Products And Compositions Patents (Class 208/14)
  • Patent number: 7833407
    Abstract: A high solvency dispersive power (HSDP) crude oil is added to a blend of incompatible oils to proactively address the potential for fouling heat exchange equipment. The HSDP component dissolves asphaltene precipitates and maintains suspension of inorganic particulates before coking affects heat exchange surfaces. An HSDP oil is also flushed through heat exchange equipment to remove any deposits and/or precipitates on a regular maintenance schedule before coking can affect heat exchange surfaces.
    Type: Grant
    Filed: August 21, 2006
    Date of Patent: November 16, 2010
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Glen B. Brons, Chris A. Wright, George A. Lutz, Daniel P. Leta
  • Patent number: 7828958
    Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. The crude product may include at least one of the catalysts.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: November 9, 2010
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, Stanley Nemec Milam
  • Publication number: 20100276334
    Abstract: The invention concerns a process for converting a stream of natural or associated gas into liquid fractions, comprising: a) a step for converting said stream of gas into a synthesis gas SG; b) a step FT for Fischer-Tropsch synthesis to convert the SG into liquid fractions; c) a step for fractionating the effluents from the Fischer-Tropsch synthesis into at least one relatively heavy fraction comprising waxes with a boiling point of 565° C. or more and at least one relatively light fraction; d) a step HCKI for isomerization hydrocracking of the relatively heavy fraction, in which at least 75% by weight of the fraction of the feed with a boiling point of more than 565° C. is converted into compounds boiling below 565° C.; e) at least one step for mixing at least the effluents from step HCKI (step d)), the light fraction from step c) and a crude oil P, to thereby produce an oil P*.
    Type: Application
    Filed: November 12, 2007
    Publication date: November 4, 2010
    Applicant: IFP
    Inventors: Eric Lenglet, Patrick Chaumette
  • Publication number: 20100276335
    Abstract: In some embodiments, the invention is a method of removing sulfur from a hydrocarbon feed using the steps of dissolving metallic sodium in a first solvent, combining the sodium/first solvent solution with a sulfur-free alkane or cycloalkane second solvent, vaporizing the first solvent from sodium/first solvent/second solvent combination to transfer the dissolved metallic sodium into the second solvent, and then combine the resultant liquid with a liquid hydrocarbon feed containing an organosulfur species. The resulting stream is combined with a hydrogen donor. The combination is heated and pressurized to form a liquid hydrocarbon product containing sodium sulfide. The liquid hydrocarbon product containing sodium sulfide is then cooled, and the sodium sulfide is extracted. The extracted sodium sulfide is then processed in a sodium sulfur cell to regenerate the sodium and recycle it to the feed.
    Type: Application
    Filed: February 25, 2008
    Publication date: November 4, 2010
    Applicant: Trans Ionics Corporation
    Inventor: Robert C. Schucker
  • Patent number: 7819930
    Abstract: Briefly described, embodiments of this disclosure include methods of recovering bio-oil products, fuels, diesel fuels, and the like are disclosed.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: October 26, 2010
    Assignee: University of Georgia Research Foundation, Inc.
    Inventors: Thomas Adams, Manuel Garcia, Dan Geller, John W. Goodrum, Joshua T. Pendergrass
  • Publication number: 20100264060
    Abstract: A process for removing color contaminants and non-color contaminants from oil comprising the step of passing an oil feed through a permeable transition metal oxide membrane, wherein said oil that has passed through said transition metal oxide membrane has less color contaminants and non-color contaminants relative to said oil feed.
    Type: Application
    Filed: August 23, 2007
    Publication date: October 21, 2010
    Applicant: Hyflux LTD
    Inventor: Yi Tan
  • Patent number: 7811445
    Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. The crude product may include, hydrocarbon gas that is non-condensable at 25° C. and 0.101 MPa, naphtha, kerosene, residue, or mixtures thereof.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: October 12, 2010
    Assignee: Shell Oil Company
    Inventors: Scott Lee Wellington, Stanley Nemec Milam
  • Patent number: 7799206
    Abstract: A method is disclosed for producing a stable pipelineable blend from a heavy residue of a catalytic hydroconversion process operating at high (60-80%) conversion rate by blending the heavy residue with a virgin bitumen, such as a bitumen produced from the Peace River or Cold Lake oil sand deposits in Alberta, Canada, and/or with a Wabasca virgin heavy crude oil wherein the 524° C.+ Fraction of the blend is controlled such that: 1) The blend comprises less than 40 vol % of heavy 524° C.+ components, i.e. components which boil at atmospheric pressure at a temperature above about 524 Degrees Celsius; and 2) The 524° C.+ fraction in the blend comprises less than about 80 vol % of heavy residue originating from the hydroconversion process.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: September 21, 2010
    Assignee: Shell Oil Company
    Inventors: Franciscus Gondulfus Antonius Van Den Berg, Scott John Fryer, Marshall Glenn Letts, Michael Robert Margerum, William James Power, Oscar Kui Yin Sy, Larry Vadori
  • Publication number: 20100200470
    Abstract: Compositions and methods are provided for separating bitumen from oil sands in an efficient and environmentally acceptable manner, and for recovering residual bitumen from existing tailings ponds.
    Type: Application
    Filed: April 23, 2010
    Publication date: August 12, 2010
    Applicant: Vary Petrochem, LLC
    Inventors: Robert C. Yeggy, Vito Altavilla
  • Publication number: 20100200469
    Abstract: Compositions and methods are provided for separating bitumen from oil sands in an efficient and environmentally acceptable manner, and for recovering residual bitumen from existing tailings ponds.
    Type: Application
    Filed: April 23, 2010
    Publication date: August 12, 2010
    Applicant: Vary Petrochem, LLC
    Inventors: Robert C. Yeggy, Vito Altavilla
  • Patent number: 7763160
    Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The one or more catalysts include a transition metal sulfide catalyst. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed.
    Type: Grant
    Filed: December 16, 2004
    Date of Patent: July 27, 2010
    Inventors: Scott Lee Wellington, Stanley Nemec Milam
  • Publication number: 20100181228
    Abstract: A process is provided for producing petroleum coke that is high in strength and sufficiently small in thermal expansion coefficient and sufficiently suppressed from puffing. The process includes coking a feedstock containing a first heavy oil having a sulfur content of 1.0 percent by mass or less, a nitrogen content of 0.5 percent by mass or less, and an aromatic index of 0.1 or greater, produced by hydrodesulfurizing a heavy oil with a sulfur content of 1 percent by mass or more under conditions (1) where the total pressure is 10 MPa or greater and less than 16 MPa and the hydrogen partial pressure is 5 MPa or greater and 16 MPa or less or conditions (2) where the total pressure is 20 MPa or greater and 25 MPa or less and the hydrogen partial pressure is greater than 20 MPa and 25 MPa or less, and a second heavy oil with an aromatic index of 0.3 or greater and an initial boiling point of 150° C. or higher.
    Type: Application
    Filed: April 15, 2008
    Publication date: July 22, 2010
    Applicant: NIPPON PETROLEUM REFINING CO., LTD.
    Inventors: Tamotsu Tano, Takashi Oyama, Kazuhisa Nakanishi, Toshiyuki Oda, Keiji Higashi
  • Patent number: 7741526
    Abstract: A feedstock containing at least 1 wt % butenes, at least 1 wt % pentenes, at least 1 wt % hexenes, at least 10 wppm C4 dienes, at least 10 wppm C5 dienes, and optionally at least 10 wppm C6 dienes can be selectively hydrogenated over a catalyst (e.g., a noble metal) to form a stream containing 100 wppm to 4000 wppm total dienes. The hydrogenated stream, and an olefinic recycle stream having less than 10 wt. % C1+ moieties, can be contacted with a molecular sieve catalyst, e.g., at a recycle to feed ratio between 0.1 and 3.0, at a WHSV of at least 1.0 based on olefin in the feed, and at a reactor ?T no greater than 40° F. (22° C.), thus forming a reaction product that can then be separated into a distillate, e.g., having from 1 wt % to 30 wt % non-normal C9 olefins, and the aforementioned olefinic recycle stream.
    Type: Grant
    Filed: July 19, 2006
    Date of Patent: June 22, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Keith H. Kuechler, Stephen H. Brown, Marc P. Puttemans, Steven E. Silverberg, An A. Verberckmoes
  • Publication number: 20100147739
    Abstract: High molecular weight naphthenic tetra-acids are added to a base crude oil to prevent and/or reduce fouling of crude oil refinery equipment. The method includes adding an effective amount of a high molecular weight naphthenic tetra-acid to the base crude oil to form a crude oil mixture and feeding the crude oil mixture to a crude oil refinery component. Particularly, the high molecular weight naphthenic tetra-acids include ARN acids.
    Type: Application
    Filed: December 4, 2009
    Publication date: June 17, 2010
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Steven W. LEVINE, Glen B. Brons, George A. Lutz, Daniel P. Leta, Clifford C. Walters
  • Patent number: 7737311
    Abstract: Use of a Fischer-Tropsch derived fuel in a fuel composition is disclosed, for the purpose of reducing catalyst degradation in a catalytically driven or catalyst containing system which is running on, or is to be run on, the composition or its products, wherein the Fischer-Tropsch derived fuel is used to reduce the level of silicon in the fuel composition, such as by reducing the concentration of silicon-containing antifoaming additive(s) in the fuel composition. It may also be used to reduce loss of efficiency of fuel atomization and/or combustion, and/or to reduce build up of silicon deposits, in a fuel consuming system which is running on, or is to be run on, the fuel composition.
    Type: Grant
    Filed: September 3, 2004
    Date of Patent: June 15, 2010
    Assignee: Shell Oil Company
    Inventors: Roger Francis Cracknell, Trevor Stephenson
  • Publication number: 20100139167
    Abstract: Embodiments disclosed herein provide hydrocarbon additives and methods of making and using the same. The additives are suitable for use in conjunction with gasifiers, furnaces, or other high-temperature vessels. The additives may be part of an input stream to a reaction vessel of a hydrocarbon gasifier. The additives may include materials that at least partially reduce the infiltration of slag into the refractory material.
    Type: Application
    Filed: December 8, 2008
    Publication date: June 10, 2010
    Applicant: General Electric Company
    Inventors: Peter Joel Meschter, Paul Stephen Dimascio
  • Publication number: 20100133143
    Abstract: Methods for treating a subsurface formation and compositions produced therefrom are described herein. At least one method for producing hydrocarbons from a subsurface formation includes providing heat to the subsurface formation using an in situ heat treatment process. One or more formation particles may be formed during heating of the subsurface formation. Fluid that includes hydrocarbons and the formation particles may be produced from the subsurface formation. The formation particles in the produced fluid may include cenospheres and have an average particle size of at least 0.5 micrometers.
    Type: Application
    Filed: September 2, 2009
    Publication date: June 3, 2010
    Applicant: Shell Oil Company
    Inventors: Augustinus Wilhelmus Maria Roes, Vijay Nair, Erwin Hunh Munsterman, Petrus Franciscus Van Bergen, Franciscus Gondulfus Antonius Van Den Berg
  • Publication number: 20100096295
    Abstract: The present invention provides methods and systems for obtaining oil or a combustible gas from oil shale or coal, by subjecting oil shale or coal to microwave radiation for a time sufficient to at least partially decompose or extract oil, gas, or other carbon-containing materials from the oil shale and coal. The disclosed processes and systems use microwave radiation comprising at least one frequency component in the range of from about 4 GHz to about 18 GHz.
    Type: Application
    Filed: October 2, 2009
    Publication date: April 22, 2010
    Applicant: GLOBAL RESOURCE CORPORATION
    Inventors: Frank G Pringle, Carl Everleigh, Julian Forthe
  • Publication number: 20100089794
    Abstract: Methods for producing a crude product, methods for preparing a diluted hydrocarbon composition, crude products, diluents and uses of such crude products and diluents are described. The method includes contacting of a hydrocarbon feed with one or more catalysts, where at least one of the catalyst includes one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Columns 6 of the Periodic Table. The method produces a crude product having a MCR content of at most 90% of MCR content of the hydrocarbon feed and having total content of UV aromatics in a VGO fraction of the crude product which is greater than or equal to the total UV aromatics content of the hydrocarbon feed VGO fraction of the hydrocarbon feed. The crude product may be separated into two or more portions, which portions may be useful as a diluent.
    Type: Application
    Filed: April 10, 2009
    Publication date: April 15, 2010
    Inventors: Opinder Kishan BHAN, Scott Lee WELLINGTON
  • Patent number: 7695610
    Abstract: The invention relates to oil refining, more particularly to a composition of a light fuel oil for use in medium-speed diesel engines of marine power units. The inventive light fuel oil comprises, in % by wt.: black oil—(4-10), tar—(2-10), light catalytic cracking gas oil—(10-30), heavy catalytic cracking gas oil—(5-10), a straight-run diesel fuel—(8-10), a viscosity breaking residuum of a heavy oil fraction—the rest. The selected component ratio will enable to improve the fuel stability in transportation and storage, expand the range of available fuels and increase the production volumes of quality fuels, while rationally using poor-quality products readily available at refineries.
    Type: Grant
    Filed: July 13, 2006
    Date of Patent: April 13, 2010
    Assignee: Oiltreid Limited Liabilities Company
    Inventors: Valentin Filippovich Bolshakov, Aleksandr Valentinovich Bolshakov, Tamara Nikitovna Mitusova, Sergey Olegovich Shinkov, Tatiana Felikosovna Ovchinnikova
  • Publication number: 20100078354
    Abstract: We provide a base stock comprising hydrocarbons with consecutive numbers of carbon atoms, wherein the base stock has a boiling range from 388 to 538° C., a VI from 105 to less than 120, and a Noack volatility from 6.6 to 11.5 wt % or a CCS VIS at ?25° C. from 2500 to 4500 mPa·s. We also provide a base stock slate comprising the base stock and an additional base stock having an additional boiling range from 371 to 496° C., and other properties.
    Type: Application
    Filed: June 10, 2009
    Publication date: April 1, 2010
    Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Steve K. Lee, Ryan J. Schexnaydre, Susan M. Abernathy
  • Publication number: 20100078355
    Abstract: We provide a process to manufacture a base stock, comprising hydrocracking, separating, and dewaxing, wherein the base stock has a ratio of Noack volatility to CCS VIS at ?25° C. multiplied by 100 from 0.15 to 0.40. We also provide a base stock made by a process, and a base oil manufacturing plant that produces the base stock.
    Type: Application
    Filed: June 10, 2009
    Publication date: April 1, 2010
    Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Steve K. Lee, Ryan J. Schexnaydre
  • Publication number: 20100078353
    Abstract: A process to manufacture a base oil, comprising selecting an original base oil having an original VI, an original volatility, and an original CCS VIS; and removing a lower boiling fraction, whereby the base oil is made having a kinematic viscosity at 100° C. from 4.2 to 4.6 mm2/s, a VI that is at least 4 higher than the original VI, a volatility that is at least 3 wt % lower than the original volatility, and a CCS VIS that is within 200 mPa·s of the original CCS VIS. A process to manufacture a base oil, comprising selecting an original base oil and removing a lower boiling fraction from the original base oil, whereby the base oil has a ratio of a Noack Volatility to a CCS VIS at ?25° C. multiplied by 100 from 0.80 to 1.55. Also a base oil, made by the processes disclosed herein.
    Type: Application
    Filed: June 10, 2009
    Publication date: April 1, 2010
    Inventors: John M. Rosenbaum, Brent K. Lok, Kathy A. Helling, Ryan J. Schexnaydre, Scott C. Deskin, Susan M. Abernathy
  • Patent number: 7682499
    Abstract: The invention provides for a mineral insulating oil having a naphthenic base oil and a paraffinic base oil wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a mineral insulating oil having a naphthenic base oil, a paraffinic base oil, and an antioxidant agent wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a process for producing a mineral insulating oil including contacting a naphthenic base oil and a paraffinic base oil wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1. The invention also provides for a process for producing a mineral insulating oil including contacting a naphthenic base oil, a paraffinic base oil, and an antioxidant agent wherein the naphthenic base oil includes a ratio of total sulfur to basic nitrogen of less than about 80:1.
    Type: Grant
    Filed: August 24, 2006
    Date of Patent: March 23, 2010
    Assignee: Shell Oil Company
    Inventors: Steven Allen Holmes, Ronald Wayne Dever
  • Publication number: 20100051507
    Abstract: Hydrocarbon-soluble molybdenum catalyst precursors include a plurality of molybdenum cations that are each bonded with a plurality of organic anions to form an oil soluble molybdenum salt. A portion of the molybdenum atoms are in the 3+ oxidation state such that the plurality of molybdenum atoms has an average oxidation state of less than 4+, e.g., less than about 3.8+, especially less than about 3.5+. The catalyst precursors can form a hydroprocessing molybdenum sulfide catalyst in heavy oil feedstocks. The oil soluble molybdenum salts are manufactured in the presence of a reducing agent, such as hydrogen gas, to obtain the molybdenum in the desired oxidation state. Preferably the reaction is performed with hydrogen or an organic reducing agent and at a temperature such that the molybdenum atoms are reduced to eliminate substantially all molybdenum oxide species.
    Type: Application
    Filed: November 11, 2009
    Publication date: March 4, 2010
    Applicant: HEADWATERS TECHNOLOGY INNOVATION, LLC
    Inventors: ZHIHUA WU, Zhenhua Zhou, Bing Zhou
  • Publication number: 20100032340
    Abstract: A method of deresinating a crude oil comprises contacting the crude oil with a carbon dioxide containing fluid, the crude oil having an initial API gravity and comprising an oil phase, resins, and asphaltenes, and wherein the carbon dioxide containing fluid enters the oil phase of the crude oil In a manner such that the resins and asphaltenes precipitate out of the crude oil such that the final API gravity of the crude oil is higher than the initial API gravity of the crude oil.
    Type: Application
    Filed: October 16, 2009
    Publication date: February 11, 2010
    Inventors: Nael Naguib Zaki, Peter Kelley Kilpatrick, Ruben Guillermo Carbonell
  • Publication number: 20100031572
    Abstract: A method of increasing the hydrogen/carbon monoxide (H2/CO) ratio in a syngas stream derived from a carbonaceous fuel including coal, brown coal, peat, and heavy residual oil fractions, preferably coal. The fuel-derived syngas stream is divided into at least two sub-streams, one of which undergoes a catalytic water shift conversion reaction. The so-obtained converted sub-stream is combined with the non-converted sub-stream(s) to form a second syngas stream with an increased H2/CO ratio. The method of the present invention can provide a syngas with a H2/CO ratio more suitable for efficient hydrocarbon synthesis carried out on a given catalyst, such as in one or more Fischer-Tropsch reactors, as well as being able to accommodate variation in the H2/CO ratio of syngas formed from different qualities of feedstock fuels.
    Type: Application
    Filed: December 29, 2005
    Publication date: February 11, 2010
    Inventors: Joachim Ansorge, Scott Bilton, Hendrik Jan Van Der Ploeg, Arold Marcel Albert Routier, Cornelis Jacobus Smit
  • Publication number: 20100025289
    Abstract: A middle distillate, comprising hydrocarbons having a boiling range between 150° C. and 350° C., a NMR branching index greater than 60, and a CH3/CH2 hydrogen ratio greater than 2.6. Also, there is provided the middle distillate made by a process compressing alkylating an isoparaffin with an olefin under alkylation conditions over an unsupported ionic liquid catalyst, and providing an amount of halide containing additive to the alkylating step to achieve the NMR branching index and the CH3/CH2 hydrogen ratio.
    Type: Application
    Filed: July 31, 2008
    Publication date: February 4, 2010
    Inventors: Sven Ivar Hommeltoft, Stephen J. Miller, Ajit Pradhan, Susan M. Abernathy
  • Publication number: 20100025290
    Abstract: The invention relates to dispersions comprising I) at least one polymer that is effective for mineral oils as a cold extrusion improver and is soluble in oil, II) at least one organic solvent that cannot be mixed with water, III) water, IV) at least one alkanolamine salt of a polycyclic carboxylic acid as a dispersing agent, and V) possibly at least one organic solvent that can be mixed with water.
    Type: Application
    Filed: June 28, 2007
    Publication date: February 4, 2010
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Michael Feustel, Matthias Krull, Christoph Kayser, Mario Loew
  • Publication number: 20090301929
    Abstract: The present invention relates to a catalyst composition for the reaction of hydrocarbons comprising a zeolite with has a faujasite structure and a fibrous zeolite which comprises essentially non-crossing one-dimensional channels. Further, the catalyst composition comprises in a preferred embodiment a metal component selected from metals of the group VIB and VIII of the periodic table of elements and their compounds. The invention relates further to a process for the synthesis of such a catalyst composition and to a process for hydrocracking hydrocarbon feedstocks by using said catalyst composition.
    Type: Application
    Filed: October 26, 2006
    Publication date: December 10, 2009
    Inventors: Götz Burgfels, Stephan Wellsch, Josef Schönlinner, Friedrich Schmidt, Volker Kurth, Vebjorn Knut Grande, Jorunn Steinsland Rosvoll, Per Aksel Skjølsvik
  • Publication number: 20090268375
    Abstract: The present invention provides a raw coke having such a structure that the graphitized product resulting from graphitization of the raw coke at a temperature of 2800° C. under an inactive gas atmosphere will have ratios of the crystallite size to the lattice constant of 360 or less in the (002) plane and 1500 or less in the (110) plane, as a raw coke providing active carbon produced by alkali-activating the raw coke, which is reduced in remaining alkali content and can simplify washing operation because washing liquid can easily pass through the activated carbon, or as a raw coke for the production of needle coke.
    Type: Application
    Filed: December 27, 2006
    Publication date: October 29, 2009
    Applicants: NIPPON OIL CORPORATION, NIPPON PETROLEUM REFINING COMPANY, LIMITED
    Inventors: Takashi Oyama, Kazuhisa Nakanishi, Tamotsu Tano, Keiji Higashi, Ippei Fujinaga, Hiromitsu Hashisaka, Toshitaka Fujii, Takashi Noro, Akio Sakamoto, Kiwamu Takeshita, Keizou Ikai, Masaki Fujii, Hideki Ono
  • Publication number: 20090255849
    Abstract: Mercaptans and/or hydrogen sulfide (H2S) in hydrocarbons, naphthas, gasolines, and the like may be scavenged therefrom by being brought into intimate contact with a mercaptan scavenger formulation containing at least one disubstituted azodicarboxylate of the formula R1OOCN?NCOOR2, where R1 and R2 are independently alkyl groups, alkenyl groups and aromatic groups having from 1 to 18 carbon atoms. These scavengers remove mercaptans and/or H2S from hydrocarbons faster than many conventional mercaptan scavengers. An effective scavenging amount of disubstituted azodicarboxylate in the hydrocarbon fluid ranges from about 5 to about 20 parts by weight based on 1 part as sulfur of mercaptan and/or H2S.
    Type: Application
    Filed: April 8, 2009
    Publication date: October 15, 2009
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Jianzhong Yang, Joseph J. Arensdorf, Melanie V. Baker
  • Publication number: 20090255850
    Abstract: A catalyst and a method of preparation of said catalyst is described herein. The catalyst includes one or more metals from Columns 6-10 of the Periodic Table and/or one or more compounds of one or more metals from Columns 6-10 of the Periodic Table, a pore size distribution with a median pore diameter ranging from 105 ? to 150 ?, with 60% of the total number of pores in the pore size distribution having a pore diameter within 60 ? of the median pore diameter, with at least 50% of its pore volume in pores having a pore diameter of at most 600 ?, and between 5% and 25% of its pore volume in pores having a pore diameter between 1000 ? and 5000 ?. Methods of producing said catalyst are described herein. Crude products and products made from said crude products are described herein.
    Type: Application
    Filed: April 10, 2009
    Publication date: October 15, 2009
    Inventors: Opinder Kishan BHAN, Scott Lee WELLINGTON
  • Publication number: 20090236264
    Abstract: A process for steam cracking liquid hydrocarbon feedstocks containing synthetic crude oil comprises i) hydroprocessing a wide boiling range aliquot containing a) normally liquid hydrocarbon portion substantially free of resids and b) thermally cracked hydrocarbon liquid, boiling in a range from about 600° to about 1050° F., to provide a synthetic crude oil substantially free of resids; ii) adding to the synthetic crude oil a normally liquid hydrocarbon component boiling in a range from about 100° to about 1050° F.; and iii) cracking the mixture resulting from ii) in a cracker furnace comprising a radiant coil outlet to provide a cracked effluent, wherein the cracking is carried out under conditions sufficient to effect a radiant coil outlet temperature which is greater than the optimum radiant coil outlet temperature for cracking the synthetic crude oil separately. A method for upgrading synthetic crude for use in cracking is also provided, as well as a feedstock for cracking.
    Type: Application
    Filed: June 5, 2009
    Publication date: September 24, 2009
    Inventors: Paul F. Keusenkothen, James N. McCoy, James Earl Graham, Chad David Reimann
  • Publication number: 20090236263
    Abstract: Total acid number and/or corrosiveness of a crude or refined hydrocarbon, where the total acid number and/or corrosiveness is due to the presence of acid compounds such as carboxylic acid (naphthenic acid), may be reduced by treating the hydrocarbon with a metallic overbase. The effect of this treatment may be substantially enhanced by the presence of a hydrogen transfer agent. The abstract is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims. 37 CFR 1.
    Type: Application
    Filed: March 23, 2009
    Publication date: September 24, 2009
    Applicant: Baker Hughes Incorporated
    Inventors: Ksenija Babic-Samardzija, Joseph L. Stark, Michael J. Zetlmeisl, Bradley G. Harrell, Lawrence N. Kremer
  • Patent number: 7588680
    Abstract: In some embodiments, the invention is a method of removing sulfur from a hydrocarbon feed using the steps of dissolving metallic sodium in a first solvent, combining the sodium/first solvent solution with a sulfur-free alkane or cycloalkane second solvent, vaporizing the first solvent from sodium/first solvent/second solvent combination to transfer the dissolved metallic sodium into the second solvent, and then combine the resultant liquid with a liquid hydrocarbon feed containing an organosulfur species. The resulting stream is combined with a hydrogen donor. The combination is heated and pressurized to form a liquid hydrocarbon product containing sodium sulfide. The liquid hydrocarbon product containing sodium sulfide is then cooled, and the sodium sulfide is extracted.
    Type: Grant
    Filed: February 26, 2007
    Date of Patent: September 15, 2009
    Assignee: Trans Ionics Corporation
    Inventor: Robert C. Schucker
  • Patent number: 7572362
    Abstract: The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. It utilizes a short residence-time pyrolytic reactor operating under conditions that result in a rapid pyrolytic distillation with coke formation. Both physical and chemical changes taking place lead to an overall molecular weight reduction in the liquid product and rejection of certain components with the byproduct coke. The liquid product is upgraded primarily because of its substantially reduced viscosity, increased API gravity, and the content of middle and light distillate fractions. While maximizing the overall liquid yield, the improvements in viscosity and API gravity can render the liquid product suitable for pipelining without the use of diluents.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: August 11, 2009
    Assignee: Ivanhoe Energy, Inc.
    Inventors: Barry Freel, Jerry F. Kriz, Doug Clarke
  • Patent number: 7572365
    Abstract: The present invention is directed to the upgrading of heavy petroleum oils of high viscosity and low API gravity that are typically not suitable for pipelining without the use of diluents. It utilizes a short residence-time pyrolytic reactor operating under conditions that result in a rapid pyrolytic distillation with coke formation. Both physical and chemical changes taking place lead to an overall molecular weight reduction in the liquid product and rejection of certain components with the byproduct coke. The liquid product is upgraded primarily because of its substantially reduced viscosity, increased API gravity, and the content of middle and light distillate fractions. While maximizing the overall liquid yield, the improvements in viscosity and API gravity can render the liquid product suitable for pipelining without the use of diluents.
    Type: Grant
    Filed: October 11, 2002
    Date of Patent: August 11, 2009
    Assignee: Ivanhoe Energy, Inc.
    Inventors: Barry Freel, Jerry F. Kriz, Doug Clarke
  • Patent number: 7563357
    Abstract: A process for steam cracking liquid hydrocarbon feedstocks containing synthetic crude oil comprises i) hydroprocessing a wide boiling range aliquot containing a) normally liquid hydrocarbon portion substantially free of resids and b) thermally cracked hydrocarbon liquid, boiling in a range from about 600° to about 1050° F., to provide a synthetic crude oil substantially free of resids; ii) adding to the synthetic crude oil a normally liquid hydrocarbon component boiling in a range from about 100° to about 1050° F.; and iii) cracking the mixture resulting from ii) in a cracker furnace comprising a radiant coil outlet to provide a cracked effluent, wherein the cracking is carried out under conditions sufficient to effect a radiant coil outlet temperature which is greater than the optimum radiant coil outlet temperature for cracking the synthetic crude oil separately. A method for upgrading synthetic crude for use in cracking is also provided, as well as a feedstock for cracking.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: July 21, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Paul F Keusenkothen, James N McCoy, James Earl Graham, Chad David Reimann
  • Publication number: 20090152164
    Abstract: It has been discovered that metals and/or amines can be removed or transferred from a hydrocarbon phase to a water phase in an emulsion breaking process by using a composition that contains water-soluble hydroxyacids. Suitable water-soluble hydroxyacids include, but are not necessarily limited to glycolic acid, gluconic acid, C2-C4 alpha-hydroxy acids, poly-hydroxy carboxylic acids, thioglycolic acid, chloroacetic acid, polymeric forms of the above hydroxyacids, poly-glycolic esters, glycolate ethers, and ammonium salt and alkali metal salts of these hydroxyacids, and mixtures thereof. The composition may also include at least one mineral acid to reduce the pH of the desalter wash water. A solvent may be optionally included in the composition. The invention permits transfer of metals and/or amines into the aqueous phase with little or no hydrocarbon phase undercarry into the aqueous phase.
    Type: Application
    Filed: February 23, 2009
    Publication date: June 18, 2009
    Applicant: Baker Hughes Incorporated
    Inventors: Tran M. Nguyen, Lawrence N. Kremer, Jerry J. Weers
  • Patent number: 7537686
    Abstract: A method for upgrading heavy oils by contacting the heavy oil with an inhibitor additive and then thermally treating the inhibitor additized heavy oil. The invention also relates to the upgraded product from the inhibitor enhanced thermal treatment process.
    Type: Grant
    Filed: May 12, 2005
    Date of Patent: May 26, 2009
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Ramesh Varadaraj, Christopher P. Eppig, Douglas W. Hissong, Robert C. Welch
  • Publication number: 20090120845
    Abstract: Methods for liberating organic carbonaceous products from mineral matrices such as oil shale and the products liberated by the present methods inter alia, the invention in a preferred embodiment subjects oil shale to resonance disintegration including inter alia rapid pressure and directional changes to essentially instantaneously vary forces acting thereon. Oil shale processed by non-impact processing according to the invention liberates kerogen from the mineral matrix to permit subsequent conversion to shale oil or other utilization.
    Type: Application
    Filed: April 10, 2006
    Publication date: May 14, 2009
    Inventor: James P. Yates
  • Patent number: 7527724
    Abstract: The present invention is a method of removing sulphur from a hydrocarbon feed stream, comprising the steps of: (a) dissolving sodium in a liquid solvent to form a solution containing sodium atoms; (b) combining the liquid solution from step (a) with a liquid hydrocarbon feed containing an organosulfur component to form a combined stream at a temperature of addition and at a pressure near or above the vapor pressure of the solvent at the temperature of addition; (c) reacting the combined stream for sufficient reaction time and at sufficient reaction temperature to form a modified composition comprising one or more sulfur-containing species and less of the organosulfur species than had been present in the hydrocarbon feed; (d) extracting a portion of the sulfur-containing species from the modified composition.
    Type: Grant
    Filed: October 20, 2006
    Date of Patent: May 5, 2009
    Assignee: Trans Ionics Corporation
    Inventor: Robert C. Schucker
  • Patent number: 7501103
    Abstract: Tropospheric volume elements enriched with vital elements and/or protective substances as well as procedures for their production and application. The term “vital elements” applies to all matter supporting the development of life within the earth's biosphere and the term “protective substances” means all those substances which contribute directly or indirectly to the prevention of harmful effects on the earth's biosphere and in particular on man. Tropospheric volume elements in the form of clouds which contain contaminants and which can escape from industrial facilities due to damage or malfunction are enriched with protective substances which prevent the organism from taking in radioactive elements and minimize the extent of the area affected by the clouds and possess additional warning and identification properties.
    Type: Grant
    Filed: July 29, 2002
    Date of Patent: March 10, 2009
    Inventor: Franz-Dietrich Oeste
  • Publication number: 20090032435
    Abstract: Atmospheric and/or vacuum resid fractions of a high solvency dispersive power (HSDP) crude oil are added to a blend of crude oil to prevent fouling of crude oil refinery equipment and to perform on-line cleaning of fouled refinery equipment. The HSDP resid fractions dissolve asphaltene precipitates and maintain suspension of inorganic particulates before coking affects heat exchange surfaces.
    Type: Application
    Filed: August 15, 2008
    Publication date: February 5, 2009
    Applicant: ExxonMobil Research and Engineering Company
    Inventors: Glen B. Brons, Chris A. Wright, George A. Lutz, Mark A. Greaney
  • Patent number: 7470823
    Abstract: The present invention relates to polyethers which are obtainable from 1 -butene oxide and an alcohol using a double metal cyanide compound as a catalyst and have a content of unsaturated components of 6 mol% or more, to a process for preparing such a polyether and also to the use of a polyether according to the invention as a carrier oil or in a carrier oil formulation, in particular in additive packages for gasoline fuels, and furthermore also to carrier oil formulations and also to fuels comprising a polyether according to the invention.
    Type: Grant
    Filed: March 10, 2003
    Date of Patent: December 30, 2008
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Stoesser, Edward Bohres, Georg Heinrich Grosch, Wilfried Sager, Marc Walter
  • Publication number: 20080314796
    Abstract: A treated oil, such as a treated heavy oil, which has a viscosity which is lower than the viscosity of the oil prior to the treatment thereof (i.e., the initial oil). The temperature at which 80 mass % of the treated oil has boiled is within 25° C. of temperature at which 80 mass % of the oil prior to the treatment thereof has boiled. Thus, the treated oil and the oil prior to the treatment thereof, have distillation curves or boiling point curves which are the same as or approximate to each other.
    Type: Application
    Filed: December 6, 2007
    Publication date: December 25, 2008
    Inventors: Michel Chornet, Esteban Chornet
  • Publication number: 20080296202
    Abstract: The present invention provides a process for the treatment of crude oil or aged crude oil residue comprising the steps of (a) contacting the oil or residue with a phenol resin and with a diluent, to provide a diluted phenol resin treated oil or residue; and (b) optionally removing solid material from the diluted phenol resin treated oil or residue.
    Type: Application
    Filed: December 21, 2006
    Publication date: December 4, 2008
    Applicant: Innospec Limited
    Inventors: Andrea Sneddon, Jenny-Ann Ostlund
  • Patent number: 7438877
    Abstract: Selective, irreversible removal of hydrogen sulfide (H2S) and other sulfhydryl compounds from a gas stream, such as sour natural gas and sour hydrocarbon liquids is achieved with a scavenging agent having hydroxyalkyl functionality and alkylamine functionality. This scavenger possesses a higher capacity for H2S removal compared with a scavenger having only hydroxyalkyl functionality. The scavenging agent is made by reacting at least one alkanolamine and at least one alkyl amine with an aldehyde, such as formaldehyde.
    Type: Grant
    Filed: September 1, 2006
    Date of Patent: October 21, 2008
    Assignee: Baker Hughes Incorporated
    Inventors: Tauseef Salma, Alexander A. Lambert, III, Gordon T. Rivers
  • Patent number: 7431821
    Abstract: The present invention relates to an olefinic naphtha and a process for producing lower olefinc from this naphtha. In the process of the present invention for producing lower olefins, preferably ethylene, at least a portion of a hydrocarbon asset is converted to synthesis gas and at least a portion of the synthesis gas is converted to an olefinic naphtha by a Fischer-Tropsch process. At least a portion of the olefinic naphtha is converted in a naphtha cracker to a product stream comprising lower olefins, and at least a portion of the lower olefins from the product stream of the cracker are recovered.
    Type: Grant
    Filed: January 31, 2003
    Date of Patent: October 7, 2008
    Assignee: Chevron U.S.A. Inc.
    Inventors: Dennis J. O'Rear, Guan Dao Lei