Abstract: A method of preparing near net shape, monolithic, porous SiC foams is disclosed. Organosilicon precursors are used to produce polymeric gels by thermally induced phase separation, wherein, a sufficiently concentrated solution of an organosilicon polymer is cooled below its solidification temperature to form a gel. Following solvent removal from the gel, the polymer foam is pretreated in an oxygen plasma in order to raise its glass transition temperature. The pretreated foam is then pyrolized in an inert atmosphere to form a SiC foam.

Abstract: A method of making a microporous carbon material which includes providing a precursor selected from the group consisting of crystalline salts of aromatic sulfonates and nonporous polymeric salts. Heat treatment of such precursors in the temperature range of 350.degree. to 850.degree. C. in an inert oxygen free atmosphere for a sufficient time promotes thermally induced hydrogen abstraction and rearrangement of BSUs which result in the formation of a carbonaceous microporous material having a pore size distribution in the range of about 4-15 .ANG.. The structural and storage characteristics of the microporous carbon materials are also disclosed.

Abstract: An improved process is provided for the preparation of activated carbon, which comprises swelling a carbonaceous material in a polar organic solvent containing an activating agent, removing the solvent, carbonizing the material, and removing the activating agent from the product. The activated carbon is produced in a short time with a high yield, and has a high surface area with a very narrow pore size distribution. Both the solvent and activating agents may be recovered and recycled.

Abstract: This invention concerns composite materials comprising a plurality of carbon fibrils in a matrix wherein the carbon fibrils are each characterized by a substantially constant diameter between about 3.5 to 70 nanometers and are substantially free of pyrolytically deposited thermal carbon.

Abstract: Reactant for thermochemical systems, including a support which is, for example, recompressed expanded graphite or vermiculite, and an active agent, for example a salt. According to the invention, the support is in the form of granules of graphite having a density of between 0.20 and 0.5 g/cm.sup.3 and whose diameter lies between 0.2 cm and 2.5 cm.

Abstract: A supported catalyst comprising a carbon fibril aggregate and a catalytically effective amount of a catalyst supported therein, a process for performing a catalytic reaction in fluid phase using the supported catalyst and a process for making the supported catalyst are disclosed.

Abstract: Disclosed is a phosphorus treated activated carbon composition suitable for use as catalyst support, catalyst, and an adsorbent, which is produced by treating (e.g., by mixing or impregnating) an activated carbon material having a surface area greater than 100 m.sup.2 /g with a phosphorus-containing compound, drying, and heating to a temperature of from 450.degree. C. to about 1200.degree. C., wherein the resulting composition is characterized by a phosphorus compound combined with the carbon in the amount of from above 2.5% to about 10% phosphorus, based on the weight of the composition.

Abstract: A high energy density capacitor incorporating a variety of carbon foam electrodes is described. The foams, derived from the pyrolysis of resorcinol-formaldehyde and related polymers, are high density (0.1 g/cc-1.0 g/cc) electrically conductive and have high surface areas (400 m.sup.2 /g-1000 m.sup.2 /g). Capacitances on the order of several tens of farad per gram of electrode are achieved.

Abstract: A process is provided for the manufacture of a catalytically-active carbonaceous char capable of rapidly decomposing hydrogen peroxide in aqueous solutions. The process of the invention uses a low-temperature carbonization and extensive oxidation of a bituminous coal or material having bituminous properties followed by exposure to a nitrogen-containing compound as the temperature of the carbonized and extensively oxidized char is increased to minimally 700.degree. C. The resultant char may then be activated as desired. These catalytically-active chars have the ability to rapidly decompose aqueous solutions of hydrogen peroxide and are useful for catalytic conversion of H.sub.2 S, SO.sub.2, NO, chloramines, and/or peroxides in liquid and/or gaseous streams.

Abstract: A dual-impregnated activated carbon composition includes activated carbon impregnated with a Group 6-12 metal salt and a Group 1 metal carbonate salt, where the molar ratio on the activated carbon of the Group 1 metal to the Group 6-12 metal is 1 or greater. The dual-impregnated activated carbon composition is particularly suitable for filtering gaseous contaminants.

Abstract: A catalyst material of carbon black powder having nitrogen affixed to its surface and process for its production by contacting carbon black powder particles with a plasma or low energy beam of nitrogen containing ions affixing the nitrogen ions to the surface of the particles in a concentration of about 0.1 to about 10 percent, based upon the total number of surface atoms. The catalysts are particularly suited for use in phosphoric acid fuel cells.

Abstract: A catalyst for dimerizing a lower .alpha.-olefin monomer with an enhanced selectivity comprises a carrier comprising at least one anhydrous potassium compound, preferably a mixture of potassium fluoride with potassium carbonate, and a carbon material; and a catalytic component carried on the carrier and comprising an alkali metal, preferably sodium metal, the catalyst preferably being compression molded into grains.

Abstract: A process is provided for the removal of peroxides from gaseous or liquid media. The improvement is provided by the use of a carbonaceous char active for peroxide decomposition which is prepared by the carbonization and oxidation of a bituminous coal or bituminous coal-like material at temperatures below 700.degree. C. followed by exposure of the carbonized, oxidized char to a nitrogen-containing compound during the initial calcination and condensation of the carbon structure as the temperature is raised to above 700.degree. C.

Abstract: A carbon body and method for making the body. The body is characterized by carbon particles bonded together with bentonite clay and a cured epoxy resin. The bentonite content is about 5% to about 30% by weight based on carbon. The epoxy resin and curing agent content as measured before curing is about 5% to about 40% by weight based on carbon. The curing agent as measured before curing makes up about 5 parts to about 40 parts per 100 weight parts based on the epoxy resin. The resin has an average functionality of at least 3. The body has higher strength after exposure to temperatures of up to about 250.degree. C. in air than bodies absent the bentonite and resin. Additionally, the body has the properties of surface area retention after exposure to high temperatures, and water resistance.

Abstract: An improved process is provided for the manufacture of a catalytically-active carbonaceous char capable of rapidly decomposing hydrogen peroxide in aqueous solutions. The process of the invention uses a low temperature carbonization and extensive oxidation of a bituminous coal or bituminous coal-like material followed by exposure to a nitrogen-containing compound at high temperatures during the initial calcination and/or activation. The resultant catalytically-active chars have the ability to rapidly decompose aqueous solutions of hydrogen peroxide and are useful for catalytic conversion of H.sub.2 S, SO.sub.x, NO.sub.x, chloramines, and/or peroxides in liquid and/or gaseous streams.

Abstract: This invention relates to a shaped composition composed of a carbonaceous pyropolymer having recurring units containing at least carbon and hydrogen atoms. The composition is characterized by a crush strength of at least 6 kg and has a bimodal pore distribution having maxima at pore diameters of about 60 to 900 .ANG. and about 120 to 160 .ANG..

Abstract: A preparing process of activated carbon includes steps of: combusting scrap tires containing metal wire at 400.degree. C. to 900.degree. C. under the presence of oxygen, carbon dioxide and vapor; reheating the generated combustible gases up to 800.degree. C. to 900.degree. C. by adding a further fuel; causing the exhaust gas to heat-exchange with a water pipe boiler so that the temperature of the exhaust gas downs to 180.degree. C. to 250.degree. C.; and introducing the exhaust having a temperature of 180.degree. C. to 250.degree. C. into an electric dust collector so as to collect activated carbon. The particle size of the thus obtained distributed substantially in a range of 90 to 110 mesh and the CEC (cation exchange capacity) of the activated carbon falls within 30 to 40.

Abstract: The invention relates to a catalyst comprising a rare metal of Group VIII of the Periodic Table of Elements which has been deposited on an inert support and which has been used to dehalogenate .alpha.-halogenated carboxylic acids in the presence of hydrogen, and a rare metal of Group VIII of the Periodic Table of Elements which has been deposited on an inert support and which is such that the granulometry of b) is very much lower than that of a) to form a homogeneous mixture as a result of the action of currents of .alpha.-halogenated carboxylic acid and hydrogen.It is particularly useful for regenerating palladium catalysts used in the purification of crude monochloroacetic acid.

Abstract: Carbonaceous chars capable of catalytically decomposing aqueous hydrogen peroxide at higher rates at given char densities than other known catalytic chars are provided for. This improvement is provided by an increase in the catalytic activity at a given char density of the said catalytically-active carbonaceous char. The catalytically-active carbonaceous chars are useful for, but not limited to, the catalytic conversion of H.sub.2 S, SO.sub.x, NO.sub.x, peroxides, and/or chloramines in liquid and/or gaseous media.

Abstract: A dual-impregnated activated carbon composition includes activated carbon impregnated with a Group 6-12 metal salt and a Group 1 metal carbonate salt, where the molar ratio on the activated carbon of the Group 1 metal to the Group 6-12 metal is 1 or greater. The dual-impregnated activated carbon composition is particularly suitable for filtering gaseous contaminants.

Abstract: The ability of a packed bed of adsorbent to hold a gas is increased by employing at least two sizes of adsorbent particles having nominal diameters differing by at least 7/1. In a preferred embodiment, the capacity of a bed of carbon molecular sieve particles for adsorption of natural gas is significantly improved.

Abstract: A process for the preparation of aniline by hydrogenation of nitrobenzene in the gas phase in the presence of a catalyst containing a noble metal is described. The process can be carried out in an improved manner if the catalyst employed is palladium on graphite or petrol coke, as the support, containing 0.001-1% by weight of Pd, based on the total weight of the catalyst, it being possible for the catalyst also to contain, in addition to the Pd, 0.001-0.5% by weight of Ir and/or 0.001-0.3% by weight of Rh, all figures being based on the total weight of the catalyst.

Abstract: The present invention relates to specific activated carbon materials including from 1 to 5% by weight of nitrogen, from 3 to 30% by weight of oxygen and from 40 to 95% by weight of carbon, and having an average pore radius of from 15 to 30 .ANG., with the proviso that mesopores occupy at least 50% by volume based on the total pore volume, and also relates a process for the preparation thereof, and to the use thereof as catalysts.

Abstract: The present invention provides a process for producing a selected paraffin from a reaction mixture containing(i) an acceptor olefin having the carbon backbone structure of said selected paraffin;(ii) a donor paraffin having a carbon backbone structure different from that of said selected paraffin;(iii) less than about 10 mole percent molecular hydrogen; which process comprises the steps of contacting said reaction mixture with a heterogeneous catalyst comprising active carbon in the absence of an added catalytic metal or metal compound to convert at least a portion of said acceptor olefin to said selected paraffin and to dehydrogenate at least a portion of said donor paraffin.

Abstract: A process is provided for preparing fibrous or film type activated carbon including the steps of carbonizing a cellulosic material and activating the resulting carbon, each stop occurring at a temperature between 200.degree. C. and 1100.degree. C. in an oxidation-suppressing atmosphere, in which, prior to activation, the cellulosic material or carbon is impregnated with at least one boron-containing compound and at least one phosphorus-containing compound. This impregnation treatment greatly increases the activation rate, so reducing the activation time and therefore energy costs. Higher levels of production of fibrous activated carbons can thus be achieved.

Abstract: A carbon- and nitrogen-based catalyst consisting essentially of active carbon or active coke and comprising at least 90% by weight of graphite structures containing at least 10% of pores larger than 100 nm in diameter and having incorporated therein an isocyanate which forms C-N-ring structures, the percentage graphite content being at least 90% by weight. The catalayst is especially effective in the low temperature reduction of nitrogen oxides in waste gases.

Abstract: A process for preparing carbon fibrils using discrete, unfused, metal-containing catalytic particles encapsulated in non-graphitic carbon, a carbide, or an organic polymer.

Abstract: A supported metal catalyst useful in the preparation of an electrode for an electrochemical cell comprises the residue after pyrolysis of an organometallic complex which is the reaction product of a transition metal salt or noble metal salt and at least one of 2,2' dipyridylamine or substituted derivative thereof.

Abstract: The invention relates to a method of producing activated carbon with a large surface area and a low sulfur content. Coconut shell char, as a carbonaceous material, is mixed with granular potassium hydroxide hydrate with a water content of 2 to 25 weight %, as an activator, in a weight ratio of 1:2 through 1:6 and the mixture is heat-treated at a temperature necessary for activation.

Abstract: A process for manufacturing a carbon catalyst for use in NO.sub.x reduction with ammonia catalyzed by active carbons and active cokes is described. The new carbon catalyst exhibits improved catalytic activity and hence a higher yield in NO. In the manufacturing process, a mixture of ground, oxidized hard coal and binders is moulded, carbonized at temperatures between 700.degree. and 900.degree. C., and then activated with steam at a temperature of 800.degree. to 850.degree. C. for 45 to 100 minutes, until a degree of activation of 5 to 15% is obtained.

Abstract: Carbon fibers with a large specific surface area are obtained by a process which comprises the steps of:(a) providing cured novolak resin fibers;(b) impregnating the novolak resin fibers with a polymerizable vinyl monomer;(c) polymerizing the vinyl monomer; and(d) carbonizing the novolak resin fibers containing the polymerized vinyl monomer.

Abstract: Supported carbon-coated catalyst material and a method for producing and using same in catalytic reaction processes, preferably in ebullated or fluidized catalyst beds. The catalyst materials are prepared by depositing a porous carbon layer on a support material of a selected metal oxide or compound to produce 5-40 wt. % carbon thereon, then preferentially treating the carbon based layer by partial oxidation, pyrolysis or reduction to enhance and activate the carbon layer on the catalyst. Promoter materials can also be advantageously added either to the support material or to the carbon layer in 0.5-10 wt. % to provide an improved composite carbon-coated catalyst having total pore volume of 0.3-1.0 cc/gm, substantially increased surface area of 80-600 M.sup.2 /gm, low surface acidity, particle strength of 1.8-5 lb/mm with reduced particle attrition losses and improved catalyst performance characteristics.

Abstract: A process for the conversion of a heavy hydrocarbon oil in the presence of hydrogen and iron-petroleum coke catalyst is described in which the iron-petroleum coke catalyst is prepared by grinding petroleum coke particles and particles of an iron compound in oil to form an additive slurry or paste and mixing the petroleum coke-iron oil slurry or paste with the heavy hydrocarbon oil to form a feedstock to hydroconverter.

Abstract: The present invention relates to physical chemistry.The material is made as a three-dimensional matrix with a pore volume of from 0.2 to 1.7 cm.sup.3 /g. The matrix is formed by bent layers of carbon of 100-10,000 .ANG. thickness and 100-10000 .ANG. radius of curvature. The true density of the material according to the present invention is 1.80-2.10 g/cm.sup.3, its X-ray density is 2.112-2.236 g/cm.sup.3, the pore size distribution has its maximum within the range of 200-2,000 .ANG..The present invention can be useful in, for example, in the production of catalysts.

Abstract: Process for producing an active catalyst by ammonia treatment of active carbons at high temperatures, in which an active carbon/active coke is impregnated with an aqueous solution of ammonium sulphate, which can be reacted with sulphuric acid, is dried at 120.degree. C. and is then heated in an inert gas stream to temperatures above 350.degree. C. Application of the active carbon catalyst as a reducing and/or oxidizing catalyst, for example for NO.sub.x elimination from exhaust gases using ammonia.

Abstract: Novel porous and porous/nonporous composites useful as electrodes in electrochemical cells and methods for making same are provided. The porous composites comprise a pressure-molded composite of carbon particles and thermoplastic resin particles which have a particle size distribution of 0 to 45 .mu.m. The pores are formed by dry mixing a water-leachable salt with a pore size distribution of 5 to 200 .mu.m with the carbon and resin mixture and water extracting the salt to form the porous composite.

Abstract: A process for producing shaped, agglomerated, particulate solids, by combining finely divided solids with a polymeric binder solution and curing the combination with polyvalent metal cations; and the products of such process.

Abstract: A method of making activated carbon microspherules including kneading activated carbon particles of a size below 100 .mu.m, together with a dispersion of a water-insoluble synthetic resin to form an intimate mixture; pressing the mixture through a screen having holes related to the size of the desired microspherules; powdering the pressed material; and granulating and drying the resulting microspherules.

Abstract: A method of treating an aqueous sodium sulfide solution, such as white liquor in kraft pulping systems, for the oxidation of the sulfide with oxygen in the presence of a specific activated carbon catalyst which is (a) a particulate activated carbon catalyst having an average particle diameter of 0.2-4 mm, a pore volume of at least 0.25 cc/g in pores with diameters of not smaller than 100 .ANG. and a pore volume of at least 35% of the total pore volume in pores with diameters of not smaller than 100 .ANG. or (b) a fibrous activated carbon catalyst having a specific surface area of 300-2500 m.sup.2 /g and an outer surface area of 0.1-5 m.sup.2 /g.

Abstract: Elemental carbon with or without added oxygen functionality is chemically modified with covalently bonded nitrogen-containing groups to provide novel, high performance elemental carbons for electrochemical cells, including electrodes for energy consuming cells, and especially energy producing cells like lithium-oxyhalide high energy-density batteries, alkaline batteries, and the like.

Abstract: A low density, open-celled microcellular carbon foam is disclosed which is prepared by dissolving a carbonizable polymer or copolymer in a solvent, pouring the solution into a mold, cooling the solution, removing the solvent, and then carbonizing the polymer or copolymer in a high temperature oven to produce the foam. If desired, an additive can be introduced in order to produce a doped carbon foam, and the foams can be made isotropic by selection of a suitable solvent. The low density, microcellular foams produced by this process are particularly useful in the fabrication of inertial confinement fusion targets, but can also be used as catalysts, absorbents, and electrodes.

Abstract: Catalysts comprising a carbon-containing sulfide of molybdenum or tungsten are prepared by contacting, in the presence of sulfur, hydrogen and a hydrocarbon, ammonia and ammonium substituted molybdate, thiomolybdate, tungstate and thiotungstate salts at a temperature of from about 200.degree.-600.degree. C. These catalysts are useful for hydrotreating reactions. In a preferred embodiment, these catalysts will be promoted with certain transition metal sulfides, such as cobalt sulfide, which results in catalysts having greater activity than conventional catalysts such as cobalt-molybdate on alumina.

Abstract: A method is described for producing hydrophobic carbon molecular sieves. The method does not employ a binder to form or shape previously carbonized materials. Instead, a cross-linked oxygen-free polymer is first produced. Fine particles of this polymer are then pelletized or shaped as by simple extrusion. The extruded pellets are then carbonized in an oxygen-free atmosphere to yield binderless homogeneous particles of similar shape comprised of carbon sieves.

Abstract: Novel porous and porous/nonporous composites useful as electrodes in electrochemical cells and methods for making same are provided. The porous composites comprise a pressure-molded composite of carbon particles and thermoplastic resin particles which have a particle size distribution of 0 to 45 .mu.m. The pores are formed by dry mixing a water-leachable salt with a pore size distribution of 5 to 200 .mu.m with the carbon and resin mixture and water extracting the salt to form the porous composite.

Abstract: Hollow porous microspheres are used as substrates and containers for catalyst to make microsphere catalysts.The hollow porous microspheres are made from dispersed particle compositions. The microspheres have a single central cavity, have substantially uniform diameters and substantially uniform wall thickness and the walls of the microspheres have substantially uniform void content, i.e., interconnecting voids, and have substantially uniform distribution of interconnecting voids. The interconnecting voids in the walls of the microspheres are continuous and extend from the outer wall surface of the microsphere to the inner wall surface of the microsphere.The microsphere catalysts are prepared by coating or impregnating the hollow porous microspheres with a catalyst or by applying a catalyst support to the microspheres and then coating or impregnating the microspheres and catalyst support with a catalyst.

Abstract: This invention relates to the production of a novel, porous, carbon structure. A stabilised porous polymer comprising cavities joined by interconnecting pores is heated in an inert atmosphere to yield a stable, porous, carbon structure having the inherent structure of the original stabilised polymer.

Abstract: A filter composed of a mesh structure substrate having deposited thereon and therein activated carbon fiber treated with an alkali and having a length within the range of from 5 to 1,000.mu., wherein the mesh structure substrate has an average cell diameter 3 to 100 times the length of the activated carbon fiber, wherein the activated carbon fiber is adhered to the substrate by a binder, and wherein the activated carbon fiber is deposited on and in the substrate by impregnating the substrate with a dispersion obtained by dispersing activated carbon fiber in a dispersion or solution of a binder, and drying methods for forming and using the same are also disclosed.

Abstract: Machinable and structurally stable, low density microcellular carbon, and catalytically impregnated carbon, foams, and process for their preparation, are provided. Pulverized sodium chloride is classified to improve particle size uniformity, and the classified particles may be further mixed with a catalyst material. The particles are cold pressed into a compact having internal pores, and then sintered. The sintered compact is immersed and then submerged in a phenolic polymer solution to uniformly fill the pores of the compact with phenolic polymer. The compact is then heated to pyrolyze the phenolic polymer into carbon in the form of a foam. Then the sodium chloride of the compact is leached away with water, and the remaining product is freeze dried to provide the carbon, or catalytically impregnated carbon, foam.

Abstract: An insoluble and infusible substrate with a polyacene-type skelatal structure having a hydrogen/carbon atomic ratio of from 0.05 to 0.60 and containing open pores having an average diameter of not more than 10 micrometers, said substrate being a heat-treated product of an aromatic condensation polymer consisting of carbon, hydrogen and oxygen. The substrate, when doped with a dopant, gives an electrically conductive material. When having a specific surface area of at least 600 m.sup.2 /g, the substrate is especially useful as an electrode of an organic cell.

Abstract: Catalyst supports, catalysts, method for the preparation thereof, and dimerization processes therewith are provided. Catalyst supports consist essentially of potassium carbonate with a crush strength of at least 5 pounds and at least one carbonaceous compound. Catalysts consist essentially of at least one elemental alkali metal deposited on the novel catalyst supports. Optionally, the catalysts further consist essentially of at least one promoter selected from the group consisting of elemental copper, elemental cobalt, and finely divided stainless steel.