the thermoplastic resin composition. The thermoplastic resin composition may include from 70 to 99% by mass of (A) a polyphenylene ether, from 1 to 30% by mass of (B) a copolymer including an aromatic vinyl compound and an unsaturated dicarboximide derivative as constituent monomers, and from 0 to 20% by mass of (C) a copolymer including an aromatic vinyl compound and a cyanided vinyl compound as constituent monomers, based on 100% by mass of the total of the (A) component, the (B) component and the (C) component, wherein the (B) component has a weight-average molecular weight of from 70,000 to 250,000.Type: GrantFiled: November 6, 2008Date of Patent: February 5, 2013Assignee: Asahi Kasei Chemicals CorporationInventor: Kazunori Terada
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Patent number: 8357450Abstract: The present invention provides a polyamide-polyphenylene ether resin composition comprising a polyamide having an alicyclic structure and composed of dicarboxylic acid units comprising from 20 to 100 mol % of cyclohexanedicarboxylic acid units and diamine units comprising aliphatic diamine units with from 6 to 12 carbon atoms, a polyphenylene ether, and a compatibilizer for a polyamide and a polyphenylene ether.Type: GrantFiled: June 3, 2008Date of Patent: January 22, 2013Assignee: Asahi Kasei Chemicals CorporationInventors: Takaaki Miyoshi, Hiroaki Furukawa
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Patent number: 8354491Abstract: Described are container(s) comprising polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 15 to 50 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 50 to 85 mole % 1,4-cyclohexanedimethanol residues; wherein the total mole % of said dicarboxylic acid component is 100 mole %, and the total mole % of said glycol component is 100 mole %; wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a 1/8-inch thick bar; and wherein the melt viscosity of said polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.Type: GrantFiled: January 28, 2011Date of Patent: January 15, 2013Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
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Publication number: 20130005853Abstract: Fiber reinforced epoxy resin composites are produced using a specific epoxy resin system. The epoxy resin system contains at least one polyglycidyl ether of a polyphenol. The system also contains a hardener that contains a mixture of aminocyclohexanealkylamine and polyalkylene polyamine hardeners. The ratio of epoxy resin groups to amine hydrogen groups is from 1.05 to 1.50. The epoxy resin system contains a tertiary amine catalyst such as a tertiaryaminophenol, a benzyl tertiary amine or an imidazole compound.Type: ApplicationFiled: June 21, 2012Publication date: January 3, 2013Inventors: Timothy A. Morley, Radhakrishnan Karunakaran, Carol L. O'Connell, Nigel Shields, Nikhil K. Verghese, Martin Reimers
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Patent number: 8338547Abstract: To provide a structure material having excellent mechanical characteristics and a functional material having excellent regularity, provided are a polymer alloy which is composed of at least two components of thermoplastic resins and of which the structure can be controlled finely and evenly dispersed and a production method of the polymer alloy. With respect to a polymer alloy composed of at least two or more components of thermoplastic resins, a precursor (A) of at least one thermoplastic resin among the thermoplastic resin components composing the polymer alloy is chemically reacted in the co-presence of the remaining thermoplastic resin component (B1) and/or a precursor (B2) of the thermoplastic resin component to induce spinodal decomposition, so that it is made possible to obtain a polymer alloy having excellent regularity and of which the structure is finely controllable and the structure is evenly dispersed.Type: GrantFiled: September 18, 2008Date of Patent: December 25, 2012Assignee: Toray Industries, Inc.Inventors: Hiroshi Takahashi, Sadayuki Kobayashi
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Publication number: 20120308831Abstract: A low temperature curable epoxy resin composition which comprises: an epoxy component that contains an epoxy compound having per molecule at least two epoxy groups and that is liquid at 25° C.; an aromatic amine based curing agent that contains an aromatic amine compound having per molecule at least two amino groups directly bonded to the aromatic ring and that is liquid at 25° C.; and Mg(II) acetylacetonate as a cure accelerator. The composition, which contains a novel cure accelerator using a metal complex, exhibits high stability at room temperature while lowering a cure temperature or shortening a cure time.Type: ApplicationFiled: November 30, 2010Publication date: December 6, 2012Applicant: NAGASE CHEMTEX CORPORATIONInventors: Katsuyuki Mizuike, Tomoki Isobe, Makoto Shinohara
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Patent number: 8299202Abstract: The present invention relates to A phenol compound according to Formula (I): wherein: R1 is selected from the group consisting of, optionally substituted, 2-pyridyl, 3-pyridiyl and 4-pyridyl groups, wherein R1 is at position 2 or 3 of the phenol ring; R2 is selected from the group consisting of, optionally substituted, 2-pyridyl, 3-pyridiyl, 4-pyridyl and phenyl groups, wherein R2 is at position 5 or 6 of the phenol ring; and the phenol ring is optionally substituted at one or two positions, independently selected from positions 2, 3, 5 and 6, with a halogen atom or a with an optionally substituted C6-C12 aryl group or an optionally substituted C1-C10 alkyl group. The present invention relates also to (co)polymers comprising the phenol compound according to Formula (I) and membranes and ionic resins comprising said (co)polymers.Type: GrantFiled: January 30, 2009Date of Patent: October 30, 2012Inventors: Doetze Jakob Sikkema, Ronny Mathieu Versteegen, Maarten Jozef Pouderoijen
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Patent number: 8299204Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbons atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.Type: GrantFiled: October 27, 2006Date of Patent: October 30, 2012Assignee: Eastman Chemical CompanyInventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8288025Abstract: The present invention includes method, compositions and devices including acid-base polymer membranes with high proton conductivity at low relative humidity, good thermal and mechanical stabilities and low methanol crossover. The acid-base polymer membrane includes an acidic polymer mixed with a basic polymer. The acidic polymer includes an acidic group attached to an aromatic polymer, while the basic polymer includes at least one heterocyclic ring structure attached to an aromatic polymer.Type: GrantFiled: July 18, 2007Date of Patent: October 16, 2012Assignee: Board of Regents, The University of Texas SystemInventors: Arumugam Manthiram, Yongzhu Fu
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Patent number: 8287970Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.Type: GrantFiled: November 20, 2008Date of Patent: October 16, 2012Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Spencer Allen Gilliam, Alan Keith Phillips
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Publication number: 20120245264Abstract: The invention relates to: a polycarbonate resin composition which is a polycarbonate resin composition (X) including a polycarbonate resin (A) and an aromatic polycarbonate resin (B), the polycarbonate resin (A) containing structural units (a) derived from a dihydroxy compound having the portion represented by the following general formula (1) as part of the structure thereof and further containing a dihydroxy compound (b) of an alicyclic hydrocarbon, and in which the content of the dihydroxy compound (b) of an alicyclic hydrocarbon in the polycarbonate resin (A) is 35 mol % or higher; and a molded article obtained from the composition. [Chem. 1] ?CH2—O???(1) (The case where the portion represented by the general formula (1) is part of —CH2—O—H is excluded.Type: ApplicationFiled: May 30, 2012Publication date: September 27, 2012Applicant: MITSUBISHI CHEMICAL CORPORATIONInventor: Haruo Sasaki
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Publication number: 20120232198Abstract: The invention is to provide a polycarbonate resin composition having excellent weatherability, transparency, hue, heat resistance, thermal stability, moldability, and mechanical strength and a molded article obtained therefrom. The invention relates to: a polycarbonate resin composition which includes a polycarbonate resin (A) containing constituent units derived from a dihydroxy compound (a) having the portion represented by a general formula (1) as part of the structure thereof and constituent units derived from a dihydroxy compound (b) of an alicyclic hydrocarbon having up to 11 carbon atoms and an aromatic polycarbonate resin (B) represented by a general formula (2); and a molded article obtained from the composition. The above general formulae (1) and (2) are described in the specification of the present application.Type: ApplicationFiled: May 22, 2012Publication date: September 13, 2012Applicant: MITSUBISHI CHEMICAL CORPORATIONInventor: Haruo SASAKI
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Publication number: 20120205590Abstract: The present invention provides nano-sized particles of melanin, and the method for formation of the melanin particles comprise the following steps: adding a base to a dopamine.H+X?-containing solution (wherein H+X? is an acid) and allowing an acid-base neutralization reaction; and forming nano-sized particles of melanin by controlling the addition of nucleic dopamine.H+X? to base (b) at a ratio of a:b=1:0.1-1, and allow concurrent or consecutive formation of melanin by oxidation curing of the dopamine in air (polymerization). The manufacturing method according to the present invention can produce nano-sized melanin particles in a short period of time. Furthermore, the nano-sized melanin particles made according to the present invention are distinctive from conventional solvents containing dispersions of natural melanin and synthetic melanin, and have excellent application in various fields.Type: ApplicationFiled: October 22, 2010Publication date: August 16, 2012Applicant: SNU R&DB FOUNDATIONInventors: Jin Kyu Lee, Kuk Youn Ju
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Patent number: 8227556Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.Type: GrantFiled: June 21, 2011Date of Patent: July 24, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Allen Wai-Yee Ko, Michael L. Todt
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Patent number: 8211588Abstract: A sulfonated poly(arylene sulfone) contains an unsaturated bond. A cross-linked material may be formed from the sulfonated poly(arylene sulfone), and a clay nanocomposite may include the sulfonated poly(arylene sulfone) or the cross-linked material. A fuel cell includes the clay nanocomposite.Type: GrantFiled: January 4, 2010Date of Patent: July 3, 2012Assignees: Samsung Electronics Co., Ltd., Korea Advanced Institute of Science and TechnologyInventors: Yeong-suk Choi, Sang-ouk Kim, Sun-hwa Lee, Won-jun Lee
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Patent number: 8202948Abstract: Phosphorus-containing compounds are disclosed which are obtainable by reacting: (A) at least one organophosphorus compound having a group selected from the group H—P?O; the group P—H and the group P—OH; and (B) at least one compound having the following Formula (I): [R?(Y)m?]m(X—O—R?)n??Formula (I) wherein R? is an organic group; Y is a functional group selected from the group consisting of hydroxy, carboxylic acid, and amine; X is a hydrocarbylene group; R? is hydrogen or a hydrocarbyl group having from 1 to 8 carbon atoms, R is alkyl or aryl group having from 1 to 12 carbon atoms; m?, m and n are, independently, numbers equal to or greater than 1; and (C) a thermosetting or thermoplastic composition.Type: GrantFiled: November 4, 2010Date of Patent: June 19, 2012Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Publication number: 20120149837Abstract: A thermoplastic resin composition obtained by mixing 100 parts by weight of at least one thermoplastic resin (A) with 0.1 to 4 parts by weight of (B) a polyfunctional compound having three or more functional groups in which at least one of the terminal structures haying the functional groups is a structure represented by formula (1): where R is an alkylene group with 1-15 carbon atoms; n is an integer of 1 to 10; and X is at least one functional group selected from the group consisting of hydroxyl group, aldehyde group, carboxyl group, sulfo group, amino group, isocyanate group, carbodiimide group, oxazoline group, oxazine group, amide group, silanol group and silyl ether group.Type: ApplicationFiled: January 27, 2012Publication date: June 14, 2012Applicant: TORAY INDUSTRIES, INC.Inventors: Sadanori Kumazawa, Hiroyuki Ohme, Yuki Amano, Takamasa Owaki
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Patent number: 8193107Abstract: Binder compositions for making fiberglass products and methods for making and using same are provided. The binder composition can include a phenol-aldehyde resin or a mixture of Maillard reactants and one or more modifiers selected from the group consisting of a copolymer comprising one or more vinyl aromatic derived units and at least one of maleic anhydride and maleic acid; an adduct of styrene, at least one of maleic anhydride and maleic acid, and at least one of an acrylic acid and an acrylate; and one or more latexes.Type: GrantFiled: August 20, 2010Date of Patent: June 5, 2012Assignee: Georgia-Pacific Chemicals LLCInventors: Kim Tutin, John B. Hines, Stacey L. Wertz, Kelly A. Shoemake, Ramji Srinivasan
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Patent number: 8193302Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3 -cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.Type: GrantFiled: October 27, 2006Date of Patent: June 5, 2012Assignee: Eastman Chemical CompanyInventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 8168732Abstract: The present description discloses a polymeric composition which is a melt-processed alloy comprised of (a) a polyarylene sulfide resin, (b) a polyaryl-ether-ketone resin, and a reactive compound which results in (c) a graft copolymer of the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin in addition to the starting resins. Exemplary melt-processed polymeric compositions can be made by reacting an alkoxy silane with the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin to produce a graft copolymer of a portion of one or both of the resins, sufficient to render the composition uniform and homogeneous. It is normally preferred for the exemplary organosilane compound, to be an amino silane. The subject invention further reveals an insulated wire comprising (1) an electrical conductor and (2) a layer of the melt-processed alloy composition; and fiber reinforced composites comprising fibers substantially fully impregnated with the alloy polymeric composition.Type: GrantFiled: April 18, 2008Date of Patent: May 1, 2012Assignee: Ticona LLCInventors: Manoj Ajbani, Andrew Auerbach, Ke Feng
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Patent number: 8143357Abstract: Phosphorus-containing compounds useful for flame retardant epoxy resins are disclosed. The flame retardant epoxy resins may be used to make electrical laminates. This invention is particularly useful in end use applications in which a low bromine or low halogen content is required or desired.Type: GrantFiled: November 4, 2010Date of Patent: March 27, 2012Assignee: Dow Global Technologies LLCInventor: Joseph Gan
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Patent number: 8133933Abstract: Phenolic resin binder systems for sand molds, used in metal casting, which improve the quality of thermally reclaimed sand, are described. The substantial or complete elimination of calcium compounds (e.g., calcium stearate and calcium hydroxide, conventionally employed as a mold lubricant and a resin curing catalyst, respectively) allows the thermally reclaimed sand to be reused over multiple thermal reclamation cycles without the adverse effects previously encountered.Type: GrantFiled: August 11, 2006Date of Patent: March 13, 2012Assignee: Georgia-Pacific Chemicals LLCInventors: Richard Rediger, Edward Lucas
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Patent number: 8133967Abstract: Described are restaurant smallware, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.Type: GrantFiled: October 7, 2010Date of Patent: March 13, 2012Assignee: Eastman Chemical CompanyInventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Publication number: 20120045955Abstract: An enhanced prepreg for printed circuit board (PCB) laminates includes a substrate and a resin applied to the substrate. The resin includes a curable polymer and a polymerization initiator polymer having a backbone with a free radical initiator forming segment that breaks apart upon being subjected to heat to generate a plurality of non-volatile initiating species. This resin composition eliminates possible volatile loss of the free radical initiator during all processing steps in the preparation of PCB laminates. The resin may additionally include a cross-linking agent, flame retardant and viscosity modifiers. In one embodiment, a sheet of woven glass fibers is impregnated with the resin and subsequently dried or cured. The glass cloth substrate may include a silane coupling agent to couple the resin to the substrate. In another embodiment, resin coated copper (RCC) is prepared by applying the resin to copper and subsequently curing the resin.Type: ApplicationFiled: August 20, 2010Publication date: February 23, 2012Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: Dylan Joseph Boday, Joseph Kuczynski
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Patent number: 8119762Abstract: Described are film or sheet, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.Type: GrantFiled: November 10, 2010Date of Patent: February 21, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8119761Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues in the amount from 80 to 100 mole %, 2,2,4,4-tetramethyl-1,3- cyclobutanediol in the preferable amount from 30 to 40 mole % and 1,4-cyclohexanedimethanol in the preferable amount from 60 to 70 mole % , wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mote %; and the inherent viscosity of polyester is from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachtoroethane at a concentration of 0.5 g/100 ml at 25° C., polyester has a Tg from 110 to 160° C. and polyester composition comprises no polycarbonate. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.Type: GrantFiled: March 28, 2006Date of Patent: February 21, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8101705Abstract: Described are articles, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.60 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 100° C. to 130° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate. Composition can be manufactured into articles as fibers, films, bottles or sheets.Type: GrantFiled: May 20, 2010Date of Patent: January 24, 2012Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8088400Abstract: An alcohol-soluble, water-insoluble, disinfectant composition and a method of using the same for disinfecting and for providing a prolonged antimicrobial property to a variety of surfaces, including skin. The composition comprises an antimicrobial polymer that is capable of imparting an antimicrobial property to a surface without the use of a metal or metal-containing compound. The composition is applied to a surface and allowed to evaporate leaving a coating of antimicrobial polymer.Type: GrantFiled: August 22, 2006Date of Patent: January 3, 2012Assignee: Quick-Med Technologies, Inc.Inventors: William Toreki, Gerald Olderman
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Patent number: 8067525Abstract: Described are film(s) and/or sheet(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 29, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8062455Abstract: The instant invention relates to compositions comprising a benzoxazine resin and an advancement resin based on bisphenol A diglycidyl ether and bisphenol S and, optionally, ferrocene and aluminium trihydrate. Such compositions are, when cured to form polymeric networks, difficultly inflammable and resistant to high temperatures. Such compositions may especially be used in the production of printed wiring boards.Type: GrantFiled: March 21, 2006Date of Patent: November 22, 2011Assignee: Huntsman Advanced Materials Americas LLCInventor: Dave Tsuei
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Patent number: 8063173Abstract: Described as one aspect of the invention are polyesters containing (a) a dicarboxylic acid component having from 70 to 100 mole % of terephthalic acid residues and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component having from 11 to 25 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 75 to 89 mole % of 1,4-cyclohexanedimethanol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %. The polyesters may be manufactured into articles.Type: GrantFiled: March 28, 2006Date of Patent: November 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Patent number: 8063172Abstract: Described are film(s) and/or sheet(s) made using polyester compositions comprising polyesters comprising (a) a dicarboxylic acid component comprising 70 to 100 mole % of terephthalic acid residues, and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: November 22, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
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Publication number: 20110282010Abstract: An epoxy resin composition having low moisture permeability, transparency and a high refractive index. The epoxy resin composition includes an epoxy compound, and a compound having two or more crosslinking groups that are reactive with the epoxy compound. The weight ratio of (a) to (b) is from 0.3 to 3, and the epoxy resin composition has a refractive index of 1.6 or higher.Type: ApplicationFiled: January 13, 2010Publication date: November 17, 2011Applicant: 3M INNOVATIVE PROPERTIES COMPANYInventor: Jun Fujita
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Publication number: 20110275766Abstract: A poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst has a monomodal molecular weight distribution with a reduced content of very high molecular weight species. It also exhibits increased morpholine incorporation in the high molecular weight fraction. Compared to commercially available poly(2,6-dimethyl-1,4-phenylene ether) prepared using a di-n-butylamine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits reduced odor. Compared to other poly(2,6-dimethyl-1,4-phenylene ether) prepared using a morpholine-containing polymerization catalyst, the poly(2,6-dimethyl-1,4-phenylene ether) of the invention exhibits improved molecular weight build during compounding and improved compatibilization with polyamides.Type: ApplicationFiled: April 11, 2011Publication date: November 10, 2011Inventors: Alvaro Carrillo, Stephen M. Farnell, Hua Guo
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Publication number: 20110274907Abstract: Curative fibre components comprise one or more fibres for filaments of curative suitable to cure curable resins such as thermoset resin. In curative fibre components comprising a plurality of fibres of curative, the fibres can be commingled, such as twisting, to form a thread or yarn. Curative fibre components can be used to form a material in the form of a sheet, fabric, layer, textile or mat of woven or non-woven curative fibres. Curative fibre components can be used to produce composite materials such as fibre reinforced resinous composite materials. The curative fibre components can be commingled, including interwoven, stitched and layered with other fibres or fibrous materials, such as fibrous reinforcement, fibrous curable resin, fibrous thermoplastic, other non-reinforcing fibres to form composite materials, prepregs, preforms and articles.Type: ApplicationFiled: November 24, 2009Publication date: November 10, 2011Inventors: Mark Raymond Steele, Andrew Gibbs, Amy Grace Atinkson
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Patent number: 8034857Abstract: Compositions comprise phase separated polyetherimide/polyphenylene ether sulfone blends. The dispersed phase has an average cross sectional size of 0.1 to 10 micrometers. The composition retains has good hydrolytic stability and is capable of withstanding steam autoclaving at temperatures of 130 to 138° C.Type: GrantFiled: September 11, 2007Date of Patent: October 11, 2011Assignee: Sabic Innovative Plastics IP B.V.Inventors: Ganesh Kailasam, Robert R Gallucci, Mark Alan Sanner
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Patent number: 8030374Abstract: An object of the present invention is to prevent, in blending an inorganic filler for the purpose of improving rigidity of a thermoplastic resin, deterioration in impact resistance and surface smoothness caused by the inorganic filler. The invention relates to a polyphenylene ether based resin composition containing (a) from 10 to 93% by weight of a polyphenylene ether based resin and optionally a styrene based resin, (b) from 2 to 20% by weight of a styrene based thermoplastic elastomer modified with an imidazolidinone compound, and (c) from 5 to 60% by weight of an inorganic filler that has been surface treated with a silane compound.Type: GrantFiled: August 8, 2003Date of Patent: October 4, 2011Assignee: Asahi Kasei Chemicals CorporationInventors: Juro Ozeki, Toru Yamaguti
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Publication number: 20110213095Abstract: Sodium carbonate (Na2CO3) having a certain particle size distribution and its use in preparing poly(aryl ether ketone)s, especially PEEK. Poly(aryl ether ketone)s made using the described sodium carbonate. A method for providing a sodium carbonate having a certain particle size distribution, which is especially well suited for the preparation of poly(aryl ether ketone)s.Type: ApplicationFiled: October 23, 2009Publication date: September 1, 2011Applicant: SOLVAY ADVANCED POLYMERS, L.L.C.Inventor: Chantal Louis
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Publication number: 20110207861Abstract: The invention relates to a continuous process for producing a reactive polymer based on compounds according to the structures (A1) and/or (A2) and phenolic resin in an extruder and to the reactive polymer produced according to said process and the use thereof for producing composite materials.Type: ApplicationFiled: April 2, 2009Publication date: August 25, 2011Applicant: EVONIK DEGUSSA GmbHInventors: Marianne Omeis, Thomas Weihrauch, Frank Bauer, Elke Fiebig-Bauer, Silvia Herda
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Publication number: 20110184128Abstract: A thermoplastic composition is prepared by melt blending a poly(arylene ether) and an other resin, where the poly(arylene ether) has a particular molecular weight distribution. The thermoplastic composition exhibits significantly increased melt flow compared to compositions containing poly(arylene ether)s with similar intrinsic viscosities but different molecular weight distributions. The increased melt flow facilitates preparation of the thermoplastic composition and subsequent article fabrication procedures.Type: ApplicationFiled: September 21, 2009Publication date: July 28, 2011Inventors: Hua Guo, Michael L. Todt, John Yates
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Patent number: 7985827Abstract: Described are polyester compositions comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, wherein said 2,2,4,4-tetramethyl-1,3-cyclobutanediol contains certain cis to trans ratios; and 1,4-cyclohexanedimethanol residues.Type: GrantFiled: March 28, 2006Date of Patent: July 26, 2011Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7968194Abstract: The invention provides an adhesive sheet which can be stuck to a wafer at low temperatures of 100° C. or below, which is soft to the extent that it can be handled at room temperature, and which can be cut simultaneously with a wafer under usual cutting conditions; a dicing tape integrated type adhesive sheet formed by lamination of the adhesive sheet and a dicing tape; and a method of producing a semiconductor device using them. In order to achieve this object, the invention is characterized by specifying the breaking strength, breaking elongation, and elastic modulus of the adhesive sheet in particular numerical ranges.Type: GrantFiled: July 17, 2008Date of Patent: June 28, 2011Assignee: Hitachi Chemical Co., Ltd.Inventors: Teiichi Inada, Michio Mashino, Michio Uruno
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Patent number: 7968195Abstract: The invention provides an adhesive sheet which can be stuck to a wafer at low temperatures of 100° C. or below, which is soft to the extent that it can be handled at room temperature, and which can be cut simultaneously with a wafer under usual cutting conditions; a dicing tape integrated type adhesive sheet formed by lamination of the adhesive sheet and a dicing tape; and a method of producing a semiconductor device using them. In order to achieve this object, the invention is characterized by specifying the breaking strength, breaking elongation, and elastic modulus of the adhesive sheet in particular numerical ranges.Type: GrantFiled: July 17, 2008Date of Patent: June 28, 2011Assignee: Hitachi Chemical Co., Ltd.Inventors: Teiichi Inada, Michio Mashino, Michio Uruno