With At Least One Nonepoxy Or Nonphenolic Reactant Patents (Class 528/106)
  • Publication number: 20030114631
    Abstract: A reaction product of a polymer containing at least one cross-linkable functional group, a crosslinking agent, and a softener, and processes for preparing and using the same. Cellulosic products comprising the reaction product and processes for preparing the same.
    Type: Application
    Filed: March 1, 2002
    Publication date: June 19, 2003
    Inventors: Cynthia D. Walton, Joseph F. Warchol
  • Patent number: 6566423
    Abstract: Novel cold-curing mixtures comprising epoxide compounds, curing agents, additives and optionally further auxiliary and filler materials, which have low irritant potential, which are free of solvents and are self-levelling and which, in the cured state, are colorfast and have a surface which, in terms of optical and tactile properties, is faultless.
    Type: Grant
    Filed: November 29, 2001
    Date of Patent: May 20, 2003
    Assignee: Bakelite AG
    Inventors: Markus Schrötz, Martin Fulgraff, Peter Martischewski, Jürgen Schillgalies, Rolf Herzog
  • Patent number: 6558797
    Abstract: An adhesive-coated copper foil which comprises a copper foil and disposed on one side thereof a layer of an adhesive composition comprising (a) an epoxy resin, (b) a polyfunctional phenol, (c) a curing accelerator as an optional ingredient, and (d) a compound having a triazine ring or isocyanuric ring. The adhesive layer has low hygroscopicity, excellent heat resistance, and satisfactory adhesion to copper foils. By using the adhesive-coated copper foil, a copper-clad laminate and a printed circuit board both having excellent properties can be obtained.
    Type: Grant
    Filed: June 22, 2001
    Date of Patent: May 6, 2003
    Assignee: Hitachi Chemical Company, Ltd.
    Inventors: Michitoshi Arata, Nozomu Takano, Kazuhito Kobayashi
  • Publication number: 20030036623
    Abstract: A lightfast epoxy resin is formed by phosgenating Bisphenol A by reaction with phosgene to produce Bisphenol A bischloroformate. The Bisphenol A bischloroformate is then reacted with either epichlorohydrin, glycidol or pinacol and another chemical to produce a lightfast epoxy resin. By phosgenating the Bisphenol A prior to the reaction with either epichlorohydrin, glycidol or pinacol and another chemical, the resulting epoxy resin has improved lightfastness and is not degraded by sunlight. The epoxy resin of the present invention can be used in paints, coatings, and plastics for vehicles.
    Type: Application
    Filed: August 14, 2002
    Publication date: February 20, 2003
    Inventor: Ellis Breskman
  • Publication number: 20030013836
    Abstract: According to the present invention, a resin composition having a high refractive index and low dispersion characteristics is provided. THE resin composition comprises a carbonate residue, a phosphonic acid residue represented by the following structural formula (1), and a dihydric phenol residue represented by the following structural formula (2), wherein the mol fractions of the phosphonic acid residue and the carbonate residue satisfy equation (3).
    Type: Application
    Filed: May 20, 2002
    Publication date: January 16, 2003
    Inventors: Keijiro Takanishi, Takuya Kumagai, Ryouichi Ishinabe
  • Patent number: 6506868
    Abstract: The present invention provides a partial condensate of glycidyl ether group-containing alkoxysilane which is obtainable by dealcoholization reaction between glycidol and a partial condensate of alkoxysilane, compositions comprising the same and preparation methods thereof. Further, the present invention provides an alkoxy-containing silane-modified polyimide resin, alkoxy-containing silane-modified polyamide-imide resin and alkoxy-containing silane-modified phenol resin which are modified with the partial condensate of glycidyl ether group-containing alkoxysilane, and preparation methods thereof.
    Type: Grant
    Filed: March 7, 2001
    Date of Patent: January 14, 2003
    Assignee: Arakawa Chemical Industries, Ltd.
    Inventors: Hideki Goda, Shoji Takeda, Tetsuji Higashino
  • Patent number: 6441106
    Abstract: The present invention provides a curing agent for epoxy resin containing a siloxane-modified phenol resin (3) obtained by dealcoholization condensation reaction between a phenol resin (1) and a hydrolyzable alkoxysilane (2). The present invention further provides an epoxy resin composition comprising an epoxy resin and the above-mentioned curing agent for epoxy resin. The present invention further provides a method for preparing a siloxane-modified phenol resin (3) characterized by subjecting a phenol resin (1) and a hydrolyzable alkoxysilane (2) to dealcoholization condensation reaction.
    Type: Grant
    Filed: September 12, 2000
    Date of Patent: August 27, 2002
    Assignee: Arakawa Chemical Industries, Ltd.
    Inventors: Hideki Goda, Shoji Takeda
  • Publication number: 20020111459
    Abstract: A polymer comprising recurring units of formula (2) is prepared by effecting deblocking reaction on a polymer comprising recurring units of formula (1) in the presence of an acid catalyst.
    Type: Application
    Filed: December 6, 2001
    Publication date: August 15, 2002
    Applicant: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takanobu Takeda, Osamu Watanabe
  • Patent number: 6388044
    Abstract: The present invention provides a thermosetting polyether resin obtained by polycondensing a dihalogen compound with a bisphenol compound to obtain a polyether resin having a repeating unit represented by the formula (1), and introducing a functional group which causes a cross-linking reaction by heating into the resulted polyether resin; The present invention also provides a polyether resin having a low dielectric constant represented by the formula (3):
    Type: Grant
    Filed: September 7, 2000
    Date of Patent: May 14, 2002
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Yuji Yoshida, Akira Yokota, Sadanobu Iwase, Hyuncheol Choi
  • Patent number: 6369183
    Abstract: A composition of matter, comprising: a chemically functionalized carboxylate-alumoxane that is functionalized with a chemically reactive substituent, and a reactive compound, wherein the chemically reactive substituent reacts with the reactive compound so as to link the carboxylate-alumoxane to the reactive compound and form a polymer matrix. The functional groups on the carboxylate-alumoxane can vary depending on the desired properties of the matrix. Also, the composition of matter may comprise a cross-linked matrix in which the cross-linked components consist of functionalized alumoxanes.
    Type: Grant
    Filed: August 13, 1998
    Date of Patent: April 9, 2002
    Assignee: Wm. Marsh Rice University
    Inventors: Ronald Lee Cook, Andrew Ross Barron, Kevin Joseph Gleason, David Brent MacQueen, Georgette Laila Siparsky, Yoshihiro Koide, Cullen Taylor Vogelson
  • Patent number: 6361879
    Abstract: A sealed semiconductor chip having a surface film of a sealed resin composition, wherein the resin composition has a linear expansion coefficient of 60×10−6/K or less at a temperature equal to or less than its glass transition point and 140×10−6/K or less at a temperature equal to or higher than its glass transition point; a semiconductor-sealing resin composition for sealing a semiconductor chip, which has a linear expansion coefficient of 60×10−6/K or less at a temperature equal to or less than its glass transition point and 140×10−6/K or less at a temperature equal to or higher than its glass transition point; the sealed semiconductor chip is chip size and has high reliability; the semiconductor-sealing resin composition creates a good seal on chip wafers and has high reliability; and the chip wafers sealed with a surface film of the resin composition warp little.
    Type: Grant
    Filed: September 23, 1999
    Date of Patent: March 26, 2002
    Assignees: Toray Industries, Inc., Fujitsu Limited
    Inventors: Yasuaki Tsutsumi, Masayuki Tanaka, Toshimi Kawahara, Yukio Takigawa
  • Patent number: 6329489
    Abstract: The invention is directed to a process for making a reactive silane oligomer having low polydispersity, viscosity and volatility. The process utilizes reacting unsymmetrical difunctional silane monomers with water, diol monomers, or a combination thereof to make the reactive silane oligomer. The unsymmetrical difunctional silane monomers are with silane reactive groups having significantly different reactivities. Use of such reactive silane oligomers results in multi-component coating compositions having high miscibility, low VOC, low viscosity and high percentage of solids.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: December 11, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Basil V. Gregorovich, Isidor Hazan, Robert R. Matheson, Lech Wilczek
  • Patent number: 6320020
    Abstract: A sulfur-containing (thio)ether (co)polymer comprising repetitive structural units represented by general formulas 1 and 2, and an optical element using the (co)polymer: where A and B are bivalent organic group; R1 and R2 are hydrogen or alkyl; X1 to X4 are oxygen or sulfur; Y1 and Y2 are halogen, hydroxy, —OR3 or —SR4, in which R3 is sulfur-containing alkyl, aryl, heterocycle or acyl optionally having a substituent other than SH; and R4 is alkyl, aryl, heterocycle or acyl; provided that —OR3 and/or —SR4 constitute 10 to 100% of the total of Y1+Y2. The (co)polymer exhibits good optical, mechanical and thermal properties and a higher refractive index, and may be prepared in a good productivity. The sulfur-containing (thio)ether (co)polymer is useful for manufacturing a variety of optical elements.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: November 20, 2001
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Keisuke Takuma, Kenichi Sugimoto, Atsuo Otsuji, Rihoko Suzuki, Kenichi Fujii, Masao Imai
  • Patent number: 6291077
    Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.
    Type: Grant
    Filed: August 28, 2000
    Date of Patent: September 18, 2001
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
  • Patent number: 6197916
    Abstract: A method for preparing bisphenol A is disclosed, with a selectivity for the p,p′-isomer of greater than about 97%. The method involves reacting phenol with p-isopropenylphenol or 2-(4-hydroxyphenyl)-2-propanol in the presence of a catalyst, at a reaction temperature of no greater than about 65° C. The bisphenol A product is preferably purified by a technique which omits the use of adduct crystallization.
    Type: Grant
    Filed: August 30, 1999
    Date of Patent: March 6, 2001
    Assignee: General Electric Company
    Inventors: Eric James Pressman, Joseph Richard Wetzel
  • Patent number: 6166151
    Abstract: A lactone chain-extended polyester polyol of the present invention comprises the reaction product of a lactone and a previously chain-extended phenolic-based hydroxyl compound. The previously chain-extended phenolic-based hydroxyl compound may comprise the reaction product of (i) a lactone or an alkoxylating agent selected from the group consisting of alkylene oxides and alkylene carbonates, and (ii) a phenolic aralkylation polymer comprising the reaction product of a phenolic monomer having at least two free reactive positions; a styrene derivative; and a coupling agent. The previously chain-extended phenolic-based hydroxyl compound also may be chain-extended by reacting with a lactam to produce a lactam chain-extended polyester polyamide. The polyols and polyamides of the present invention provide unique combinations of hard and soft functionalities, which translates into materials exhibiting a unique combination of toughness and hardness.
    Type: Grant
    Filed: June 22, 1999
    Date of Patent: December 26, 2000
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: Rajan Hariharan, David A. Hutchings, Kenneth A. Bourlier, Ellen V. Nagy
  • Patent number: 6127491
    Abstract: Phenolic resin polyols are disclosed. The polyols, which contain aliphatic or mixed phenolic and aliphatic hydroxyl groups, are the reaction products of aralkylated phenols or phenol aralkylation polymers with an oxyalkylating agent selected from alkylene oxides and alkylene carbonates. The phenolic resin polyols are versatile intermediates for many polymer systems, including urethanes, epoxies, alkyds, acrylates, and polyesters.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: October 3, 2000
    Assignee: Gerorgia-Pacific Resins, Inc.
    Inventors: David C. Dehm, David A. Hutchings, Alan K. Randall, Mark A. Peters
  • Patent number: 6124401
    Abstract: This invention provides for a coating composition comprising: (A) at least one polymeric material selected from (i) at least one homopolymer of ethylene having a melt index of at least about 220 grams per ten minutes as determined by ASTM D1238, condition 190/2.16, or (ii) at least one copolymer of ethylene and a second ethylenically unsaturated monomer having a melt index of at least about 20 grams per ten minutes as determined by ASTM D1238, condition 190/2.16, or (iii) at least one thermoplastic acrylic homopolymer or copolymer having a glass transition temperature (Tg) of greater than 0.degree. C. but less than 110.degree. C., or (iv) a mixture of (i), (ii) and/or (iii); and (B) at least one thermoplastic polymeric material different than (A) having a melting point in the range of about 80.degree. C. to about 130.degree. C.
    Type: Grant
    Filed: April 5, 1993
    Date of Patent: September 26, 2000
    Assignee: Ferro Corporation
    Inventors: Donald P. Hart, Jr., Robert C. Stroup
  • Patent number: 6120905
    Abstract: This invention relates to a hybrid nonisocyanate polyurethane network polymer formed by cross-linking at least one cyclocarbonate oligomer and at least one amine oligomer. The cyclocarbonate oligomer contains a plurality of terminal cyclocarbonate groups. At least one cyclocarbonate oligomer further comprises from about 4% to about 12% by weight of terminal epoxy groups. Because at least one cyclocarbonate oligomer contains both cyclocarbonate and epoxy reactive groups, the network formed therefrom is referred to as a hybrid nonisocyanate polyurethane network. The cyclocarbonate oligomer or oligomers have an average functionality towards primary amines of from about 2.0 to about 5.44. The amine oligomer comprises at least one primary amine-terminated oligomer terminated with primary amine groups and has an average functionality towards cyclocarbonate groups of from about 3.0 to about 3.8. The amine oligomer is present in an amount from about 0.93 to about 0.
    Type: Grant
    Filed: June 15, 1998
    Date of Patent: September 19, 2000
    Assignee: Eurotech, Ltd.
    Inventor: Oleg L. Figovsky
  • Patent number: 5945500
    Abstract: Methods for preparing low free resorcinol resins are disclosed. These methods generally comprise reacting a resin with an aromatic olefinic compound; suitable resins include one or more resins selected from the group consisting of a dihydric phenol, a polyhydric phenol, a dihydric phenolic novolak resin and a polyhydric phenolic novolak resin; the addition product of at least one of these resins and at least one compound selected from the group consisting of a monooxirane compound and a polyoxirane compound; and a phenol or alkyl or aralkyl substituted mono- or dihydric phenol modified form of these resins. The resins produced by this method are also disclosed, as are rubber compositions utilizing the resin produced by this method.
    Type: Grant
    Filed: August 6, 1998
    Date of Patent: August 31, 1999
    Assignee: Indspec Chemical Corp.
    Inventors: Raj B. Durairaj, Alex Peterson, Jr.
  • Patent number: 5936056
    Abstract: Methods for preparing low free resorcinol resins are disclosed. These methods generally comprise reacting a resin with an aromatic olefinic compound; suitable resins include one or more resins selected from the group consisting of a dihydric phenol, a polyhydric phenol, a dihydric phenolic novolak resin and a polyhydric phenolic novolak resin; the addition product of at least one of these resins and at least one compound selected from the group consisting of a monooxirane compound and a polyoxirane compound; and a phenol or alkyl or aralkyl substituted mono- or dihydric phenol modified form of these resins. The resins produced by this method are also disclosed, as are rubber compositions utilizing the resin produced by this method.
    Type: Grant
    Filed: March 7, 1997
    Date of Patent: August 10, 1999
    Assignee: Indspec Chemical Corporation
    Inventors: Raj B. Durairaj, Alex Peterson, Jr.
  • Patent number: 5874501
    Abstract: The present invention relates to a novel oxirane pre-polymer comprised of the catalyzed or uncatalyzed reaction product of phenyl intermediates with a difunctional oxirane oligomer having at least one aromatic moiety and at least one aliphatic moiety, characterized in that substantially hydrolyzable oxygen atoms in said phenyl are bonded to said oligomers, and there is substantially no bonding between oligomer moieties. In a particularly preferred embodiment the present invention relates to a novel oxirane prepolymer comprising the reaction product of a phenyl intermediate with an inorganic oxide having at least one hydrolyzable oxygen and a difunctional oxirane oligomer aliphatic moiety characterized in that a majority of all hydrolyzable oxygen atoms in said oxide are bonded to at least one of the phenyl groups of the intermediate phenyl and one phenyl group is bonded to said oligomer and there is substantially no bonding between oligomer moieties.
    Type: Grant
    Filed: August 18, 1997
    Date of Patent: February 23, 1999
    Inventor: Donald J. Keehan
  • Patent number: 5844063
    Abstract: The present invention relates to a resinous copolymer comprising monomer units of each of the groups of phenol compounds (I) and olefinically unsaturated non-acid terpene compounds (II), characterized in that the copolymer contains monomer units from the group of polyunsaturated olefin compounds (III), the monomer units of compound (III) being 1 to 70% by weight of the total of the monomer units of compounds (II) and (III), the monomer units of compounds (II) and (III) being at least 50% by weight of the total of monomer units of compounds (I), (II) and (III). The melting point of the copolymer is at least 130.degree. C. The copolymers are particularly useful in printing ink formulations.
    Type: Grant
    Filed: October 20, 1997
    Date of Patent: December 1, 1998
    Assignee: Arizona Chemical, S.A.
    Inventors: Jacques Salvetat, Ronald Wind
  • Patent number: 5821318
    Abstract: A composition which consists essentially of the following components:A1) polyamines of formula (I) and/or (II) ##STR1## wherein R.sub.1 and R.sub.2 are each independently of the other a hydrogen atom or a methyl x is an integer from 1 to 3, and y is an integer from 0 to 2, the sum of x and y being up to and including 4, and z is an integer from 0 to 2; orA2) a mixture of polyamines of formula (I) and/or (II) with further polyamines; B) an aliphatic, cycloaliphatic or araliphatic alcohol or a mixture of corresponding alcohols; and C) an alkyl- and/or aralkyl-substituted monophenol or a mixture of corresponding monophenols, component C) constituting 20 to 50 percent of the total weight of the cited components. The compositions are useful as hardeners for epoxy resins to give cured material of particularly good resistance to chemicals.
    Type: Grant
    Filed: January 6, 1997
    Date of Patent: October 13, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Walter Fischer
  • Patent number: 5776374
    Abstract: The present invention relates to crosslinkable thermoplastic compositions comprising a plurality of crosslinkable moieties, capable of undergoing addition polymerization, incorporated by functionalization of the precursor poly(hydroxy ethers). The poly(hydroxy ethers) comprise recurring moieties derived from aromatic dihydroxy compounds. The crosslinkable polymeric compositions are crosslinked to obtain crosslinked thermoset polymeric compositions of the invention. The polymeric compositions of the inventions can be suitably used either as an active guiding layer, and/or as a NLO active upper and lower cladding layers in an electro-optic device. The polymeric compositions can also be used as non-NLO polymers for the upper and lower cladding layers, prior to orientation by the application of an electric field.
    Type: Grant
    Filed: November 7, 1995
    Date of Patent: July 7, 1998
    Assignee: The Dow Chemical Company
    Inventors: Mark D. Newsham, Michael N. Mang, Robert J. Gulotty, Jr., Dennis W. Smith, Jr.
  • Patent number: 5710234
    Abstract: Ortho spiroesters of excellent heat resistance and low volume shrinkage during curing are disclosed. Resin compositions of excellent heat resistance and low curing shrinkage containing these ortho spiroesters are also provided. These photosensitive or heat-curable resin compositions are formulated from photo- or heat-polymerizable compounds containing ethylenic double bonds and carboxyl groups, photopolymerization initiators and sensitizers, or polymerization initiators which generate radicals by heat, and said ortho spiroesters. These resin compositions have low curing shrinkage and are useful for applications requiring dimensional accuracy such as molding materials, encapsulants, adhesives and coatings and also for the preparation of image-forming materials such as protective films for color filters, inks and electrically insulating spacers for touch panels.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: January 20, 1998
    Assignees: Nippon Steel Chemical Co., Ltd., Nippon Steel Corporation
    Inventors: Koichi Fujishiro, Masaya Furukawa, Kazuhiro Watanabe, Takero Teramoto
  • Patent number: 5708059
    Abstract: A stable, aqueous epoxy resin dispersion including: (A) an epoxy resin prepared by condensation of at least one epoxide compound having on average at least two epoxide groups per molecule, with an aralkylated polyhydroxy aromatic compound obtained by reaction of a polyhydroxy aromatic compound with an aromatic compound which carries an alkenyl group; (B) a dispersant; and water, is useful, for example, in a coating or adhesive.
    Type: Grant
    Filed: February 11, 1997
    Date of Patent: January 13, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Armin Pfeil, Michael Hoenel, Uwe Neumann
  • Patent number: 5696212
    Abstract: In a method for curing a resin by utilizing an intramolecular crosslinking reaction, the improvement wherein the crosslinking reaction is a ring opening addition reaction between a lactone structure and an active hydrogen-containing functional group.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: December 9, 1997
    Assignee: Kansai Paint Co., Ltd.
    Inventor: Osamu Isozaki
  • Patent number: 5693739
    Abstract: A cationic final rinse metal treatment composition comprises a water soluble or water dispersible phenolic polymer which is the reaction product of: an amino phenol and either an anhydride-containing polymer or a di-epoxide, said polymer including a group imparting cationic functionality to the polymer.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: December 2, 1997
    Assignee: PPG Industries, Inc.
    Inventors: Edward E. McEntire, Richard M. Nugent, Jr., Ralph C. Gray
  • Patent number: 5688877
    Abstract: A method of preparing epoxy parts wherein the interval of low viscosity of an amine-hardened epoxy system can be extended without sacrifice of cure time. Suitable catalysts for the epoxy-amine hardener reaction are generated in situ. As an advantage, more epoxy articles may be prepared with a given mold capacity having improved wet-out of fiber reinforcement attributed to a larger interval of low viscosity.
    Type: Grant
    Filed: June 11, 1996
    Date of Patent: November 18, 1997
    Assignee: The Dow Chemical Company
    Inventors: Raymond A. Koenig, Joseph Gan, Richard J. Hayman
  • Patent number: 5663246
    Abstract: Cyclic acetal derivative of a resole includes the reaction product of an ortho resole compound with a carbonyl compound or a carbonyl compound derivative. The cyclic acetal derivatives of phenolic resole compounds exhibit enhanced storage stability and can be readily activated at elevated temperatures to prepare phenolic based adhesives and coatings.
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: September 2, 1997
    Assignee: Lord Corporation
    Inventors: Esther Spaltenstein, Ernest B. Troughton, Jr.
  • Patent number: 5658996
    Abstract: The present invention relates to a novel oxirane pre-polymer comprised of the catalyzed or uncatalyzed reaction product of tris or tetraphenyl intermediates with a difunctional oxirane oligomer having at least one aromatic moiety and at least one aliphatic moiety, characterized in that substantially hydrolyzable oxygen atoms in said phenyl are bonded to said oligomers, and there is substantially no bonding between oligomer moieties. In a particularly preferred embodiment the present invention relates to a novel oxirane prepolymer comprising the reaction product of a phenyl intermediate with an inorganic oxide having at least one hydrolyzable oxygen and a difunctional oxirane oligomer aliphatic moiety characterized in that a majority of all hydrolyzable oxygen atoms in said oxide are bonded to at least one of the phenyl groups of the tris-phenyl and one phenyl group of the tris-phenyl group is bonded to said oligomer and there is substantially no bonding between oligomer moieties.
    Type: Grant
    Filed: February 20, 1996
    Date of Patent: August 19, 1997
    Inventor: Donald J. Keehan
  • Patent number: 5585453
    Abstract: Polycyclic spiroorthoester which undergo expansion on polymerization to f resins, rather than shrinkage on polymerization, are employed in fabrication of composite, filament-reinforced, interceptor motor cases. The advantages which accrue to such use of the specified resins relate to the imparting of unique characteristics to the interceptor motor case such as increased structural strength, a reduction in the number of microcracks and voids, and improved bonding between resin and reinforcement. These unique characteristics impart benefits where needed since composite motor cases are fabricated from high strength filaments or tapes such as fiberglass, graphite, poly-p-phenyleneterephthalamide (Kevlar), in a polymeric matrix, and the primary mode of failure is due either to poor adhesion between the matrix and the filament or tapes or because of the development of microcracks or voids in the matrix.The spiroorthoester, 1,4,6-trioxaspiro [4.
    Type: Grant
    Filed: July 14, 1982
    Date of Patent: December 17, 1996
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventor: David C. Sayles
  • Patent number: 5563224
    Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-triazines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: October 8, 1996
    Assignee: Cytec Technology Corp.
    Inventors: Jeno G. Szita, Paul S. Waterman
  • Patent number: 5556896
    Abstract: Copolymer compositions are provided, including those which undergo less than .+-.1.0% bulk polymerization shrinkage and are useful as strain-free composites, high-strength adhesives, and precision castings. The copolymer compositions are formed from the cationic initiated polymerization of alicyclic spiroorthocarbonate monomers and epoxy resin monomers or comonomers. A preferred spiroorthocarbonate monomer is 2,3,8,9-di(tetramethylene)-1,5,7,11-tetraoxaspiro-[5,5]undecane. A preferred epoxy resin is a three component epoxy comonomer mixture of (i) diglycidyl ether of bisphenol A, (ii) 3,4-epoxycyclohexanemethyl-3,4-epoxycyclohexane carboxylate, and (iii) vinyl cyclohexene dioxide, preferably in a ratio of 5:4:1 by weight.
    Type: Grant
    Filed: July 1, 1993
    Date of Patent: September 17, 1996
    Assignee: The Curators of the University of Missouri
    Inventors: Thomas J. Byerley, J. David Eick, Cecil C. Chappelow
  • Patent number: 5466772
    Abstract: Unsaturated polyurethanes containing from 20 to 80% by weight of polyethylene glycol units, which can be prepared by reactinga) at least one organic polyisocyanate,b) an unsaturated fatty alcohol or its polyalkylene glycol ether, an unsaturated fatty amine or a reaction product of an unsaturated fatty acid and a monoepoxide,c) a compound which contains not only two groups which react with isocyanate groups but also at least one group which is ionic.d) a polyalkylene glycol having a molecular mass of from 750 to 10,000, and if desirede) a compound containing from three to six hydroxyl or amino groups,the ratio of the isocyanate groups in a) to the hydroxyl and amino groups in the remaining components being from 0.7:1 to 1.2:1. These unsaturated polyurethanes are used as dispersants for alkyd resins.
    Type: Grant
    Filed: March 3, 1994
    Date of Patent: November 14, 1995
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Karl-Hans Angelmayer, Gerd Walz, Joachim Zoeller
  • Patent number: 5412044
    Abstract: Adducts containing terminating nitro (nitroso) groups and one or more mesogenic moieties are prepared by reacting (A) at least one compound containing an average of more than one vicinal epoxide group per molecule with (B) at least one compound containing one or more nitro (nitroso) groups and an average of one reactive hydrogen atom per molecule; with the proviso that at least one member of components (A) and (B) contains a mesogenic moiety. Reduction of these adducts provides amines which are useful as curing agents for epoxy resins.
    Type: Grant
    Filed: May 12, 1994
    Date of Patent: May 2, 1995
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls
  • Patent number: 5405932
    Abstract: Oil-soluble, phenolic resin-modified natural resinic acid esters, which are able to form self-gelling mineral oil solutions and in the form of gel varnishes can advantageously be used as binder resins in printing inks for offset printing and letterpress printing, and also processes for their preparation from natural resins, phenols, aldehydes, condensation catalyst, esterifying agents and modifiers by reaction of the components at temperatures in the range from 80.degree. to 300.degree. C., individual components preferably being initially introduced and the other components being metered in, the combined use of a magnesium compound as condensation catalyst and the continuous removal of the water of reaction during the condensation reaction by azeotropic distillation with co-use of an inert organic solvent as distillative entraining agent being necessary and decisive for the self-gelling property of the process product.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: April 11, 1995
    Assignee: Hoechst AG
    Inventors: Albert Bender, Walter Hilker, Lothar Bothe
  • Patent number: 5395911
    Abstract: A thermally curable mixture contains 10-70% by weight of reactive compounds, 0.05-2% by weight of at least one basic catalyst, and at least one solvent. The reactive compounds are consisting essentially of a first reactive compound and a second reactive compound at a molar ratio between 1:1 and 1:10. The first reactive compound is a formamide selected from the group consisting of hydroxyformamides, di-formamides and polyformamides, and the second reactive compound is at least one compound having an epoxy equivalent between 100 and 800 g KOH per mole epoxy group, selected from a group of aromatic di-glycidylethers and aromatic poly-glycidylethers. The basic catalyst is at least one chemical agent selected from the group consisting of tertiary ammonium salts, tertiary aromatic amines, and tertiary heterocyclic amines. The solvent is at least one chemical compound selected from the group consisting of aliphatic alcohols, ether alcohols, diether, and tertiary amides.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: March 7, 1995
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Rainer B. Frings, Gerwald F. Grahe
  • Patent number: 5364925
    Abstract: An epoxy resin composition useful in an electrical laminate, which composition comprises:(A) an epoxy resin prepared by reacting (A-1) an epoxy resin having an average of more than one, but less than three epoxy groups per molecule and (A-2) a phenolic compound having an average of more than one, but less than three hydroxyl groups per molecule at a ratio to provide an epoxy to phenolic equivalent ratio of 1:x;(B) y equivalent of a phenolic compound having an average of more than one, but less than three hydroxyl groups per molecule; and(C) at least one catalyst for catalyzing a reaction of Component (A) and Component (B);wherein x and y satisfy the following equations:x.gtoreq.0.01y.gtoreq.0.010.02.ltoreq.x+y<1.00.The disclosed epoxy resin composition, exhibits low viscosity when dissolved in an organic solvent and good heat resistance when cured.
    Type: Grant
    Filed: August 13, 1993
    Date of Patent: November 15, 1994
    Assignee: The Dow Chemical Company
    Inventors: Masahiko Kohno, Takahiko Ohmura
  • Patent number: 5362822
    Abstract: An adduct is prepared by reacting (A) a compound containing at least one epoxy group per molecule, with (B) a compound containing at least one epoxide reactive group per molecule selected from the group consisting of phenolic, thiol, secondary amine and carboxyl; wherein (i) when compound (A) is a polyepoxide, compound (B) contains a single epoxide reactive group per molecule; (ii) when compound (A) is a monoepoxide it is a monoglycidyl ether and compound (B) contains at least two epoxide reactive groups per molecule; and (iii) at least one of components (A) and (B) contains a rodlike mesogenic moiety. These adducts are useful in the preparation of polyurethanes.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: November 8, 1994
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 5354840
    Abstract: Functional-amine polyesters have at least a first residue of a first monomer, a second residue of a second monomer and from about 0.1 to about 3.0 mole percent of a functional-amine residue of a functional amine prepared by reacting the first and second monomers and the functional amine in an inert atmosphere. The functional amine has a functional group which facilitates polymerizing the amine and the first and second monomers. The amine residue facilitates reaction of the functional-amine polyester in an organic peroxide cross-linking reaction system.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: October 11, 1994
    Assignee: Xerox Corporation
    Inventor: Peter G. Odell
  • Patent number: 5342902
    Abstract: The present invention relates to poly(ester-ether) compositions and to a process for their preparation. In particular, the invention relates to poly(ester-ether) compositions obtained by reacting a polyester which is prepared from a dicarboxylic acid and an aliphatic diol with a dihydroxy aromatic compound in the presence of a metal catalyst. Incorporation of the dihydroxy aromatic compound into the polyester chain causes an increase in the Tg value and increases the thermal stability of the polyester. These poly(ester-ether) compositions are useful in molded articles of all types.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: August 30, 1994
    Assignee: Eastman Chemical Company
    Inventors: W. Ronald Darnell, W. J. Jackson, Jr.
  • Patent number: 5342904
    Abstract: Polymer modified adducts are prepared by (A) reacting (1) an epoxy resin having an average of more than one vicinal epoxide group with (2) a compound containing an average of two or more hydrogen atoms reactive with an epoxide group; and (B) partially vinylizing reacting the product from step (A); and (C) polymerizing the partially vinylized product from step (B) with (3) a polymerizable ethylenically unsaturated monomer; with the proviso that at least one of the components (1), (2) or (3) contain one or more mesogenic or rodlike moieties. These adducts are useful as epoxy resin curing agents.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: August 30, 1994
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls
  • Patent number: 5340911
    Abstract: A method for producing a liquid crystalline polyester, which comprises reacting compounds of the following formulas: ##STR1## and a dicarboxylic acid of the following formula ##STR2## wherein R.sup.1 is a bivalent aromatic hydrocarbon group having from 6 to 18 C atoms as starting material, for polycondensation in a molten state.
    Type: Grant
    Filed: October 20, 1993
    Date of Patent: August 23, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Osamu Kishiro, Rie Shirahama, Yasuyuki Sakata, Hideaki Tanaka, Ken Honma
  • Patent number: 5310859
    Abstract: A liquid crystalline polyester comprising dicarboxylic acid units of the following formula (1): ##STR1## wherein R.sup.1 is a bivalent aromatic hydrocarbon group having from 6 to 18 carbon atoms, diol units of the following formula (2):--OCH.sub.2 CH.sub.
    Type: Grant
    Filed: April 5, 1991
    Date of Patent: May 10, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Osamu Kishiro, Rie Shirahama, Yasuyuki Sakata, Hideaki Tanaka, Ken Honma
  • Patent number: 5175231
    Abstract: A urethane is formed in a new way, without requiring the use of isocyanates. The urethane is formed by reacting a compound containing a plurality of cyclocarbonate groups with a diamine in which the two amine groups have different reactivities with cyclocarbonate, so as to form a urethane oligomer with amine end groups. The urethane oligomer can then be reacted in several different ways to form polyurethane.
    Type: Grant
    Filed: April 17, 1992
    Date of Patent: December 29, 1992
    Assignee: Fiber-Cote Corporation
    Inventors: Leonid Rappoport, Roger D. Brown
  • Patent number: 5169912
    Abstract: The present invention relates to a novel oxirane prepolymer comprising the catalyzed reaction product of an inorganic oxide having at least one hydrolyzable oxygen with a difunctional oxirane oligomer having at least one aromatic moiety and at least one oxirane containing aliphatic moiety, characterized in that substantially all of the hydrolyzable oxygen atoms in said oxide are bonded to said oligomer and there is substantially no bonding between oligomer moieties.The present invention also relates to a novel inorganic oxide containing polymer, said polymer comprising at least three crosslinked prepolymer moieties, each said prepolymer moiety being the reaction product of an inorganic oxide having at least one hydrolyzable oxygen with a difunctional oxirane oligomer having at least one aromatic moiety and at least one oxirane containing aliphatic moiety.
    Type: Grant
    Filed: April 5, 1991
    Date of Patent: December 8, 1992
    Inventor: Donald J. Keehan
  • Patent number: 5089547
    Abstract: A cross-linked low surface adhesion composition, that can be utilized as either an electrographic toner powder or as an additive for conventional electrographic toner powder, exhibits improved transfer and contributes to an increase in the useful life of the developer. The low surface adhesion composition employs a silicone resin and a polyester resin cross-linked with a polyfunctional epoxy novolac resin.
    Type: Grant
    Filed: August 6, 1990
    Date of Patent: February 18, 1992
    Assignee: Eastman Kodak Company
    Inventors: John M. McCabe, John C. Wilson
  • Patent number: 5026816
    Abstract: The present invention relates to a novel oxirane prepolymer comprising the catalyzed reaction product of an inorganic oxide having at least one hydrolyzable oxygen with a difunctional oxirane oligomer having at least one aromatic moiety and at least one oxirane containing aliphatic moiety, characterized in that substantially all of the hydrolyzable oxygen atoms in said oxide are bonded to said oligomer and there is substantially no bonding between oligomer moieties.The present invention also relates to a novel inorganic oxide containing polymer, said polymer comprising at least three crosslinked prepolymer moieties, each said prepolymer moiety being the reaction product of an inorganic oxide having at least one hydrolyzable oxygen with a difunctional oxirane oligomer having at least one aromatic moiety and at least one oxirane containing aliphatic moiety.
    Type: Grant
    Filed: January 19, 1989
    Date of Patent: June 25, 1991
    Inventor: Donald J. Keehan