CRYSTALLINE THIN-FILM TRANSISTOR
A method for forming a thin film transistor includes joining a crystalline substrate to an insulating substrate. A doped layer is deposited on the crystalline substrate, and the doped layer is patterned to form source and drain regions. The crystalline substrate is patterned to form an active area such that a conductive channel is formed in the crystalline substrate between the source and drain regions. A gate stack is formed between the source and drain regions, and contacts are formed to the source and drain regions and the gate stack through a passivation layer.
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This application is a Continuation application of co-pending U.S. patent application Ser. No. 13/736,534 filed on Jan. 8, 2013, incorporated herein by reference in its entirety.
BACKGROUND1. Technical Field
The present invention relates to display devices, and more particularly to thin film transistors having a crystalline channel that meets low-temperature processing requirements of low-cost and/or flexible substrates.
2. Description of the Related Art
Mainstream thin film transistor (TFT) devices are comprised of amorphous or polycrystalline materials as active channel materials. One reason for the use of such materials is that amorphous and polycrystalline materials permit large area and low cost deposition. This is particularly suitable for low-cost substrates such as glass or flexible plastic. However, the performance of these devices (particularly mobility and therefore drive current and switching speed) is limited by the non-crystalline nature of the semiconductor active material. On the other hand, high processing temperatures typically required for crystalline semiconductor materials are not compatible with low-cost substrates associated with amorphous and polycrystalline devices.
Active matrix TFT organic light emitting diode (OLED) displays employ amorphous and polycrystalline devices. Typically amorphous hydrogenated silicon (a-Si:H) or low temperature polysilicon (LTPS) TFTs are employed as a backplane. However, the mobility of a-Si:H is too low for high resolution OLED displays, and LTPS suffers from device-to-device threshold voltage (VT) variation and compensation circuitry limit resolution.
SUMMARYA method for forming a thin film transistor includes joining a crystalline substrate to an insulating substrate. A doped layer is deposited on the crystalline substrate, and the doped layer is patterned to form source and drain regions. The crystalline substrate is patterned to form an active area such that a conductive channel is formed in the crystalline substrate between the source and drain regions. A gate stack is formed between the source and drain regions, and contacts are formed to the source and drain regions and the gate stack through a passivation layer.
A method for forming a thin film transistor for displays includes joining a crystalline substrate to an insulating substrate; depositing a doped layer on the crystalline substrate; patterning the doped layer to form source and drain regions; patterning the crystalline substrate to form an active area such that a conductive channel is formed in the crystalline substrate between the source and drain regions; forming a gate stack between the source and drain regions; forming contacts to the source and drain regions and the gate stack through a first passivation layer; forming one or more metallization layers to provide lines for connecting components; and depositing and patterning a transparent conductor on the insulating substrate to form pixel electrodes.
A thin film transistor includes a crystalline substrate wafer bonded to an insulating substrate and patterned to form an active area such that a conductive channel is formed in the crystalline substrate between source and drain regions formed on the active area. A gate stack is formed between the source and drain regions. Contacts are coupled to the source and drain regions and the gate stack and formed through a passivation layer.
These and other features and advantages will become apparent from the following detailed description of illustrative embodiments thereof, which is to be read in connection with the accompanying drawings.
The disclosure will provide details in the following description of preferred embodiments with reference to the following figures wherein:
In accordance with the present principles, devices and methods for fabrication are described that permit the use of crystalline substrate materials for thin film transistors. The use of crystalline materials, e.g., monocrystalline or multicrystalline material, permits higher carrier mobility and better operational efficiency over noncrystalline materials (e.g., amorphous or polycrystalline materials). In addition, in accordance with the present methods, costs of fabrication are maintained comparable to the costs for non-crystalline devices.
The present embodiments, enable cost effective fabrication of not only standard resolution displays, e.g., 100 dots per inch (dpi), but for high definition (HD) (about 150 dpi), microdisplays/picoprojectors (greater than 1000 dpi) and beyond. In accordance with particularly useful embodiments, crystalline substrates may be processed using layer transfer techniques to avoid expensive and high temperature CMOS (complementary metal oxide semiconductor) processing/foundry.
It is to be understood that the present invention will be described in terms of a given illustrative architecture for a display device; however, other architectures, structures, substrate materials and process features and steps may be varied within the scope of the present invention.
It will also be understood that when an element such as a layer, region or substrate is referred to as being “on” or “over” another element, it can be directly on the other element or intervening elements may also be present. In contrast, when an element is referred to as being “directly on” or “directly over” another element, there are no intervening elements present. It will also be understood that when an element is referred to as being “connected” or “coupled” to another element, it can be directly connected or coupled to the other element or intervening elements may be present. In contrast, when an element is referred to as being “directly connected” or “directly coupled” to another element, there are no intervening elements present.
A design for an integrated circuit or display device may be created in a graphical computer programming language, and stored in a computer storage medium (such as a disk, tape, physical hard drive, or virtual hard drive such as in a storage access network). If the designer does not fabricate chips or displays or the photolithographic masks used to fabricate chips or displays, the designer may transmit the resulting design by physical means (e.g., by providing a copy of the storage medium storing the design) or electronically (e.g., through the Internet) to such entities, directly or indirectly. The stored design is then converted into the appropriate format (e.g., GDSII) for the fabrication of photolithographic masks, which typically include multiple copies of the design in question that are to be formed on a wafer or substrate. The photolithographic masks are utilized to define areas of the wafer or substrate (and/or the layers thereon) to be etched or otherwise processed.
Methods as described herein may be used in the fabrication of integrated circuit chips or displays. The resulting integrated circuit chips or displays can be distributed by the fabricator in raw form, as a bare die, or in a packaged form. In any case, the chip or display is then integrated with other chips, discrete circuit elements, and/or other signal processing devices as part of either (a) an intermediate product, such as a screen, or (b) an end product, such as a display device. The end product can be any product that includes a display, ranging from toys and other low-end applications to advanced computer products having a display, a keyboard or other input device, and a central processor.
Reference in the specification to “one embodiment” or “an embodiment” of the present principles, as well as other variations thereof, means that a particular feature, structure, characteristic, and so forth described in connection with the embodiment is included in at least one embodiment of the present principles. Thus, the appearances of the phrase “in one embodiment” or “in an embodiment”, as well any other variations, appearing in various places throughout the specification are not necessarily all referring to the same embodiment.
It is to be appreciated that the use of any of the following “/”, “and/or”, and “at least one of', for example, in the cases of “A/B”, “A and/or B” and “at least one of A and B”, is intended to encompass the selection of the first listed option (A) only, or the selection of the second listed option (B) only, or the selection of both options (A and B). As a further example, in the cases of “A, B, and/or C” and “at least one of A, B, and C”, such phrasing is intended to encompass the selection of the first listed option (A) only, or the selection of the second listed option (B) only, or the selection of the third listed option (C) only, or the selection of the first and the second listed options (A and B) only, or the selection of the first and third listed options (A and C) only, or the selection of the second and third listed options (B and C) only, or the selection of all three options (A and B and C). This may be extended, as readily apparent by one of ordinary skill in this and related arts, for as many items listed.
Referring now to the drawings in which like numerals represent the same or similar elements and initially to
A crystalline substrate 14 is applied to the substrate 12 by a transfer process. The transfer process may include a wafer transfer process (e.g., wafer bonding) and may include cleaving, etching adhesion or other wafer transfer techniques. The substrate 14 may be bonded to the substrate 12 using adhesives, or the substrate 12 (e.g., a silicon oxide, silicon nitride or the like) may be grown on a thick substrate and cleaved along a crystal plane to form the substrate 14, e.g., spalling, smart cut, epitaxial layer lift-off (ELO), etc. In one particularly useful embodiment, the substrate 14 includes monocrystalline Si, although other monocrystalline or multi or polycrystalline materials may be employed. Other substrate materials may include, e.g., SiGe, Ge, GaAs, etc. The substrate 14 may be doped prior to wafer/layer transfer.
Source and drain regions 16, 18 are formed on the substrate 14, and may form a homojunction or a heterojunction. The source and drain regions 16, 18 may be deposited epitaxially using a low temperature process. In one embodiment, the deposition process includes a plasma enhanced chemical vapor deposition (PECVD) process, at a temperature below about 400 degrees C. and preferably at a temperature between about 150 to about 250 degrees C., and more preferably below 200 degrees C. The source and drain regions 16, 18 may be selectively grown on the substrate 14 and doped later using appropriate masking techniques. The source and drain regions 16, 18 may be deposited in amorphous, nanocrystalline, microcrystalline or crystalline form, patterned and doped later or grown and doped in-situ. The source and drain regions 16, 18 may include Si and, in particular, hydrogenated Si in a noncrystalline form (e.g., amorphous, nanocrystalline, microcrystalline).
The source and drain regions 16, 18 may be spaced apart to form channel regions having a length, L, and width, W. Since crystalline material is employed for substrate 14, carrier mobility is increased. This permits the use of smaller W and/or longer L devices. In particularly useful embodiments, a W/L ratio is less than 25 and more preferably less than 5. The smaller W leads to better display resolution (more dpi). The longer L reduces lithography costs (a larger dimension is easier to process). Increased mobility also can reduce power consumption as operation voltages can be reduced.
A gate stack is formed, which includes the formation and patterning of a gate dielectric 22. The gate dielectric 22 preferably includes a high dielectric constant (high-k) material where the dielectric constant is greater than the dielectric constant of silicon dioxide. Such materials may include hafnium dioxide, silicon oxynitride, zirconium dioxide, titanium dioxide, tantalum oxide, etc. The gate stack further includes a gate conductor 23, which may include a metal or other conductive material. The gate conductor 23 may include, e.g., aluminum, chromium, molybdenum, nickel, titanium-nitride, etc. or combinations of materials. The gate stack is patterned to properly size the gate dimensions.
A dielectric layer 24 is formed over the TFT device 25 and is patterned to open up holes for contacts 26, 28 and 30. The contacts 28 and 26 connect to the source and drain regions 16, 18 and the contact 30 connects to the gate conductor 23. The dielectric layer 24 may include a silicon oxide or silicon nitride although other materials may be employed. The contacts 26, 28 and 30 may include a metal such as aluminum, chromium, molybdenum, copper, doped polysilicon, etc.
A transparent conductive material is deposited and patterned to form electrode 20. The transparent conductive material may include indium tin oxide, although other transparent conductors, such as, aluminum-doped zinc oxide, fluorine doped tin oxide, etc. The electrode 20 connects to the contact 26. A passivation layer 32 is formed over the TFT device 25 and the electrode 20 and then is removed from portions of the electrode 20 using a masked etch. The passivation layer 32 may include a dielectric material (e.g., silicon dioxide, etc.). The passivation layer 32 also serves to provide edge planarization for the electrode 20.
It should be understood that during processing of the TFT device 25, other TFT devices and/or pixel structures may also be formed. These may include a switching transistor (TFT), contacts, capacitors, etc.
Referring to
In the illustrative embodiment shown, data line 48, power line 47, interconnects 52, 26, 27, 28 and a capacitor plate 49 are formed during M1 metallization. In addition, an address or select line 50, switching TFT gate conductor 51, interconnect 54, driver TFT gate conductor 23 and capacitor plate 42 are formed during M2 metallization. A via 46 is formed between M1 and M2 from M2 material. In the illustrative examples of
A transparent conductor plate 20 (corresponding to electrode 20 of
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Smart cut is similar to spalling in that it cleaves a larger substrate to achieve the substrate 14 and provide a thin crystalline layer. The layer is cleaved using bubble formation along the cleave line. Substrate 12 is attached to the larger substrate and bubbles are formed in the larger substrate by stress or other means. The substrate 14 is then separated from the larger substrate enabling the transfer of a very thin layer of crystalline material onto substrate 12. In the ELO process, a thin portion of the thick substrate which has been grown epitaxially is transferred onto substrate 12 using known techniques. Other cleaving and transfer processes may also be employed. It should be noted that the substrate 14 may be doped during formation (in-situ) and is preferably doped in advance of the transfer process but may be doped after the transfer process. In another embodiment, the thick substrate may have an insulating substrate 12 formed thereon and a back side of the thick substrate may be etched to form the thin substrate 14 on substrate 12. Wafer transfer is one technique employed to enable the use of crystalline substrates with comparable costs to other display technologies, i.e., LTPS, amorphous Si, etc.
Referring to
In a particularly useful embodiment, a PECVD (or hot-wire chemical vapor deposition (HWCVD)) process is employed to selectively form a crystalline Si (or SiGe) doped layer on top of exposed portions of the substrate 14, although non-crystalline morphologies may be formed as well depending on the deposition parameters employed. The PECVD (or HWCVD) is preferably a low temperature process. The doped layer may include a Si containing layer, a Ge containing layer, or combinations thereof. In particularly useful embodiments, the doped layer may include hydrogen content in the range of about 5-40% (atomic percent), and may include germanium (Ge), carbon (C), fluorine (F), deuterium (D), nitrogen (N) and combinations thereof. Non-crystalline refers to amorphous, nanocrystalline or microcrystalline, while crystalline refers to single crystalline or polycrystalline.
The gas source providing Si for the doped layer may include silane (SiH4), other gases such as disilane (Si2H6), dichlorosilane (DCS), tetrafluorosilane (SiF4) or combinations thereof may be used as well. The gas source providing Ge for Ge containing layers may include germane (GeH4). In-situ p-type doping may be performed using diborane (B2H6) or trimethylboron (TMB) sources, and in-situ n-type doping may be performed using a phosphine (PH3) gas source, although other dopant sources may be used as well.
In one embodiment, the selective epitaxial growth of silicon is performed in a hydrogen diluted silane environment using PECVD. The gas ratio of hydrogen gas to silane gas ([H2]/[SiH4]) at 150 degrees C. is preferably between 0 to about 1000. In particularly useful embodiments, epitaxial growth of silicon begins at a gas ratio of about 5-10. The epitaxial Si quality is improved by increasing the hydrogen dilution, e.g., to 5 or greater.
Epitaxial silicon can be grown using various gas sources, e.g., silane (SiH4), dichlorosilane (DCS), SiF4, SiCl4 or the like. The quality of epitaxial silicon improves by increasing the dilution of hydrogen using these or other gases. For higher hydrogen dilution, smoother interfaces were produced (epitaxial silicon to crystalline silicon) and fewer stacking faults and other defects were observed.
Radio-frequency (RF) or direct current (DC) plasma enhanced chemical vapor deposition (CVD) is preferably performed at deposition temperature ranges from about room temperature to about 400 degrees C., and preferably from about 150 degrees C. to about 200 degrees C. Plasma power density may range from about 2 mW/cm2 to about 2000 mW/cm2. A deposition pressure range may be from about 10 mTorr to about 5 Torr.
A carrier gas such as hydrogen (H2), deuterium (D2), helium (He) or argon (Ar) may be used for any or all of the layers. The carrier gas may be pre-mixed with the gas sources or flowed simultaneously with the gas source at the time of growth. The gas flow ratio is preferably [H2]/[SiH4]>5. For p++ growth (n-type substrate), Ge may be included in the doped layer. In this case, the gas flow ratio is preferably [H2]/([SiH4]+[GeH4])>5.
After deposition, the source and drain regions 16, 18 are patterned using lithographic masking and etching.
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In accordance with the present principles, employing a crystalline substrate to form the TFT channel results in higher TFT channel mobility and therefore allows sufficient TFT drive current at larger TFT channel lengths. The degradation of the TFT drive current due to large source/drain series resistance is lower at larger TFT channel lengths. As a result, the source drain series resistance is not as critical an issue if a crystalline substrate is used according to the present principles.
The process described employs low-temperature steps (e.g., less than 250° C.). These temperatures are compatible with low-cost substrates such as glass or plastic. CMOS foundry/processing is not necessary despite the use of crystalline substrate materials. Further, using the crystalline substrate enables higher resolution displays. For example, higher mobility is provided. This permits the use of pixels with smaller dimensions since the higher mobility permits sufficient drive current using TFTs with shorter channel widths (better resolution). In addition, higher mobility permits sufficient drive currents using TFTs with larger channel lengths thus reducing lithography costs. Furthermore, higher drive currents resulting from higher mobility reduce voltage requirements for driving the TFTs, which lowers power consumption.
Referring to
In block 102, a crystalline substrate is joined to an insulating substrate (e.g., a handle substrate), preferably using a wafer bonding technique. In one embodiment, the insulating layer is formed on a thick crystalline substrate, and a portion of the thick crystalline substrate is removed to form a thin crystalline layer for the crystalline substrate joined to the insulating substrate. Removing the portion of the thick substrate may include cleaving (e.g., spalling, smart cut, epitaxial layer lift-off, etc.) or etching.
In block 104, a doped layer is deposited on the crystalline substrate. In block 106, this may include depositing the doped layer by a plasma enhanced chemical vapor deposition process having a deposition temperature less than 250 degrees C. Alternately, a HWCVD process may be employed.
In block 110, the doped layer is patterned to form source and drain regions. In block 112, the crystalline substrate is patterned to form an active area such that a conductive channel is formed in the crystalline substrate between the source and drain regions. In block 114, a gate stack is formed between the source and drain regions. The gate stack may include a high dielectric constant (high-K) gate dielectric and a metal gate conductor.
In block 116, contacts are formed to the source and drain regions and the gate stack through a first passivation layer. In block 118, one or more metallization layers are formed to provide lines for connecting components and for forming the components themselves, for example, capacitor electrodes, pixel electrodes, etc. These components may be formed or partially formed during contact formation in block 116. In block 120, a transparent conductor is deposited and patterned on the insulating substrate to form pixel electrodes. In one embodiment, electroluminescent material is formed on the electrodes to form a light emitting diode pixel. The pixel electrodes may be employed in liquid crystal displays or other active matrix displays. The electrodes may be completed by forming a second electrode. Processing continues to complete the display device.
Having described preferred embodiments for crystalline thin-film transistors (which are intended to be illustrative and not limiting), it is noted that modifications and variations can be made by persons skilled in the art in light of the above teachings. It is therefore to be understood that changes may be made in the particular embodiments disclosed which are within the scope of the invention as outlined by the appended claims. Having thus described aspects of the invention, with the details and particularity required by the patent laws, what is claimed and desired protected by Letters Patent is set forth in the appended claims.
Claims
1. A thin film transistor, comprising:
- a crystalline substrate wafer bonded to an insulating substrate and patterned to form an active area such that a conductive channel is formed in the crystalline substrate;
- epitaxial crystalline source and drain regions formed on an upper surface of the crystalline substrate on opposing sides of the conductive channel;
- a gate stack formed between the source and drain regions; and
- contacts coupled to the source and drain regions and the gate stack and formed through a passivation layer.
2. The thin film transistor as recited in claim 1, wherein the insulating substrate includes glass or plastic.
3. The thin film transistor as recited in claim 1, wherein the conductive channel includes a width to length ratio of less than 25.
4. The thin film transistor as recited in claim 1, wherein the conductive channel includes a width to length ratio of less than 5.
5. The thin film transistor as recited in claim 1, wherein the insulating substrate includes a handle substrate employed during wafer bonding.
6. The thin film transistor as recited in claim 1, wherein the thin film transistor is configured to drive an organic light emitting diode pixel.
7. The thin film transistor as recited in claim 1, wherein the gate stack includes a high dielectric constant (high-K) gate dielectric and a metal gate conductor.
8. The thin film transistor as recited in claim 1, wherein the crystalline substrate is monocrystalline.
9. The thin film transistor as recited in claim 1, wherein the crystalline substrate.
Type: Application
Filed: Aug 14, 2013
Publication Date: Jul 10, 2014
Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION (Armonk, NY)
Inventors: BAHMAN HEKMATSHOARTABARI (WHITE PLAINS, NY), NING LI (WHITE PLAINS, NY), DEVENDRA K. SADANA (PLEASANTVILLE, NY), DAVOOD SHAHRJERDI (WHITE PLAINS, NY)
Application Number: 13/967,128
International Classification: H01L 29/786 (20060101);