From Hydrocarbon Patents (Class 526/348)
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Patent number: 8637625Abstract: Propylene copolymer (a) comprising at least 1-butene as a comonomer, (b) having a comonomer content in the range of 1.0 to 3.0 wt.-%, (c) having a xylene soluble fraction equal or below 2.5 wt.-%, and (d) being partially crystallized in the ?-modification.Type: GrantFiled: November 16, 2009Date of Patent: January 28, 2014Assignee: Borealis AGInventors: Klaus Bernreitner, Manfred Stadlbauer, Norbert Hafner, Wilfried Töltsch
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Publication number: 20140024794Abstract: The present invention relates to a polypropylene which has—a melt flow rate MFR(230° C., 2.16 kg) of at least 13 g/10 min,—an amount of xylene solubles XS of 6.0 wt % or less, and—a crystalline fraction, wherein at least 10% of the crystalline fraction melts the temperature range of from 160 to 170° C., as determined by the stepwise isothermal segregation technique (SIST).Type: ApplicationFiled: October 5, 2011Publication date: January 23, 2014Applicant: Borealis AGInventors: Saeid Kheirandish, Petar Doshev, Michael Reisecker, David Friel, Sybille Simon
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Publication number: 20140023331Abstract: Disclosed is a composition for a high strength loose tube type fiber optic cable with excellent flexibility and excellent impact resistance, which includes a polypropylene-polyethylene copolymer having a melt flow index (MFI) of 1.1 g/10 minutes to 3.0 g/10 minutes at 230° C. and a flexural modulus of 10,000 to 23,000 kg/cm2. A fiber optic cable including a loose tube formed with the composition for a high strength loose tube type fiber optic cable has excellent flexibility and impact resistance as well as excellent appearance.Type: ApplicationFiled: July 18, 2012Publication date: January 23, 2014Applicant: LS Cable & System Ltd.Inventors: Jeong-Eun LIM, Yu-Hyoung LEE, Gi-Joon NAM
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Patent number: 8633287Abstract: A polymerization process for copolymerizing ethylene and a series of ?-olefins to form a branched polyethylene, in which the series of ?-olefins is generated in-situ by an ethylene oligomerization catalyst, is improved if the oligomerization catalyst has a Schulz-Flory constant of about 0.30 to about 0.55. This makes very little higher molecular weight ?-olefins, which allows for easy removal of unpolymerized ?-olefins from the polyolefin product.Type: GrantFiled: August 17, 2010Date of Patent: January 21, 2014Assignee: E I du Pont de Nemours and CompanyInventor: Joel David Citron
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Patent number: 8633290Abstract: An optical resin comprises a copolymer of 4-methyl-1-pentene and at least one monomer selected from the group consisting of 3-methyl-1-pentene, 3-methyl-1-butene and 4,4-dimethyl-1-pentene. The content of a constituent unit (a) derived from 4-methyl-1-pentene is equal to or more than 60 mol % and equal to or less than 99 mol %, and the total content of a constituent unit (b) derived from at least one monomer selected from the group consisting of 3-methyl-1-pentene, 3-methyl-1-butene and 4,4-dimethyl-1-pentene is equal to or more than 1 mol % and equal to or less than 40 mol %.Type: GrantFiled: July 13, 2009Date of Patent: January 21, 2014Assignees: Mitsui Chemicals, Inc., Sharp CorporationInventors: Satoshi Kawamoto, Kouichi Kizu, Sunil Krzysztof Moorthi, Akira Sakai
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Patent number: 8629203Abstract: Coated reinforcing biofiber for thermoplastic articles is disclosed. The coating on the biofiber comprises a plastisol. The coated reinforcing biofiber can be used in thermoplastic compounds to simulate the appearance of natural wood while adding significantly increased flexural modulus for the wood plastic composite (WPC).Type: GrantFiled: February 16, 2011Date of Patent: January 14, 2014Assignee: PolyOne CorporationInventors: Roman B. Hawrylko, Sang H. Lee
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Patent number: 8629223Abstract: The present invention relates to a method for initiating an ethylene polymerization reaction in an ethylene polymerization loop reactor. More particularly, the invention relates to the timing upon which hydrogen is introduced into the ethylene polymerization loop reactor. The catalysts used in the ethylene polymerization reaction according to present invention are preferably metallocene catalysts.Type: GrantFiled: December 17, 2010Date of Patent: January 14, 2014Assignee: Total Research & Technology FeluyInventor: Daniel Siraux
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Publication number: 20140011927Abstract: An ethylene/?-olefin copolymer comprising units derived from ethylene; and units derived from at least one ?-olefin; wherein the ethylene/?-olefin copolymer has a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; an Mw/Mn of from 3 to 5; and from 300 to 500 vinyl unsaturations per 1,000,000 carbon atoms in the ethylene/?-olefin copolymer is provided. Also provided is a process for producing an ethylene/?-olefin copolymer comprising: (1) polymerizing ethylene and one or more ?-olefins in a polymerization reactor; (2) thereby producing an enhanced melt strength ethylene/?-olefin copolymer having from 300 to 500 vinyl unsaturation units per 1,000,000 carbon atoms, a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; and a Mw/Mn of from 3 to 5.Type: ApplicationFiled: March 1, 2012Publication date: January 9, 2014Applicant: Dow Global Technologies LLCInventors: Lawrence J. Effler, Teresa P. Karjala, Mehmet Demirors, Nilesh R. Savargaonkar, Selim Bensason, Zhe Zhou
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Patent number: 8623261Abstract: A method of preparing a thermoformed article which is relatively isotropic in terms of shrinkage of the final thermoformed article along the sheet extrusion flow path (the longitudinal direction) and the transverse direction. The article is prepared from an isotactic polypropylene produced by the polymerization of propylene with an isospecific metallocene catalyst. The polymer has a melt flow rate within the range of 1-5 grams/10 minutes and a melting temperature of no more than 160° C. The polypropylene is extruded to provide a sheet which is oriented in at least one direction and has a thickness of 10-100 mils. The sheet is heated to a temperature of 135-160° C, and thermoformed in contact with a template having the desired configuration to produce the thermoformed article. The thermoformed article is then cooled and retrieved from the template to arrive at the final product.Type: GrantFiled: December 13, 2007Date of Patent: January 7, 2014Assignee: Fina Technology, Inc.Inventors: Mahesh Patkar, Michael Musgrave
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Patent number: 8623962Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.Type: GrantFiled: September 21, 2012Date of Patent: January 7, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, Jr., Donna J. Crowther, Patrick Brant
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Patent number: 8623974Abstract: This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35° C., one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol % of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.Type: GrantFiled: March 5, 2012Date of Patent: January 7, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Peijun Jiang, Patrick Brant
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Patent number: 8618319Abstract: A novel catalyst component for producing a crystalline ?-olefin polymer or ?-olefin/(meth)acrylate copolymer having few branches, especially a polymer having a high molecular weight, and a method for producing an ?-olefin polymer or an ?-olefin/(meth)acrylate copolymer using the catalyst component. A metal complex represented by the following general formula (D), as well as a method for producing an ?-olefin polymer and a method for producing an ?-olefin/(meth)acrylate copolymer using the metal complex.Type: GrantFiled: April 27, 2009Date of Patent: December 31, 2013Assignees: Japan Polypropylene Corporation, Japan Polyethylene CorporationInventors: Fumihiko Shimizu, Shixuan Xin, Akio Tanna, Shiho Goromaru, Koushi Matsubara
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Patent number: 8618227Abstract: The present invention relates to a process for improving the devolatilization of polymer slurry produced in an olefin polymerization reactor. The process is characterized in that it involves an adjustment of the temperature of the interior surface of the flash line for periodically transferring polymer slurry from the polymerization reactor to a downstream processing unit. In particular, in accordance with the present process, the temperature of the interior surface of the flash line is adjusted to a temperature which is equal to or higher than the softening temperature of the polymer passing through said flash line whereby said temperature is higher in a first half of the length of the flash line than in the remaining length of the flash line.Type: GrantFiled: December 4, 2012Date of Patent: December 31, 2013Assignee: Total Research & Technology FeluyInventors: Lieven Van Looveren, Marc Moers, Mathias Wijffels
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Patent number: 8609794Abstract: The present invention generally relates to a process that selectively polymerizes ethylene in the presence of an alpha-olefin, and to a metal-ligand complex (precatalyst) and catalyst useful in such processes, and to related compositions. The present invention also generally relates to ligands and intermediates useful for preparing the metal-ligand complex and to processes of their preparation.Type: GrantFiled: May 11, 2011Date of Patent: December 17, 2013Assignee: Dow Global Technologies, LLC.Inventors: Jerzy Klosin, Pulikkottil J. Thomas, Robert D. Froese, Xiuhua Cui
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Patent number: 8609792Abstract: The invention relates to A process for the polymerization of ethylene to produce a polyethylene resin in at least two slurry loop reactors connected to each other in series, the resin having a bimodal molecular weight distribution, a molecular weight distribution MWD of at least 7.0, an HLMI of from 1 to 100 g/10 min, and a density of from 0.935 to 0.960 g/cm3, wherein in one reactor 30 to 47 wt % based on the total weight of the polyethylene resin of a high molecular weight (HMW) polyethylene fraction is produced having an HL275 of from 0.05 to 1.8 g/10 min (the equivalent of HLMI of from 0.01 to 1.56 g/10 min), a density of from 0.925 to 0.942 g/cm3 and an MWD of at least 5.0, and in the other reactor a low molecular weight (LMW) polyethylene fraction is produced having an HLMI of from 10 to 1500 g/10 min and a density of from 0.960 to 0.975 g/cm3, in the presence of a Ziegler-Natta catalyst system.Type: GrantFiled: February 7, 2011Date of Patent: December 17, 2013Assignee: Total Research & Technology FeluyInventors: Aurélien Vantomme, Daniel Siraux, Alain Van Sinoy, Jean-Léon Gielens
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Publication number: 20130327006Abstract: Melt-blown fiber comprising a terpolymer of propylene, ethylene and a C4 to C10 ?-olefin, wherein further said melt blown fiber and/or said terpolymer has/have a melt flow rate MFR25 (230° C.) of at least 300 g/10 min, the amount of propylene in said terpolymer is at least 90.0 wt.-%, the weight ratio of ethylene and a-olefin within said terpolymer is 1/100 to below 1/1, and the terpolymer has <2,1> regiodefects of below 0.4 mol.-%.Type: ApplicationFiled: January 9, 2012Publication date: December 12, 2013Inventors: Henk Van Paridon, Antti Tynys, Joachim Fiebig, Matthew Parkinson
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Patent number: 8604146Abstract: Disclosed herein are catalyst compositions and polymers, i.e., propylene-based polymers, produced therefrom. The present catalyst compositions include an internal electron donor with a compounded alkoxyalkyl ester and optionally a mixed external electron donor. The present catalyst compositions improve catalyst selectivity, improve catalyst activity, and/or improve hydrogen response. Propylene-based polymer produced from the present catalyst composition has a melt flow rate greater than 10 g/10 min.Type: GrantFiled: December 21, 2010Date of Patent: December 10, 2013Assignee: Dow Global Technologies LLCInventors: Linfeng Chen, Kelly Gonzalez
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Patent number: 8598241Abstract: Provided are polypropylene resin pre-foamed particles including, as base resin, polypropylene resin that satisfies the following requirements (a) through (c): (a) in cross fractionation chromatography, an amount of components eluted at a temperature of not more than 40° C. is not more than 2.0% by weight; (b) a melting point is not less than 100° C. but not more than 160° C.; and (c) propylene monomer units are present in an amount of not less than 90 mol % but not more than 100 mol %, and olefin units each having a carbon number of 2 or 4 or more are present in an amount of not less than 0 mol % but not more than 10 mol %. The polypropylene resin pre-foamed particles can be molded by in-mold foaming molding at a not high molding heating steam pressure, and a polypropylene resin in-mold foaming molded product excellent in dimensional stability at high temperatures can be prepared from the polypropylene resin pre-foamed particles.Type: GrantFiled: January 13, 2010Date of Patent: December 3, 2013Assignee: Kaneka CorporationInventors: Toru Yoshida, Hiroshi Tsuneishi
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Patent number: 8598242Abstract: Disclosed is an expanded polypropylene copolymer resin particle whose base resin is a polypropylene random copolymer resin having a melting point of not more than 145° C., the base resin having a H/W ratio of not more than 8 where H (%) is a maximum height of an elution peak and W (° C.) is a peak width at half a height of the peak in an elution curve obtained from a differential value of eluted content measured by cross fractionation chromatography, and a ratio (Mw/Mn) of a weight-average molecular weight (Mw) and a number-average molecular weight (Mn) being not less than 3.5 in a molecular weight distribution measurement of a whole of eluted components. With such an expanded polypropylene copolymer resin particle, it is possible to provide expanded polypropylene copolymer resin particles which are capable of producing an in-mold expansion-molded article with a low molding heating vapor pressure, and which causes few deformation or shrinkage of an obtained in-mold expansion-molded article (i.e.Type: GrantFiled: March 30, 2010Date of Patent: December 3, 2013Assignee: Kaneka CorporationInventor: Kenichi Senda
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Patent number: 8598287Abstract: A process for polymerizing olefin(s) utilizing a cyclic bridged metallocene catalyst system to produce polymers with improved properties is provided. The catalyst system may include a cyclic bridged metallocene, LA(R?SiR?)LBZrQ2, activated by an activator, the activator comprising aluminoxane, a modified aluminoxane, or a mixture thereof, and supported by a support, where: LA and LB are independently an unsubstituted or a substituted cyclopentadienyl ligand bonded to Zr and defined by the formula (C5H4-dRd), where R is hydrogen, a hydrocarbyl substituent, a substituted hydrocarbyl substituent, or a heteroatom substituent, and where d is 0, 1, 2, 3 or 4; LA and LB are connected to one another with a cyclic silicon bridge, R?SiR?, where R? are independently hydrocarbyl or substituted hydrocarbyl substituents that are connected with each other to form a silacycle ring; and each Q is a labile hydrocarbyl or a substituted hydrocarbyl ligand.Type: GrantFiled: October 9, 2008Date of Patent: December 3, 2013Assignee: Univation Technologies, LLCInventors: Chi-I Kuo, Dongming Li, Ching-Tai Lue, Francis C. Rix, Mark G Goode, Daniel P. Zilker, Jr., Tae Hoon Kwalk
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Patent number: 8598283Abstract: Methods for shutting down and restarting polymerization in a gas phase polymerization reactor are provided. The method can include introducing a polymerization neutralizer to the reactor in an amount sufficient to stop polymerization therein. The method can also include stopping recovery of a polymer product from the reactor and stopping introduction of a catalyst feed and a reactor feed to the reactor. The method can also include adjusting a pressure within the reactor from an operating pressure to an idling pressure. The method can also include adjusting a superficial velocity of a cycle fluid through the reactor from an operating superficial velocity to an idling superficial velocity. The method can also include maintaining the reactor in an idled state for a period of time.Type: GrantFiled: February 17, 2011Date of Patent: December 3, 2013Assignee: Univation Technologies, LLCInventors: Eric J. Markel, Robert O. Hagerty, Richard B. Pannell, Michael E. Sieloff, Jerome Holveck
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Patent number: 8598284Abstract: An oxygen-bridged bimetallic complex of the general formula (I) Cp2R1M1-O-M2R22Cp??(I), wherein Cp is independently a cyclopentadienyl, indenyl or fluorenyl ligand which can be substituted, or a ligand isolobal to cyclopentadienyl, R1, R2 independently are halide, linear or branched or cyclic alkyl, aryl, amido, phosphido, alkoxy or aryloxy groups, which can be substituted, M1 is Zr, Ti or Hf, and M2 is Ti, Zn, Zr or a rare earth metal. The complex can be useful as a polymerization catalyst.Type: GrantFiled: September 10, 2010Date of Patent: December 3, 2013Assignee: Georg-August-Universitat GoettingenInventors: Herbert W Roesky, Prabhuodeyara M Gurubasavaraj
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Patent number: 8586163Abstract: Heterophasic propylene copolymer (HECO) comprising wherein the heterophasic propylene copolymer (HECO) is ?-nucleated and the elastomeric phase has an intrinsic viscosity measured in tetraline at 135° C. of equal or below 4.0 dl/g.Type: GrantFiled: October 27, 2008Date of Patent: November 19, 2013Assignee: Borealis Technology OyInventors: Bo Malm, Klaus Bernreitner, Franz Ruemer
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Patent number: 8586497Abstract: Olefin polymerization catalyst systems including a high molecular weight catalyst compound and a low molecular weight catalyst compound, and methods of making same are provided. High molecular weight catalysts include metallocene catalysts and low molecular weight catalysts include non-metallocene compounds including biphenyl phenol compounds. Generally catalyst systems may include less than about 5.0 mol % of the high molecular weight catalyst compound relative to said low molecular weight catalyst. Methods for olefin polymerization including the aforementioned catalyst systems, and polyolefins and products made therefrom.Type: GrantFiled: November 12, 2008Date of Patent: November 19, 2013Assignee: Univation Technologies, LLCInventors: Rainer Kolb, Dongming Li, Francis C. Rix, Cesar A. Garcia-Franco
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Publication number: 20130302629Abstract: Random copolymers of propylene with ethylene, and optionally other olefins, comprising from 3.5% to 6.5% by weight of ethylene and having a melt flow rate (MFR) according to ISO 1133 (230° C., 2.16 Kg) of less than 10 g/10 min and a melting temperature (Tm), determined by DSC, satisfying the relation: 45° C.?Tm+C?150° C. wherein C is the quantity (by weight) of ethylene in the copolymer. The random copolymers of the invention are specifically suited for cast film and/or sheet applications.Type: ApplicationFiled: July 29, 2011Publication date: November 14, 2013Applicant: Basell Poliolefine Italia, S.r.l.Inventors: Marco Ciarafoni, Monica Galvan, Roberta Marzolla, Paola Massari
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Patent number: 8580902Abstract: Provided are catalyst systems, processes for polymerizing one or more olefins, polymers resulting therefrom, and articles prepared from such polymers. The processes comprise contacting under polymerization conditions one or more olefin monomers, preferably propylene, with a catalyst system comprising a transition metal compound and an activator of the formula (1) or (2) as described herein. The polymer compositions described herein exhibit advantageously narrow composition distributions and high melting points in comparison to conventional polymers having the same comonomer content. The polymers described herein exhibit improved properties, e.g., pellet stability, impact properties, heat seal properties, and structural integrity in film and fabricated parts applications.Type: GrantFiled: August 14, 2009Date of Patent: November 12, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Donna J. Crowther, Peijun Jiang, Rainer Kolb
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Patent number: 8569437Abstract: A solar cell encapsulated with an encapsulating material which is a non-crystalline or low-crystalline ?-olefin-based copolymer or its composition (I). The composition (C) can contain 50 to 100 parts by weight of non-crystalline ?-olefin polymer (A) which meets the following requirements: (a) the ?-olefin having 3 to 20 carbon atoms is not less than 20 mol %, (b) practically no melt peak as measured by a differential scanning calorimeter is observed, and (c) the Mw/Mn is not more than 5, and 50 to 0 parts by weight of crystalline ?-olefin polymer (B) (the total of (A) and (B) being 100 parts by weight). The non-crystalline or low-crystalline ?-olefin copolymer may also have a crystallinity of not higher than 40% as measured by use of X rays.Type: GrantFiled: January 2, 2013Date of Patent: October 29, 2013Assignees: Du Pont-Mitsui Polychemicals, Co., Ltd., Mitsui Chemicals Tohcello, Inc.Inventors: Koichi Nishijima, Akira Yamashita
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Patent number: 8569433Abstract: A manufacturing system for producing polyolefin includes a polymerization reactor, a flash chamber, and a purge column. In certain embodiments, the purge column may receive a solids stream directly from the flash chamber. Further, the purge column may function as a feed tank for an extruder within an extrusion/loadout system. According to certain embodiments, the manufacturing system may be configured to consume less than 445 kilowatt-hours of energy per metric ton of polyolefin produced based on consumption of electricity, steam, and fuel gas.Type: GrantFiled: October 19, 2012Date of Patent: October 29, 2013Assignee: Chevron Phillips Chemical Company LPInventors: Robert R. McElvain, John D. Hottovy, Ralph W. Romig, Donald W. Verser, David H. Burns, John H. Tait, Richard Peacock, James E. Hein, Scott E. Kufeld, Carl W. Fenderson, Anurag Gupta, Dale A. Zellers
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Patent number: 8569532Abstract: A complex containing a ligand of formula (I): useful in the formation of olefin polymerization catalysts and their use in olefin polymerization.Type: GrantFiled: June 11, 2012Date of Patent: October 29, 2013Assignee: Borealis Technology OyInventors: Alexander Zelmanovich Voskoboynik, Andrei Fyodorovich Asachenko, Dmitry Konanovich, Mikhail V. Nikulin, Alexey Tzarev, Janne Maaranen, Tiina Vanne, Jyrki Kauhanen, Erik Mansner, Esa Kokko, Laura Saarinen
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Patent number: 8568894Abstract: The invention provides a film comprising at least one layer formed from a composition comprising a propylene-based polymer and a saturated compound, selected from the group consisting of aliphatic amides, hydrocarbon waxes, hydrocarbon oils, fluorinated hydrocarbons, siloxanes, and combinations thereof; and wherein the propylene-based polymer has less than 0.01 mole percent total unsaturations, as determined by 1H NMR.Type: GrantFiled: July 2, 2009Date of Patent: October 29, 2013Assignee: Dow Global Technologies LLCInventors: Teresa E. Bernal-Lara, Andrea Hazlitt
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Publication number: 20130281339Abstract: Provided are ethylene-based copolymers, methods of preparing the same, lubricating oil compositions including the same, methods for preparing such lubricating oil compositions, and end uses for such ethylene-based copolymers and lubricating oil compositions. The ethylene-based copolymers may include from about 35 wt. % to about 60 wt. % of units derived from ethylene and at least 1.0 wt. % of one or more alpha-olefin comonomers having 3 to 20 carbon atoms. The ethylene-based copolymers are substantially amorphous and have a polydispersity index of about 2.8 or less.Type: ApplicationFiled: October 12, 2012Publication date: October 24, 2013Applicant: ExxonMobil Chemical CompanyInventors: Rainer KOLB, Sudhin DATTA, Liehpao O. FARNG, Vera MINAK-BERNERO, Eric B. SIROTA, Thomas T. SUN, Mun Fu TSE
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Patent number: 8563674Abstract: Polyethylene which comprises ethylene homopolymers and copolymers of ethylene with ?-olefins and has a molar mass distribution width Mw/Mn of from 6 to 100, a density of from 0.89 to 0.97 g/cm3, a weight average molar mass Mw of from 5000 g/mol to 700 000 g/mol and has from 0.01 to 20 branches/1000 carbon atoms and at least 0.5 vinyl groups/1000 carbon atoms, wherein the 5-50% by weight of the polyethylene having the lowest molar masses have a degree of branching of less than 10 branches/1000 carbon atoms and the 5-50% by weight of the polyethylene having the highest molar masses have a degree of branching of more than 2 branches/1000 carbon atoms, a process for its preparation, catalysts suitable for its preparation and also fibers, moldings, films or polymer blends in which this polyethylene is present.Type: GrantFiled: May 27, 2010Date of Patent: October 22, 2013Assignee: Basell Polyolefine GmbHInventor: Shahram Mihan
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Patent number: 8563671Abstract: Method employing a supported metallocene catalyst composition in the production of an isotactic ethylene propylene co-polymer. The composition comprises a metallocene component supported on a particulate silica support having average particle size of 10-40 microns, a pore volume of 1.3-1.6 ml/g, a surface area of 200-400 m2/g. An alkylalumoxane cocatalyst component is incorporated on the support. The isospecific metallocene is characterized by the formula: B(CpRaRb)(FlR?2)MQn??(1) or by the formula: B?(Cp?R?aR?b)(Fl?)M?Q?n???(2) In the formulas Cp and Cp? are substituted cyclopentadienyl groups, Fl and Fl? are fluorenyl groups, and B and B? are structural bridges. R? are substituents at the 2 and 7 positions, Ra and R?a are substituents distal to the bridge, and Rb and R?b are proximal to the bridge. M and M? are transition metals, Q? is a halogen or a C1-C4 alkyl group; and n? is an integer of from 0-4.Type: GrantFiled: September 18, 2012Date of Patent: October 22, 2013Assignee: Fina Technology, Inc.Inventors: William Gauthier, David Rauscher, Jun Tian, Nathan Williams
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Patent number: 8563673Abstract: A propylene-based resin molded article satisfying the following requirements (1) through (4): Requirement (1) Lc/La?1.50 Requirement (2) Lc?10.0 Requirement (3) F1?0.07 Requirement (4) F2?0.06 wherein in Requirements (1) through (4), La denotes the distance (unit: nm) between crystalline lamellae calculated from the long-period distance calculated from a small-angle X-ray scattering profile and the degree of crystallization calculated from the amount of heat of fusion measured by differential scanning calorimetry, Lc denotes the thickness (unit: nm) of a crystalline lamella calculated from the distance between crystalline lamellae and the long-period distance, F1 denotes the degree of orientation calculated from the infrared dichroic ratio measured at a wave number of 997 cm?1, and F2 denotes the degree of orientation calculated from the infrared dichroic ratio measured at a wave number of 973 cm?1.Type: GrantFiled: May 29, 2007Date of Patent: October 22, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Takafumi Iwata, Hideki Oshima, Satoru Moritomi
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Patent number: 8563669Abstract: An olefin polymerization reactor is provided with a first cylinder extending vertically; a first tapered cylindrical member placed in the first cylinder, having the inner diameter decreasing progressively downward, and having a gas inlet orifice at a bottom end thereof; a first liquid supplying part supplying a liquid so that the liquid may come into contact with an outer surface of the first tapered cylindrical member; and a gas supplying part supplying an olefin-containing gas through the gas inlet orifice into a first reaction region surrounded by an inner surface of the first tapered cylindrical member and an inner surface of the first cylinder above the first tapered cylindrical member, to form a spouted bed in the first reaction region.Type: GrantFiled: March 23, 2012Date of Patent: October 22, 2013Assignee: Sumitomo Chemical Company, LimitedInventors: Hideki Sato, Hiroyuki Ogawa
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Patent number: 8557931Abstract: The present invention relates to a slurry process for preparing an ethylene polymer having a melt flow ratio F/P, according to ASTM 1238, of higher than 25, carried out in two or more stages of polymerization at temperatures in the range from 60 to 120° C., in which at least two of the said two or more polymerization stages are carried out under different concentration of a molecular weight regulator, said process being carried out in the presence of a catalyst system comprising the product obtained by contacting (A) a solid catalyst component comprising Ti, Mg, halogen, and having a porosity (PF), measured by the mercury method and due to pores with radius equal to, or lower than, 1 ?m of at least 0.3 cm3/g and a surface area determined by BET method, of lower than 100 m2/g, and (B) of an organoaluminum compound.Type: GrantFiled: February 15, 2010Date of Patent: October 15, 2013Assignee: Basell Polyolefin GmbHInventors: Diego Brita, Gianni Collina
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Patent number: 8557924Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 935 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 50.Type: GrantFiled: May 25, 2009Date of Patent: October 15, 2013Assignee: Borealis AGInventors: Mats Bäckman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlöf
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Patent number: 8557936Abstract: This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly ?-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.Type: GrantFiled: October 20, 2010Date of Patent: October 15, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Garth R. Giesbrecht, Timothy M. Boller, Alexander Z. Voskoboynikov, Andrey F. Asachenko, Mikhail V. Nikulin, Alexey A. Tsarev
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Patent number: 8557917Abstract: The present invention relates to a process for the preparation of a propylene homo- or copolymer, comprising the following steps: (i) feeding propylene and hydrogen, and optionally one or more comonomers, to a reactor R1, wherein the hydrogen is fed to the reactor R1 in a periodically varying amount, (ii) preparing a first fraction of the propylene homo- or copolymer in the reactor R1 in the presence of a catalyst, (iii) transferring the first fraction to a reactor R2, and (iv) preparing a second fraction of the propylene homo- or copolymer in the reactor R2, wherein the melt flow rate MFR (2.16 kg, 230° C.) of the propylene homo- or copolymer is higher than the melt flow rate MFR (2.16 kg, 230° C.) of the first fraction.Type: GrantFiled: October 6, 2009Date of Patent: October 15, 2013Assignee: Borealis AGInventors: Pauli Leskinen, Michiel Bergstra
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Patent number: 8557932Abstract: Process for the preparation of a multimodal polyolefin polymer at temperatures of from 40 to 150° C. and pressures of from 0.Type: GrantFiled: December 20, 2010Date of Patent: October 15, 2013Assignee: Basell Polyolefine GmbHInventors: Gerhardus Meier, Michael Aulbach, Harald Prang
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Publication number: 20130261277Abstract: This invention relates to a process for polymerization, comprising (i) contacting, at a temperature greater than 35° C., one or more monomers comprising ethylene and/or propylene, with a catalyst system comprising a metallocene catalyst compound and an activator, (ii) converting at least 50 mol % of the monomer to polyolefin; and (iii) obtaining a branched polyolefin having greater than 50% allyl chain ends, relative to total unsaturated chain ends. The invention also relates to the branched polyolefins and functionalized branched polyolefins.Type: ApplicationFiled: May 23, 2013Publication date: October 3, 2013Inventors: Peijun Jiang, Patrick Brant
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Patent number: 8546497Abstract: A propylene polymerization reaction apparatus and a production method of a propylene-based polymer are capable of producing a continuous multi-stage polymer in low cost, high productivity and stably, and significantly reducing generation amount of an off-specification product accompanying change of polymerization condition, in multi-stage continuous vapor phase polymerization method of a propylene-based polymer using a catalyst for olefin polymerization. A reaction apparatus for producing a propylene-based polymer by a multi-stage continuous vapor phase polymerization method is used. One or more reactor of a horizontal-type reactor having inside a stirring machine which rotates around a horizontal axis, and a continuous stirred tank reactor to be connected to the horizontal-type reactor are provided, and a production method of a propylene-based polymer using the same.Type: GrantFiled: November 5, 2010Date of Patent: October 1, 2013Assignee: Japan Polypropylene CorporationInventors: Takanori Nakashima, Katsuhiko Oono, Kenji Mitsutani, Takao Tayano, Tomoyuki Yoshida, Shigeo Mizukami, Yusuke Yamada
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Patent number: 8545980Abstract: A polypropylene resin having: (1) a melt flow rate (MFR) of 6 to 100 g/10 minutes, (2) a molecular weight distribution (Mw/Mn), measured by gel permeation chromatography, of 3 to 6, and (3) a 116° C. non-eluted component content (100-W116(%)) of 50% or more and a content of components eluted at 90° C. or less (W90) of 10 to 30%, measured by temperature-rising fractional chromatography (TREF).Type: GrantFiled: October 31, 2005Date of Patent: October 1, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takeharu Tajima, Toshitaka Kanai, Tomoaki Takebe, Yutaka Minami
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Patent number: 8546501Abstract: This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly ?-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.Type: GrantFiled: October 20, 2010Date of Patent: October 1, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Garth R. Giesbrecht, Timothy M. Boller, Alexander Z. Voskoboynikov, Andrey F. Asachenko, Mikhail V. Nikulin, Alexey A. Tsarev
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Patent number: 8541522Abstract: This invention relates to Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly ?-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.Type: GrantFiled: October 20, 2010Date of Patent: September 24, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Garth R. Giesbrecht, Timothy M. Boller, Alexander Z. Voskoboynikov, Andrey F. Asachenko, Mikhail V. Nikulin, Alexey A. Tsarev
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Patent number: 8541521Abstract: Group 4 catalyst compounds containing di-anionic tridentate nitrogen/oxygen based ligands are provided. The catalyst compounds are useful, with or without activators, to polymerize olefins, particularly ?-olefins, or other unsaturated monomers. Systems and processes to oligomerize and/or polymerize one or more unsaturated monomers using the catalyst compound, as well as the oligomers and/or polymers produced therefrom are also provided.Type: GrantFiled: October 20, 2010Date of Patent: September 24, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Garth R. Giesbrecht, Timothy M. Boller, Alexander Z. Voskoboynikov, Andrey F. Asachenko, Mikhail V. Nikulin, Alexey A. Tsarev
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Publication number: 20130245220Abstract: The present invention relates to a process for maintaining a continuous gas-phase (co-) polymerisation of olefins in a large fluidised bed reactor in a homogeneous mode whilst operating at high space time yield and condensation rate in the presence of a polymerisation catalyst.Type: ApplicationFiled: November 16, 2011Publication date: September 19, 2013Applicant: INEOS Commercial Services UK LimitedInventors: Jean-Louis Chamayou, Daniel Marissal
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Patent number: 8536289Abstract: A process for the production of a corona-treated polyolefin film comprising the gas-phase polymerization of one or more ?-olefins in the presence of a polymerization catalyst and an antistatic agent having a molecular weight higher than 500, said antistatic agent being fed at any stage of the polymerization process in an amount from 30 to 500 ppm weight based on the weight of the produced polyolefin.Type: GrantFiled: December 17, 2010Date of Patent: September 17, 2013Assignee: Basell Polyolefine GmbHInventors: Tiziana Caputo, Monica Galvan, Antonio Mazzucco, Paola Massari
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Patent number: 8530580Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 924 to 960 kg/m3, a melt index MFR5 of from 0.5 to 6.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 50. The compositions further have a level of volatile compounds of at most 100 ppm by weight and/or a homogeneity rating of at most 3.Type: GrantFiled: May 25, 2009Date of Patent: September 10, 2013Assignee: Borealis AGInventors: Mats Bäckman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlöf
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Patent number: 8530019Abstract: Articles having a Shore A hardness of 50 to 95 and made from polyolefin compositions comprising an ethylene-alpha-olefin interpolymer (random or block or a mixture of the two) are paintable without the need for a primer or other surface treatment with paints free of phthalate-based plasticizer and designed to paint SBS- or SEBS-type rubber based compositions. These polyolefin compositions are free of (1) phthalate-based plasticizer, (2) halogen-containing polymer, and (3) leachable, small polymeric units derived from styrene monomer. In addition, the content of the alpha-olefin in the polyolefin composition is at least 9.7 mole percent.Type: GrantFiled: February 22, 2010Date of Patent: September 10, 2013Assignee: Dow Global Technologies LLCInventors: Robert Hai-Feng He, Stephen Yau-Sang Cheng, Shuwen Peng, Jose Manu Rego, Gloria Stucchi