Radiation Sensitive Composition Comprising Ethylenically Unsaturated Compound Patents (Class 430/281.1)
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Patent number: 12226997Abstract: A lithographic printing plate precursor is disclosed which comprises a support, a photopolymerizable image recording layer and an overcoat which comprises a low-molecular radical inhibitor. After image-wise exposure, the plate is heated whereby the radical inhibitor diffuses from the overcoat to the image recording layer, resulting in an increase of the daylight stability of the exposed and heated precursor. Such plate is especially suitable for on-press processing.Type: GrantFiled: May 25, 2021Date of Patent: February 18, 2025Assignee: ECO3 BVInventors: Katleen Himschoot, Eva Vermeiren, Thomas Billiet, Fabienne Goethals
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Patent number: 12220870Abstract: A light polymerizable composition for use in the additive manufacturing of medical devices may include a first photo-initiator and a second photo-initiator. The first photo-initiator activates to initiate curing of the composition when exposed to light of a first wavelength in an additive manufacturing device and the second photo-initiator limits the transmission of the light of the first wavelength that activates the first photo-initiator in the additive manufacturing device. The second photo-initiator is activated to further cure the composition when exposed to a light of a second wavelength different from the first wavelength by activating the second photo-initiator to produce free radicals at a higher rate when exposed to the light of the second wavelength than when exposed to the light of the first wavelength.Type: GrantFiled: November 27, 2023Date of Patent: February 11, 2025Inventors: H. David Dean, Al Siblani, Eric J. Mott, John P. Fisher, Martha O. Wang, Antonios G. Mikos
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Patent number: 12189288Abstract: Provided is a composition including colloidal silica particles; and a solvent, in which a viscosity at 25° C. is 4 mPa·s or lower. The colloidal silica particles are a composition in which a plurality of spherical silica particles are linked in a beaded shape or a composition in which a plurality of spherical silica particles are linked in a planar shape. The solvent includes a solvent A1 having a boiling point of 190° C. to 280° C. Provided is also a film forming method using the above-described composition.Type: GrantFiled: May 14, 2021Date of Patent: January 7, 2025Assignee: FUJIFILM CorporationInventor: Takahiro Okawara
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Patent number: 12173188Abstract: Provided are an ultraviolet absorbing agent represented by General Formula (1) and an application thereof. In General Formula (1), R11 represents a monovalent substituent. n is 1 or 2. W1 and W2 each independently represent a hydrogen atom, a cyano group, a carbamoyl group, a sulfamoyl group, a nitro group, an acyl group, an alkylsulfonyl group, an arylsulfonyl group, an alkylsulfinyl group, an arylsulfinyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, an alkyl group, an aryl group, or a heterocyclic group, where at least one of W1 or W2 represents a substituent having a Hammett's substituent constant ?p value of 0.2 or more. W1 and W2 may be bonded to each other to form a ring.Type: GrantFiled: November 10, 2021Date of Patent: December 24, 2024Assignee: FUJIFILM CORPORATIONInventor: Takashi Katou
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Patent number: 12111574Abstract: A resist composition containing a polymeric compound having a constitutional unit (a01) derived from a compound represented by General Formula (a0-1).Type: GrantFiled: December 9, 2021Date of Patent: October 8, 2024Assignee: TOKYO OHKA KOGYO CO., LTD.Inventor: Takuya Ikeda
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Patent number: 12111573Abstract: A resist composition containing a polymeric compound having a constitutional unit (a01) derived from a compound represented by General Formula (a0-1).Type: GrantFiled: December 14, 2021Date of Patent: October 8, 2024Assignee: TOKYO OHKA KOGYO CO., LTD.Inventor: Takuya Ikeda
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Patent number: 12085855Abstract: A method for manufacturing a semiconductor device includes forming a photoresist layer including a photoresist composition over a substrate. The photoresist layer is selectively exposed to actinic radiation to form a latent pattern and the latent pattern is developed by applying a developer to the selectively exposed photoresist layer to form a patterned photoresist. The photoresist composition includes a photoactive compound and a resin comprising a radical-active functional group and an acid labile group.Type: GrantFiled: April 1, 2021Date of Patent: September 10, 2024Assignee: TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.Inventors: Siao-Shan Wang, Ching-Yu Chang, Chin-Hsiang Lin
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Patent number: 12001139Abstract: A resist composition is provided comprising a base polymer and a quencher comprising a cyclic ammonium salt having a fluorinated saturated hydrocarbyl group or fluorinated aryl group. The resist composition has a high sensitivity and forms a pattern with improved LWR or CDU, independent of whether it is of positive or negative tone.Type: GrantFiled: July 21, 2021Date of Patent: June 4, 2024Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Jun Hatakeyama, Tomomi Watanabe
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Patent number: 11945887Abstract: Provided are a curable composition including a compound represented by Formula (1) or Formula (2), a curable compound, and a solvent; a film formed of the curable composition; a near-infrared cut filter; a solid-state imaging element; an image display device; an infrared sensor; and a camera module. In the formulae, X1 to X5 each independently represent O, S, or a dicyanomethylene group, and R1 to R5 each independently represent a group represented by Formula (R2), and the like, in which at least one of R1 or R2 is the group represented by Formula (R2) and at least one of R3 or R4 is the group represented by Formula (R2).Type: GrantFiled: December 11, 2020Date of Patent: April 2, 2024Assignee: FUJIFILM CorporationInventors: Tokihiko Matsumura, Suguru Samejima
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Patent number: 11934102Abstract: There is provided a manufacturing method for a cured substance, which makes it possible to obtain a cured substance having excellent breaking elongation, a manufacturing method for a laminate, including the manufacturing method for a cured substance, a manufacturing method for a semiconductor device, including the manufacturing method for a cured substance or the manufacturing method for a laminate, and there is provided a treatment liquid that is used in the manufacturing method for a cured substance. The manufacturing method for a cured substance includes a film forming step of applying a resin composition containing a precursor of a cyclization resin onto a base material to form a film, a treatment step of bringing a treatment liquid into contact with the film, and a heating step of heating the film after the treatment step, in which the treatment liquid contains at least one compound selected from the group consisting of a basic compound having an amide group and a base generator having an amide group.Type: GrantFiled: June 20, 2023Date of Patent: March 19, 2024Assignee: FUJIFILM CorporationInventors: Atsuyasu Nozaki, Misaki Takashima, Naoki Sato, Atsushi Nakamura
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Patent number: 11822241Abstract: A salt represented by formula (I), an acid generator and a resist composition: wherein R1, R2 and R3 each represent a hydroxy group, —O—R10, —O—CO—O—R10 or —O-L1-CO—O—R10, L1 represents an alkanediyl group, R4, R5, R6, R7, R8 and R9 each represent a halogen atom, an alkyl fluoride group or a hydrocarbon group, R10 represents an acid-labile group, X1, X2 and X3 each independently represent an oxygen atom or a sulfur atom, m1 is an integer of 1 to 5, m2, m3, m8 and m9 represent an integer of 0 to 5, m4, m5, m6 and m7 represent an integer of 0 to 4, in which 1?m1+m7?5, 0?m2+m8?5, 0?m3+m9?5, and AI? represents an organic anion.Type: GrantFiled: April 16, 2021Date of Patent: November 21, 2023Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Katsuhiro Komuro, Takashi Nakakoji, Koji Ichikawa
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Patent number: 11809077Abstract: A photoresist composition comprises a first polymer formed by free radical polymerization. The first polymer comprises polymerized units formed from a monomer that comprises an ethylenically unsaturated double bond and an acid-labile group; a photoacid generator; a quencher of formula (1): and a solvent.Type: GrantFiled: March 11, 2021Date of Patent: November 7, 2023Assignee: ROHM AND HAAS ELECTRONIC MATERIALS LLCInventors: Thomas Cardolaccia, Jason A. DeSisto, Choong-Bong Lee, Mingqi Li, Tomas Marangoni, Chunyi Wu, Cong Liu, Gregory P. Prokopowicz
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Patent number: 11796912Abstract: A radiation-sensitive composition contains: particles that include a metal oxide, a cation that includes a metal, an anion. The anion is preferably a conjugated base of an acid and the acid has preferably a pKa of no greater than 3. The content of the particles in terms of solid content equivalent is preferably no less than 50% by mass, and more preferably no less than 70% by mass. The hydrodynamic radius of the particles as determined by a dynamic light scattering analysis is preferably no greater than 10 nm. The total content of the cation and the anion with respect to 100 parts by mass of the particles is preferably no less than 5 parts by mass. The acid is preferably sulfonic acid, nitric acid, organic azinic acid, disulfonylimidic acid or a combination thereof.Type: GrantFiled: February 27, 2019Date of Patent: October 24, 2023Assignee: JSR CORPORATIONInventor: Motohiro Shiratani
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Patent number: 11762289Abstract: A photosensitive resin composition includes: (A) a binder resin; (B) a photopolymerizable monomer; (C) a photopolymerization initiator; (D) a quantum dot surface-modified with a compound having a thiol group at one terminal end and an alkoxy group, a cycloalkyl group, a carboxyl group, or a hydroxy group at the other terminal end; and (E) a solvent. A curable composition includes: (A?) a resin; (B?) a quantum dot surface-modified with a compound represented by Chemical Formula 1 or Chemical Formula 2; and (C?) a solvent. A method of manufacturing the surface-modified quantum dot, and a color filter manufactured using the photosensitive resin composition or the curable composition are also disclosed.Type: GrantFiled: October 9, 2018Date of Patent: September 19, 2023Assignee: Samsung SDI Co., Ltd.Inventors: Jinsuop Youn, Misun Kim, Hong Jeong Yu, Bumjin Lee, Yonghee Kang, Dongjun Kim, Byeonggeun Son, Jihyeon Yim, Mi Jeong Choi, Jonggi Kim, Minjee Park, Hojeong Paek, Woo Jung Shin, Young Woong Jang
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Patent number: 11640114Abstract: A compound represented by the formula (I): wherein R1, R2, R3, R4, X1, X2, Xa, Xb, L1, L2, L3 and L4 are defined in the specification.Type: GrantFiled: June 29, 2020Date of Patent: May 2, 2023Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Masahiko Shimada, Koji Ichikawa
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Patent number: 11609493Abstract: This photosensitive resin composition comprises: a photosensitive prepolymer having a carboxyl group and an ethylenically unsaturated group; a photopolymerization initiator; a thermosetting agent; and a pigment. The thermosetting agent is a polycarbodiimide compound represented by formula (1), in which a carbodiimide group is protected by an amino group that dissociates at temperatures of 80? or greater. The polycarbodiimide compound has a weight average molecular weight of 300-3000, and a carbodiimide equivalent weight of 150-600. When formed into a film having a dry film thickness of 10-40 ?m, the maximum value of the transmittance of the photosensitive resin composition is at least 7% for the transmission spectrum of at least some of the wavelength from 350-430 nm. (In formula (1), R1, R2, X1, X2, and n are as defined in the description.Type: GrantFiled: February 6, 2018Date of Patent: March 21, 2023Assignee: ARISAWA MFG. CO., LTD.Inventors: Takashi Gondaira, Makoto Tai
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Patent number: 11610728Abstract: An electronic component comprising a glass body containing a photosensitizer; a conductor as at least a part of an electric element, arranged on the glass body; a terminal electrode as a terminal of the electric element, arranged above an outer surface of the glass body, with the terminal electrode being electrically connected to the conductor; and an insulating film arranged above the outer surface of the glass body. The insulating film reflects or absorbs light in a photosensitive wavelength range of the photosensitizer contained in the glass body.Type: GrantFiled: August 27, 2021Date of Patent: March 21, 2023Assignee: Murata Manufacturing Co., Ltd.Inventors: Yoshitaka Matsuki, Hiraku Kawai, Yuichi Iida, Masahiro Kubota, Fumihiko Naruse
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Patent number: 11608394Abstract: A method for generating reactive species in a medium in which light irradiates the medium including a nanoparticle. A photoinitiator composed of semiconductor nanoparticles for photo-polymerization and 2D and 3D printing.Type: GrantFiled: February 6, 2019Date of Patent: March 21, 2023Assignee: YISSUM RESEARCH DEVELOPMENT COMPANY OF THE HEBREW UNIVERSITY OF JERUSALEM LTD.Inventors: Uri Banin, Shlomo Magdassi, Nir Waiskopf, Lior Efraim Verbitsky
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Patent number: 11591433Abstract: The present disclosure is to provide a photopolymer composition including a polymer matrix or a precursor thereof including a reaction product of a reactive isocyanate compound having a hydrogen bonding functional group capable of forming multiple hydrogen bonds and at least one isocyanate group, and a polyol having at least two hydroxyl groups; a photoreactive monomer; and a photoinitiator, a hologram recording medium produced from the photopolymer composition, an optical element including the photopolymer composition and a holographic recording method using the photopolymer composition.Type: GrantFiled: December 7, 2018Date of Patent: February 28, 2023Assignee: LG CHEM, LTD.Inventors: Heon Kim, Yeongrae Chang, Seokhoon Jang, Se Hyun Kwon
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Patent number: 11545386Abstract: A workpiece unit that includes a workpiece, a tape stuck to the workpiece; and an annular frame to which an outer circumferential edge of the tape is stuck and which has an opening defined centrally therein. The workpiece is disposed in the opening in the annular frame and supported on the annular frame by the tape, and at least one of the tape and the annular frame has an irreversible discoloring section that discolors in response to an external stimulus. Such a configuration makes it possible to determine whether or not a process involving an external stimulus has been carried out on the workpiece unit, based on the appearance of the workpiece unit (i.e., based on whether the irreversible discoloring section has been discolored or not).Type: GrantFiled: January 13, 2020Date of Patent: January 3, 2023Assignee: DISCO CORPORATIONInventors: Yoshinobu Saito, Masayuki Matsubara
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Patent number: 11543750Abstract: A lithographic printing plate precursor has an image-recording layer on a hydrophilic support, in which the image-recording layer contains an infrared absorbing dye that decomposes by exposure to an infrared ray and a color developer that develops color due to the exposure to an infrared ray. A method for producing a lithographic printing plate includes image-exposing the lithographic printing plate precursor using an infrared laser.Type: GrantFiled: December 16, 2019Date of Patent: January 3, 2023Assignee: FUJIFILM CorporationInventors: Keisuke Nogoshi, Takeshi Inasaki, Kazuaki Enomoto
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Patent number: 11534945Abstract: This patent application claims the use of directed energy in the form of electronically scanned ion beams to form plastic parts by selectively curing commodity or engineering resin in the shape of the part. Polymerization is limited to the vicinity of the controlled Bragg-peak of the ion beam (i.e., where linear energy transfer is maximized), if necessary, by the use of chemical polymerization inhibitors or conditions that inhibit polymerization.Type: GrantFiled: November 26, 2018Date of Patent: December 27, 2022Assignee: Directed Energy Materials LLCInventor: George Edward Parris
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Patent number: 11493844Abstract: The present invention provides a photosensitive resin composition for a flexographic printing plate, the photosensitive resin composition including at least a hydrophilic copolymer (A), a thermoplastic elastomer (B), a photo-polymerizable monomer (C), a photo-polymerization initiator (D), a plasticizer (E), and an acidic group-containing polymer (F), wherein the photosensitive resin composition for the flexographic printing plate has an acid value of 1 to 100 mgKOH/g, as measured by neutralization titration.Type: GrantFiled: March 23, 2018Date of Patent: November 8, 2022Assignee: ASAHI KASEI KABUSHIKI KAISHAInventors: Hiroshi Ogawa, Hideo Saito, Tohru Kihara, Kenji Ota
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Patent number: 11472943Abstract: A polymerizable composition for an optical material includes a compound represented by General Formula (1) and a polymerization reactive compound.Type: GrantFiled: July 25, 2018Date of Patent: October 18, 2022Assignee: MITSUI CHEMICALS, INC.Inventors: Shinsuke Ito, Kouji Suesugi
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Patent number: 11421049Abstract: An a photopolymerization formulation is provided as is an improved method for forming an object using the formulation.Type: GrantFiled: November 5, 2020Date of Patent: August 23, 2022Assignee: Piedmont Chemical Industries, LLCInventors: Paul D. Weipert, Theodosios Diplas, Michael Christian Meers
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Patent number: 11378885Abstract: According to one embodiment, a pattern formation material includes a first monomer. The first monomer includes a first molecular chain, a first group, and a second group. The first molecular chain includes a first end and a second end. The first group has an ester bond to the first end. The second group has an ester bond to the second end. The first group is one of acrylic acid or methacrylic acid. The second group is one of acrylic acid or methacrylic acid. The first molecular chain includes a plurality of first elements bonded in a straight chain configuration. The first elements are one of carbon or oxygen. The number of the first elements is 6 or more. A film including the first monomer is caused to absorb a metal compound including a metallic element.Type: GrantFiled: March 13, 2018Date of Patent: July 5, 2022Assignee: Kioxia CorporationInventors: Koji Asakawa, Naoko Kihara, Seekei Lee, Norikatsu Sasao, Tomoaki Sawabe, Shinobu Sugimura
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Patent number: 11370862Abstract: A planographic printing plate precursor includes: a support; and an image recording layer which includes a radical initiator, a radical polymerizable component, and a radiation absorption compound, and in which the image recording layer shows two or more peaks of a radical generation amount in a radical generation amount-versus-time curve after exposure to image forming radiation, in which the radical initiator includes an electron-donating radical initiator and an electron-accepting radical initiator, and the radiation absorption compound comprises a compound represented by the following Formula 1.Type: GrantFiled: May 12, 2019Date of Patent: June 28, 2022Assignee: FUJIFILM CORPORATIONInventors: Tadao Shibamoto, Taira Murakami, Kyosuke Tsumura, Kotaro Kudo
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Patent number: 11351509Abstract: In accordance with an embodiment, a filter membrane is sealed with a sealing material prior to using the filter membrane to filter process fluids. The sealing material is a fluorine-based polymer or a polymer with a cross-linking group. Once the sealing material has been placed in contact with the filter membrane, a cross-linking reaction may be initiated using either physical or chemical processes to cross-link the sealing material and to seal the filter membrane within the sealing material, thereby separating the filter membrane from the process fluids, reducing or eliminating leaching of the filter membrane into the process fluid.Type: GrantFiled: July 23, 2014Date of Patent: June 7, 2022Assignee: Taiwan Semiconductor Manufacturing Company, Ltd.Inventors: Kuan-Hsin Lo, Ching-Yu Chang
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Patent number: 11261273Abstract: Disclosed is a resin comprising a structural unit derived from a compound represented by formula (I?) and a structural unit having an acid-labile group: wherein R1 and R2 each independently represent an alkyl group which may have a halogen atom, a hydrogen atom or a halogen atom, Ar represents an aromatic hydrocarbon group which may have a substituent, L1 represents a group represented by formula (X1-1), etc., L11, L13, L15 and L17 each independently represent an alkanediyl group, L12, L14, L16 and L18 each independently represent —O—, —CO—, —CO—O—, —O—CO— or —O—CO—O—, and * and ** are bonds, and ** represents a bond to an iodine atom.Type: GrantFiled: December 7, 2017Date of Patent: March 1, 2022Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Tatsuro Masuyama, Satoshi Yamaguchi, Koji Ichikawa
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Patent number: 11262361Abstract: Disclosed herein are photodegradable hydrogels and associated kits for selectively capturing and releasing cells. The hydrogels result from cross linking in the presence of a photoinitiator (1) a macromer having a polymeric backbone structure, a photo labile moiety, and a first linking moiety, and (2) a cell-binding moiety having a second linking moiety. These two components are cross-linked by a polymerization reaction of the linking moieties to form a photodegradable hydrogel incorporating the cell-binding moiety within the hydrogel. Also disclosed are methods of making the hydrogels, and methods of using the hydrogels for selectively capturing and releasing cells and for detecting cells in a fluid. Such methods can be used to detect the presence and quantity of certain rare cell types in a biological fluid.Type: GrantFiled: July 18, 2014Date of Patent: March 1, 2022Assignee: The General Hospital CorporationInventors: Mark W. Tibbitt, Kristi S. Anseth, April M. Kloxin, Mehmet Toner, John Oakey, Ajay Shah
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Patent number: 11124477Abstract: A novel sulfonium compound has formula (A). A positive resist composition comprising a polymer and a quencher containing the sulfonium compound is improved in resolution and LER during pattern formation and has storage stability. In formula (A), R1, R2, R3, and R4 are independently a C1-C20 monovalent hydrocarbon group, p is an integer of 0-5, q is an integer of 0-5, and r is an integer of 0-4.Type: GrantFiled: September 4, 2019Date of Patent: September 21, 2021Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Naoya Inoue, Masaki Ohashi, Daisuke Domon, Keiichi Masunaga, Masaaki Kotake
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Patent number: 11069730Abstract: The present technology relates to a solid-state imaging apparatus capable of suppressing occurrence of color mixing, a method for manufacturing the solid-state imaging apparatus, and an electronic device. The solid-state imaging apparatus includes a plurality of pixels arranged in a pixel region. Each of the pixels has: a first optical filter layer disposed on a photoelectric conversion unit; a second optical filter layer disposed on the first optical filter layer; and a separation wall separating at least a part of the first optical filter layer for each of the pixels. Either the first optical filter layer or the second optical filter layer in at least one of the pixels is formed by an infrared cut filter, while the other is formed by a color filter. The present technology can be applied to a CMOS image sensor including a visible light pixel.Type: GrantFiled: August 31, 2017Date of Patent: July 20, 2021Assignee: Sony Semiconductor Solutions CorporationInventors: Sintaro Nakajiki, Yukihiro Sayama
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Patent number: 11054743Abstract: This invention discloses a fluorene polyfunctional photoinitiator as represented by general formula (I), a photosensitive resin composition containing the same, the preparation of the same, and uses of the two. This compound has the advantages of simple synthesis, low cost, and good solubility, and has good application effects in photocurable compositions. Compared with conventional small molecule photoinitiators, it is not only excellent in photoinitiation activity, but also has the advantages such as low mobility, low odor, and yellowing resistance. The composition has high photosensitivity and good developability, high resolution, and excellent adaptation to a substrate, and is very suitable for producing a black matrix having high light-shielding property, a high-precision and high quality color filter and a liquid crystal display device, and can also be used in optical spacers and ribs, photoresist, wet film, dry film and so on.Type: GrantFiled: September 28, 2016Date of Patent: July 6, 2021Assignees: CHANGZHOU TRONLY ADVANCED ELECTRONIC MATERIALS CO., LTD., CHANGZHOU TRONLY NEW ELECTRONIC MATERIALS CO., LTD.Inventor: Xiaochun Qian
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Patent number: 11042094Abstract: An object of the present invention is to provide a treatment liquid for patterning a resist film and a pattern forming method, each of which can simultaneously suppress the occurrence of pattern collapse in a resist L/S pattern and the occurrence of omission failure in a resist C/H pattern. The treatment liquid of the present invention is a treatment liquid for patterning a resist film, which is used for subjecting a resist film obtained from an actinic ray-sensitive or radiation-sensitive resin composition to at least one of development or washing, and contains an organic solvent, in which the treatment liquid contains a first organic solvent having a relative dielectric constant of 4.0 or less and a second organic solvent having a relative dielectric constant of 6.0 or more.Type: GrantFiled: March 28, 2018Date of Patent: June 22, 2021Assignee: FUJIFILM CorporationInventors: Shuji Hirano, Hideaki Tsubaki, Toru Tsuchihashi, Wataru Nihashi, Kei Yamamoto
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Patent number: 11036135Abstract: Provided are: a curable composition having excellent photolithographic properties and resin elution properties; a cured product of the curable composition; and a curing method of the curable composition. The curable composition is characterized by including: (A) at least one selected from the group consisting of a water-soluble polyfunctional (meth)acrylates and water-soluble polyfunctional (meth)acrylamides; and (B) a photosensitive group-containing water-soluble polymer. The water-soluble polyfunctional (meth)acrylates are preferably compounds represented by Formula (I) below, and the water-soluble polyfunctional (meth)acrylamides are preferably compounds represented by Formula (II) below.Type: GrantFiled: November 21, 2017Date of Patent: June 15, 2021Assignee: ADEKA CORPORATIONInventors: Kenji Hara, Masatomi Irisawa
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Patent number: 11016385Abstract: The disclosure provides a photosensitive adhesive composition including 10 parts by weight to 90 parts by weight of a monomer having a vinyl ether functional group, 10 parts by weight to 90 parts by weight of a tertiary amine polymer, and 0.5 parts by weight to 10 parts by weight of a photoacid initiator. The weight-average molecular weight of the tertiary amine polymer is between 2000 and 20000. The disclosure also provides a photosensitive conductive adhesive composition and an electronic device containing the photosensitive conductive adhesive composition.Type: GrantFiled: December 19, 2018Date of Patent: May 25, 2021Assignee: Industrial Technology Research InstituteInventors: Yi-Chi Yang, Shou-Yi Ho, Kuo-Chan Chiou
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Patent number: 11009829Abstract: The disclosure belongs to the technical field of photopolymer materials, and more particularly relates to a dual image storage material as well as a preparation method and application thereof. The dual image storage material is obtained by selective photoreaction of 1 to 50 parts by weight of an organic fluorescent material, 7 to 50 parts by weight of liquid crystal, 0.2 to 10 parts by weight of a photoinitiator and 33 to 67 parts by weight of photopolymerizable monomers. The obtained dual image storage material can present a high-brightness holographic pattern under sunlight and a fluorescent pattern under ultraviolet light in the same spatial position. The presented holographic and fluorescent patterns may be the same or different. The obtained dual image storage material can be used in the field of optical anti-counterfeiting, optical information storage, displays or the like.Type: GrantFiled: July 12, 2019Date of Patent: May 18, 2021Assignee: HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGYInventors: Haiyan Peng, Ye Zhao, Xiaolin Xie, Xingping Zhou, Xiaoyu Zhao
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Patent number: 10990006Abstract: A photosensitive composition including: a plurality of quantum dots, wherein the quantum dot includes an organic ligand bound to a surface of the quantum dot; a photoinitiator; a binder including a carboxylic acid group; a photopolymerizable monomer having a carbon-carbon double bond; and a solvent, wherein the photoinitiator includes a first photoinitiator including an oxime compound and a second photoinitiator including at least one selected from a phosphine oxide compound and an amino ketone compound.Type: GrantFiled: December 12, 2016Date of Patent: April 27, 2021Assignees: SAMSUNG ELECTRONICS CO., LTD., SAMSUNG SDI CO., LTD., SAMSUNG DISPLAY CO., LTD.Inventors: Shang Hyeun Park, Hojeong Paek, Jonggi Kim, Nayoun Won, Shin Ae Jun
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Patent number: 10962884Abstract: An object of the present invention is to provide a treatment liquid for patterning a resist film and a pattern forming method, each of which can simultaneously suppress the occurrence of pattern collapse in a resist L/S pattern and the occurrence of omission failure in a resist C/H pattern. The treatment liquid of the present invention is a treatment liquid for patterning a resist film, which is used for subjecting a resist film obtained from an actinic ray-sensitive or radiation-sensitive resin composition to at least one of development or washing, and contains an organic solvent, in which the treatment liquid contains a first organic solvent having an SP value of 16.3 MPa1/2 or less and a second organic solvent having an SP value of 17.1 MPa1/2 or more.Type: GrantFiled: March 28, 2018Date of Patent: March 30, 2021Assignee: FUJIFILM CorporationInventors: Hideaki Tsubaki, Toru Tsuchihashi, Wataru Nihashi, Kei Yamamoto
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Patent number: 10921708Abstract: Provided are a radiation-sensitive resin composition having good sensitivity and excellent temporal stability of the sensitivity, a cured film, a pattern forming method, a solid-state imaging device, and an image display device. The radiation-sensitive resin composition includes a resin, a polymerizable compound having an ethylenically unsaturated bond, a photopolymerization initiator, an organic solvent, and water, in which the photopolymerization initiator includes an oxime ester compound having at least one group selected from a branched alkyl group and a cyclic alkyl group, and the content of water is 0.1% to 2% by mass with respect to the mass of the radiation-sensitive resin composition.Type: GrantFiled: May 25, 2018Date of Patent: February 16, 2021Assignee: FUJIFILM CorporationInventors: Yuki Nara, Kaoru Aoyagi
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Patent number: 10921710Abstract: A polymer comprising units having a highly fused homoadamantane skeleton at side chain end bonded to the polymer backbone via a linking group has an appropriate solvent solubility and is capable of suppressing acid diffusion. A resist composition comprising the polymer and a specific photoacid generator exhibits a good DOF margin, CD uniformity, and a minimal CD change during PPD, and is quite effective in precise micropatterning.Type: GrantFiled: July 27, 2018Date of Patent: February 16, 2021Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Teppei Adachi, Ryosuke Taniguchi, Kazuhiro Katayama
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Patent number: 10908502Abstract: A resist composition including a resin component having a structural unit derived from a compound represented by formula (a0-1), in which W represents a polymerizable group-containing group; Ra01 represents an alkyl group or an aromatic heterocyclic group containing an oxygen atom or a sulfur atom; in the case where Ra01 is an aromatic heterocyclic group containing an oxygen atom or a sulfur atom, Ra02 is a group which forms an aliphatic cyclic group containing an electron-withdrawing group, together with the tertiary carbon atom (*C) to which Ra01 is bonded; and when Ra01 is an alkyl group, Ra02 is a group in which an aliphatic cyclic group containing an electron-withdrawing group forms a condensed ring together with an aromatic heterocyclic group containing an oxygen atom or a sulfur atom.Type: GrantFiled: October 1, 2018Date of Patent: February 2, 2021Assignee: Tokyo Ohka Kogyo Co., Ltd.Inventors: Masatoshi Arai, Takuya Ikeda, Koshi Onishi
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Patent number: 10859914Abstract: A method for producing an electronic device includes the pattern forming method, and an actinic ray-sensitive or radiation-sensitive resin composition for organic solvent development. Specifically, provided is a pattern forming method, including a film forming step of forming a film by an actinic ray-sensitive or radiation-sensitive resin composition, an exposure step of irradiating the film, and a development step of developing the film using a developer containing an organic solvent, in which the composition contains a resin containing a repeating unit having an Si atom and a repeating unit having an acid-decomposable group and a compound capable of generating an acid upon irradiation with actinic rays or radiation, the content of Si atoms in the resin is 1.0 to 30 mass %, and the content of the resin in the total solid content of the composition is 20 mass % or more.Type: GrantFiled: July 24, 2017Date of Patent: December 8, 2020Assignee: FUJIFILM CorporationInventors: Naoya Hatakeyama, Akiyoshi Goto, Michihiro Shirakawa, Keita Kato, Keiyu Ou
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Patent number: 10781276Abstract: An object of the present invention is to provide a polymer used for a resist composition having high absorption efficiency for a particle beam or an electromagnetic wave, and excellence in sensitivity, resolution and pattern performance characteristics, and provide a resist composition containing the polymer and a method of manufacturing a device using thereof. The polymer comprises: a unit A; and a unit B, wherein the unit A has an onium salt structure and generates a first radical by irradiation with a particle beam or an electromagnetic wave, the unit B has a radical generating structure containing at least one multiple bond which is between a carbon atom and a carbon atom or between a carbon atom and a heteroatom, and generates a second radical by irradiation with a particle beam or an electromagnetic wave, and the multiple bond is not one contained in a benzenoid aromatic.Type: GrantFiled: September 29, 2016Date of Patent: September 22, 2020Assignee: TOYO GOSEI CO., LTD.Inventors: Satoshi Enomoto, Takumi Yoshino
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Patent number: 10759890Abstract: Provided are: a curable composition that has excellent flexibility and shows excellent adhesion to both a plastic substrate and a conductor layer; a coating film of the curable composition; and a printed circuit board comprising a pattern-cured coating film obtained from the coating film. The present invention relates to: a curable composition for a printed circuit board, which is characterized by comprising (A) a block copolymer, (B) a hydroxyl group-containing (meth)acrylate compound and (C) a photopolymerization initiator; a coating film obtained by photo-curing the curable composition; and a printed circuit board comprising a resist pattern formed from the coating film.Type: GrantFiled: September 30, 2014Date of Patent: September 1, 2020Assignee: TAIYO INK MFG. CO., LTD.Inventors: Masayuki Shimura, Yoshiyuki Furuta, Masao Yumoto
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Patent number: 10754064Abstract: Problem to Be Solved: to provide a chromophore having a far superior nonlinear optical activity to conventional chromophores and to provide a nonlinear optical element comprising said chromophore. Solution: a chromophore comprising a donor structure D, a ?-conjugated bridge structure B, and an acceptor structure A, the donor structure D comprising an aryl group substituted with a substituted oxy group; and a nonlinear optical element comprising said chromophore.Type: GrantFiled: April 3, 2018Date of Patent: August 25, 2020Assignees: NATIONAL INSTITUTE OF INFORMATION AND COMMUNICATIONS TECHNOLOGY, SUMITOMO ELECTRIC INDUSTRIES, LTD., KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATIONInventors: Akira Otomo, Isao Aoki, Hideki Miki, Hidehisa Tazawa, Shiyoshi Yokoyama
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Low ash and ash-free acid neutralizing compositions and lubricating oil compositions containing same
Patent number: 10731103Abstract: An oleaginous nanoparticle dispersion of nanoparticles having a core of an organic base material immobilized within a surfactant layer, the use thereof as a low ash, or ash-free source of TBN in lubricating oil compositions, and lubricating oil compositions formulated with such oleaginous nanoparticle dispersions.Type: GrantFiled: December 11, 2017Date of Patent: August 4, 2020Assignee: Infineum International LimitedInventors: Jacob Emert, Rachel Tundel, Peter Wright, Sandip Agarwal, Xinhua Li, Joseph McLellan, Patrick Reust -
Patent number: 10725379Abstract: A resin composition including the following components (a) and (b). (a) A polyimide precursor having a structural unit represented by the following general formula (1); and (b) a compound represented by the following general formula (2): wherein in the formula R1 is a tetravalent organic group, R2 is a divalent organic group and R3 and R4 are independently a hydrogen atom, an alkyl group, a cycloalkyl group or a monovalent organic group having a carbon-carbon unsaturated double bond.Type: GrantFiled: December 13, 2013Date of Patent: July 28, 2020Assignee: Hitachi Chemical DuPont MicroSystems, Ltd.Inventors: Keishi Ono, Tetsuya Enomoto, Masayuki Ohe, Keiko Suzuki, Kazuya Soejima, Etsuharu Suzuki
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Patent number: 10726966Abstract: Disclosed is a method of forming a conductive polymer thin film pattern, including (a) Coating substrate with solution including PEDOT:PSS (poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)) to form coating layer including solution on substrate, (b) irradiating a predetermined portion of the coating layer with light, thus manufacturing a pre-patterned substrate including PEDOT:PSS patterned on the predetermined portion and the coating layer other than the predetermined portion, and (c) removing the coating layer from the pre-patterned substrate, thus manufacturing a conductive polymer thin film having a PEDOT:PSS pattern.Type: GrantFiled: November 1, 2018Date of Patent: July 28, 2020Assignee: Korea Institute of Industrial TechnologyInventors: Changhun Yun, Hyeck Go
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Patent number: 10700387Abstract: A carboxymethyl cellulose is provided with a polydispersity index of 10 or more and a weight average molecular weight of 2,000,000 or more in a negative electrode mix slurry. Accordingly, phase stability of the negative electrode mix slurry is improved, achieving improved adhesiveness and low resistance of a negative electrode manufactured therefrom.Type: GrantFiled: November 14, 2017Date of Patent: June 30, 2020Assignee: LG CHEM, LTD.Inventors: Kwang-Ho Jeong, Ye-Cheol Rho, Jin-Sook Ryu, Je-Young Kim, Jung-Woo Yoo