Semiconductor device having a ferroelectric TFT and a dummy element
The present invention provides a semiconductor device including a semiconductor element and a dummy semiconductor element adjacent to the semiconductor element. When the semiconductor element is a capacitor element including a bottom electrode, a top electrode and a dielectric layer between the electrodes, a dummy capacitor element also has dummy electrodes and a dummy dielectric layer between the dummy electrodes. The dummy electrode is located so that a space between the top electrode of the capacitor element ad the dummy top electrode is in a predetermined range (e.g. 0.3 μm to 14 μm). The dummy capacitor element prevents the capacitor dielectric layer from degrading since the collisions of the etching ions with the capacitor dielectric layer in a dry etching process is suppressed.
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The present invention relates to a semiconductor device. More particularly the present invention relates to a semiconductor device including a semiconductor element such as a capacitor and a transistor in which a dielectric with high dielectric constant or a ferroelectric is used.
BACKGROUND OF THE INVENTIONWith increases in the packing density of semiconductor memories, a capacitor element with larger capacity is needed. Therefore, a technology to integrate a capacitor element including a dielectric layer with high dielectric constant or a ferroelectric characteristics into a integrated circuit lately has attracted considerable attention.
In order to put a nonvolatile RAM into practice which enables writing and reading with lower operating voltage at higher speed compared to conventional devices, a technology to integrate a capacitor element including a ferroelectric layer has been pursued.
A conventional method for manufacturing a semiconductor device including a dielectric with high dielectric constant or a ferroelectric characteristics (hereinafter, a dielectric with high dielectric) is explained below referring to
As shown in
However, in such a capacitor element produced by the conventional method, a capacitor dielectric layer with high dielectric constant is degraded in electric characteristics. Such a degradation also is observed in a transistor including a dielectric layer with high dielectric constant.
SUMMARY OF THE INVENTIONTherefore, with the foregoing in mind, it is the object of the present invention to suppress a degradation of a dielectric with high dielectric constant in a semiconductor element.
In order to achieve the above-described object, an embodiment of the semiconductor device of the present invention comprises a substrate, a semiconductor element and a dummy semiconductor element. The semiconductor element includes a first dielectric layer on the substrate and an electrode on the first dielectric layer, and the dummy semiconductor element includes a second dielectric layer on the substrate and a dummy electrode on the second dielectric layer. The dummy semiconductor is located so that a space between the electrode and the dummy electrode is in a predetermined range. The predetermined range is preferably between 0.3 μm and 1.4 μm.
When the semiconductor element is a capacitor element, an embodiment of the semiconductor device of the present invention comprises a substrate, a capacitor element and a dummy capacitor element. The capacitor element includes a bottom electrode on the substrate, a first dielectric layer on the bottom electrode and a top electrode on the first dielectric layer, and the dummy capacitor element includes a dummy bottom electrode on the substrate and a second dielectric layer on the dummy bottom electrode and a dummy top electrode on the second dielectric layer. The dummy capacitor element is located so that a space between the top electrode and the dummy top electrode is in a predetermined range (e.g. 0.3 μm to 14 μm).
Two or more semiconductor elements can be included in the semiconductor device. In such a case, an embodiment of the semiconductor device of the present invention comprises a substrate, at least two capacitor elements, and a dummy capacitor element. Each capacitor element includes a bottom electrode, a first dielectric layer and a top electrode, and the dummy capacitor element includes a dummy bottom electrode, a second dielectric layer and a dummy top electrode as described above. The capacitor elements and the dummy capacitor element are located so that a space between an adjacent pair of electrodes selected from the top electrodes and the dummy top electrode, in which at least one electrode in the pair is one of the top electrodes, is in a predetermined range (e.g. 0.3 μm to 14 μm). The semiconductor device can include two or more dummy semiconductor devices.
Such a semiconductor device of the present invention can be manufactured by a method which comprises forming a dielectric film on a substrate, forming the electrically conductive film on the dielectric film, and etching the electrically conductive film so as to form the electrode. When etching the electrically conductive film, a dummy electrode is formed with the electrode so that a space between the electrode and the dummy electrode is in a predetermined range (e.g. 0.3 μm to 14 μm).
The inventors have succeeded in elucidating the degradation of the dielectric with high dielectric constant in a semiconductor element.
As shown in
Therefore, the large exposed surface of the dielectric film 203 with high dielectric constant causes an electrostatic repulsion between the etching ions 210 and the electrical charges 211. As shown in
According to the present invention, the surface of the dielectric film exposed to the etching ions is limited by the dummy element, which can reduce the electrical charges on the dielectric film. Therefore, the collision with the etching ions proceeding diagonally is suppressed to prevent the semiconductor element from degrading in electrical characteristics.
These and other advantages of the present invention will become apparent those skilled in the art upon reading and understanding the following detailed description.
In the semiconductor device of the invention, the space between the electrode and the dummy electrode is preferably in the range of 0.3 μm to 9 μm, more preferably in the range of 0.3 μm to 5 μm.
In the semiconductor device of the invention, the electrode and the dummy electrode are preferably composed of the same electrically conductive material. The electrode and the dummy electrode are preferably formed by etching the same electrically conductive film.
In the semiconductor device of the invention, the first dielectric layer is composed of the material selected from a dielectric material having a dielectric constant of 100 or more and a ferroelectric material.
In the semiconductor device of the invention, the first dielectric layer and the second dielectric layer are composed of the same dielectric material. The first dielectric layer and the second dielectric layer are preferably included in the same dielectric film. The first dielectric layer and the second dielectric layer are preferably formed by etching the same dielectric film.
Some embodiments of the present invention are explained below referring to the drawings.
First embodimentAs shown in
A method for manufacturing the semiconductor device is explained below referring to
As shown in
Next, as shown in
After second photoresist layers 28 are formed in another predetermined pattern by photolithography as shown in
Thus, the capacitor element 16 and the dummy capacitor element 17 are formed at the same time. In the semiconductor device, the space between the second electrode 20 and the second dummy electrode 23 is set in the range of 0.3 μm to 14 μm.
As shown in
As shown in
The semiconductor device can be produced by the same method as described above except for a pattern of the photoresist layers. The suitable materials for the layers also are the same as the first embodiment.
In the semiconductor device, each second electrode 36 is surrounded by four electrodes. The four electrode are selected from the other second electrodes 36 and the dummy electrodes 39. The space between the second electrode 26 and the electrodes adjacent to the second electrode is set in the range of 0.3 μm to 14 μm.
Such an arrangement also can suppress the damage to the capacitor dielectric layer 35. In addition, the dummy capacitor elements 33 can reduce the difference in electrical characteristics among the capacitor elements 32, especially the difference between the outer elements and the inner elements.
The dummy capacitor element may have another shape such as a frame-like shape as described in the first embodiment.
Third embodimentAs shown in
The semiconductor device can be produced by the same method as described above except for a pattern of the photoresist layers. The suitable materials for the layers also are the same as the first embodiment. The space between the second electrode 46 and the dummy electrode 49 is set in the range of 0.3 μm to 14 μm.
Such an arrangement also can suppress the damage of the capacitor dielectric layer 45.
The semiconductor device described above or in the first embodiment may include two or more capacitor elements.
Fourth embodimentAs shown in
As shown in
The semiconductor device can be produced by the same method as described above except for a pattern of the photoresist layers. The suitable materials for the layers also are the same as the first embodiment.
As described in the second embodiment, the space between the second electrode 56 and the electrodes adjacent to the second electrode 56 is set in the range of 0.3 μm to 14 μm.
Such an arrangement also can suppress the damage to the capacitor dielectric layer 55 and reduce the difference in electrical characteristics among the capacitor elements 52. In addition, the semiconductor device has less undulations since some of the films remains without etching. Less undulations make wiring to the integrated circuit easier.
In the embodiments as described above, the electrode and the dummy electrode corresponding to the electrode are composed of the same material. The capacitor dielectric element and the dummy dielectric layer also are composed of the same material. The capacitor element is integrated into the circuit in the semiconductor device while the dummy capacitor element is produced not for being integrated into the circuit but for suppressing the collision of the etching ions with the dielectric in the capacitor element. As long as the desired object can be achieved, the shape, the material and the arrangement of the dummy element are not limited.
For example, electrically conductive oxides such as RuO2 and IrO2 can be used as a material for the electrode as well as various kinds of metal. Dielectric compounds such as BaxSr1-xTiOx, Pb(Zr1-xTix)O3, SrBi2(Ta1-xNbx)2O9, Bi4Ti3O12(0≦x≦1) can be used for the dielectric capacitor layer.
Fifth embodimentOther semiconductor elements such as transistors also can be used for the semiconductor element of the present invention as well as capacitor elements.
For example, in the case of a transistor, a gate electrode 121 on a substrate 120 corresponds to the top electrode in a capacitor element as shown in
In the memory cell in
The transistor 97 and the capacitor element 98 are connected with other elements by bit lines 89, 90 and 95. A field oxide layer 82 and insulating layers 83 and 84 formed on a substrate 81 prevent unnecessary contacts between the elements.
A memory cell in
The transistor 117 and the capacitor element 118 also are connected with each other and other elements by bit lines 109, 110 and 115. Insulating layers 102 and 104 prevent unnecessary contacts between the elements. In the memory cells as shown in
The semiconductor device for which the dummy element can be used is not limited to the memory cells as described above.
EXAMPLEThe devices as shown in
As shown in
As shown in
The space α between a second electrode 66 and a second dummy electrode 69 in the first dummy capacitor element 62 was set at 1.5 μm. The space β between the second electrode 66 and a second dummy electrode 73 in the second dummy capacitor element 63 was set at 12.8 μm. The devices were produced by the process as described above. The capacitor dielectric layer was composed of SrBixTaxOy at a thickness of 0.24 μm. The electrodes were composed of Pt.
On the other hand, semiconductor devices were produced in the same way but without the first dummy elements 62 and the second dummy elements 63. Remnant polarization in each device was measured.
As shown in
The relationship between the space β and the remnant polarization was investigated. As shown in
The invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The embodiments disclosed in this application are to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, all changes that come within the meaning and range of equivalency of the claims are intended to be embraced therein.
Claims
1. A semiconductor device comprising:
- a substrate,
- a semiconductor element on the substrate, the semiconductor element including a first dielectric layer and an electrode on the first dielectric layer, and
- a dummy semiconductor element on the substrate, the dummy semiconductor element including a second dielectric layer and a dummy electrode on the second dielectric layer,
- wherein the dummy semiconductor element is located so that a space between the electrode and the dummy electrode is in a predetermined range, and the semiconductor device is a transistor in which the electrode works as a gate electrode of the transistor; and said first dielectric layer is composed of the material selected from a dielectric material having a dielectric constant of 100 or more and a ferroelectric material.
2. A semiconductor device according to claim 1, wherein the predetermined range of the space is between 0.3 μm and 14 μm.
3. A semiconductor device according to claim 1, wherein the electrode and the dummy electrode are composed of the same electrically conductive material.
4. A semiconductor device according to claim 1, wherein the first dielectric layer and the second dielectric layer are composed of the same dielectric material.
5. A semiconductor device according to claim 1, wherein the electrode is surrounded by the dummy electrode.
6. A semiconductor device comprising:
- a substrate,
- a multilayer formed on the substrate, the multilayer comprising a plurality of semiconductor elements and a plurality of dummy semiconductor elements, and
- a semiconductor element area on the substrate, which includes the plurality of semiconductor elements, the semiconductor element area being surrounded by the plurality of dummy semiconductor elements,
- wherein each of the plurality of semiconductor elements includes a capacitor which is comprised of a bottom electrode, a first dielectric layer on the bottom electrode and a top electrode on the first dielectric layer, and the first dielectric layer is composed of a material selected from a dielectric material having a dielectric constant of 100 or more and a ferroelectric material,
- wherein each of the plurality of dummy semiconductor elements includes a dummy capacitor which is comprised of a dummy bottom electrode, a second dielectric layer on the dummy bottom electrode and a dummy top electrode on the second dielectric layer, and the second dielectric layer is composed of a material selected from a dielectric material having a dielectric constant of 100 or more and a ferroelectric material,
- wherein each of the plurality of dummy semiconductor elements is located so that a space between the electrode and the dummy electrode is in a predetermined range, and
- wherein the multilayer is produced by a method comprising: forming a dielectric film for the first dielectric layer and the second dielectric layer; forming an electrically conductive film on the dielectric film; etching the electrically conductive film so as to form the electrode and the dummy electrode, and wherein each of the plurality of semiconductor elements and each of the plurality of dummy semiconductor elements have the same dimensions.
7. A semiconductor device according to claim 6, wherein the predetermined range of the space is between 0.3 μm and 14 μm.
8. A semiconductor device according to claim 6, wherein remnant polarization in the capacitor is in the range of 13 to 15 μC/cm2.
9. A semiconductor device according to claim 6, wherein the first dielectric layer and the second dielectric layer are composed of a material selected from SrBixTaxOy, BaxSr1-xTiOx, Pb(Zr1-xTix)O3, SrBi2(Ta1-xNbx)2O9 or Bi4Ti3O12, where 0≦x≦1.
Type: Grant
Filed: Jul 1, 2003
Date of Patent: Dec 9, 2008
Assignee: Panasonic Corporation (Osaka)
Inventors: Akihiro Matsuda (Takatsuki), Yoshihisa Nagano (Jyoetsu), Yasuhiro Uemoto (Otsu)
Primary Examiner: Thomas L Dickey
Attorney: Hamre, Schumann, Mueller & Larson, P.C.
Application Number: 10/611,307
International Classification: H01L 21/70 (20060101);