Containing More Than 10% Nonferrous Elements (e.g., High Alloy, Stainless) Patents (Class 428/685)
  • Patent number: 4851298
    Abstract: A tube of a muffler for an internal combustion engine includes at least two generally rectangular sheets which are joined together at one end by crimping and wound in a tubular configuration to constitute two consecutive layers. In the tubular configuration, the other end of each of the two sheets overlaps the sheet itself and welded to the latter straddling a coupling portion where the two sheets are joined. While one of the sheets which constitutes an inner layer of the tube is made of a material which is resistive to corrosion due to chemical reactions with combustion gas and others flowing through the tube, the other which constitutes an outer wall of the same is made of a material which withstands adverse ambient conditions such as briny air and high humidity.
    Type: Grant
    Filed: June 13, 1988
    Date of Patent: July 25, 1989
    Assignee: Sankei Giken Kogyo Kabushiki Kaisha
    Inventor: Masuo Fukuda
  • Patent number: 4842958
    Abstract: A chromate surface treated steel sheet having very excellent paintability, corrosion resistance, and workability, more specifically surface treated steel sheets for paint coating, having very excellent properties, specifically with respect to corrosion resistance after paint coating, paint adhesion in services long after the paint coating (so-called secondary paint adhesion), corrosion resistance of paint coating defect portions, and resistance to secondary work cracking. The steel sheet contains not more than 0.15% carbon, 0.005 to 0.10% acid soluble aluminium, 0.5 to 20% chromium with the balance being iron and unavoidable impurities, and the chromate coating applied on the steel substrate comprises a metallic chromium layer in an amount ranging from 1 to 300 mg/m.sup.2, and a hydrated chromium oxide layer in an amount ranging from 5 to 50 mg/m.sup.2 in term of the metallic chromium contained therein.
    Type: Grant
    Filed: April 14, 1987
    Date of Patent: June 27, 1989
    Assignee: Nippon Steel Corporation
    Inventors: Seijun Higuchi, Tomonari Ohga, Toshinori Katayama, Fumio Yamamoto
  • Patent number: 4818634
    Abstract: A composite metal spring material, and formed electrically conductive contact spring members made from the material, comprise metallurgically bonded layers of copper and stainless steel of selected compositions which are subjected to a novel sequence of heat-treating steps for providing the spring materials and members with spring characteristics of improved strength and stability.
    Type: Grant
    Filed: December 24, 1986
    Date of Patent: April 4, 1989
    Assignee: Texas Instruments Incorporated
    Inventor: Thomas Bliss
  • Patent number: 4808486
    Abstract: A machine part such as a cylinder or a feeding screw of an injection molding machine and the like is produced such that a separating metallic plate is inserted in a mold adapted to mold the cylinder or the feeding screw, thereby providing two molding cavities on both sides of the separating plate, and melted metals adapted to form a main portion and a corrosion and wear resistant portion of the cylinder or feeding screw are poured into the two cavities. In this manner the two kinds of metals poured into the two cavities are metallurgically fused together with the separating plate interposed therebetween.
    Type: Grant
    Filed: July 6, 1987
    Date of Patent: February 28, 1989
    Assignee: Toshiba Kikai Kabushiki Kaisha
    Inventors: Harutoshi Yamamoto, Zenichi Mochizuki, Sadasue Sakomoto
  • Patent number: 4806438
    Abstract: A titanium-clad steel with improved bonding properties and a method for the manufacture thereof are disclosed. The titanium-clad steel is characterized by comprising a Ti-cladding, a base metal steel, and an insert between them, the insert being made of an alloy consisting essentially of, in % by weight, 0.05% or less of carbon, 3 to 20% by weight of at least one of niobium (Nb) and vanadium (V), and a balance of iron.
    Type: Grant
    Filed: November 25, 1987
    Date of Patent: February 21, 1989
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventor: Shigeharu Hinotani
  • Patent number: 4804588
    Abstract: A steel wear pin or shaft product utilizes three separate alloys each having opposing metallurgical properties in a core and outer layers which form a structure optimizing the desired properties of each alloy, thus providing a superior product with a substantially improved service life.
    Type: Grant
    Filed: November 10, 1987
    Date of Patent: February 14, 1989
    Assignee: Tricon Metals & Services, Inc.
    Inventors: Grant J. Murphy, Jr., Howard S. Turnipseed
  • Patent number: 4800135
    Abstract: Continuously hot dip aluminum coated ferritic chromium alloy steel strip. After the steel has been given a pretreatment to remove surface contaminants, the steel is protected in a hydrogen atmosphere until it is passed into the molten aluminum coating metal. The coating metal readily wets the steel surface to prevent uncoated areas or pin holes in the coating layer.
    Type: Grant
    Filed: February 20, 1987
    Date of Patent: January 24, 1989
    Assignee: Armco Inc.
    Inventors: Farrell M. Kilbane, Richard A. Coleman, Frank C. Dunbar, Alan F. Gibson
  • Patent number: 4784922
    Abstract: The present invention provides corrosion resistance clad steels comprising a steel core and a cladding of a corrosion resistance metallic material tightly covering the circumference of the core, the interface between the core and cladding being metallurgically bonded. As the core materials, steel bars for concrete reinforcement including PC steel bars; or materials for sections (e.g., angles or channels) may be appropriately selected depending on the intended use. The foregoing steel materials is produced by a method comprising the steps of arranging the corrosion resistance metallic cladding member over the entire surface of the circumference of the steel core member and hot rolling to form an intimate metallurgical bonding at the interface between both members, thereby forming the foregoing clad steel material. The material may be formed into deformed steel bars.
    Type: Grant
    Filed: October 3, 1986
    Date of Patent: November 15, 1988
    Assignee: Mitsubishi Steel Mfg. Co., Ltd.
    Inventor: Tsuneo Yoshimura
  • Patent number: 4751046
    Abstract: An austenitic stainless steel alloy showing a high cavitation erosion resistance making it particularly useful for the manufacture and/or repair of hydraulic machine components. The alloy consists essentially of from 8 to 30% by weight of Co; from 13 to 30% by weight of Cr; from 0.03 to 2.0% by weight of C; up to 0.3% by weight of N; up to 5.0% by weight of Si; up to 1.0% by weight of Ni; up to 2.0% by weight of Mo; and up to 16% by weight of Mn, the balance being substantially Fe, with the proviso that at least one of the following conditions is satisfied: the amount of C is higher than 0.3%, and/or the amount of Si is higher than 3.0% and/or the amount of Mn is higher than 9.0%.
    Type: Grant
    Filed: October 23, 1986
    Date of Patent: June 14, 1988
    Assignee: Hydro Quebec
    Inventor: Raynald Simoneau
  • Patent number: 4745037
    Abstract: Brazing of metal parts employing a thin, homogeneous, ductile, filler metal foil is disclosed. The brazing foil, useful for brazing stainless steels, is less than about 0.064 mm (0.0025 inch) thick and has a composition consisting essentially of 0 to about 6 atom percent iron, 0 to about 21 atom percent chromium, 0 to about 4 atom percent molybdenum, 0 to about 5 atom percent tungsten, 0 to about 20 atom percent cobalt, 0 to about 19 atom percent boron, 0 to about 12 atom percent silicon, 0 to about 22 atom percent phosphorus, 0 to about 3 atom percent carbon and the balance nickel and incidental impurities. In addition to containing the foregoing elements within the above-noted composition ranges, the composition must be such that the total of iron, chromium, molybdenum, tungsten, cobalt and nickel ranges from about 70 to 84 atom percent and the total of boron, silicon, phosphorus and carbon ranges from about 16 to 30 atom percent.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: May 17, 1988
    Assignee: Allied Corporation
    Inventors: Nicholas DeCristofaro, Peter Sexton
  • Patent number: 4740429
    Abstract: Metal-ceramic joined articles having a splendid joint strength can be provided easily, even when the metallic member has a largely different thermal expansion coefficient from that of the ceramic member of the metal-ceramic article.
    Type: Grant
    Filed: July 17, 1986
    Date of Patent: April 26, 1988
    Assignee: NGK Insulators, Ltd.
    Inventor: Nobuo Tsuno
  • Patent number: 4721153
    Abstract: A compound roll for rollng composed of a shell made of high-chromium cast iron and a core made of cast or forged steel. The shell has a large residual compressive stress. The high-chromium cast iron shell has a composition by weight of 2.0-3.5% C, 0.5-1.5% Si, 0.4-1.5% Mn, 8-25% Cr, 0.5-3.0% Mo, 1.5% or less Ni and the balance being essentially Fe for hot rolling, and 2.5-3.5% C, 0.5-1.5% Si, 0.4-1.5% Mn, 0.5-3.0% Ni, 8-25% Cr, 1.0-5.0% Mo and the balance being essentially Fe for cold rolling. The shell's Shore hardness is 70 or more for hot rolling and 90 or more for cold rolling, and the core's tensile strength and elongation are 55 kg/mm.sup.2 or more and 1.0% or more, respectively. The residual compressive stress of the shell is 20 kg/mm.sup.2 or more and serves to prevent cracks from penetrating into the depths of the shell, thereby preventing spalling effectively. This compound roll can be manufactured by a shell casting method.
    Type: Grant
    Filed: September 12, 1986
    Date of Patent: January 26, 1988
    Assignee: Hitachi Metals, Inc.
    Inventors: Yoshikazu Sano, Michio Haga, Toshio Okitsu
  • Patent number: 4720435
    Abstract: Disclosed is an iron-base alloy eminently suited for use as components in nuclear energy installations. The alloy normally contains, in percent by weight, about 20% chromium, about 10% nickel, about 5.5% silicon, about 1.5% carbon, about 8% niobium plus vanadium, about 0.05% nitrogen, less than 1% cobalt as an impurity and the balance iron plus normal impurities found in alloys of this class.
    Type: Grant
    Filed: June 18, 1986
    Date of Patent: January 19, 1988
    Assignee: Haynes International, Inc.
    Inventors: Paul Crook, Richard D. Zordan
  • Patent number: 4714659
    Abstract: Thermal protective shield to be used in connection with hot gases in engines, particularly for the combustion of solid, liquid or gaseous fuels or in e.g. Stirling engines driven by solar energy. The thermal protective shield consists of a multi-layer material, wherein at least two layers are joined to each other over a surface corresponding to the entire surface exposed to the hot gases, and wherein the outer layer facing the hot gas consits of an alloy of the type iron-chrome-aluminium. Preferably, the layers are joined together by hot-rolling.
    Type: Grant
    Filed: August 27, 1984
    Date of Patent: December 22, 1987
    Assignee: Bulten-Kanthal AB
    Inventors: Hakan Lindgren, Bjorn Anderson
  • Patent number: 4698270
    Abstract: A spiral thermostatic coil is made from a four layer thermostatic metal comprising relatively thick intermediate LES and HES layers bonded to each other, a low expansion, corrosion-resistant, relatively thin metal layer bonded to the LES layer, and a high expansion, corrosion-resistant relatively thin metal layer bonded to the HES layer. The flexivity is reduced less than about 10% by the corrosion-resistant layers.
    Type: Grant
    Filed: November 17, 1986
    Date of Patent: October 6, 1987
    Assignee: GTE Products Corporation
    Inventor: Jacob J. Ornstein
  • Patent number: 4677034
    Abstract: Low temperature regime hot corrosion of superalloy components in gas turbines is reduced by the application thereover of cobalt-chromium alloys, the chromium content of such coatings (final composition) being in the 37.5-50 weight percent range. To the extent practicable, aluminum content in these coatings is kept to a minimum. In any event, during the annealing step some small amount at least of aluminum migrates from the superalloy into the coating. At completion of the annealing operation, the alluminum content at the exterior surface of the final coating, however, is to be less than the concentration of aluminum that will form a continuous film of aluminum oxide.
    Type: Grant
    Filed: March 28, 1983
    Date of Patent: June 30, 1987
    Assignee: General Electric Company
    Inventor: Krisham L. Luthra
  • Patent number: 4615920
    Abstract: Workpieces are very rapidly pack diffusion coated by using an excess of energizers in the pack, heating the retort containing the packed workpieces at a rate that brings the workpieces to diffusion-coating temperature and then completing the diffusion coating, all in less than 50 minutes, then cooling the retort. Workpiece can have top coating layer of aluminum flake covered by a layer of extremely fine alumina or silica in a magnesium chromate binder, to provide surface having roughness at least about 10 micro-inches smoother than before the top coating. More active diffusion coated products are also produced.
    Type: Grant
    Filed: April 25, 1983
    Date of Patent: October 7, 1986
    Assignee: Alloy Surfaces Company, Inc.
    Inventor: Alfonso L. Baldi
  • Patent number: 4609577
    Abstract: A method of producing a weld overlay on a ferrous base metal surface, by applying to the surface by electric arc welding a plurality of layers of an austenitic stainless steel filler of specific composition, and providing a flux which produces a substantially fully austenitic overlay at least in the uppermost layer. The overlay has improved machinability, metal-to-metal wear resistance and corrosion resistance, and the capability of work hardening.
    Type: Grant
    Filed: January 10, 1985
    Date of Patent: September 2, 1986
    Assignee: Armco Inc.
    Inventor: W. Herbert Long
  • Patent number: 4585481
    Abstract: Improved coating compositions are described for the protection of superalloys at elevated temperatures. The coatings are of the MCrAlY type where M is nickel or cobalt and are significantly improved by the addition of from 0.1-7% silicon and 0.1-2% hafnium. Coatings of the invention are preferably applied by plasma spraying and as so applied are found to be substantially more effective than prior art coatings.
    Type: Grant
    Filed: August 22, 1983
    Date of Patent: April 29, 1986
    Assignee: United Technologies Corporation
    Inventors: Dinesh K. Gupta, David S. Duvall
  • Patent number: 4564566
    Abstract: The pressure plate of a pressing tool is made of a chromium containing alloy essentially consisting of, each in percent by weight, carbon up to 0.3, silicon up to 1.0, manganese up to 1.5, chromium in the range of 11 to 17.2, molybdenum up to 1.5, nickel up to 6.0, copper up to 4.5, columbium up to 0.45, and nitrogen up to 0.10, the remainder being iron and impurities resulting from the melting conditions, wherein a chromium equivalent defined as the sum of % chromium+% molybdenum+1.5.times.% silicon.times.0.5.times.% columbium has a value smaller than or equal to 17.2, a nickel equivalent defined as the sum of % nickel+0.5.times.% manganese+30.times.% carbon+20.times.% nitrogen has a value greater than or equal to 4.65 the chromium equivalent to nickel equivalent ratio has a value smaller than or equal to 3.0 and the ferrite content is smaller or equal to 5%. The pressure plate is provided with a uniformly structured working surface by chemical or electrochemical etching.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: January 14, 1986
    Assignee: Vereinigte Edelstahlwerke Aktiengesellschaft
    Inventors: Werner J. Jerlich, Hans Kaiserfeld, Alfred Kugler
  • Patent number: 4558202
    Abstract: For making defect-free welds for joining two austenitic stainless steel mers, using gas tungsten-arc welding, a thin foil-like iron member is placed between the two steel members to be joined, prior to making the weld, with the foil-like iron member having a higher melting point than the stainless steel members. When the weld is formed, there results a weld nugget comprising melted and then solidified portions of the joined members with small portions of the foil-like iron member projecting into the solidified weld nugget. The portions of the weld nugget proximate the small portions of the foil-like iron member which project into the weld nugget are relatively rich in iron. This causes these iron-rich nugget portions to display substantial delta ferrite during solidification of the weld nugget which eliminates weld defects which could otherwise occur.
    Type: Grant
    Filed: August 17, 1983
    Date of Patent: December 10, 1985
    Assignee: The United States of America as represented by the Department of Energy
    Inventors: Christopher Bagnall, Marvin A. McBride
  • Patent number: 4536455
    Abstract: A centrifugally cast double-layer tube with resistance to carbon deposition, comprising an inner layer of a specific metallic material containing 1-10 wt % of Al and an outer layer of a heat resisting metallic material, can be applied to apparatuses for treating a fluid, containing hydrocarbons, their derivatives, or carbon monoxide, at elevated temperatures and to piping for transferring the fluid without carbon deposition on its inside surface, because the surface of said inner layer is oxidized to form a firm Al-containing oxide film prior to and/or during the treatment of the fluid, and also a sufficient strength and ductility of the tube are preserved by the support of the outer layer of said tube.
    Type: Grant
    Filed: July 26, 1983
    Date of Patent: August 20, 1985
    Assignees: JGC Corporation, Taihei Kinzoku Kogyo Co., Ltd.
    Inventors: Keikichi Maeda, Takahiro Iijima, Eiichi Sato
  • Patent number: 4532191
    Abstract: A high temperature oxidation resistant alloy of MCrAlY, where M is a base metal comprising iron, cobalt, nickel or a combination thereof, is formed by laser cladding of a coating layer to a substrate.
    Type: Grant
    Filed: June 27, 1984
    Date of Patent: July 30, 1985
    Assignee: Exxon Research and Engineering Co.
    Inventors: Michael J. Humphries, Chih-an Liu, Richard C. Krutenat
  • Patent number: 4529669
    Abstract: A welded structure for use at very low temperatures having structural metallic members of austenitic stainless steel welded with a welding material of austenitic stainless steel. The oxygen content of the portion of the deposited metal where there is no dilution with the material of the structural metallic member is not greater than 0.06 wt %. The structural metallic members and the deposited metal have chemical compositions consisting essentially of 0.01 to 0.1 wt % of C, 0.05 to 1 wt % of Si, 1 to 10 wt % of Mn, 8 to 20 wt % of Ni, 16 to 22 wt % of Cr and the balance substantially Fe and have a fully austenite structure. The Ni equivalent of the deposited metal ranges between 17 and 22. The welded structure for use at very low temperatures can be used, for example, as the container for the magnet of a superconducting generator rotor.
    Type: Grant
    Filed: September 15, 1983
    Date of Patent: July 16, 1985
    Assignee: Hitachi, Ltd.
    Inventor: Takanobu Mori
  • Patent number: 4522890
    Abstract: A composite structure of thin films including alternating layers of relatively high conductivity metals and low conductivity metals to combine the effects of reflection and absorption and thereby maximize the attenuation of the structure. Additionally, a similar structure of layers of materials with differing magnetic permeabilities may be used for the same purpose.
    Type: Grant
    Filed: October 11, 1983
    Date of Patent: June 11, 1985
    Assignee: Illinois Tool Works Inc.
    Inventors: Jack C. Volkers, William R. Conley
  • Patent number: 4515870
    Abstract: Hardfacing of metal parts employing a thin, homogeneous ductile foil is disclosed. The hardfacing foil has a composition consisting essentially of about 0 to about 25 atom percent cobalt, 0 to about 30 atom percent nickel, 0 to about 30 atom percent chromium, 0 to about 5 atom percent tungsten, 0 to about 4 atom percent molybdenum, about 2 to about 25 atom percent boron, 0 to about 15 atom percent silicon, and 0 to about 5 atom percent carbon, the balance being iron and incidental impurities with the proviso that the total or iron, cobalt, nickel, chromium, tungsten and molybdenum ranges from about 70 to 88 atom percent and the total of boron, silicon and carbon ranges from about 12 to 30 atom percent. The ductile foil permits continuous hardfacing of soft matrix, like low carbon and low alloy steels, imparting superior resistance to wear and corrosion.
    Type: Grant
    Filed: September 19, 1984
    Date of Patent: May 7, 1985
    Assignee: Allied Corporation
    Inventors: Debasis Bose, Amitava Datta, Nicholas J. DeCristofaro, Claude Henschel
  • Patent number: 4514470
    Abstract: Disclosed is a novel three-layered metallic interlayer material which provides good diffusion bonding between titanium alloys and steel or between titanium alloys and nickel alloys. The interlayer is comprised of three separate layers of metals as follows: a nickel layer which is placed in contact with the steel or nickel alloys, a Group V-B metal layer which is placed in contact with the titanium alloy and a copper layer which is sandwiched between the nickel and the Group V-B metal layers.
    Type: Grant
    Filed: November 22, 1982
    Date of Patent: April 30, 1985
    Assignee: Avco Corporation
    Inventors: Dan G. Rosenthal, Louis J. Fiedler
  • Patent number: 4507366
    Abstract: The object of the invention is to improve the performance of the rolls of roughing and finishing stands of a hot strip train or mill and in particular to retard as far as possible the banding phenomenon, namely the phenomenon of the incrusting of hard oxides or scale formed at the conventional rolling temperatures.For this purpose, the roll is made, at least in the working region thereof, from a chrome steel in which the ratio between the respective contents of chromium and carbon is between 7 and 12 and in which the content of equivalent carbon is between 1.5 and 1.7%. This content of equivalent carbon is calculated as the sum of the content of carbon and the content of chromium, the latter being given a coefficient 0.05.
    Type: Grant
    Filed: April 29, 1983
    Date of Patent: March 26, 1985
    Assignee: Union Siderurgique du Nord et de l'est de la France
    Inventors: Jean C. Werquin, Bernard Mercier
  • Patent number: 4504553
    Abstract: An infrared radiation reflecting substrate, having deposited thereon a first layer formed from a metal or an alloy, and a second layer deposited on the first layer and consisting of a solar radiation absorbing amorphous material, such as amorphous carbon. The substrate can be formed from an infrared radiation reflecting layer deposited on a primary substrate.
    Type: Grant
    Filed: March 30, 1983
    Date of Patent: March 12, 1985
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Andre Aubert, Jean Valignat, Christophe Wyon
  • Patent number: 4499158
    Abstract: A welded structural member adapted to be subjected to a flowing fluid and comprising a base member consisting mainly of iron and a coating layer formed by a build-up welding on the surface of the base member, the coating layer having a higher erosion resistance than the base member. The coating layer contains 0.03 to 0.4 wt % of C, 0.1 to 1 wt % of Si, 0.5 to 20 wt % of Mn, 1 to 5.5 wt %, of Ni, 1 to 12 wt % of Co, 8 to 23 wt % of Cr and the balance Fe. The structure of the coating layer is mainly unstable austenite.
    Type: Grant
    Filed: February 15, 1983
    Date of Patent: February 12, 1985
    Assignee: Hitachi, Ltd.
    Inventors: Tsutomu Onuma, Fumio Hataya
  • Patent number: 4482612
    Abstract: A roll of which surface cracks are hardly caused under the condition of repetitive heating and cooling. A roll comprises that the alloy consisting of no more than 0.10 percent by weight of carbon, 10.about.14 percent by weight of chromium, 0.1.about.1.0 percent by weight of molybdenum, 0.5.about.2.0 percent by weight of cobalt and essentially balanced iron is coated on the surface of a roll body consisting of low alloy or carbon steel by build-up welding.Therefore, build-up welding layer of the above-mentioned compositions excel in view of resistance to corrosion, and that fact is related with a long-life of a roll.
    Type: Grant
    Filed: August 13, 1982
    Date of Patent: November 13, 1984
    Assignee: Kuroki Kogyosho Co., Ltd.
    Inventors: Hironori Kuroki, Tsuguo Honda
  • Patent number: 4480016
    Abstract: Metal parts are brazed by means of an amorphous filler metal foil. The brazing foil, useful for brazing stainless steels, has a composition consisting essentially of about 0-10 atom percent iron, about 0-20 atom percent chromium, about 3-5 atom percent molybdenum, about 5-35 atom percent cobalt, about 14-19 atom percent boron and the balance nickel and incidental impurities. The ductile foil permits fabrication of preforms of complex shapes which do not require binders and/or fluxes necessary for brazing powders presently used to braze stainless steels and nickel base alloys, and exhibits excellent braze-metal and high-temperature strengths.
    Type: Grant
    Filed: September 27, 1982
    Date of Patent: October 30, 1984
    Assignee: Allied Corporation
    Inventor: Claude Henschel
  • Patent number: 4477538
    Abstract: A coating for nickel/cobalt base alloys used in gas turbine constructions comprises a platinum metal underlayer, an intermediate MCrAlY layer, and a platinum metal overlayer. The platinum type metal is selected from the group consisting of platinum, rhodium, palladium and/or iridium. The MCrAlY material consists of yttrium (Y), aluminum (Al), chromium (Cr) and a balance represented by the letter (M) and selected from the group cobalt, iron and nickel.
    Type: Grant
    Filed: February 17, 1981
    Date of Patent: October 16, 1984
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Robert L. Clarke
  • Patent number: 4456483
    Abstract: A ferritic stainless steel characterized by superior toughness both prior to and after welding, and by superior crevice and integranular corrosion resistance. The steel consists essentially of, by weight, up to 0.08% carbon, up to 0.06% nitrogen, from 25.00 to 35.00% chromium, from 3.60 to 5.60% molybdenum, up to 2.00% manganese, between 2.00 and 5.00% nickel, up to 2.00% silicon, up to 0.5% aluminum, up to 2.00% of elements from the group consisting of titanium, zirconium and columbium, balance essentially iron. The sum of carbon plus nitrogen is in excess of 0.0275%. Titanium, zirconium and columbium are in accordance with the following equation:%Ti/6+%Zr/7+%Cb/8.gtoreq.
    Type: Grant
    Filed: June 8, 1982
    Date of Patent: June 26, 1984
    Assignee: Allegheny Ludlum Steel Corporation
    Inventors: Harry E. Deverell, Thomas H. McCunn
  • Patent number: 4456482
    Abstract: A ferritic stainless steel characterized by superior crevice and intergranular corrosion resistance. The steel consists essentially of, by weight, up to 0.08% carbon, up to 0.06% nitrogen, from 25.00 to 35.00% chromium, from 3.60 to 5.60% molybdenum, up to 2.00% manganese, up to 2.00% nickel, up to 2.00% silicon, up to 0.5% aluminum, up to 2.00% of elements from the group consisting of titanium, zirconium and columbium, balance essentially iron. The sum of carbon plus nitrogen is in excess of 0.0275%. Titanium, zirconium and columbium, are in accordance with the following equation:%Ti/6+%Zr/7+%Cb/8.gtoreq.
    Type: Grant
    Filed: June 8, 1982
    Date of Patent: June 26, 1984
    Assignee: Allegheny Ludlum Steel Corporation
    Inventors: Thomas J. Nichol, Thomas H. McCunn
  • Patent number: 4443406
    Abstract: A heat-resistant and corrosion-resistant weld metal alloy consisting essentially of, by weight, less than 0.08% of C, 0.1 to 1.0% of Si, 2 to 3% of Mn, 32 to 42% of Ni, 21 to 25% of Cr, 0.8 to 1.7% of Mo, 0.1 to 1.0% of Nb, up to 0.5% of Ti, up to 2% of Co, up to 2% of Cu, up to 1% of W, up to 0.2% of N, up to 1.0% of V, up to 1.0% of Zr, up to 1.0% of Ta and the balance Fe, wherein the following conditions are met: Ti+Zr.ltoreq.1.0%, Ni+Co.ltoreq.42%, W+V.ltoreq.1.0%, Nb+Ta.ltoreq.1.0%, and 4.ltoreq.Nb/C.ltoreq.15; and an austenitic welded structure composed of an austenitic structural alloy and of a weld metal of the above-mentioned kind are provided by the invention.
    Type: Grant
    Filed: May 24, 1982
    Date of Patent: April 17, 1984
    Assignees: Hitachi, Ltd., Babcock-Hitachi Kabushiki Kaisha
    Inventors: Masayuki Sukekawa, Yoshimitsu Tobita, Seishin Kirihara, Hisashi Morimoto, Kenichi Usami, Katsumi Iijima
  • Patent number: 4437926
    Abstract: Metal alloy having high catalytic activity. It comprises a refractory base metal mass containing carbon and at least one metal of the platinum type, the surface of which has been subjected to intergranular acid corrosion which produces microfissures and causes the formation of microcrystals of the platinum metals.Application in exhaust catalytic converters.The present invention relates to refractory metallic alloys exhibiting a high catalytic activity which are particularly useful for reducing exhaust gas pollution from automobiles.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: March 20, 1984
    Assignee: Regie Nationale des Usines Renault
    Inventor: Jean-Louis Barnabe
  • Patent number: 4436791
    Abstract: The composite bimetallic roll for cold rolling obtained by casting comprises a heart metal constituted by a nodular or lamellar cast iron and a case metal constituted by a steel having a chromium content of 8 to 16% and a carbon content of 0.65 to 0.95%. The chromium/carbon ratio is between 11 and 16 and the structure of the case metal is martensitic with a content of residual austenite of less than 10%.
    Type: Grant
    Filed: October 29, 1981
    Date of Patent: March 13, 1984
    Assignee: Union Siderurgique du Nord et de l'Est de la France
    Inventors: Jacques Bocquet, Jean C. Werquin
  • Patent number: 4417097
    Abstract: A low porosity coating comprised of at least two layers of material or composites capable of protecting a metal substrate from the corrosive effects of a chlorine-metal chloride environment at temperature values ranging up to 650.degree. C. The first of the two layers has a coefficient of thermal expansion that lies between the metal of the substrate and that of a metal oxide(s) layer disposed upon the first layer. A layer of metal oxide is disposed on the first layer, the metal oxide having a coefficient of expansion somewhat less than the first layer and a minimum solubility in the chlorine-chloride environment. The material or composite of the first layer and the metal oxide of the oxide layer are applied by a technique which sprays particles of the material or composite and metal oxide(s) against a surface at relatively high velocities and temperatures.
    Type: Grant
    Filed: June 4, 1981
    Date of Patent: November 22, 1983
    Assignee: Aluminum Company of America
    Inventor: Subodh K. Das
  • Patent number: 4414286
    Abstract: A composite thermostat metal having layers of metal of relatively high and relatively low coefficients of thermal expansion metallurgically bonded together has a relatively thin, corrosion-resistant layer of an austenitic stainless steel metallurgically bonded to the low expansion side of the thermostat metal, the stainless steel material being selected from the group consisting of austenitic stainless steels which undergo austenite to martensite transformation and concomitant lowering of coefficient of thermal expansion during work hardening. The stainless steel material is work hardened to a selected extent for lowering its coefficient of thermal expansion so that it cooperates with the other components of the thermostat metal in providing the thermostat metal with suitably high flexivity while also providing improved corrosion-resistance properties on the low expansion side of the thermostat metal.
    Type: Grant
    Filed: May 26, 1981
    Date of Patent: November 8, 1983
    Assignee: Texas Instruments Incorporated
    Inventor: Henry Ty
  • Patent number: 4409296
    Abstract: A rapidly quenced, cast metallic strip is disclosed comprising a plurality of dissimilar portions, each portion metallurgically alloy-bonded during casting to adjacent portions along the longitudinal extent of the strip. In the method and apparatus for producing such strip a stream of molten metal is delivered onto a casting surface from a first crucible and at least one additional dissimilar stream of molten metal is delivered onto the casting surface such that a peripheral edge of the dissimilar stream contacts a peripheral edge portion of adjacent dissimilar metal to create a metallurgical alloy-bond therebetween during casting.
    Type: Grant
    Filed: October 22, 1980
    Date of Patent: October 11, 1983
    Assignee: Allegheny Ludlum Steel Corporation
    Inventor: Brian L. Ward
  • Patent number: 4399611
    Abstract: A decorative metal article of manufacture and the process of making it including assembling alternate layers of steel and brazing alloys, heating them while in intimate contact, then removing portions of the layers leaving elevated portions adjacent to depressed portions, and then subjecting the structure to compression to compress the elevated portions to the level of the depressed portion, and finally polishing the article.
    Type: Grant
    Filed: November 10, 1980
    Date of Patent: August 23, 1983
    Inventor: Thomas E. Maringer
  • Patent number: 4383004
    Abstract: A thermocouple bimetal of the type made from a metallic component of high thermal expansion which is bonded to a component of low thermal expansion and in which said component of low thermal expansion consists of a thermally age-hardenable iron-nickel-titanium alloy with 26 to 55% nickel, 1-5% free titanium, 0-16% cobalt, remainder iron including impurities conditioned by the melt, and said component of high thermal expansion consists of a thermally age-hardenable iron-nickel-manganese-titanium alloy with 14-26% nickel, 3-10% manganese, 1-5% free titanium, remainder iron including impurities conditioned by the melt. An advantageous method of producing such a bimetal is also described.
    Type: Grant
    Filed: April 17, 1981
    Date of Patent: May 10, 1983
    Assignee: G. Rau GmbH & Co.
    Inventor: Heinz Spengler
  • Patent number: 4371589
    Abstract: An article of improved wear characteristics and composed of a relatively low wear resistant base metal coated by a particulate refractory metal having a melting point of at least 1490.degree. C. deposited within the near-surface region thereof comprising a base metal or alloy of relatively low wear resistance, a refractory metal deposited within said near-surface region, said refractory metal being selectively deposited in the form of discrete particles, and the particles being idiomorphic or blocky or equiaxial or spheroidal or acicular or dendritic and a plurality of these particles having dimensions of less than 10 micrometers, a plurality of the particles being contiguous to form clusters of the particles that are spaced from each other. The clusters of particles may form microscopic regions of refractory metal which in turn may produce macroscopic regions of refractory metal having the appearance of a continuous coating.
    Type: Grant
    Filed: April 20, 1979
    Date of Patent: February 1, 1983
    Assignee: Warner London Inc.
    Inventors: Joshua B. Warner, James S. Wolf
  • Patent number: 4366210
    Abstract: Thermostat metals combining properties of relatively high flexivity and good corrosion resistance are prepared by metalurgically bonding a corrosion resistant high expansive alloy (1) to a less corrosion resistant low expansive alloy (2) and capping the low expansive alloy (2) with a corrosion resistant, moderately low expansive alloy (3) of similar hardness to that of the low expansive alloy (2).The preferred high expansive alloy (1) is comprised of about 18 wt. % Ni; 11 wt. % Cr; and balance Fe.The preferred low expansive alloy (2) is Invar (36 wt. % Ni; balance Fe).The preferred corrosion resistant low expansive alloy (3) is comprised of about 20 wt. % Ni; 26 wt. % Co; 7 wt. % Cr; balance Fe.The preferred volumetric ratios of the metals is about 50% of the high expansive alloy (1), 30 to 40% of the low expansive metal (2) and 10 to 20% of the corrosion resistant low expansive alloy.
    Type: Grant
    Filed: November 14, 1980
    Date of Patent: December 28, 1982
    Assignee: Hood and Co., Inc.
    Inventors: Stanley M. Golemo, Jr., Anthony J. Izbicki
  • Patent number: 4326011
    Abstract: A coated article and method for producing the coated article are described. The article is provided with a coating system which provides protection against hot corrosion at moderate temperatures (1200.degree.-1700.degree. F.). An overlay coating based on a metal selected from the group consisting of iron, nickel or cobalt or mixtures thereof and containing chromium and optionally aluminum, yttrium and/or hafnium is applied to the article to be protected. A silicon rich surface zone is produced at the surface of the overlay coating. Methods including pack cementation and physical vapor deposition are described for producing the coating.
    Type: Grant
    Filed: February 11, 1980
    Date of Patent: April 20, 1982
    Assignee: United Technologies Corporation
    Inventors: Joseph A. Goebel, Richard H. Barkalow, Nicholas E. Ulion
  • Patent number: 4318966
    Abstract: Compensation is provided in a welded structure formed from dissimilar metals e.g. carbon steel and stainless steel for knife-line corrosion occurring at the interface between the dissimilar metals by making the length of the path along which knife-line corrosion is liable to occur between the metals towards the load bearing area of the weld exceed the expected extent of knife-line corrosion over the design life of the structure. The interface exposed to the corrosive environment may be displaced from the load bearing region of the weld by providing a layer of metal e.g. the weld metal over, and fused to the surface of the one of the components with which the metal of the layer forms a knife-line corrodable combination. That surface may include the surface of an appendage integral with or welded to the component.
    Type: Grant
    Filed: March 31, 1980
    Date of Patent: March 9, 1982
    Assignee: Imperial Chemical Industries Limited
    Inventor: Richard Fawcett
  • Patent number: 4314007
    Abstract: A composite shaped article comprising at least one reinforcing core of a heat-resistant oxide-dispersion-hardened metal or alloy and a cladding of a heat-resistant metal or alloy which is compatible with the core material, the core being wholly encapsulated within and bonded to the cladding material.A method for making the articles is provided.
    Type: Grant
    Filed: August 6, 1979
    Date of Patent: February 2, 1982
    Assignee: BBC Brown, Boveri & Company Limited
    Inventor: Gernot Gessinger
  • Patent number: 4292208
    Abstract: Diffusion coating a substrate metal with a different metal, such as aluminum and zinc, that is then chemically removed from the coated substrate, provides the residual metal with a very desirable catalytic surface. At least about a third of the removable metal can be dissolved out. Platinum wire screens activated in this way make effective exhaust catalysts for automotive engines. Chromium-rich coating for protective purposes can be applied on a superalloy, diffusion coating in a pack that in addition to the chromium to be diffused, also contains at least about 3% Ni.sub.3 Al. Also the formation of alpha-chromium is reduced when the pack diffusion is carried out in a retort effectively not over five inches in height. Pack aluminizing in the presence of chromium makes a very effective aluminum- and chromium-containing top coating over platinum plated or platinum coated nickel-base superalloys.
    Type: Grant
    Filed: January 3, 1979
    Date of Patent: September 29, 1981
    Assignee: Alloy Surfaces Company, Inc.
    Inventors: Alfonso L. Baldi, Victor V. Damiano
  • Patent number: 4273159
    Abstract: A box tool joint member of generally tubular configuration is adapted for securement by welding to one end of a steel tube to form a drill pipe. The box tool joint member comprises a body having a cylindrical outer periphery, an internally threaded socket at one end of the body, and a weld neck of smaller outer diameter than the body adjacent to the other end of the body. A tapered transition piece connecting the neck with the adjacent end of the body provides an elevator shoulder. A correlative pin tool joint member is welded to the opposite end of the tube to complete the drill pipe.The box tool joint member has an annular band of hard facing over the outer periphery of the transition piece and extending down over the adjacent part of the weld neck and up around the adjacent part of the body. The hard facing is corrosion resistant and has a smooth finished surface. Underneath the hard facing and extending beyond both ends of the hard facing is an annular butter layer of non-hardenable steel.
    Type: Grant
    Filed: March 16, 1978
    Date of Patent: June 16, 1981
    Assignee: Smith International, Inc.
    Inventors: Jimmie B. Bolton, Sam T. Crews