Abstract: A magnesium-ion cell comprising (a) a cathode comprising a carbon or graphitic material as a cathode active material having a surface area to capture and store magnesium thereon, wherein the cathode forms a meso-porous structure having a pore size from 2 nm to 50 nm and a specific surface area greater than 50 m2/g; (b) an anode comprising an anode current collector alone or a combination of an anode current collector and an anode active material; (c) a porous separator disposed between the anode and the cathode; (d) electrolyte in ionic contact with the anode and the cathode; and (e) a magnesium ion source disposed in the anode to obtain an open circuit voltage (OCV) from 0.5 volts to 3.5 volts when the cell is made.
Abstract: A nonaqueous electrolytic solution that can provide a battery that is low in gas generation, has a large capacity, and is excellent in storage characteristics and cycle characteristics.
Abstract: A rechargeable lithium battery is provided. The battery includes an electrolyte including a lithium salt, a non-aqueous organic solvent including an ethylene carbonate-based compound and a pyrocarbonate-based additive; a negative electrode that includes a negative active material including a crystalline-based carbon core and an amorphous-based carbon shell surrounding the crystalline-based carbon core; and a positive electrode comprising a positive active material.
Abstract: A storage battery is provided comprising a positive electrode of vanadium, a negative electrode of zinc, and an electrolyte of potassium hydroxide dissolved in alcohol or glycol. Upon charging, the vanadium oxidizes to vanadium pentoxide and zinc oxide is reduced to the metal. The reverse reactions occur during discharge.
Abstract: An organic electrolytic solution including a lithium salt, an organic solvent, and a linear or cyclic polymerizable monomer that is negatively charged due to localization of electrons on the monomer, and a lithium battery employing the same. Since the organic electrolytic solution prevents decomposition of an electrolyte and elution from or precipitation of metal ions, the lithium battery employing the organic electrolytic solution has excellent lifetime characteristics and cycle characteristics.
Type:
Grant
Filed:
May 7, 2010
Date of Patent:
October 29, 2013
Assignee:
Samsung SDI Co., Ltd.
Inventors:
Dong-joon Lee, Young-gyoon Ryu, Dong-min Im, Seok-soo Lee
Abstract: A positive electrode active material has an average particle diameter of 4.5 to 15.5 ?m and a specific surface area of 0.13 to 0.80 m2/g. A positive electrode mixture layer contains at least one of a silane coupling agent and/or at least one of aluminum, titanium, or zirconium based coupling agent having an alkyl or an alkoxy groups having 1 to 18 carbon atoms at a content of 0.003% by mass or more and 5% by mass or less with respect to the mass of the positive electrode active material. The nonaqueous electrolyte contains a 1,3-dioxane derivative at a content of 0.05% by mass or more with respect to the total mass of the nonaqueous electrolyte. Thus a nonaqueous secondary battery that has good high-temperature cycle characteristics and suppresses an increase in self-discharge after repetition of charge and discharge cycles at high temperature is provided.
Abstract: The present invention relates to non-aqueous electrolytes having stabilization additives and electrochemical devices containing the same. Thus the present invention provides electrolytes containing an alkali metal salt, a polar aprotic solvent, a first additive that is a substituted or unsubstituted organoamine, substituted or unsubstituted alkane, substituted or unsubstituted alkene, or substituted or unsubstituted aryl compound, and/or a second additive that is a metal (chelato)borate. When used in electrochemical devices with, e.g., lithium manganese oxide spinel electrodes, the new electrolytes provide batteries with improved calendar and cycle life.
Type:
Grant
Filed:
May 26, 2011
Date of Patent:
October 8, 2013
Assignee:
Uchicago Argonne, LLC
Inventors:
Khalil Amine, Jaekook Kim, Donald R. Vissers
Abstract: A protected transition metal hexacyanoferrate (TMHCF) battery cathode is presented, made from AxMyFez(CN)n.mH2O particles, where the A cations are either alkali or alkaline-earth cations, and M is a transition metal. In one aspect the cathode passivation layer may be materials such as oxides, simple salts, carbonaceous materials, or polymers that form a film overlying the AxMyFez(CN)n.mH2O particles. In another aspect, the cathode passivation layer is a material such as oxygen, nitrogen, sulfur, fluorine, chlorine, or iodine that interacts with the AxMyFez(CN)n.mH2O particles, to cure defects in the AxMyFez(CN)n.mH2O crystal lattice structure. Also presented are TMHCF battery synthesis methods.
Abstract: A method for cleaning a semiconductor structure includes subjecting a semiconductor structure to an aqueous solution including at least one fluorine compound, and at least one strong acid, the aqueous solution having a pH of less than 1. In one embodiment, the aqueous solution includes water, hydrochloric acid, and hydrofluoric acid at a volumetric ratio of water to hydrochloric acid to hydrofluoric acid of 1000:32.5:1. The aqueous solution may be used to form a contact plug that has better contact resistance and improved critical dimension bias than conventional cleaning solutions.
Abstract: Disclosed is a secondary battery including a cathode, an anode, a separator, and an electrolyte, wherein the electrolyte includes a ternary eutectic mixture prepared by adding (c) a carbonate-based compound to a eutectic mixture containing (a) an amide group-containing compound and (b) an ionizable lithium salt, and the carbonate-based compound is included in an amount of less than 50 parts by weight based on 100 parts by weight of the electrolyte. The use of the disclosed ternary eutectic mixture having flame resistance, chemical stability, high conductivity, and a broad electrochemical window, as the electrolyte material, improves both the thermal stability and quality of the battery.
Type:
Grant
Filed:
April 10, 2008
Date of Patent:
October 1, 2013
Assignee:
LG Chem, Ltd.
Inventors:
Jiwon Park, Jae Seung Oh, Byoung-bae Lee, Shin Jung Choi, Jaeduk Park
Abstract: A secondary battery is disclosed. In one embodiment, the battery includes i) an electrode assembly, ii) an electrolyte, iii) a tape attached to at least part of an outer surface of the electrode assembly and iv) a case accommodating the electrode assembly, electrolyte and tape. The tape includes a base layer, and wherein at least a portion of the base layer is configured to exhibit an adhesive property when contacting the electrolyte so as to contact an inner surface of the case.
Abstract: A method for producing a lithium ion conductive solid electrolyte including the step of bringing one or more compounds selected from phosphorous sulfide, germanium sulfide, silicon sulfide and boron sulfide into contact with lithium sulfide in a hydrocarbon-based solvent.
Abstract: An object is to provide a nonaqueous electrolyte and a nonaqueous-electrolyte secondary battery which have excellent discharge load characteristics and are excellent in high-temperature storability, cycle characteristics, high capacity, continuous-charge characteristics, storability, gas evolution inhibition during continuous charge, high-current-density charge/discharge characteristics, discharge load characteristics, etc. The object has been accomplished with a nonaqueous electrolyte which comprises: a monofluorophosphate and/or a difluorophosphate; and further a compound having a specific chemical structure or specific properties.
Abstract: A method of producing an alkaline single ion conductor with high conductivity includes: a) providing a hydrocarbon oligomer or polymer having immobilized acidic substituent groups selected from the group consisting of a sulfonic acid group, sulfamide group, a phosphonic acid group, or a carboxy group, in its alkaline ion form wherein at least a part of the acidic protons of the substituent groups have been exchanged against alkali cations, and b) solvating the hydro-carbon oligomer or polymer of step a) in an aprotic polar solvent for a sufficient time to effect a solvent uptake of at least 5% by weight and to obtain a solvated product, wherein the molar ratio of solvent/alkaline cation is 1:1 to 10,000:1, and which solvated product has a conductivity of at least 10?5 S/cm at room temperature (24° C.).
Type:
Application
Filed:
November 2, 2011
Publication date:
August 22, 2013
Applicant:
Max-Planck-Gesellschaft zur Foerderung der Wissenschaften e.V.
Inventors:
Annette Fuchs, Klaus-Dieter Kreuer, Joachim Maier, Andreas Wohlfarth
Abstract: Disclosed is a rechargeable lithium battery that includes a positive electrode having an active mass density of about 3.4 g/cc to about 4.0 g/cc, a negative electrode, and an electrolyte including a non-aqueous organic solvent including a compound represented by Chemical Formula 1 in an amount of about 10 volume % to about 50 volume % based on the total amount of the non-aqueous organic solvent. Chemical Formula 1: CH3COO—R1, wherein R1 is a C1 to C4 linear or branched alkyl group.
Type:
Application
Filed:
September 5, 2012
Publication date:
August 15, 2013
Applicant:
SAMSUNG SDI CO., LTD.
Inventors:
Ji-Young Kim, Wan-Mook Lim, Myoung-Han Ryu, Hyun-Ki Jung, Hyo-Rim Bak
Abstract: A secondary battery capable of decreasing progression temperature of a precipitation-dissolution reaction of aluminum is provided. A cathode 11 and an anode 12 are separated from each other by a separator 13. An electrolyte with which the separator 13 is impregnated contains an alkyl sulfone (R1—S(?O)2—R2: each of R1 and R2 represents an alkyl group) and a solvent (having a specific dielectric constant of 20 or less) together with an aluminum salt. A content of the solvent is equal to or larger than 30 mol % and is less than 88 mol %, and a mol ratio (a content of the aluminum salt/a content of the alkyl sulfone) is equal to or larger than 4/5 and is less than 7/3.
Abstract: The present invention provides a cathode having a protection layer formed by a complex between the surface of a cathode active material and an aliphatic nitrile compound, as well as an electrochemical device comprising the cathode. Also, the present invention provides an electrochemical device comprising: (1) a cathode having a protection layer formed by a complex between the surface of a cathode active material and an aliphatic nitrile compound; (2) an anode having a passivation layer formed by a compound selected from the group consisting of vinylene carbonate, its derivative and an ether compound; and (3) an electrolyte solution containing a lithium salt and a solvent.
Abstract: Disclosed are lithium/carbon monofluoride batteries suitable for long term use at highly elevated temperatures. Organosilicon electrolytes having low vapor pressure and high flash points are used, along with lithium salts and ceramic separators. Methods of using these batteries at high temperatures are also disclosed.
Type:
Grant
Filed:
May 10, 2010
Date of Patent:
July 16, 2013
Assignee:
Wisconsin Alumni Research Foundation
Inventors:
Monica L. Usrey, Xin Chen, Jose A. Pena Hueso, Robert C. West, Robert J. Hamers
Abstract: Disclosed is a non-aqueous electrolyte secondary battery using a polyanion compound or a lithium nickelate as a positive electrode active material, suppressing the elution of a transition metal from the polyanion compound or ameliorating the deterioration of a binder by a residual alkali component, and provides a non-aqueous electrolyte secondary battery having a negative electrode intercalating and deintercalating lithium ions, a positive electrode containing a lithium-containing compound as a positive electrode active material, and a non-aqueous electrolyte with a lithium salt dissolved in organic solvent. The lithium-containing compound is a polyanion compound or a lithium nickelate. The non-aqueous electrolyte contains a fluorosilane compound: R1 to R3: alkyl group having 1-8 carbon(s), an alkenyl group having 2-8 carbons, a cycloalkyl group having 5-carbons, an aryl group having 6-8 carbons or a fluorine atom.
Abstract: The present invention relates to a solid composite for use in the cathode of a lithium- sulphur electric current producing cell wherein the solid composite comprises 1 to 75 wt.-% of expanded graphite, 25 to 99 wt.-% of sulphur, 0 to 50 wt.-% of one or more further conductive agents other than expanded graphite, and 0 to 50 wt.
Type:
Application
Filed:
May 26, 2011
Publication date:
June 27, 2013
Applicant:
Sion Power Corporation
Inventors:
Ruediger Schmidt, Alexander Panchenko, Bastian Ewald, Philip Hanefeld, Sorin Ivanovici, Helmut Moehwald, Igor P. Kovalev
Abstract: A non-aqueous electrolyte secondary battery includes a positive electrode containing a positive-electrode active material, a negative electrode containing a negative-electrode active material, and a non-aqueous electrolyte, and is characterized in that the non-aqueous electrolyte contains 1.0 wt % or less of a compound represented by formula (1) and 2.0 wt % or less of a cyclic sulfate ester represented by formula (2), based on the total weight of the non-aqueous electrolyte. By using the non-aqueous electrolyte including a specified amount of the compound represented by formula (1) and a specified amount of the cyclic sulfate ester, when the battery is used at a low temperature after being stored at a high temperature, the increase of the internal resistance is inhibited.
Abstract: The present invention provides electrochemical cells and batteries having one or more electrically conductive tabs and carbon sheet current collectors, where the tabs are connected to the carbon sheet current collectors; and methods of connecting the tabs to the carbon based current collectors. In one embodiment, the electrically conductive tabs are metallic tabs.
Type:
Grant
Filed:
January 4, 2012
Date of Patent:
June 18, 2013
Assignee:
Leyden Energy, Inc.
Inventors:
Marc Juzkow, Aakar Patel, Jun Lui, Konstantin Tikhonov, Michael Erickson, Hashmat Haidari, Thomas Nagy, Hongli Dai
Abstract: A lithium ion secondary battery includes a positive electrode, a negative electrode, a non-aqueous electrolyte, and a separator interposed between the positive electrode and the negative electrode. The separator includes a polyolefin layer and an oxidation-resistant layer. The oxidation-resistant layer includes an oxidation-resistant polymer. A main chain of the oxidation-resistant polymer does not include a —CH2— group and a —CH(CH3)— group. The oxidation-resistant layer faces the positive electrode.
Abstract: An organic electrolytic solution including a lithium salt, an organic solvent, and a compound represented by the formula and a lithium battery employing the organic electrolytic solution. Groups Z1 and Z2 are each, independently, a cyano group, an isocyano group, a substituted or unsubstituted dicyanoethylphosphino group, or a substituted or unsubstituted dialkoxyphosphoryloxy group. Groups R1 through R4 are described fully in the Description. The organic electrolyte solution inhibits decomposition of an electrolytic solution and elution or precipitation of metal ions, and thus the lithium battery including the organic electrolytic solution has excellent cycle characteristics and lifetime characteristics.
Type:
Grant
Filed:
May 7, 2010
Date of Patent:
May 21, 2013
Assignee:
Samsung SDI Co., Ltd.
Inventors:
Dong-Joon Lee, Young-Gyoon Ryu, Dong-Min Im, Sook-Soo Lee
Abstract: Disclosed is an electrode comprising an aliphatic nitrile compound, wherein the aliphatic nitrile compound is coated on a surface of the electrode or is incorporated into the electrode active materials. A lithium secondary battery having the electrode is also disclosed. The lithium secondary battery has excellent safety so as to prevent ignition and explosion generated when the internal temperature of the battery is increased due to the heat emission caused by the reaction of an electrolyte with a cathode and the structural collapse of a cathode occurring upon overcharge. Additionally, it is also possible to prevent ignition and explosion when the battery is exposed to high temperature due to an increase in temperature resulting from heating or local short circuit caused by physical impacts. Further, it is possible to solve the problems of an increase in viscosity and degradation in battery performance at a low temperature occurring when an aliphatic nitrile compound is used as an additive for electrolyte.
Abstract: Provided are an electrolyte solution for lithium secondary battery, which includes dipentaerythritol hexaacrylate and a (meth)acrylate compound having a C4 to C12 linear or branched alkyl group as electrolyte additives, and a lithium secondary battery including the electrolyte solution. The electrolyte solution can improve the safety of the battery, and the performance characteristics, particularly cycle life characteristics, of the battery.
Type:
Application
Filed:
August 22, 2012
Publication date:
May 16, 2013
Applicant:
SOULBRAIN CO., LTD.
Inventors:
Soo Young KIM, Ji Seong HAN, Eun Gi SHIM, Ji Young CHOI, Wan Chul KANG
Abstract: A lithium battery includes a cathode; an anode; and an organic electrolyte solution. The cathode includes cathode active materials that discharge oxygen during charging and discharging. The organic electrolyte solution includes: lithium salt; an organic solvent, and at least one selected from the group consisting of compounds represented by Formula 1 and Formula 2 below: P(R1)a(OR2)b??Formula 1 O?P(R1)a(OR2)b.??Formula 2 R1 is each independently a substituted or unsubstituted C1-C20 alkyl group or a substituted or unsubstituted C6-C30 aryl group. R2 is each independently a substituted or unsubstituted C1-C20 alkyl group or a substituted or unsubstituted C6-C30 aryl group. a and b are each independently in a range of about 0 to about 3 and a+b=3.
Type:
Grant
Filed:
August 16, 2010
Date of Patent:
May 7, 2013
Assignee:
Samsung SDI Co., Ltd.
Inventors:
Dong-joon Lee, Dong-min Im, Young-gyoon Ryu, Seok-soo Lee
Abstract: The invention provides a lithium ion secondary battery comprising a positive electrode, a negative electrode and an electrolysis solution containing an aprotic solvent having an electrolyte dissolved in it, wherein the negative electrodes uses an amorphous carbon material as a negative electrode active material. The amorphous carbon material has (A) an average particle diameter (median size) of 7 ?m to 20 ?m inclusive as measured by a laser diffraction scattering method and (B) a particle size distribution as measured by a laser diffraction scattering method, in which distribution the ratio of particles of less than 3 ?m in diameter is 1% by mass to 10% mass inclusive, and is free of an electrical conducting material.
Abstract: A non-aqueous electrolyte solution containing a lithium salt, a non-aqueous solvent, and a compound expressed by the following formula (IIc): wherein Z6 represents an integer of 2 or larger, X6 represents a Z6-valent hydrocarbon group having 2-6 carbon atoms, R61 represents, independently of each other, an alkyl group having 1-6 carbon atoms, R62 represents, independently of each other, an alkyl group having 1-6 carbon atoms substituted by one or more halogen atoms and any two or more of R61 and/or R62 may be linked with each other to form a ring.
Abstract: A nonaqueous secondary battery comprising: a positive electrode; a negative electrode; and a nonaqueous electrolyte solution, wherein the nonaqueous electrolyte solution contains at least a cyclic nitrogen-containing compound represented by the general formula (1): wherein X represents an optionally branched divalent group derived from a chain saturated hydrocarbon and having 1 to 5 carbon atoms, ?C?CH2, ?C?O, ?C?S?O, ?O or ?S; and A1 and A2 may be the same or different and each represent an optionally substituted methylene group, ?C?O or ?SO2.
Abstract: A lithium secondary battery is intended to suppress deterioration upon storage at high temperature of 50° C. or higher without deteriorating the output characteristics at a room temperature. The battery includes a positive electrode capable of occluding and releasing lithium ions, a negative electrode capable of occluding and releasing lithium ions, a separator disposed between the positive electrode and the negative electrode, and an electrolyte. The electrolyte contains a compound having a double bond in the molecule and a compound having a plurality of polymerizable functional groups in the molecule, and the electrolyte contains a compound represented by formula (4): (in which Z1 and Z2 each represent any one of an allyl group, a methallyl group, a vinyl group, an acryl group, and a methacryl group).
Abstract: A secondary battery capable of improving the cycle characteristics is provided. The secondary battery includes a cathode and an anode oppositely arranged with a separator in between, and an electrolytic solution. At least one of the cathode, the anode, the separator, and the electrolytic solution contains a sulfone compound having a carbonate group and a sulfonyl group.
Abstract: A cylindrical secondary battery including an electrode assembly including a positive electrode having a positive electrode active material layer containing lithium carbonate (Li2CO3), a negative electrode including a negative electrode active material layer, and a separator separating the positive electrode from the negative electrode, a can housing the electrode assembly, a cap assembly disposed on the can, and an electrolyte injected into the can. A content of the lithium carbonate (Li2CO3) is in the range of 1.0 to 1.5 wt % of the total weight of the positive electrode active material layer, a content of the electrolyte is in the range of 10.8 to 11.93 wt % of the total weight of a bare cell, and an operating pressure for interrupting current by the cap assembly is in the range of 7 to 9 kgf/cm2.
Abstract: The sudden generation of heat being frequently caused in the case of the overcharge of a lithium secondary cell which have a positive electrode comprising a composite metal oxide of lithium and cobalt or a composite metal oxide of lithium and nickel, a negative electrode comprising metallic lithium, a lithium alloy or a material capable of occluding and releasing lithium, and a nonaqueous electrolyte solution comprising a nonaqueous solvent and an electrolyte dissolved therein can be efficiently prevented by the addition, to the nonaqueous electrolyte solution, of an organic compound which, when the lithium secondary cell is overcharged, decomposes into a decomposition product capable of dissolving out the cobalt or nickel contained in the positive electrode and depositing it ion the negative electrode (for example, a tert-alkylbenzene derivative).
Type:
Grant
Filed:
June 21, 2011
Date of Patent:
March 12, 2013
Assignee:
Ube Industries, Ltd.
Inventors:
Toshikazu Hamamoto, Akira Ueki, Koji Abe, Kazuhiro Miyoshi
Abstract: An electrolyte for a rechargeable lithium battery including a non-aqueous organic solvent, a lithium salt, and an electrolyte additive including a compound represented by the following Chemical Formula 1, and a rechargeable lithium battery including the electrolyte for a rechargeable lithium battery. In Chemical Formula 1, Ar1 and Ar2 are the same or different and are independently aromatic organic groups, and X is a halogen.
Abstract: A lithium secondary battery includes a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, and a non-aqueous electrolyte. The positive electrode active material comprises at least one lithium-containing composite oxide represented by the following general formula: LixM11?yM2yO2 where M1 and M2 are different elements, M1 is Ni or Co, M2 is at least one selected from Ni, Co, Mn, Mg, and Al, 1?x?1.05, and 0?y?0.7. The negative electrode active material comprises at least one selected from the group consisting of silicon, tin, a silicon-containing alloy, and a tin-containing alloy. The non-aqueous electrolyte includes an organic peroxide.
Abstract: Disclosed are a nonaqueous electrolytic solution for lithium secondary battery comprising an electrolyte dissolved in a nonaqueous solvent and containing at least one compound represented by the formula (I) in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution; a lithium battery containing the electrolytic solution and excellent in low-temperature and high-temperature cycle property; and a formyloxy group-containing compound having a specific structure which is used in lithium batteries, etc. (wherein X represents an alkylene group, an alkenylene group or an alkynylene group; R1 represents H, an alkyl group, a cycloalkyl group or a group of the formula (II); R2 represents an alkyl group, a cycloalkyl group or a group of the formula (II); R3 to R7 each represent H, F, a methoxy group or an ethoxy group.
Abstract: The present invention provides an electrolyte containing novel additive for electrochemical device and the electrochemical device thereof. The additive is a compound represented by below formula (I): wherein R is defined as herein; n is 2, 3, or 4. The additive of the present invention can protect the surface of the carbonaceous material on the anode, suppresses the occurrence of exfoliation, and therefore increases the lifetime of the electrochemical device. Furthermore, the additive of the present invention also slows down the decay of capacity on the cathode during charging-discharging cycles, and hence maintains a better performance.
Type:
Grant
Filed:
March 19, 2010
Date of Patent:
February 19, 2013
Assignee:
Taiwan Hopax Chems, Mfg. Co., Ltd.
Inventors:
Chih-Wei Huang, Li-Jane Her, Jou-Yeh Su
Abstract: There are provided a nonaqueous-type electrolyte solution having high flame retardancy and a good capacity retention rate, and a device comprising the nonaqueous-type electrolyte solution. The nonaqueous-type electrolyte solution is used in a device comprising a positive electrode, a negative electrode and the nonaqueous-type electrolyte solution, and contains a lithium salt and a compound having a phosphazene structure, and further contains 0.05% by mass or more and 12.0% by mass or less of at least one disulfonate ester selected from a cyclic disulfonate ester and a chain disulfonate ester based on the total of the nonaqueous-type electrolyte solution.
Abstract: A battery capable of obtaining the high energy density and obtaining the superior cycle characteristics is provided. In an anode, the thickness of a single face of an anode active material layer containing a carbon material as an anode active material is from 75 ?m to 120 ?m. An electrolytic solution contains difluoroethylene carbonate as a solvent. Thereby, the energy density of the anode is improved, and the diffusion and the acceptance of lithium ions in the anode are improved.
Abstract: The present invention provides an electrolyte solvent for batteries, which comprises fluoroethylene carbonate and linear ester solvent. Also, the present invention provides a lithium secondary battery comprising a positive electrode, a negative electrode and an electrolyte, wherein the electrolyte comprises fluoroethylene carbonate and linear ester solvent. The inventive electrolyte solvent can improve the battery safety without deteriorating the battery performance.
Type:
Grant
Filed:
March 20, 2012
Date of Patent:
February 12, 2013
Assignee:
LG Chem, Ltd.
Inventors:
Keun Yung Im, Ki Young Lee, Joon Sung Bae, Young Taek An
Abstract: The present invention provides a cathode having a protection layer formed by a complex between the surface of a cathode active material and an aliphatic nitrile compound, as well as an electrochemical device comprising the cathode. Also, the present invention provides an electrochemical device comprising: (1) a cathode having a protection layer formed by a complex between the surface of a cathode active material and an aliphatic nitrile compound; (2) an anode having a passivation layer formed by a compound selected from the group consisting of vinylene carbonate, its derivative and an ether compound; and (3) an electrolyte solution containing a lithium salt and a solvent.
Abstract: The present invention provides an electrolyte for lithium secondary batteries that allows the batteries to operate safely at a charging voltage up to 4.35V, wherein the electrolyte comprises a combination of a fluoroethylene carbonate compound and a linear ester compound as solvent. Also, the present invention provides a lithium secondary battery that can operate at a charging voltage up to 4.35V, which comprises a positive electrode, a negative electrode and an electrolyte, wherein the electrolyte comprises fluoroethylene carbonate compound and linear ester compound as solvent.
Type:
Grant
Filed:
August 16, 2010
Date of Patent:
February 5, 2013
Assignee:
LG Chem, Ltd.
Inventors:
Keun Yung Im, Ki Young Lee, Joon Sung Bae, Young Tack An
Abstract: A non-aqueous electrolyte secondary battery wherein the non-aqueous electrolyte contains a non-aqueous solvent, a solute dissolved in the non-aqueous solvent, and hydrogenated terphenyl, the solute includes a boron-containing alkali salt and a boron-free alkali salt, the negative electrode includes a negative electrode active material comprising a randomly oriented carbon composite (A), and the carbon composite (A) contains a graphitic carbon substance (B) and a carbon substance (C) that is different from the graphitic carbon substance (B).
Type:
Grant
Filed:
February 23, 2007
Date of Patent:
February 5, 2013
Assignees:
Panasonic Corporation, Mitsubishi Chemical Corporation
Abstract: A non-aqueous electrolyte secondary battery including: an electrode group in which a positive electrode and a negative electrode are spirally wound with a separator interposed therebetween; and a non-aqueous electrolyte including a non-aqueous solvent and a lithium salt dissolved in the non-aqueous solvent, the positive electrode including a positive electrode material mixture layer containing a nickel-containing lithium composite metal oxide, wherein a product of A and B equals 150 to 350, A equals 15 to 20%, and B equals 10 to 25%, where A (%) represents a porosity of the positive electrode material mixture layer, and B (%) represents a volume percentage of ethylene carbonate in the non-aqueous solvent.
Abstract: Disclosed are a non-aqueous electrolyte solution for a lithium secondary battery and a lithium secondary battery comprising the same. The non-aqueous electrolyte solution for a lithium secondary battery may include difluorotoluene having a lowest oxidation potential among components of the non-aqueous electrolyte solution. The lithium secondary battery may have improvement in basic performance including high rate charge/discharge characteristics, cycle life characteristics, and the like, and may remarkably reduce swelling caused by decomposition of an electrolyte solution under high voltage conditions such as overcharge.
Abstract: A negative electrode material for non-aqueous electrolyte secondary batteries, characterized in that the negative electrode material comprises a composite particle including solid phases A and B, the solid phase A being dispersed in the solid phase B, and the ratio (IA/IB) of the maximum diffracted X-ray intensity (IA) attributed to the solid phase A to the maximum diffracted X-ray intensity (IB) attributed to the solid phase B satisfies 0.001?IA/IB?0.1, in terms of a diffraction line obtained by a wide-angle X-ray diffraction measurement of the composite particle.
Abstract: A non-aqueous electrolyte secondary battery including: an electrode group in which a positive electrode and a negative electrode are spirally wound with a separator interposed therebetween; and a non-aqueous electrolyte including a non-aqueous solvent and a lithium salt dissolved in the non-aqueous solvent, the positive electrode including a positive electrode material mixture layer containing a nickel-containing lithium composite metal oxide, wherein a product of A and B equals 150 to 350, A equals 15 to 20%, and B equals 8 to 25%, where A (%) represents a porosity of the positive electrode material mixture layer, and B (%) represents a volume percentage of ethylene carbonate in the non-aqueous solvent.
Abstract: A nonaqueous electrolyte battery, including a case, a positive electrode housed in the case, a negative electrode housed in the case, and a nonaqueous electrolyte containing an ionic liquid and lithium ions of which molar amount is no smaller than 1.8×10?5 mol per mAh of the battery capacity.
Type:
Grant
Filed:
January 24, 2006
Date of Patent:
January 8, 2013
Assignee:
Kabushiki Kaisha Toshiba
Inventors:
Hidesato Saruwatari, Takashi Kishi, Takashi Kuboki, Norio Takami
Abstract: A battery capable of improving battery characteristics such as cycle characteristics is provided. An electrolytic solution is impregnated in a separator. The electrolytic solution contains 4-fluoro-1,3-dioxolane-2-one. Fluorine ion content in the electrolytic solution is preferably from 10 weight ppm to 3200 weight ppm. Thereby, chemical stability of the electrolytic solution is improved, and cycle characteristics are improved. The present invention is effective for the case using an anode active material containing Sn or Si as an element for an anode.