Alkali Metal Silicate Containing Patents (Class 106/600)
  • Patent number: 7094285
    Abstract: A modified alkali silicate composition for forming an inorganic polymer matrix having improved mechanical properties. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), a non-silicate network former and/or reactive glass, water and optionally one or more multivalent cation(s) selected from Groups 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15 or 16 of the periodic table such as an alkaline earth salt, water and optional processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and curing the composite at a temperature from about 15° C. up to 1000° C. and a pressure of up to 20,000 psi for typical high-performance organic polymer processing (temperatures about 15° C. to about 200° C. and pressures <200 psi). The composite can be shaped by compression molding as well as other known fabrication methods.
    Type: Grant
    Filed: February 12, 2004
    Date of Patent: August 22, 2006
    Assignee: Goodrich Corporation
    Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
  • Patent number: 7056380
    Abstract: A water-based black enamel composition capable of being deposited on a glass substrate, especially on a glass sheet. The enamel composition includes: 20 to 40% by weight of water-soluble sodium silicate and/or potassium silicate; a water-soluble base, in an amount sufficient for the pH of the composition to be at least 10.5; 5 to 25% by weight of water; 40 to 60% by weight of a metal oxide chosen from the group consisting of copper oxides, iron oxides, cobalt oxides, mixtures of these oxides, and mixtures of at least one of the oxides with chromium oxide(s); less than 10% by weight of zinc oxide; at least 10% by weight of a glass frit having a melting point below 680° C.; and less than 10% by weight of a glass frit having a Littleton point above 700° C. A glazing, especially an automobile glazing, including at least one glass sheet can have at least one of the faces of the glass sheet coated at least partially with the enamel composition.
    Type: Grant
    Filed: June 6, 2001
    Date of Patent: June 6, 2006
    Assignee: Saint-Gobain Glass France
    Inventor: Andre Beyrle
  • Patent number: 7044224
    Abstract: The present invention relates to methods of stimulating a subterranean formation. More particularly, but not by way of limitation, the present invention relates to methods of fracturing subterranean formations utilizing a fracturing fluid comprising a permeable cement composition that may be used as a propping agent. One method of stimulating a subterranean formation of the present invention comprises the following steps: preparing a permeable cement composition comprising a hydraulic cement, water, and a degradable material capable of undergoing an irreversible degradation downhole; injecting the permeable cement composition into the subterranean formation at a pressure sufficient to create a fracture in the subterranean formation; and allowing the permeable cement composition to form a proppant matrix having voids in the fracture.
    Type: Grant
    Filed: June 27, 2003
    Date of Patent: May 16, 2006
    Assignee: Halliburton Energy Services, Inc.
    Inventor: Philip D. Nguyen
  • Patent number: 7041167
    Abstract: Disclosed are concrete and fiber cement formulations and products comprising low-density calcium silicate hydrate, and methods for producing these formulations and products. The disclosed formulations exhibit accelerated curing times. Other advantages of the disclosed formulations include improved dimensional stability in extruded products, reduced cracking, and reduced wash-out in underwater applications. The products of the disclosed formulation have lower cost of production and faster time to market.
    Type: Grant
    Filed: March 4, 2002
    Date of Patent: May 9, 2006
    Assignee: James Hardie International Finance B.V.
    Inventor: Chongjun Jiang
  • Patent number: 7022178
    Abstract: A binding agent system based on water glass is disclosed, comprising an aqueous alkali silicate solution having the general composition: xSiO2·yM2O ·zH2O, with M standing for the alkali ions Li+, K+, or Na+, and a hygroscopic base, which is added in the ratio 1:4 to 1:6, with the modulus Na2O/SiO2 being equal to 2.5 to 3.5 at a proportion of solids of 20 to 40% and with 30% sodium hydroxide in an aqueous solution being used as the hygroscopic base. According to the present invention, the aqueous alkali silicate solution contains an emulsion solution having 8 to 10% silicone oil in relation to the quantity of binder, with the silicone oil having a boiling point?250°. The quantity of binder for a core sand mixture is 1.0 to 2.5%, in relation to the total quantity of granular solid, with the production method being performed in a core shooter comprising a vertically positioned housing having a horizontal air intake. The core sand mixture is introduced via a funnel into a slotted sand cylinder.
    Type: Grant
    Filed: October 21, 2000
    Date of Patent: April 4, 2006
    Assignee: Hydro Aluminium Deutschland GmbH
    Inventor: Thomas Steinhäuser
  • Patent number: 6986859
    Abstract: A modified alkali silicate composition for forming an inorganic network matrix. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), an acidic inorganic composition, such as a reactive glass, water and optional fillers, additives and processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and applying the temperature and pressure necessary to consolidate the desired form. The composite can be shaped by compression molding as well as other known fabrication methods. A notable aspect of the invention is that, although composite and neat resin components prepared from the invention can exhibit excellent dimensional stability to 1000° C. and higher, they can be prepared at the lower temperatures and pressures typical to organic polymer processing.
    Type: Grant
    Filed: July 21, 2004
    Date of Patent: January 17, 2006
    Assignee: Goodrich Corporation
    Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
  • Patent number: 6974498
    Abstract: Many commercial radiant energy processing systems, such as luminaires and light detectors, require highly efficient diffusely reflective surfaces that can withstand high temperatures. As disclosed herein, a reflector for such a device is constructed of a substrate with a reflective coating, for example painted onto one or more surfaces of the substrate. The coating material comprises a zinc oxide pigment, preferably an uncalcined zinc oxide together with a small amount of a dispersing agent. The pigment and water are mixed together with an alkali metal silicate vehicle-binder (preferably a potassium silicate), for example, in a sheer mixer. The resulting material can be painted onto the desired surface, for example by spraying, spot-brushing or dipping.
    Type: Grant
    Filed: October 17, 2003
    Date of Patent: December 13, 2005
    Assignee: Advanced Optical Technologies, LLC
    Inventor: Matthew Brown
  • Patent number: 6969422
    Abstract: A modified alkali silicate composition for forming an inorganic network matrix. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), an acidic inorganic composition, such as a reactive glass, water and optional fillers, additives and processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and applying the temperature and pressure necessary to consolidate the desired form. The composite can be shaped by compression molding as well as other known fabrication methods. A notable aspect of the invention is that, although composite and neat resin components prepared from the invention can exhibit excellent dimensional stability to 1000° C. and higher, they can be prepared at the lower temperatures and pressures typical to organic polymer processing.
    Type: Grant
    Filed: June 1, 2001
    Date of Patent: November 29, 2005
    Assignee: Goodrich Corporation
    Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
  • Patent number: 6966945
    Abstract: A modified alkali silicate composition for forming an inorganic network. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), an acidic oxoanionic compound such as phosphoric acid, water and optionally one or more multivalent cation(s) selected from Groups 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15 or 16 of the periodic table such as an alkaline earth salt, water and optional processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and curing the composite at a temperature from about 15° C. up to 1000° C. and a pressure of up to 20,000 psi for typical high-performance organic polymer processing (temperatures about 15° C. to about 200° C. and pressures <200 psi). The composite can be shaped by compression molding as well as other known fabrication methods.
    Type: Grant
    Filed: June 1, 2001
    Date of Patent: November 22, 2005
    Assignee: Goodrich Corporation
    Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
  • Patent number: 6921431
    Abstract: A coating admixture, method of coating and substrates coated thereby, wherein the coating contains colloidal silica, colloidal alumina, or combinations thereof; a filler such as silicon dioxide, aluminum oxide, titanium dioxide, magnesium oxide, calcium oxide and boron oxide; and one or more emissivity agents such as silicon hexaboride, carbon tetraboride, silicon tetraboride, silicon carbide, molybdenum disilicide, tungsten disilicide, zirconium diboride, cupric chromite, or metallic oxides such as iron oxides, magnesium oxides, manganese oxides, chromium oxides, copper chromium oxides, cerium oxides, terbium oxides, and derivatives thereof. In a coating solution, an admixture of the coating contains water. A stabilizer such as bentonite, kaolin, magnesium alumina silicon clay, tabular alumina and stabilized zirconium oxide is also added.
    Type: Grant
    Filed: September 9, 2003
    Date of Patent: July 26, 2005
    Assignee: Wessex Incorporated
    Inventors: Timothy G. Evans, John W. Olver, John G. Dillard, Jason Andrew Simmons, Rex Allen Churchward
  • Patent number: 6881701
    Abstract: The present invention provides a coating composition for substrates. The coating composition of the present invention generally includes a silicate binder and a plurality of photocatalytic particles. The silicate binder functions as a bonding agent to establish the coating on the substrate. A plurality of photocatalyst particles are dispersed throughout the silicate binder. The particles are included in an amount that provides sufficient distribution of the particles in the resulting coating. The incorporation of the present invention onto substrates prevents algal growth on building materials utilizing the coated substrates.
    Type: Grant
    Filed: April 15, 2003
    Date of Patent: April 19, 2005
    Assignee: 3M Innovative Properties Company
    Inventor: Jeffry L. Jacobs
  • Patent number: 6869475
    Abstract: An asbestos free, calcium silicate insulating material, suitable for use in applications where a tough, fire resistant, heat insulating, electrical insulating, and corrosion resistant material is desirable. The calcium silicate insulating material is produced by combining Portland cement, blast furnace slag cement, a siliceous component, wollastonite and organic fibrous material in the presence of water to form a slurry. The slurry is then placed under steam pressure, to react the portland cement, blast furnace slag cement, siliceous component and water, dried, and heat treated if necessary.
    Type: Grant
    Filed: October 28, 2003
    Date of Patent: March 22, 2005
    Assignee: BNZ Materials, Inc.
    Inventor: Thomas R. Krowl
  • Patent number: 6866709
    Abstract: The present invention relates to compositions comprising the reaction product of amorphous silica or ultra-fine silica and one or more bases. The present invention also relates to materials and method involving the use of such products. In particular, the present invention i.a. relates to new mineral wool products, e.g. products comprising man-made vitreous fibres (such as glass fibres, slag fibres, stone fibres and rock fibres) or perlite, having included therein a binder component which comprises amorphous silica and aklali metal organosiliconates, e.g. potassium methyl siliconate. An important feature of such products is the preparation of the binder systems under vigorous mixing. Such products provide good fire, heat and sound insulating properties. The present invention also provides to a method for removing odorous substances from a gas where materials prepared from ultra-fine silica, water, and one or more components enabling porosity-conferring binding of the material, e.g. a base or bases.
    Type: Grant
    Filed: October 29, 1999
    Date of Patent: March 15, 2005
    Assignee: Aalborg Universitet
    Inventor: Kjeld Holbek
  • Patent number: 6855199
    Abstract: A method is described for the electrochemical protection of reinforcement in concrete in harsh environments, for instance in contact with, or in close proximity to, seawater. On concrete, a composition comprising graphite dispersed in a curable mineralic binder in the form of water glass or another water-soluble inorganic silicate, a dispersion agent, optionally together with conventional additives is applied. The application is performed by spraying or brushing. An impregnation is optionally performed, either concurrent with the application of the composition or thereafter. If necessary a post treatment is performed. Further, the use of the composition for electromechanical protection or reinforcement in concrete in connection with, for instance, quay constructions, bridges, bridge piers and similar constructions is described.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: February 15, 2005
    Assignee: Protector AS
    Inventor: Franz Pruckner
  • Publication number: 20040231563
    Abstract: An aqueous film forming inorganic composition which is prepared by reacting metallic silicon and an alkali metal hydroxide in an aqueous solvent in the presence of at least one compound selected from the group consisting of a fluoride and sulfurous acid, nitrous acid, phosphorous acid and a salt of the acid, characterized in that it has a pH value of 10 to 13 at 20° C. and comprises colloidal particles of the product of the above reaction having various, that is, relatively large, medium and relatively small particle diameters; an inorganic foam prepared by heating the composition to 150° C. or higher; and methods for preparing the composition and the foam. The aqueous film forming inorganic composition can be suitably used for preparing an inorganic foam and a thermally insulating composite material which are excellent in thermal insulation, and is not pollutant to the environment and can be recycled in the environment.
    Type: Application
    Filed: June 7, 2004
    Publication date: November 25, 2004
    Inventors: Hiroshi Kokuta, Katsuhiro Kokuta, Hideaki Uchida, Kenji Kokuta, Naoto Kokuta
  • Patent number: 6821631
    Abstract: A method of treating substrates, such as wood, including the steps of applying an alkali silicate solution to one or more substrates and applying an alkali borate solution with boric oxide (B2O3) content to the substrates. Substrates that have been treated using the present method include a borate-silicate polymer within the substrate. When the present substrates are wood, wood products, or green lumber, they may be used to build structures.
    Type: Grant
    Filed: October 28, 2002
    Date of Patent: November 23, 2004
    Assignee: Wood treatment Products, Inc.
    Inventors: Robert N. Grantham, Robert R. Weaver, III
  • Patent number: 6818055
    Abstract: A porous silicate granular material, especially as aggregate for the production of construction materials such as lightweight concrete, mortar or heat-insulating plaster containing glass and a glassy crystalline component comprising 45 to 85 wt. % SiO2, 5 to 20 wt. % alkali oxide, 5 to 30 wt. % alkaline earth oxide and 2 to 30 wt. % of other oxides such as Al2 O3 and/or Fe2O3. The glassy crystalline component accounts for 5 to 75 wt. % of the granular material. The glassy crystalline component of the granular material is a sinter reaction product. There is also a method of producing such a granular material in which the mixture is agglomerated at a temperature of 20° C. to 150° C. at normal pressure with the water vapour partial pressure being adjusted, selected or controlled as a function of time-temperature and carbon dioxide being excluded or admitted, whereby the admission of carbon dioxide is controlled by adjusting or selecting the carbon dioxide partial pressure.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: November 16, 2004
    Assignee: Mattig & Lindner GmbH
    Inventor: Siegfried Schelinski
  • Patent number: 6818314
    Abstract: A chemical, thermal, and electrical corrosion resistant dry mix for use in fusing glass to metal motor vehicle and building industry articles. A chemical, thermal, and electrical corrosion resistant composition for fusing glass to metal motor vehicle and building industry articles. A method of glass fusing metal motor vehicle and building industry articles using a chemical, thermal, and electrical corrosion resistant dry mix. A method of glass fusing metal motor vehicle and building industry articles with a chemical, thermal, and electrical corrosion resistant composition. A method of fusing single or multiple layers of glass to metal motor vehicle and building industry articles.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: November 16, 2004
    Inventor: Gary D. Wilson
  • Patent number: 6811602
    Abstract: A process for preparing a silicate porous product, which comprises a step of forming a clay mineral into a dispersion by means of a dispersant, a step of removing gases dissolved in the dispersion, a step of freezing the dispersion and drying it in its frozen state under reduced pressure, and a step of firing the dried product obtained by the drying.
    Type: Grant
    Filed: March 27, 2002
    Date of Patent: November 2, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Yoshihisa Beppu, Shinji Kondoh
  • Patent number: 6805737
    Abstract: The invention relates to a lightweight substance molded body made of a lightweight aggregate and a sintering auxiliary agent, wherein said molded body consist of a sintering product containing 60-95 wt. % lightweight aggregate with 40-5 wt. % water-soluble alkali silicate.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: October 19, 2004
    Assignees: Fraunhofer-Gesellschaft Zur Förderung Der Angewandten Forschung e.v., Gips-Schüle-Stiftung
    Inventors: Holger Gödeke, Jürgen Werner, Gerhard Babuke
  • Publication number: 20040194667
    Abstract: An aqueous inorganic solution for sealing the porosity of metal components made of sintered compacted powdered metal and castings formed from liquid metal, and a process for applying the solution onto the components. The solution consists primarily of a blend of inorganic metallic salt silicates with the metal ions being taken from Group 1A elements.
    Type: Application
    Filed: April 16, 2004
    Publication date: October 7, 2004
    Inventor: Craig J. Reuscher
  • Patent number: 6800375
    Abstract: A chemical, thermal, and electrical corrosion resistant dry mix for use in fusing glass to metal motor vehicle and building industry articles. A chemical, thermal, and electrical corrosion resistant composition for fusing glass to metal motor vehicle and building industry articles. A method of glass fusing metal motor vehicle and building industry articles using a chemical, thermal, and electrical corrosion resistant dry mix. A method of glass fusing metal motor vehicle and building industry articles with a chemical, thermal, and electrical corrosion resistant composition. A method of fusing single or multiple layers of glass to metal motor vehicle and building industry articles.
    Type: Grant
    Filed: November 20, 2002
    Date of Patent: October 5, 2004
    Inventor: Gary D. Wilson
  • Patent number: 6800130
    Abstract: The invention relates to a construction material comprising a hydraulic binder, water, and an aluminum-modified colloidal silica. The invention also relates to a method for preparing such materials and the use thereof.
    Type: Grant
    Filed: February 3, 2003
    Date of Patent: October 5, 2004
    Assignee: Akzo Nobel N.V.
    Inventors: Peter Greenwood, Hans Bergqvist, Ulf Skarp
  • Publication number: 20040182285
    Abstract: A modified alkali silicate composition for forming an inorganic polymer matrix having improved mechanical properties. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), a non-silicate network former and/or reactive glass, water and optionally one or more multivalent cation(s) selected from Groups 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15 or 16 of the periodic table such as an alkaline earth salt, water and optional processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and curing the composite at a temperature from about 15° C. up to 1000° C. and a pressure of up to 20,000 psi for typical high-performance organic polymer processing (temperatures about 15° C. to about 200° C. and pressures <200 psi).
    Type: Application
    Filed: February 12, 2004
    Publication date: September 23, 2004
    Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
  • Publication number: 20040182284
    Abstract: Thermochromic material comprising a thermochromic component and a binder, wherein the thermochromic component is crystal phases based on oxides of heavy metals of I, II, III, IV, V, VI, VII, VIII groups of the Periodic System selected from the group consisting of compounds of the following general formulae:
    Type: Application
    Filed: May 17, 2004
    Publication date: September 23, 2004
    Inventors: Anna Vasilievna Belykh, Alexandr Mikhailovich Efremov, Mikhail Dmitrievich Mikhailov
  • Patent number: 6793729
    Abstract: A conductive material for use in interior coating of a cathode ray tube (CRT), which includes an aqueous dispersion medium containing potassium silicate and a dispersing agent; and graphite particles. The potassium silicate of the aqueous dispersion medium has a silicon dioxide (SiO2) to potassium oxide (K2O) mole ratio in the range of 4.5:1 to 6:1, and is prepared by adding hydrosilica gel to a potassium silicate aqueous solution having a SiO2 to K2O mole ratio less than 4.5:1. When the conductive material, which uses potassium silicate dispersed in an aqueous dispersion medium with a SiO2:K2O mole ratio in the range of 4.5:1 to 6:1, as a binder, is applied to form a conductive layer on the funnel of a CRT, adhesiveness of the conductive layer markedly increases. Use of the potassium silicate as a binder decreases the amount of gas released during a hot-evacuation process, and thus shortens evacuation time.
    Type: Grant
    Filed: October 9, 2001
    Date of Patent: September 21, 2004
    Inventor: Chang-Hun Lee
  • Patent number: 6793728
    Abstract: The present invention relates to a composition for coating a metal substrate which is intended to be fabricated and overcoated, and wherein the binder comprises an aqueous silica sol or alkali metal silicate having a SiO2/M2O mole ratio of at least 6:1, where M represents total alkali metal and ammonium ions, and wherein the silica particles have an average size equal to or smaller than 10 nm. Very good results are obtained if the dried coating is post-treated with a film-strengthening solution.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: September 21, 2004
    Assignee: International Coatings Ltd.
    Inventors: Gerard Howard Davies, Paul Anthony Jackson, Peter Joseph McCormack
  • Patent number: 6749679
    Abstract: A cement composition for use in acidic environment containing liquid alkali silicate, vitreous silicate setting agent, lime containing material and inert filler and building materials made therefrom as well as the method of making such building materials. The liquid alkali silicate may include sodium silicate or potassium silicate. The vitreous silicate setting agent may include soda-lime glass powder or coal fly ash. The lime containing material refers to the materials containing more than 20% lime and may include quicklime, hydrated lime, Portland cement, blast furnace slag or steel slag. The inert fillers include ground quartz, ground ceramic, and/or clay.
    Type: Grant
    Filed: January 23, 2002
    Date of Patent: June 15, 2004
    Assignee: Advanced Materials Technologies, LLC
    Inventor: Caijun Shi
  • Publication number: 20040101748
    Abstract: The present invention discloses a novel polymer alloy that may be used as a casing for alkaline storage batteries. The present invention discloses a sealed alkaline storage battery comprising a cell in which power generating elements and an alkaline electrolyte are accommodated in a battery casing of a synthetic resin. The polymer alloy comprises polyphenylene ether, polystyrene and glass fibers. The polymer alloy of the present invention comprises about 30 to 45 weight % polyphenylene ether, about 30 to 45 weight % polystyrene and about 10 to 40 weight % glass fibers. Preferably, the polymer alloy comprises 1 to 1 ratio of polyphenylene ether to polystyrene and the polystyrene is high impact polystyrene. Additionally, the polymer alloy may further include 0 to 15 weight % of an elastomer.
    Type: Application
    Filed: November 26, 2002
    Publication date: May 27, 2004
    Inventors: Rajeev Puttaiah, Ronald Himmler, Lin R. Higley, Marshall D. Muller, Subhash K. Dhar
  • Patent number: 6730148
    Abstract: An inorganic fire-proof coating material can form a coat film to be transformed into a foamed layer demonstrating quite superior heat insulation ability by uniform foaming as subject to heat, such as that upon fire to prevent softening of the steel material coated by the coat film for a long period to be sufficiently practically applicable as a fire-proofing coat for steel frame structure or the like, and an inorganic fire-proof structure formed by coating the fire-proof coating material. The fire-proof coating material is consisted of an aqueous paste containing water soluble alkaline silicate in a content greater than or equal to 30 Wt % in components excluding water, holmite series mineral powder, and SiO2 supplying components other than water soluble alkaline silicate and holmite series mineral.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: May 4, 2004
    Assignees: Kawaguchi-Mac Industry Co, Ltd, Osaka Oil & Fat Co., Ltd.
    Inventor: Fujio Kondo
  • Patent number: 6689286
    Abstract: A shaped thermal insulation body comprises inorganic material. The shaped body has the following, weight-related composition: approx. 20 wt. % inorganic filling material: approx. 40 wt. % opacifier; approx. 10 wt. % fibrous material; and approx. 15 wt. % hardening agent as well as approx. 15 wt. % water. The shaped body only contains a small amount of fumed silica with a comparatively small BET surface. Water glass is excluded during its manufacture. It can be used as a spacer for radiant heaters.
    Type: Grant
    Filed: February 27, 2002
    Date of Patent: February 10, 2004
    Assignee: E.G.O. Elektro-Geraetebau GmbH
    Inventors: Eugen Wilde, Guenter Kratel, Bernhard Mikschl, Horst Pfob, Erich John
  • Patent number: 6645278
    Abstract: An intumescent powder where the molar ratio of SiO2 to Li2O+Na2O+K2O is between 2.20 to 3.70 to 1.00 and the molar ratio of Li2O to Li2O+Na2O+K2O is 0.20 to 0.35 has an intumescent point of 195° C. or higher and thus will not prematurely intumesce if mixed with another material at temperatures below 195° C. The powder as used is usually dried to 8-12% by weight to moisture for most purposes is ground to 50 to −500 microns. Preferred methods of manufacture comprise taking a source of lithium hydroxide or lithium silicate and a source of sodium silicate to create a powder with ratios as outlined above.
    Type: Grant
    Filed: July 5, 2002
    Date of Patent: November 11, 2003
    Assignee: Pyrophobic Systems Ltd.
    Inventors: Kevin B. Langille, Dat T. Nguyen, Dwight E. Veinot, Jorgen O. Bernt
  • Patent number: 6641649
    Abstract: An aqueous fire resistance treatment composition consisting of water, sodium silicate, a calcined filler and a latent acid catalyst is disclosed. The composition may be applied to cardboard substrates such as corrugated cardboard. The composition is then cured to provide enhanced fire resistance.
    Type: Grant
    Filed: October 15, 2002
    Date of Patent: November 4, 2003
    Assignee: Novio Phenolic Foam Pty Ltd
    Inventors: Anthony Jacob John, Per Ingmar Quist
  • Patent number: 6638354
    Abstract: Disclosed are amorphous precipitated silicas, silica gels, and amorphous carbons derived from biomass and methods of producing them with and without adhered or deposited amorphous carbons produced by acidifying a caustic silicate solution produced by caustic digestion of biomass ash containing silica with and without activated carbon, the ash being obtained from thermal pyrolysis of the biomass, the acidifying effective to produce a slurry of the precipitated silica and silica gels with and without adhered or deposited amorphous carbon, and separated from the slurry the precipitated silicas and silica gels with and without the adhered or deposited amorphous carbons. The properties of the precipitated silica with adhered or deposited carbon being within the range as utilized in rubber compositions thereby avoiding the blending of silica and carbon components for such use.
    Type: Grant
    Filed: January 30, 2002
    Date of Patent: October 28, 2003
    Assignees: Agritec, Inc., Occidental Chemical Corporation
    Inventors: Douglas K. Stephens, Clyde W. Wellen, Jeffrey B. Smith, Kenneth F. Kubiak
  • Patent number: 6632876
    Abstract: The invention relates to a product for the internal coating of a pipeline component (1), in particular a metal pipeline component, comprising an internal wall (4) of high curvature. This product comprises a solid charge and a liquid. The liquid is a solution of an alkali metal silicate and the solid charge comprises sand, between 20 and 30% by mass of a binder which sets chemically by reaction with the liquid, and between 4 and 10% by mass of plasticizing adjuvants. The solid charge and the liquid are intended to be mixed (in 5) with a liquid/binder ratio by mass of between approximately 0.3 and 0.45. Application to pipelines for discharge of waste water made of spheroidal graphite cast iron.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: October 14, 2003
    Assignee: Pont-A-Mousson S.A.
    Inventor: Pascal Soukatchoff
  • Publication number: 20030190431
    Abstract: The present invention provides a coating composition for substrates. The coating composition of the present invention generally includes a silicate binder and a plurality of photocatalytic particles. The silicate binder functions as a bonding agent to establish the coating on the substrate. A plurality of photocatalyst particles are dispersed throughout the silicate binder. The particles are included in an amount that provides sufficient distribution of the particles in the resulting coating. The incorporation of the present invention onto substrates prevents algal growth on building materials utilizing the coated substrates.
    Type: Application
    Filed: April 15, 2003
    Publication date: October 9, 2003
    Applicant: 3M Innovative Properties Company
    Inventor: Jeffry L. Jacobs
  • Publication number: 20030097966
    Abstract: Disclosed are amorphous precipitated silicas, silica gels, and amorphous carbons derived from biomass and methods of producing them with and without adhered or deposited amorphous carbons produced by acidifying a caustic silicate solution produced by caustic digestion of biomass ash containing silica with and without activated carbon, the ash being obtained from thermal pyrolysis of the biomass, the acidifying effective to produce a slurry of the precipitated silica and silica gels with and without adhered or deposited amorphous carbon, and separated from the slurry the precipitated silicas and silica gels with and without the adhered or deposited amorphous carbons. The properties of the precipitated silica with adhered or deposited carbon being within the range as utilized in rubber compositions thereby avoiding the blending of silica and carbon components for such use.
    Type: Application
    Filed: January 30, 2002
    Publication date: May 29, 2003
    Applicant: Agritec, Inc.
    Inventors: Douglas K. Stephens, Clyde W. Wellen, Jeffrey B. Smith, Kenneth F. Kubiak
  • Patent number: 6569793
    Abstract: A process is disclosed in which coarse silica, calcium oxides and magnesium oxides are treated in a ball mill together with grinding aids and cold-strength binders. This material is then agglomerated with water to produce a product that reacts at elevated temperatures, e.g. in a fluidized bed reactor, to produce synthetic silicates.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: May 27, 2003
    Assignee: Specialty Minerals (Michigan) Inc.
    Inventors: John Albert Hockman, Steven Andrew Ciccarelli
  • Patent number: 6524543
    Abstract: Disclosed is a commercial grade of soluble silicate solutions, clear homogenous and water white essentially free of unreacted silica, made by dissolving in a closed container biogenic silica, preferably rice hull ash, in a strong alkali solution, preferably sodium hydroxide in the presence of an agent, such as an active carbonaceous material, which prevents discoloration of the soluble silicates by absorbing and/or reacting with polyvalent metals, organic materials, and the like, in the biogenic silica as it dissolves in and reacts with the alkali solution. The invention takes advantage of the residue of such active carbonaceous material on the biogenic silica, such as rice hulls, left by commercial energy burning thereof which effectively prevents discoloration. A solid residue results from the method which is an active carbonaceous material including concentrated manganese from the biogenic silica, both of which are valuable commercial products.
    Type: Grant
    Filed: August 25, 1998
    Date of Patent: February 25, 2003
    Inventors: Roy S. Rieber, William A. Mallow, Jesse R. Conner
  • Patent number: 6506246
    Abstract: A substantially water-free hardener composition suitable for admixture with a cement to give a product capable of reaction with a silicate to form a hardened mass, comprises: (a) from 5 to 99.9%, preferably 75 to 99.8%, of an organic carbonate hardener for the silicate; (b) from 0.01 to 20%, preferably 0.02 to 10% of an organic retarder, preferably an organic acid retarder such as citric acid for the cement, the % being by weight based on the total weight of (a) and (b). The organic carbonate hardener is preferably a mixture of ethylene and propylene carbonates in proportions of from 3:1 to 1:3 by weight. The hardener may include a cement such as Portland cement. Suitable amounts are (a) organic carbonate hardener from 10 to 60%, (b) organic retarder is from 0.05 to 10% and (c) cement from 20 to 85%.
    Type: Grant
    Filed: June 8, 2001
    Date of Patent: January 14, 2003
    Assignee: Fosroc International Limited
    Inventors: Leslie W. Cheriton, Anthony C. Plaisted, Anthony M. James, Judith A. Simcox
  • Patent number: 6506247
    Abstract: A refractory furnace cement is provided, that can be formulated to be air setting and substantially free of silica. The composition can be formed with a refractory agent, a rheology modifier, a corrosion inhibitor, a binder, such as a sodium silicate type binder, a flocculating agent and various inorganic fillers, to promote thermal stability, shelf stability, appropriate setting times and cold mortar strength.
    Type: Grant
    Filed: November 28, 2001
    Date of Patent: January 14, 2003
    Assignee: Hercules Chemical Company Incorporated
    Inventor: Fred Richard Scholer
  • Patent number: 6506248
    Abstract: A formulation for preparing a cementitious product comprising a cementitious material, a siliceous material, and a low bulk density material being substantially calcium silicate hydrate and including unreacted siliceous reactant. A method of forming a cementitious product comprises adding a cementitious material, a siliceous material and a low bulk density material to water to form a slurry, forming a green shaped article from the slurry and curing the article in an autoclave, wherein the low bulk density material is substantially calcium silicate hydrate and includes unreacted siliceous reactant.
    Type: Grant
    Filed: July 17, 2001
    Date of Patent: January 14, 2003
    Assignee: James Hardie Research Pty Limited
    Inventors: Steve Duselis, Peter Goodwin, Nigel Kirby, Basil Naji, Anhthe Nguyen, Brian Sloane, David Stitt, James Gleeson
  • Patent number: 6506498
    Abstract: Coating powders are provided which provide high-temperature, translucent coatings useful for light-emitting devices such as incandescent bulbs. The coating powders comprise a binder, at least 90 wt % up to 100 wt % of which is a silicone resin. The coating powders are filled with between about 10 and about 50 phr of fillers selected from the group consisting of needle-like calcium metasilicate, mica, rod-like glass particles, and mixtures thereof, the fillers having aspect ratios between about 8 and about 40.
    Type: Grant
    Filed: March 16, 2001
    Date of Patent: January 14, 2003
    Assignee: Rohm and Haas Company
    Inventors: Owen H. Decker, Charles P. Tarnoski, Lee F. Spencer, Roy M. Berstler, James G. Fotiou
  • Patent number: 6478870
    Abstract: A process for preparing a flowable slurry comprising mixing 25-70 wt. % water; an alkaline material selected from the group consisting of chlorosilicon manufacturing byproducts, direct process residue gels, cement kiln dust, and mixtures thereof; and a process aid selected from the group consisting of sucrose, raffinose, lignin, methylglucopyranoside, lactose, fructose, sodium polyphosphate, trehalose and mixtures thereof to form a flowable slurry. This slurry is especially useful in the manufacture of cement.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: November 12, 2002
    Assignee: Dow Corning Corporation
    Inventor: Ollie William Marko
  • Patent number: 6468336
    Abstract: The present invention relates to novel water-borne shop primer (preconstruction primer) compositions comprising 5-40% by volume of a pigment mixture; 1.4-10% by volume of one or more water soluble silicates (based on the dry volume of the silicate); 40-90% by volume of water; and optionally one or more additives; said pigment mixture comprising 40-90% by weight of zinc, 10-60% by weight of micaceous iron oxide (MIO), and 0-50% by weight of a second filler (e.g. barium sulphate, kaolin, muscovite, quartz, etc.). The present invention also provides a method of using a shop primer composition for temporary protection of a steel surface, and to a method for the manufacture of a steel construction.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: October 22, 2002
    Assignee: J.C. Hempel's Skibsfarve-Fabrik A/S
    Inventors: Helle Fiedler, Dorte Jeanette Jensen, Ulla Kirsten Neestrup Hansen, Gruska Elisabeth Folkmann Musaeus
  • Patent number: 6464774
    Abstract: The present invention relates to provide a decorative wear resistant lithium silicate and sodium silicate based surface coating for use on concrete, timber or steel, comprising a coat of a high viscosity lithium silicate and sodium silicate solution incorporating a non reactive or inert filler and a pigment colouring matter, and after the coat is touch dry, the coat is treated with flame of gases directly to make fast reaction and harden the coat.
    Type: Grant
    Filed: February 24, 2000
    Date of Patent: October 15, 2002
    Inventor: Yukio Satoh
  • Patent number: 6419737
    Abstract: A cementitious matrix consisting essentially of aluminosilicate polymer containing a liquid component of an aqueous solution of an alkali metal silicate having the formula M2O.RSiO2.XH2O, in which: M is an alkali metal monovalent cation such K+ or Na+; R is the molar ratio of SiO2/M2O, where the range is between 0.5/1 and 9/1; and X is the amount of water, where the amount of water is between 30 and 70 wt %; and a powder component which contains the silico-aluminous reactive raw materials Al6Si2O13 and Al2O3.4SiO2, with a relative proportion between 40 and 60 wt %, where the particle size of both components ranges between 40 and 70 microns. The cementitious matrix has high mechanical strength and is resistant to high temperatures.
    Type: Grant
    Filed: January 18, 2000
    Date of Patent: July 16, 2002
    Assignee: H.T.B.S. Corporation B.V.
    Inventor: Anas Haji
  • Patent number: 6409818
    Abstract: The present invention is directed to a composition and method for forming an inexpensive, semi-permanent cured foamed cementitious cover layer over deicing salt which is stored outdoors in large bulk mounds or piles and a salt pile or mound covered with such a layer.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: June 25, 2002
    Assignee: Cargill, Incorporated
    Inventor: Philip S. Johnson
  • Publication number: 20020058576
    Abstract: A modified alkali silicate composition for forming an inorganic network matrix. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), an acidic inorganic composition, such as a reactive glass, water and optional fillers, additives and processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and applying the temperature and pressure necessary to consolidate the desired form. The composite can be shaped by compression molding as well as other known fabrication methods. A notable aspect of the invention is that, although composite and neat resin components prepared from the invention can exhibit excellent dimensional stability to 1000° C. and higher, they can be prepared at the lower temperatures and pressures typical to organic polymer processing.
    Type: Application
    Filed: June 1, 2001
    Publication date: May 16, 2002
    Inventors: Anthony M. Mazany, John W. Robinson, Craig L. Cartwright
  • Patent number: 6375735
    Abstract: Disclosed are amorphous precipitated silicas, silica gels, and amorphous carbons derived from biomass and methods of producing them with and without adhered or deposited amorphous carbons produced by acidifying a caustic silicate solution produced by caustic digestion of biomass ash containing silica with and without activated carbon, the ash being obtained from thermal pyrolysis of the biomass, the acidifying effective to produce a slurry of the precipitated silica and silica gels with and without adhered or deposited amorphous carbon, and separated from the slurry the precipitated silicas and silica gels with and without the adhered or deposited amorphous carbons. The properties of the precipitated silica with adhered or deposited carbon being within the range as utilized in rubber compositions thereby avoiding the blending of silica and carbon components for such use.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: April 23, 2002
    Assignees: Agritec, Inc., Occidental Chemical Corporation
    Inventors: Douglas K. Stephens, Clyde W. Wellen, Jeffrey B. Smith, Kenneth F. Kubiak