Acetates Patents (Class 536/69)
  • Patent number: 4312980
    Abstract: A solution of cellulose triacetate in a mixed solvent consisting essentially of a chlorinated hydrocarbon with a boiling point lower than that of an aqueous medium and an aliphatic higher alcohol with 6 or more than 6 carbon atoms is suspended into the aqueous medium to form droplets of the above-mentioned solution, and then the chlorinated hydrocarbon in the droplets is removed by evaporation to obtain spherical particles of cellulose triacetate containing the aliphatic higher alcohol. The spherical particles thus obtained are saponified and removed of the aliphatic higher alcohol, to prepare porous cellulose spherical particles.
    Type: Grant
    Filed: July 30, 1980
    Date of Patent: January 26, 1982
    Assignees: Chisso Corporation, Yoshiaki Motozato
    Inventors: Yoshiaki Motozato, Hiroaki Ishibashi
  • Patent number: 4306060
    Abstract: Cellulose acetate is prepared acetylating cellulose at a high temperature of 50.degree.-85.degree. C. and then ripening the acetylated cellulose at a high temperature of 110.degree.-120.degree. C.
    Type: Grant
    Filed: December 15, 1980
    Date of Patent: December 15, 1981
    Assignee: Daicel Chemical Industries, Ltd.
    Inventor: Yoshiyuki Ikemoto
  • Patent number: 4269972
    Abstract: Cellulose diacetate having improved resistance to delustering in hot water is produced by acetylation cellulose in the presence of a catalyst and then hydrolyzing (or ripening) the product to form secondary cellulose acetate; wherein the catalyst in the acetylated mixture is completely neutralized before about the middle of the hydrolysis reaction at the latest and thereafter hydrolysis is carried out at a temperature of about 110.degree. to 120.degree. C. while maintaining the concentration of acetic acid in the reaction mixture at about 67 to 78% by weight based on the total weight of the acetic acid and water, the relation between the hydrolysis temperature and the concentration of acetic acid being defined by the area between and including points A, B, C and D in FIG. 2.
    Type: Grant
    Filed: June 11, 1979
    Date of Patent: May 26, 1981
    Assignee: Daicel Ltd.
    Inventors: Hideo Yabune, Yoshiyuki Ikemoto
  • Patent number: 4249000
    Abstract: Polymers from the group consisting of cellulose and its ester and ether derivatives, of polyvinyl alcohol and its ester derivatives, polymers with vinyl esters and homopolymers and copolymers of acrylates and methacrylates are modified with monofunctional or difunctional cyclic .beta.-ketonic acids or their esters, in particular with succinylsuccinic acid or its ester derivatives. The modified polymers are particularly suitable for obtaining semi-permeable membranes for osmotic separation methods.
    Type: Grant
    Filed: February 21, 1979
    Date of Patent: February 3, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Batzer, Joel Sinnreich
  • Patent number: 4234719
    Abstract: Cellulose acetate is produced from methanol, carbon monoxide and cellulose in an integrated series of steps wherein acetic anhydride produced in a first step by the carbonylation of methyl acetate is used to acetylate cellulose to produce cellulose acetate and to co-produce acetic acid, the co-produced acetic acid is dehydrated and the dehydrated acetic acid reacted with methanol to produce methyl acetate which is then fed to the first step and carbonylated to produce additional quantities of acetic anhydride.
    Type: Grant
    Filed: June 29, 1979
    Date of Patent: November 18, 1980
    Assignee: Halcon Research and Development Corp.
    Inventor: Chee-Gen Wan
  • Patent number: 4234718
    Abstract: Cellulose acetate is produced from methanol, carbon monoxide and cellulose in an integrated series of steps wherein acetic anhydride produced in a first step by the carbonylation of methyl acetate is used to acetylate cellulose to produce cellulose acetate and to co-produce acetic acid is converted to ketene, the ketene is reacted with methanol to produce methyl acetate which is then fed to the first step and carbonylated to produce additional quantities of acetic anhydride.
    Type: Grant
    Filed: June 29, 1979
    Date of Patent: November 18, 1980
    Assignee: Halcon Research and Development Corp.
    Inventor: David Brown
  • Patent number: 4234528
    Abstract: An asymmetrical ultrafiltration membrane based on cellulose hydrate which may be dried without destructive shrinkage and which has been saponified without reduction in flow-through or separation performance is prepared by adding hydrophobic synthetic silicic acid to a casting solution based on cellulose triacetate optionally partially substituted by cellulose diacetate, and then casting the cellulose acetate membrane and saponifying to the cellulose hydrate form.
    Type: Grant
    Filed: April 10, 1979
    Date of Patent: November 18, 1980
    Assignee: Sartorius GmbH
    Inventors: Dietmar Nussbaumer, Horst Perl
  • Patent number: 4228276
    Abstract: Improved method for preparing cellulose acetate powder, particularly extrusion-grade powder, by direct precipitation, with the precipitation step occurring at a temperature of about 65.degree. C. to about 95.degree. C. and with the coagulating agent subsequently being removed from the resulting liquid powder slurry also at a temperature of about 65.degree. C. to about 95.degree. C.; and the cellulose acetate powder product resulting from the improved method, the powder being particularly adapted to take up plasticizer up to about 50 percent by weight and still flow uniformly without caking or becoming tacky.
    Type: Grant
    Filed: March 26, 1979
    Date of Patent: October 14, 1980
    Assignee: Eastman Kodak Company
    Inventors: Chung-Ming Kuo, Richard T. Bogan
  • Patent number: 4162359
    Abstract: Cellulose acetate is produced by subjecting highly purified cellulosic dissolving pulp to a bleaching sequence including at least one alkaline extraction stage and acetylating the bleached pulp to convert the pulp to cellulose acetate. The yellowness index of the cellulose acetate is reduced by carrying out the alkaline extraction stage in the presence of from 0.2 to 3.3%, based on dry pulp weight, of sodium or hydrogen peroxide.
    Type: Grant
    Filed: March 13, 1978
    Date of Patent: July 24, 1979
    Assignee: International Telephone and Telegraph Corporation
    Inventors: Phyllis C. Leithem, Romeo Conca
  • Patent number: 4067824
    Abstract: A gelled perfume formulation comprising conventional perfume oil or a commercial perfume composition and a polymeric carbohydrate derivative which acts as the gelling agent. The gelled formulation is applied on the skin as a smooth thin film. The composition possesses aesthetically pleasing clarity and enduring fragrance. This perfume can be conveniently transported and easily dispensed.
    Type: Grant
    Filed: September 27, 1976
    Date of Patent: January 10, 1978
    Assignee: Anheuser-Busch, Incorporated
    Inventors: James Teng, Marcella C. Stubits, Abraham Minton, James H. Baker
  • Patent number: 4038253
    Abstract: It has been found that certain polymers containing pendant diazo ester groups are photosensitive and have utility in the preparation of both lithographic and relief printing plates, as well as for etching resists for printed circuits. This is a continuation of application Ser. No. 412,218, filed Nov. 2, 1973 now abandoned.
    Type: Grant
    Filed: June 2, 1976
    Date of Patent: July 26, 1977
    Assignee: Hercules Incorporated
    Inventor: Brian D. Kramer
  • Patent number: 4024334
    Abstract: Cellulose esters, such as cellulose acetate and/or cellulose acetate butyrate, prepared in the form of gel beads are active as adsorbents, especially for debittering of fruit juices by removal of limonin.
    Type: Grant
    Filed: February 20, 1975
    Date of Patent: May 17, 1977
    Assignee: Commonwealth Scientific and Industrial Research Organization
    Inventors: Bruce Veness Chandler, Robert Leonard Johnson
  • Patent number: 4016353
    Abstract: A process for producing organic acid esters of cellulose, in an efficient and rapid manner, which includes confricating cellulose in the presence of esterification chemicals, the confrication step providing the major driving force in conducting the esterification reaction.
    Type: Grant
    Filed: April 14, 1975
    Date of Patent: April 5, 1977
    Assignee: Crown Zellerbach Corporation
    Inventors: David W. Goheen, Michael D. Fahey, Harvey L. Claussen
  • Patent number: 4012570
    Abstract: A reactive matrix comprises a co-enzyme chemically attached to a water insoluble organic polymeric support material. The reactive matrix may be used in a process for the separation of mixtures containing a plurality of enzymes.
    Type: Grant
    Filed: September 4, 1975
    Date of Patent: March 15, 1977
    Inventors: Peter Duncan Goodearl Dean, Christopher Robin Lowe
  • Patent number: 4012571
    Abstract: A reactive matrix comprises a co-enzyme chemically attached to a water insoluble organic polymeric support material. The reactive matrix may be used in a process for the separation of mixtures containing a plurality of enzymes.
    Type: Grant
    Filed: September 4, 1975
    Date of Patent: March 15, 1977
    Inventors: Peter Duncan Goodearl Dean, Christopher Robin Lowe
  • Patent number: 4012568
    Abstract: A reactive matrix comprises a co-enzyme chemically attached to a water insoluble organic polymeric support material. The reactive matrix may be used in a process for the separation of mixtures containing a plurality of enzymes.
    Type: Grant
    Filed: September 2, 1975
    Date of Patent: March 15, 1977
    Inventors: Peter Duncan Goodearl Dean, Christopher Robin Lowe
  • Patent number: 4012572
    Abstract: A reactive matrix comprises a co-enzyme chemically attached to a water insoluble organic polymeric support material. The reactive matrix may be used in a process for the separation of mixtures containing a plurality of enzymes.
    Type: Grant
    Filed: September 4, 1975
    Date of Patent: March 15, 1977
    Inventors: Peter Duncan Goodearl Dean, Christopher Robin Lowe
  • Patent number: 4012569
    Abstract: A reactive matrix comprises a co-enzyme chemically attached to a water insoluble organic polymeric support material. The reactive matrix may be used in a process for the separation of mixtures containing a plurality of enzymes.
    Type: Grant
    Filed: September 2, 1975
    Date of Patent: March 15, 1977
    Inventors: Peter Duncan Goodearl Dean, Christopher Robin Lowe
  • Patent number: 4011377
    Abstract: A reactive matrix comprises a co-enzyme chemically attached to a water insoluble organic polymeric support material. The reactive matrix may be used in a process for the separation of mixtures containing a plurality of enzymes.
    Type: Grant
    Filed: September 4, 1975
    Date of Patent: March 8, 1977
    Inventors: Peter Duncan Goodearl Dean, Christopher Robin Lowe
  • Patent number: 4011205
    Abstract: A reactive matrix comprises a co-enzyme chemically attached to a water insoluble organic polymeric support material. The reactive matrix may be used in a process for the separation of mixtures containing a plurality of enzymes.
    Type: Grant
    Filed: September 2, 1975
    Date of Patent: March 8, 1977
    Inventors: Peter Duncan Goodearl Dean, Christopher Robin Lowe
  • Patent number: 4000126
    Abstract: A translucent film having good water permeability and having dissociating power with respect to metallic ions is produced by subjecting one side of a cellulose film to acetylation treatment so as to highly acetylate said one side while leaving the other side unacetylated.
    Type: Grant
    Filed: March 31, 1975
    Date of Patent: December 28, 1976
    Assignee: Agency of Industrial Science & Technology
    Inventor: Tsutomu Nakagawa