Abstract: The present invention discloses a complex of clay and polyoxyalkylene amine and a method for producing the same. The clay in the present invention is layered and includes silicate, and the polyoxyalkylene amine with molecular weight over 1,800 is provided as an intercalacting agent to enlarge interlayer distances of the clay at an unprecedented spacing. The method for producing the complex is primarily to acidify the polyoxyalkylene amine with an inorganic acid, which is then mixed with the clay swelled with water previously; and the mixture is then powerfully stirred at 60-80° C. for cation exchanging to obtain the titled inorganic/organic complex. According to the present invention, the complex is an excellent surfactant and a reinforcing agent of polymers.

Abstract: Vinyl monomers are stabilized by a composition which includes an alkyl hydroxyl amine and a sulfide compound or at least two alkyl hydroxyl amines and a phenolic compound.

Abstract: This invention relates to nanocomposites comprised of a functionalized elastomeric polymer, including oligomers which are elastomeric, which contains a particulate dispersion therein of an intercalated, and at least partially exfoliated, swellable clay, such as for example montmorillonite clay. Said clay may be pre-intercalated and thereafter blended with, or intercalated and at least partially exfoliated in situ within, a functionalized elastomer in an aqueous medium, wherein said functionalized elastomer contains at least one functional group selected from acid, acid-salt, anhydride, and protonated amine-modified epoxy groups. The invention further relates to articles of manufacture, including industrial belts and tires, having at least one component comprised of such nanocomposite where such component may be a coating thereon or other integral component. Such tire component may be, for example, a tire tread, tire sidewall and/or tire innerliner.

Abstract: Processes for utilizing various emulsion polymerization procedures for preparing aqueous nanocomposite dispersions are disclosed. The disclosed processes include both in-situ polymerizations in the presence of at least partially exfoliated, lightly modified clays as well as admixtures of polymer dispersions with at least partially exfoliated, lightly modified clay dispersions. The disclosed nanocomposite dispersions are useful for preparing a variety of materials, such as coatings, adhesives, caulks, sealants, plastics additives, and thermoplastic resins. Processes for preparing polymer nanocomposite powders and use of these powders as plastic resin and plastics additives are also disclosed.

Abstract: The invention relates to addition compounds of formula (1) in which: n is a number from 1 to 10; Z represents a group —CH2—CH2—, —CH2—CH(CH3)—, —CH(CH3)CH2— or a combination thereof; s is number from 1 to 200; B represents hydrogen, —CO—CH═CH—COOM, COCH(SO3M)CH2COOM, —CO—CH2—CH(SO3M)-COOM, —SO3M, —SO2M and/or —PO3MM, whereby M is preferably a cation selected from the group Li+, Na+, K+, NH4+, HO—CH2—CH2—NH3+, (HO—CH2—CH2—)3NH+, and; Y is a radical of an amine of formula (4). The inventive addition compounds are used as dispersing agents of solids, for example, pigments, particularly in aqueous media.

Abstract: The invention is directed to a polymer-clay nanocomposite material comprising a melt-processible matrix polymer and a layered clay material having low quartz content. This invention is also directed to a process for preparing polymer-clay nanocomposites, and articles or products produced from nanocomposite materials.

Abstract: The invention provides coating material compositions comprising stable adducts which, at relatively high temperatures, generate radicals that possess initiating activity, and also provides processes for preparing them, and for the use of such coating material compositions. Stable adducts of this kind may be used in order to initiate polymerization of ethylenically unsaturated monomers.

Abstract: Use of a compound according to one of the formulae I to III 1

Abstract: A water repellent and oil resistant composition capable of imparting excellent water repellency and oil resistance to paper even under a condition of drying at a low temperature for a short time, is provided. The composition comprising a fluorocopolymer (A) obtained by polymerizing a polyfluoroalkyl group-containing (meth)acrylate, vinylidene chloride and a compound of the formula [CH2═C(R)COO—CH2—CH(OH)CH2N+(CH3)3·X− (R: a hydrogen atom or a methyl group, and X−: a counter ion)] or the like by means of a lipophilic polymerization initiator (E) having a solubility of less than 3 g in 100 g of water, a non-fluorine surfactant (B), a medium (C) and a water-soluble polymer (D) (a polyacrylamide, a polyvinyl alcohol or starch).

Abstract: Described is a composition which is suitable for removing adhering substances, such as (synthetic) resins, paint lacquers, polymer foams and mastics by means of forming a dispersion. The composition comprises at least one amphoteric compound and optionally a surfactant substance. There are also provided for the first time polymers or mixtures of polymers which are at least practically free of organic solvents and a method for producing these, i.e. by separation from the above stated dispersion.

Abstract: The invention relates to a dispersing agent or salt thereof, comprising at least one dendrimer, said dendrimer comprising functional groups, that have reacted with a functional moiety, said moiety being defined as R—X, X being a pigment affinic group, and R being a linking moiety chain having at least 2 atoms in the chain, with the proviso that the functional group and the pigment affinic group are different.

Abstract: Aromatic-aliphatic copolycarbonate resin composition obtained by compounding 0.001 to 0.5 part by weight of a benzotriazole ultraviolet absorbent and 0.005 to 0.1 part by weight of a phosphorus antioxidant having a specified structure per 100 parts by weight of an aromatic-aliphatic copolycarbonate resin. A polycarbonate resin composition according to the present invention cuts ultraviolet rays efficiently, shows excellent color tone and melt stability, and shows extremely little coloration at the time of molding.

Abstract: A composition having a trisamino triphenyl compound and a layer composition having a trisamino triphenyl compound and a polyamide.

Abstract: The invention relates to a powdery pigment preparation containing a pigment which is dispersed in an acrylate resin and which is characterized in that the acrylate resin has an average molar mass Mw ranging from 40000 to 80000 g/mol and is a copolymer comprised of 50 to 65 mol % ethyl methacrylate, of 30 to 45 mol % butyl methacrylate, and of 0.5 to 5 mol % methacrylic acid. The powdery pigment preparation can be used for dying films, particularly those made of polymethyl methacrylate. The films do not have any specks nor holes.

Abstract: An adhesive composition which can be formulated to have low or substantially no VOC emissions is provided. Adhesives in accordance with the invention can be formulated as high solids, one-part, reactive, cross-linked adhesives. This can be achieved by utilizing amide-ester-acrylate reactions or reactions with any other carboxylated polymers. Adhesive compositions in accordance with the invention can include oils, such as various drying oils and similarly acting polymers, co-polymers, and fatty acids. Adhesives in accordance with the invention can also include various hydrocarbon resins, particularly crosslinkable hydrocarbons having a melting point in the range 70° C. to 140° C. Cross-linking agents, such as materials with pendant oxazoline groups are also advantageously included. Various other mixing, flow and other handling ingredients can also be included.

Abstract: To provide a plastic spectacle lens which has a very durable hard coat layer and primer layer and prevents the cracking and peeling off of the layer and a reduction in the hardness of the layer, and other coated articles. This coated article has a coat layer containing titanium oxide and an organic Co(II) compound on the surface of a substrate.

Abstract: The present invention relates to interior parts of a car comprising a new propylene resin composition. The present resin composition has good molding abilities and a good balance of physical properties as well as a good appearance, lower gloss and scratch resistance. Specifically, the present invention relates to a molded article for interior parts of a car comprising a polypropylene resin composition comprising the following components; a crystalline homopolypropylene having MFR of 500 to 3,000 g/10 min.; a polypropylene consisting of a crystalline homopolypropylene and an ethylene-propylene copolymer rubber having 45 to 80% by mass of a ethylene content; a polypropylene consisting of a crystalline homopolypropylene and an ethylene-propylene copolymer rubber having 25% by mass or more to below 45% by mass of a ethylene content; and an ethylene-&agr;-olefin copolymer rubber.

Abstract: Liquid composition polymerizable, by means of radicalic polymerization, into organic glass, comprising the product obtained from the transesterification of a mixture of diallyl carbonate (A) and a phthalic ester (B), with one or more polyols (C), linear or branced, containing from two to eight carbon atoms in the molecule.

Abstract: The invention relates to thermoplastic nanocomposites comprising a) a thermoplastic (A), in which from 0.1 to 10% by weight of the monomer units present in component (A) bear ionic groups, and b) at least one phyllosilicate (B), uniformly dispersed in component (A). The invention further relates to a process for preparing these nanocomposites, and also to their use.

Abstract: In one aspect, the present invention provides hydrogels comprising polymer molecules and bridging molecules, wherein substantially all the polymer molecules are cross-linked by hydrogen bonds between polymer molecules and bridging molecules, wherein each bridging molecule is linked to at least two polymer molecules, and wherein there are substantially no covalent linkages between the polymer molecules. In some embodiments, the polymer molecules are poly(vinyl alcohol) (PVA) and the bridging molecules are amino acids. Some embodiments of the invention provide devices comprising hydrogels, and pharmaceutical compositions comprising biologically active molecules within hydrogels. Another aspect provides methods for forming hydrogels of the invention.

Abstract: A gas barrier coating composition which undergoes no decrease in barrier properties to gases such as oxygen and water vapor even under high-humidity conditions, contains no compounds thought to be harmful to the human body, and is harmless to the human body; and a gas barrier coating film with excellent gas barrier properties comprising the composition. The gas barrier coating composition comprises (a) a polyvinyl alcohol resin and (b) at least one member selected from the group consisting of a specific metal alcoholate, a hydrolysate of the metal alcoholate, a condensate of the metal alcoholate, a chelate compound of the metal alcoholate, a hydrolysate of the chelate compound and an acylated metal compound. The coating film obtained from the composition has excellent gas barrier properties.

Abstract: This invention relates to a polymer-clay nanocomposite comprising (i) a melt-processible matrix polymer, and incorporated therein (ii) a mixture of at least two layered clay materials. The invention also relates to articles produced from a nanocomposite and a process for preparing a nanocomposite.

Abstract: The present invention is directed to an epoxidized block copolymer (E) obtained by epoxidizing a block copolymer (C) comprising a polymer block (A) composed mainly of a vinyl aromatic hydrocarbon compound and a polymer block (B) composed mainly of a conjugated diene compound or a product (D) of hydrogenation of the block copolymer (C). The epoxidized block copolymer (E) meets at least one of the following requisites: (1) having a molar ratio (R) of contained hydroxyl to epoxy ranging from 0.001 to 0.

Abstract: An aqueous binder composition containing a urea-formaldehyde resin modified with an additive comprising (1) styrene acrylic acid or styrene acrylate, (2) an adduct of styrene, maleic anhydride, and an acrylic acid or acrylate or (3) a physical mixture of a styrene acrylic acid or styrene-acrylate copolymer and a styrene-maleic anhydride copolymer. The resulting binder is used in the preparation of fiber mats.

Abstract: This invention discloses a novel polyester composition having ultraviolet light penetration reduction characteristics use to manufacture polyester bottles. The polyester composition of this invention results from mixing preferably 10-1000 ppm of azimido-benzene ultraviolet absorbent with preferably 0.01 to 2 mol % of 2,6 naphthalene dicarboxylate copolyester and pre-polymerized polyester of preferably over 98 mol %. Using precise concentration and mole ratios when forming the polyester composition of this invention is critical for reducing ultraviolet light penetration, and for keeping manufactured polyester bottles haze values to commercial acceptable levels.

Abstract: A method is provided for the manufacture of elastic, fire resistant, organo-mineral systems based on water-glass in which, to the water-glass, compounds, having terminal amino groups are added, in which at least one free hydrogen atom on at least one amino group and at least one alkylene group interrupted by one oxygen and/or sulphur atom are present as well as the products and the two component systems which can be obtained therewith. The later can be applied in mining for filling and/or agglutination of anchors.

Abstract: A nanocomposite concentrate composition comprising about 10 weight percent to about 90 weight percent of a layered silicate material and about 10 weight percent to about 90 weight percent of a matrix polymer comprising about 90-99.8% by weight of a polyolefin and about 0.2% to about 10%, preferably about 0.2% to about 3%, more preferably about 1% to 3% by weight, of a maleic anhydride-modified polyolefin, based on the total weight of polyolefins, wherein the layered silicate material is dispersed uniformly throughout the matrix polymer. Shearing of the concentrate and later (after shear) addition of an added matrix polymer avoids thermal degradation of the added matrix polymer and optimizes the dispersion of the nanomer throughout the matrix polymer; provides increased tensile strength; and reduces degradation of the polymer by melt formation of a concentrate thereby decreasing heat degradation of added matrix polymer.

Abstract: The present invention relates to oxygen scavenging compositions comprising a) platelet particles having attached thereto at least one oxygen scavenging organic cation and b) at least one oxidation catalyst. The oxygen scavenging compositions of the present invention maybe readily incorporated into a variety of matrix polymers to create polymer composites, which display improved passive barrier and oxygen scavenging capabilities. Articles formed from these composites are also disclosed.

Abstract: A polyolefin-based nanocomposite and a method of preparing the same are disclosed. The polyolefin-based nanocomposite is prepared by melt kneading a mixture including (A) 40-99.8% by weight of a matrix polymer of polyolefin; (B) 0.1-30% by weight of a polyolefin compatilizer containing polar reactive groups; and (C) 0.1-30% by weight of a layered clay material having a quaternary ammonium ion bonded to the surface thereof. The quaternary ammonium ion contains (I) at least one alkyl group having at least 15 carbon atoms; and (ii) a substitutent having —Si—O—Si-linkage and at least one terminal reactive group.

Abstract: A method of producing a heat insulating board comprising two opposed facings and a core made of a rigid synthetic resin foam, which comprises spraying or injecting a foam mix for the rigid synthetic resin foam into the space between the opposed face materials and expanding and curing the foam mix, wherein the foam mix comprises a particular polyol, a polyisocyanate, a foam stabilizer, a catalyst and a blowing agent, wherein the polyol contains a polyether polyol having a hydroxyl value of at most 84 mgKOH/g and an oxyethylene group content of at least 40 wt %; a polyether polyol which is obtained by adding a cyclic ether to an amine compound and has a hydroxyl value of from 250 to 900 mgKOH/g; and fine polymer particles stably dispersed in the polyol.

Abstract: A mixture of a polyester, such as poly(ethylene terephthalate) PET, or a polyamide, and a suitable stabilizer selected from the group consisting of hydroxylamine stabilizers, substituted hydroxylamine stabilizers, nitrone stabilizers and amine oxide stabilizers, when extrusion compounded exhibits a lower residual acetaldehyde content than does polyester or polyamide alone when similarly treated. The invention pertains to any polyester or polyamide used in the manufacture of molded articles, fibers or films, for instance bottles or containers which are used to store consumer materials, for example food, beverages and water.

Abstract: A UVA stabilized polyethylene terephthalate overlamination film having a maximum peak absorption of about 380 nm, an approximate absorptive area % of <14% and a Visible Absorbance value of less than about 20%, coated with an adhesive layer to facilitate anchorage of the polyethylene terephthalate film to a secondary print substrate.

Abstract: The invention relates to additives for improving lubricating properties of fuel oils, comprising A) 10-95% by weight of at least one oil-soluble amphiphile which comprises nitrogen- or oxygen-containing groups substituted by alkyl, alkenyl, hydroxyalkyl or aromatic radicals, and B) 5-90% by weight of at least one copolymer which contains B1) from 0.5 to 15 mol % of structural units which are derived from olefinically unsaturated compounds which have at least one free hydroxyl group, and B2) from 85 to 99.5 mol % of structural units which are derived from ethylene, and, if required, B3) from 0 to 20 mol % of further structural units selected from the group consisting of (meth)acrylic acid, (meth)acrylates, vinyl esters, vinyl ethers and alkenes, and the copolymer has an average molar mass Mw of from 500 to 100,000 g/mol and an OH number of from 5 to 500 mg KOH/g.

Abstract: Curable fluoroelastomer compositions having improved compression set after curing are provided, as well as compositions that are of relatively high purity. These compositions include a hydrogen-containing fluoroelastomer having interpolymerized units derived from a cure-site monomer, a curative (optionally with a co-agent), and an organo-onium. When the fluoroelastomer contains units derived from vinylidene fluoride, the composition is essentially free from an inorganic acid acceptor. Methods of improving the compression of cured fluoroelastomer and cured fluoroelastomers having improved compression set are also provided.

Abstract: The bondability of a polyolefin, particularly to cyanoacrylate adhesives, is improved by incorporating in the polyolefin a polymerization initiator capable of initiating the polymerization of the monomers constituting the cyanoacrylate adhesive. The polymerization initiator may, for example, be a sterically hindered nitrogen base and may be mixed with the polyolefin at a temperature above the polyolefin's glass transition temperature using, for example, co-extrusion or co-injection methods.

Abstract: The present invention is directed to an antistatic pressure sensitive adhesive. The antistatic pressure sensitive adhesive comprises a pressure sensitive adhesive, and an antistatic agent comprising at least one organic salt. Certain embodiments of the antistatic pressure sensitive adhesive also have a luminous transmission of greater than about 89% according to ASTM D 1003-95. Additional embodiments of the antistatic pressure sensitive adhesive have a haze of less than about 5% according to ASTM D 1003-95, and in specific embodiments the haze is less than about 2% according to ASTM D 1003-95.

Abstract: An aqueous surface treatment composition, methods for the production thereof, and an apparatus for the preparation of aqueous surface treatment compositions. The composition comprises a water soluble thickening polymeric thickening agent, water and a basic neutralizing agent. Additionally, coloring agents and polyols may be added to the composition. The polymeric water soluble thickening agent and basic neutralizing agent are present in sufficient quantity to afford a viscous composition that, upon application to a suitable surface, provide a surface treatment. The apparatus useful for the production of aqueous surface treatment compositions simultaneously and rapidly mixes and dispenses a fast forming viscous compositions.

Abstract: A water and oil repellent composition comprising a compound of the following formula (1) and a thermoplastic polymer, as essential components: 1

Abstract: Disclosed herein is a modified clay mineral comprising a layered clay mineral intercalated with a catalyst that can catalyze a polymerization reaction. Also disclosed herein are a polymer/clay nanocomposite and a method for its manufacture, the polymer/clay nanocomposite comprising a polymer matrix and a layered clay mineral uniformly dispersed in the polymer matrix, the layered clay mineral being intercalated with a catalyst that catalyzes the polymerization of the polymer matrix.

Abstract: The present invention relates to a method of making improved polyolefinic elastic articles from cured, irradiated or crosslinked amorphous ethylene interpolymers. In particular, the invention relates to a method of making a shaped article (e.g. film or fiber) characterized by improved elevated temperature elasticity as well as washability and dryability. The inventive elastic article comprises a substantially cured, irradiated, or crosslinked (or curable, irradiated or crosslinkable) homogeneously branched ethylene interpolymer characterized as having a density less than 0.90 g/cm3 and containing at least one nitrogen-containing stabilizer. The improved elastic article of the present invention is particularly suitable for use in applications where good elasticity must be maintained at elevated temperatures and after laundering such as, for example, elastic waist bands of undergarments and other clothing.

Abstract: This invention relates to a process for preparing an amorphous polyamide-clay nanocomposite comprising the steps of: a. melt mixing a layered clay material with an oligomeric polyamide resin to form an oligomeric polyamide resin-clay composite, and b.

Abstract: A calendered film or sheet of a polyester resin composition has a haze value of less than 5 percent. The polyester resin composition comprises a polyester having a crystallization half-time from a molten state of at least 5 minutes and an additive comprising (i) a fatty acid or a salt of a fatty acid containing more than 18 carbon atoms and (ii) an ester wax comprising a fatty acid containing more than 18 carbon atoms with an alcohol containing from 2 to 28 carbon atoms, wherein the ratio of the fatty acid or salt of the fatty acid to the ester wax is 1:1 or greater. Also, the present invention is a process for producing such calendered film or sheet having a haze value of less than 5 percent.

Abstract: This invention is directed to a polymer-clay nanocomposite, products produced from the nanocomposite, and a process for preparing a polymer-clay nanocomposite. The polymer-clay nanocomposite comprises (a) a matrix polymer, (b) an amorphous oligomer, and (c) a layered clay material.

Abstract: An adhesive composition which can be formulated to have low or substantially no VOC emissions is provided. Adhesives in accordance with the invention can be formulated as high solids, one-part, reactive, cross-linked adhesives. This can be achieved by utilizing amide-ester-acrylate reactions or reactions with any other carboxylated polymers. Adhesive compositions in accordance with the invention can include oils, such as various drying oils and similarly acting polymers, co-polymers, and fatty acids. Adhesives in accordance with the invention can also include various hydrocarbon resins, particularly crosslinkable hydrocarbons having a melting point in the range 70° C. to 140° C. Cross-linking agents, such as materials with pendant oxazoline groups are also advantageously included. Various other mixing, flow and other handling ingredients can also be included.

Abstract: This invention relates to a composite composition comprising one or more polyamide polymers or copolymers, one or more layered clay materials, and one or more alkoxylated ammonium cations. The invention also relates to a process for preparing a nanocomposite and articles produced from the nanocomposite, including bottles.

Abstract: The present invention relates to flame retardant polycarbonate compositions with improved weathering performance, said compositions comprising one or more cyanoacrylic esters. The invention also relates to methods for improving the flame retardancy and weathering performances of polycarbonate compositions by incorporating cyanoacrylic ester(s). Finally, the invention further relates to articles manufactured from flame retardant polycarbonate compositions comprising cyanoacrylic ester(s).

Abstract: The present invention provides additive packages for polyolefins The additive packages of the present invention comprise at least one non-phenolic antioxidant and a hindered amine light stabilizer. The additive packages may contain other additives as needed, and may optionally include an acid scavenger. Articles made from the resultant polymers, such as radiator surge tanks, exhibit enhanced stain and discoloration resistance upon exposure to high temperatures and harsh chemicals such as those experienced in “under the hood” spaces of modem automobiles.

Abstract: This invention is of a composition comprised of a smectite clay modified with an organic chemical composition and a polymer. The composition consists of an organic chemical/smectite clay intercalate that has been ion-exchanged and reacted and intercalated with one or more quarternary ammonium compounds and an anionic material and further blended into a polymer resin to make a nanocomposite composition. This material can be blended into a wide variety of polymers. This kind of system gives improved dispersion over conventional organoclays, intercalates or hybrid clays described in the literature, especially in non-polar resins. The defined organoclay has been found to be highly dispersible in a variety of polymers, whether polar or non-polar.

Abstract: Provided is a rubber composition comprising 100 parts by weight of a rubber component comprising at least one selected from the group consisting of natural rubber and synthetic rubbers and 0.

Abstract: The invention relates to the use of copolymers consisting essentially of