Treating Electrolytic Or Nonelectrolytic Coating After It Is Formed Patents (Class 205/220)
  • Patent number: 6136175
    Abstract: The electronic component, specifically a SAW component with conductive structures disposed on a substrate is encapsulated for protection against environmental influences. The electrically conductive structures are sealed with a gas diffusion-constricting protective layer formed with an electrochemical or ion bombardment process.
    Type: Grant
    Filed: June 22, 1998
    Date of Patent: October 24, 2000
    Assignee: Siemens Aktiengesellschaft
    Inventors: Alois Stelzl, Hans Kruger, Wolfgang Pahl, Jurgen Machui
  • Patent number: 6132589
    Abstract: This invention relates to a treated copper foil, comprising: a copper foil with a layer of zinc oxide adhered to the base surface of at least on side of said copper foil, said layer of zinc oxide having a thickness of about 3 .ANG. to about 80 .ANG.; and a layer of a trivalent chromium oxide adhered to said layer of zinc oxide. In one embodiment, the foil has a layer of a silane coupling agent adhered to the layer of trivalent chromium oxide. The invention also relates to a process for applying the layer of zinc oxide and the layer of trivalent chromium oxide to the copper foil. The invention also relates to laminates comprising a dielectric substrate and the foregoing copper foil adhered to the substrate. In one embodiment, the dielectric substrate is comprised of an epoxy resin made with a curing agent that is other than an amine curing agent.
    Type: Grant
    Filed: September 10, 1998
    Date of Patent: October 17, 2000
    Assignee: GA-TEK Inc.
    Inventors: Thomas J. Ameen, Edward Czapor
  • Patent number: 6113772
    Abstract: According to the present invention there is provided a method for making lithographic printing plates or a printing cylinder including the steps of applying image-wise a solution of ions of an oleophilic metal with an ink jet on a hydrophilic metallic base and reducing said ions by electroplating in order to obtain an oleophilic metal image.
    Type: Grant
    Filed: February 22, 1999
    Date of Patent: September 5, 2000
    Assignee: Agfa-Gevaert, N.V.
    Inventor: Ludo Van Rompuy
  • Patent number: 6063141
    Abstract: A method for manufacturing a cathode for a molten carbonate fuel cell includes oxidation of a porous precursor electrode and contact with molten carbonate. Following assembly of a layered arrangement containing the precursor electrode, a matrix layer made of molten carbonate, and a porous anode, the precursor electrode is anodically oxidized with a preset curve for the current density, and doped by contact with molten carbonate.
    Type: Grant
    Filed: December 18, 1998
    Date of Patent: May 16, 2000
    Assignee: MTU Motoren-Und Turbinen-Union Friedrichshafen GmbH
    Inventors: Hartmut Wendt, Hans-Juergen Salge, Manfred Bischoff
  • Patent number: 6059953
    Abstract: A metal plate for electromagnetic heating is disclosed which includes a substrate comprising aluminum or aluminum alloys, an intermediate layer formed on at least a portion of one surface of the substrate and comprising zinc or zinc alloys and a conductive layer formed on the intermediate layer for serving as a heat generating body when eddy current induced by high-frequency magnetic flux flows therethrough. Methods of manufacturing a metal plate for electromagnetic heating and a metallic mold for electromagnetic heating are also disclosed.
    Type: Grant
    Filed: December 24, 1997
    Date of Patent: May 9, 2000
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Toshiyuki Hatta, Fumio Matsuyama, Masaya Nishi, Taichiro Nishikawa, Shuzo Nagai, Kenji Miyazaki, Shinji Inazawa
  • Patent number: 6039857
    Abstract: The present invention relates to a method for forming a polyoxide film on a doped polysilicon layer, which is suitable for use as an inter-polysilicon polyoxide film between a doped polysilicon floating gate and a doped polysilicon control gate. The method includes conducting an electrolytic reaction at a room, temperature such that a polyoxide layer is formed on a doped polysilicon layer acting as an anode. The polyoxide layer is preferably further subjected with a rapid thermal processing to improve its electrical characteristics.
    Type: Grant
    Filed: November 9, 1998
    Date of Patent: March 21, 2000
    Inventors: Ching-Fa Yeh, Jeng-Shu Liu
  • Patent number: 5989396
    Abstract: An electrode is disclosed having a coating on part of the electrode, e.g., a front face, comprising the oxides of tin, antimony, at least one platinum group metal and at least one valve metal. Another part of the electrode, such as a back face, has a coating comprising the oxides of at least one valve metal and at least one platinum group metal. The electrode can be generally plate-shaped and most desirably has at least one chamfered corner. The electrode is particularly useful in a cell wherein brine electrolyte is electrolyzed to prepare a disinfectant solution containing hypochlorite. The disinfectant solution can be especially serviceable, such as in maritime application, for treating water, e.g., freshwater as represented by desalinated water.
    Type: Grant
    Filed: April 1, 1998
    Date of Patent: November 23, 1999
    Assignee: ELTECH Systems Corporation
    Inventors: Albert R. Prasnikar, Richard C. Carlson, Richard J. Coin, Lynne M. Ernes, Thomas A. Mitchell, Catherine M. Lezan
  • Patent number: 5863410
    Abstract: An electrolytic process for producing copper foil having a low profile surface exhibiting a high peel strength when bonded to a polymeric substrate, which process comprises: (a) preparing an electrolyte comprising a copper sulfate-sulfuric acid solution, containing as addition agents, a low molecular weight water-soluble cellulose ether, a low molecular weight water-soluble polyalkylene glycol ether, a low molecular weight water-soluble polyethylene imine and a water-soluble sulfonated organic sulfur compound; (b) passing an electric current through the electrolyte from a primary anode to a cathode spaced from the primary anode in a first electrodeposition zone under first mass transfer conditions including a first current density to electrodeposit on the cathode a base copper foil having a fine-grained microstructure and a matte surface having micropeaks with a height not greater than about 150 microinches; (c) passing the base foil and electrolyte from the first electrodeposition zone to a second electrodep
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: January 26, 1999
    Assignee: Circuit Foil USA, Inc.
    Inventors: Charles B. Yates, Chintsai T. Cheng, Adam M. Wolski
  • Patent number: 5858198
    Abstract: A process for electroplating a metal clad substrate by coating the substrate with a coating of carbonaceous particles. The coating of particles is applied to the substrate from an aqueous dispersion and then the coating is saturated with an etchant for the metal cladding on the substrate to undercut the carbonaceous coating and facilitate its removal from areas where plating is undesired.
    Type: Grant
    Filed: September 8, 1997
    Date of Patent: January 12, 1999
    Assignee: Shipley Company, L.L.C.
    Inventors: Steven M. Florio, Jeffrey P. Burress, Carl J. Colangelo, Edward C. Couble, Mark J. Kapeckas
  • Patent number: 5827420
    Abstract: A gas mixture having a preselected concentration of nitric oxide, usable in inhalation therapy for example, is produced by controllably establishing the coulometric reduction of copper ions in a solution of nitric acid accompanied by purging the chamber in which the reduction reaction occurs with an inert gas. A free-standing, portable NO generator for use in the production of such a gas mixture is also disclosed.
    Type: Grant
    Filed: July 29, 1997
    Date of Patent: October 27, 1998
    Assignee: World Precision Instruments, Inc.
    Inventors: Shahram Z. Shirazi, Valentin Zhelyaskov
  • Patent number: 5810990
    Abstract: A method for continuously plating and finishing a part wherein a surface of the part is plated by a process that raises its temperature above atmospheric temperature and the part is then immediately force cooled to a temperature at which the plated surface may be properly machined. The part may be a cylinder block having at least one cylinder bore which is plated by flowing plating liquid across the surface of the cylinder bore and applying an electrical potential to cause plating material to be deposited. The cylinder block may be cooled by forced air cooling or liquid cooling to atmospheric temperature and then the plated cylinder bore may be immediately finish honed.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: September 22, 1998
    Assignee: Yamaha Hatsudoki Kabushiki Kaisha
    Inventor: Hirohiko Ikegaya
  • Patent number: 5811215
    Abstract: According to the present invention there is provided a method for preparing a hydrophilic surface of an aluminum lithographic base comprising the steps of roughening and anodizing a side of an aluminum foil and sealing said side of the aluminum foil with hot water within a temperature range from 70.degree. C. to 100.degree. C. for at least 5 seconds and rinsing said side of the aluminum foil with water characterized in that between said hot water treatment and said rinsing said side of the aluminum foil is treated with an aqueous silicate solution within a temperature range from 70.degree. C. to 100.degree. C. for at least 5 seconds.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: September 22, 1998
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Marc Van Damme, Joan Vermeersch
  • Patent number: 5755949
    Abstract: A plate-, foil- or web-shaped workpiece of aluminum or an alloy thereof is subjected, in an electrolyte bath, to an alternating current at a frequency of 0.1 to 25 Hz. During the AC treatment, an anodic potential is imposed on the workpiece, in the range of 0 to 5 Volts. The total charge input is 10 to 60 kC/m.sup.2. Prior to the electrochemical graining, the workpiece is mechanically grained. After the graining steps, an etching treatment as well as an anodical oxidation and, thereafter, a hydrophilization are performed.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: May 26, 1998
    Assignee: AGFA-Gevaert AG
    Inventor: Martin Philip Amor
  • Patent number: 5738776
    Abstract: A process for electroplating a metal clad substrate by coating the substrate with a coating of carbonaceous particles. The coating of particles is applied to the substrate from an aqueous dispersion and then the coating is saturated with an etchant for the metal cladding on the substrate to undercut the carbonaceous coating and facilitate its removal from areas where plating is undesired.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: April 14, 1998
    Assignee: Shipley Company, L.L.C.
    Inventors: Steven M. Florio, Jeffrey P. Burress, Carl J. Colangelo, Edward C. Couble, Mark J. Kapeckas
  • Patent number: 5714053
    Abstract: A method for making high power electrochemical capacitors (20) provides for depositing an electrically conducting polymer (24) onto a metal substrate (22). The electrically conducting polymer is initially grown in the presence of a soft anion, i.e., an anion having a high degree of polarizability. Subsequently, the polymer is treated with a relatively hard anion which at least partially replaces the soft anion in the polymer. The result is an electrochemical charge storage device which has enhanced electrochemical properties.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: February 3, 1998
    Assignee: Motorola, Inc.
    Inventor: Jason N. Howard
  • Patent number: 5706999
    Abstract: A composite material of silicon carbide particles in an aluminum matrix is base coated with a layer of a nickel-boron alloy by an electroless process. The base-coated composite material is heat treated at a temperature of about 450.degree. C. to interdiffuse the base coating with the composite material. A nickel or gold top layer is electrolytically deposited over the base coat on the heat-treated composite material.
    Type: Grant
    Filed: November 28, 1995
    Date of Patent: January 13, 1998
    Assignee: Hughes Electronics
    Inventors: John K. Lim, Joseph S. Russo
  • Patent number: 5683567
    Abstract: The present invention relates to an electrolytic electrode comprising a core material made of a valve metal, a dense electrically conductive tin oxide layer formed on the core material, an .alpha.-lead dioxide layer formed on the tin oxide layer, and a .beta.-lead dioxide layer formed on the .alpha.-lead dioxide layer. The present invention also relates to a method for preparing the electrolytic electrode.
    Type: Grant
    Filed: January 18, 1995
    Date of Patent: November 4, 1997
    Assignee: Permelec Electrode Ltd.
    Inventors: Takayuki Shimamune, Yasuo Nakajima
  • Patent number: 5660707
    Abstract: A post plating or post coating method for improving formability and weldability properties in sheet steel product having a protective zinc or zinc alloy layer formed on at least one surface thereof. The steps of the method comprise immersing the sheet steel product into a bath containing at least zinc to apply the protective layer, removing the sheet steel product from the bath, the sheet steel product having a protective zinc or zinc alloy layer formed on at least one surface thereof, and applying an alkaline solution to the protective layer to form a zinc oxide layer thereon, the alkaline solution being applied at a location outside the bath.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: August 26, 1997
    Assignee: Bethlehem Steel Corporation
    Inventors: C. Ramadeva Shastry, Stavros G. Fountoulakis, Elmer J. Wendell
  • Patent number: 5612146
    Abstract: A soft-magnetic multilayer thin film produced by electroplating, wherein an anode-dissolution process is effected by intermittently applying a reverse d.c. bias current with respect to the plating-forward current. Involving the anode-dissolution process allows the formation of a re-dissolution effect layer differing in crystal structure from the plated film layer. A soft-magnetic multilayer thin film characterized by having a multilayer film structure which comprises a plated layer and a re-dissolution effect layer laminated to each other and which the plated layer is at least magnetically isolated. Further, a method of manufacturing a soft-magnetic multilayer thin film having a multilayer film structure magnetically isolated only through plating, which is offered by introducing the anode-dissolution process.
    Type: Grant
    Filed: March 5, 1996
    Date of Patent: March 18, 1997
    Assignee: Matshushita Electric Industrial Co., Ltd.
    Inventors: Nobuyuki Komura, Yuuji Omata
  • Patent number: 5578175
    Abstract: A process for manufacturing an iridium and palladium oxides-coated titanium electrode comprises preparing a titanium substrate having a surface, applying iridium and palladium to be formed on the surface of the titanium substrate, and heat-treating the iridium and palladium oxides-applied titanium substrate to obtain an iridium and palladium oxides-coated titanium electrode. This invention provides a process for obtaining a coated titanium electrode having therein a good adhesion between the coating material and the titanium electrode, and having an excellent electrochemical stability and a superior catalytic activity in an acidic environment.
    Type: Grant
    Filed: August 16, 1994
    Date of Patent: November 26, 1996
    Assignee: National Science Council
    Inventors: Kwang-Lung Lin, Ju-Tung Lee, Yuan-Po Lee
  • Patent number: 5558759
    Abstract: A finishing process for a base metal substrate comprising the steps of polishing the surface of the base metal substrate, electroplating the metal substrate with copper, electroplating a layer of metal over the copper plate, and depositing a substantially moisture impervious coating on the metal layer.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: September 24, 1996
    Assignee: Sargent Manufacturing Company
    Inventor: Roger Pudem
  • Patent number: 5556532
    Abstract: Black- or brown-oxidised copper laminates that are to be integrated into an electrical multilayer laminate in a subsequent process step are electrochemically reduced in order to avoid the formation of so-called "pink rings". To that end, they are connected as the cathode of an electrolysis in a suitable electrolyte. The atomic hydrogen produced in statu nascendi during the electrolysis completely or partially reduces the copper oxide layer on the metallic regions of the copper laminates, whereby the resistance of the surfaces of the metallic regions of the copper laminates to subsequent acid attack is considerably improved. The electrochemical reduction may optionally be coupled with a chemical reduction or precede a chemical reduction.
    Type: Grant
    Filed: November 2, 1994
    Date of Patent: September 17, 1996
    Assignee: Hans Hollmuller Maschinenbau GmbH & Co.
    Inventor: Joachim Markowski
  • Patent number: 5458863
    Abstract: The invention is a method, involving temperatures between room temperature and 100.degree. C., for coating a metal substrate with hydroxyapatite. The intended application is coating porous metal coats of orthopedic and endosseous implants such that the underlying metal is not sintered and the hydroxyapatite coating has chemical and physical properties that are close to biological apatite. The method involves: (i) cleaning the metal substrate, (ii) coating the metal substrate with brushite by electrodeposition at room temperature, (iii) dislodging bubbles periodically during brushite electrodeposition, and (iv) converting the brushite coating to hydroxyapatite at a temperature between room temperature and 100.degree. C.
    Type: Grant
    Filed: November 25, 1994
    Date of Patent: October 17, 1995
    Inventor: Robert D. Klassen
  • Patent number: 5456816
    Abstract: A method for manufacturing a nickel alloy electroplated cold-rolled steel sheet excellent in press-formability and phosphating-treatability, which comprises the steps of: (a) cold-rolling a hot-rolled steel sheet at a reduction ratio of from 60 to 85% to prepare a cold-rolled steel sheet consisting essentially of: up to 0.06 wt. % carbon, up to 0.5 wt. % silicon, up to 2.5 wt. % manganese, up to 0.1 wt. % phosphorus, up to 0.025 wt. % sulfur, up to 0.10 wt. % soluble aluminum, up to 0.05 wt. % nitrogen, and the balance being iron and incidental impurities; then, (b) subjecting the cold-rolled steel sheet to a continuous annealing treatment which comprises heating the cold-rolled steel sheet to a recrystallization temperature and then slowly cooling same; then, (c) forming, on at least one surface of the annealed cold-rolled steel sheet, a nickel alloy electroplating layer having a plating weight of from 5 to 60 mg/m.sup.
    Type: Grant
    Filed: April 28, 1994
    Date of Patent: October 10, 1995
    Assignee: NKK Corporation
    Inventors: Toyofumi Watanabe, Akihiko Furuta, Tadashi Ono, Yoshinori Yomura, Shuichi Iwado
  • Patent number: 5422228
    Abstract: A method of producing a thin film multi-layered substrate involving the steps of subjecting a copper wiring formed on a substrate to chromate treatment with an aqueous solution containing potassium bichromate or sodium bichromate as a principal component and containing chromic anhydride blended therewith, forming an interlevel insulating film consisting of photosensitive polyimide on the copper wiring, and exposing and developing the photosensitive polyimide film to form a pattern. A miniature pattern can be formed at a high speed and with high production yield.
    Type: Grant
    Filed: August 3, 1993
    Date of Patent: June 6, 1995
    Assignee: Fujitsu Limited
    Inventor: Kazuaki Satoh
  • Patent number: 5413694
    Abstract: A method of improving the electromagnetic (EM) shielding performance of a mposite material is provided. The composite material has conductive and semi-conductive filler particles suspended in a non-conductive resin. The filler particles can be up to 40 weight percent of the composite material. The composite material is electroplated with a conductive material onto a portion of its surface to improve the electrical connection between the conductive material and a portion of the filler particles. EM shielding performance can be further enhanced by injecting an exponentially decaying electromagnetic pulse through the composite material that has been electroplated.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: May 9, 1995
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: David S. Dixon, Michael D. Obara, James V. Masi, William G. Bradley
  • Patent number: 5372701
    Abstract: The invention relates to an improved process and apparatus for electroplating an object and removing the excess electroplating solution from the electroplating object. The improvement comprises performing the electroplating process utilizing an apparatus and in a manner which eliminates all waste rinse solution and which provides substantially complete recovery of the chemicals utilized, but not used up, in the plating process.
    Type: Grant
    Filed: December 3, 1991
    Date of Patent: December 13, 1994
    Inventors: Louis J. Gerdon, James R. Worth
  • Patent number: 5356527
    Abstract: The present invention relates to a technique for improving the tarnish and oxidation resistance of copper and copper based alloy materials. A chromium-zinc coating is electrolytically applied to copper or copper based alloy surface using a caustic electrolyte solution. The coated material is then rinsed in an aqueous solution containing a phosphate salt of alkali metals or alkaline earth metals, or a borate salt of alkali metals or alkaline earth metals. The pH of the rinse solution is maintained from about 5 to about 12 and preferably from about 7 to about 10.
    Type: Grant
    Filed: August 9, 1991
    Date of Patent: October 18, 1994
    Assignee: Olin Corporation
    Inventors: Chung-Yao Chao, Lifun Lin
  • Patent number: 5202013
    Abstract: A process for coloring a metal surface and colored metal products thus produced. The process involves forming a layer of a metal oxide on a surface of the metal to be colored and then bringing about permanent plastic deformation of the surface. If the oxide layer is of a suitable thickness (e.g. 500.ANG.-1 .mu.m) and the deformation is sufficiently high (preferably producing a reduction in thickness of the metal article by 30% or more), the resulting metal article exhibits an attractive color (usually a dichroic pastel color). The article can then be fabricated into finished articles, e.g. beverage cans, in the usual way.
    Type: Grant
    Filed: October 15, 1991
    Date of Patent: April 13, 1993
    Assignee: Alcan International Limited
    Inventors: Bryn Chamberlain, Harry Sang, Dan Fern, Prasad Apte, Lorne D. Kenny
  • Patent number: 5110710
    Abstract: Disclosed is a light-sensitive lithographic printing plate which comprises an aluminum or aluminum alloy support having been pretreated and a light-sensitive layer provided thereon, wherein the surface of the support adjacent to the light-sensitive layer is treated by use of an aqueous solution containing at least one selected from the group consisting of nitric acid, nitrate, nitrous acid and nitrite. According to this invention, lithographic printing plates which are free from stain due to residual light-sensitive layer, excellent in developability, good in water retention at image area and excellent in press life, can be obtained.
    Type: Grant
    Filed: May 15, 1991
    Date of Patent: May 5, 1992
    Assignee: Konica Corporation
    Inventors: Yasuji Tomita, Hideyuki Nakai, Kiyoshi Goto
  • Patent number: 5102508
    Abstract: A method is described for producing colored surfaces on parts of aluminum or aluminum alloy which is characterized by the following process steps:1. The parts are pre-treated by degreasing or cleaning,2. The parts are electrolytically anodically/alkalinely brightened,3. The parts are electrolytically anodized with the use of direct current,4. The parts are electrolytically and/or organically colored, and5. The oxide layer on the parts is compacted.
    Type: Grant
    Filed: May 23, 1990
    Date of Patent: April 7, 1992
    Assignee: Gebr. Happich GmbH
    Inventors: Klaus D. Bartkowski, Peter Venn
  • Patent number: 5102507
    Abstract: A process is disclosed for treating the surface of a valve metal such as aluminum to form a two layer protective coating thereon using an anodizing bath consisting essentially of an aqueous solution having a concentration ranging from about 0.001 molar to a saturated solution of a phosphorus-containing compound selected from the class consisting of a phosphorus acid ester and salts thereof. A non-porous barrier valve metal oxide layer is formed on a surface of the valve metal, and a functionalized layer comprised of a phosphate ester is formed on the oxide layer.
    Type: Grant
    Filed: October 16, 1989
    Date of Patent: April 7, 1992
    Assignee: Aluminum Company of America
    Inventors: Larry F. Wieserman, Karl Wefers, Gary A. Nitowski