Abstract: Application of a redox polymer of the poly-[Me(R-Salen)] type onto a conducting substrate is accomplished by the method of electrochemical polymerization. Said polymerization is accomplished by supplying a voltage between the substrate (that serves as an anode) and a counter electrode (that serves as a cathode), with both of them being submerged into the electrolyte containing an organic solvent and the compounds capable of dissolving in said solvent. The process is accompanied by the production of electrochemically inactive (at concentrations of no less than 0.01 mol/l) ions within the range of potentials from ?3.0 V to +1.5 V, and metal complex [Me(R-Salen)] dissolved at a concentration of no less than 5-10?5 mol/l, (where: Me is a transition metal having at least two different degrees of oxidation, R is an electron-donating substituent, Salen is a residue of bis-(salicylaldehyde)-ethylenediamine in Schiff's base.

Abstract: A coated article is obtained by electrodeposition coating using an electrodeposition coating composition, which comprises: (A) a resin component obtained by reacting an epoxy resin, an amino compound and/or a phenolic compound; (B) a resin component having a specific structural unit; (C) a blocked polyisocyanate compound; and (D) at least one rust inhibiting component selected from the group consisting of metal ions selected from zirconium, titanium, cobalt, vanadium, tungsten and molybdenum, oxymetal ions of the metal, and fluorometal ions of the metal.

Abstract: A composite coated metal sheet comprising a coated film having a low environmental impact prepared free from hexavalent chromium, and having good corrosion resistance equivalent to that provided by chromate treatment and excellent adhesiveness between the coated film and a resin layer formed on the coated film. Also, a treatment agent and a method of manufacturing the composite coated metal sheet with the treatment agent is described. The composite coated metal sheet comprises a coated film formed on a surface of a plated metal sheet or metal sheet, the coated film contains an oxide and/or a hydroxide of metal other than chromium, and an organic component comprising modified and/or unmodified functional group(s).

Abstract: The disclosed invention relates to an article, comprising: a substrate having a surface comprising aluminum or an aluminum alloy; a sealed anodic coating layer overlying at least part of the surface of the substrate; and a layer of a silicon-containing polymer overlying the sealed anodic coating layer. The article may be useful as a brake or wheel component.

Abstract: Electrochemically deposited indium composites are disclosed. The indium composites include indium metal or an alloy of indium with one or more ceramic materials. The indium composites have high bulk thermal conductivities. Articles containing the indium composites also are disclosed.

Abstract: A method for growing carbon nanotubes having a determined chirality includes fragmenting at least one initial carbon nanotube having a determined chirality to obtain at least two portions of carbon nanotube. Each portion has a free growth end. Atoms of carbon are supplied with an autocatalyst addition of the atoms of carbon at the free growth end of each portion of nanotube to determine an elongation or growth of the nanotube.

Abstract: Process for the anodic electro-dipcoating of conducting surfaces by dipping in an aqueous anodic electro-dipcoating bath and connecting up as the anode, in which an aqueous anodic electro-dipcoating bath is used that contains 1 to 15 wt. %, referred to the binder solids of the electro-dipcoating bath, of one or more phosphoric acid epoxy esters and/or phosphonic acid epoxy esters that have been produced in the presence of alcohols.

Abstract: A method of manufacturing an aluminum substrate for printed circuits, comprises an oxide layer forming step and a heat-drying step. At the oxide layer forming step, an anodic oxide layer is formed on at least one surface of an aluminum plate by anodizing the aluminum plate in an electrolytic solution of phosphoric acid concentration: 3 to 20 mass % and bath temperature: not less than 25° C. but less than 40° C. At the heat-drying step, the anodic oxide layer is dried by heating it at 150 to 300° C. for 0.5 hour or more. According to this method, a proper oxide layer can be formed, resulting in an aluminum substrate for printed circuits capable of enhancing adhesiveness to a resin plate.

Abstract: The present invention provides a lead-free cationic electrodeposition coating composition which contains an aqueous medium, a binder resin composed of a cationic epoxy resin and a blocked isocyanate curing agent dispersed or dissolved in the aqueous medium, a neutralizing acid in order to neutralize the cationic epoxy resin, an organic solvent, and a metal catalyst, wherein the electrodeposition coating composition has a volatile organic content of 1% by weight or less, a metal ion content of 500 ppm or less, a neutralizing acid amount of 10 to 30 mg equivalent based on 100 g of binder resin solid content. The lead-free cationic electrodeposition coating composition has high throwing power, and exert a little influence on the environment due to its low VOC, low metal ion content, and reduced consumption of a coating composition itself.

Abstract: A method for producing a conductive polymer film, using an apparatus comprising a prism having a working electrode, a light-emitting means and a light probe disposed on both sides of the prism, a container attached to the prism in a liquid-tight manner with its open side facing the working electrode, an electrolytic solution containing a conductive-polymer-forming monomer and a dopant, which is contained in the container, a counter electrode immersed in the electrolytic solution, a power supply means connected to the working electrode and the counter electrode, and a controller connected to the light probe and the power supply means, the method comprising (1) forming the conductive polymer film on the working electrode by supplying current from the power supply means to the working electrode and the counter electrode, while projecting light to the prism, (2) determining an absorption spectrum from the light reflected by the conductive polymer film, (3) storing the relation between the absorbance of the conduc

Abstract: CED coating compositions comprising water, at least one monobasic acid, a resin solids content comprising a thermally crosslinkable binder system comprising (i1) at least one self-crosslinkable CED binder with isocyanate-reactive functional groups and oxime- and/or N,N-dialkyl hydroxylamine-blocked aromatic isocyanate groups and/or (i2) at least one externally crosslinkable CED binder with isocyanate-reactive functional groups and, as a crosslinking agent A, at least one polyisocyanate with oxime- and/or N,N-dialkyl hydroxylamine-blocked aromatic isocyanate groups, and at least one polybasic acid in a proportion of 1 to 50 meq acid per 100 g of resin solids.

Abstract: The invention relates to an anodic electrophoretic paint comprising at least one binding agent for anodic electrophoretic paint and an aqueous liquid medium, which anodic electrophoretic paint additionally contains at least one platelet-type metal pigment coated with a coating composition, wherein (a) the platelet-type metal pigment has a d50 value of the cumulative size distribution curve of from 4 to 35 ?m and is selected from the group consisting of leafing metal pigments, metal pigments coated with synthetic resin(s), and mixtures thereof, and (b) the coating composition is a coating composition having an organic backbone containing at least 10 carbons and possessing one or more functional groups for effecting adhesion or binding to the pigment surface, wherein the functional group is selected from the group consisting of phosphonic acids, phosphonates, phosphoric acids, phosphate esters, sulfonates, polyalcohols, and mixtures thereof, and (c) the coating composition exhibits acidic properties.

Abstract: Disclosed herein is a method of forming a guanidine group on carbon nanotubes to improve the dispersibility of carbon nanotubes, a method of attaching carbon nanotubes having guanidine groups to a substrate, and carbon nanotubes and a substrate manufactured by the above methods. The method of forming the guanidine group on the carbon nanotubes includes forming a carboxyl group on the carbon nanotubes, and forming the guanidine group on the carboxyl group of the carbon nanotubes. In addition, the method of attaching the carbon nanotubes having guanidine groups to the substrate includes coating a substrate with a polymer having crown ether attached thereto, drying the polymer layer having crown ether attached thereto formed on the substrate to be semi-dried, and coating the semi-dried polymer layer with a solution including carbon nanotubes having guanidine groups dispersed therein.

Abstract: A relatively thick electrode is positioned opposite the surface of a substrate/second electrode. The electrode and the substrate surface are both contacted by a solution including silicon nanoparticles. The substrate surface is completely immersed in the solution in a manner such that there is not an air/solution interface and there is no meniscus at the substrate surface. Application of electrical potential between the electrode and the substrate creates a film of silicon nanoparticles on the substrate. Drying of the film induces the film to roll up and form a silicon nanoparticle nanotube material. A film may be subdivided into an array of identical portions, and the identical portions will roll into identical tubes having same length and diameter. A silicon nanoparticle nanotube material of the invention includes nanotubes formed of silicon nanoparticles.

Abstract: The present invention is intended to provide a process for forming an electrodeposition coating film, wherein generation of gas pinhole is reduced and coating film appearance is excellent without using a specific resin as a binder resin. The present invention relates a process for forming an electrodeposition coating film having reduction of generation of gas pinhole, comprising a step of electrocoating by immersing an article to be coated in a cationic electrodeposition coating composition, wherein, the cationic electrodeposition coating composition comprises 10 to 30 parts by weight of a pigment comprising zinc oxide based on 100 parts by weight of a solid content of the coating composition, and the content of zinc oxide contained in the pigment is 0.25 to 5 parts by weight based on 100 parts by weight of the pigment.

Abstract: The present invention relates to a vertical-alignment type porous silicon including a first pore 11 which is formed in an upper side of the silicon, a second pore 12 which is formed in a lower side of the first pore 11 and has a diameter that is larger or smaller than a diameter of the first pore 11, a third pore 13 which is formed in a lower side of the second pore 12 and has a diameter that is identical or similar to the diameter of the first pore 11, and one or more pore parts 11, 12, and 13 which includes the first pore 11, the second pore 12, and the third pore 13. A pore part having a double structure is formed in a silicon. Thus, the silicon having an improved surface area can be obtained as compared to a known porous silicon, and since different electronic materials can be implanted into different pores, it is easy to form interfaces of the implanted electronic materials.

Abstract: A process is described for the preparation of modified electrodes useful for the measurement of analytes in biological fluids, comprising the deposition of Prussian blue on screen printed electrodes, and the modified electrodes prepared via said process; the enzymatic electrodes and the biosensors comprising said modified electrodes and the method for the determination of analytes in biological fluids which uses said modified electrodes are also described.

Abstract: In a cationic electrodeposition coating composition and a method of preparing the cationic electrodeposition coating composition, a cationic electrodeposition coating composition is prepared by dispersing a cationic electrodeposition resin in an aqueous medium containing about 0.5 to 3% by weight of zinc acetate. The cationic electrodeposition resin is prepared by reacting about 40 to about 60% by weight of a cationic resin prepared by an epoxy-amino addition reaction, about 2 to about 5% by weight of an acrylic cationic resin having an amino group, and about 30 to about 50% by weight of a polyisocyanate curing agent including partially blocked isocyanate functional groups. The cured film formed on the hard disc driver base frame by using the cationic electrodeposition coating composition contains no heavy metal such as lead or tin, has no appearance defect such as a pinhole and has excellent corrosion-resistance even when being cured at low temperature.

Abstract: An article to be inserted in a human or animal body cavity, use of the article and preparation thereof. The article has a biologically inhibiting arrangement of electrically connected electrode materials in direct contact with each other on one or more surfaces of the article The arrangement includes as electrode materials a metallic anode material and a cathode material, where the potential of the cathode material is higher than the potential of the anode material, The cathode material is an electrically conductive material selected among certain non-metallic materials. The arrangement provided on the article releases biological inhibiting ions of the metallic anode material or complexes of such ions when the biologically inhibiting arrangement is contacted with a body fluid.

Abstract: A surface treatment of electrical contact pieces in electrolytic plants, in particular of machines for the treatment of circuit boards and conductor sheets is discloses, wherein the contact pieces are made of titanium or some other oxidizing and therefore chemically and electrochemically resistant material. To eliminate unwanted metallization of the contact pieces as a result of an inadequate demetallization on account of the insulating oxide layer and in order to enhance protection against wear, an electrically conductive diamond coating is applied at least on the contact-making areas of the contact pieces.

Abstract: Disclosed are compositions and methods for alleviating the problem of reaction of lithium or other alkali or alkaline earth metals with incompatible processing and operating environments by creating an ionically conductive chemical protective layer on the lithium or other reactive metal surface. Such a chemically produced surface layer can protect lithium metal from reacting with oxygen, nitrogen or moisture in ambient atmosphere thereby allowing the lithium material to be handled outside of a controlled atmosphere, such as a dry room. Production processes involving lithium are thereby very considerably simplified. One example of such a process is the processing of lithium to form negative electrodes for lithium metal batteries.

Abstract: Methods for the application of a polymer-free coating onto a medical device using plasma electrolytic deposition, comprising: (i) optionally applying a metal precoating onto a medical device; (ii) placing the medical device in an electrolyte solution comprising an electrolyte; and (iii) establishing an electric potential under plasma electrolytic deposition conditions between an electrode and the medical device, such that the plasma electrolytic deposition conditions are adequate to sustain deposition from the electrolyte solution onto the surface of the medical device to form the coating. The invention also relates to coating compositions and coated medical devices, such as stents, made according to these methods. If desired, the polymer-free coating can be a drug-eluting coating.

Abstract: A photovoltaic cell exhibiting an overall conversion efficiency of at least 9.0% is prepared from a copper-indium-gallium-diselenide thin film. The thin film is prepared by simultaneously electroplating copper, indium, gallium, and selenium onto a substrate using a buffered electro-deposition bath. The electrodeposition is followed by adding indium to adjust the final stoichiometry of the thin film.

Abstract: A method for anodizing magnesium products, the method includes the steps of: providing an electrolyte, the electrolyte including a base solution, a blackening agent, and a complexing agent; putting a substrate material as an anode in the electrolyte, and putting another material as a cathode in the electrolyte; and supplying power between the anode and the cathode until a black coating is formed on the substrate material.

Abstract: A conductive diamond electrode including an electrode substrate comprising a material selected from the group consisting of a valve metal and an alloy based on the valve metal, at least a surface of the metal or alloy having been subjected to plasticization processing, or heat treatment in vacuum or inert atmosphere; and a conductive diamond film formed on the plasticization processed surface of the electrode substrate. When the electrode substrate is subjected to plasticization processing and heat treatment, peeling resistance of the conductive diamond film is improved, thereby an electrode life is prolonged.

Abstract: A biomimetically produced bone-analogous coating, comprising organic and inorganic main constituents, is suitable for coating metallic implant materials of any desired surfaces. The coating comprises a collagen matrix mineralized with calcium phosphate.

Abstract: A method and apparatus wherein an electrically conductive element is placed inside a previously installed metallic water vessel such as a supply pipe or well. A direct current voltage is then applied between the element and the conductive wall of the vessel. The conductive element can be a partially insulated wire. For causing deposition on the vessel, the voltage applied to the conductive element is of an amount sufficient to cause the potential of the metallic vessel to be lowered below the potential of the element by at least ?0.3 volts, and more adequately ?1.3 volts. An alternative embodiment involves reversing the polarity of the voltage applied between the conductive element and the vessel, causing the oxidation/reduction reaction to reverse, resulting in calcium carbonate being removed from the vessel by the production of acid at the surface of the vessel.

Abstract: A process directed to preparing surfactant-polycrystalline inorganic nanostructured materials having designed microscopic patterns. The process includes forming a polycrystalline inorganic substrate having a flat surface and placing in contact with the flat surface of the substrate a surface having a predetermined microscopic pattern. An acidified aqueous reacting solution is then placed in contact with an edge of the surface having the predetermined microscopic pattern. The solution wicks into the microscopic pattern by capillary action. The reacting solution has an effective amount of a silica source and an effective amount of a surfactant to produce a mesoscopic silica film upon contact of the reacting solution with the flat surface of the polycrystalline inorganic substrate and absorption of the surfactant into the surface. Subsequently an electric field is applied tangentially directed to the surface within the microscopic pattern.

Abstract: In an anodization apparatus and an anodization method for electrochemically treating a target substrate by irradiating the target substrate with light, treatment of a large target substrate can be made possible with smaller constituent elements. The electrical contact with the target substrate by a contact member is realized by a plurality of contact members or by the movement of a contact member to change the electrical contact position. The target substrate is manufactured in advance so as to have such a structure that portions thereof to be in contact with the plural contact members are connected to portions of a conductive layer on a treatment part thereof respectively.

Abstract: A method for depositing a film of an advanced material on a surface of an article is disclosed. The method comprises placing the article within a bath having a pair of spaced electrodes one of which is formed by the article and an electrolyte containing a source of the material to be deposited. A stream of bubbles is generated within the electrolyte adjacent to the cathode. A potential difference is applied across the cathode and anode such that a plasma glow discharge is formed in the bubble region. The plasma of ionised gaseous molecules formed within the bubble region acts to deposit a film of material on the surface of the article. The method may be carried out at atmospheric pressure and does not require a vacuum apparatus. An apparatus for carrying out this method is also disclosed.

Abstract: A technique includes applying a charge to a flow plate of a fuel cell stack and depositing a material on at least a portion of the flow plate in response to the charge. In some embodiments of the invention, the technique may be applied to a fuel cell stack that includes a passageway to communicate a coolant. As a result of the technique, the fuel cell stack may include a layer to line the passageway to electrically insulate the stack from the coolant.

Abstract: A new technique to synthesize barium titanate (BaTiO3) on homogeneous substrates (titanium) or heterogeneous substrates (silicon wafers, metal, glass, ceramics, polymers, other metals, etc.) is disclosed to include a first step to deposit a titanium film on a substrate by sputtering, and a second step to synthesize barium titanate film with uniformly dispersed spherical particles on the titanium-coated substrate in a electrolyte containing barium ions by electrochemically anodic oxidation.

Abstract: In order to regenerate permanganate solutions being utilized for the etching and roughening of plastics surfaces electrolytic methods are known. Though relatively small quantaties of by-products are produced with these methods as compared to chemical regeneration methods, large quantaties of manganese dioxide are produced when printed circuit boards are treated. In order to avoid formation of manganese dioxide during the regeneration method a novel cathode 2 has been found which is provided with a porous, electrically nonconducting layer 7 on the cathode body 3. The layer 7 preferably consists of a plastics material being resistant to acid and/or alkali.

Abstract: Thin films of transition metal complex-based redox polymers are electrodeposited on electrodes. When hydrated, an electrodeposited film conducts electrons by electron exchange between backbone-bound, but mobile, functional segments of its redox polymer constituents. These functional segments, or redox complexes, have labile ligands in their inner coordination spheres. The backbones of the redox polymers have strongly coordinating ligands. Electrodeposition results from coordinative crosslinking by exchange of labile ligands and strongly coordinating ligands between polymer chains. When a biological macromolecule or protein, such as a redox enzyme, is added to the solution from which the redox polymer is electrodeposited, it is co-electrodeposited on the electrode surface. When the co-deposited film contains redox enzymes, for example, the modified electrode may be used to catalyze the electrooxidation or electroreduction of substrates of the enzymes.

Abstract: This invention is to reduce the influence of a gas generated by an anodizing reaction. A silicon substrate (101) to be processed is horizontally held. A negative electrode (129) is arranged on the upper side of the silicon substrate (101), and a positive electrode (114) is brought into contact with the lower surface of the silicon substrate (101). The space between the negative electrode (129) and the silicon substrate (101) is filled with an HF solution (132). The negative electrode (129) has a number of degassing holes (130) to prevent a gas generated by the anodizing reaction from staying on the lower side of the negative electrode (129).

Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an energy enhanced process to deposit a silicate containing coating or film upon a metallic or conductive surface.

Abstract: A method for forming a highly adherent coating of a desired calcium phosphate phase on titanium-based substrates for use as orthopedic and dental implants. The calcium phosphate phase coating is electrochemically deposited onto the substrate from a metastable calcium phosphate electrolyte solution using a modulated electrical potential under pH, temperature and electrolyte composition and concentration conditions favorable for forming the desired calcium phosphate.

Abstract: Using pulsed current and relatively low average voltages, articles containing light metals such as magnesium may be rapidly anodized to form protective surface coatings. The anodizing solutions employed may contain phosphate, permanganate, silicate, zirconate, vanadate, titanate, hydroxide, alkali metal fluoride and/or complex fluoride, optionally with other components present.

Abstract: The disclosure relates to a process for forming a deposit on the surface of a metallic or conductive surface. The process employs an electrolytic process to deposit a silicate containing coating or film upon a metallic or conductive surface.

Abstract: There is disclosed a process and apparatus for carrying out plasma electrolytic oxidation of metals and alloys, forming ceramic coatings on surfaces thereof at a rate of 2-10 microns per minute. The process comprises the use of high-frequency current pulses of a certain form and having a given frequency range, combined with the generation of acoustic vibrations in a sonic frequency range in the electrolyte, the frequency ranges of the current pulses and the acoustic vibrations being overlapping. The process makes it possible to introduce ultra-disperse powders into the electrolyte, with the acoustic vibrations helping to form a stable hydrosol, and to create coatings with set properties. The process makes it possible to produce dense hard microcrystalline ceramic coatings of thickness up to 150 microns. The coatings are characterised by reduced specific thickness of an external porous layer (less than 14% of the total coating thickness) and low roughness of the oxidised surface, Ra 0.6-2.1 microns.

Abstract: A process for forming oxide based dense ceramic composite coatings on reactive metal and allow bodies involves suspension of at least two reactive metal or alloy bodies in a non-metallic, non-conducting, non-reactive chamber in such a way that it causes either partial or full immersion of the bodies in a continuously circulating electrolyte. Thyristor controlled, modified shaped wave multiphase alternating current power supply is applied across the bodies where in each body is connected to an electrode. Electric current supplied to the bodies is slowly increased to a particular value till the required current density is achieved and the maintained at the same level throughout the process. Visible arcing at the surface of the immersed regions of the bodies is identified when the applied electric potential crosses 60V. Electric potential is further increased gradually to compensate the increasing resistance of the coating.

Abstract: A method, a composition and a method for making the composition for anodizing metal surfaces, especially magnesium surfaces is disclosed. The composition is a basic aqueous solution including hydroxylamine, phosphate anions and nonionic surfactants. A complementary method, composition and method for making the composition for rendering an anodized metal surface, especially a magnesium surface, conductive is disclosed. The composition is a basic aqueous solution including bivalent nickel, pyrophosphate anions, sodium hypophosphite and either ammonium thiocyanate or lead nitrate.

Abstract: A process for producing a zinc oxide acicular structure by growing an acicular zinc oxide on a substrate, the process comprising the steps of holding the substrate in an electrolytic solution in which at least zinc ions are present, and forming zinc oxide on the substrate by electrodeposition. The electrolytic solution contains at least one cosolute. Also disclosed is a photoelectric conversion device comprising a charge transport layer having the zinc oxide acicular structure.

Abstract: Disclosed is a method of preparing self-assembled monolayers on a metal comprising electrolyzing a thiosulfate compound in a solvent, where the electricity for the electrolysis is applied at a voltage for a period of time.

Abstract: A method and apparatus for anodizing a component. The component is placed in a container having a supply port, a drain port and a supply passage. The supply passage faced on a surface of the component to be anodized. A reaction medium is supplied from the supply port to the drain port. An electric current is supplied from an electrode provided on the drain port side of the surface. The apparatus prevents any hydrogen gas created by the electrode from recirculating to the surface of the component.

Abstract: A method of fabricating a semiconductor device, having a reduced-oxygen Cu—Zn alloy thin film (30) electroplated on a Cu surface (20) by electroplating, using an electroplating apparatus, the Cu surface (20) in a unique chemical solution containing salts of zinc (Zn) and copper (Cu), their complexing agents, a pH adjuster, and surfactants; and annealing the electroplated Cu—Zn alloy thin film (30); and a semiconductor device thereby formed. The method controls the parameters of pH, temperature, and time in order to form a uniform reduced-oxygen Cu—Zn alloy thin film (30), having a controlled Zn content, for reducing electromigration on the Cu—Zn/Cu structure by decreasing the drift velocity therein which decreases the Cu migration rate in addition to decreasing the void formation rate, for improving device reliability, and for increasing corrosion resistance.

Abstract: A polishing method and polishing apparatus able to easily flatten an initial unevenness with an excellent efficiency of removal of excess copper film and suppress damage to a lower interlayer insulation film, and a plating method and plating apparatus able to deposit a flat copper film. The polishing method comprises the steps of measuring thickness equivalent data of a film on a wafer, making a cathode member smaller than the surface face a region thereof, interposing an electrolytic solution between the surface and the cathode member, applying a voltage using the cathode member as a cathode and the film an anode, performing electrolytic polishing by electrolytic elution or anodic oxidation and chelation and removal of a chelate film in the same region preferentially from projecting portions of the film until removing the target amount of film obtained from the thickness equivalent data, and repeating steps of moving the cathode member to another region to flattening the regions over the entire surface.

Abstract: A conductive cap for use in an electronic component, has an opening at a bottom portion thereof, and is constructed to be fixed to the upper surface of a substrate of the electronic component at the opening portion of the cap so as to cover at least an electronic component element mounted on the upper surface of the substrate having terminal electrodes provided thereon. The end surface of the opening and the inner and outer surfaces thereof in connection to and in the vicinity of the end surface are provided with an insulating film disposed thereon.

Abstract: Using aqueous electrolytes containing complex fluorides or oxyfluorides such as fluorozirconates, fluorotitanates, and fluorosilicates, articles containing light metals such as magnesium and aluminum may be rapidly anodized to form protective surface coatings. White coatings may be formed on aluminum articles using pulsed direct current or alternating current. When the article to be anodized is comprised of magnesium, pulsed direct current having a relatively low average voltage is preferably used.

Abstract: This invention relates to radioactively coated devices, preferably radioactively coated medical devices. These coated devices are characterized as having a low rate of leaching of the radioisotope from the surface of the coated device and a uniform radioactive coating, and are therefore suitable for use within biological systems. Methods for coating a device with a radioisotope comprising are also disclosed. One method comprises immersing the device within a solution containing a &Ugr;, &bgr;+, &agr;, &bgr;− or &egr; (electron capture) emitting radioisotope, then exposing the immersed substrate to tuned vibrational cavitation to produce a coated substrate. A second method involves coating a substrate using electroless plating, and yet a third method involves the use of electroplating a radioisotope onto a substrate of interest. With these methods, the coating procedures are followed by baking the coated substrate at a temperature below the recrystallization temperature of the substrate.