Silicon Nitride Formation Patents (Class 438/791)
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Patent number: 7651956Abstract: A process for forming a thin layer exhibiting a substantially uniform property on an active surface of a semiconductor substrate. The process includes varying the temperature within a reaction chamber while a layer of a material is formed upon the semiconductor substrate. Varying the temperature within the reaction chamber facilitates temperature uniformity across the semiconductor wafer. As a result, a layer forming reaction occurs at a substantially consistent rate over the entire active surface of the semiconductor substrate. The process may also include oscillating the temperature within the reaction chamber while a layer of a material is being formed upon a semiconductor substrate.Type: GrantFiled: December 6, 2000Date of Patent: January 26, 2010Assignee: Micron Technology, Inc.Inventors: Garry Anthony Mercaldi, Don Carl Powell
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Publication number: 20100013062Abstract: A nonvolatile memory cell is provided. A semiconductor substrate is provided. A conducting layer and a spacer layer are sequentially disposed above the semiconductor substrate. At least a trench having a bottom and plural side surfaces is defined in the conducting layer and the spacer layer. A first oxide layer is formed at the bottom of the trench. A dielectric layer is formed on the first oxide layer, the spacer layer and the plural side surfaces of the trench. A first polysilicon layer is formed in the trench. And a first portion of the dielectric layer on the spacer layer is removed, so that a basic structure for the nonvolatile memory cell is formed.Type: ApplicationFiled: October 2, 2008Publication date: January 21, 2010Applicant: NANYA TECHNOLOGY CORP.Inventors: Shin-Bin Huang, Ching-Nan Hsiao, Chung-Lin Huang
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Patent number: 7648927Abstract: Embodiments of the invention generally provide a method for depositing films or layers using a UV source during a photoexcitation process. The films are deposited on a substrate and usually contain a material, such as silicon (e.g., epitaxy, crystalline, microcrystalline, polysilicon, or amorphous), silicon oxide, silicon nitride, silicon oxynitride, or other silicon-containing materials. The photoexcitation process may expose the substrate and/or gases to an energy beam or flux prior to, during, or subsequent a deposition process. Therefore, the photoexcitation process may be used to pre-treat or post-treat the substrate or material, to deposit the silicon-containing material, and to enhance chamber cleaning processes.Type: GrantFiled: June 20, 2006Date of Patent: January 19, 2010Assignee: Applied Materials, Inc.Inventors: Kaushal K. Singh, Joseph M. Ranish
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Patent number: 7645712Abstract: A substrate having at least two metal oxide semiconductor devices of a same conductive type and a gap formed between the two devices is provided. A first stress layer is formed over the substrate to cover the metal-oxide semiconductor devices and the substrate, filling the gap. An etching back process is then performed to remove a portion of the stress material layer inside the gap. A second stress layer and a dielectric layer are sequentially formed on the first stress layer. The first stress layer and the second stress layer provide a same type of stress. A portion of the second stress layer is removed to form a contact opening. A second conductive layer is filled into the contact opening to form a contact.Type: GrantFiled: December 30, 2008Date of Patent: January 12, 2010Assignee: United Microelectronics Corp.Inventors: Neng-Kuo Chen, Teng-Chun Tsai, Chien-Chung Huang
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Patent number: 7638413Abstract: A method of fabricating a semiconductor uses chemical vapor deposition, or plasma-enhanced chemical vapor deposition, to deposit an amorphous silicon film on an exposed surface of a substrate, such as ASIC wafer. The amorphous silicon film is doped with nitrogen to reduce the conductivity of the film and/or to augment the breakdown voltage of the film. Nitrogen gas, N2, is activated or ionized in a reactor before it is deposited on the substrate.Type: GrantFiled: April 4, 2005Date of Patent: December 29, 2009Assignee: Pan Jit Americas, Inc.Inventors: Michael Kountz, George Engle, Steven Evers
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Patent number: 7638443Abstract: A method of forming an ultra-thin SiN film includes: supplying a Si source gas into a reactor in which a substrate is placed on a susceptor; supplying an N source gas into the reactor at a flow rate which is at least 300 times that of the Si source gas; applying an RF power between an upper electrode and the susceptor in the reactor; and depositing an ultra-thin SiN film on the substrate.Type: GrantFiled: November 14, 2007Date of Patent: December 29, 2009Assignee: ASM Japan K.K.Inventors: Rei Tanaka, Taku Hitomi
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Patent number: 7635651Abstract: A method of smoothening a dielectric layer. First, a substrate is provided. Next, a dielectric layer is formed on the semiconductor substrate. Finally, the dielectric layer is smoothened by a plasma treatment employing a silane based gas and a nitrogen based gas.Type: GrantFiled: August 23, 2005Date of Patent: December 22, 2009Assignee: Taiwan Semiconductor Manufacturing Co., Ltd.Inventors: Wen-Long Lee, Jun Wu, Shih-Chi Lin, Chyi-Tsong Ni
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Publication number: 20090305517Abstract: A method of manufacturing a semiconductor device has: carrying a substrate into a process chamber; depositing a thin film on the substrate by supplying inside the process chamber a first film deposition gas including at least one element among plural elements forming a thin film to be deposited and capable of accumulating a film solely and a second film deposition gas including at least another element among the plural elements and incapable of accumulating a film solely; carrying the substrate on which is deposited the thin film out from inside the process chamber; and removing a first sediment adhering to an interior of the process chamber and a second sediment adhering to an interior of the supply portion and having a chemical composition different from a chemical composition of the first sediment by supplying cleaning gases inside the process chamber and inside a supply portion that supplies the first film deposition gas while changing at least one of a supply flow rate, a concentration, and a type betweeType: ApplicationFiled: March 27, 2007Publication date: December 10, 2009Applicant: HITACHI KOKUSAI ELECTRIC INC.Inventors: Sadao Nakashima, Takahiro Maeda, Kiyohiko Maeda, Kenji Kameda, Yushin Takasawa
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Publication number: 20090302391Abstract: A stress liner having first and second stress type is provided over a first type and a second type transistor to improve reliability and performance without incurring area penalties or layout deficiencies.Type: ApplicationFiled: June 5, 2008Publication date: December 10, 2009Applicant: CHARTERED SEMICONDUCTOR MANUFACTURING, LTD.Inventors: Jae Gon LEE, Jingze TIAN, Shyue Seng TAN, Luona GOH, Wei LU, Elgin QUEK
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Patent number: 7626244Abstract: A structure and a method of making the structure. The structure includes a field effect transistor including: a first and a second source/drain formed in a silicon substrate, the first and second source/drains spaced apart and separated by a channel region in the substrate; a gate dielectric on a top surface of the substrate over the channel region; and an electrically conductive gate on a top surface of the gate dielectric; and a dielectric pillar of a first dielectric material over the gate; and a dielectric layer of a second dielectric material over the first and second source/drains, sidewalls of the dielectric pillar in direct physical contact with the dielectric layer, the dielectric pillar having no internal stress or an internal stress different from an internal stress of the dielectric layer.Type: GrantFiled: February 28, 2007Date of Patent: December 1, 2009Assignee: International Business Machines CorporationInventors: Brent Alan Anderson, Edward Joseph Nowak
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Publication number: 20090289306Abstract: Disclosed are methods of making and using a high-K dielectric liner to facilitate the lateral oxidation of a high-K gate dielectric, integrated circuit structures containing the high-K dielectric liner and/or oxidized high-K gate dielectric, and other associated methods.Type: ApplicationFiled: May 21, 2008Publication date: November 26, 2009Applicant: KABUSHIKI KAISHA TOSHIBAInventors: Takeshi Watanabe, Ryosuke Iijima
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Publication number: 20090280654Abstract: A process for forming a silicon nitride layer on a gate oxide film as part of formation of a gate structure in a semiconductor device includes: forming a layer of silicon nitride on top of a gate oxide film on a semiconductor substrate by a nitridation process, heating the semiconductor substrate in an annealing chamber, exposing the semiconductor substrate to N2 in the annealing chamber, and exposing the semiconductor substrate to a mixture of N2 and N2O in the annealing chamber.Type: ApplicationFiled: May 9, 2008Publication date: November 12, 2009Inventors: Cheng-Ta Wu, Da-Yu Chuang, Yen-Da Chen, Lihan Lin
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Patent number: 7615432Abstract: A stress nitride structure is formed on an integrated circuit field effect transistor by high density plasma (HDP) depositing a first stress nitride layer on the integrated circuit field effect transistor and then plasma enhanced chemical vapor depositing (PECVD) a second stress nitride layer on the first stress nitride layer. The first stress nitride layer is non-conformal and the second stress nitride layer is conformal. Related structures also are described.Type: GrantFiled: November 2, 2005Date of Patent: November 10, 2009Assignees: Samsung Electronics Co., Ltd., International Business Machines CorporationInventors: Junjung Kim, Jae-eun Park, Ja-hum Ku, Daewon Yang
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Patent number: 7615454Abstract: The present invention provides a semiconducting device including a gate region positioned on a mesa portion of a substrate; and a nitride liner positioned on the gate region and recessed surfaces of the substrate adjacent to the gate region, the nitride liner providing a stress to a device channel underlying the gate region. The stress produced on the device channel is a longitudinal stress on the order of about 275 MPa to about 450 Mpa.Type: GrantFiled: October 22, 2007Date of Patent: November 10, 2009Assignee: International Business Machines CorporationInventors: Dureseti Chidambarrao, Omer H. Dokumaci
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Patent number: 7615421Abstract: The present invention relates to a method for fabricating thin film transistor, more particularly, to a method for fabricating thin film transistor which not only manufactures a polycrystalline silicon layer having large grain size and containing a trace of residual metal catalyst by heat treating thereby crystallizing the metal catalyst layer after forming an amorphous silicon layer on a substrate, forming a capping layer formed of nitride film having 1.78 to 1.90 of the refraction index when crystallizing the amorphous silicon layer and forming a metal catalyst layer on the capping layer, but also controls characteristics of the polycrystalline silicon layer by controlling the refraction index of the capping layer.Type: GrantFiled: December 15, 2004Date of Patent: November 10, 2009Assignee: Samsung Mobile Display Co., Ltd.Inventors: Sang-Woong Lee, Jae-Young Oh, Tae-Hoon Yang, Jin-Wook Seo, Ki-Yong Lee, Cheol-Ho Yu
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Patent number: 7601652Abstract: Embodiments of the invention generally provide a method for depositing films using photoexcitation. The photoexcitation may be utilized for at least one of treating the substrate prior to deposition, treating substrate and/or gases during deposition, treating a deposited film, or for enhancing chamber cleaning. In one embodiment, a method for depositing silicon and nitrogen-containing film on a substrate includes heating a substrate disposed in a processing chamber, generating a beam of energy of between about 1 to about 10 eV, transferring the energy to a surface of the substrate; flowing a nitrogen-containing chemical into the processing chamber, flowing a silicon-containing chemical with silicon-nitrogen bonds into the processing chamber, and depositing a silicon and nitrogen-containing film on the substrate.Type: GrantFiled: June 21, 2005Date of Patent: October 13, 2009Assignee: Applied Materials, Inc.Inventors: Kaushal K. Singh, Sean M. Seutter, Jacob Smith, R. Suryanarayanan Iyer, Steve G. Ghanayem, Adam Brailove, Robert Shydo, Jeannot Morin
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Patent number: 7592268Abstract: A method for fabricating a semiconductor device is provided. The method includes: forming a plurality of gate lines on a substrate by performing an etching process; forming an oxide layer on the gate lines and the substrate by employing an atomic layer deposition (ALD) method; and sequentially forming a buffer oxide layer and a nitride layer on the oxide layer.Type: GrantFiled: December 6, 2005Date of Patent: September 22, 2009Assignee: Hynix Semiconductor Inc.Inventors: Ki-Won Nam, Kyung-Won Lee
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Publication number: 20090233454Abstract: A method for using a film formation apparatus includes, in order to inhibit metal contamination: performing a cleaning process using a cleaning gas on an inner wall of a process container and a surface of a holder with no productive target objects held thereon; and then, performing a coating process of forming a silicon nitride film by alternately supplying a silicon source gas and a nitriding gas to cover with the silicon nitride film the inner wall of the process container and the surface of the holder with no productive target objects held thereon.Type: ApplicationFiled: March 10, 2009Publication date: September 17, 2009Applicant: TOKYO ELECTRON LIMITEDInventors: Mitsuhiro OKADA, Yamato Tonegawa
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Patent number: 7585752Abstract: Chemical vapor deposition processes utilize chemical precursors that allow for the deposition of thin films to be conducted at or near the mass transport limited regime. The processes have high deposition rates yet produce more uniform films, both compositionally and in thickness, than films prepared using conventional chemical precursors. In preferred embodiments, a higher order silane is employed to deposit thin films containing silicon that are useful in the semiconductor industry in various applications such as transistor gate electrodes.Type: GrantFiled: October 12, 2004Date of Patent: September 8, 2009Assignee: ASM America, Inc.Inventors: Michael A. Todd, Mark Hawkins
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Patent number: 7585790Abstract: A method of forming a semiconductor device. The method comprises steps of providing a substrate having a first transistor, a second transistor and non-salicide device formed thereon and the conductive type of the first transistor is different from that of the second transistor. A buffer layer is formed over the substrate and a tensile material layer is formed over the buffer layer. A portion of the tensile material layer over the second transistor is thinned and a spike annealing process is performed. The tensile material layer is removed to expose the buffer layer over the substrate and a patterned salicide blocking layer is formed over the non-salicide device. A salicide process is performed for forming a salicide layer on a portion of the first transistor and the second transistor.Type: GrantFiled: July 20, 2006Date of Patent: September 8, 2009Assignee: United Microelectronics Corp.Inventors: Wen-Han Hung, Cheng-Tung Huang, Kun-Hsien Lee, Shyh-Fann Ting, Li-Shian Jeng, Tzyy-Ming Cheng, Chia-Wen Liang, Neng-Kuo Chen
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Patent number: 7582540Abstract: This method for manufacturing an SOI wafer includes: a step of forming insulating films in a front surface and a mirror-polished rear surface of an active layer wafer; a step of removing the insulating film in the front surface of the active layer wafer; a step of subjecting the active layer wafer to a rapid thermal annealing process; a step of bonding the active layer wafer and a support wafer with the insulating film formed in the rear surface therebetween so as to form a bonded wafer; a step of subjecting the bonded wafer to a heat treatment for bonding enhancement which enhances a bonding strength between the active layer wafer and the support wafer; and a step of thinning the active layer wafer in the bonded wafer so as to form an SOI layer.Type: GrantFiled: November 30, 2005Date of Patent: September 1, 2009Assignee: Sumco CorporationInventors: Takaaki Shiota, Yasuhiro Oura
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Publication number: 20090209111Abstract: A method for fabricating a semiconductor device, according to the present invention includes the steps of: preparing an SOI substrate, which comprises a semiconductor supporting layer, an oxide layer formed on the semiconductor supporting layer and an SOI layer formed on the oxide layer; forming a semiconductor device on the SOI layer; forming a passivation layer over the SOI substrate, the passivation layer allowing a UV light to pass through it; and applying a UV light to the SOI substrate after the step of forming the semiconductor device is completed.Type: ApplicationFiled: February 13, 2009Publication date: August 20, 2009Applicant: OKI SEMICONDUCTOR CO., LTD.Inventors: Wataru Shimizu, Ikuo Kurachi
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Publication number: 20090203227Abstract: A silicon-containing insulating film is formed on a target substrate by CVD, in a process field to be selectively supplied with a first process gas including di-iso-propylaminosilane gas and a second process gas including an oxidizing gas or nitriding gas. The film is formed by performing a plurality of times a cycle alternately including first and second steps. The first step performs supply of the first process gas, thereby forming an adsorption layer containing silicon on a surface of the target substrate. The second performs supply of the second process gas, thereby oxidizing or nitriding the adsorption layer on the surface of the target substrate. The second step includes an excitation period of supplying the second process gas to the process field while exciting the second process gas by an exciting mechanism.Type: ApplicationFiled: January 28, 2009Publication date: August 13, 2009Applicant: TOKYO ELECTRON LIMITEDInventors: Kazuhide Hasebe, Shigeru Nakajima, Jun Ogawa
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Patent number: 7566668Abstract: A method of forming a contact is provided. A substrate having at least two metal oxide semiconductor devices is provided and a gap is formed between the two devices. A first stress layer is formed over the substrate to cover the metal-oxide semiconductor devices and the substrate. The first stress layer is formed by first forming a first stress material layer over the substrate to cover the metal-oxide semiconductor devices and to fill the gap, the stress material inside the gap. An etching back process is then performed to remove a portion of the stress material layer inside the gap. A second stress layer and a dielectric layer are sequentially formed on the first stress layer. A portion of the second stress layer is removed to form a contact opening. A first conductive layer is filled into the contact opening to form a contact.Type: GrantFiled: December 24, 2007Date of Patent: July 28, 2009Assignee: United Microelectronics Corp.Inventors: Neng-Kuo Chen, Teng-Chun Tsai, Chien-Chung Huang
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Publication number: 20090181550Abstract: A film formation process is performed to form a silicon nitride film on a target substrate within a process field configured to be selectively supplied with a first process gas containing a silane family gas and a second process gas containing a nitriding gas. The method is preset to compose the film formation process of a main stage with an auxiliary stage set at one or both of beginning and ending of the film formation process. The main stage includes an excitation period of supplying the second process gas to the process field while exciting the second process gas by an exciting mechanism. The auxiliary stage includes no excitation period of supplying the second process gas to the process field while exciting the second process gas by the exciting mechanism.Type: ApplicationFiled: January 6, 2009Publication date: July 16, 2009Inventors: Kazuhide Hasebe, Nobutake Nodera, Eun-jo Lee
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Publication number: 20090170341Abstract: A process for forming dielectric films containing at least metal atoms, silicon atoms, and oxygen atoms on a silicon substrate comprises a first step of oxidizing a surface portion of the silicon substrate to form a silicon dioxide film; a second step of forming a metal film on the silicon dioxide film in a non-oxidizing atmosphere; a third step of heating in a non-oxidizing atmosphere to diffuse the metal atoms constituting the metal film into the silicon dioxide film; and a fourth step of oxidizing the silicon dioxide film containing the diffused metal atoms to form the film containing the metal atoms, silicon atoms, and oxygen atoms.Type: ApplicationFiled: December 23, 2008Publication date: July 2, 2009Applicant: CANON KABUSHIKI KAISHAInventors: Naomu Kitano, Yusuke Fukuchi, Nobumasa Suzuki, Hideo Kitagawa
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Publication number: 20090170344Abstract: A method for forming dielectric films including metal nitride silicate on a silicon substrate, comprises a first step of depositing a film containing metal and silicon on a silicon substrate in a non-oxidizing atmosphere using a sputtering method; a second step of forming a film containing nitrogen, metal and silicon by nitriding the film containing metal and silicon; and a third step of forming a metal nitride silicate film by oxidizing the film containing nitrogen, metal and silicon.Type: ApplicationFiled: December 18, 2008Publication date: July 2, 2009Applicants: CANON KABUSHIKI KAISHA, CANON ANELVA CORPORATIONInventors: Yusuke Fukuchi, Naomu Kitano
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Publication number: 20090163040Abstract: A substrate processing apparatus, including: a reaction container in which a substrate is processed; a seal cap, brought into contact with one end in an opening side of the reaction container via a first sealing member and a second sealing member so as to seal the opening of the reaction container air-tightly; a first gas channel, formed in a region between the first sealing member and the second sealing member in a state where the seal cap is in contact with the reaction container; a second gas channel, provided to the seal cap and through which the first gas channel is in communication with an inside of the reaction container; a first gas supply port that is provided to the reaction container and supplies a first gas to the first gas channel; and a second gas supply port that is provided to the reaction container and supplies a second gas into the reaction container, wherein a front end opening of the first gas supply port opening to the first gas channel, and a base opening of the second gas channel openinType: ApplicationFiled: August 9, 2007Publication date: June 25, 2009Applicant: Hitachi Kokusai Electric Inc.Inventors: Kiyohiko Maeda, Takeo Hanashima, Masanao Osanai
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Patent number: 7550398Abstract: A semiconductor device includes a silicon nitride (SiN) film provided on a crystal surface of a nitride semiconductor, the SiN film having a hydrogen content equal to or smaller than 15 percent.Type: GrantFiled: March 30, 2005Date of Patent: June 23, 2009Assignee: Eudyna Devices, Inc.Inventors: Masahiro Tanaka, Tsutomu Komatani
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Patent number: 7550356Abstract: A method of fabricating strained-silicon transistors includes providing a semiconductor substrate, in which the semiconductor substrate includes a gate, at least a spacer, and a source/drain region; performing a first rapid thermal annealing (RTA) process; removing the spacer and forming a high tensile stress film over the surface of the gate and the source/drain region; and performing a second rapid thermal annealing process.Type: GrantFiled: November 14, 2005Date of Patent: June 23, 2009Assignee: United Microelectronics Corp.Inventors: Cheng-Tung Huang, Chia-Wen Liang, Tzyy-Ming Cheng, Tzer-Min Shen, Yi-Chung Sheng
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Patent number: 7547646Abstract: A stress relief layer between a single-crystal semiconductor substrate and a deposited silicon nitride layer or pad nitride is formed from thermally produced silicon nitride. The stress relief layer made from thermally produced silicon nitride replaces a silicon dioxide layer or pad oxide which is customary at this location for example in connection with mask layers. After patterning of a mask, which includes a protective layer portion formed from deposited silicon nitride, the material which is provided according to the invention for the stress relief layer reduces the restrictions imposed for subsequent process steps, such as for example wet-etching steps, acting both on the semiconductor substrate or structures in the semiconductor substrate and also on the stress relief layer.Type: GrantFiled: October 28, 2004Date of Patent: June 16, 2009Assignee: Infineon Technologies AGInventors: Henry Bernhardt, Michael Stadtmüller, Olaf Storbeck, Stefan Kainz
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Publication number: 20090149032Abstract: The present invention suppresses metallic contamination in a processing chamber and a breakage of a quartz member, while suppressing decrease in film formation rate in a thin film formation process immediately after dry cleaning of the inside of the processing chamber, and enhances the operation rate of a apparatus. The method according to the invention includes the steps of: removing the thin film on the inside of the processing chamber by supplying a fluorine gas solely or a fluorine gas diluted by an inert gas solely, as the cleaning gas, to the inside of the processing chamber heated to a first temperature; and removing an adhered material remaining on the inside of the processing chamber after removing the thin film by supplying a fluorine gas solely or a fluorine gas diluted by an inert gas solely, as the cleaning gas, to the inside of the processing chamber heated to a second temperature.Type: ApplicationFiled: December 2, 2008Publication date: June 11, 2009Applicant: HITACHI KOKUSAI ELECTRIC INC.Inventors: Kenji Kameda, Jie Wang, Yuji Urano
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Publication number: 20090124087Abstract: A vertical plasma processing apparatus for a semiconductor process for performing a plasma process on target substrates all together includes an exciting mechanism configured to turn at least part of a process gas into plasma. The exciting mechanism includes first and second electrodes provided to a plasma generation box and facing each other with a plasma generation area interposed therebetween, and an RF power supply configured to supply an RF power for plasma generation to the first and second electrodes and including first and second output terminals serving as grounded and non-grounded terminals, respectively. A switching mechanism is configured to switch between a first state where the first and second electrodes are connected to the first and second output terminals, respectively, and a second state where the first and second electrodes are connected to the second and first output terminals, respectively.Type: ApplicationFiled: October 15, 2008Publication date: May 14, 2009Inventors: Nobutake Nodera, Jun Sato, Masanobu Matsunaga, Kazuhide Hasebe, Hisashi Inoue
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Publication number: 20090117715Abstract: A semiconductor device in which selectivity in epitaxial growth is improved. There is provided a semiconductor device comprising a gate electrode formed over an Si substrate, which is a semiconductor substrate, with a gate insulating film therebetween and an insulating layer formed over sides of the gate electrode and containing a halogen element. With this semiconductor device, a silicon nitride film which contains the halogen element is formed over the sides of the gate electrode when an SiGe layer is formed over the Si substrate. Therefore, the SiGe layer epitaxial-grows over the Si substrate with high selectivity. As a result, an OFF-state leakage current which flows between, for example, the gate electrode and source/drain regions is suppressed and a manufacturing process suitable for actual mass production is established.Type: ApplicationFiled: October 14, 2008Publication date: May 7, 2009Applicant: FUJITSU LIMITEDInventors: Masahiro Fukuda, Yosuke Shimamune, Masaaki Koizuka, Katsuaki Ookoshi
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Patent number: 7528043Abstract: Gate and storage dielectric systems and methods of their fabrication are presented. A passivated overlayer deposited between a layer of dielectric material and a gate or first storage plate maintains a high K (dielectric constant) value of the dielectric material. The high K dielectric material forms an improved interface with a substrate or second plate. This improves dielectric system reliability and uniformity and permits greater scalability, dielectric interface compatibility, structural stability, charge control, and stoichiometric reproducibility. Furthermore, etch selectivity, low leakage current, uniform dielectric breakdown, and improved high temperature chemical passivity also result.Type: GrantFiled: November 22, 2005Date of Patent: May 5, 2009Assignee: Micron Technology, Inc.Inventor: Arup Bhattacharyya
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Publication number: 20090111284Abstract: Embodiments of the invention generally provide a method for depositing silicon-containing films. In one embodiment, a method for depositing silicon-containing material film on a substrate includes heating a substrate disposed in a processing chamber to a temperature less than about 550 degrees Celsius; flowing a nitrogen and carbon containing chemical comprising (H3C)—N?N—H into the processing chamber; flowing a silicon-containing source chemical with silicon-nitrogen bonds into the processing chamber; and depositing a silicon and nitrogen containing film on the substrate.Type: ApplicationFiled: January 5, 2009Publication date: April 30, 2009Inventors: Yaxin Wang, Yuji Maeda, Thomas C. Mele, Sean M. Seutter, Sanjeev Tandon, R. Suryanarayanan Iyer
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Publication number: 20090104731Abstract: A semiconductor device manufacturing method including a process of forming a silicon oxide film by thermally oxidizing silicon in the atmosphere of oxygen gas or in the atmosphere of mixed gas of oxygen and hydrogen at a temperature of 800° C. or more in the state in which at least the silicon surface serving as a light-receiving portion of a photodiode is exposed, and a process of depositing a silicon nitride film on the silicon oxide film. At least the silicon oxide film and the silicon nitride film are finally left on the surface of the photodiode as an antireflection film.Type: ApplicationFiled: November 17, 2008Publication date: April 23, 2009Applicant: Sony CorporationInventor: Tomotaka Fujisawa
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Publication number: 20090104755Abstract: A method of depositing a silicon and nitrogen containing film on a substrate. The method includes introducing silicon-containing precursor to a deposition chamber that contains the substrate, wherein the silicon-containing precursor comprises at least two silicon atoms. The method further includes generating at least one radical nitrogen precursor with a remote plasma system located outside the deposition chamber. Moreover, the method includes introducing the radical nitrogen precursor to the deposition chamber, wherein the radical nitrogen and silicon-containing precursors react and deposit the silicon and nitrogen containing film on the substrate. Furthermore, the method includes annealing the silicon and nitrogen containing film in a steam environment to form a silicon oxide film, wherein the steam environment includes water and acidic vapor.Type: ApplicationFiled: October 22, 2007Publication date: April 23, 2009Applicant: Applied Materials, Inc.Inventors: Abhijit Basu Mallick, Srinivas D. Nemani, Ellie Yieh
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Publication number: 20090104754Abstract: Embodiments of methods for improving electrical leakage performance and minimizing electromigration in semiconductor devices are generally described herein. Other embodiments may be described and claimed.Type: ApplicationFiled: December 18, 2008Publication date: April 23, 2009Applicant: TEL EPION INC.Inventors: Noel Russell, Steven Sherman, John J. Hautala
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Patent number: 7521324Abstract: In order to provide a semiconductor device having good quality by keeping the relative permittivity of a High-K insulation film in a high state, or to provide a method for manufacturing a semiconductor device in which the relative permittivity of the High-K insulation film can be kept in a high state, a semiconductor device is disclosed that includes a silicon substrate, a gate electrode layer, and a gate insulation film between the silicon substrate and the gate electrode layer. The gate insulation film is a high relative permittivity (high-k) film being formed by performing a nitriding treatment on a mixture of a metal and silicon. The High-K film itself becomes a nitride so as to prevent SiO2 from being formed.Type: GrantFiled: March 31, 2004Date of Patent: April 21, 2009Assignees: Tokyo Electron LimitedInventors: Tadahiro Ohmi, Akinobu Teramoto, Hidetoshi Wakamatsu, Yasuo Kobayashi
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Publication number: 20090098741Abstract: Boron-containing nitride films, including silicon boron nitride and boron nitride films, are deposited during, e.g., integrated circuit fabrication. The films are deposited in a process chamber having a reaction space that is defined as an open volume of the chamber directly above the substrate. The boron-containing nitride films are formed by flowing silicon and boron precursors into the process chamber while maintaining the volume, as measured under standard conditions, of silicon and boron precursors, e.g., SiH4 and B2H6, flowed into the process chamber per minute at about 6.2% or less of the volume of the reaction space. In some embodiments, N2 is flowed into the process chamber at a flow rate of about 100 times the total flow rate of the silicon and boron precursors. The deposited films have good film thickness controllability and high in-plane film thickness uniformity for use as, e.g., etch stop layers.Type: ApplicationFiled: October 15, 2007Publication date: April 16, 2009Applicant: ASM Japan K.K.Inventors: Rei Tanaka, Takashige Watanabe, Hideaki Fukuda
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Patent number: 7514370Abstract: Embodiments of the invention provide a method of forming a compressive stress nitride film overlying a plurality of p-type field effect transistor gate structures produced on a substrate through a high-density plasma deposition process. Embodiments include generating an environment filled with high-density plasma using source gases of at least silane, argon and nitrogen; biasing the substrate to a high frequency power of varying density, in a range between 0.8 W/cm2 and 5.0 W/cm2; and depositing the high-density plasma to the plurality of gate structures to form the compressive stress nitride film.Type: GrantFiled: May 19, 2006Date of Patent: April 7, 2009Assignee: International Business Machines CorporationInventors: Daewon Yang, Woo-Hyeong Lee, Tai-chi Su, Yun-Yu Wang
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Patent number: 7514374Abstract: For avoiding the metallic inner surface of a PECVD reactor to influence thickness uniformity and quality uniformity of a ?c-Si layer (19) deposited on a large-surface substrate, (15) before each substrate is single treated at least parts of the addressed wall are precoated with a dielectric layer (13).Type: GrantFiled: June 28, 2006Date of Patent: April 7, 2009Assignee: Oerlikon Trading AG, TrubbachInventors: Hai Tran Quoc, Jérôme Villette
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Patent number: 7510984Abstract: A method of forming a silicon nitride film comprises: forming a silicon nitride film by applying first gas containing silicon and nitrogen and second gas containing nitrogen and hydrogen to catalyst heated in a reduced pressure atmosphere. A method of manufacturing a semiconductor device comprising the steps of: forming a silicon nitride film by the method as claimed in claim 1 on a substrate having the semiconductor layer, a gate insulation film selectively provided on a principal surface of the semiconductor layer, and a gate electrode provided on the gate insulation film; and removing the silicon nitride film on the semiconductor layer and the gate electrode and leaving a sidewall comprising the silicon nitride film on a side surface of the gate insulation film and the gate electrode by etching the silicon nitride film in a direction generally normal to the principal surface of the semiconductor layer.Type: GrantFiled: February 15, 2005Date of Patent: March 31, 2009Assignee: Ulvac, Inc.Inventors: Tsuyoshi Saito, Hiromi Itoh, Makiko Kitazoe
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Publication number: 20090078989Abstract: Provided are a method of forming silicon nitride at a low temperature, a charge trap memory device including crystalline nano dots formed by using the same, and a method of manufacturing the charge trap memory device. The method of forming silicon nitride includes loading a substrate into a chamber of a silicon nitride deposition device comprising a filament; increasing a temperature of the filament to a temperature whereby a reactant gas to be injected into the chamber may be dissociated; and injecting the reactant gas into the chamber so as to form a crystalline silicon nitride film or crystalline silicon nitride nano dots on the substrate. In the method, the temperature of the filament may be maintained at 1,400° C.˜2,000° C., and a pressure in the chamber may be maintained at several to several ten torr when the reactant gas in injected into the chamber.Type: ApplicationFiled: June 18, 2008Publication date: March 26, 2009Inventors: Kwang-soo Seol, Nong-moon Hwang, Chan-soo Kim, Dong-kwon Lee, Woong-kyu Youn, Sang-moo Choi
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Publication number: 20090075490Abstract: A method of forming a silicon-containing film comprising providing a substrate in a reaction chamber, injecting into the reaction chamber at least one silicon-containing compound; injecting into the reaction chamber at least one co-reactant in the gaseous form; and reacting the substrate, silicon-containing compound, and co-reactant in the gaseous form at a temperature equal to or less than 550° C. to obtain a silicon-containing film deposited onto the substrate. A method of preparing a silicon nitride film comprising introducing a silicon wafer to a reaction chamber; introducing a silicon-containing compound to the reaction chamber; purging the reaction chamber with an inert gas; and introducing a nitrogen-containing co-reactant in gaseous form to the reaction chamber under conditions suitable for the formation of a monomolecular layer of a silicon nitride film on the silicon wafer.Type: ApplicationFiled: September 18, 2008Publication date: March 19, 2009Applicant: L'Air Liquite Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges ClaudeInventor: Christian DUSSARRAT
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Patent number: 7501355Abstract: Methods for forming silicon nitride hard masks are provided. The silicon nitride hard masks include carbon-doped silicon nitride layers and undoped silicon nitride layers. Carbon-doped silicon nitride layers that are deposited from a mixture comprising a carbon source compound, a silicon source compound, and a nitrogen source in the presence of RF power are provided. Also provided are methods of UV post-treating silicon nitride layers to provide silicon nitride hard masks. The carbon-doped silicon nitride layers and UV post-treated silicon nitride layers have desirable wet etch rates and dry etch rates for hard mask layers.Type: GrantFiled: June 29, 2006Date of Patent: March 10, 2009Assignee: Applied Materials, Inc.Inventors: Ritwik Bhatia, Li-Qun Xia, Chad Peterson, Hichem M'Saad
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Publication number: 20090061651Abstract: A substrate processing apparatus comprising: a reaction tube that processes a substrate; a support portion that supports the substrate in the reaction tube; a process gas supply line that supplies a process gas into the reaction tube; and an exhaust line that exhausts an inside of the reaction tube, wherein the process gas is supplied into the reaction tube to form a silicon nitride film on the substrate, at least the reaction tube is made of quartz, a plurality of projections are provided on the inner wall of the reaction tube, and the diameter of the projections is larger than 2 ?m but smaller than 86 ?m.Type: ApplicationFiled: September 3, 2008Publication date: March 5, 2009Applicant: HITACHI KOKUSAI ELECTRIC INC.Inventors: Sadao Nakashima, Takahiro Maeda, Jie Wang
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Patent number: 7498232Abstract: Methods of fabricating semiconductor devices and structures thereof are disclosed. In a preferred embodiment, a method of fabricating a semiconductor device includes providing a workpiece having a plurality of trenches formed therein, forming a liner over the workpiece, and forming a layer of photosensitive material over the liner. The layer of photosensitive material is removed from over the workpiece except from over at least a portion of each of the plurality of trenches. The layer of photosensitive material is partially removed from over the workpiece, leaving a portion of the layer of photosensitive material remaining within a lower portion of the plurality of trenches over the liner.Type: GrantFiled: July 24, 2006Date of Patent: March 3, 2009Assignee: Infineon Technologies AGInventor: Josef Maynollo
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Patent number: 7491660Abstract: A method is provided for making a FET device in which a nitride layer overlies the PFET gate structure, where the nitride layer has a compressive stress with a magnitude greater than about 2.8 GPa. This compressive stress permits improved device performance in the PFET. The nitride layer is deposited using a high-density plasma (HDP) process, wherein the substrate is disposed on an electrode to which a bias power in the range of about 50 W to about 500 W is supplied. The bias power is characterized as high-frequency power (supplied by an RF generator at 13.56 MHz). The FET device may also include NFET gate structures. A blocking layer is deposited over the NFET gate structures so that the nitride layer overlies the blocking layer; after the blocking layer is removed, the nitride layer is not in contact with the NFET gate structures. The nitride layer has a thickness in the range of about 300-2000 ?.Type: GrantFiled: October 17, 2007Date of Patent: February 17, 2009Assignees: International Business Machines Corporation, Novellus Systems. Inc.Inventors: Richard A. Conti, Ronald P. Bourque, Nancy R. Klymko, Anita Madan, Michael C. Smits, Roy H. Tilghman, Kwong Hon Wong, Daewon Yang