Abstract: The method of making an acid-absorbing biosolid composition provides a method for the use of recycled materials to produce an acid-absorbing composition that may then be recycled as a fertilizer after absorbing the acid. The method includes the steps of: collecting sewage sludge; drying the sewage sludge to remove water therefrom to form dried sludge; adding hydrochloric acid to the dried sludge to form a liquid intermediary product; heating the liquid intermediary product to produce a dried porous biomass; and mixing inorganic waste material with the dried porous biomass to produce the acid-absorbing biosolid composition. Thereafter, the acid-absorbing biosolid composition may be placed in a gas flow to absorb an acidic component therefrom; and then recycled for use as fertilizer following absorption of the acidic component from the gas flow.

Abstract: The invention is directed to methods and equipment for generating an activated sorbent from a sorbent precursor with the addition of certain chemicals that enhance the effectiveness of the activated sorbent. The invention is also directed to the methods and equipment for generating some of the chemicals that are added to the raw carbonaceous material or activated sorbent to enhance its effectiveness. The invention is also directed to methods and equipment for generating certain chemicals that can be added to a gas stream to convert a given gaseous pollutant to a form that is more easily removed from the gas stream. The invention is also directed to methods and equipment for adding an activated sorbent and various chemicals for a gas stream having one or more gaseous pollutants.

Abstract: The disclosure relates to metal organic frameworks or isoreticular metal organic frameworks, methods of production thereof, and methods of use thereof.

Abstract: A purging apparatus for a storage chamber is disclosed. The purging apparatus is configured for establishing a purge gas flow through the storage chamber. The purging apparatus may include a gas purifier and a particle filter. The gas purifier may provide a purge gas to the storage chamber. The purge gas may flow through the storage chamber, and a mixture of the purge gas and potential contaminants may subsequently exit the storage chamber as exhaust gas. The particle filter may receive and filter the exhaust gas. The filtered gas may be provided to the gas purifier for purification and recirculation. The gas purifier may purify the filtered gas by substantially removing at least one of: an acid, a base, an organic compound, water or oxygen from the filtered gas. The purified filtered gas may then be recirculated and provided to the storage chamber as the purge gas.

Abstract: The various embodiments of the present invention relate to compositions, apparatus, and methods comprising sorbent fibers. More particularly, various embodiments of the present invention are directed towards sorbent fiber compositions for temperature swing adsorption processes. Various embodiments of the present invention comprise sorbent fiber compositions, apparatus comprising a plurality of sorbent fibers, and methods of using the same for the capture of at least one component from a medium, for example CO2 from flue gas.

Abstract: A method of transferring filter media between a media bed of a dry scrubber and a filter media container, comprising placing the media bed in flow communication with the filter media container, obstructing a majority of an airflow path of the media bed, the airflow path extending from an unfiltered air input opening of the dry scrubber, through the media bed of the dry bed scrubber, to a filtered air output opening of said dry bed scrubber, powering a blower in the airflow path of the media bed when the airflow path is obstructed and the media bed is in flow communication with the filter media container, whereby the filter media is transferred between the media bed and the filter media container.

Abstract: Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Abstract: This invention provides methods for separating gas components from a gas stream. The methods are particularly advantageous in that an environmentally friendly biomass absorbent is used to assist in the separation process. The invention is particularly suited to separate water soluble gas components from a gas stream. The water soluble gas components can be used to condition the biomass for additional use, such as a conditioned feed for a biofuel. In general, the conditioned biomass will have increased enzyme digestibility, making the conditioned biomass highly suitable as feedstock for biofuel production.

Abstract: The present invention relates to an integrated membrane/adsorbent process and system for removal of carbon dioxide from natural gas on a ship that houses natural gas purification equipment. Additional membrane units or adsorbent beds are used to reduce the amount of product gas that is lost in gas streams that are used to regenerate the adsorbent beds. These systems produce a product stream that meets the specifications of less than 50 parts per million carbon dioxide in natural gas for liquefaction.

Abstract: Porous bulk materials formed of shape-persistent, non-collapsible, three-dimensional molecular cage building blocks are presented that are useful for a variety of applications including gas separation/storage, sensing, and catalysis.

Abstract: Fe2(dobdc) has a metal-organic framework with a high density of coordinatively-unsaturated FeII centers lining the pore surface. It can be effectively used to separate O2 from N2 and in a number of additional separation applications based on selective, reversible electron transfer reactions. In addition to being an effective O2 separation material, it can be used for many other processes, including paraffin/olefin separation, nitric oxide/nitrous oxide separation, acetylene storage, and as an oxidation catalyst.

Abstract: One or more embodiments relates to the production of a fabricated fiber having an asymmetric polymer network and having an immobilized liquid such as an ionic liquid within the pores of the polymer network. The process produces the fabricated fiber in a dry-wet spinning process using a homogenous dope solution, providing significant advantage over current fabrication methods for liquid-supporting polymers. The fabricated fibers may be effectively utilized for the separation of a chemical species from a mixture based on the selection of the polymer, the liquid, and the solvent utilized in the dope.

Abstract: Disclosed herein are highly interpenetrated robust metal-organic frameworks having the repeat unit Zn5(BTA)6(TDA)2, useful for applications such as selective gas storage, selective gas sorption and/or separation, and gas detection.

Abstract: The present invention provides a multi-functional nonwoven fabric for filter that has excellent properties to adsorb various toxic/harmful substances such as odorous substances, VOCs, allergens, and pathogenic viruses, has antibacterial/antimold properties, and suppresses pressure loss to a minimal level, and the present invention also provides a method that can produce such a nonwoven fabric in a simple manner. Due to the simple steps of immersing the nonwoven fabric in an aqueous polypeptide solution and further treating it with a metal salt, it is possible to obtain a nonwoven fabric for filter having excellent adsorption properties in which the fiber surface of the nonwoven fabric is coated with insolubilized polypeptide that has been crosslinked with a metal. Also, a method that can produce such a filter in a simple manner was found.

Abstract: The various embodiments of the present invention relate to compositions, apparatus, and methods comprising sorbent fibers. More particularly, various embodiments of the present invention are directed towards sorbent fiber compositions for temperature swing adsorption processes. Various embodiments of the present invention comprise sorbent fiber compositions, apparatus comprising a plurality of sorbent fibers, and methods of using the same for the capture of at least one component from a medium, for example CO2 from flue gas.

Abstract: Apparatus and methods for reducing or eliminating undesirable air-borne substances, such as odors, bacteria, viruses, fungi, and toxins, are provided. A filter containing nanocrystalline metal oxide or metal hydroxide particles may be installed within an air handling apparatus such as an existing HVAC unit located within a building, and particularly within a home, or a portable air processor or purifier. The air handling apparatus comprises a blower which pulls air containing various undesirable substances from within the enclosed environment and directs it through a filtering device containing the nanocrystalline particles. The undesirable substances are sorbed by the nanocrystalline particles thereby creating a deodorized stream of air that may then be directed back into various portions of the enclosed environment or vented to the atmosphere.

Abstract: The invention concerns a crystalline solid designated IM-18 which has the X-ray diffraction diagram given below. Said solid has a chemical composition expressed by the empirical formula: mXO2:nGeO2:pZ2O3:qR:sF:wH2O, in which R represents one or more organic species, X represents one or more tetravalent element(s) other than germanium, Z represents at least one trivalent element and F is fluorine.

Abstract: Embodiments of the invention relate to a composite hydrogen storage material comprising active material particles and a binder, wherein the binder immobilizes the active material particles sufficient to maintain relative spatial relationships between the active material particles.

Abstract: The present invention relates to a method for producing a porous metal-organic framework material comprising the step reacting a reaction mixture in the liquid phase of at least one copper compound having at least one at least bidentate, organic compound which can bind by coordination to the copper in the presence of a nonaqueous solvent, the at least one at least bidentate, organic compound being derived from a polycarboxylic acid having at least three carboxyl groups, and the reaction proceeding at atmospheric pressure above 80° C.

Abstract: Method for recovering a desired component from a waste gas comprising (a) at an operating facility, introducing a waste gas comprising the desired component and one or more undesired components into an adsorber containing adsorbent material selective for the desired component, adsorbing at least a portion of the desired component therein, (b) terminating flow of waste gas into the adsorber; and (c) recovering and concentrating the desired component by either (1) isolating the adsorber, transporting the adsorber to a central processing facility, or (2) withdrawing from the adsorber an intermediate gas enriched in the desired component, compressing the intermediate gas and storing it in a vessel, isolating the vessel, transporting the vessel to a central processing facility to provide a concentrated product further enriched in the desired component.

Abstract: Embodiments of crystalline, titanium silicate molecular sieves are described having a formula representing mole ratios of oxides of nM1O:TiO2:ySiO2:zH2O:wX where M1 refers to a metal cation or mixture of metal cations; n is from about 1 to about 2; y is from about 1 to about 10; z is from 0 to about 100; X is a halide anion other than fluorine, or combination of halide anions that excludes fluorine; and w is greater than 0. The pore size of the sieves can be adjusted by ion exchanging M1 cations with a suitable amount of another species. Embodiments of the invention are useful for various adsorptive fluid separation processes, including pressure swing adsorption processes. For example, disclosed embodiments are useful for separating methane from air.

Abstract: A method for reducing the content of foreign molecules in gaseous or liquid form dissolved in a pressure transfer liquid of a pressure measuring transducer. A pressure receiving chamber is closed by an isolating diaphragm. A pressure measuring chamber is connected to the pressure receiving chamber, and a pressure sensor arranged in the pressure measuring chamber, in which the liquid serves to fill an inner space of the pressure measuring transducer formed by the pressure receiving chamber is provided. The pressure measuring chamber is connected therewith, and transfers an external pressure acting on the isolating diaphragm to the pressure sensor in measurement operation. The liquid is brought into contact with at least one adsorptive body, and foreign molecules dissolved in the liquid are bound to the adsorptive bodies by adsorption.

Abstract: Includes gas adsorption device (1) in which gas adsorbent (3) is decompression-sealed by first package (4) with poor gas permeability, and second package (2) with poor gas permeability. Second package (2) is at least partially flexible. Air that is a gas that gas adsorbent (3) can adsorb is filled between gas adsorption device (1) and second package (2). In this configuration, gas adsorbent (3) adsorbs air when first package (4) is damaged, and thus a pressure inside second package (2) reduces. Due to this pressure reduction, the shape or dimension of second package (2) changes. Any damage to first package (4), i.e., any degradation in adsorption capacity of gas adsorption device (1), can thus be determined by confirming this change.

Abstract: A metal-organic framework-based mesh-adjustable molecular sieve (MAMS) exhibiting a temperature-dependent mesh size. The MAMS comprises a plurality of metal clusters bound with a plurality of amphiphilic ligands, each ligand comprising a hydrophobic moiety and a functionalized hydrophilic moiety, and wherein the metal clusters and amphiphilic ligand functionalized hydrophilic moieties form a metal cluster layer, the metal cluster layer forming at least one hydrophilic pore. On each side of the metal cluster layer, a plurality of associated amphiphilic ligand hydrophobic moieties cooperate with the metal cluster layer to form a tri-layer and a plurality of tri-layers are packed in a facing-spaced apart relationship to form at least one hydrophobic pore.

Abstract: This application discloses porous self-sealing media comprising a sintered mixture of an absorbent material and a thermoplastic. The self-sealing media block passage of organic solvents or organic solvents in aqueous mixtures, wherein the organic solvents are at concentrations greater than about 40%. The self-sealing media also block acidic solutions. The self-sealing media are useful in a variety of applications such as a pipette tip filter, in line filter, vent, non-mechanical check valve, safety valve, and suction canister.

Abstract: According to one embodiment, a generated gas collecting method collects a generated gas after exposing the interior of a chamber to an organic gas having a boiling point higher than that of the generated gas.

Abstract: A porous metal organic framework containing an at least bidentate organic compound coordinated to a metal ion, wherein the metal ion is AlIII and the at least bidentate organic compound is 2-aminoterephthalic acid, and wherein the framework is in powder form and has a specific surface area determined by the Langmuir method (N2, 77 K) of at least 2500 m2/g. In addition, a shaped body containing the metal organic framework, processes for preparing the metal organic framework and shaped body, and processes for storing and separating gases with the metal organic framework and shaped body.

Abstract: Methods for performing separation of gaseous entities via contacting the gaseous entities with a sorbent material including a porous structured organic film including a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein at a macroscopic level the covalent organic framework is a film are described.

Abstract: Embodiments of the present invention are directed to systems and methods for treating landfill gas using landfill leachate. In one embodiment of the present invention, a method includes receiving landfill leachate from at least one of a plurality of sources, and pretreating the landfill leachate to adjust at least one chemical property of at least one component of the landfill leachate. The leachate contacts landfill gas, so that at least one component of the landfill gas chemically reacts with at least one component of the landfill leachate to form a spent landfill leachate and a treated landfill gas. The method also includes recycling a first portion of the spent landfill leachate, recirculating a second portion of the spent landfill leachate to at least one of the plurality of sources, and subjecting the treated landfill gas to flare.

Abstract: The present invention relates to an integrated membrane/absorbent/adsorbent process and system for removal of mercury and sulfur compounds from natural gas on a ship that houses natural gas purification equipment. First mercury and most of the sulfur compounds are removed by an adsorbent bed and then the natural gas stream passes through a membrane unit to produce a partially purified natural gas residue stream to be dried and then liquefied and a carbon dioxide permeate stream that can be used as a fuel gas.

Abstract: This invention relates to aggregates of small particles of synthetic faujasite zeolite. Small primary particles of zeolite are clustered into larger secondary particles. The observable average width of the primary particles may be 0.3 micron or less and the observable average width of the secondary particles may be 0.8 micron or more. The silica to alumina ratio of the zeolite may be less than 4:1.

Abstract: Disclosed are tetratopic carboxylic acid phenyl for use in metal-organic framework compounds. These compounds are useful in catalysis, gas storage, sensing, biological imaging, drug delivery and gas adsorption separation.

Abstract: A gas separation process uses a structured particulate bed of adsorbent coated shapes/particles laid down in the bed in an ordered manner to simulate a monolith by providing longitudinally extensive gas passages by which the gas mixture to be separated can access the adsorbent material along the length of the particles. The particles can be laid down either directly in the bed or in locally structured packages/bundles which themselves are similarly oriented such that the bed particles behave similarly to a monolith but without at least some disadvantages. The adsorbent particles can be formed with a solid, non-porous core with the adsorbent formed as a thin, adherent coating on the exposed exterior surface. Particles may be formed as cylinders/hollow shapes to provide ready access to the adsorbent. The separation may be operated as a kinetic or equilibrium controlled process.

Abstract: The various embodiments of the present invention relate to compositions, apparatus, and methods comprising sorbent fibers. More particularly, various embodiments of the present invention are directed towards sorbent fiber compositions for temperature swing adsorption processes. Various embodiments of the present invention comprise sorbent fiber compositions, apparatus comprising a plurality of sorbent fibers, and methods of using the same for the capture of at least one component from a medium, for example CO2 from flue gas.

Abstract: One exemplary embodiment can be an apparatus for isomerizing a hydrocarbon stream rich in a C4 hydrocarbon and/or at least one of a C5 and C6 hydrocarbon. The apparatus can include: a first drier and a second drier adapted to receive a fluid including at least one reactant; and a reaction zone communicating with the first drier to receive the fluid including at least one reactant and with the second drier to receive the regenerant. Generally, the first drier operates at a first condition to dry the fluid including at least one reactant and the second drier operates at a second condition during regeneration with a regenerant. The regenerant is displaced from the drier using a down-flow regenerant displacement assembly.

Abstract: A carbon composite material, including a plurality of spaced graphene sheets, each respective sheet having opposed generally planar surfaces, and a plurality of functionalized carbonaceous particles. At least some functionalized carbonaceous particles are disposed between any two adjacent graphene sheets, and each respective at least some functionalized carbonaceous particle is attached to both respective any two adjacent graphene sheets. Each respective graphene sheet comprises at least one layer of graphene and at least portions of respective any two adjacent graphene sheets are oriented substantially parallel with one another.

Abstract: A method is described for separating off trace components from a fraction (1) containing at least nitrogen and helium, wherein this fraction is partially condensed (E) before enrichment of the helium. The partially condensed fraction (2) is fed at least in part to at least one separation column (T) and separated therein into a helium-rich gas fraction (6) and a nitrogen-rich liquid fraction which also contains the unwanted trace components (5).

Abstract: A fluid separation apparatus suitable for separating a mixed fluid with different properties and capable of separating a complex fluid mixture efficiently is provided. The fluid separation apparatus includes a sampling entrance, a first separation column, a second separation column, a bypass line, a detector and a guide multi-channel valve. A mixed fluid flows into the first separation column via the sampling entrance. The second separation column is connected to the first separation column in series and connected to the bypass line in parallel. The detector is connected to the second separation column and the bypass line. The guide multi-channel valve has different modes to control a flow-through status and a closed status between the first separation column and the second separation column, between the first separation column and the bypass line, between the second separation column and the detector, and between the bypass line and the detector.

Abstract: Toxic substances such as heavy metals are extracted from a medium using a sorbent composition. The sorbent composition is derived by sulfidation of red mud, which contains hydrated ferric oxides derived from the Bayer processing of bauxite ores. Exemplary sulfidizing compounds are H2S, Na2S, K2S, (NH4)2S, and CaSx. The sulfur content typically is from about 0.2 to about 10% above the residual sulfur in the red mud. Sulfidized red mud is an improved sorbent compared to red mud for most of the heavy metals tested (Hg, Cr, Pb, Cu, Zn, Cd, Se, Th, and U). Unlike red mud, sulfidized red mud does not leach naturally contained metals. Sulfidized red mud also prevents leaching of metals when mixed with red mud. Mixtures of sulfidized red mud and red mud are more effective for sorbing other ions, such as As, Co, Mn, and Sr, than sulfidized red mud alone.

Abstract: Thermally-activated cellulosic-based carbon is rendered more thermally stable by exposure to a halogen and/or a halogen-containing compound. Such treated cellulosic-based carbon is suitable for use in mitigating the content of hazardous substances in flue gases, especially flue gases having a temperature within the range of from about 100° C. to about 420° C.

Abstract: The disclosure provides for novel metal-triazolate frameworks, methods of use thereof, and devices comprising the frameworks thereof.

Abstract: The present invention relates to a process for producing at least one CO2-lean gas and at least one CO2-rich fluid. In particular, it relates to a process for capturing dioxide in a fluid containing at least one compound more volatile than carbon dioxide such as, for example, methane CH4, oxygen O2, argon Ar, nitrogen N2, carbon monoxide CO, helium He and/or hydrogen H2.

Abstract: Disclosed are embodiments for methods and devices for filtering undesired particles from a medium by bonding the undesired particles to attachment particles. In some embodiments, the methods include receiving a plurality of attachment particles into a volume, where the volume contains a plurality of undesired particles and the medium. The method may also include contacting the plurality of attachment particles and the plurality of undesired particles contained in the medium, resulting in formation of bonded particles in the medium. Contacting may result in collisions, causing bonding between some undesired particles and some attachment particles. Some embodiments of the method also include removing at least a portion of the medium and bonded particles from the volume through a filter coupled to the volume with an exhaust, the filter configured to capture the bonded particles while allowing the medium to pass through.

Abstract: The present invention relates to active charcoals with improved mechanical properties. They can advantageously be used in the sweetening of petroleum fractions, as oxidation catalyst support in the conversion of mercaptans to disulphides, but also in any other type of reaction, such as, for example, for the oxidation of cyanide present in water or in the synthesis of glyphosate, and in processes for purification and/or separation by selective adsorption in a liquid phase and/or in a gas phase (decolouration of liquid foodstuffs, water treatment, air treatment, recovery of solvents, and the like).

Abstract: A method comprising (i) providing a metal organic framework formed by AlIII ions to which fumarate ions are coordinated to produce a porous framework structure, (ii) bringing a substance into contact with the metal organic framework such that the substance is uptaken by the porous metal organic framework to provide storage of or controlled release of, the substance.

Abstract: The present invention generally relates to compositions comprising and methods for forming functionalized carbon-based nanostructures.

Abstract: Apparatuses for controlling a humidity level within an enclosed volume storage device and methods for using same. The apparatus, in one embodiment, comprises a container having outer walls defining an inner volume, at least one of the outer walls, preferably an lid wall, having perforations therein. The apparatus further comprises a composition capable of adsorbing and desorbing water and contained in the inner volume of the container. The composition is hydrated to a hydration level less than about 0.13 mL water per gram of the composition. The methods include a step of hydrating the composition in an apparatus of the invention to a hydration level less than about 0.13 mL water per gram of composition.

Abstract: EMM-11 is a novel synthetic crystalline microporous material having a single crystalline phase with a unique 3-dimensional channel system comprising three sets of channels, namely a first set comprising 10-ring channels, and a second set and third set comprising 8-ring channels, having a unique T-atom connectivity and X-ray diffraction pattern which identify it as a novel material, and may be prepared with an organic structure directing agent, preferably, 3-isopropyl-1-methyl-1H-imidazol-3-ium. EMM-11 may be used in organic compounds conversion and absorptive processes.

Abstract: An adsorbent material comprising a metal organic phase and a porous silica phase is provided. The adsorbent material can be a synthesized from at least one porous silica material, one or more metal ions, and at least one organic linker comprising one or more multidentate functional groups capable of forming coordinate bonds with the metal ions. The porous silica can be an ordered mesoporous silica material. Methods of making the adsorbent material and methods of removing molecules from a fluid using the adsorbent material are also provided.

Abstract: Composite adsorbent beads have a porous and non-adsorbent core comprising at least one inorganic material and a porous and adsorbent shell comprising at least one adsorbent layer comprising a porous adsorbent material on the surface of the core. The core preferably comprises agglomerated inorganic particles having a mean particle size equal to or smaller than the mean particle size of the surrounding agglomerated adsorbent particles. The beads preferably are manufactured by calcining together a non-sintered core and the adsorbent layer. The beads can be used at the outlet end of an adsorption column to improve performance.