With Solid Catalyst Or Absorbent Patents (Class 208/213)
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Patent number: 7556729Abstract: Described is a method for the selective hydrodesulfurization of an olefin-containing hydrocarbon feedstock that uses a catalyst composition having a high content of a nickel component and an effective but small amount of a molybdenum component supported on a porous refractory oxide. A preferred catalyst composition contains an immaterial amount of a cobalt component.Type: GrantFiled: April 24, 2006Date of Patent: July 7, 2009Assignee: Shell Oil CompanyInventors: Opinder Kishan Bhan, Paul Benjerman Himelfarb
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Patent number: 7547386Abstract: An integrated process for the hydroprocessing of multiple feedstreams including vacuum gas oil and light cycle oil. The light cycle oil is reacted with hydrogen in a hydrocracking zone and the hydrocarbon feedstream comprising vacuum gas oil is reacted with hydrogen in a hydrodesulfurization reaction zone. The hydrotreated vacuum gas oil is good FCC feedstock. Naphtha and ultra low sulfur diesel are recovered in a common fractionation column.Type: GrantFiled: February 2, 2005Date of Patent: June 16, 2009Assignee: UOP LLCInventors: Vasant P. Thakkar, Richard K. Hoehn
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Patent number: 7544285Abstract: A bulk metal oxide catalyst composition of the general formula (X)b(M)c(Z)d(O)e??(I) wherein X represents at least one non-noble Group VIII metal; M represents at least one non-noble Group VIb metal; Z represents one or more elements selected from aluminium, silicon, magnesium, titanium, zirconium, boron, and zinc; one of b and c is the integer 1; and d and e and the other of b and c each are a number greater than 0 such that the molar ratio of b:c is in the range of from 0.5:1 to 5:1, the molar ratio of d:c is in the range of from 0.2:1 to 50:1, and the molar ratio of e:c is in the range of from 3.7:1 to 108:1; is prepared by controlled (co)precipitation of component metal compounds, refractory oxide material, and alkali compound in protic liquid. Resulting compositions find use in hydrotreatment processes involving particularly hydrodesulphurisation and hydrodenitrification.Type: GrantFiled: February 20, 2004Date of Patent: June 9, 2009Assignee: Shell Oil CompanyInventors: Laszlo Domokos, Hermanus Jongkind, Johannes Anthonius Robert Van Veen
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Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system
Patent number: 7517446Abstract: A fixed bed hydroprocessing system, and also a method for upgrading a pre-existing fixed bed hydroprocessing system, involves preliminarily upgrading a heavy oil feedstock in one or more slurry phase reactors using a colloidal or molecular catalyst and then further hydroprocessing the upgraded feedstock within one or more fixed bed reactors using a porous supported catalyst. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. Asphaltene or other hydrocarbon molecules otherwise too large to diffuse into the pores of the fixed bed catalyst can be upgraded by the colloidal or molecular catalyst.Type: GrantFiled: April 28, 2005Date of Patent: April 14, 2009Assignee: Headwaters Heavy Oil, LLCInventors: Roger K. Lott, Lap-Keung Lee, Peter C. Quinn -
Patent number: 7513990Abstract: The invention relates to a process for sulfurization of catalysts for hydrotreatment, in particular the catalysts for hydrotreating refractory oxides by sulfurization, in which said catalysts are subjected to a sulfurization stage under a gas atmosphere that contains hydrogen sulfide (H2S), hydrogen (H2), and optionally a cover gas for dilution and in which the H2S/H2 molar ratio is more than 4 and the H2S partial pressure is at least equal to 1 kPa. Said sulfurization stage can be carried out in the hydrotreatment unit (sulfurization in situ) or, prior to the charging of the catalyst, in the hydrotreatment unit (sulfurization ex situ) and is generally carried out at a temperature of less than 600° C., preferably less than 500° C. The invention also relates to the catalysts that are sulfurized by said sulfurization process and their use for hydrorefining and/or hydroconversion/hydrocracking of hydrocarbon feedstocks.Type: GrantFiled: September 8, 2005Date of Patent: April 7, 2009Assignee: Institut Francais du PetroleInventors: Denis Guillaume, Sylvie Lopez, Tivadar Cseri
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Patent number: 7513989Abstract: The invention relates to a hydrocracking process for hydrocracking petroleum and chemical feedstocks using bulk Group VIII/VIB catalysts. Preferred catalysts include those comprised of Ni—Mo—W.Type: GrantFiled: January 14, 2000Date of Patent: April 7, 2009Assignee: ExxonMobil Research and Engineering CompanyInventors: Stuart Leon Soled, Kenneth Lloyd Riley, Gary P. Schleicher, Richard A. Demmin, Darlene Schuette, legal representative, Ian Alfred Cody, William L. Schuette
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Patent number: 7510648Abstract: The invention provides an optimum method for utilizing a desulfurizing agent for liquid hydrocarbons which can efficiently remove sulfur content from kerosene without performing addition of hydrogen to a low sulfur concentration and which has a prolonged lifetime. The invention provides a desulfurization method which includes removing sulfur content from kerosene by use of a metallic desulfurizing agent without performing addition of hydrogen, characterized in that the method employs desulfurization conditions satisfying the following formula (1): 1.06×Pope0.44<Tope/T50<1.78×Pope0.22??(1) (wherein Tope is operation temperature (° C.); Pope is operation pressure (MPa); and T50 is a temperature per 50 percent recovered as determined by “test method for distillation at atmospheric pressure” stipulated in JIS K2254 “Petroleum products—Determination of distillation characteristics as revised in 1998”).Type: GrantFiled: July 22, 2003Date of Patent: March 31, 2009Assignee: Idemitsu Kosan Co., Ltd.Inventors: Tadashi Kisen, Hiroto Matsumoto, Hisashi Katsuno, Kazuhito Saito
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Patent number: 7507328Abstract: A process for the selective hydrodesulfurization of olefinic naphtha streams containing a substantial amount of organically-bound sulfur and olefins. The olefinic naphtha stream is selectively desulfurized in a hydrodesulfurization reaction stage. The hydrodesulfurized effluent stream is separated into a light and heavy liquid fraction and the heavier fraction is further processed in a mercaptan destruction reaction stage to reduce the content of mercaptan sulfur in the final product.Type: GrantFiled: November 23, 2005Date of Patent: March 24, 2009Assignee: ExxonMobile Research and Engineering CompanyInventors: Edward S. Ellis, John P. Greeley, Vasant Patel, Murali V. Ariyapadi
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Patent number: 7504022Abstract: A process for desulphurizing a gasoline cut containing olefins, sulphur-containing compounds and optionally molecules belonging to C3 and C4 cuts comprises at least a first step A for contacting said gasoline cut with an acidic resin having an acid capacity of more than 4.7 equivalents per kg and a specific surface area of less than 55 m2/g, and a second step B for fractionation of the mixture from the first step.Type: GrantFiled: April 18, 2006Date of Patent: March 17, 2009Assignee: Institut Francais du PetroleInventor: Florent Picard
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Publication number: 20090065396Abstract: In one aspect, a hydrodesulfurization process is provided that selectively desulfurizes a hydrocarbon stream with minimal olefin saturation and minimal recombination of sulfur into mercaptans. In another aspect, the process includes a multi-stage reaction zone including at least first and second serial hydrodesulfurization reaction zones that sequentially remove sulfur from a hydrocarbon stream. In yet another aspect, the process is particularly suited to selectively desulfurize an olefinic naphtha hydrocarbon stream, such as FCC naphtha, steam cracked naphtha, coker naphtha, or other gasoline boiling hydrocarbon streams.Type: ApplicationFiled: September 7, 2007Publication date: March 12, 2009Inventors: Peter Kokayeff, Laura Elise Leonard
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Publication number: 20090065397Abstract: A method and an apparatus for removing sulfur hydrocarbon compounds from naphtha stream as well as a method and an apparatus for simultaneously removing sulfur hydrocarbon compounds from two streams is shown and described. The method includes providing a separator vessel having a top, a bottom, a primary feed inlet in a co-feed inlet disposed vertically above the primary feed inlet. The separator vessel further includes a catalyst bed disposed between the co-feed inlet and the top. The top includes a vapor outlet and bottom includes a bottoms outlet The method includes delivering a primary feed stream comprising sulfur hydrocarbon compounds through the effluent inlet and delivering a vaporized co-feed stream that also comprises sulfur hydrocarbon compounds through the co-feed inlet.Type: ApplicationFiled: September 7, 2007Publication date: March 12, 2009Inventors: Richard K. Hoehn, David A. Lindsay, Giles R. Maddox
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Publication number: 20090065395Abstract: A method for obtaining a petroleum distillate product is provided, the method includes subjecting an untreated light Fischer-Tropsch liquid to a two-step hydrogenation process, each step to be carried in the presence of a catalyst comprising an amorphous substrate having a metallic composition embedded therein. After the first step of hydrogenation, an intermediate hydrotreated light Fischer-Tropsch liquid is obtained, followed by the second step of hydrogenation thereof, obtaining the petroleum distillate product as a result. An apparatus for carrying out the method is also provided.Type: ApplicationFiled: September 7, 2007Publication date: March 12, 2009Applicant: UOP, LLCInventor: Peter Kokayeff
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Patent number: 7501549Abstract: An integrated process for the isolation of benzene contained within a fluid catalytically cracked naphtha is disclosed wherein a C6 fraction containing a benzene concentrate is subjected to etherification with alcohol (e.g. methanol and/or ethanol) to convert the C6 isoolefins to ethers which are separated by fractional distillation. If desired the ethers may be dissociated to the isoolefins and alcohol. The remaining material in the benzene concentrate may then be treated to remove olefins and organic sulfur compounds so that the benzene may be removed by solvent extraction. Alternatively the benzene in the remaining material may be subjected to hydrogenation.Type: GrantFiled: October 6, 2006Date of Patent: March 10, 2009Assignee: Catalytic Distillation TechnologiesInventors: Gary G. Podrebarac, Richard Foley
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Publication number: 20090050534Abstract: Disclosed is a process for removing organic sulfur from more than one reactive fuel gas stream. A reactor vessel that is provided with at least one bed of hydrodesulfurization catalyst is used to hydrodesulfurize multiple reactive fuel gas streams with a less reactive fuel gas stream being introduced into the reactor vessel at a point above the introduction point of a more reactive fuel gas stream. An hydrotreated fuel gas is yielded from the reactor vessel having a hydrogen sulfide concentration and a low organic sulfur content.Type: ApplicationFiled: May 23, 2008Publication date: February 26, 2009Inventor: Gary Lee RIPPERGER
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Patent number: 7476309Abstract: The present invention pertains to a method for hydroprocessing a heavy hydrocarbon oil, comprising bringing a heavy hydrocarbon oil into contact with hydroprocessing catalyst I in the presence of hydrogen in a first stage, after which the effluent of the first stage is contacted in whole or in part with hydroprocessing catalyst II in the presence of hydrogen in a second stage. The method according to the invention combines efficient contaminant removal with high cracking rate and low sediment formation. The invention also pertains to the combination of catalysts.Type: GrantFiled: June 10, 2002Date of Patent: January 13, 2009Assignee: Albemarle Netherlands B.V.Inventors: Satoshi Abe, Katsuhisa Fujita
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Patent number: 7455762Abstract: This invention relates to a process for selectively hydrodesulfurizing naphtha feedstreams using a catalyst comprising at least one hydrodesulfurizing metal supported on a low acidity, ordered mesoporous support material.Type: GrantFiled: July 26, 2005Date of Patent: November 25, 2008Assignee: ExxonMobil Research and Engineering CompanyInventors: Chuansheng Bai, Gary B. McVicker, Stuart S. Shih, Michael C. Kerby, Edward A. Lemon, Jr.
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Patent number: 7449103Abstract: An ebullated bed hydroprocessing system, and also a method for upgrading a pre-existing ebullated bed hydroprocessing system, involves introducing a colloidal or molecular catalyst, or a precursor composition capable of forming the colloidal or molecular catalyst, into an ebullated bed reactor. The colloidal or molecular catalyst is formed by intimately mixing a catalyst precursor composition into a heavy oil feedstock and raising the temperature of the feedstock to above the decomposition temperature of the precursor composition to form the colloidal or molecular catalyst in situ. The improved ebullated bed hydroprocessing system includes at least one ebullated bed reactor that employs both a porous supported catalyst and the colloidal or molecular catalyst to catalyze hydroprocessing reactions involving the feedstock and hydrogen. The colloidal or molecular catalyst provides catalyst in what would otherwise constitute catalyst free zones within the ebullated bed hydroprocessing system.Type: GrantFiled: April 28, 2005Date of Patent: November 11, 2008Assignee: Headwaters Heavy Oil, LLCInventors: Roger K. Lott, Lap-Keung Lee
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Patent number: 7445702Abstract: Propane and/or butanes are separated from a hydrocarbon feedstock contaminated with alkyl mercaptans by fractional distillation at such a pressure that the separated overheads stream containing said propane and/or butanes is at a temperature in the range 50 to 100° C. Sufficient oxygen is introduced into the hydrocarbon feedstock to oxidise the mercaptans therein and the resultant mixture is subjected to the fractional distillation in a column including at least one bed of a catalyst capable, under the prevailing conditions, of oxidising the mercaptans to higher boiling point sulphur compounds. These higher boiling point sulphur compounds are separated as part of the liquid phase from the distillation.Type: GrantFiled: October 30, 2003Date of Patent: November 4, 2008Assignee: Johnson Matthey PLCInventor: Peter Edward James Abbott
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Patent number: 7438798Abstract: A method and product for removing sulfur compound molecules from gasoline or diesel fuel includes exposing the gasoline or diesel fuel to a plurality of molecularly imprinted polymer beads (MIPS) that have receptor sites on the surfaces thereof that include imprints that match the physical shape of at least a portion of a sulfur compound molecule. A quantity of the sulfur molecules align with and adhere to some of the receptor sites and, accordingly, they are removed from the gasoline or diesel fuel producing a remediated or sweetened gasoline or diesel fuel. According to one embodiment, the MIPS are contained in an enclosure having a plurality of openings large enough to permit the solution to pass through and small enough so as to prevent the MIPS from passing through. According to another embodiment the MIPS are applied (i.e., coated) to the inside surface of a conduit and the gasoline or diesel fuel is forced or allowed to flow through the conduit thereby removing some of the sulfur molecules therefrom.Type: GrantFiled: April 27, 2006Date of Patent: October 21, 2008Inventor: Anna Madeleine Leone
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Patent number: 7435330Abstract: A heavy oil reforming method which reforms a heavy oil to give a fuel suitable for a gas turbine, eliminates sulfur and vanadium, i.e., harmful components, from a heavy oil, and enables almost all the hydrocarbons in the heavy oil to be used in gas turbine combustion; an apparatus therefor; and a gas turbine power generation system using the reformed heavy oil as fuel is disclosed. The method includes reacting a heavy oil with supercritical water and then with a scavenger for sulfur and vanadium to eliminate sulfur and vanadium from the heavy oil.Type: GrantFiled: October 7, 2003Date of Patent: October 14, 2008Assignee: Hitachi, Ltd.Inventors: Nobuyuki Hokari, Tomohiko Miyamoto, Hirokazu Takahashi, Atsushi Morihara, Hiromi Koizumi
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Patent number: 7435336Abstract: The present invention relates to a process for carrying our gas-liquid countercurrent processing comprising passing the liquid material and the gas reactant in countercurrent flow through the fixed bed of catalyst in a reactor, characterized in that the fixed bed of catalyst includes two or more catalyst layers, with the difference of voidage between the adjacent catalyst layers being at least 0.05. The voidages of the catalyst layers can be increased or decreased in the direction of the flow of the liquid phase. The process of the invention can be effected with an increased range of gas-liquid ratio and an improved stability and flexibility.Type: GrantFiled: October 9, 2003Date of Patent: October 14, 2008Assignees: China Petroleum & Chenical Corporation, Fushun Research Institute of Petroleum and Petrochemicals Sinopec, Corp.Inventors: Baoping Han, Xiangchen Fang, Ronghui Zeng, Ping Wu, Mei Jin, Hongjiang Sun
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Patent number: 7435337Abstract: The invention describes the application of caesium-exchanged X, Y or LSX type faujasite zeolites for intense desulphurization of FCC gasoline, and to a method for preparing said zeolites.Type: GrantFiled: June 2, 2006Date of Patent: October 14, 2008Assignee: Institut Francais du PetroleInventors: Michel Thomas, Alexandre Nicolaos
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Patent number: 7431831Abstract: A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil, products and hydrogen to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the products and hydrogen while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor. In the next reactor, a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, products, hydrogen and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. The slurry reactor system is, in this invention, preceded by an in-line pretreating step, such as hydrotreating or deasphalting.Type: GrantFiled: December 16, 2005Date of Patent: October 7, 2008Assignee: Chevron U.S.A. Inc.Inventors: Darush Farshid, Bruce Reynolds
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Patent number: 7431825Abstract: The present invention describes novel methods for reducing sulfur in gasoline with hydrotalcite like compound additives, calcined hydrotalcite like compounds, and/or mixed metal oxide solution solutions. The additives can optionally further comprise one or more metallic oxidants and/or supports. The invention is also directed to methods for reducing gasoline sulfur comprising contacting a catalytic cracking feedstock with a mixed metal oxide compound comprising magnesium and aluminum and having an X-ray diffraction pattern displaying a reflection at least at a two theta peak position at about 43 degrees and about 62 degrees, wherein the ratio of magnesium to aluminum in the compound is from about 1:1 to about 10:1.Type: GrantFiled: December 5, 2003Date of Patent: October 7, 2008Assignee: Intercat, Inc.Inventors: Albert A. Vierheilig, Bruce Keener
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Patent number: 7431822Abstract: Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil, hydrogen, and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is separated internally, within one of more of the reactors, to separate only the converted oil and hydrogen into a vapor product while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor as a liquid product. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons in the next reactor, once again creating a mixture of unconverted oil, hydrogen, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.Type: GrantFiled: December 16, 2005Date of Patent: October 7, 2008Assignee: Chevron U.S.A. Inc.Inventors: Darush Farshid, James Murphy, Bruce Reynolds
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Patent number: 7431824Abstract: The instant invention is directed to a process employing slurry catalyst compositions in the upgrading of heavy oils. The slurry catalyst composition is not permitted to settle, which would result in possible deactivation. The slurry is recycled to an upgrading reactor for repeated use and products require no further separation procedures for catalyst removal.Type: GrantFiled: September 10, 2004Date of Patent: October 7, 2008Assignee: Chevron U.S.A. Inc.Inventors: Kaidong Chen, Julie Chabot
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Patent number: 7431827Abstract: A process for the production of low sulfur, low olefin gasoline wherein a cracked naphtha, such as a full boiling range cracked naphtha, is first separated by fractional distillation into at least two fractions while simultaneously selectively hydrogenating the polyunsaturated compounds contained therein. The mono olefins in the light fraction are then subjected to etherification with alcohol to produce ethers or hydration with water to produce alcohols. The heavy fraction is subjected to sulfur removal by hydrodesulfurization or chemisorption. The two fractions are then combined to produce a low sulfur, low olefin gasoline.Type: GrantFiled: October 27, 2004Date of Patent: October 7, 2008Assignee: Catalytic Distillation TechnologiesInventors: Kerry L. Rock, Yi-Gang Xiong, Arvids Judzis, Jr.
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Patent number: 7431828Abstract: A two-stage hydrotreating process is disclosed wherein a hydrocarbon stream is first desulphurized followed by a dehydrogenation step, which process comprises in combination contacting the feed and hydrogen over a hydrotreating catalyst at hydrotreating conditions, heating the hydrotreated effluent and hydrogen-rich gas from the hydrotreating reactor and contacting said effluent and hydrogen gas over a hydrotreating catalyst in a post-treatment reactor at a temperature sufficient to increase the polyaromatic hydrocarbon content and lower the hydrogen content of said effluent.Type: GrantFiled: July 6, 2005Date of Patent: October 7, 2008Assignee: Haldor Topsoe A/SInventors: Michael G. Hunter, Rasmus G. Egeberg, Kim G. Knudsen
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Patent number: 7431823Abstract: The instant invention is directed to a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the products and hydrogen, while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.Type: GrantFiled: December 16, 2005Date of Patent: October 7, 2008Assignee: Chevron U.S.A. Inc.Inventors: Darush Farshid, Bruce Reynolds
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Patent number: 7422679Abstract: Naphtha hydrodesulfurization selectivity is increased by reducing the amount of COX (CO plus ½ CO2) in the hydrodesulfurization reaction zone to less than 100 vppm. While this is useful for non-selective hydrodesulfurization, it is particularly useful for selectively desulfurizing an olefin-containing naphtha without octane loss due to olefin saturation by hydrogenation. The COX reduction is achieved by removing COX from the treat gas before it is passed into the reaction zone.Type: GrantFiled: May 1, 2003Date of Patent: September 9, 2008Assignee: ExxonMobil Research and Engineering CompanyInventors: Edward S. Ellis, Thomas R. Halbert, Garland B. Brignac, John P. Greeley, Richard A. Demmin, Theresa A. Lalain
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Patent number: 7419585Abstract: A process for upgrading a residua feedstock using a short vapor contact time thermal process unit comprised of a horizontal moving bed of fluidized hot particles. The residua feedstock is preferably atomized so that the Sauter mean diameter of the residua feedstock entering the reactor is less than about 2500 ?m. One or more horizontally disposed screws is preferably used to fluidize a bed of hot particles.Type: GrantFiled: January 6, 2003Date of Patent: September 2, 2008Assignee: Exxonmobil Research and Engineering CompanyInventors: Peter S. Maa, Craig Y. Sabottke
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Patent number: 7419582Abstract: A hydrocracking process wherein the feedstock is hydrotreated and the liquid and gaseous effluent from the hydrotreater is directly introduced into the upper end of a hydrocracking vessel which provides a liquid seal to prevent the passage of the gaseous stream containing hydrogen sulfide and ammonia from the hydrotreater to enter the hydrocracking zone containing hydrocracking catalyst. Fresh hydrogen is then introduced into the hydrocracking zone. An apparatus for hydrocracking a hydrocarbon feedstock is also disclosed.Type: GrantFiled: July 11, 2006Date of Patent: September 2, 2008Assignee: UOP LLCInventors: Richard K. Hoehn, Vasant P. Thakkar, Vedula K. Murty, Douglas W. Kocher-Cowan, Jennifer L. Anderson
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Patent number: 7419586Abstract: A process for the selective hydrodesulfurization of olefinic naphtha streams containing a substantial amount of organically-bound sulfur and olefins. The olefinic naphtha stream is selectively desulfurized in a first hydrodesulfurization stage. The effluent stream from this first stage is sent to a separation zone wherein a lower boiling naphtha stream and a higher boiling naphtha stream are produced. The lower boiling naphtha stream is sent through at least two more separation zones, each at a lower temperature than the preceding separation stage. The higher boiling naphtha stream, which contains most of the sulfur moieties, is passed to a second hydrodesulfurization stage wherein at least a fraction of the sulfur moieties are removed.Type: GrantFiled: November 23, 2005Date of Patent: September 2, 2008Assignee: ExxonMobil Research and Engineering CompanyInventors: Edward S. Ellis, John P. Greeley, Vasant Patel, Murali V. Ariyapadi
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Patent number: 7416653Abstract: Contact of a crude feed with one or more catalysts produces a total product that includes a crude product. The crude feed has a residue content of at least 0.2 grams of residue per gram of crude feed. The crude product is a liquid mixture at 25° C. and 0.101 MPa. One or more properties of the crude product may be changed by at least 10% relative to the respective properties of the crude feed. In some embodiments, gas is produced during contact with one or more catalysts and the crude feed.Type: GrantFiled: December 16, 2004Date of Patent: August 26, 2008Assignee: Shell Oil CompanyInventors: Scott Lee Wellington, Thomas Fairchild Brownscombe, Stanley Nemec Milam
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Publication number: 20080173571Abstract: The desulfurization of fossil fuels is effected by the combination of fossil fuels with an aqueous mixture of hydroperoxide and quaternary ammonium fluoride phase transfer catalyst, the mixture then subjected to ultrasound to oxidize sulfur compounds present in the fuels. The polar oxidized species are removed via extraction. Another aspect is a portable, continuous ultrasound assisted desulfurization device having a sonoreactor for subjecting mixtures of fossil fuels to sonication to effect removal of sulfur containing compounds.Type: ApplicationFiled: September 13, 2007Publication date: July 24, 2008Inventors: Teh-Fu Yen, Meng-Wei Wan
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Patent number: 7399402Abstract: Process for the hydrotreatment of a mixture of C4 to C8 hydrocarbon-based compounds, rich in olefins and monoaromatic compounds, by hydrogenation in the presence of a solid catalyst, characterized in that an ammonia precursor is introduced into the charge of hydrocarbon-based compounds and in that the catalyst comprises at least one transition metal supported on at least one refractory oxide.Type: GrantFiled: November 6, 2001Date of Patent: July 15, 2008Assignee: Total Petrochemicals Research FeluyInventors: Catherine Olivier, Walter Vermeiren, Jean-Pierre Dath
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Patent number: 7384542Abstract: A process for the production of low sulfur diesel and high octane naphtha.Type: GrantFiled: June 7, 2004Date of Patent: June 10, 2008Assignee: UOP LLCInventors: Vasant P. Thakkar, Richard K. Hoehn
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Patent number: 7384540Abstract: A process for hydrotreating a hydrocarbon feed comprises at least two steps with intermediate stripping of the effluent from the first step with pressurized hydrogen substantially free of impurities which are undesirable for the catalyst for the second step, in particular to eliminate part of the H2S formed, each step being carried out with a hydrogen recycle loop that is exclusive to that step.Type: GrantFiled: November 22, 2001Date of Patent: June 10, 2008Assignee: Institut Francais du PetroleInventor: Renaud Galeazzi
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Patent number: 7381322Abstract: This invention provides a resid cracking apparatus comprising a riser, reactor, stripper cum separator with adjustable outlets in flow communication with adsorbent and catalyst regenerators for converting hydrocarbon residues containing higher concentration of conradson carbon content, poisonous metals such as nickel & vanadium and basic nitrogen etc., into lighter and valuable products and a process thereof.Type: GrantFiled: November 4, 2005Date of Patent: June 3, 2008Assignee: Indian Oil Corporation LimitedInventors: Kasliwal Pankaj, Rama Rao Marri, Dixit Jagdev Kumar, Saroya Latoor Lal, Sukumar Mandal, Satish Makhija, Sobhan Ghosh
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Publication number: 20080116114Abstract: Process for the catalytic hydrotreating of a hydrocarbon feed stock containing silicon compounds comprising the steps of contacting the feed stock in presence of hydrogen with a first hydrotreating catalyst being arranged in at least two reactors being connected in series at an outlet temperature of up to 410° C. to reduce content of the silicon compounds in the feed stock; cooling of the feed stock such treated to a temperature of between 280° and 350° C.; and contacting the cooled feed stock with a second hydrotreating catalyst at conditions being effective in reduction of sulphur compound and nitrogen compound concentration.Type: ApplicationFiled: October 23, 2007Publication date: May 22, 2008Inventors: Rasmus Breivik, Kim Gron Knudsen
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Publication number: 20080116113Abstract: A system which circulates fluidizable solid particles through a fluidized bed reactor, a fluidized bed regenerator, and a fluidized bed reducer to thereby provide for substantially continuous desulfurization of a hydrocarbon-containing fluid stream and substantially continuous regeneration of the solid particles is disclosed.Type: ApplicationFiled: November 22, 2006Publication date: May 22, 2008Inventors: Victor G. Hoover, Daniel T. Fernald, Gwen J. DeBrower
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Patent number: 7371318Abstract: The invention relates to a process for the elimination of sulphur compounds from the diesel fraction, which is characterized in that an oxidising reaction of said sulphur compound is carried out by using at least an organic-inorganic composite as catalyst, said composite comprising Si, Ti; and silicon bonded to carbon, and organic and inorganic hydroperoxides as oxidizing agents. According to the inventive process, said organic-inorganic composite can be obtained by a method comprising a post-synthesis silylation step.Type: GrantFiled: October 10, 2003Date of Patent: May 13, 2008Assignees: Consejo Superior De Investigaciones Cientificas, Universidad Politecnica De ValenciaInventors: Avelino Corma Canós, Marcelo Eduardo Domine, Cristina Martinez Sánchez
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Patent number: 7361265Abstract: A process for the hydrodesulfurization of cracked olefin streams is described, the process aiming at reducing the sulfur content while at the same time minimizing the hydrogenation degree of said olefins. In order to dilute the added reaction hydrogen, the process makes use of non-reactive compounds such as N2, CH4, C2H6, C3H8, C4H10, Group VIII noble gases as well as admixtures of same in any amount, in gas or vapor phase.Type: GrantFiled: March 12, 2003Date of Patent: April 22, 2008Assignee: Petroleo Brasileiro S.A.-PetrobrasInventors: Rafael M. de Almeida, Jefferson Roberto Gomes
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Patent number: 7361266Abstract: The present invention is related to a method of subjecting a feed oil to a refining process. This method includes a fractional distillation step 1 in which a feed oil is separated into a distillate oil M1 and a bottom oil M2 by a distillation process, a separation step in which the bottom oil is separated into a bottom light oil and a residue, and a hydrorefining step 3 in which the obtained distillate oil M1 and the bottom oil M2 are subjected to hydrorefining in the presence of hydrogen and a catalyst. In the hydrorefining step 3, the bottom light oil (deasphalted oil M3) is passed through a first catalyst layer 12 of a hydrorefining unit providing a plurality of catalyst layers 12, 13, and 13 filled with a hydrorefining catalyst, and a mixed oil comprising the distillate oil M1 and the bottom light oil (deasphalted oil M3) is passed through a downstream catalyst layer 13 and subject to a hydrogenation process.Type: GrantFiled: March 15, 2002Date of Patent: April 22, 2008Assignee: JGC CorporationInventors: Makoto Inomata, Tsuyoshi Okada, Kozo Imura, Hajime Sasaki
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Patent number: 7347931Abstract: The invention relates to a catalyst for the selective hydrodesulfurization of hydrocarbon-containing feedstocks that comprise sulfur-containing compounds and olefins. This catalyst comes in a sulfurized form and comprises a substrate that is selected from among the refractory oxides, at least one metal that is selected from the group that consists of the metals of groups VI and VII of the periodic table and carbon, whereby the carbon content is less than or equal to 2.8% by weight. The invention also relates to a method for the production of the catalyst that is described above, as well as a process that uses this catalyst for the selective hydrodesulfurization of hydrocarbon-containing feedstocks that contain sulfur-containing compounds and olefins.Type: GrantFiled: January 29, 2004Date of Patent: March 25, 2008Assignee: Institut Francais du PetroleInventors: Denis Uzio, Nathalie Marchal-George, Christophe Bouchy, Florent Picard
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Publication number: 20080011648Abstract: Increased selectivity of middle distillate and increased catalyst activity are obtained in a hydrocracking process by the use of a catalyst containing a hydrogenation component, a beta zeolite having an overall silica to alumina mole ratio of less than 30 and a SF6 adsorption capacity of at least 28 wt-%, a Y zeolite having a unit cell size of from 24.25 to 24.32 angstrom, and a support.Type: ApplicationFiled: July 17, 2006Publication date: January 17, 2008Inventor: Li Wang
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Publication number: 20080011647Abstract: Increased selectivity of middle distillate and/or increased catalyst activity are obtained in a hydrocracking process by the use of a catalyst containing a beta zeolite and a Y zeolite having a unit cell size of from 24.25 to 24.32 angstrom. The catalyst may also contain an additional Y zeolite having a unit cell size of from 24.33 to 24.38 angstrom.Type: ApplicationFiled: July 17, 2006Publication date: January 17, 2008Inventor: Li Wang
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Publication number: 20080011649Abstract: Increased selectivity of middle distillate and/or increased catalyst activity are obtained in a hydrocracking process by the use of a catalyst containing a beta zeolite and a Y zeolite having a unit cell size of 24.33 to 24.38 angstrom. The catalyst may also contain an additional Y zeolite having a unit cell size of from 24.25 to 24.32 angstrom.Type: ApplicationFiled: July 17, 2006Publication date: January 17, 2008Inventor: Li Wang
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Patent number: 7318845Abstract: A distillate fuel steam reformer system in which a fuel feed stream is first separated into two process streams: an aliphatics-rich, sulfur-depleted gas stream, and an aromatics- and sulfur-rich liquid residue stream. The aliphatics-rich gas stream is desulfurized, mixed with steam, and converted in a reforming reactor to a hydrogen-rich product stream. The aromatics-rich residue stream is mixed with air and combusted to provide heat necessary for endothermic process operations. Reducing the amounts of sulfur and aromatic hydrocarbons directed to desulfurzation and reforming operations minimizes the size and weight of the overall apparatus. The process of the invention is well suited to the use of microchannel apparatuses for heat exchangers, reactors, and other system components, which may be assembled in slab configuration, further reducing system size and weight.Type: GrantFiled: June 23, 2003Date of Patent: January 15, 2008Assignee: Applied Research Associates, Inc.Inventors: Aly H. Shaaban, Timothy J. Campbell
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Patent number: 7314602Abstract: Contact, mixing, and often quenching box (8), with main dimension (D) and height (H7), comprising at least one duct section (B1) located on the upper part of said box (8) for entry of fluids in which said box (8) comprises, downstream from said duct section (B1), in the direction in which the fluids circulate, a means (B4) that provides, in said box (8), for making the fluids swirl in an approximately nonradial direction, and not parallel to the overall direction of circulation of said fluids, and comprising at least one annular, peripheral duct section (B6) for the exit of said mixture of fluids formed in said box (8) whose lower level is located above the upper level for fluid entry through at least one lateral inlet (B3) located in said box (8) above means (B4). A reaction cell (4), of an elongated shape along an approximately vertical axis comprising the contact, mixing, and quenching box (8) is useful for performing exothermic reactions.Type: GrantFiled: July 2, 2002Date of Patent: January 1, 2008Assignee: Institut Francais du PetroleInventors: Ludovic Raynal, Isabelle Harter, Francis Aubry