With Organic Amine, Or From Organic Amine Salt Of A Carboxylic Acid Patents (Class 528/332)
  • Patent number: 5780579
    Abstract: The present invention relates to a method for the preparation of polyamino acids, with controlled molecular weights, by polymerization of N-carboxyanhydrides (NCAs) of at least one amino acid, using at least one initiator of the strong base type and in liquid medium, characterized in that it consists in including, in the liquid reaction medium, given amounts of water and/or of alcohol. Application: synthesis of polyamino acids with mechanical and rheological characteristics adapted to applications as biomaterials.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: July 14, 1998
    Assignee: Flamel Technologies (Societe Anonyme)
    Inventors: Gerard Soula, Jean-Michel Grosselin, Rafael Jorda, Catherine Castan
  • Patent number: 5780576
    Abstract: Thermoplastic molding materials containA) from 1 to 99% by weight of a partly aromatic copolyamide composed ofa.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,a.sub.2) from 6 to 25 mol % of units which are derived from isophthalic acid,a.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine anda.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms,the molar percentages of components a.sub.1) to a.sub.4) together giving 100%,B) from 1 to 99% by weight of a polyetherimide,C) from 0 to 30% by weight of a polymeric component having OH groups,D) from 0 to 60% by weight of fibrous or particulate fillers or mixtures thereof,E) from 0 to 40% by weight of rubber impact modifiers andF) from 0 to 40% by weight of conventional additives and processing assistants.
    Type: Grant
    Filed: April 12, 1996
    Date of Patent: July 14, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
  • Patent number: 5780577
    Abstract: A polyamide resin composition and a biaxially stretched film comprising the polyamide resin composition. The polyamide resin composition comprises (1) 93 to 99.5% by weight of a polyamide resin and (2) 0.5 to 7% by weight of an acid-modified resin, the acid-modified resin being obtained by adding 0.5 to 5 parts by weight of an unsaturated. carboxylic acid to 100 parts by weight of an ethylene-vinyl acetate copolymer having a vinyl acetate content of 20 to 50% by weight partially saponified to have a degree of saponification of 50 to 95 mol %.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: July 14, 1998
    Assignee: Ube Industries, Ltd.
    Inventor: Yutaka Yamaguchi
  • Patent number: 5777066
    Abstract: A method for producing poly-o-hydroxy amides by conversion of an activated dicarboxylic acid derivative with a bis-o-aminophenol. A solution of the activated dicarboxylic acid derivative is added to a solution of the bis-o-aminophenol in a lactone, and a tertiary amine is added to the resulting mixture, wherein the lactone has the following structure: ##STR1## where A is--(CR.sup.1 R.sup.2).sub.m --or--(CR.sup.3 R.sup.4).sub.n --NR.sup.5 --,R.sup.1 to R.sup.5 are independent of one anotherR.sup.1 and R.sup.2 are hydrogen, alkyl with 1 to 7 carbon atoms (linear or branched), --CO(CH.sub.2).sub.p CH.sub.3, or --COO(CH.sub.2).sub.p CH.sub.3, with p=0 or 1,R.sup.3 and R.sup.4 are hydrogen or alkyl with 1 to 3 carbon atoms (linear or branched),R.sup.5 is hydrogen or methyl,m is a whole number from 2 to 11, andn is a whole number from 1 to 3.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: July 7, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne, Eva Rissel
  • Patent number: 5777067
    Abstract: Disclosed are a method for producing a polyamide resin which comprises the steps of extracting with water a polyamide resin obtained by polymerizing caprolactam in the presence of water; condensing the extracted aqueous solution containing unreacted caprolactam and its low polymerized materials; and polymerizing the condensate by adding an additional amount of caprolactam, the improvement wherein(a) among the low polymerized materials of caprolactam, a cyclic dimer is supplied to a polymerization reactor after subjecting it to ring-opening reaction to give a chain structure material in an amount of 15% by weight or more based on the total amount of the cyclic dimer, or(a') a condensate obtained by condensing said aqueous solution until reaching a water partial pressure of 10 kg/cm.sup.2 G or more and a temperature of 230.degree. C.
    Type: Grant
    Filed: October 29, 1996
    Date of Patent: July 7, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Shinichi Sato, Masaaki Miyamoto, Kenji Tsuruhara
  • Patent number: 5773555
    Abstract: There are proposed a method and a device for manufacturing polyamides, in which polyamide granulate manufactured by polycondensation in the molten mass is after-condensed in the solid phase, being heated. The polyamide granulate is heated in one step to a first temperature of between 70.degree. C. and 150.degree. C., and held for a predetermined period of time at this temperature, and then, in a second step, is heated to a second higher temperature, however lying beneath the melting point, and is after-condensed at this temperature, until the desired average degree of polycondensation is achieved.
    Type: Grant
    Filed: March 13, 1996
    Date of Patent: June 30, 1998
    Assignee: Karl Fischer Industrieanlagen GmbH
    Inventors: Friedrich Weger, Rainer Hagen
  • Patent number: 5773556
    Abstract: Low-flammability polyamide molding materials are obtained by admixing calcium or aluminum phosphinates. These salts confer improved flame protection on polyamides compared with other metal salts.
    Type: Grant
    Filed: February 27, 1997
    Date of Patent: June 30, 1998
    Assignee: Ticona GmbH
    Inventors: Hans-Jerg Kleiner, Winfried Budzinsky, Gunther Kirsch
  • Patent number: 5770680
    Abstract: A process is provided for preparing a dispersion of a polyamide in water, said process comprising:dissolving a polyamide having an amine value of greater than about 2 in an organic solvent to form a solution of said polyamide in said solvent, said polyamide and said solvent being at a temperature below the softening point of, said polyamide during said dissolving, said solution further comprising a surfactant and an inorganic alkaline material,adding sufficient water containing an acid to said solution with mixing to form an oil-in-water dispersion, the temperature of said solution and said water being below the softening point of said polyamide during said adding, the amount of said acid being sufficient to neutralize a portion of said inorganic alkaline material, but insufficient to coagulate said polyamide from the resulting oil-in-water dispersion, andremoving at least a major amount of said organic solvent from said oil-in-water dispersion.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: June 23, 1998
    Inventors: Stephen A. Fischer, David I. Devore, Kartar S. Arora, Reimar Heucher
  • Patent number: 5770679
    Abstract: Polyamide resin compositions which are useful for molding parts with excellent malleability, thoughness, rigidity, and high heat deformation temperatures are prepared from 10 to 89% by weight of a polyamide resin, 1 to 30% by weight of at least one type of elastomer selected from among elastomers composed of ethylene/propylene/dienes, elastomers composed of ethylene/unsaturated carboxylic acid unsaturated carboxylic acid esters, and elastomers obtained by graft-modifying these elastomers, and from 10 to 60% by weight of a copolymer of ethylene and cyclic olefin that is noncrystalline and has a glass transition temperature of from 100.degree. to 190.degree. C.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: June 23, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ryuichi Hayashi, Reiko Koshida
  • Patent number: 5767228
    Abstract: The present invention relates to an aromatic polyamide pulp and its preparing process which has both excellent physical properties and high degree of polymerization wherein aromatic diamine is reacted with aromatic diacid chloride in amides and/or urea-based polymerization solvent containing inorganic salts and/or a little of Lewis acid compound. The present invention can easily provide the pulp of high polymerization degree and high orientation by stirrer in the continuous transferable polymerization-orientation-gelation apparatus within a short time without use of a tertiary amine affecting human body and without regard to isotropic or anisotropic, and continuous or uncontinuous ejection.
    Type: Grant
    Filed: October 4, 1996
    Date of Patent: June 16, 1998
    Assignee: Kolon Industries, Inc.
    Inventors: Jong Cheol Kim, Hyeong Rack Lee, Jae Hyun Lee, Seung Jo Lee, In Sik Han, Du Hyun Kim, Seock Chul Ryu, Won Jun Choe, Young Hwan Park
  • Patent number: 5763561
    Abstract: Improved high temperature polyamides, and particularly partially aromatic polyamides, containing less than about 40 .mu.eq/g carboxylic acid endgroups, when stabilized with a copper-containing thermal stabilizer, the polyamides exhibit improved thermal oxidative stability.
    Type: Grant
    Filed: May 27, 1997
    Date of Patent: June 9, 1998
    Assignee: Amoco Corporation
    Inventor: Robert G. Keske
  • Patent number: 5760164
    Abstract: A liquid system for executing the anionic lactam polymerization is proposed, which contains activators as well as catalysts and selectively additives and which is liquid at room temperature and remains stable when stored.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: June 2, 1998
    Assignee: Ems-Inventa Ag
    Inventors: Eduard Schmid, Roman Eder
  • Patent number: 5760163
    Abstract: Branched polyamides are prepared by mixingA) from 10 to 99.7% by weight of a melt of a polyamide prepolymer having a viscosity number of from 40 to 90 ml/g withB) from 0.3 to 6% by weight of a polybasic carboxylic acid, where the number n of the free carboxylic acid groups is 3.ltoreq.n.ltoreq.10, and alsoC) from 0 to 80% by weight of further additives and processing aids,where the percentages by weight of the components A) to C) add up to 100%, and subsequently further condensing the mixture in the solid phase.
    Type: Grant
    Filed: November 14, 1996
    Date of Patent: June 2, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Herbert Fisch, Gunter Pipper, Jens Rieger, Martin Laun, Volker Warzelhan
  • Patent number: 5760167
    Abstract: A copolyamide composition prepared from hexamethylene diamine and mixtures of adipic acid, terephthalic acid and isophthalic acid, has a melting point below 300.degree. C., a glass transition temperature between 100.degree. C. and 130.degree. C. and physical properties similar to nylon 66.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: June 2, 1998
    Assignee: Industrial Technology Research Institute
    Inventors: Wu-Bin Yuo, Chien-Shiun Liao, Wen-Jeng Lin, Li-Kuei Lin, Tien-San Lee, Szu-Yuan Chan
  • Patent number: 5756647
    Abstract: A process for the activated anionic lactam polymerization is proposed, wherein a liquid system is employed, which simultaneously contains activator and anionic catalyst for the polymerization of the lactam.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: May 26, 1998
    Assignee: EMS-Inventa AG
    Inventors: Eduard Schmid, Roman Eder
  • Patent number: 5756646
    Abstract: An agent for improving surface quality of paper comrising an acrylamide resin composition obtained by hydrolyzing an acrylamide resin which is obtained by polymerizing an acrylamide monomer in the presence of a urea compound, or copolymerizing an acrylamide monomer and an acrylonitrile monomer; an acrylamide monomer and a cross-linking agent; or an acrylamide monomer, an acrylnitrile monomer and a cross-linking agent in the presence of a urea compound. This agent provides paper with excellent surface strength, tensile strength and internal strength far better than conventional paper quality improving agents.
    Type: Grant
    Filed: March 15, 1996
    Date of Patent: May 26, 1998
    Assignee: Japan PMC Corporation
    Inventors: Kenji Nasu, Hiroharu Kawano, Satoshi Takizawa, Kiyoshi Iwai
  • Patent number: 5756593
    Abstract: The present invention is directed to methods of preparing high purity polyalkylene oxide carboxylic acids. The methods include reacting a polyalkylene oxide such as polyethylene glycol with a t-butyl haloacetate in the presence of a base followed by treatment with an acid such as trifloroacetic acid. The resultant polymer carboxylic acids are of sufficient plurty so that expensive and time consuming purification steps required for pharmaceutical grade polymers are avoided.
    Type: Grant
    Filed: June 27, 1997
    Date of Patent: May 26, 1998
    Assignee: Enzon, Inc.
    Inventors: Anthony J. Martinez, Richard B. Greenwald
  • Patent number: 5750640
    Abstract: The invention provides reaction products of:(A) an acylating reagent, with(D) a polyalkenyl derivative of an ethylenically unsaturated carboxylic reagent (C), and(E) a polyamine containing at least two --NH.sub.2 and/or --NH groups, or with(F) the pre-formed product of reagents (D) and (E), wherein the acylating reagent (A) is the reaction product of(B) a C.sub.4 -C.sub.20 polyene or oligomer prepared therefrom, and(C) an ethylenically unsaturated carboxylic reagent; lubricating oil compositions, fuel compositions and additive concentrates containing them; and use of the reaction products as dispersant additives.
    Type: Grant
    Filed: September 1, 1995
    Date of Patent: May 12, 1998
    Assignee: Shell Oil Company
    Inventors: Richard Mark Scott, Robert William Shaw
  • Patent number: 5750043
    Abstract: This invention relates to water soluble fluorochemical foam stabilizers and film formers derived from polyamines, perfluoroalkyl group containing esters or acid halides and hydrophilic and hydrophobic group containing compounds which react with primary, secondary and tertiary amino groups. The novel foam stabilizers and film formers are useful as additives for aqueous film forming foam fire fighting agents improving the foam stability against polar solvents and enhancing the fire fighting performance.
    Type: Grant
    Filed: August 25, 1994
    Date of Patent: May 12, 1998
    Assignee: Dynax Corporation
    Inventor: Kirtland P. Clark
  • Patent number: 5750636
    Abstract: This invention provides a process wherein a stable solution of polycarbodiimide with a number-average molecular-weight of 5,000 to 60,000 can be very easily prepared by using an organic diisocyanate (e.g., 2,4-tolylene diisocyanate or 2,6-tolylene diisocyanate) as starting material, a cyclic phosphine oxide as catalyst and a chlorinated aromatic compound as solvent and by controlling certain reaction conditions within the reaction temperature range of 110.degree. to 150.degree. C.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: May 12, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yasuyoshi Komoto, Yasuyuki Takiguchi, Ken Yahata, Akira Hayashida, Minoru Takamizawa
  • Patent number: 5750639
    Abstract: A polyamide resin composition having good molding fluidity, heat and chemical resistance and dimensional stability is provided containing: (A) 30-90 weight percent, based on components (A) and (B), of a polyamide resin containing (i) 10-99 weight percent, based on components (i) and (ii) of an aromatic polyamide containing a carboxylic acid component derived from terephthalic acid or a mixture of terephthalic and isophthalic acid in which the isophthalic acid constitutes 40 mole percent or less of the mixture, and an aliphatic diamine component derived from a mixture of hexamethylene diamine and 2-methylpentamethylene diamine; and (ii) 1-90 weight percent, based on components (i) and (ii), of at least one polyamide selected from the group consisting of polyamides containing repeat units derived from alipathic dicarboxylic acids and alipathic diamines and polyamides containing repeat units derived from aliphatic aminocarboxylic acids; and (B) 10-70 weight percent, based on components (A) and (B), of an inorgan
    Type: Grant
    Filed: July 24, 1996
    Date of Patent: May 12, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Ryuichi Hayashi
  • Patent number: 5750637
    Abstract: This invention provides a process for the preparation of a polycarbodiimide solution wherein the polycarbodiimide is synthesized by heating an organic diisocyanate (e.g., 2,4-tolylene diisocyanate or 2,6-tolylene diisocyanate) in the presence of a carbodiimidation catlayst characterized in that a non-chlorinated aromatic hydrocarbon is used as the solvent and the resulting polycarbodiimide has a number average molecular weight from about 3,000 to about 10,000; wherein the synthesis is performed in the temperature range of from about 100.degree. to about 120.degree. C.
    Type: Grant
    Filed: June 4, 1996
    Date of Patent: May 12, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yasuyuki Takiguchi, Ken Yahata, Yasuyoshi Komoto, Akira Hayashida, Minoru Takamizawa
  • Patent number: 5750638
    Abstract: A method for producing poly-o-hydroxy amides by heating a dicarboxylic acid to a temperature .gtoreq.80.degree. C., together with a sulfonic acid chloride and a tertiary amine in a suitable solvent, to form a reaction mixture and reacting the mixture obtained with a bis-o-aminophenol solution at a temperature <80.degree. C.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: May 12, 1998
    Assignee: Siemens Aktiengesesllschaft
    Inventors: Recai Sezi, Hellmut Ahne, Roland Gestigkeit
  • Patent number: 5739262
    Abstract: This invention relates to a novel ternary polyamide for the production of monofilaments, films and injection moulded articles.
    Type: Grant
    Filed: November 13, 1995
    Date of Patent: April 14, 1998
    Assignee: Bayer AG
    Inventors: Heinrich Morhenn, Dieter Brokmeier, Werner Nielinger
  • Patent number: 5723562
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: March 3, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5710210
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 20, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5705600
    Abstract: The present invention relates to blends of a polyester, polyamide or polyester/amide containing a copolymerizable fluorescence quenching compound and a second polymer. The blends of the present invention display reduced fluorescence. Specifically the blends comprise(a) a polyester/amide comprising:(1) a dicarboxylic acid component which comprises at least 0.1 mol % of a dicarboxylic acid selected from the group consisting of terephthalic acid and/or terephthalate ester;(2) a diol and/or diamine component;(3) 0.1 to 99.9 mol %, based on 100 mol % dicarboxylic acid and 100 mol % diol, of a copolymerizable fluorescence quenching compound;(b) a second polymer selected from the group poly(alkylene terephthalate) homo and copolyesters, poly(alkylene naphthalate) homo and copolyesters, poly(cycloalkylene terephthalate) homo and copolyesters, poly(alkylene 1,4-cyclohexanedicarboxylate) homo and copolyesters, and polycarbonate homo and copolymers.
    Type: Grant
    Filed: December 22, 1995
    Date of Patent: January 6, 1998
    Assignee: Eastman Chemical Company
    Inventors: Allan Scott Jones, Jean Carroll Fleischer, Max Allen Weaver
  • Patent number: 5705603
    Abstract: The invention relates to reaction products of polyetheramines with polymers containing dicarboxylic anhydride groups, which contain 20-80, preferably 40-60, mol % of bivalent structural units A and/or C and, if required, B ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are hydrogen or methyl,a and b are equal to zero or one and a+b is equal to one,Y is X or NRR.sup.3,X is --OH, --O--C.sub.1-30 -alkyl, NR.sup.3 R.sup.4 or --O.sup..crclbar. N.sup..sym. R.sup.3 R.sup.4,R.sup.3 and R.sup.4, independently of one another, are hydrogen, C.sub.6 -C.sub.40 -alkyl or R,R is ##STR2## with the proviso that at least 1 mol % of the anhydride groups bonded to the polymer have reacted with a polyetheramine,Z is C.sub.2 -C.sub.4 -alkyl,n is a number from 1 to 1000,R.sup.5 is hydrogen, C.sub.1 -C.sub.30 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.6 -C.sub.30 -aryl andR.sup.6 is hydrogen or C.sub.1 -C.sub.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Krull, Michael Feustel, Erdmann Mielcke
  • Patent number: 5705602
    Abstract: A star-like or comb-like branched aliphatic polyamino compound for use as a basic catalyst or a curing agent, as an effective thixotropic agent or viscosity adjusting agent for an aqueous medium, as a component for any one of a coating-forming agent, a sealing agent, a molding material and an adhesive resin, or as a substantially solvent-free coating composition, molding material or adhesive resin. The process for the production of the above compound comprises (a) forming an adduct of ammonia or an aliphatic amino compound having an amino group (compound A) with methyl acrylate, adding an alkylenediamine having 2 to 12 carbon atoms to the adduct to carry out an ester-amide exchange reaction (b), thereby obtaining a polyamino compound (B) having a total of 2 to 100 aliphatic primary amino and secondary amino groups per molecule and having a number average molecular weight of 170 to 10,000, and forming an adduct of the polyamino compound (B) with an acrylic acid ester (C) of the formula (1),CH.sub.2 =CHCOO--R.
    Type: Grant
    Filed: February 19, 1997
    Date of Patent: January 6, 1998
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Miki Kawashima, Takeo Yamaguchi, Toru Kurihashi, Norifumi Watanabe
  • Patent number: 5700900
    Abstract: A copolyamide composition and article molded therefrom, the molded article being transparent, being especially rigid, tough and cold impact resistant, having good resistance to solvents, and exhibiting negligible changes in mechanical properties in the conditioned state due to very low water absorption. The copolyamide composition including long-chain monomer building blocks and being comprised of from about 30 to about 96 parts by weight of at least one long-chain monomer which is suitable as a long-chain building block for a polyamide and which has from 9 to 12 carbon atoms; and from about 4 to about 70 parts by weight of precursor monomers for semiaromatic polyamides, which precursor monomers comprise at least one diamine, H.sub.2 N--R--NH.sub.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: December 23, 1997
    Assignee: EMS-Inventa AG
    Inventors: Manfred Hewel, Hans Dalla Torre
  • Patent number: 5693744
    Abstract: An amorphous polyamide represented by the formula(2) ##STR1## in which each R is at least one alkylene radical having 1 to 10 carbon atoms, R' is an electron acceptor group represented by the formula(3), ##STR2## wherein Y is --C.tbd.N, --NO.sub.2, --SO.sub.2 --R(R.dbd.C.sub.n H.sub.2n+1, n=1 to 20 alkyl derivatives), ##STR3## R" is at least one aliphatic or aromatic divalent group having 2 to 20 carbon atoms, and n is an integer of more than 3, having second order nonlinear optical property, and a method for preparing the polymer by the polycondensation of dicarboxylic acid derivative, having second order nonlinear optical property in its side chain, with diamine are disclosed.
    Type: Grant
    Filed: June 21, 1995
    Date of Patent: December 2, 1997
    Assignee: Korea Research Institute of Chemical Technology
    Inventors: Kil Yeong Choi, Moon Young Jin, Young Wun Kim
  • Patent number: 5688905
    Abstract: An amine hardener composition for curing epoxy resin based coatings and related products comprising (A) from 5 to 75% of a diamine which possesses a vapor pressure less than about 133 Pascals at 20.degree. C., contains both a primary and a tertiary amine and corresponds to either of the structures: ##STR1## where R.sub.1 and R.sub.2 are independently C.sub.1 -C.sub.8 alkyl; X is --CH.sub.2 --CH.sub.2 --, --CH.sub.2 --CH.sub.2 --CH.sub.2 --, or --CH.sub.2 --O--CH.sub.2 --; and n is 2-6, (B) from 5 to 95% of a polyamide, amidoamine, Mannich base or cycloaliphatic amine curing agent; and (C) from 0 to 50% of other active hydrogen containing dismines or polyamines. Coatings based on the composition can be formulated at up to 100% solids, and have an excellent combination of pot life and dry speed.
    Type: Grant
    Filed: September 20, 1995
    Date of Patent: November 18, 1997
    Assignee: Air Products and Chemicals, Inc.
    Inventor: Frederick Herbert Walker
  • Patent number: 5672676
    Abstract: New polyesteramides having glass transition temperatures (Tg's) of up to 130.degree. C. and heat deflection temperatures that are in the 100.degree. C. to 110.degree. C. range are disclosed. The new polyesteramides of this invention are made by sequential addition of selected diamines to the diacid/glycol melt. The polyesteramides comprise:--?--A--G--!.sub.x --?--A--NH--R--NH--!.sub.y --wherein A is an organic dicarboxylic acid; G is a glycol selected from linear aliphatic diols and cycloaliphatic diols having 5 to 20 carbon atoms; R is selected from alkyl, cycloalkyl, arylkyl, or aryl; and x and y are whole numbers having an x/y ratio between about 9 to about 0.5 and sum of X and Y is from about 2 to about 500.
    Type: Grant
    Filed: August 21, 1995
    Date of Patent: September 30, 1997
    Assignee: Eastman Chemical Company
    Inventor: Sam Richard Turner
  • Patent number: 5670603
    Abstract: This invention relates to polymers having non-linear optical properties which polymers include fluorene moieties having at least one electron accepting group and at least one electon donating group substituted to different phenyl rings of the fluorene moiety.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: September 23, 1997
    Assignee: AlliedSignal Inc.
    Inventors: Chengjiu Wu, Jianhui Shan, Ajay Nahata
  • Patent number: 5670480
    Abstract: A method of making a polymer having specific physiochemical properties by forming a first module having a structure which includes at least two structural diversity elements suitable to impart a desired physical property to a polymer which is made from said monomer; and reacting one or more modules to form a polymer having specific physiochemical properties. The base module can be formed by reacting a first compound having at least one structural diversity element and a first reactive group, with a second compound having at least one structural diversity element and a second reactive group, wherein the first and second groups combine by an addition reaction. Specifically, an aminimide compound, an oxazolone compound or derivatives thereof are useful as base modules in the invention.
    Type: Grant
    Filed: June 10, 1996
    Date of Patent: September 23, 1997
    Assignee: ArQule, Inc.
    Inventor: Joseph C. Hogan, Jr.
  • Patent number: 5663283
    Abstract: An electrophotographic photosensitive member, has an electroconductive support, an interlayer, and a photosensitive layer provided in the order named. The interlayer contains a polyamide having a structural unit represented by the formula (I) below: ##STR1## wherein R.sub.1 is a substituted or unsubstituted alkyl group, R.sub.2 is a substituted or unsubstituted alkylene group, and n is an integer of one or more.
    Type: Grant
    Filed: March 20, 1995
    Date of Patent: September 2, 1997
    Assignee: Canon Kabushiki Kaisha
    Inventors: Teigo Sakakibara, Kiyoshi Sakai, Takashi Koyama, Noriko Ohtani
  • Patent number: 5658995
    Abstract: Random block copolymers having the formula: ##STR1## wherein R.sub.1 is --CH.dbd.CH-- or (--CH.sub.2 --).sub.j, in which j is zero or an integer from one to eight; R.sub.2 is selected from hydrogen, straight and branched alkyl and alkylaryl groups containing up to 18 carbon atoms and derivatives or biologically and pharmaceutically active compounds covalently bonded to said copolymer; each R.sub.3 is independently an alkylene group containing up to 4 carbon atoms; y is an integer between about 5 and about 3000; and f is the percent molar fraction of alkylene oxide in the copolymer and ranges between about 1 and about 99 mole percent. Implantable medical devices and drug delivery implants containing the random block copolymers are also disclosed, along with methods for drug delivery and for preventing the formation of adhesions between injured tissues employing the random block copolymers. Polyarylate random block copolymers are also described.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: August 19, 1997
    Assignee: Rutgers, The State University
    Inventors: Joachim B. Kohn, Chun Yu
  • Patent number: 5646236
    Abstract: Polyesters obtained by reacting from 5 to 50 parts of at least one linear or branched, aliphatic or cycloaliphatic, at least dihydric alcohol, from 2 to 40 parts of at least one at least dibasic, aromatic carboxylic acid, from 0 to 40 parts of at least one 2-alkenyldicarboxylic anhydride, from 10 to 30 parts of at least one at least dibasic, linear or branched, aliphatic carboxylic acid, from 0 to 15 parts of an aliphatic, linear or branched hydroxy acid, from 0 to 15 parts of an aliphatic, linear or branched polyamine having at least one primary and at least one secondary or tertiary amino group, from 0 to 15 parts of a glycidyl ester of a branched, aliphatic monocarboxylic acid or of a glycidyl ether of a branched, aliphatic alcohol, and from 0 to 15 parts of polyhydroxyamine are useful, for example, as additives in coating compositions.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: July 8, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Markus A. Schafheutle, Achim Voelker, Susanne Wehner, Gerd Walz, Joachim Zoeller
  • Patent number: 5644020
    Abstract: The invention relates to thermoplastically processible aliphatic polyesteramides which are biodegradable (compostable).
    Type: Grant
    Filed: May 10, 1996
    Date of Patent: July 1, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ralf Timmermann, Ralf Dujardin, Rainhard Koch
  • Patent number: 5633034
    Abstract: The invention relates to a process for forming a circuit assembly comprising (i) coating onto a substrate a layer of polyamic ester selected from a unique class of polyamic esters; (ii) imidizing the polyamic ester to form a layer of polyimide having an even surface and (iii) forming circuit conductors on the even surface of the polyimide.
    Type: Grant
    Filed: May 9, 1996
    Date of Patent: May 27, 1997
    Assignee: International Business Machines Corporation
    Inventors: Kenneth R. Carter, Richard A. DiPietro, James L. Hedrick, John P. Hummel, Robert D. Miller, Martha I. Sanchez, Willi Volksen, Do Y. Yoon
  • Patent number: 5627253
    Abstract: A polyimide resin having excellent storage stability which cures to give a highly adherent, highly heat-resistant, and highly moisture-resistant film is disclosed, said resin being prepared by reacting(A) a tetracarboxylic dianhydride and(B) a diamino-functional siloxane compound having the general formula ##STR1## in which each R.sup.1 is independently selected from C.sub.1 to C.sub.20 monovalent hydrocarbon radicals, each R.sup.2 is independently selected from C.sub.1 to C.sub.20 divalent hydrocarbon radicals, R.sup.3 is selected from the group consisting of hydrogen and --SiR.sup.1.sub.3 wherein R.sup.1 is defined as above, a is an integer from 1 to 20, b is an integer from 1 to 20, c is an integer from 0 to 20, and d is an integer from 1 to 20.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: May 6, 1997
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventor: Hisataka Nakashima
  • Patent number: 5614597
    Abstract: Wet strength resins for paper are prepared by a process comprising the following steps in sequence: (1) reacting a polyamidoamine with an epihalohydrin until the amount of unreacted epihalohydrin present is less than about 10% by weight of the amount of epihalohydrin charged, (2) adding a water-soluble, nonpolymeric amine in an amount of about 0.1 to about 50 mole %, based on the amine in the polyamidoamine, and (3) heating to effect crosslinking. An optional amine additive reaction step can be included after step (2). A nonhalogen acid such as sulfuric acid can be added toward the end of the crosslinking step to decrease the total organic halogen content and increase the wet strengthening effectiveness.
    Type: Grant
    Filed: December 14, 1994
    Date of Patent: March 25, 1997
    Assignee: Hercules Incorporated
    Inventor: Barton K. Bower
  • Patent number: 5612439
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 18, 1997
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5606012
    Abstract: Polymeric polyetheramidoamine hydrogel materials, which are capable of complexing heparin in physiological conditions are herein described. Said materials are useful in the manufacturing of medical devices.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: February 25, 1997
    Assignee: Societa' Consortile Ricerche Angelini S.p.A.
    Inventors: Maria C. Tanzi, Gianfranco Palumbo
  • Patent number: 5604292
    Abstract: Novel conjugated amino substituted phenylene polymers are disclosed having on-linear optical properties, and which can be converted to electrically conductive polymers. Such polymers are produced by reacting a novel bis-cycloalkylene sulfonium salt of 2,5,N,N-tetramethylaniline hydrochloride, such as 2,5-(N,N-dimethyl)aniline hydrochloride dimethylene bis-(tetramethylene sulfonium chloride) with alkali metal hydroxide to form a cycloalkylene sulfonium salt precursor polymer, and then heating the precursor polymer under conditions to produce the amino substituted phenylene vinylene polymer, such as poly(2-(N,N-dimethylamino) phenylene vinylene). The polymers can also be made directly by treatment of the bis chlormethyl dimethyl aniline hydrochloride derivative with alkali metal alkoxide.
    Type: Grant
    Filed: May 31, 1994
    Date of Patent: February 18, 1997
    Assignee: The Untied States of America as represented by the Secretary of the Navy
    Inventors: John D. Stenger-Smith, William P. Norris, Andrew P. Chafin, Scott T. Sackinger
  • Patent number: 5594093
    Abstract: A nonlinear optical polymer material comprising at least one polymer selected from the group consiting of polyimides, acrylic resins and benzocyclobutene resins containing, as a guest molecule, as a side chain, or in the main chain, a molecule or a chemical moiety having a basic structure of merocyanine dye represented by the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 independently represent hydrogen or an organic group, provided that R.sup.1 and R.sup.2 or R.sup.3 and R.sup.5 may independently combine together to form an organo ring structure, and n is an integer of 1 to 3.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 14, 1997
    Assignee: Fujitsu Limited
    Inventors: Wataru Sotoyama, Satoshi Tatsuura, Tetsuzo Yoshimura, Azuma Matsuura, Tomoaki Hayano
  • Patent number: 5585456
    Abstract: A composition of matter (resin) useful for imparting wet strength to paper products is prepared from a polyamine, a polycarboxylic acid or ester, a dialdehyde and epichlorohydrin. Wet strengthened paper products made using the resin are more easily repulped than paper products made with conventional wet strength agents.
    Type: Grant
    Filed: September 8, 1995
    Date of Patent: December 17, 1996
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Margaret A. Dulany, Chad E. Garvey, Clay E. Ringold, Ramji Srinivasan
  • Patent number: 5578695
    Abstract: The invention provides a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the following formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500.The invention also provides a curable composition including (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of a resin having at least two epoxy groups in the molecule and a resin having at least two hydroxyl groups in the molecule, and (iii) a resin having at least two epoxy groups in the molecule, and (B) the above-mentioned crosslinking agent.
    Type: Grant
    Filed: December 13, 1994
    Date of Patent: November 26, 1996
    Assignee: Kansai Paint Company, Ltd.
    Inventor: Osamu Isozaki
  • Patent number: 5574128
    Abstract: Polyetheresteramides, characterized in that they comprise both of the following repeating entities: ##STR1## in which X represents the residue of a polyamide-diacid oligomer with an Mn of between 300 and 8000, Y represents the residue of a polyetherdiol with an Mn of between 200 and 5000, and Z represents the residue of a polyetherdiamine with an Mn of between 200 and 5000, wherein the proportion by mass of the entities Z resulting from the condensation of the polyetherdiamine with respect to the total amount of the entities resulting from the polyetherdiol and polyetherdiamine, i.e. Z/(Z+Y), is between 1 and 50%. The polyetheresteramides according to the invention can be used as is and are suitable for the production of mouldings, extrudates, films, sheaths, or composite materials such as multi-layer film. They can also be mixed with other polymers and in particular with polyamides.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: November 12, 1996
    Assignee: Elf Atochem S.A.
    Inventors: Didier Judas, Jean-Marc Sage
  • Patent number: 5567798
    Abstract: A composition of matter (resin) useful for imparting wet strength to paper products is prepared from a polyamine, a polycarboxylic acid or ester, a dialdehyde and epichlorohydrin. Wet strengthened paper products made using the resin are more easily repulped than paper products made with conventional wet strength agents.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: October 22, 1996
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Margaret A. Dulany, Chad E. Garvey, Clay E. Ringold, Ramji Srinivasan