Polycarboxylic Acid Patents (Class 560/190)
  • Publication number: 20130157197
    Abstract: A resist composition comprising: a base component (A) that exhibits changed solubility in a developing solution by the action of acid; a photoreactive quencher (C); and an acid-generator component (B) that generates acid upon exposure, wherein the photoreactive quencher (C) contains a compound represented by general formula (c1) shown below. In the formula, R1 represents a hydrogen atom or a hydrocarbon group of 1 to 20 carbon atoms which may have a substituent; each of R2 and R3 independently represents a hydrogen atom or a hydrocarbon group of 1 to 20 carbon atoms which may have a substituent; at least two of R1 to R3 may be mutually bonded to form a ring; X represents an oxygen atom or a sulfur atom; n represents 0 or 1; and Z+ represents an organic cation.
    Type: Application
    Filed: December 6, 2012
    Publication date: June 20, 2013
    Applicant: TOKYO OHKA KOGYO CO., LTD.
    Inventor: Tokyo Ohka Kogyo Co., Ltd
  • Publication number: 20130150617
    Abstract: Provided is a monolithic catalyst for synthesizing an oxalate by carbon monoxide (CO) gaseous-phase coupling, a preparation method and the use thereof. In the catalyst, a ceramic honeycomb or a metal honeycomb was used as skeletal carrier, metal oxides were used as a carrier coating, precious metals Pt, Pd, Ir, Rh were used as active ingredients, as well as Fe, Co, Ni were used as additives, wherein the carrier coating accounts for 5 to 50 wt % of the honeycomb carrier the active ingredients of the catalyst account for 0.1 to 5 wt. % of the carrier coating; the additives of the catalyst account for 0.3 to 10 wt. % of the carrier coating; and the atomic ratio of the active ingredients to the additives was 0.1 to 3. the reaction for synthesizing the oxalate was carried out in a fixed bed reactor, wherein, N2 was used as a carrier gas. The volume ratio of N2:CO: Alkyl nitrite was 20-80:5-60:10-40, and the retention time was 0.5-10 s.
    Type: Application
    Filed: May 31, 2011
    Publication date: June 13, 2013
    Inventors: Xinbin Ma, Yujun Zhao, Baowei Wang, Shengping Wang, Jing Lv, Zhenghua Li
  • Publication number: 20130150613
    Abstract: A method for hydrolyzing an ester is provided. In accordance with the method, a compound A is provided which has first and second ester moieties. The compound is reacted in a liquid medium with a base having the formula MaXb, such that the first ester moiety is converted to a carboxyl moiety and the second ester moiety remains, wherein the ratio [Xk?]:[A] in the liquid medium is no greater than 1.6, and wherein k>0.
    Type: Application
    Filed: November 16, 2012
    Publication date: June 13, 2013
    Inventor: Satomi Niwayama
  • Publication number: 20130137614
    Abstract: A process for improving the oxidation stability of lubricants including providing one or more esters containing branched alkyl groups which are reaction products of branched alcohols with a) one or more aliphatic dicarboxylic acids corresponding to general formula (II): HOOC—R2—COOH in which R2 is a branched or unbranched, saturated alkyl group containing 0 to 34 carbon atoms, or b) one or more saturated branched monocarboxylic acids corresponding to general formula (III): R3—COOH in which R3 is a branched alkyl group of 3 to 39 carbon atoms, or c) one or more saturated monocarboxylic acids corresponding to general formula (III) in which R3 is a linear alkyl group of 3 to 29 carbon atoms, or d) a mixture thereof, as lubricants, with the proviso that the esters have an oxidation stability of 1000 hours or more, as determined by the Turbine Oil Stability Test (TOST test) to DIN EN ISO 4263-3.
    Type: Application
    Filed: January 24, 2013
    Publication date: May 30, 2013
    Applicant: Cognis IP Management GmbH
    Inventor: Cognis IP Management GmbH
  • Patent number: 8450519
    Abstract: The invention relates to a process for preparing chiral octenoic acid derivatives, which constitute important intermediates in the preparation of medicament active ingredients, and also to novel intermediates which are used in the process for preparing the octenoic acid derivatives mentioned.
    Type: Grant
    Filed: March 16, 2012
    Date of Patent: May 28, 2013
    Assignee: Reuter Chemischer Apparatebau KG
    Inventors: Milan Soukup, Karl Reuter, Florian Stolz, Viktor Meier, Jofzsef Balint, Mark Kantor
  • Publication number: 20130131374
    Abstract: A pentaerythritol tetraester which is a mixed ester of pentaerythritol and carboxylic acids is provided, wherein the carboxylic acids consist of isobutyric acid and 3,5,5-trimethylhexanoic acid and the molar ratio of isobutyric acid to 3,5,5-trimethylhexanoic acid in the carboxylic acids is 36/64 to 80/20. The pentaerythritol tetraester may be used in a refrigerant oil or the like which exhibits excellent miscibility with a difluoromethane refrigerant among other properties.
    Type: Application
    Filed: June 30, 2011
    Publication date: May 23, 2013
    Applicant: KH NEOCHEM CO., LTD.
    Inventors: Toshihiro Inayama, Satoshi Hiyoshi, Nobuhito Amemiya, Shigehisa Kishimoto
  • Publication number: 20130115654
    Abstract: A method for utilizing agricultural biomass components, namely cellulose, hemicellose, and lignin, and converting them to value-added biobased chemical products is described herein. The present method provides treatments to obtain a plurality of component streams from agricultural biomass for producing derivative products while minimizing waste products.
    Type: Application
    Filed: November 9, 2011
    Publication date: May 9, 2013
    Applicant: Thesis Chemistry, LLC
    Inventors: John R. Peterson, Christopher M. Yost, Jian Wu
  • Publication number: 20130115653
    Abstract: A method for utilizing woody biomass components, namely cellulose, hemicellose, and lignin, and converting them to value-added biobased chemical products is described herein. The present method provides treatments to obtain a plurality of component streams from woody biomass for producing derivative products while minimizing waste products.
    Type: Application
    Filed: November 9, 2011
    Publication date: May 9, 2013
    Applicant: Thesis Chemistry, LLC
    Inventors: John R. Peterson, Christopher M. Yost, Jian Wu
  • Publication number: 20130108882
    Abstract: An asphalt-containing substrate having an adhesive, coating or sealant composition applied to the substrate surface and adhesive, coating or sealant compositions are described herein. The composition resists softening of the asphalt compound in the asphalt-containing substrate at elevated temperatures and includes at least one base material and at least one plasticizer. The plasticizer has is a low molecular weight compound and preferably includes an ester-containing reaction product of at least one glycerol and at least one carboxylic acid or a glycol and an aryl carboxylic acid. The composition base material is preferably a polymer or copolymer that includes polyurethanes, silylated polyurethanes, silylated polyethers, copolymers thereof, and blends thereof. Products containing the composition and a method of applying the composition to a substrate are also disclosed herein.
    Type: Application
    Filed: October 31, 2012
    Publication date: May 2, 2013
    Applicant: HENRY COMPANY LLC
    Inventor: Henry Company LLC
  • Publication number: 20130096042
    Abstract: A bearing lubricant composition includes a base oil containing an ester compound (?) represent by the general formula (1), and has a pour point of ?30° C. or lower and a viscosity index of 150 or more. [wherein, A1 is a C3-8 linear or branched alkylene group; and at least one of Xa and Xb is a C2-20 linear or branched alkyl ether group, or when it is not an alkyl ether group, it is a C5-13 linear or branched alkyl group.
    Type: Application
    Filed: September 28, 2012
    Publication date: April 18, 2013
    Applicants: BALBIS CO., LTD., KNC LABORATORIES., LTD., Sato Special Oil Co., Ltd.
    Inventors: BALBIS CO., LTD, Sato Special Oil Co., Ltd., KNC LABORATORIES CO., LTD.
  • Patent number: 8414906
    Abstract: The present invention relates to oligoesters and their use for the creation of additives. Oligoester containing additives and/or oligoesters themselves may be used for formulating pharmaceutical preparations, cosmetics or personal care products such as shampoos and conditioners. These oligoesters are particularly useful for the creation of multi-purpose additives that can impart conditioning, long substantivity and/or UV protection. Individual oligoesters and oligoester mixtures are described.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: April 9, 2013
    Assignee: Croda, Inc.
    Inventors: Abel G. Pereira, Helena S. Barinova, Christopher Westergom
  • Patent number: 8410306
    Abstract: The present invention relates to a novel process for preparing alkyl polycarboxylates from an aqueous solution of an ammonium salt of the polycarboxylic acid by reactive distillation, and to a process for hydrogenating the alkyl carboxylates prepared in this way.
    Type: Grant
    Filed: April 4, 2007
    Date of Patent: April 2, 2013
    Assignee: BASF SE
    Inventors: Christophe Bauduin, Wolfgang Fischer, Rolf Pinkos, Edzard Scholten
  • Publication number: 20130052149
    Abstract: The disclosed invention relates to a process, comprising: conducting unit operations in at least two process zones in a process microchannel to treat and/or form a non-Newtonian fluid, a different unit operation being conducted in each process zone; and applying an effective amount of shear stress to the non-Newtonian fluid to reduce the viscosity of the non-Newtonian fluid in each process zone, the average shear rate in one process zone differing from the average shear rate in another process zone by a factor of at least about 1.2.
    Type: Application
    Filed: October 4, 2012
    Publication date: February 28, 2013
    Applicant: VELOCYS, INC.
    Inventor: Velocys, Inc.
  • Publication number: 20130039872
    Abstract: The present invention relates to a process for the preparation of an ester in a reactor, a device, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions.
    Type: Application
    Filed: December 30, 2010
    Publication date: February 14, 2013
    Inventors: Peter Daute, Wilhelm Reiners, Martin Schäfer, Udo Frerichs, Hinrich Hildebrandt, Joern Ellerbrake
  • Patent number: 8367747
    Abstract: Novel bioabsorbable and/or biocompatible polyurethanes, polyureas, polyamideurethanes and polyureaurethanes with tunable physical, mechanical properties and hydrolytic degradation profiles are provided for use in biomedical applications such as stents, stent coatings, scaffolds, foams, and films. The disclosed polymers may be derived from biocompatible and/or bioabsorbable polyisocyanates. The present invention also relates to new and improved methods for the preparation of the biocompatible and/or bioabsorbable polyisocyanates.
    Type: Grant
    Filed: May 22, 2009
    Date of Patent: February 5, 2013
    Assignee: Bezwada Biomedical, LLC
    Inventor: Rao S. Bezwada
  • Patent number: 8367860
    Abstract: The present invention provides a method for efficiently using an aqueous solution of (meth)acrylic acid at a low concentration formed in a production/storage step of (meth)acrylic acid. In the present invention, a (meth)acrylic acid derivative is produced by using as a raw material an aqueous solution of (meth)acrylic acid formed by one or both of: a device which reduces a pressure of a gas comprising (meth)acrylic acid in production of (meth)acrylic acid; and a device which collects (meth)acrylic acid from a gas comprising (meth)acrylic acid.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: February 5, 2013
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Yasushi Ogawa, Shuhei Yada, Yoshiro Suzuki, Kenji Takasaki, Yukihiro Hasegawa
  • Publication number: 20130027654
    Abstract: To provide a liquid crystal composition satisfying at least one characteristic such as a high maximum temperature of a nematic phase, a low minimum temperature thereof, a small viscosity, a suitable optical anisotropy, a large negative dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and heat, or a liquid crystal composition having a suitable balance regarding at least two characteristics, and an AM device having a short response time, a large voltage holding ratio, a large contrast ratio and a long service life; a liquid crystal composition contains a specific compound having a polymerizable group as a first component, and may contain a specific compound having a large negative dielectric anisotropy and a low minimum temperature as a second component or a specific compound having a small viscosity or a large maximum temperature as a third component, and a liquid crystal display device contains the composition.
    Type: Application
    Filed: July 25, 2012
    Publication date: January 31, 2013
    Applicants: JNC PETROCHEMICAL CORPORATION, JNC CORPORATION
    Inventors: Yukihiro FUJITA, Yoshimasa FURUSATO
  • Patent number: 8361172
    Abstract: In the present invention, a fuel composition and a process for making the same are disclosed. Specifically, in the present invention, triglycerides useful for distillate fuels are described along with their method for preparation from Fischer-Tropsch acid by-products and the glycerol by-product from biodiesel generation. By using these two by-product streams, the overall efficiency of both processes is improved and a new source of distillate fuels is created. These triglycerides can be used to improve the lubricity of Fischer-Tropsch derived distillate fuels. In addition, these triglycerides also have low melting points and have viscosities compatible with distillate fuels.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: January 29, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventor: Dennis J. O'Rear
  • Publication number: 20130012565
    Abstract: This invention relates to novel derivatives of 4-hydroxybutyric acid and prodrugs thereof, and pharmaceutically acceptable salts of the foregoing. This invention also provides pharmaceutical compositions comprising a compound of this invention and the use of such compositions in methods of treating narcolepsy, fibromyalgia, other disorders or conditions that are beneficially treated by improving nocturnal sleep or by administering sodium oxybate.
    Type: Application
    Filed: February 14, 2012
    Publication date: January 10, 2013
    Applicant: Concert Pharmaceuticals Inc.
    Inventors: Roger D. Tung, Adam J. Morgan, I. Robert Silverman
  • Patent number: 8349930
    Abstract: There is provided a compound of the formula (I) wherein R1 is an alkyl, alkenyl or alkynyl group containing x carbon atoms, wherein x is from 1 to 10, wherein one of R2 and R3 is an alkyl, alkenyl or alkynyl group containing y carbon atoms, wherein y is from 1 to 10, wherein the other of R2 and R3 is a branched group of the formula (II) wherein q is from 0 to 3, wherein each R5 is independently selected from —OH and —O—C(O)—R4, wherein n is from 10 to 20 and m is selected from 2n-q, 2n-2-q, 2n-4-q, and 2n-6-q, wherein each R4 is independently selected from alkyl, alkenyl and alkynyl groups containing z carbon atoms, wherein z is from 7 to 21, wherein z is different to at least one of x and y.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: January 8, 2013
    Assignee: Danisco A/S
    Inventors: Bjarne Nielsen, Flemming Vang Sparsø
  • Publication number: 20130005631
    Abstract: Provided are a lubricating oil base oil having characteristics of low volatility and excellent low-temperature fluidity and capable of providing long-lasting lubrication property in a wide temperature range from low temperature to high temperature, and a lubricating oil composition using the same. The lubricating oil base oil includes a diester obtained through a reaction between a diol component formed of 1,12-dodecanediol and a carboxylic acid component formed of 2-methylpentanoic acid or 2-methylpentanoic acid and 2-ethylhexanoic acid. The diester is represented by R2COOR1OOCR3, where R1 represents an alkylene derived from the diol component and R2 and R3 each represent an alkyl derived from the carboxylic acid component, and includes 45 to 100 mol % of a diester in which both of R2 and R3 represent C5 alkyls.
    Type: Application
    Filed: March 31, 2011
    Publication date: January 3, 2013
    Inventors: Tadashi Kuratomi, Katsumi Nagano
  • Publication number: 20130006099
    Abstract: The present embodiments disclose the preparation of hyperpolarized 13C dialkyl succinate compounds and hyperpolarized 13C dialkyl fumarate compounds and their use in real time, in vivo metabolic imaging of the TCA cycle.
    Type: Application
    Filed: July 1, 2012
    Publication date: January 3, 2013
    Inventors: Niki Zacharias Millward, Pratip Bhattacharya
  • Publication number: 20120329888
    Abstract: Method of producing a nanoparticle suspension with the steps (i) preparation of an emulsion of a disperse polar phase, where the aqueous phase comprises one or more precursor substances forming the nanoparticles, in a continuous organic phase in the presence of an emulsifier stabilizing the emulsion, (ii) conversion of the one or more precursor substances to nanoparticles in the disperse aqueous phase, (iii) breaking of the emulsion and phase separation, where the nanoparticle suspension is obtained as one phase, (iv) separation off of the nanoparticle suspension, (v) optionally isolation of the nanoparticles from the nanoparticle suspension, wherein the emulsifier is selected from compounds of the general formula (I) in which X is O, NH, Y is C(O), NH, R is a saturated or a mono- or polyunsaturated, linear or branched hydrocarbon radical having 6 to 30 carbon atoms and R1 is hydrogen or C1-C4-alkyl, and R2 is a saturated or a mono- or polyunsaturated, linear or branched hydrocarbon radical having 1 to 30 car
    Type: Application
    Filed: March 7, 2011
    Publication date: December 27, 2012
    Applicant: BASF SE
    Inventors: Robert Engel, Wolfgang Gerlinger, Stefan Braese, Thierry Muller, Christina Belenki, Heike P. Schuchmann, Marion Gedrat
  • Patent number: 8338635
    Abstract: A method for hydrolyzing an ester is provided. In accordance with the method, a compound A is provided which has first and second ester moieties. The compound is reacted in a liquid medium with a base having the formula MaXb, such that the first ester moiety is converted to a carboxyl moiety and the second ester moiety remains, wherein the ratio [Xk?]:[A] in the liquid medium is no greater than 1.6, and wherein k>0.
    Type: Grant
    Filed: May 30, 2008
    Date of Patent: December 25, 2012
    Assignee: Satomi Niwayama
    Inventor: Satomi Niwayama
  • Patent number: 8334400
    Abstract: There are provided a novel hydroxyl compound having proper hydroxyl values which exhibits not only excellent moisturizing ability and emollient ability when it is blended in cosmetics, but also, among others, excellent gloss-holding ability, and a cosmetic comprising said hydroxyl compound. A hydroxyl compound obtained by reacting a di- or higher-valent alcohol with a monovalent carboxylic acid to obtain an ester compound, which is then reacted with dimer acid, characterized in that the di- or higher-valent alcohol is diglycerin, and the monovalent carboxylic acid is a carboxylic acid having 5 to 10 carbon atoms, and a molar ratio among diglycerin, the carboxylic acid having 5 to 10 carbon atoms and dimer acid is 1.0:1.5 to 1.6:0.4 to 0.6.
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: December 18, 2012
    Assignee: Kokyu Alcohol Kogyo Co., Ltd.
    Inventors: Kyoichi Takeda, Yuki Kokeguchi
  • Patent number: 8329938
    Abstract: Retinyl hydroxyesters and retinyl oligo-hydroxyesters were prepared using a chemoenzymatic process from retinol and short chain esters of hydroxycarboxylic acids or short chain esters of hydroxycarboxylic acids. The presence of the hydroxyl group on the acid can result in a mixture of esters from various oligomers of the hydroxycarboxylic acid. The retinyl ester products are readily enzymatically hydrolyzed in vitro, which indicates that application to the skin should result in release of the anti-aging ingredient retinol (without the inherent instability and irritation) along with the acid, which, if chosen appropriately, should also have desirable biological effects. This combination should be effective as an anti-aging skin care ingredient.
    Type: Grant
    Filed: February 21, 2011
    Date of Patent: December 11, 2012
    Assignee: Eastman Chemical Company
    Inventor: Neil Warren Boaz
  • Patent number: 8324331
    Abstract: A compound represented by general formula (a-i) below, and a polymeric compound having a structural unit represented by general formula (a-ii) below (wherein R represents a hydrogen atom, a lower alkyl group or a halogenated lower alkyl group; X represents a divalent organic group represented by general formula (x-1) below; and R1 represents an organic group having a fluorine atom).
    Type: Grant
    Filed: December 16, 2009
    Date of Patent: December 4, 2012
    Assignee: Daito Chemix Corporation
    Inventors: Toshiharu Shimamaki, Kenji Uenaga
  • Publication number: 20120298125
    Abstract: A method for producing triacetin from one or more plants of genus Nicotiana is provided. The triacetin can be derived inter alia from Nicotiana species biomass or from seed. In certain embodiments, the triacetin is produced by condensation of glycerin, generated by hydrolysis of acylglycerol-containing starting material derived from tobacco biomass or seed, and acetic acid, also derived from tobacco biomass or seed. The invention also provides articles and compositions including tobacco articles and tobacco compositions that include triacetin produced from one or more plants of genus Nicotiana.
    Type: Application
    Filed: May 27, 2011
    Publication date: November 29, 2012
    Inventors: Michael Francis Dube, William Coleman
  • Patent number: 8318964
    Abstract: Problem To provide an environmentally-friendly method for producing industrially an ester compound. Solution The present invention is a method for producing an ester compound which comprises subjecting a carboxylic acid and an alcohol to dehydration-condensation reaction using an involatile acid catalyst and then removing the residual acid catalyst by bringing a weak basic substance into contact with the residual acid catalyst.
    Type: Grant
    Filed: October 20, 2007
    Date of Patent: November 27, 2012
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Shigeaki Imazeki, Ryohiko Kinoshita
  • Publication number: 20120289461
    Abstract: A protein synthesis promoter that exhibits a protein synthesis-promoting effect includes a whey protein hydrolyzate having a molecular weight distribution that is within a range of 10 kDa or less and has a main peak of 200 Da to 3 kDa, an average peptide length (APL) of 2 to 8, a free amino acid content of 20% or less, a branched-chain amino acid content of 20% or more, and an antigenicity equal to or less than 1/100,000th of that of ?-lactoglobulin.
    Type: Application
    Filed: February 10, 2011
    Publication date: November 15, 2012
    Applicant: Megmilk Snow Brand Co., Ltd.
    Inventor: Susumu Miura
  • Publication number: 20120283161
    Abstract: Disclosed is a lubricating oil composition which includes a diester-based base oil having an asymmetric structure in which the number of carbons of the alkyl chain bound to one ester group with respect to a central atom is two more than that of the alkyl group bound to the other ester group, and which has low viscosity and a comparatively small amount of evaporation at high temperature. When this composition is used for a motor of a small hard disk, power consumption can be reduced and stability at high temperature can be enhanced.
    Type: Application
    Filed: October 12, 2011
    Publication date: November 8, 2012
    Applicant: SAMSUNG ELECTRO-MECHANICS CO., LTD.
    Inventors: Ha Yong Jung, Myung Hwa Choi, Wang Hyun Kwon, Hyung Kyu Kim, Kun Kim
  • Publication number: 20120277455
    Abstract: The invention relates to a series of novel chiral phosphorus ligands of formulae (Ia) and (Ib): wherein R, 1-rR>4 and X are as defined herein. The invention also relates to chiral metal complexes prepared with these chiral phosphorus ligands. The chiral metal complexes are useful as catalysts for carrying out asymmetric hydro genation.
    Type: Application
    Filed: November 1, 2010
    Publication date: November 1, 2012
    Applicant: BOEHRINGER INGELHEIM INTERNATIONAL GMBH
    Inventors: Bo Qu, Chris Hugh Senanayake, Wenjun Tang, Xudong Wei, Nathan K. Yee
  • Patent number: 8293935
    Abstract: A method of producing an alkyl ester of a carboxylic acid is provided, the method comprising: adding an alkanol and a mineral acid to a carboxylic acid salt to provide a carboxylic acid/alkanol solution and a precipitated mineral acid salt; separating the mineral acid salt from the carboxylic acid/alkanol solution; esterifying the carboxylic acid; and isolating an alkyl ester of the carboxylic acid.
    Type: Grant
    Filed: December 2, 2010
    Date of Patent: October 23, 2012
    Assignee: Board of trustees of Michigan State University
    Inventors: Alvaro Orjuela, Abraham Yanez-McKay, Carl Lira, Dennis Miller
  • Publication number: 20120264662
    Abstract: This invention relates to functionalized monomers. The functionalized monomer may be reacted with an enophilic reagent (e.g., maleic anhydride) to form an enophilic reagent modified functionalized monomer. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents, functional compositions (e.g., food products, cleaners, etc.), and the like.
    Type: Application
    Filed: March 23, 2012
    Publication date: October 18, 2012
    Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, Georgeta Hategan
  • Publication number: 20120245375
    Abstract: A process for preparing an alpha, omega-dicarboxylic acid or an ester thereof, which includes (a) subjecting at least one unsaturated fatty acid or fatty acid derivative to ozonolysis to obtain an ozonolysis reaction mixture; and (b) oxidizing the ozonolysis reaction mixture with an oxidizing agent in the presence of an acid catalyst to obtain an oxidized reaction mixture comprising at least one alpha, omega-dicarboxylic acid or ester; wherein the process is performed using a solvent and the acid catalyst has a pKa of less than or equal to zero, as measured at 25° C.
    Type: Application
    Filed: March 20, 2012
    Publication date: September 27, 2012
    Applicant: Evonik Degussa GmbH
    Inventors: Peter HANNEN, Harald Haeger, Martin Roos
  • Patent number: 8263800
    Abstract: The present invention comprises a compound comprising Formula 1A, 1B, or 1C (Ra—O—CO—)2X??Formula 1A Ra—O—CO—X—CO—O—(CH2CH2)Rf??Formula 1B Ra—O—CO—X—CO—O—R??Formula 1C wherein Ra is the group Rf(CH2CF2)d—(CgH2g)—; RfOCF2CF2—(CgH2g)—; RfOCFHCF2O(CH2CH2O)v—(CgH2g)—; RfOCFHCF2O(CwH2w); RfOCF(CF3)CONH—(CgH2g); or Rf(CH2)h[(CF2CF2)i(CH2CH2)j]k; Rf is CcF(2c+1); d is 1 to about 3; g is 1 to 4; v is 1 to about 4; w is from about 3 to about 12; h is 1 to about 6; i, j, and k are each independently 1, 2, or 3, or a mixture thereof; provided that the total number of carbon atoms in group (vi) is from about 8 to about 22; X is a linear or branched difunctional alkyl sulfonate group —CeH(2e?1)(SO3M)-, wherein e is 2 or 3; M is a monovalent cation selected from the group consisting of hydrogen, ammonium, alkali metal, or alkaline earth metal; R is H or a linear or branched alkyl group CbH(2b+1)—; and b is from 1 to about 18.
    Type: Grant
    Filed: July 1, 2008
    Date of Patent: September 11, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Peter Michael Murphy, Tracy Hewat
  • Publication number: 20120178959
    Abstract: The invention relates to a process for preparing chiral octenoic acid derivatives, which constitute important intermediates in the preparation of medicament active ingredients, and also to novel intermediates which are used in the process for preparing the octenoic acid derivatives mentioned.
    Type: Application
    Filed: March 16, 2012
    Publication date: July 12, 2012
    Inventors: Milan SOUKUP, Karl Reuter, Florian Stolz, Viktor Meier, Jofzsef Balint, Mark Kantor
  • Publication number: 20120164506
    Abstract: Provided is a heat transfer fluid formulation comprising at least one diester or triester species having ester links on adjacent carbons. The formulation exhibits an excellent balance of dielectric and heat transfer properties, and is useful as a coolant for electric vehicles.
    Type: Application
    Filed: December 23, 2010
    Publication date: June 28, 2012
    Applicant: Chevron U.S.A. Inc.
    Inventors: Sandra G. Claeys, Serge S. Lievens, Paul Van De Ven, Zhen Zhou, Stephen J. Miller, Ryan J. Schexnaydre, Saleh Elomari
  • Publication number: 20120157658
    Abstract: This invention relates to methods, compositions, and apparatuses for producing macrocyclic compounds. First, one or more reactants are provided in a reaction medium, which are capable of forming the macrocyclic compound through a desired reaction pathway that includes at least cyclization, and which are further capable of forming undesired oligomers through a undesired reaction pathway that includes undesirable oligomerization. Oligomerization of such reactions in the reaction medium is modulated to reduce formation of undesired oligomers and/or to reduce separation of the undesired oligomers from the reaction medium, relative to a corresponding unmodulated oligomerization reaction, thereby maximizing yields of the macrocyclic compound. The macrocyclic compound so formed is then recovered from the reaction medium. Preferably, the macrocyclic compound spontaneously separates from the reaction medium via phase separation.
    Type: Application
    Filed: November 8, 2011
    Publication date: June 21, 2012
    Inventors: Thomas E. Johnson, Billy T. Fowler
  • Patent number: 8183298
    Abstract: A fatty acid ester of pentaerythritol, a pentaerythritol oligomer, or mixtures thereof, where the fatty acid has 6 to 22 carbon atoms, and the ester contains less than 0.3% by weight C17 fatty acid acyl groups and has a melting point of at least 30° C. is provided. A process for the production of a C16/C18 fatty acid pentaerythritol ester including (A) providing about 1.8 to about 2.2 mol of a fatty acid mixture per mol of pentaerythritol; (B) esterifying component (A) at temperatures ranging from about 180° C. to about 250° C. in an inert gas atmosphere in the absence of solvent to form a reaction mixture; (C) stirring the reaction mixture in vacuo until it has an acid value of less than 1 and an OH value of 145 to 158 is provided. A cosmetic and/or pharmaceutical composition including the above-described ester is also provided.
    Type: Grant
    Filed: March 26, 2005
    Date of Patent: May 22, 2012
    Assignee: Cognis IP Management GmbH
    Inventors: Ulrich Issberner, Catherine Weichold, Achim Ansmann, Stefan Bruening, Helga Gondek
  • Publication number: 20120118198
    Abstract: Electronic inks are disclosed herein. One embodiment of the electronic ink includes a non-polar carrier fluid, a plurality of negatively charged colorant particles dispersed in the non-polar carrier fluid, a small molecular additive, and a charge director. Each of the negatively charged colorant particles includes a surface modified with an acidic functional group. The small molecular additive has at least two branches, each of which includes nitrogen or oxygen atoms.
    Type: Application
    Filed: October 16, 2009
    Publication date: May 17, 2012
    Inventors: Zhang-Lin Zhou, Jong-Souk Yeo, Jeffrey Todd Mabeck, Richard H. Henze
  • Publication number: 20120102826
    Abstract: A diesel fuel additive composition, a fuel containing the fuel additive, a method for improving diesel engine performance using the additive. The diesel fuel additive includes a reaction product of (a) a hydrocarbyl-substituted acylating agent and (b) a reactant selected from the group consisting of a nitrogen-containing compound, a hydroxyl-containing compound, and water that provides a reaction product selected from the group consisting (1) a mono-amide/mono-acid or metal free mono-acid salt thereof, (2) a diacid or metal free diacid salt thereof, and (3) mono-ester/mono-acid or metal free mono-acid salt thereof. The reaction product includes at least about 10 molar percent acid groups based on total moles of the reaction product.
    Type: Application
    Filed: November 3, 2010
    Publication date: May 3, 2012
    Applicant: AFTON CHEMICAL CORPORATION
    Inventor: Xinggao FANG
  • Patent number: 8168817
    Abstract: The present invention relates to the ability of certain unsaturated Guerbet esters to repair damage to the hair and skin. The compounds are oleate esters of Guerbet alcohols. The low viscosity, polarity of the ester group and very low titer point allow the esters of the present invention to spread rapidly and efficiently on the hair and skin, providing an elegant feel and lubricate the surface of the hair or skin repairing damage done to the hair or skin by washing, and allowing for the replacement of the oils from inside the hair or skin.
    Type: Grant
    Filed: November 8, 2010
    Date of Patent: May 1, 2012
    Assignee: SurfaTech Corp
    Inventor: Kevin A. O'Lenick
  • Publication number: 20120095145
    Abstract: A coalescent composition for coating compositions such as paints, adhesives, and coatings comprising a blend of dibasic esters, specifically (i) esters of adipic, glutaric, and/or succinic diacids and/or (ii) esters of isomers of adipic acid have advantages, including efficiency and low VOC.
    Type: Application
    Filed: December 20, 2011
    Publication date: April 19, 2012
    Applicant: Rhodia Operations
    Inventors: Lichang Zhou, Derek Pakenham, Jose Ruiz, Pu Chen, Charles Aymes, Keri Veres, Bernard Koltisko
  • Publication number: 20120095099
    Abstract: The invention relates to trans carotenoid compounds and salts thereof as well as compositions thereof, methods for making them, and uses thereof. These compounds are useful in improving diffusivity of oxygen between red blood cells and body tissues in mammals including humans.
    Type: Application
    Filed: August 5, 2011
    Publication date: April 19, 2012
    Applicant: Diffusion Pharmaceuticals LLC
    Inventors: John L. Gainer, Marc Lanz
  • Publication number: 20120088869
    Abstract: Organic materials which possess outstanding stability to oxidative, thermal or light-induced degradation comprise as stabilizers at least one compound of the formula I wherein the general symbols are as defined in claim 1. The compounds of formula I are especially useful as stabilizers for protecting polymers and lubricants against oxidative, thermal or light-induced degradation and as scavengers for oxidized developer in color photographic material.
    Type: Application
    Filed: December 20, 2011
    Publication date: April 12, 2012
    Inventors: Michèle GERSTER, Peter NESVADBA
  • Publication number: 20120083435
    Abstract: Provided herein are compounds, including those of the Formula II in which n is an integer equal to or greater than 1; R2, is selected from hydrogen and optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched; and R3, and R4, independently for each occurrence, are selected from optionally substituted alkyl that is saturated or unsaturated, and branched or unbranched. Also provided are compositions containing such compounds and methods of making both compounds and compositions thereof.
    Type: Application
    Filed: August 31, 2011
    Publication date: April 5, 2012
    Inventor: Jakob BREDSGUARD
  • Publication number: 20120071457
    Abstract: A new metallo-?-lactamase inhibitor which acts as a medicament for inhibiting the inactivation of ?-lactam antibiotics and recovering anti-bacterial activities is disclosed. The maleic acid derivatives having the general formula (I) have metallo-?-lactamase inhibiting activities. It is possible to recover the anti-bacterial activities of ?-lactam antibiotics against metallo-?-lactamase producing bacteria by combining the compound of the general formula (I) with ?-lactam antibiotics.
    Type: Application
    Filed: November 29, 2011
    Publication date: March 22, 2012
    Inventors: Ken Chikauchi, Mizuyo Ida, Takao Abe, Yukiko Hiraiwa, Akihiro Morinaka, Toshiaki Kudo
  • Publication number: 20120071686
    Abstract: Diesters are prepared by first hydrolyzing dinitrile compounds into imide compounds and then reacting such imide compounds with at least one alcohol.
    Type: Application
    Filed: October 21, 2008
    Publication date: March 22, 2012
    Inventors: Roland Jacquot, Philippe Leconte
  • Patent number: 8138116
    Abstract: The application discloses a Titanium oxide composition and the application thereof. The mentioned Titanium oxide composition comprises Titanium co-precipitate(s), organic acid, diol, and water. According to this application, a catalyzed poly-esterification with said Titanium oxide composition is also disclosed. The mentioned polyesterification comprises a step of adding said Titanium oxide composition into at least one stage selected from slurry stage, esterification stage, and polycondensation stage.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: March 20, 2012
    Assignee: Far Eastern New Century Corporation
    Inventors: Hsin-Chin Ho, Ching-Tsu Peng, Shih-Fong Lee, Yui-Chi Lin, Chun-Wei Chen