Abstract: A corrosion-resistant architectural material which is essentially lead free and is not highly reflective. The coating on the material is a two-phase metallic coating comprised of zinc and tin. The tin-zinc coating may also include aluminum, antimony, bismuth, copper, magnesium, nickel and/or titanium to improve the coating process and/or improve the properties of the tin-zinc coating.

Abstract: A corrosion-resistant metal strip and method for making the same which is essentially lead free and is not highly reflective. The coating on the metal strip is a metallic coating comprised of tin and a very low weight percentage of lead. The coating alloy may also include antimony, bismuth, copper, zinc to improve the coating process and/or improve the properties of the tin coating. A metal layer may also applied to the surface of the metal strip prior to applying the metallic alloy coating.

Abstract: A magnetic recording medium having two magnetic layers is disclosed. The magnetic recording medium has a surface fatty acid content of 0.38 to 2.53 .mu.g per square centimeter and a magnetic layer closest to a support contains ferromagnetic powder of Co-containing FeOx wherein x represents 1.33 to 1.43. It is improved in electromagnetic conversion characteristics, light-shielding property and erasing property, and is suitably used for audio or video recording medium.

Abstract: Various metal coatings have been used for many years to inhibit oxidation of metals exposed to the natural elements of the atmosphere over a period of time. Terne alloy coatings which normally contain about 20% tin and about 80% lead are some of the most popular metal coating treatments to resist corrosion. The special formulation of the present invention reformulates the terne coating to constitute a tin and lead based coating where tin constitutes at least 90% of the terne and lead amounts to less than 0.1% and preferably less than 0.05% of the terne. The low lead terne coating may also include antimony and bismuth to provide strength and hardness to the low lead terne formulation having corrosion resistive qualities similar to that of standard terne coating formulations.

Abstract: A corrosion-resistant colored architectural material which is essentially lead free and is not highly reflective. The coating on the material is a two-phase metallic coating comprised of a large weight percentage of zinc and a relatively large weight percentage of tin. The tin-zinc composition provides for both a highly corrosive-resistant coating which protects the surface of the architectural material from oxidation and also produces a gray, earth tone colored which is not highly reflective.

Abstract: There is disclosed a multi-layer sliding member having a back metal and a Cu--Zn-based alloy layer bonded to the back metal with a sufficiently high bonding strength. A method of producing such a sliding member is also disclosed. The multi-layer includes a back metal, a brazing material bonded to the back metal, a diffusion mixture layer bonded to the brazing material, and a Cu--Zn-based alloy layer bonded to the diffusion mixture layer. The diffusion mixture layer is a layer in which not less than 10 wt. % Ni, components of the Cu--Zn-based alloy and components of the brazing material are mixed with one another. The diffusion mixture layer has a thickness of 5.about.300 .mu.m.

Abstract: A corrosion-resistant, environmentally-safe gasoline tank for motor vehicles, wherein the components of the gasoline tank are made of a metal material having a hot-dipped coating of zinc-tin applied to the exposed surfaces of the metal material. The tin-zinc coating includes at least 15 weight percent tin and at least 7 weight percent zinc. The tin-zinc alloy may also include metal additives such as nickel, antimony and/or bismuth.

Abstract: An improved cast grate cooler side plate having a bottom surface containing a metal alloy insert embedded therein wherein said insert is formed from an alloy selected from the group consisting of:A. an alloy consisting essentially of, by weight,______________________________________ Carbon about 1.5-3% Chromium about 23-30% Manganese <2.5% Silicon <2.5% Nickel up to about 3% Molybdenum up to about 3% Iron essentially the balance ______________________________________B. an alloy consisting essentially of, by weight, ______________________________________ Carbon about 2.5-3.6% Chromium about 1.4-3.5% Manganese about 0.4-0.7% Silicon about 0.4-0.7% Nickel about 4.0-4.75% Iron essentially the balance ______________________________________andC. an alloy consisting essentially of, by weight, ______________________________________ Carbon about 0.25-1.6% Chromium about 3-12% Manganese <1.5% Silicon <1.5% Molybdenum <2% Vanadium <1.

Abstract: A composite roll for hot rolling wherein the outer layer portion of a composite roll comprises a steel comprised of, in terms of % by weight, 1.5 to 2.4% of C, 3 to 6% of V and 10 to 20% of at least one element selected from the group consisting of Cr, Mo and W and optionally at least one element of 0.05 to 0.20% of Al and 0.02 to 0.10% of Ti as an inoculation material, with the balance comprising Fe and unavoidable impurities, the outer layer portion comprising a metallic structure which has a crystal grain diameter of 30 to 150 .mu.m and is surrounded by a eutectic carbide crystallized in the grain boundary or a metallic structure wherein a primary crystallized carbide is further dispersed and crystallized in a matrix structure of the crystal. It is excellent particularly in the surface roughening resistance.

Abstract: The present invention aims to prevent the occurrence of flaws in an Fe-Cr-Al alloy steel sheet, thereby improving the yield. In the present invention, a cast slab comprising an outer layer and an inner layer with the concentration of at least one element selected from Cr, Al and REM (REM being at least one element selected from the group consisting of rare earth elements including Y of lanthanoids) in the outer layer being 70% or less of that of the inner layer, is provided, heated, hot-rolled and cold-rolled to produce a steel sheet or a foil material.

Abstract: A corrosion-resistant colored architectural material which is essentially lead free and is not highly reflective. The coating on the material is a two-phase metallic coating comprised of a large weight percentage of zinc and a relatively large weight percentage of tin. The tin-zinc composition provides for both a highly corrosive-resistant coating which protects the surface of the architectural material from oxidation and also produces a gray, earth tone colored which is not highly reflective.

Abstract: A colored, corrosion resistant architectural material having improved corrosion-resistant properties wherein the material includes stainless steel which is coated with a tin and the tin coated material is post-treated with an oxidizing solution to remove the tin coating to expose a barrier which includes an alloy of chromium, iron and tin. The barrier exhibits excellent corrosion resistance especially with respect to chlorine and has a dark grey or earth tone grey color.

Abstract: Various metal coatings have been used for many years to inhibit oxidation of metals exposed to the natural elements of the atmosphere over a period of time. Terne alloy coatings which normally contain about 20% tin and about 80% lead are some of the most popular metal coating treatments to resist corrosion. The special formulation of the present invention reformulates the terne coating to constitute a tin and lead based coating where tin constitutes at least 90% of the terne and lead amounts to less than 0.1% and preferably less than 0.05% of the terne. The low lead terne coating may also include antimony and bismuth to provide strength and hardness to the low lead terne formulation having corrosion resistive qualities similar to that of standard terne coating formulations.

Abstract: A weather-resistant strip roofing material having improved corrosion-resistant properties includes a strip of stainless steel which is pre-treated by an aggressive pickling process and/or a chemical activating process prior to applying a hot-dip tin coating, The pre-treatment of the stainless steel strip produces superior alloying between the stainless steel and the tin coating which reduces flaking of the tin coating.

Abstract: The clad sheet comprises a first layer or cladding of an iron-base or nickel-base alloy including at least 11% chromium and at least 17% nickel and resisting corrosion by very corrosive mediums such as acids, and a second layer or base of austenitic stainless steel including at least 11% chromium and at the most 17% nickel resisting atmospheric corrosion. The clad sheets may be cold re-rolled down to a thickness of 2 mm.

Abstract: A pressure-bonded composite material includes at least one layer of a stabilized low carbon steel core material and one layer of a stainless steel joined at an interface, wherein the stabilized carbon steel includes columbium (niobium) and at least one other carbide-forming element in amounts effective to prevent carbon migration from the carbon steel to the stainless steel and the composite material has a physical grain size no larger than ASTM #6.

Abstract: Avoidance of the corrosion initiation sites consisting of Mn particles deposited on the TiG welded inner tube surface is achieved through suppression of emission of manganese fumes by addition of a protective non corrosive metallic layer. The latter melts during the welding and arises in a non-corrosive internal metallic coating of the welded zone.

Abstract: Raw sheet metal substrate (36) passing through an extrusion die (54) is partially laminated with a thin film of plastic (40). A boundary line (42) is formed between the laminated and unlaminated portions of the substrate (36). The sheet metal substrate (36) is folded upon itself so that the plastic laminate (40) bears in pressing relation against the unlaminated portion of the substrate (36) to create a fold (44) sealed against lateral moisture penetration. The unlaminated portion of the substrate (36) may be chrome plated (50). The extrusion die (54) includes an adjustable die member (64) and an adjustable wear plate (78). Alternatively, the extrusion die (54) may include an adjustable extrusion orifice (62) for varying the thickness of the plastic extruded onto the sheet metal substrate (36). Two sheet metal substrates (36') are moved through the extrusion die (54') simultaneously and in back-to-back relation to neutralize reaction forces from the respective emissions of pressurized plastic.

Abstract: Disclosed herein is an endoscopic extraction device which retains its operative usefulness for longer periods of time, and therefore need to be replaced less frequently. This extended instrument life is accomplished through the use of a composite wire construction, which includes, an inner monofilament wire of nitinol material surrounded by six stranded stainless steel wires. A wire construction in which a nitinol wire is surrounded by five stranded stainless steel wires is also disclosed. After constructing a wire basket in the normal manner using this material, heat is applied to the formed basket in its pre-formed shape to set the memory characteristics of the inner nitinol core.

Abstract: A composite tube with improved resistance to thermal fatigue and stress corrosion for use in soda recovery units comprising an inner tubing of a conventional carbon steel and an outer liner of a Cr--Ni--Mo--Fe-based alloy with austenitic structure which alloy contains, in weight-%, 0.01-0.04 C, 19.5-23.5 Cr, 38-46 Ni, 2.5-3.5 Mo, up to 0.5 Si, up to 0.3N, and the remainder being Fe, except normal impurities.

Abstract: Various metal coatings have been used for many years to inhibit oxidation of metals exposed to the natural elements of the atmosphere over a period of time. Terne alloy coatings which normally contain about 20% tin and about 80% lead are some of the most popular metal coating treatments to resist corrosion. The special formulation of the present invention reformulates the terne coating to constitute a tin and lead based coating where tin constitutes at least 90% of the terne and lead amounts to less than 0.1% and preferably less than 0.05% of the terne. The low lead terne coating may also include antimony and bismuth to provide strength and hardness to the low lead terne formulation having corrosion resistive qualities similar to that of standard terne coating formulations.

Abstract: Line pipe having good corrosion-resistance and weldability, in which at least the inner surface of the pipe that is in direct contact with the fluid moved through the pipe is formed of high chromium steel that contains, by weight percent, 7.5 to 16 percent chromium, a carbon content reduced to no more than 0.03 percent and a nitrogen content reduced to no more than 0.02 percent, and a substrate that is not in direct contact with the fluid and is formed of steel that contains 0.02 to 0.25 percent carbon, 0.1 to 1.0 percent silicon, 0.05 to 2.0 percent manganese and 0.005 to 0.1 percent aluminum, a phosphorus impurity content reduced to no more than 0.015 percent and a sulfur impurity content reduced to no more than 0.005 percent, and in which the thickness of the high chromium steel portion does not exceed 25 percent of the total thickness of the pipe.

Abstract: A composite roll including a metal core and a hard face formed from a steel composition including the elements carbon, manganese, silicon, chromium, molybdenum, niobium, vanadium and iron in specified amounts, as well as incidental impurities. The composition may optionally further include tungsten, nickel, tantalum and/or titanium. The composite roll may further comprise a buffer layer.

Abstract: In a process for forming a solid lubricating film on an iron-base substrate, an organic material having a vapor pressure of 10.sup.-4 Torr or less at room temperature is deposited on an iron-base alloy substrate in a vacuum atmosphere in a vacuum degree of 10.sup.-4 Torr or more, and simultaneously ions of a metal element having a chemical affinity to carbon is irradiated on the iron-base alloy substrate at a dose of 1.times.10.sup.16 ions/cm.sup.2 or more, the ions having an energy of 5 keV or more. Accordingly, the iron-base substrate is coated with a solid lubricating film which includes an atom mixture layer including carbide of the metal element and alloy of iron and the metal element and a carbon layer including amorphous carbon. Hence, the solid lubricating film has an excellent lubricating property as well as a high adhesion property to the iron-base substrate. Namely, the excellent lubricating property will last for a long period of time.

Abstract: Plating is carried out of a stainless steel sheet whose carbide redissolution temperature is lower than 1000.degree. C. onto an armor steel sheet and the plated sheet obtained is quenched so that the Brinell hardness of the armor steel is between 250 and 700 BH. The plating may be carried out by corolling, explosion plating or explosion plating followed by rerolling. Tempering may be performed at a temperature between 200.degree. and 600.degree. C. on the plated and quenched sheet. The quenching is preferably carried out on an oil quenching machine under a press. The armors obtained comprise a stainless coating layer free from carbide precipitates at the grain boundaries. Storage tanks which resist projectiles and are employed for storing liquid corrosive products can be made from the stainless armors according to the invention.

Abstract: A heat-resistant cast steel having a metal matrix substantially consisting of a ferrite phase and a pearlitic-colony phase has a composition consisting essentially, by weight, of C: 0.05-0.25%, Si:2.5-3.5%, Mn:2% or less, Cr:4-8%, N:0.05% or less, and Fe and inevitable impurities: balance, as well as at least one selected from the group consisting of (i) W and/or Co:0.1-2%, (ii) a rare earth element and/or Y:0.1% or less, (iii) Mg and/or Ca:0.005-0.03%, and (iv) B:0.001-0.01%.

Abstract: The corrosion resistance inherent in stainless steel is further improved by a cladding layer provided on the surface thereof. The cladding layer is formed of a coating material which is applied onto the surface of the stainless steel and, then, burnt to be fused by laser beams. The coating material contains a larger amount of Cr than that of the stainless steel. The thus fused material and a fused portion of the stainless steel are mixed with each other to form the cladding layer of remarkable corrosion resistance due to a larger amount of Cr contained therein. The formation of the cladding layer on the inner surface of a small diameter pipe is enabled by a coating film shaping device which has a jig for shaping the applied material into a film of a uniform thickness and by a laser irradiation torch which has an arrangement for emitting the laser means radially outward from the inside of the pipe.

Abstract: A weld overlaid stainless clad steel for high temperature and high pressure hydrogen service has the improved elevated temperature strength and excellent resistance to hydrogen induced disbonding. The base steel of the clad steel in the invention contains, in weight percent, 0.05% to 0.30% carbon, not more than 1.5% manganese, 0.8% to 5.5% chromium, 0.5% to 1.5% molybdenum and 0.0005% to 0.010% boron, at least one of 0.010% to 0.040% titanium, 0.010% to 0.040% columbium, with the balance of iron and any other incidental impurities.

Abstract: A bimetallic composite back-up cylinder for a rolling mill, in particular for a four-coil or six-roll stand of a hot strip train finisher, comprises a metal envelope made of a steel having a chromium content between 13 and 17 wt. %, and a carbon content between 0.5 and 0.8 wt. % the chromium/carbon ratio being between 20 and 25.

Abstract: A billet is provided for subsequent heating and working into a finished product in, for example, a rolling mill. The billet comprises a mass of swarf jacketed in a tubular jacket. At least one end of the jacket is joined to an end piece which surrounds the end of the mass of swarf. The end piece and the jacket are materials of different composition. In particular, a jacket of stainless steel with mild steel end pieces at each end is envisaged. The end pieces may be open ended sleeves or caps. Where an open ended sleeve is used it may be closed by crimping its end or by the provision of an insert which is welded or crimped into the sleeve. The end of the swarf exposed in the sleeve may also be sealed by application of a graphite paste.

Abstract: Stainless steel sheets are plated with zinc and further phosphated so as to have chromaticness indices of L=45-53, a=0.0-0.4 and b=1.3-4.4. Thus treated stainless steel sheets have sufficient strength, excellent corrosion resistance and a color well harmonizing with other building materials and environment and do not suffer from color change for a prolonged period of time.

Abstract: A bimetallic saw blade or band saw includes a support strip (1) and a tool steel top layer (2) of high speed tool steel and sawteeth (6) in at least the top layer. The support strip is martensitically hardenable maraging steel having a maximum carbon concentration of 0.05 wt. % and a content of alloying elements of at least 10 wt. %.

Abstract: A method of preparing a roughened substrate surface for subsequent coating with a fluorocarbon polymer in a liquid medium. The surface of the substrate is thermally sprayed with a stainless steel alloy containing from 25 to 35 percent by weight of chromium. A metal-coated substrate produced by this method and an article having thereon a fluorocarbon surface coated by this method are also described.

Abstract: Continuously hot dip aluminum coated ferritic chromium alloy steel strip. After the steel has been given a pretreatment to remove surface contaminants, the steel is protected in a hydrogen atmosphere until it is passed into the molten aluminum coating metal. The coating metal readily wets the steel surface to prevent uncoated areas or pin holes in the coating layer.

Abstract: In heat-connection between metal and ceramic, martensite stainless steel or martensite heat-resistant steel which can be hardened a gas or vacuum after having been heated beyond the quenching temperature thereof are used as metal. The heat connection is brazing or shrinkage fit at 800.degree. C. or more. Stress strain caused by a difference in thermal expansion coefficient between the two can be reduced. Further, since the metal can be connected to ceramic while hardening the metal, man-hour can be reduced markedly.

Abstract: To obtain a composite material which has a substantially reduced incidence of defects after forming, there is made a composite having at least one layer of plain-carbon steel and, between it and a layer of stainless steel, an interleaving layer of silicon steel.

Abstract: A method of coating a substrate comprises plasma spraying a prealloyed feed powder onto a substrate, where the prealloyed feed powder comprises a significant amount of an alloy of stainless steel and at least one refractory element selected from the group consisting of titanium, zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. The plasma spraying of such a feed powder is conducted in an oxygen containing atmosphere and forms an adherent, corrosion resistant, and substantially homogenous metallic refractory alloy coating on the substrate.

Abstract: A bimetallic strip or band for manufacturing metal saw blades and metal band saw bands includes a support strip and a tool steel top layer. The top layer is high speed tool steel. The support strip is martensitically hardenable maraging steel having a maximum carbon concentration of 0.05 wt. % and a content of alloying elements of at least 10 wt. %.

Abstract: Chrome-coated stainless steel is provided that has better adhesion, even when it is being shaped, than conventional wet-type plating, and better atmospheric corrosion resistance than bare stainless steel. In addition, the chrome-coated stainless steel, provided by means of physical vapor deposition, also possesses the same color tone and luster as chromium, and thus has superior decorative compatibility with existing wet-type chrome plated parts.

Abstract: Corrosive-resistant, amorphous metal alloy coatings for crystalline metal surfaces wherein the coating is formed by vapor deposition of a mixture of(1) from 8 to 30 atomic percent of boron, silicon, or mixtures thereof and(2) the remainder being a modified metal composition formed by modifying the composition of the crystalline metal of the surface to produce a final amorphous metal alloy coating that is anodic in reference to the crystalline metal of the surface.

Abstract: Composite pipe adapted for use, for example, in line pipes for crude oil or natural gas producing oil wells and having excellent corrosion resistance and mechanical properties to withstand high temperatures and high pressures, the composite pipe having an outer layer made of a material comprising in % by weight 0.05 to 0.20% of C, up to 1.0% of Si, up to 2.0% of Mn, up to 1.0% of Cr, 0.2 to 2.0% of Ni, up to 1.0% of Mo, 0.05 to 0.15% of V, up to 0.1% of Al, and the balance inevitable impurities and Fe, the material being up to 0.45 in carbon equivalent expressed by: ##EQU1## an inner layer made of stainless steel, high alloy steel or like corrosion resistant alloy, and an intermediate layer substantially intermediate between the outer layer and the inner layer in composition and having a thickness of 10 to 100 .mu.m, the intermediate layer providing a boundary between the outer and inner layers and being metallurgically joint to the outer layer and the inner layer integrally therewith.

Abstract: The invention comprises a process for the production of clad hot rolled strip. A steel slab as base material is cladded with a layer material of a corrosion-resistnt material. The slab is of a low-alloy steel having a carbon content of up to 0.25% by weight, the layer material preferably is stainless, more particularly a stainless austenitic steel or a wrought alloy on a nickel basis. The steel slab and the layer material are connected by explosive cladding, the resulting composite body being heated to rolling temperature and is subsequently rolled down to one quarter of the initial thickness with a high reduction of pass of phi greater than 0.10 and then rolled to final thickness of the hot rolled strip. The finish rolling temperature is in the range of 900.degree. C. The clad hot rolled strip is subjected to a cooling rate in the core of at least 8.degree. C./s to a cooling temperature of below 650.degree. C.

Abstract: A clad metal comprising at least one layer of rephosphorized carbon steel metallurgically bonded to at least one layer of stainless steel. In a preferred embodiment the rephosphorized carbon steel layer comprises at least about 0.05 weight percent phosphorus and the stainless steel layer comprises a type 444 stainless steel. A clad metal made in accordance with the present invention may be produced into any one of a variety of shaped, configurations or parts including, for example, slabs, blooms, sheet strip or finished parts. Once the clad metal has been produced by forming a metallurgical bond between the various components thereof, the clad metal may be subjected to further processing including, for example, forging, stamping, rolling, welding, machining, and the like. The invention further provides a unique parting compound for use in the production of clad metals which are clad on only one side. Such parting compound comprises a mixture of levigated alumina and an inert binder.

Abstract: A low coefficient of expansion alloy is coated with a thermal barrier coating having a low coefficient of expansion compatible with the alloy. The alloy, preferably a 900 series iron-base alloy, includes an oxidation resistant intermediate bond coating and a zirconia containing thermal barrier. An article of manufacture made from this material could be utilized in heat engines where close tolerances are mandated.

Abstract: Continuously hot dip aluminum coated ferritic chromium alloy steel strip. After the steel has been given a pretreatment to remove surface contaminants, the steel is protected in a hydrogen atmosphere until it is passed into the molten aluminum coating metal. The coating metal readily wets the steel surface to prevent uncoated areas or pin holes in the coating layer.

Abstract: A wear-resistant metal member comprises a surface that has a sprayed layer consisting essentially of, by weight, 2 to 10% C, 18 to 60% Cr, 0.3 to 20% V, 25% or less Mo, 25% or less W, 10% or less Nb, 10% or less Ti, 10% or less Zr, 10% or less Hf and the balance being Fe in a proportion of 20% or greater. The sprayed layer has a martensite-phase matrix containing carbide particles, nitride particles or carbonitride particles. In addition, the member of the present invention is produced by the steps of: plasma-spraying the above-described metal in a reduced pressure atmosphere; and quenching the thus-sprayed metal layer from a predetermined temperature to form a materisite phase in that layer. In addition, the sprayed metal layer may be subjected to carburizing, nitriding or carbonitriding to form a carburized, nitrided or carbonitrided layer in the sprayed metal layer.

Abstract: A stainless clad plate or sheet (herein called sheet) comprising a super-low carbon steel layer containing at least one of Ti and Nb (Ti+Nb.ltoreq.0.15% and ##EQU1## and an austenite stainless steel layer on one or both sides of the carbon steel layer. The thickness of the stainless steel layer is preferably from 2.5 to 30% of the total thickness of the clad steel sheet. The stainless clad steel sheet is produced preferably by continuous casting stainless steel melt on the carbon steel slab, hot and cold rolling the stainless clad steel slab, and annealing under specific conditions for desired properties.

Abstract: Adherent, thermal shock-resistant protective coatings for nickel base super alloys are obtained by applying to the base metal a thin bond coat of an alloy of chromium aluminum and yttrium with materials selected from the group consisting of iron, cobalt, nickel and nickel-cobalt and applying thereover a continuously graded mixture of this material with a zirconia-based ceramic, the concentration of zirconia-based ceramic increasing from the bond coat to the outer layer. The zirconia ceramic may be stabilized by the addition thereto of amounts of magnesium oxide or other materials.

Abstract: A high precision transfer lamination plate/mandrel is fabricated in a sanch construction design wherein an inner core is constructed of a low coefficient of thermal expansion (CTE) comprised of an iron-nickel alloy core member (e.g., Kovar or Invar) with stainless steel cladding on each side of the core member. The stainless steel is selected from AISI type 302, 304, or 316. The stainless steel cladding outer surface of the top and bottom plate to which an electroplated copper foil circuitry is applied must be free of pits, scratches, and defects so as to yield a continuous circuitry satisfactory for military electronics. A matched (CTE) of the transfer lamination plate/mandrel with a composite material to which the electronic circuitry is transferred results in adherence of the copper circuitry minimally to the plate/mandrel to avoid blistering and enables the transfer to be achieved without distortion of circuitry features due to CTE mismatch.

Abstract: The object of the invention is to improve the performance of the rolls of roughing and finishing stands of a hot strip train or mill and in particular to retard as far as possible the banding phenomenon, namely the phenomenon of the incrusting of hard oxides or scale formed at the convenience rolling temperatures.For this purpose, the roll is made, at least in the working region thereof, from a chrome steel in which the ratio between the respective contents of chromium and carbon is between 7 and 12 and in which the content of equivalent carbon is between 1.5 and 1.7%. This content of equivalent carbon is calculated as the sum of the content of carbon and the content of chromium, the latter being given a coefficient 0.05.