Catalytic Patents (Class 208/113)
  • Publication number: 20040074809
    Abstract: Reduced emissions of gas phase reduced nitrogen species in the off gas of an FCC regenerator operated in a partial or incomplete mode of combustion is achieved by contacting the off gas with an oxidative catalyst/additive composition having the ability to reduce gas phase nitrogen species to molecular nitrogen. Fluidizable particles of the oxidative catalyst/additives are circulated throughout the partial or incomplete burn FCC unit along with the FCC catalyst inventory. The flue gas having a reduced content of gas phase reduced nitrogen species and NOx is passed to a downstream CO boiler, preferably a low NOx CO boiler. In the CO boiler, as CO is oxidized to CO2, a reduced amount of gas phase reduced nitrogen species is oxidized to NOx, thereby providing an increase in the overall reduction of NOx emitted into the environment.
    Type: Application
    Filed: October 21, 2002
    Publication date: April 22, 2004
    Inventors: George Yaluris, John Allen Rudesill
  • Patent number: 6723228
    Abstract: An additive used in catalytic cracking of hydrocarbons, which is in the form of homogeneous liquid and comprises a composite metal compound, wherein said composite metal compound consists of the oxides, hydroxides, organic acid salts, inorganic acid salts or metal organic complex compounds of at least one of the 1st group metals and at least one of the 2nd group metals, wherein the 1st group metals are selected from the group consisting of the metals of the IIIA, IVA, VA, VIA groups of the Element Period Table, boron, silicon, phosphorous and tellurium; wherein the 2nd group metals are selected from the group consisting of alkali-earth metals, transition metals, and rare earth metals, is disclosed. A process of catalytic cracking of hydrocarbons, utilizing the additive is also disclosed. The additive can passivate metals and promote the oxidation of CO, and is operated easily with production cost decreased.
    Type: Grant
    Filed: June 11, 2003
    Date of Patent: April 20, 2004
    Assignees: China Petrochemical Corporation, Luoyang Petrochemical Engineering Corporation
    Inventors: Shuqin Su, Guoliang Wang, Haiqing Guo, Xianliang Deng, Longyan Wang, Wenyi Qi, Shufang Liu, Baojian Shen, Jinlong Liu, Dongming Zhao
  • Patent number: 6723227
    Abstract: Fluidized catalytic cracking process which process comprises: (a) separating the hydrocarbon product from the spent catalyst by means of one or more gas-solid separation steps; (b) stripping the spent catalyst in a dense phase fluidized stripping zone by introducing a stripping medium in the lower portion of the stripping zone; (c) introducing part of the spent catalyst obtained in step (b) to a regeneration zone wherein the coke is removed from the catalyst by means of combustion; (d) introducing the remaining part of the spent catalyst and part of the hot regenerated catalyst into a lower portion of an elongated dilute phase stripping zone; (e) introducing a stream of a stripping medium into the lower portion of the dilute phase stripping zone to contact the resulting mixture of spent catalyst and regenerated catalyst therein; (f) passing a stream of the spent catalyst mixed with the hot regenerated catalyst and stripping medium in the dilute phase stripping zone; (g) introducing the separated catalyst of s
    Type: Grant
    Filed: November 8, 2001
    Date of Patent: April 20, 2004
    Assignee: Shell Oil Company
    Inventor: Rene Samson
  • Publication number: 20040069681
    Abstract: A catalyst regenerator for regenerating spent light FCC catalyst and heating the catalyst to supply heat to an FCC reactor. The regenerator has discharge outlets for catalyst and off gas and a valve for introducing spent catalyst through a central stand pipe portion. The regenerator houses a dense phase catalyst bed. A centerwell receives a lower end of the standpipe portion and defines an annulus therebetween. The spent catalyst is introduced through the standpipe portion into the annulus. A fuel distributor introduces fuel into the centerwell for mixing with the catalyst in the annulus. A fluidization distributor introduces fluidization gas into the centerwell for fluidizing the catalyst in the annulus. A radial slot in the centerwell introduces the catalyst and fuel mixture from the annulus below the upper surface of the dense phase bed. An air distributor located below the radial slot introduces combustion air into the dense phase bed.
    Type: Application
    Filed: October 10, 2002
    Publication date: April 15, 2004
    Applicant: Kellogg Brown & Root, Inc.
    Inventors: Robert B. Peterson, Chris Santner, Michael Tallman
  • Publication number: 20040069684
    Abstract: A method and system for recovering fines from a light FCC-type effluent gas. Cracked gases from the reactor are cooled by direct contact with circulating oil in an oil quench tower. The circulating oil also washes out the catalyst fines carried with the reactor effluent gas. A flow of the oil from the quench tower bottoms is sent through one of a pair of filters to remove fines and recycled to the tower. The other filter is in backwash operation using a compressed gas to remove the fines therefrom and into a surge drum. Fuel oil or quench oil is added to the drum to form a slurry, which carries the catalyst fines to the regenerator where the oil is combusted to supply the FCC system heat requirements. Since a minimum amount of fuel oil is generated in the FCC, fuel oil is imported to inventory the quench tower.
    Type: Application
    Filed: October 10, 2002
    Publication date: April 15, 2004
    Applicant: Kellogg Brown & Root, Inc.
    Inventors: Michael Tallman, Robert B. Peterson, Maureen F. Gilbert
  • Publication number: 20040060846
    Abstract: The present invention provides a catalytic cracking reactor system and process in which a riser reactor is configured to have two sections of different radii in order to produced improved selectivity to propene and butenes as products.
    Type: Application
    Filed: September 30, 2003
    Publication date: April 1, 2004
    Inventor: Warren S. Letzsch
  • Patent number: 6709572
    Abstract: A catalytic cracking process for selectively producing C2 to C4 olefins is described in which a feedstock containing hydrocarbons having at least 5 carbon atoms is contacted, under catalytic cracking conditions, with a catalyst composition comprising the synthetic porous crystalline material ITQ-13 and, optionally, a large pore molecular sieve, such as zeolite Y.
    Type: Grant
    Filed: February 14, 2003
    Date of Patent: March 23, 2004
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Avelino Corma
  • Publication number: 20040035751
    Abstract: The present invention relates to new mesoporous inorganic solids in the form of primary and/or secondary inorganic particles of D10≧1 &mgr;m and D50≧3 &mgr;m, preferably from D10≧2 &mgr;m and D50≧10 &mgr;m the size of which can go up to 10 mm, wherein the microporous volume (pores of size less than or equal to 2 &mgr;m) represents at most 10% of the total porous volume up to 300 nm.
    Type: Application
    Filed: May 14, 2003
    Publication date: February 26, 2004
    Applicant: CECA, S.A.
    Inventor: Dominique Plee
  • Publication number: 20040035750
    Abstract: The present invention provides an FCC catalyst which not only deactivates catalyst poison metals, such as nickel, vanadium and the like, in feedstock oils, inhibits the generation of hydrogen or coke, has excellent cracking activity and bottom oil-treating ability, and can yield a gasoline and LCO fraction in high yields, but also retains the performances on a high level over long and has an improved catalyst life; and an FCC method using the catalyst.
    Type: Application
    Filed: February 25, 2003
    Publication date: February 26, 2004
    Inventors: Tadashi Shibuya, Junko Naito, Hidenori Yamada, Nobuki Sekine
  • Patent number: 6696614
    Abstract: Catalyst for steam cracking reactions consisting of pure mayenite having the general formula: 12CaO.7Al2O3 having an X-ray diffraction spectrum as indicated in Table I, obtained with a preparation process comprising the following steps: dissolution of salts containing calcium and aluminum with water; complexing of the dissolved salts by means of polyfunctional organic hydroxyacids; drying of the solution resulting from the completing in order to obtain a solid precursor product; calcination of the solid precursor product at a temperature ranging from 1300 to 1400° C. for at least two hours.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: February 24, 2004
    Assignees: ENICHEM S.p.A., ENITECNOLOGIE S.p.A.
    Inventors: Paolo Pollesel, Caterina Rizzo, Carlo Perego, Renato Paludetto, Gastone Del Piero
  • Publication number: 20040031728
    Abstract: A shelf is incorporated into a typical FCC riser that permits the tips of the nozzles to extend past the wall of the riser while preventing the tips from promoting coke build-up and protecting the tips from erosion. The shelf can be part of an angled section that often appears in a transition zone for increasing the internal diameter of the riser to accommodate the volumetric expansion of the feed. The shelf section reduces the non-uniformity in the mixing of the catalyst and feed and minimizes backmixing of the feed injection. The shelf of this invention accomplishes these objectives without recessing the feed injectors into the riser wall which can interfere with the spray pattern.
    Type: Application
    Filed: September 2, 2003
    Publication date: February 19, 2004
    Inventor: Aziz A. Sattar
  • Publication number: 20040016676
    Abstract: A catalytic composition useful for cracking and reducing the viscosity of heavy hydrocarbons. The catalytic composition comprises Portland cement, a volcanic ash component, titanium dioxide, and a transition metal salt. Optionally, a hydrogen source is added to the catalytic composition.
    Type: Application
    Filed: July 24, 2003
    Publication date: January 29, 2004
    Inventor: Jeffrey P. Newton
  • Publication number: 20040004024
    Abstract: The present invention relates to non-noble metal catalyst comprising Cu—Al/Ce—Al complex oxides and aluminum oxide support. The catalysts comprise Ce—Al complex oxide and Cu—Al complex oxide successively loaded on the aluminum oxide support, wherein the loading weight ratio is 0.02-0.10 for Ce—Al—O/Al2O3 and 0.05-0.15 for Cu—Al—O/Al2O3, and the Cu—Al complex oxide is dispersed in cluster form on the surface of the aluminum oxide support pre-covered with high dispersed nanoparticles of the Ce—Al complex oxide.
    Type: Application
    Filed: April 21, 2003
    Publication date: January 8, 2004
    Inventors: Bingxiong Lin, Wanjing Zhang, Yingjun Liu, Shijie Li, Neng Li
  • Publication number: 20040004023
    Abstract: An integrated fluid catalytic cracking (FCC) and desulfurization system for processing hydrocarbon-containing fluids. The integrated system employs a cracking/desulfurization unit having a reactor, a regenerator, and a reducer. A mixture of solid FCC catalyst particulates and solid sulfur sorbent particulates are circulated through the reactor, regenerator, and reducer to provide for substantially continuous cracking and desulfurization of the hydrocarbon-containing fluid, as well as substantially continuous regeneration of both the FCC catalyst and the sulfur sorbent.
    Type: Application
    Filed: July 5, 2002
    Publication date: January 8, 2004
    Inventors: Edward L. Sughrue, Gil J. Greenwood
  • Publication number: 20040004025
    Abstract: A downflow catalytic cracking reactor, comprising: one or more catalyst delivery pipes, reactor top cover, one or more feed nozzles, reactor vessel, downflow reaction pipe, the upper end of the reaction vessel is close connected with top cover along the direction of circumference; the bottom of the reactor vessel is close connected with the outer wall of the downflow reaction pipe; the upper section of the downflow reaction pipe locates inside the reactor vessel, while the lower section extends from the bottom of the reactor vessel; feed nozzle locates on the top cover and/or side wall of the reactor vessel with the outlet of the feed nozzle being above the inlet of downflow reaction pipe; catalyst delivery pipe is fixedly jointed with the reactor vessel and communicated with catalyst lifting zone formed by the reactor vessel and the downflow reaction pipe. Besides, the present invention also provides the use of the reactor.
    Type: Application
    Filed: April 24, 2003
    Publication date: January 8, 2004
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING SINOPEC
    Inventors: Kejia Xu, Shuandi Hou, Jun Long, Xiaoxiang Zhong, Jiushun Zhang, Zhanzhu Zhang, Songnian Li, Xuefeng Wu, Jun He
  • Publication number: 20030234209
    Abstract: This invention provides a method for controlling solids circulation in a gas-solids reaction system. The method entails aerating solid particles in a standpipe. Aeration fluid is injected into the standpipe at the appropriate location to increase apparent density of the solid particles.
    Type: Application
    Filed: May 2, 2003
    Publication date: December 25, 2003
    Inventors: Jeffrey S. Smith, Nicolas P. Coute, Rathna P. Davuluri, Steven S. Lowenthal, Suisheng M. Dou
  • Patent number: 6660158
    Abstract: A catalytic cracking process is described wherein the cracking takes place in a reactor under the influence of a rotating fluidized bed catalyst and compressed gases and/or steam is injected in order to effect movement of the catalyst bed.
    Type: Grant
    Filed: August 9, 2001
    Date of Patent: December 9, 2003
    Assignee: EllyCrack AS
    Inventor: Olav Ellingsen
  • Publication number: 20030221992
    Abstract: The present invention relates to a process for increasing the capacity for processing residua and obtaining higher yields of liquids having an average boiling point equal to or less than about 510° C. A residual feedstock is introduced with recycled product asphaltenes into a short vapor contact time thermal process unit wherein the vaporized product is sent to a fractionator zone to produce a 510° C.− fraction and a 510° C.+ fraction. The 510° C.+ fraction is sent to a solvent extraction zone to produce an asphaltene-rich fraction that is recycled to the short vapor contact time thermal process unit.
    Type: Application
    Filed: February 18, 2003
    Publication date: December 4, 2003
    Inventors: Martin L. Gorbaty, Michael Siskin, Mitchell Jacobson
  • Publication number: 20030221991
    Abstract: An additive to enhance the activity of an FCC catalyst containing zeolite and matrix components comprises zeolite microspheres having a novel morphology comprising a macroporous matrix and crystallized zeolite freely coating the walls of the pores of the matrix. The additives formed from microspheres containing a metakaolin and kaolin calcined through its exotherm, the latter calcined kaolin being derived from a kaolin having a high pore volume. Kaolin having a high pore volume can be a pulverized ultrafine kaolin or a kaolin which has been pulverized to have an incipient slurry point less than 57% solids.
    Type: Application
    Filed: May 31, 2002
    Publication date: December 4, 2003
    Inventor: Michael Thomas Hurley
  • Patent number: 6656344
    Abstract: A sequential processing for heavy petroleum residues is disclosed which uses a separate mixture of catalyst and adsorbent. The solid adsorbent and FCC (fluids catalytic cracking) catalyst particles differ significant at least on particle size or density or both. The adsorbent preferably consist of calcined coke or metal oxides of Al, Si, or Mg having enhanced ability of selectively capture different impurities of the residual oil. The adsorbent particles first treat the residual hydrocarbons in the riser bottom end subsequently the actual catalyst tales care of catalytic cracking in the upper section of the riser. The spent solid mixture is fed to the catalyst separator which uses steam at sufficiently high velocity but at lower temperature to lift the catalyst particles out of the separator. Such a novel low temperature faster separation minimizes Vanadium mobility and deactivation of the catalyst. A net coke stream is withdrawn from the separator/burner especially while processing residues above 5 wt % CCR.
    Type: Grant
    Filed: September 8, 2000
    Date of Patent: December 2, 2003
    Inventors: Marri Rama Rao, Vutukuru Lakshmi Narasimha Murthy, Sanjeev Singh, Asit Kumar Das, Sobhan Ghech, Debasis Bhattacharyya, Sansh Makhija, Sukumar Mandal
  • Patent number: 6656345
    Abstract: The invention provides a method for converting a hydrocarbon feedstock to propylene comprising: contacting an olefinic hydrocarbon feedstock boiling in the naphtha range with a catalyst comprising a zeolitic catalyst selected from the group consisting of medium pore zeolites having a ratio of silica to alumina above 200 and pore diameter less than 0.7 nm under cracking conditions to selectively produce propylene. The preferred catalyst comprises of a zeolite having an 8, 10, or 12 membered ring pore structure. The preferred catalysts are selected from the group consisting of zeolites from the families MFI, MEL, MTW, TON, MTT, FER, MFS, and the zeolites ZSM-21, ZSM-38 and ZSM-48. Preferably the method is carried out to produce propylene with greater than 50% specificity, more preferably, the propylene to butylene ratio is at least 2:1 or a propylene to ethylene ratio of at least 4:1. The olefinic hydrocarbon feedstock consists essentially of hydrocarbons boiling within the range of 18° to 220° C.
    Type: Grant
    Filed: May 4, 1999
    Date of Patent: December 2, 2003
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Tan-Jen Chen, Mechilium (Marcel) Johannes Gerardus Janssen, Luc Roger Marc Martens, Machteld Maria Mertens, Philip Andrew Ruziska, Lynn L. Zhao, Jannetje Maatje van den Berge
  • Patent number: 6656346
    Abstract: A heavy fraction oil is catalytically cracked by contacting the oil with a catalyst mixture consisting of 60 to 95 wt % of a base cracking catalyst containing an ultra stable Y-type zeolite and less than 0.5 wt % of rare-earth metal oxide, and 5 to 40 wt % of an additive containing a shape-selective zeolite, in a fluid catalytic cracking apparatus under conditions that a reaction zone outlet temperature is in the range of 580 to 630° C., the catalyst/oil ratio is in the range of 15 to 40 wt/wt, and the contact time of hydrocarbons in the reaction zone is in the range of 0.1 to 1.0 seconds, wherein the yield of light-fraction olefins can be enhanced.
    Type: Grant
    Filed: June 7, 2001
    Date of Patent: December 2, 2003
    Assignees: King Fahd University of Petroleum and Minerals, Petroleum Energy Center
    Inventors: Takashi Ino, Toshiaki Okuhara, Mohammad Abul-Hamayel, Abdullah Aitani, Abdulgader Maghrabi
  • Patent number: 6652736
    Abstract: The invention concerns a stripping method for extracting solid fluidized particles whereby the particles to be stripped are subjected to a first stripping in a first chamber (9), then at least a second stripping in a second chamber (10) wherein are provided solid/gas separating means allowing the gaseous fluids derived from the second stripping to directly pass through from the bottom to the top but preventing them from going up again into the first chamber (9). The invention also concerns a device for implementing said method.
    Type: Grant
    Filed: April 23, 2001
    Date of Patent: November 25, 2003
    Assignee: Total Raffinage Distribution S.A.
    Inventors: Mariano Del Pozo, Tanneguy Descazeaud, Daniel Barthod
  • Publication number: 20030209468
    Abstract: An additive used in catalytic cracking of hydrocarbons, which is in the form of homogeneous liquid and comprises a composite metal compound, wherein said composite metal compound consists of the oxides, hydroxides, organic acid salts, inorganic acid salts or metal organic complex compounds of at least one of the 1st group metals and at least one of the 2nd group metals, wherein the 1st group metals are selected from the group consisting of the metals of the IIIA, IVA, VA, VIA groups of the Element Period Table, boron, silicon, phosphorous and tellurium; wherein the 2nd group metals are selected from the group consisting of alkali-earth metals, transition metals, and rare earth metals, is disclosed. A process of catalytic cracking of hydrocarbons, utilizing the additive is also disclosed. The additive can passivate metals and promote the oxidation of CO, and is operated easily with production cost decreased.
    Type: Application
    Filed: June 11, 2003
    Publication date: November 13, 2003
    Inventors: Shuqin Su, Guoliang Wang, Haiqing Guo, Xianliang Deng, Longyan Wang, Wenyi Qi, Shufang Liu, Baojian Shen, Jinlong Liu, Dongming Zhao
  • Patent number: 6635168
    Abstract: The present invention is directed to certain catalyst compositions and processes that are capable of reducing sulfur compounds normally found as part of the gasoline fraction streams of fluid catalytic cracking processes. The present invention requires an equilibrium cracking catalyst composition comprises at least one Y-type zeolite having kinetic conversion activity of at least about 3 in combination with a Lewis acid containing alumina composite present in at least 50 weight percent of the composition. The resultant equilibrium catalyst composition has a kinetic conversion activity of at least about 2.
    Type: Grant
    Filed: April 13, 2001
    Date of Patent: October 21, 2003
    Assignee: W. R. Grace & Co.-Conn
    Inventors: Xinjin Zhao, Wu-Cheng Cheng, John Allen Rudesill, Richard Franklin Wormsbecher, Pilip Stephen Deitz
  • Publication number: 20030188991
    Abstract: A process for treating organic compounds includes providing a composition which includes a substantially mesoporous structure of silica containing at least 97% by volume of pores having a pore size ranging from about 15 Å to about 30 Å and having a micropore volume of at least about 0.01 cc/g, wherein the mesoporous structure has incorporated therewith at least about 0.02% by weight of at least one catalytically and/or chemically active heteroatom selected from the group consisting of Al, Ti, V, Cr, Zn, Fe, Sn, Mo, Ga, Ni, Co, In, Zr, Mn, Cu, Mg, Pd, Pt and W, and the catalyst has an X-ray diffraction pattern with one peak at 0.3° to about 3.5° at 2&thgr;.
    Type: Application
    Filed: December 6, 2002
    Publication date: October 9, 2003
    Inventors: Zhiping Shan, Jacobus Cornelius Jansen, Chuen Y. Yeh, Philip J. Angevine, Thomas Maschmeyer
  • Publication number: 20030171634
    Abstract: A catalytic cracking process for selectively producing C2 to C4 olefins is described in which a feedstock containing hydrocarbons having at least 5 carbon atoms is contacted, under catalytic cracking conditions, with a catalyst composition comprising the synthetic porous crystalline material ITQ-13 and, optionally, a large pore molecular sieve, such as zeolite Y.
    Type: Application
    Filed: February 14, 2003
    Publication date: September 11, 2003
    Inventor: Avelino Corma
  • Patent number: 6616900
    Abstract: An FCC process provides ultrashort catalyst and feed contacting in an FCC riser by recovering a short contact product stream in an intermediate section of the riser. The remainder of the catalyst and gas mixture continues through the riser along a continuous flow path for further controlled cracking of the heavier adsorbed hydrocarbons and entrained hydrocarbons. Residual catalyst separated from the recovery of the short contact product stream returns to the upstream end of the riser for recycle. The section of the riser downstream of the short contact product recovery may receive additional feed to perform secondary cracking reactions. The riser arrangement greatly simplifies methods for performing ultrashort FCC feed and catalyst contacting.
    Type: Grant
    Filed: October 15, 1999
    Date of Patent: September 9, 2003
    Assignee: UOP LLC
    Inventor: David A. Lomas
  • Publication number: 20030159972
    Abstract: The present invention relates to a cracking catalyst comprising layered clays and a process for cracking hydrocarbon oils using said catalyst. Said catalyst is prepared by the process comprising the following steps: mixing and slurrying an expandable clay, a modifier component, pseudo-boehmite and water for 0.1-10 h to obtain a slurry, aging the slurry at 50-85° C. for 0.1-10 h, then drying and forming the slurry to obtain a formed material, water washing and aging the solid, and finally drying and calcining the solid, and said modifier being one or more selected from the group consisting of hydroxyl polymers of silicon, aluminum, zirconium or titanium, and substances comprising one or more of said hydroxyl polymers.
    Type: Application
    Filed: December 24, 2002
    Publication date: August 28, 2003
    Applicant: CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Zhiqing Yu, Zhijian Da, Zhenyu Chen, Enze Min, Jun Long, Caiying Li, Zhiqing Huang
  • Publication number: 20030150775
    Abstract: The invention relates to a process for converting cycle oils produced in catalytic cracking reactions into olefin and naphtha. More particularly, the invention relates to a process for hydroprocessing a catalytically cracked light cycle oil, and then re-cracking it in an upstream zone of the primary FCC riser reactor.
    Type: Application
    Filed: October 2, 2002
    Publication date: August 14, 2003
    Inventors: Gordon F. Stuntz, George A. Swan, William E. Winter, Michel Daage, Michele S. Touvelle, Darryl P. Klein
  • Publication number: 20030146132
    Abstract: Fluidized catalytic cracking reactor vessel comprising at its upper end means to separate catalyst particles from an effluent of a dilute phase fluidized catalytic cracking reactor riser, which separation means are fluidly connected to the downstream part of the reactor riser, fluidly connected with means to discharge the cleaned reactor riser effluent from the vessel and fluidly connected to means to discharge the separated catalyst to the lower end of the vessel, the vessel further comprising at its lower end means to discharge catalyst from the reactor vessel, wherein (a) between the side wall of the vessel and the separation means a shield is present, resulting in an exterior space between the vessel wall and the shield and an interior space within the shield, wherein the interior space is in open communication with the lower end of the reactor vessel at its lower end and wherein the exterior space and interior space are fluidly connected by means of one or more openings, and (b) means are present to supp
    Type: Application
    Filed: January 14, 2003
    Publication date: August 7, 2003
    Inventors: Ernst Antonius Bakker, David John Bridger, Hendricus Arien Dirkse, Stephen Brian Fowler
  • Publication number: 20030132137
    Abstract: The invention relates to a process for converting cycle oils produced in catalytic cracking reactions into light olefin and naphtha. More particularly, the invention relates to a process for hydroprocessing a catalytically cracked light cycle oil in order to form a hydroprocessed cycle oil containing a significant amount of tetralins. The hydroprocessed cycle oil is then re-cracked in an upstream zone of the primary FCC riser reactor.
    Type: Application
    Filed: October 2, 2002
    Publication date: July 17, 2003
    Inventors: Gordon F. Stuntz, George A. Swan, William E. Winter, Michel Daage, Michele S. Touvelle, Darryl P. Klein
  • Publication number: 20030127358
    Abstract: The present invention provides a catalytic cracking reactor system and process in which a riser reactor is configured to have two sections of different radii in order to produced improved selectivity to propene and butenes as products.
    Type: Application
    Filed: January 10, 2002
    Publication date: July 10, 2003
    Inventor: Warren S. Letzsch
  • Publication number: 20030121824
    Abstract: The present invention relates to a sulfur transfer additive for catalytic cracking of hydrocarbons and a catalytic cracking process of hydrocarbons using the sulfur transfer additive, said additive is a uniform liquid comprising at least two metal elements selected from the following three classes: a). alkaline earth metals, b). transition metals and P zone metals, and c). rare earth metals, and wherein there are at least two metal elements from the different classes. The present sulfur transfer additive can reduce the SOx content in the regenerator flue gas and the sulfur content in the light oil products at the same time, and has no negative effect on the activity and selectivity of the catalyst in the FCC system.
    Type: Application
    Filed: November 12, 2002
    Publication date: July 3, 2003
    Inventors: Longyan Wang, Haiqing Guo, Wenyi Qi, Shuqin Su, Xianliang Deng, Jinlong Liu, Shufang Liu
  • Publication number: 20030121825
    Abstract: An FCC process for obtaining light olefins comprises contacting a hydrocarbon feed stream with blended catalyst comprising regenerated catalyst and coked catalyst. The catalyst has a composition including a first component and a second component. The second component comprises a zeolite with no greater than medium pore size wherein the zeolite comprises at least 1 wt-% of the catalyst composition. The contacting occurs in a riser to crack hydrocarbons in the feed stream and obtain a cracked stream containing hydrocarbon products including light olefins and coked catalyst. The cracked stream is passed out of an end of the riser such that the hydrocarbon feed stream is in contact with the blended catalyst in the riser for less than or equal to 2 seconds on average. The hydrocarbon products including light olefins are separated from the coked catalyst. The first portion of the coked catalyst is passed to a regeneration zone in which coke is combusted from the catalyst to produce a regenerated catalyst.
    Type: Application
    Filed: December 10, 2002
    Publication date: July 3, 2003
    Inventors: Rusty M. Pittman, Lawrence L. Upson
  • Publication number: 20030121828
    Abstract: An improved process for deasphalting a residua feedstock by use of a short vapor residence time process unit comprised of a horizontal moving bed of fluidized and/or stirred hot particles. The vapor phase product stream from said process unit is passed to a soaker drum where a high boiling fraction is separated and recycled to the process unit after undergoing reactions causing molecular weight growth. This reactive recycle using the soaker drum results in substantially improved qualities of the liquid products compared with what is achieved by once-through residua deasphalting process alternatives.
    Type: Application
    Filed: October 29, 2002
    Publication date: July 3, 2003
    Inventors: Mitchell Jacobson, Willibald Serrand, Norman H. Sweed, Hans J.M. Weiss, Ingo W. Dreher, Udo Zentner, Jorg H. Schmalfeld
  • Patent number: 6585884
    Abstract: The present invention provides a method of producing a synthesis gas from a regeneration of spent cracking catalyst. The method includes introducing a spent cracking catalyst into a first regeneration zone in a presence of a first oxygen and carbon dioxide atmosphere and at a first regeneration temperature. For example, a temperature that does not exceed about 1400° F., and more preferable a temperature that ranges from about 1150° F. to about 1400° F., may be used as the first regeneration temperature. The method further includes introducing the spent cracking catalyst from the first regeneration zone into a second regeneration zone in a presence of a second oxygen and carbon dioxide atmosphere, and producing a synthesis gas from cracking deposits located on the spent cracking catalyst within the second regeneration zone at a second regeneration temperature substantially greater than said first regeneration temperature.
    Type: Grant
    Filed: October 17, 2002
    Date of Patent: July 1, 2003
    Inventor: Warden W. Mayes, Jr.
  • Publication number: 20030116471
    Abstract: The present invention discloses a catalytic cracking process of petroleum hydrocarbons and a tube-in-tube riser reactor used therein. In the present invention, a catalyst is fed via an inlet conduit to an inner tube and an annular space between the inner and outer tubes of the tube-in-tube riser reactor to contact a hydrocarbon feedstock, and the hydrocarbon feedstock is cracked under FCC conditions, then a reaction stream thus produced flows into a separation apparatus via a confluence tube to separate a hydrocarbon product stream from a spent catalyst, the spent catalyst is stripped and regenerated, then a regenerated catalyst is recycled for reuse. The process of the present invention can improve both product distribution and product properties.
    Type: Application
    Filed: August 28, 2002
    Publication date: June 26, 2003
    Applicant: China Petroleum & Chemical Corporation
    Inventors: Ruichi Zhang, Xiaoxiang Zhong, Jiushun Zhang, Kejia Xu, Zhigang Zhang, Shuandi Hou, Xueliang Chang, Zhiguo Wu
  • Publication number: 20030111388
    Abstract: This invention relates to a process for catalytically upgrading light petroleum hydrocarbons accompanied by low temperature regenerating the catalyst, which comprises injecting the light petroleum hydrocarbons into a catalytic cracking reactor, contacting the light petroleum hydrocarbons with a regenerated catalyst and carrying out the reaction, separating the reaction products regenerating the stripped catalyst for 10 to 50 minutes under the regeneration conditions of a temperature of 400 to 600° C. and a pressure of 0.1 to 0.6Mpa; recycling the regenerated catalyst into the reactor. The process of the present invention can reduce the olefin content of gasoline, increase the cetane number of diesel oils, and decrease the contents of sulfur and nitrogen to some extent.
    Type: Application
    Filed: May 29, 2002
    Publication date: June 19, 2003
    Applicant: China Petroleum & Chemical Corporation and Research Institute Of Petroleum Processing
    Inventors: Ruichi Zhang, Jianguo Ma, Zhili Qin, Jiushun Zhang, Zhijian Da
  • Publication number: 20030102251
    Abstract: A cavitation enhanced atomizing process comprises forming a flowing solution of the liquid to be atomized and a lower boiling cavitating liquid. This flowing solution is then contacted with a pressure reducing means, at a temperature below the bubble point of the cavitating liquid in the solution, to produce cavitation bubbles. These bubbles comprise cavitation liquid vapor and the bubble nucleation produces a two-phase fluid of the bubbles and liquid solution. The two-phase fluid is passed downstream into and through an atomizing means, such as an orifice, and into a lower pressure atomizing zone, in which the bubbles vaporize to form a spray of liquid droplets. The nucleated bubbles also grow in size as the so-formed two-phase fluid passes downstream to and through the atomizing means.
    Type: Application
    Filed: October 17, 2002
    Publication date: June 5, 2003
    Inventors: Dean C. Draemel, Nicholas C. Nahas, Teh C. Ho
  • Patent number: 6572761
    Abstract: A process of oxidizing an ash and sulfur containing fuel such as coal in order to power gas turbines using a material such as the oxides of iron which in an oxidized state can be readily reduced and which in a reduced state is readily oxidized. Preferably, the oxides of iron are circulated between two fluid bed reactors and reduced by the ash and sulfur containing fuel in the first said fluid bed reactor and oxidized by air in the second said fluid bed reactor, with ash and SO2 in the gases leaving chiefly from the first said fluid bed reactor. The temperature is controlled within the second said fluid bed reactor by use of a clean fuel and the rate of addition of the ash and sulfur containing fuel to the second fluid bed is controlled so as to limit the amount of SO2 in the gases leaving the second said fluid bed.
    Type: Grant
    Filed: July 31, 2001
    Date of Patent: June 3, 2003
    Assignee: General Electric Company
    Inventor: Richard K. Lyon
  • Patent number: 6562231
    Abstract: A composition comprises silicon, aluminum, zirconium, and boron. A process for producing the composition comprises contacting a silicon compound, an aluminum compound, a zirconium compound, and a boron compound under a condition sufficient to effect the production of a composition comprising silicon, aluminum, zirconium, and boron. Also disclosed is a process for catalytically cracking a hydrocarbon-containing fluid which comprises contacting said hydrocarbon-containing fluid with a catalyst composition which comprises silicon, aluminum, zirconium, and boron.
    Type: Grant
    Filed: April 5, 2002
    Date of Patent: May 13, 2003
    Assignee: ConocoPhillips Company
    Inventors: Lyle R. Kallenbach, Dwayne R. Senn
  • Patent number: 6558530
    Abstract: A process for the catalytic cracking in a fluidized bed where the feed stock is fully and previously vaporized before made to contact the cracking catalyst which has its origin in the regenerator. The pre-vaporization of the feed dispenses with the heat exchange with the catalyst in order to vaporize the feed. Thus, coke deposits on the catalyst surface are reduced, the yield of the gasoline unit is improved and the unit may operate under very low contact times (<0.5 seconds). Modes for adjusting the heat balance of the unit as a function of the increase in the feed temperature without harm to the catalyst circulation are also presented.
    Type: Grant
    Filed: September 2, 1999
    Date of Patent: May 6, 2003
    Assignee: Petroleo Brasileiro S.A.-Petrobas
    Inventors: Claudio Romeo Schlosser, Andrea De Rezende Pinho, Carlos Guerra Pereira
  • Patent number: 6558531
    Abstract: The invention relates to a process for maintaining heat balance in a fluidized bed catalytic cracking unit. More specifically, the invention relates to a combustion control method capable of maintaining or restoring heat balance by conducting, under appropriate conditions, fuel and an oxygen-containing gas to a transfer line. The transfer line conducts effluent including spent catalyst and combustion products to the unit's catalyst regeneration zone.
    Type: Grant
    Filed: March 13, 2001
    Date of Patent: May 6, 2003
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Todd R. Steffens, Paul K. Ladwig, George Melfi, John E. Asplin
  • Patent number: 6555090
    Abstract: The invention deals with a microporous crystalline material, with a characteristic X-ray diffractogram, comprised of oxygen tetrahedra and a metal (T+4 and T+3) with the possibility of introducing surface acidity produced by the substitution in the lattice of some T+4 cations by T+3 cations, which gives rise to a structural charge deficiency that may be compensated by protons, Brönsted acidity, and/or high ratio radium charge cations, Lewis acidity; and the obtaining method thereof, based on the preparation of a gel, its hydrothermal treatment under controlled conditions and the treatment of the resulting laminar material with a solution of an organic compound, a swollen material being obtained, which is subjected to a treatment for the formation of interlaminar pillars of polymeric oxides, obtaining a pillared material that maintains the separation between the sheets, even after calcination.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: April 29, 2003
    Assignees: Consejo Superior de Investigaciones Cientificas, Universidad Politecnica de Valencia
    Inventors: Antonio Chica Lara, Avelino Corma Canós, Vicente Fornés Segúi, Urbano Díaz Morales
  • Publication number: 20030075480
    Abstract: A fluidized particulate solids contacting process for reducing regenerator flue gas NOx emissions and/or permitting operating with an increased equilibrium solids vanadium level, which process may be an FCC process or a fluidized particulate solid hydrocarbon treating process, wherein spent FCC catalyst or other spent solid is in a regenerator with an oxygen-containing regeneration gas under catalyst (solid) regeneration conditions which include a combination of at least a regeneration temperature and an oxygen level in the regeneration gas which is effective to burn off the spent solid a majority of carbonaceous deposits thereon, while substantially preventing the formation of NOx, and thereby produce a regenerated solid having a carbon level reduced from that of the spent solid and a flue gas; maintaining the regenerated solid in a fluidized state with a fluidizing media that substantially prevents any further oxidation or regeneration; and returning the fluidized regenerated solid to the reactor (contactor
    Type: Application
    Filed: September 23, 2002
    Publication date: April 24, 2003
    Applicant: BARCO Processes Joint Venture
    Inventor: David B. Bartholic
  • Patent number: 6540904
    Abstract: The present invention provides a process for the upgradation of petroleum residue into useful fractions by subjecting petroleum residue in the presence of a solvent and ferrous sulphate catalyst to a pressure in the range of 10 atm. to 120 atm., temperature in the range of 380-420° C., for a period in the range of 0-120 minutes, in a reactor vessel, in an inert atmosphere. The charge is then cooled to room temperature and the product gas released through scrubbers. The residue is re-heated, if required, for free flow of liquid product. The resulting liquid product is distilled to obtain useful fractions.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: April 1, 2003
    Inventors: Suhas Ranjan Gun, Priya Bandhu Chowdhury, Kashi Nath Bhattacharya, Achinta Kumar Roy, Umanand Sharma, Swapan Kumar Ghosh, Awadhesh Kumar Sinha, Santosh Kumar Chanda, Sukumar Mandal, Sanjay Kumar Ray, Asit Kumar Das, Satish Makhija, Sobhan Ghosh, Akhilesh Kumar Bhatnagar
  • Publication number: 20030050523
    Abstract: A catalyst and process is disclosed to selectively upgrade a paraffinic feedstock to obtain an isoparaffin-rich product for blending into gasoline. The catalyst comprises a support of a sulfated oxide or hydroxide of a Group IVB (IUPAC 4) metal, a first component of at least one lanthanide element or yttrium component, which is preferably ytterbium, and at least one platinum-group metal component which is preferably platinum.
    Type: Application
    Filed: August 29, 2001
    Publication date: March 13, 2003
    Inventors: Ralph D. Gillespie, Michelle J. Cohn
  • Publication number: 20030044327
    Abstract: This invention is to a circulating fluid bed reactor that is designed so as to have the ability to adjust catalyst holdup within the reaction zone of the reactor while maintaining substantially constant catalyst circulation rate through the reaction zone. The ability to adjust catalyst hold up independently of catalyst circulation rate provides an advantage of having the ability to maintain a constant conversion level as catalyst activity or feed rates change.
    Type: Application
    Filed: August 31, 2001
    Publication date: March 6, 2003
    Inventors: James R. Lattner, Jeffrey S. Smith, Rathna P. Davuluri
  • Publication number: 20030029774
    Abstract: An apparatus and process is disclosed for the separation of solids from gases in a mixture which is most particularly applicable to an FCC apparatus. The mixture of solids and gases are passed through a conduit and exit through a swirl arm that imparts a swirl motion having a first annular direction to centripetally separate the heavier solids from the lighter gases. The mixture then enters a cyclone which has a curved outer wall and imparts a second swirling angular direction to the mixture. The second angular direction is counter to the first angular direction. The apparatus and method assures that a greater proportion of the mixture entering the cyclone is incorporated into the vortex to further enhance separation between the solids and gases.
    Type: Application
    Filed: August 9, 2001
    Publication date: February 13, 2003
    Inventors: Steven Niewiedzial, Daniel N. Myers