From Silicon Reactant Having At Least One Silicon-to-hydrogen Or -carbon Bond Patents (Class 528/10)
  • Patent number: 8268951
    Abstract: Present invention provides a fluorine-containing organopolysiloxane composition comprising a fluorine-containing silicone polymer having a three-dimensional, cross-linked structure, prepared by addition polymerizing the following (A), (B) and (C) and containing 10 to 30 mass % of the fluorine atoms, relative to a total mass of (A) to (C), (A) a vinyl group-containing organopolysiloxane represented by the following formula (1): (B) an organohydrogenpolysiloxane represented by the following formula (2): and (C) an organopolysiloxane having a reactive group on one end alone and represented by the following formula (3), and further comprising (D) a low viscosity silicone oil with a dynamic viscosity of 50 mm2/s or less at 25 degrees C.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: September 18, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hiromasa Yamaguchi, Teruki Ikeda
  • Patent number: 8263723
    Abstract: A curable organopolysiloxane composition comprising: (A) an novel organopolysiloxane represented by the following average structural formula: R1aSiO(4-a)/2 {wherein R1 represents a substituted or non-substituted monovalent hydrocarbon group, an alkoxy group, a hydroxyl group, or an organopolysiloxane residue of the following general formula: —X—(SiR2O)mSiR23 (wherein R2 are the same or different, substituted or unsubstituted monovalent hydrocarbon groups; X represents oxygen atoms or a bivalent hydrocarbon group; and ‘m’ is an integer equal to or greater than 1); however, at least one R1 in one molecule is the aforementioned organopolysiloxane residue, at least one R1 is a monovalent hydrocarbon group having aliphatic carbon-carbon double bonds, and ‘a’ is a positive number that satisfies the following condition: 0<a<2)}; (B) an organic silicon compound having in one molecule at least two silicon-bonded hydrogen atoms; and (C) a hydrosilylation catalyst; is capable of forming a cured product of high fle
    Type: Grant
    Filed: March 11, 2009
    Date of Patent: September 11, 2012
    Assignee: Dow Corning Toray Company, Ltd.
    Inventors: Yoshitsugu Morita, Michitaka Suto
  • Patent number: 8263222
    Abstract: Organosilicone fine particles of size in the range of 0.1-20 ?m, each having 20 or more faces with indefinite shapes and a network of convex parts that surround these faces with indefinite shapes on its surface, and being spherical as a whole respond to highly advanced requirements of recent years including improvements in optical characteristics of resin compounds, usability and feeling of cosmetics and maintainability of fluidity of development toners. The invention further provides methods of producing such organosilicone fine particles.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: September 11, 2012
    Assignee: Takemoto Yushi Kabushiki Kaisha
    Inventors: Fumiyoshi Ishikawa, Mamoru Yasui, Chiaki Saito
  • Publication number: 20120226002
    Abstract: Novel silicon compounds containing a siloxane or silane moiety and at least one moiety derived from a furfuryl alcohol, and methods for their synthesis, are provided. The novel compounds may be used as surface modifying agents, surfactants, defoamers, and as monomers for silicone polymerization.
    Type: Application
    Filed: February 29, 2012
    Publication date: September 6, 2012
    Applicant: GELEST TECHNOLOGIES, INC.
    Inventors: Barry C. ARKLES, Youlin PAN, Jonathan D. GOFF
  • Patent number: 8258251
    Abstract: Ceramic oxide aerogels having improved flexibility are disclosed. Preferred embodiments exhibit high modulus and other strength properties despite their improved flexibility. The gels may be polymer cross-linked via organic polymer chains to further improve strength properties, without substantially detracting from the improved flexibility. Methods of making such aerogels are also disclosed.
    Type: Grant
    Filed: May 7, 2010
    Date of Patent: September 4, 2012
    Assignees: The United States of America, as represented by the Administrator of the National Aeronautics and Space Administration, Ohio Aerospace Institute
    Inventors: Mary Ann B. Meador, Baochau N. Nguyen, Haiquan Guo
  • Publication number: 20120216949
    Abstract: A selective adhesive mechanism comprises an engineered surface structure or substrate and a compliant member. The compliant member is able to be a dry and non-tacky substance. The compliant member is selectively adhesive to the engineered surface when the compliant member is in contact with the engineered surface. The compliant member shows adhesion to the engineered surface when the compliant member is within a pre-selected range of hardness. In some embodiments, the compliant member comprises a polymeric member, a thermoplastic elastomer, silicone, polyurethane, or a combination thereof.
    Type: Application
    Filed: February 23, 2012
    Publication date: August 30, 2012
    Applicant: CAREY & CO.
    Inventors: Barbara Carey Stachowski, Loc Vinh Bui, Joanne Moody
  • Patent number: 8246168
    Abstract: Novel polymers for biomedical use, especially rigid gas permeable contact lenses that are based on bulky side-chain siloxane cross linkers. The siloxanes, either alone, or as copolymers with bulky and non-bulky mono-functional polymerizable siloxanes, fluoro monomers, such as hexafluoroisopropyl methacrylate, and hydrophilic monomers, result in transparent, high oxygen permeable polymers possessing excellent lathing and milling characteristics.
    Type: Grant
    Filed: November 10, 2008
    Date of Patent: August 21, 2012
    Assignee: Bausch & Lomb Incorporated
    Inventors: Joseph A. McGee, Jay F. Kunzler, Richard M. Ozark, Joseph C. Salamone
  • Patent number: 8236918
    Abstract: The present invention provides a linear, cyclic or branched polyether-functional siloxane or a mixture of polyether-functional siloxanes of the general formula (I) R[—O(3-h)/2Si(R1)(OR)h]x[—O(3-i-j)/2Si(R2)(R3)i(OR)j]y, (II) in which groups R are identical or different and R is essentially H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, 2-methoxyethyl or 2-hydroxyethyl or, in the case of cyclic siloxanes, may be a silyl radical of the silyl units of the formula (I), groups R1 are identical or different and R1 is a terminally blocked polyether group of the formula (II), R4—O[—R5—O]n[(—R6)m]— (II) and groups R2 are identical or different and R2 is a linear, branched or cyclic, optionally substituted alkyl group having 1 to 18 carbon atoms or a mercaptoalkyl group or an alkenyl group having 2 to 8 carbon atoms or an alkenyl group having 2 to 8 carbon atoms or an aryl group having 6 to 12 carbon atoms or an aminoalkyl group or the general formula (III) H2N(CH2)d[(NH)e(CH2)f]g—(CH2)3— (III) The
    Type: Grant
    Filed: November 5, 2004
    Date of Patent: August 7, 2012
    Assignee: Evonik Degussa GmbH
    Inventors: Ekkehard Mueh, Peter Jenkner, Max Preisenberger, Burkhard Standke
  • Patent number: 8222364
    Abstract: A composition includes a siloxane of the formula: (RMe2SiO1/2)a(MeRSiO2/2)b(RSiO3/2)c(SiO4/2)d wherein a is at least 2, b is from 3 to 20, c is from 0 to 10, d is from 0 to 10, and each R is independently of the formula —CR?2—CR?2—Y—Z or CR?2—CR?2—Z, wherein each R? is independently a hydrogen atom or a C1 to C10 hydrocarbyl free of aliphatic unsaturation so long as at least one R? is a hydrogen atom, Y is a divalent organic group, and Z is a polycyclic group containing at least one aromatic ring. A method of making the siloxane includes charging (HMe2SiO1/2)a(MeHSiO2/2)b(HSiO3/2)c(SiO4/2)d, a platinum catalyst, and an alkene of the formula CR?2?CR?—Y—Z or CR?2?CR?—Z into a reactor to form the siloxane. The siloxane is useful as a component in holographic storage media for photopolymer-based holographic data storage applications. The siloxane exhibits excellent compatibility when mixed with a polymerizable component before the polymerizable component is cured.
    Type: Grant
    Filed: April 10, 2007
    Date of Patent: July 17, 2012
    Assignees: Dow Corning Corporation, DCE Aprilis, Inc.
    Inventors: Kai Su, Duane R. Bujalski, Peter Y. Lo, Eric Kolb
  • Patent number: 8217130
    Abstract: Disclosed herein is a curable composition excellent in workability, adhesion properties, rubber-like properties, storage stability, and quick curability. The curable composition comprises (A) a crosslinkable silyl group-containing organic polymer and (B) a (meth)acrylic polymer obtained by polymerizing a (meth)acrylic monomer having a polymerizable unsaturated bond in the presence of a metallocene compound and a crosslinkable silyl group-containing thiol compound, at least one end of the (meth)acrylic polymer being bonded to a residue, —S—R3 (where R3 represents a group having a crosslinkable silyl group) obtained by removing a hydrogen atom from the crosslinkable silyl group-containing thiol compound.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: July 10, 2012
    Assignee: Cemedine Co., Ltd.
    Inventors: Atsushi Saito, Tomonori Saito, Naomi Okamura
  • Patent number: 8217132
    Abstract: A silicone rubber composition, which comprises 100 parts by weight of a vinyl group-introduced methylfluoroalkylvinyl-based silicone rubber obtained by copolymerization of a dimethylsiloxane copolymerization unit as the main component with 5-50% by mole of a methylfluoroalkylsiloxane copolymerization unit, and 0.2-8 parts by weight of an organic peroxide. When silica is used as a filler, it is desirable to use a surfactant for silica, and water at the same time. The present silicone rubber composition can give distinguished low-temperature characteristics and blister resistance, and thus can be used for seal materials directed to high-pressure hydrogen gas storage tanks, for example, to storage under 70 MPa, and particularly as suitable vulcanization-molding materials for O-rings, packings, gaskets, oil seals, valves, etc. High-pressure gases for storage are not limited only to hydrogen gas, but also to oxygen gas, nitrogen gas, helium gas, etc. likewise.
    Type: Grant
    Filed: June 15, 2007
    Date of Patent: July 10, 2012
    Assignee: NOK Corporation
    Inventors: Takeshi Sato, Masaya Otsuka, Masashi Kudo
  • Publication number: 20120168080
    Abstract: A composition, including a) at least one silane-functional polymer P; and b) at least one alkyltrialkoxysilane of the formula (I): R2—Si—(OR1)3, where R1 is a linear or branched univalent hydrocarbon group having from 1 to 12 carbon atoms, which optionally includes one or more C—C multiple bonds and/or optionally cycloaliphatic and/or aromatic groups; and R2 is a branched hydrocarbon group having from 6 to 10 carbon atoms. In the cured state, compositions have good mechanical properties and good adhesion properties, and exhibit improved extensibility and a low modulus of elasticity.
    Type: Application
    Filed: February 24, 2012
    Publication date: July 5, 2012
    Applicant: Sika Technology AG
    Inventors: Fabien CHOFFAT, Sara Fedier
  • Publication number: 20120172543
    Abstract: Silicone pressure sensitive adhesive (PSA) compositions and methods for their preparation are provided. In one embodiment, PSAs are formed from a silicone polymer mixture by condensation polymerization of low viscosity polyorganosiloxanes in inert solvents and/or silicone fluids, and optionally adding a silicone resin (MQ) during polymerization. The silicone polymer mixture formed may also be mixed with a silicone resin (MQ) and bodying catalyst, and bodying is allowed to continue until the desired reaction product is formed.
    Type: Application
    Filed: August 24, 2010
    Publication date: July 5, 2012
    Inventors: Stephen Edward Cray, Delphine Davio, Robert Alan Ekeland, Andreas Stammer
  • Patent number: 8211546
    Abstract: A composition comprising (A) a hydrolytic condensate of a bisphenol A alkoxysilane, (B) silica colloid sol, and (C) a curing catalyst is coated and cured to a transparent substrate to form a transparent film having crack resistance, flexibility and water vapor barrier properties.
    Type: Grant
    Filed: August 9, 2010
    Date of Patent: July 3, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Motoo Fukushima, Koichi Higuchi, Hisatoshi Komori
  • Patent number: 8207242
    Abstract: To provide a photocurable material which can form a cured product having a high transparency and a high refractive index, a process for producing the material easily, and an article having a high transparency and a high refractive index.
    Type: Grant
    Filed: June 3, 2011
    Date of Patent: June 26, 2012
    Assignee: Asahi Glass Company, Limited
    Inventors: Hideo Nomoto, Yasuhide Kawaguchi, Hideshi Sasakura
  • Patent number: 8207245
    Abstract: The present invention relates to silicon-containing biostable gels and processes for their preparation. The gels possess properties which make them useful in the manufacture and repair of biomaterials and medical devices, articles or implants, in particular the manufacture of soft tissue implants such as breast implants and the repair of orthopaedic joints such as spinal discs.
    Type: Grant
    Filed: September 28, 2005
    Date of Patent: June 26, 2012
    Assignee: Aortech International plc
    Inventors: Ajay Padsalgikar, Trang Thanh Nhan, Sriram Venkataramani, Mansour Mehrabi, Mark Bown
  • Publication number: 20120157558
    Abstract: A polyether siloxane of formula (I) R1—Si(CH3)2—O—[—Si(CH3)2—O—]n—[—Si(CH3)R—O—]m—Si(CH3)2—R2??(I) where R, R1 and R2 are the same or different, R in each occurrence is the same or different and represents —(CH2)x—O—(CH2—CR?R?—O)y—R??, R? and R? are the same or different and each represent —H, —CH3, —CH2CH3 or phenyl, R?? represents —H, alkyl or acyl, R1 and/or R2 each represent methyl or R, wherein the alkylene oxide units (CH2—CR?R?—O) within a polyether residue R can be the same or different and the polyether residues R within a polyether siloxane molecule of formula (I) can be the same or different, wherein on average (number average, averaged over all compounds of formula (I)) n+m+2=>10 to 200, m=0 to 40 for R1 and/or R2 representing R or m=1 to 40 for R1 and R2 representing —CH3, x=2 to 10, y=1 to 50, at least 25% of the R?? radicals represent hydrogen and at least 50% of all polyether residues R which have an end group R??=—H have a secondary or tertiary OH end group.
    Type: Application
    Filed: December 16, 2011
    Publication date: June 21, 2012
    Applicant: EVONIK GOLDSCHMIDT GMBH
    Inventors: Carsten Schiller, Martin Glos, Christian Eilbracht
  • Publication number: 20120133078
    Abstract: A method of forming a relief image in a structure comprising a substrate and a transfer layer formed thereon comprises covering the transfer layer with a polymerizable fluid composition, and then contacting the polymerizable fluid composition with a mold having a relief structure formed therein such that the polymerizable fluid composition fills the relief structure in the mold. The polymerizable fluid composition is subjected to conditions to polymerize polymerizable fluid composition and form a solidified polymeric material therefrom on the transfer layer. The mold is then separated from the solid polymeric material such that a replica of the relief structure in the mold is formed in the solidified polymeric material; and the transfer layer and the solidified polymeric material are subjected to an environment to selectively etch the transfer layer relative to the solidified polymeric material such that a relief image is formed in the transfer layer.
    Type: Application
    Filed: February 1, 2012
    Publication date: May 31, 2012
    Applicant: BOARD OF REGENTS, THE UNIVERSITY OF TEXAS SYSTEM
    Inventors: Carlton Grant Willson, Matthew E. Colburn
  • Publication number: 20120129352
    Abstract: A pattern-forming method includes forming a silicon-containing film on a substrate, the silicon-containing film having a mass ratio of silicon atoms to carbon atoms of 2 to 12. A shape transfer target layer is formed on the silicon-containing film. A fine pattern is transferred to the shape transfer target layer using a stamper that has a fine pattern to form a resist pattern. The silicon-containing film and the substrate are dry-etched using the resist pattern as a mask to form a pattern on the substrate in nanoimprint lithography. According to another aspect of the invention, a silicon-containing film includes silicon atoms and carbon atoms. A mass ratio of silicon atoms to carbon atoms is 2 to 12. The silicon-containing film is used for a pattern-forming method employed in nanoimprint lithography.
    Type: Application
    Filed: July 28, 2011
    Publication date: May 24, 2012
    Applicant: JSR Corporation
    Inventors: Takashi MORI, Masato TANAKA, Yukio NISHIMURA, Yoshikazu YAMAGUCHI
  • Patent number: 8173622
    Abstract: Antimicrobial compounds, such as silanol or alcohol, include a protecting or leaving group that can protect the compound from degradation during the process of preparing a medical device containing the compound or reduce the volatility of the compound relative to its counterpart without the leaving group. Nearly any hydrolysable leaving group may be employed. The leaving group may be an agent that may serve a therapeutic function in addition to protecting or retaining the antimicrobial agents.
    Type: Grant
    Filed: August 15, 2008
    Date of Patent: May 8, 2012
    Assignee: Medtronic, Inc.
    Inventors: Paul Hsien-Fu Wu, Catherine E. Taylor, Linnus Cheruiyot, Jianwei Li, Terese A. Bartlett, Matt Bergan
  • Publication number: 20120108749
    Abstract: Silicone pressure sensitive adhesive compositions including amphiphilic copolymers. The amphiphilic copolymers are based on a polydimethylhydrogensiloxane or polydimethylsiloxane based macroinitiator. A medical device including said pressure sensitive adhesive compositions for securing the device to human skin or tissue.
    Type: Application
    Filed: July 7, 2010
    Publication date: May 3, 2012
    Applicant: ConvaTec Technologies Inc.
    Inventors: Mahesh Sambasivam, James Crivello
  • Patent number: 8168740
    Abstract: Process for producing an organosiloxane polymer and novel organosiloxane polymer compositions. The process according to the invention comprises hydrolyzing tetraalkoxysilane monomers in a hydrolysis step; and polymerizing said hydrolyzed monomers in a polymerization step by subjecting them to conditions conducive to polymerization to form an organosiloxane polymer. The hydrolysis step is conducted in a reaction medium comprising an organic compound with hydroxy groups. The invention allows for the synthesis of siloxane polymer compositions suitable for thin-film applications using a high content of tetra- and trifunctional silixane polymer precursors.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: May 1, 2012
    Assignee: Braggone Oy
    Inventor: Ari Kärkkäinen
  • Publication number: 20120082850
    Abstract: The present invention relates to polysiloxane nanoparticles have the following properties: an average particle size d50 (measured using REM recordings) in the range of 10-200 nm, a specific surface area Ao of at least 50 m2/g, a pore volume of at least 0.2 cm3/g, an average pore volume d50 of at least 0.8 mn, whereas the particles have groups that contain carbon, which groups are bonded to the silicon at least partially in the form of unsubstituted or substituted alkyl, alkenyl, aryl, arylalkyl, or alkylaryl groups.
    Type: Application
    Filed: June 10, 2010
    Publication date: April 5, 2012
    Inventors: Monika Bauer, Hans-Juergen Glaesel
  • Patent number: 8148161
    Abstract: Disclosed herein is a composition having: a polymer having a carbosilane or siloxane backbone and pendant hydrogen-bond acidic groups; and a filler material having polar groups. The polymer is not covalently bound to the filler material.
    Type: Grant
    Filed: May 1, 2009
    Date of Patent: April 3, 2012
    Assignee: The United States of America, as represented by the Secretary of the Navy
    Inventors: Bernadette A. Higgins, Duane L. Simonson, Viet Nguyen, Jennifer L. Stepnowski, R Andrew McGill
  • Patent number: 8143363
    Abstract: The present invention relates to a polymerizable composition comprising, as a component A, at least one silicon-organic compound having at least two ?Si—H groups that are reactive in the hydrosilylation reaction and, as a component B, at least one benzoxazine compound having at least two unsaturated carbon-carbon bonds that are reactive in the hydrosilylation reaction with the component A. Additional objects of the present invention include adhesives, sealants or coatings containing the polymerizable composition according to the invention, and the polymerization products of said components.
    Type: Grant
    Filed: January 10, 2011
    Date of Patent: March 27, 2012
    Assignee: Henkel AG & Co. KGaA
    Inventors: Andreas Taden, Stefan Kreiling, Rainer Schoenfeld, Yusuf Yagci, Baris Kiskan, Aydogan Binnur
  • Patent number: 8143362
    Abstract: The invention relates to a curable composition comprising addition curable silicone component (A) having a linear siloxane backbone at least one unsaturated, non-activated side group pendant from the Si atom or atoms in the backbone, component (A) having an equivalent weight in the range of about 68 to about 1000, crosslinker component (B) comprising at least 2 SiH groups, catalyst component (C) being able to catalyse the reaction between component (A) and component (B), filler component (D), wherein the equivalent weight is defined as (molecular weight of the molecule)/(number of unsaturations in the molecule).
    Type: Grant
    Filed: September 3, 2010
    Date of Patent: March 27, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Peter Bissinger, Joachim W. Zech
  • Patent number: 8143359
    Abstract: The purpose of the present invention is to provide an organic silicon compound which has a vinyl group more reactive than those of the conventional organic silicon compounds and can be bonded with another compound. The present organic silicon compound is represented by the following formula (1), wherein R1 is, independently of each other, a vinyl group or an alkyl group having 1 to 4 carbon atoms, R2 is an alkylene group having 3 to 6 carbon atoms, and R3 is, independently of each other, a hydrogen atom or an alkyl group having 1 to 4 carbon atoms and optionally substituted with one or more fluorine atoms.
    Type: Grant
    Filed: November 18, 2009
    Date of Patent: March 27, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Noriyuki Koike, Takashi Matsuda, Hirofumi Kishita
  • Patent number: 8133315
    Abstract: Described is a consolidant comprising a hydrolyzate or precondensate of at least one organosilane and at least one metal compound, where the molar ratio of silicon compounds to metal compounds is in the range of from 10 000:1 to 10:1. The consolidant can be used for the hydrolysis-stable consolidation of porous or particulate materials to form moldings. The consolidant can be used for the hydrolysis-stable coating of substrates.
    Type: Grant
    Filed: January 19, 2006
    Date of Patent: March 13, 2012
    Assignee: Leibniz-Institut fuer Neue Materialien Gemeinnuetzige GmbH
    Inventors: Klaus Endres, Bernd Reinhard, Helmut Schmidt
  • Publication number: 20120058333
    Abstract: An organo polysiloxane to improve the abrasion and weather resistance of a hard coating layer obtained from a silicone-type hard coating composition. The hard coating composition contains a first organo polysiloxane having silicone-containing bond units selected from the group consisting of R—Si(—OX)2(—O*—), R—Si(—OX)(—O*—)2 and R—Si(—O*—)3) and a second organo polysiloxane having the same, where the second organo polysiloxane has a weight average molecular weight of 1/10 to 1/1.5 times that of the first organo polysiloxane. Further, a resin substrate having a hard coating layer made of a cured product of the hard coating composition that has improved abrasion and weather resistance. For resin substrates used in a bent state, the hard coating layer also improves the cracking resistance associated with mechanical stress.
    Type: Application
    Filed: September 22, 2011
    Publication date: March 8, 2012
    Applicant: Asahi Glass Company, Limited
    Inventors: Kyoko Yamamoto, Takashi Shibuya, Tatsuya Miyajima
  • Patent number: 8124710
    Abstract: MQ-T propyl siloxane resins comprising (R13SiO1/2)a, (R22SiO2/2)b, (R3SiO3/2)c, and (SiO4/2)d units, where at least 40 mole % of the R3 groups are propyl are disclosed. A method of preparing such siloxane resins by reacting a MQ siloxane resin with a T propyl siloxane resin is also disclosed. These siloxane resins are useful in a variety of personal, household, and medical care applications, and in particular, as a resin additive in pigmented cosmetic formulations.
    Type: Grant
    Filed: January 20, 2005
    Date of Patent: February 28, 2012
    Assignee: Dow Corning Corporation
    Inventors: Julie Lyn Cook, Daniel Michael Hinterman, Lori Ann Stark-Kasley, Gary Michael Wieber
  • Patent number: 8119758
    Abstract: Provided is a heat-conductive silicone composition, including: (A) 100 parts by volume of an organopolysiloxane having a specific structure, (B) 0.1 to 50 parts by volume of an organosilicon compound that functions as a wetter and contains a triorganooxysilyl group bonded to one terminal via an alkylene group that may be branched, (C) 100 to 2,500 parts by volume of a heat-conductive filler, and (D) an effective quantity of a curing agent. Also provided is a heat-conductive silicone cured product obtained by curing this composition. The heat-conductive silicone composition, even when filled with a large quantity of a heat-conductive filler in order to provide superior thermal conductivity, exhibits a minimal increase in viscosity or plasticity, and retains favorable handling properties and moldability. The heat-conductive silicone cured product exhibits excellent flexibility even when filled with a large quantity of a heat-conductive filler.
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: February 21, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Ikuo Sakurai, Nobuaki Matsumoto, Kei Miyoshi, Kunihiro Yamada
  • Patent number: 8114950
    Abstract: Long chain ?-ketocarbonyl-functional organosilicon waxes are easily synthesized from organosilicon compounds bearing a reactive hydrogen bonded to N, O, or S, with a diketene. The products remain silicone-like despite being waxy, and can be used to gel low viscosity silicones to creamy formulations useful in cosmetics.
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: February 14, 2012
    Assignee: Wacker Chemie AG
    Inventor: Christian Herzig
  • Patent number: 8097639
    Abstract: Disclosed herein is a surface functionalized poly(dimethylsiloxane) (PDMS) and methods for making the same. The surface functionalized PDMS disclosed herein is applicable in the general field of microfluidics, bioMEMS (bio-microelectromechanical systems), soft lithography, and other related biotechnology fields.
    Type: Grant
    Filed: August 29, 2008
    Date of Patent: January 17, 2012
    Assignee: Peking University
    Inventors: Hongwei Ma, Long Fu
  • Patent number: 8088547
    Abstract: A resist composition comprising (A) a hydrogen silsesquioxane resin, (B) an acid dissociable group-containing compound, (C) a photo-acid generator, (D) an organic solvent and optionally (E) additives. The resist composition has improved lithographic properties (such as high etch-resistance, transparency, resolution, sensitivity, focus latitude, line edge roughness, and adhesion) suitable as a photoresist.
    Type: Grant
    Filed: September 20, 2005
    Date of Patent: January 3, 2012
    Assignee: Dow Corning Corporation
    Inventors: Sanlin Hu, Sina Maghsoodi, Eric Scott Moyer, Sheng Wang
  • Publication number: 20110313123
    Abstract: The present invention provides a silicone resin lens obtained by molding and curing a silicon resin composition into a lens, wherein the lens has a refractive index at 400 nm of 1.5 or more, a ratio of a refractive index at 400 nm to a refractive index at 596 nm of 1.01 or more, an Abbe's number of 45 or more, and an absolute value of a differential of refractive indexes against temperatures, dn/dT, of 250×10?6/degrees C. or less. Further, the present invention provides a method for preparing the silicone resin lens according to any one of claims 1 to 4, wherein the silicone resin lens is prepared in conditions where a ratio of a molding shrinkage ratio found after subjecting the silicone resin composition to post-cure to a molding shrinkage ratio found after subjecting the silicone resin composition to molding is 0.8 to 1.2.
    Type: Application
    Filed: June 21, 2011
    Publication date: December 22, 2011
    Inventor: Tsutomu KASHIWAGI
  • Patent number: 8080614
    Abstract: A curable organopolysiloxane composition comprises at least the following components: an organopolysiloxane (A) represented by the following general formula: R13SiO(R12SiO)mSiR13 (where R1 is a monovalent hydrocarbon group, and “m” is an integer from 0 to 100); an organopolysiloxane (B) represented by the following average unit formula: (R2SiO3/2)a(R22SiO2/2)b(R23SiO1/2)c (where R2 is a monovalent hydrocarbon group, and “a”, “b”, and “c” are specific numbers); an organopolysiloxane (C) having in one molecule on average at least two silicon-bonded aryl groups and on average at least two silicon-bonded hydrogen atoms; and a hydrosilylation-reaction catalyst (D); is characterized by good fillability and curability and that, when cured, forms a cured body that possesses a high refractive index, high light transmissivity, and strong adhesion to various substrates.
    Type: Grant
    Filed: June 18, 2007
    Date of Patent: December 20, 2011
    Assignee: Dow Corning Toray Company, Ltd.
    Inventors: Yoshitsugu Morita, Masayoshi Terada, Hiroji Enami, Makoto Yoshitake
  • Patent number: 8076438
    Abstract: Organopolysiloxanes are prepared in a multistage process by a first partial hydrolysis with from 0.002 to 0.6 mol water per hydrolyzable chlorine and alcohol at a water to alcohol ratio of 0.001 to 1.5, then further hydrolyzing with additional water, and then separating an aqueous alcoholic phase from an organopolysiloxane phase.
    Type: Grant
    Filed: September 8, 2006
    Date of Patent: December 13, 2011
    Assignee: Wacker Chemie AG
    Inventor: Hartmut Ackermann
  • Patent number: 8076437
    Abstract: A light-emitting device is provided which uses an encapsulant material made from a polymer having a high relative light output. The light-emitting device includes a light-emitting element and a member sealing the light-emitting element. The encapsulant material has one or more than two kinds of units given by the following formula (1) and a refractive index of 1.55 or more. where R is a hydrogen atom, alkyl group or phenyl group, Y is an alkyl group of which the carbon number is 1 to 6 or an alkyloxy group of which the carbon number is 1 to 6 and Z is an aromatic compound that meets predetermined requirements.
    Type: Grant
    Filed: June 9, 2008
    Date of Patent: December 13, 2011
    Assignee: Sony Chemical & Information Device Corporation
    Inventors: Kouki Hatsuda, Hiroshi Samukawa, Katsuhiko Komuro
  • Patent number: 8063137
    Abstract: Described is a method for producing a molded silicone rubber product using a liquid silicone rubber (LSR) base comprising at least one vinyl siloxane polymer, at least one hydride crosslinker, and optionally at least one injection molding inhibitor. The single LSR base is fed into a feed line, and into the feed line are fed an inhibitor master batch comprising at least one liquid injection molding inhibitor and at least one vinyl siloxane polymer, and a catalyst master batch comprising at least one catalyst and at least one vinyl siloxane polymer. The invention is further directed to: said LSR base; said inhibitor master batch; said catalyst master batch; and a molded silicone rubber article produced by the methods and compositions described herein.
    Type: Grant
    Filed: July 29, 2009
    Date of Patent: November 22, 2011
    Assignee: BlueStar Silicones France
    Inventors: Edward Jeram, Reeshemah Beaty Chatham, Robert Higley
  • Publication number: 20110282022
    Abstract: The present discovery shows how to make a self-crosslinking SMP. Shape Memory Polymer (SMP) can be formulated as a castable coating. This process allows the polymer to dissolve in solvent, and as the solvent evaporates the polymers self-crosslink at room temperature in air, creating a copolymer coating wherein the copolymer coating is an SMP. This technology has coating applications where shape memory would be an asset: from shape memory textile and fabric to self-healing coatings for vehicles and morphing skins for aircraft.
    Type: Application
    Filed: May 28, 2009
    Publication date: November 17, 2011
    Applicant: Cornerstone Research Group, Inc.
    Inventor: Tat Hung Tong
  • Patent number: 8039517
    Abstract: A method of preparing an organic sol of particles is provided. Steps include: a) providing a suspension of particles in an aqueous medium; b) adding an organic liquid to form an admixture where the concentration of particles in the admixture is less than or equal to 40 percent by weight; c) maintaining the admixture at a temperature and pressure and for a time sufficient to reduce the water content to less than 30 percent by weight while simultaneously adding a water-compatible organic liquid at a rate sufficient to maintain a concentration of particles in the admixture at less than or equal to 50 percent by weight; and d) adding at least one polymer while maintaining the admixture at a temperature and pressure and for a time sufficient to provide an organic sol of particles comprising 1 percent by weight or less of water.
    Type: Grant
    Filed: December 1, 2004
    Date of Patent: October 18, 2011
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Lawrence G. Anderson, Debra L. Singer, Thomas R. Hockswender
  • Publication number: 20110251369
    Abstract: Disclosed are a polysilsesquioxane having a ladder structure with photoactive groups bonded at the siloxane main chain, and a method for preparing the same. Polysilsesquioxanes exhibiting superior thermal and mechanical properties and having various functionalities and characteristics depending on the photoactive groups introduced thereto may be prepared via a relatively simple method. The polysilsesquioxanes may be useful as an industrial material for organic-inorganic hybrid materials.
    Type: Application
    Filed: August 6, 2010
    Publication date: October 13, 2011
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Seung Sang HWANG, Kyung Youl BAEK, Seung-Sock CHOI, He Seung LEE, Albert S. LEE, Sungyoun OH
  • Publication number: 20110250105
    Abstract: The present invention relates to a serum or plasma separating material including a moisture curing component having a specific gravity of from 1.03 to 1.09, and a blood collection tube including the serum or plasma separating material. The present invention provides a serum or plasma separating material which is allowed to be present in a cured state between serum or plasma and a blood cell-containing component obtained after centrifugal separation when separating the serum or plasma component in a collection tube, exhibits a good storage stability capable of keeping the serum or the like and the cell-containing component in a separated state in the collection tube for a long period of time, is excellent in stability upon freezing or thawing and upon handling of a sample, and can be cured without need of irradiation with ultraviolet ray or the like, as well as a method of separating serum or plasma using the separating material.
    Type: Application
    Filed: November 9, 2009
    Publication date: October 13, 2011
    Inventors: Kunihiro Suto, Yasushi Kojima
  • Patent number: 8034889
    Abstract: The present invention relates to a resin for optical-semiconductor-element encapsulation obtained by reacting a silicon compound with a boron compound or an aluminum compound, wherein the silicon compound is represented by the following formula (I): wherein R1 and R2 each independently represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, or an aryl group, in which a plurality of R1's are the same or different and a plurality of R2's are the same or different; X represents a hydroxy group, an alkoxy group, an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, or an aryl group; and n is 4 to 250, and an optical semiconductor device obtained with the resin.
    Type: Grant
    Filed: November 25, 2008
    Date of Patent: October 11, 2011
    Assignee: Nitto Denko Corporation
    Inventors: Hiroyuki Katayama, Asami Kubo
  • Publication number: 20110238163
    Abstract: There is provided a device comprising a body structure having one or more surfaces wherein at least one of the surfaces comprises a pH sensitive layer comprising a linear polymer, wherein the water solubility of the linear polymer increases from a first water solubility to a second water solubility at a pH trigger. A method of forming a device, and a method of preventing or mitigating infection is also described.
    Type: Application
    Filed: March 8, 2011
    Publication date: September 29, 2011
    Applicant: LABORATORIOS FARMACEUTICOS ROVI S.A.
    Inventors: GAVIN Paul ANDREWS, DAVID Simon JONES, SEAN Patrick GORMAN
  • Patent number: 8026328
    Abstract: A method of preparing hydrophobic silica particles includes the step of reacting together in a single step a mixture of silane ether monomers and organically modified silane ether monomers with a hydrolyzing agent. The method also includes producing hydrophobic silica microparticles and nanoparticles that can include dyes and/or magnetizable components. The silica nanoparticles can be used in the detection, visualization and/or analysis of latent fingerprints.
    Type: Grant
    Filed: August 9, 2006
    Date of Patent: September 27, 2011
    Assignee: University of Sunderland
    Inventor: Frederick John Rowell
  • Patent number: 8026332
    Abstract: A sealing material for optical elements with excellent transparency, crack resistance, and heat resistance which can produce a cured product of the sealing material and a sealed optical element are provided.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: September 27, 2011
    Assignee: Lintec Corporation
    Inventors: Mikihiro Kashio, Toshio Sugizaki, Osamu Moriya
  • Patent number: 8017712
    Abstract: The present invention relates generally to a novel process for making a solid solventless MQ resin comprising the steps of (1)(A) feeding at least one MQ resin dispersed in a volatile solvent into an extrusion device, (2) removing the volatile solvent to form a solid solventless MQ resin; and (3) recovering the solid solventless MQ resin, provided steps (1) to (3) are completed without the addition of a linear silicone fluid.
    Type: Grant
    Filed: May 16, 2007
    Date of Patent: September 13, 2011
    Assignee: Dow Corning Corporation
    Inventors: Vicki Lynn Berry, Leon Neal Cook, Tina Marie Leaym, Randall Gene Schmidt
  • Publication number: 20110218313
    Abstract: A method for producing polymer particles, including (A) polymerizing and granulating a ring-opening polymerizable monomer in a compressive fluid with a catalyst in the presence of a surfactant, or (B) polymerizing and granulating an addition polymerizable monomer in a compressive fluid in the presence of a silicone surfactant.
    Type: Application
    Filed: March 4, 2011
    Publication date: September 8, 2011
    Inventors: Nobuyuki MASE, Takeshi Sako, Idzumi Okajima, Shunsuke Mori, Keishi Mizuno, Yoshitaka Yamauchi, Taichi Nemoto, Chiaki Tanaka, Satoyuki Sekiguchi, Jyun Ishiduka
  • Patent number: 8012578
    Abstract: The present invention relates to a process for the preparation of composites from thermoplastic polymers and (semi)metal oxides, in particular silicon dioxide, wherein at least a part of the (semi)metal oxides is dispersed in the polymers in nanodispersed manner (nanocomposites). The invention relates to the composites obtainable by this process and their processing to give molded articles.
    Type: Grant
    Filed: September 4, 2006
    Date of Patent: September 6, 2011
    Assignee: Deutsches Wollforschungsinstitut an der RWTH Aachen e.V.
    Inventors: Susanne Spiegelberg, Armin Alteheld, Xiaomin Zhu, Karin Peter, Martin Möller