Conductor Layer Next To Insulator Is Non-mesi Composite Or Compound, E.g., Tin (epo) Patents (Class 257/E21.204)
  • Patent number: 11942377
    Abstract: A semiconductor device includes a semiconductor substrate; a plurality of channel regions, including a p-type channel region and an n-type channel region, disposed over the semiconductor substrate; and a gate structure. The gate structure includes a gate dielectric layer disposed over the plurality of channel regions and a work function metal (WFM) structure disposed over the gate dielectric layer. The WFM structure includes an n-type WFM layer over the n-type channel region and not over the p-type channel region and further includes a p-type WFM layer over both the n-type WFM layer and the p-type channel region. The gate structure further includes a fill metal layer disposed over the WFM structure and in direct contact with the p-type WFM layer.
    Type: Grant
    Filed: February 28, 2022
    Date of Patent: March 26, 2024
    Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
    Inventors: Lung-Kun Chu, Mao-Lin Huang, Wei-Hao Wu, Kuo-Cheng Chiang
  • Patent number: 11456359
    Abstract: A semiconductor device, including a substrate, and a deposit layer and a semiconductor layer formed sequentially on the substrate. The semiconductor layer has selectively disposed therein a first region, a second region and a contact region. A gate electrode is disposed on the first region and the semiconductor layer via a gate insulating film. A source electrode is formed in contact with the contact region and the second region. A drain electrode is disposed on the back surface of the substrate. The source electrode has a first titanium (Ti) film, and a titanium nitride (TiN) film, a second Ti film, and a metal film containing aluminum (Al) sequentially formed on the first Ti film. The source electrode may further include another TiN film, on which the first Ti film is formed.
    Type: Grant
    Filed: August 29, 2016
    Date of Patent: September 27, 2022
    Assignee: FUJI ELECTRIC CO., LTD.
    Inventors: Yasuyuki Hoshi, Yuichi Harada, Takashi Shiigi
  • Patent number: 11430698
    Abstract: A method includes forming a gate dielectric on a semiconductor region, depositing a work-function layer over the gate dielectric, depositing a silicon layer over the work-function layer, and depositing a glue layer over the silicon layer. The work-function layer, the silicon layer, and the glue layer are in-situ deposited. The method further includes depositing a filling-metal over the glue layer; and performing a planarization process, wherein remaining portions of the glue layer, the silicon layer, and the work-function layer form portions of a gate electrode.
    Type: Grant
    Filed: May 19, 2020
    Date of Patent: August 30, 2022
    Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.
    Inventors: Hsin-Han Tsai, Chung-Chiang Wu, Cheng-Lung Hung, Weng Chang, Chi On Chui
  • Patent number: 11342225
    Abstract: A method includes etching a dielectric layer of a substrate to form an opening in the dielectric layer, forming a metal layer extending into the opening, performing an anneal process, so that a bottom portion of the metal layer reacts with a semiconductor region underlying the metal layer to form a source/drain region, performing a plasma treatment process on the substrate using a process gas including hydrogen gas and a nitrogen-containing gas to form a silicon-and-nitrogen-containing layer, and depositing a metallic material on the silicon-and-nitrogen-containing layer.
    Type: Grant
    Filed: July 31, 2019
    Date of Patent: May 24, 2022
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Ching-Yi Chen, Sheng-Hsuan Lin, Wei-Yip Loh, Hung-Hsu Chen, Chih-Wei Chang
  • Patent number: 10304696
    Abstract: In a transistor including an oxide semiconductor layer, an oxide insulating layer is formed so as to be in contact with the oxide semiconductor layer. Then, oxygen is introduced (added) to the oxide semiconductor layer through the oxide insulating layer, and heat treatment is performed. Through these steps of oxygen introduction and heat treatment, impurities such as hydrogen, moisture, a hydroxyl group, or hydride are intentionally removed from the oxide semiconductor layer, so that the oxide semiconductor layer is highly purified.
    Type: Grant
    Filed: April 20, 2017
    Date of Patent: May 28, 2019
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Shunpei Yamazaki, Junichi Koezuka
  • Patent number: 9768069
    Abstract: A method for forming a semiconductor device is provided. The method includes providing a semiconductor substrate with an insulating layer formed thereon. The method includes forming a gate dielectric layer in the first opening and the second opening. The method includes forming a film over the gate dielectric layer. The method includes forming a first work function metal layer in the first opening. The method includes depositing a second work function metal layer in the first opening and the second opening and in direct contact with the first work function metal layer in the first opening and the film in the second opening. A first deposition rate of the second work function metal layer over the first work function metal layer is greater than a second deposition rate of the second work function metal layer over the film.
    Type: Grant
    Filed: March 15, 2016
    Date of Patent: September 19, 2017
    Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
    Inventors: Wei-Shuo Ho, Tsung-Yu Chiang, Chia-Chun Liao, Kuang-Hsin Chen
  • Patent number: 9691867
    Abstract: The semiconductor device structures and methods for forming the same are provided. The semiconductor device structure includes a metal gate over a substrate. A first spacer is formed over sidewalls of the metal gate and having a first height. A second spacer is formed over the sidewalls of the metal gate and having a second height. The first height is higher than the second height. The first spacer is farther from the sidewalls of the metal gate than the second spacer. In addition, the semiconductor device structure includes a dielectric layer formed over the substrate to surround the first spacer and the metal gate.
    Type: Grant
    Filed: August 22, 2016
    Date of Patent: June 27, 2017
    Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING CO., LTD.
    Inventors: Chen-Liang Liao, Chih-Hsiao Chen, Yi-Lii Huang, Yao-Yu Li
  • Patent number: 8592924
    Abstract: A semiconductor device includes a semiconductor substrate having a semiconductor layer, a gate electrode, a source region, a drain region, an element separation insulating film layer and a wiring. The gate electrode include a laminated structure having a gate insulating film formed on the semiconductor layer, a metal or a metallic compound formed on the gate insulating film and a polycrystalline silicon layer formed on the metal or metallic compound. The source region and drain region are formed on a surface portion of the semiconductor substrate and sandwich the gate electrode therebetween. The element separation insulating film layer surrounds the semiconductor layer. The wiring is in contact with the metal or metallic compound of the gate electrode.
    Type: Grant
    Filed: May 14, 2012
    Date of Patent: November 26, 2013
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yoshinori Tsuchiya, Masato Koyama
  • Publication number: 20130149852
    Abstract: A method for forming a semiconductor device includes providing in a process chamber a metal-containing gate electrode film on a substrate, flowing a process gas consisting of hydrogen (H2) and optionally a noble gas into the process chamber, forming plasma excited species from the process gas by a microwave plasma source, and exposing the metal-containing gate electrode film to the plasma excited species to form a modified metal-containing gate electrode film having a lower work function than the metal-containing gate electrode film. Other embodiments describe forming semiconductor devices with gate stacks containing modified metal-containing gate electrodes for NMOS and PMOS transistors.
    Type: Application
    Filed: December 8, 2011
    Publication date: June 13, 2013
    Applicant: TOKYO ELECTRON LIMITED
    Inventors: Genji Nakamura, Toshio Hasegawa
  • Patent number: 8450169
    Abstract: The thickness and composition of a gate dielectric can be selected for different types of field effect transistors through a planar high dielectric constant material portion, which can be provided only for selected types of field effect transistors. Further, the work function of field effect transistors can be tuned independent of selection of the material stack for the gate dielectric. A stack of a barrier metal layer and a first-type work function metal layer is deposited on a gate dielectric layer within recessed gate cavities after removal of disposable gate material portions. After patterning the first-type work function metal layer, a second-type work function metal layer is deposited directly on the barrier metal layer in the regions of the second type field effect transistor. A conductive material fills the gate cavities, and a subsequent planarization process forms dual work function metal gate structures.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: May 28, 2013
    Assignee: International Business Machines Corporation
    Inventors: Unoh Kwon, Ramachandra Divakaruni, Siddarth A. Krishnan, Ravikumar Ramachandran
  • Patent number: 8450813
    Abstract: There is provided a fin transistor structure and a method of fabricating the same. The fin transistor structure comprises a fin formed on a semiconductor substrate, wherein a bulk semiconductor material is formed between a portion of the fin serving as the channel region of the transistor structure and the substrate, and an insulation material is formed between remaining portions of the fin and the substrate. Thereby, it is possible to reduce the current leakage while maintaining the advantages of body-tied structures.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: May 28, 2013
    Assignee: Institute of Microelectronics, Chinese Academy of Sciences
    Inventors: Zhijiong Luo, Haizhou Yin, Huilong Zhu
  • Patent number: 8445973
    Abstract: There is provided a fin transistor structure and a method of fabricating the same. The fin transistor structure comprises a fin formed on a semiconductor substrate, wherein an insulation material is formed between a portion of the fin serving as the channel region of the transistor structure and the substrate, and a bulk semiconductor material is formed between remaining portions of the fin and the substrate. Thereby, it is possible to reduce the current leakage while maintaining the advantages such as low cost and high heat transfer.
    Type: Grant
    Filed: June 24, 2010
    Date of Patent: May 21, 2013
    Assignee: Institute of Microelectronics, Chinese Academy of Sciences
    Inventors: Zhijiong Luo, Huilong Zhu, Haizhou Yin
  • Patent number: 8431472
    Abstract: Methods is provided for forming a CMOS device. The method includes providing a substrate and depositing a gate stack on the substrate. The gate stack includes a gate dielectric and a dummy gate including polycrystalline silicon (polySi). The method also includes depositing a dielectric layer on the substrate after depositing the gate stack on the substrate. The method further includes substituting the dummy gate with a metal without first removing the dummy gate.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: April 30, 2013
    Assignee: Globalfoundries, Inc.
    Inventor: Chang Seo Park
  • Patent number: 8420519
    Abstract: Methods are provided for fabricating integrated circuits having controlled threshold voltages. In accordance with one embodiment a method includes forming a gate dielectric overlying an N-doped silicon substrate and depositing a layer of titanium nitride and a layer of tantalum nitride overlying the gate dielectric. A sub-monolayer of tantalum oxide is deposited overlying the layer of tantalum nitride by a process of atomic layer deposition, and oxygen is diffused from the tantalum oxide through the tantalum nitride and titanium nitride.
    Type: Grant
    Filed: November 1, 2011
    Date of Patent: April 16, 2013
    Assignee: GLOBALFOUNDRIES, Inc.
    Inventors: Dina Triyoso, Elke Erben, Klaus Hempel
  • Patent number: 8330234
    Abstract: In a semiconductor device, a gate electrode having a uniform composition prevents deviation in a work function. Controlling a Vth provides excellent operation properties. The semiconductor device includes an NMOS transistor and a PMOS transistor with a common line electrode. The line electrode includes electrode sections (A) and (B) and a diffusion barrier region formed over an isolation region so that (A) and (B) are kept out of contact. The diffusion barrier region meets at least one of: (1) The diffusion coefficient in the above diffusion barrier region of the constituent element of the above electrode section (A) is lower than the interdiffusion coefficient of the constituent element between electrode section (A) materials; and (2) The diffusion coefficient in the above diffusion barrier region of the constituent element of the above electrode section (B) is lower than the interdiffusion coefficient of the constituent element between electrode section (B) materials.
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: December 11, 2012
    Assignee: NEC Corporation
    Inventor: Takashi Hase
  • Publication number: 20120187563
    Abstract: A planarization method of manufacturing a semiconductor component is provided. A dielectric layer is formed above a substrate and defines a trench therein. A barrier layer and a metal layer are formed in sequence in the trench. A first planarization process is applied to the metal layer by using a first reactant so that a portion of the metal layer is removed. An etching rate of the first reactant to the metal layer is greater than that of the first reactant to the barrier layer. A second planarization process is applied to the barrier layer and the metal layer by using a second reactant so that a portion of the barrier layer and the metal layer are removed to expose the dielectric layer. An etching rate of the second reactant to the barrier layer is greater than that of the second reactant to the metal layer.
    Type: Application
    Filed: January 24, 2011
    Publication date: July 26, 2012
    Applicant: UNITED MICROELECTRONICS CORP.
    Inventors: Ya-Hsueh HSIEH, Teng-Chun Tsai, Wen-Chin Lin, Hsin-Kuo Hsu, Ren-Peng Huang, Chih-Hsien Chen, Chih-Chin Yang, Hung-Yuan Lu, Jen-Chieh Lin, Wei-Che Tsao
  • Patent number: 8026539
    Abstract: Methods are provided for forming a semiconductor device comprising a semiconductor substrate. In accordance with an exemplary embodiment, a method comprises the steps of forming a high-k dielectric layer overlying the semiconductor substrate, forming a metal-comprising gate layer overlying the high-k dielectric layer, forming a doped silicon-comprising capping layer overlying the metal-comprising gate layer, and depositing a silicon-comprising gate layer overlying the doped silicon-comprising capping layer.
    Type: Grant
    Filed: February 18, 2009
    Date of Patent: September 27, 2011
    Assignee: GLOBALFOUNDRIES Inc.
    Inventors: Michael Hargrove, Frank Bin Yang, Rohit Pal
  • Publication number: 20110207314
    Abstract: A process is disclosed of forming metal replacement gates for PMOS transistors with oxygen in the metal gates such that the PMOS gates have effective work functions above 4.85. Metal work function layers in the PMOS gates are oxidized at low temperature to increase their effective work functions to the desired PMOS range. Hydrogen may also be incorporated at an interface between the metal gates and underlying gate dielectrics. Materials for the metal work function layers and processes for the low temperature oxidation are disclosed.
    Type: Application
    Filed: May 4, 2011
    Publication date: August 25, 2011
    Applicant: TEXAS INSTRUMENTS INCORPORATED
    Inventors: Hiroaki Niimi, James Joseph Chambers
  • Patent number: 7892961
    Abstract: A method for forming a semiconductor structure includes providing a semiconductor substrate; forming a gate dielectric layer on the semiconductor substrate; forming a metal-containing layer on the gate dielectric; and forming a composite layer over the metal-containing layer. The step of forming the composite layer includes forming an un-doped silicon layer substantially free from p-type and n-type impurities; and forming a silicon layer adjoining the un-doped silicon layer. The step of forming the silicon layer comprises in-situ doping a first impurity. (or need to be change to: forming a silicon layer first & then forming un-doped silicon layer) The method further includes performing an annealing to diffuse the first impurity in the silicon layer into the un-doped silicon layer.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: February 22, 2011
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.
    Inventors: Chen-Hua Yu, Cheng-Tung Lin, Liang-Gi Yao
  • Patent number: 7803682
    Abstract: A semiconductor memory device includes a plurality of memory transistors. Each of the memory transistors has: a floating gate electrode; an interelectrode insulating film; and a control gate electrode. The floating gate electrode includes, in a cross section taken along a bit line direction, a first conductive film, first sidewall insulating films opposed to each other across the first conductive film, and a second conductive film provided on the first sidewall insulating films and the first conductive film. The interelectrode insulating film is provided on the second conductive film. The control gate electrode includes a third conductive film provided on the interelectrode insulating film and a fourth conductive film provided on the third conductive film.
    Type: Grant
    Filed: August 21, 2007
    Date of Patent: September 28, 2010
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Katsuaki Natori, Masayuki Tanaka, Akihito Yamamoto
  • Patent number: 7781337
    Abstract: A manufacturing method of a semiconductor device includes forming a cobalt film on a silicon substrate on which a diffusion layer is formed, forming a titanium film on the cobalt film using a titanium target that has a surface from which a nitride film has previously been removed, forming a titanium nitride film on the titanium film in accordance with a reactive sputtering process using a gas containing a nitrogen atom and the titanium target, and performing a heat treatment to react the cobalt film with the silicon substrate, thereby accomplishing silicification.
    Type: Grant
    Filed: December 21, 2006
    Date of Patent: August 24, 2010
    Assignee: Oki Semiconductor Co., Ltd.
    Inventor: Keiichi Hashimoto
  • Patent number: 7776733
    Abstract: Embodiments of the invention describe TiN deposition methods suitable for high volume manufacturing of semiconductor devices on large patterned substrates (wafers). One embodiment describes a chemical vapor deposition (CVD) process using high gas flow rate of a tetrakis(ethylmethylamino) titanium (TEMAT) precursor vapor along with an inert carrier gas at a low process chamber pressure that provides high deposition rate of conformal TiN films with good step coverage in surface reaction limited regime. Other embodiments describe cyclical TiN deposition methods using TEMAT precursor vapor and a nitrogen precursor.
    Type: Grant
    Filed: May 2, 2007
    Date of Patent: August 17, 2010
    Assignee: Tokyo Electron Limited
    Inventor: Toshio Hasegawa
  • Patent number: 7754559
    Abstract: A capacitor structure is fabricated with only slight modifications to a conventional single-poly CMOS process. After front-end processing is completed, grooves are etched through the pre-metal dielectric layer to expose polysilicon structures, which may be salicided or non-salicided. A dielectric layer is formed over the exposed polysilicon structures. A conventional contact process module is then used to form contact openings through the pre-metal dielectric layer. The mask used to form the contact openings is then removed, and conventional contact metal deposition steps are performed, thereby simultaneously filling the contact openings and the grooves with the contact (electrode) metal stack. A planarization step removes the upper portion of the metal stack, thereby leaving metal contacts in the contact openings, and metal electrodes in the grooves. The metal electrodes may form, for example, transistor gates, EEPROM control gates or capacitor plates.
    Type: Grant
    Filed: March 19, 2008
    Date of Patent: July 13, 2010
    Assignee: Tower Semiconductor Ltd.
    Inventors: Efraim Aloni, Yakov Roizin, Alexey Heiman, Michael Lisiansky, Amos Fenigstein, Myriam Buchbinder
  • Patent number: 7700438
    Abstract: Methods and apparatus are provided for non-volatile semiconductor devices. The apparatus comprises a substrate having therein a source region and a drain region separated by a channel region extending to a first surface of the substrate, and a multilayered gate structure containing nano-crystals located above the channel region. The gate structure comprises, a gate dielectric substantially in contact with the channel region, spaced-apart nano-crystals disposed in the gate dielectric, one or more impurity blocking layers overlying the gate dielectric and a gate conductor layer overlying the one more impurity blocking layers. The blocking layer nearest the gate conductor can also be used to adjust the threshold voltage of the device and/or retard dopant out-diffusion from the gate conductor layer.
    Type: Grant
    Filed: January 30, 2006
    Date of Patent: April 20, 2010
    Assignee: Freescale Semiconductor, Inc.
    Inventors: Chun-Li Liu, Tushar P. Merchant, Marius K. Orlowski, Matthew W. Stoker
  • Patent number: 7648884
    Abstract: A resistive device (44) and a transistor (42) are formed. Each uses a portion of a metal layer (18) that is formed at the same time and thus additional process steps are avoided to remove the metal from the resistive device. The metal used in the resistive device is selectively treated to increase the resistance in the resistive device. A polycrystalline semiconductor material layer (34) overlies the metal layer in the resistive device. The combination of these layers provides the resistive device. In one form the metal is treated after formation of the polycrystalline semiconductor material layer. In one form the metal treatment involves an implant of a species, such as oxygen, to increase the resistivity of the metal. Various transistor structures are formed using the untreated portion of the metal layer as a control electrode.
    Type: Grant
    Filed: February 28, 2007
    Date of Patent: January 19, 2010
    Assignee: Freescale Semiconductor, Inc.
    Inventors: Byoung W. Min, James K. Schaeffer, David C. Sing
  • Patent number: 7632754
    Abstract: A method for forming a metal line of a semiconductor device includes forming an interlayer insulation film over a semiconductor substrate, forming a trench for exposing at least a portion of the semiconductor substrate by using a selective etching process, and forming a diffusion barrier layer over the interlayer film and the inner walls of the trench, by using a plasma enhanced atomic layer deposition process in which a high frequency power generator is set to have a frequency of 13.56 MHz. The plasma enhanced atomic layer deposition process is performed with a base pressure in a chamber maintained at 1×10?8 to 3×10?7 torr.
    Type: Grant
    Filed: December 28, 2006
    Date of Patent: December 15, 2009
    Assignee: Dongbu Hi-Tek Co., Ltd.
    Inventors: In-Cheol Baek, Han-Choon Lee
  • Publication number: 20090294867
    Abstract: Methods of forming dual metal gates and the gates so formed are disclosed. A method may include forming a first metal (e.g., NMOS metal) layer on a gate dielectric layer and a second metal (e.g., PMOS metal) layer on the first metal layer, whereby the second metal layer alters a work function of the first metal layer (to form PMOS metal). The method may remove a portion of the second metal layer to expose the first metal layer in a first region; form a silicon layer on the exposed first metal layer in the first region and on the second metal layer in a second region; and form the dual metal gates in the first and second regions. Since the gate dielectric layer is continuously covered with the first metal, it is not exposed to the damage from the metal etch process.
    Type: Application
    Filed: May 30, 2008
    Publication date: December 3, 2009
    Inventors: Byoung H. Lee, Sang Ho Bae, Kisik Choi, Rino Choi, Craig Huffman, Prashant Majhi, Jong Hoan Sim, Seung-Chul Song, Zhibo Zhang
  • Patent number: 7611943
    Abstract: A process (200) for making integrated circuits with a gate, uses a doped precursor (124, 126N and/or 126P) on barrier material (118) on gate dielectric (116). The process (200) involves totally consuming (271) the doped precursor (124, 126N and/or 126P) thereby driving dopants (126N and/or 126P) from the doped precursor (124) into the barrier material (118). An integrated circuit has a gate dielectric (116), a doped metallic barrier material (118, 126N and/or 126P) on the gate dielectric (116), and metal silicide (180) on the metallic barrier material (118). Other integrated circuits, transistors, systems and processes of manufacture are disclosed.
    Type: Grant
    Filed: October 12, 2005
    Date of Patent: November 3, 2009
    Assignee: Texas Instruments Incorporated
    Inventor: Kaiping Liu
  • Patent number: 7601623
    Abstract: A semiconductor device includes a semiconductor substrate having a semiconductor layer, a gate electrode, a source region, a drain region, an element separation insulating film layer and a wiring. The gate electrode include a laminated structure having a gate insulating film formed on the semiconductor layer, a metal or a metallic compound formed on the gate insulating film and a polycrystalline silicon layer formed on the metal or metallic compound. The source region and drain region are formed on a surface portion of the semiconductor substrate and sandwich the gate electrode therebetween. The element separation insulating film layer surrounds the semiconductor layer. The wiring is in contact with the metal or metallic compound of the gate electrode.
    Type: Grant
    Filed: July 16, 2008
    Date of Patent: October 13, 2009
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yoshinori Tsuchiya, Masato Koyama
  • Patent number: 7575973
    Abstract: A method of making a monolithic, three dimensional NAND string including a first memory cell located over a second memory cell, includes growing a semiconductor active region of second memory cell, and epitaxially growing a semiconductor active region of the first memory cell on the semiconductor active region of the second memory cell in a different growth step from the step of growing the semiconductor active region of second memory cell.
    Type: Grant
    Filed: March 27, 2007
    Date of Patent: August 18, 2009
    Assignee: SanDisk 3D LLC
    Inventors: Nima Mokhlesi, Roy Scheuerlein
  • Publication number: 20090057783
    Abstract: Provided is a semiconductor device and a method of fabricating a metal gate in the semiconductor device. The semiconductor device includes a metal gate formed on a gate insulating film, the metal gate is formed of a mixture of a metal nitride and a metal carbide, and a work function of the metal gate is determined according to ratios of the metal nitride with respect to the metal carbide.
    Type: Application
    Filed: March 7, 2008
    Publication date: March 5, 2009
    Inventors: Sung-ho Park, Jin-seo Noh, Joong-S. Jeon
  • Publication number: 20080299730
    Abstract: A compound metal comprising MOxNy which is a p-type metal having a workfunction of about 4.75 to about 5.3, preferably about 5, eV that is thermally stable on a gate stack comprising a high k dielectric and an interfacial layer is provided as well as a method of fabricating the MOxNy compound metal. Furthermore, the MOxNy metal compound of the present invention is a very efficient oxygen diffusion barrier at 1000° C. allowing very aggressive equivalent oxide thickness (EOT) and inversion layer thickness scaling below 14 ? in a p-metal oxide semiconductor (pMOS) device. In the above formula, M is a metal selected from Group IVB, VB, VIB or VIIB of the Periodic Table of Elements, x is from about 5 to about 40 atomic % and y is from about 5 to about 40 atomic %.
    Type: Application
    Filed: August 12, 2008
    Publication date: December 4, 2008
    Applicant: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventors: Alessandro C. Callegari, Michael A. Gribelyuk, Vijay Narayanan, Vamsi K. Paruchuri, Sufi Zafar
  • Patent number: 7429777
    Abstract: A semiconductor device includes a semiconductor substrate having a semiconductor layer, a gate electrode, a source region, a drain region, an element separation insulating film layer and a wiring. The gate electrode include a laminated structure having a gate insulating film formed on the semiconductor layer, a metal or a metallic compound formed on the gate insulating film and a polycrystalline silicon layer formed on the metal or metallic compound. The source region and drain region are formed on a surface portion of the semiconductor substrate and sandwich the gate electrode therebetween. The element separation insulating film layer surrounds the semiconductor layer. The wiring is in contact with the metal or metallic compound of the gate electrode.
    Type: Grant
    Filed: January 11, 2006
    Date of Patent: September 30, 2008
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yoshinori Tsuchiya, Masato Koyama
  • Patent number: 7300603
    Abstract: An aqueous chemical mechanical planarizing composition includes an oxidizer for promoting barrier removal and an abrasive. Inhibitor decreases removals of a metal interconnect. The composition has a carboxylic acid polymer having at least one repeat unit of the polymer comprising at least two carboxylic acid functionalities, a pH of less than or equal to 4 and a tantalum nitride removal rate of at least eighty percent of copper removal rate at a pad pressure of 13.8 kPa.
    Type: Grant
    Filed: August 5, 2003
    Date of Patent: November 27, 2007
    Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.
    Inventor: Zhendong Liu
  • Patent number: 7282403
    Abstract: An integrated circuit is provided including an FET gate structure formed on a substrate. This structure includes a gate dielectric on the substrate, and a metal nitride layer overlying the gate dielectric and in contact therewith. This metal nitride layer is characterized as MNx, where M is one of W, Re, Zr, and Hf, and x is in the range of about 0.7 to about 1.5. Preferably the layer is of WNx, and x is about 0.9. Varying the nitrogen concentration in the nitride layer permits integration of different FET characteristics on the same chip. In particular, varying x in the WNx layer permits adjustment of the threshold voltage in the different FETs. The polysilicon depletion effect is substantially reduced, and the gate structure can be made thermally stable up to about 1000° C.
    Type: Grant
    Filed: August 15, 2005
    Date of Patent: October 16, 2007
    Assignee: International Business Machines Corporation
    Inventors: Dae-Gyu Park, Cyril Cabral, Jr., Oleg Gluschenkov, Hyungjun Kim
  • Patent number: 7256125
    Abstract: For improving the reliability of a semiconductor device having a stacked structure of a polycrystalline silicon film and a tungsten silicide film, the device is manufactured by forming a polycrystalline silicon film, a tungsten silicide film and an insulating film successively over a gate insulating film disposed over the main surface of a semiconductor substrate, and patterning them to form a gate electrode having a stacked structure consisting of the polycrystalline silicon film and tungsten silicide film. The polycrystalline silicon film has two regions, one region formed by an impurity-doped polycrystalline silicon and the other one formed by non-doped polycrystalline silicon. The tungsten silicide film is deposited so that the resistivity of it upon film formation would exceed 1000 ??cm.
    Type: Grant
    Filed: August 23, 2004
    Date of Patent: August 14, 2007
    Assignee: Renesas Technology Corp.
    Inventors: Kentaro Yamada, Masato Takahashi, Tatsuyuki Konagaya, Takeshi Katoh, Masaki Sakashita, Koichiro Takei, Yasuhiro Obara, Yoshio Fukayama
  • Patent number: 7208409
    Abstract: Fluorine containing regions (70) are formed in the source and drain regions (60) of the MOS transistor. A metal layer (90) is formed over the fluorine containing regions (70) and the source and drain regions (60). The metal layer is reacted with the underlying fluorine containing regions to form a metal silicide.
    Type: Grant
    Filed: March 7, 2005
    Date of Patent: April 24, 2007
    Assignee: Texas Instruments Incorporated
    Inventors: Jiong-Ping Lu, Duofeng Yue, Xiaozhan Liu, Donald S. Miles, Lance S. Robertson
  • Patent number: 7186632
    Abstract: In a method for manufacturing a semiconductor device having a laminated gate electrode, a phosphorus-doped polysilicon is formed on a gate oxide film. A high-melting metal or a compound of a high-melting metal and silicon is formed on the polysilicon. Phosphorus is doped into the polysilicon so that a concentration of the phosphorus in the polysilicon at an interface between the polysilicon and the gate oxide film is 2×1020(1/cm3) or less. Then, thermal oxidation is carried out in a wet-hydrogen atmosphere containing water vapor.
    Type: Grant
    Filed: March 24, 2003
    Date of Patent: March 6, 2007
    Assignee: Elpida Memory, Inc.
    Inventors: Kazuo Ogawa, Kiyonori Ohyu, Kensuke Okonogi, Toshihiro Imamura, Keiichi Watanabe, Hiroyuki Ohta
  • Patent number: 7179743
    Abstract: A thin Titanium underlayer 22 is included beneath a Titanium rich Titanium Nitride layer 28 in a metal line 20 on a silicon substrate to reduce stress voiding.
    Type: Grant
    Filed: January 20, 2003
    Date of Patent: February 20, 2007
    Assignee: Systems on Silicon Manufacturing Company Pte. Ltd.
    Inventors: Khim Hong Ng, Yeow Keong Ng, Kar Hwee Koh
  • Patent number: 7115524
    Abstract: The invention includes methods of processing semiconductor substrates. In one implementation, a semiconductor substrate is provided which has an outer surface. Such surface has a peripheral region received about a peripheral edge of the semiconductor substrate. A layer including amorphous carbon is provided over the substrate outer surface. A masking layer is provided outwardly of the amorphous carbon-including layer. A resist layer is provided outwardly of the masking layer. At least a portion of the peripheral region of the outer surface includes the amorphous carbon-including layer and the resist layer, but is substantially void of the masking layer. The amorphous carbon-including layer is patterned using the resist layer and the masking layer effective to form a mask over the semiconductor substrate. After the patterning, the semiconductor substrate is processed inwardly of the mask through openings formed in the mask.
    Type: Grant
    Filed: May 17, 2004
    Date of Patent: October 3, 2006
    Assignee: Micron Technology, Inc.
    Inventors: Jeffrey W. Honeycutt, Gurtej S. Sandhu